JP4282174B2 - Method for forming water-swellable rubber seal material - Google Patents

Method for forming water-swellable rubber seal material Download PDF

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Publication number
JP4282174B2
JP4282174B2 JP25980099A JP25980099A JP4282174B2 JP 4282174 B2 JP4282174 B2 JP 4282174B2 JP 25980099 A JP25980099 A JP 25980099A JP 25980099 A JP25980099 A JP 25980099A JP 4282174 B2 JP4282174 B2 JP 4282174B2
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JP
Japan
Prior art keywords
rubber
water
swellable rubber
swellable
width direction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP25980099A
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Japanese (ja)
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JP2001079958A (en
Inventor
真人 宮野
実 大石
實 大西
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CI Kasei Co Ltd
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CI Kasei Co Ltd
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Priority to JP25980099A priority Critical patent/JP4282174B2/en
Publication of JP2001079958A publication Critical patent/JP2001079958A/en
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Publication of JP4282174B2 publication Critical patent/JP4282174B2/en
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Description

【0001】
【発明の属する技術分野】
本発明は、シールドトンネルを構築するピース面及びリング面からなる接合面を有するセグメントの少なくとも一つの接合面において平面的に曲がり部を有するシール溝に適用される水膨張性ゴムシール材の成形方法に関するものである。
【0002】
【従来の技術】
シールドトンネルを構築するセグメントは、ピース面及びリング面を連結金具で固定連結されるが、連結金具の種類によっては、シール溝がトンネルの内側近くに設けられない場合があり、この場合、連結金具部分を回避するように平面的に曲がり部を有するシール溝が設けられる。
このようにシール溝が平面的に曲がり部を有するセグメントに使用されるシール材としては、従来、平面曲がり部に相当する部分ををプレス成形で作成し、それを直線部分と接合したり、金型に直線部分を設置し、平面曲がり部を未加硫の水膨張性ゴム材料を入れ加熱プレス成形によって一体化したものを使用していた。
【0003】
【発明が解決しようとする課題】
上述の方法では、水膨張性ゴムからなる本体部分と裏面側の幅方向の中央部分に位置する非水膨張性ゴムからなる複合構造を有する水膨張性ゴムシール材の補強層となる非水膨張性ゴムが連続した構成にならず、複合構造の利点を生かすことができないという欠点があった。
【0004】
【発明の目的】
本発明は、上記の問題点を解消するため、平面的に曲がり部においても非水膨張性ゴムの連結された補強層を持った水膨張性ゴムシール材の加工方法を提供することを目的としている。
【0005】
【課題を解決するための手段】
本発明は、シールドトンネルを構築するピース面及びリング面からなる接合面を有するセグメントの少なくとも一つの接合面において平面的に曲がり部を有するシール溝に適用される水膨張性ゴムシール材の成形方法であって、該水膨張性ゴムシール材が水膨張性ゴムからなる本体部分と裏面側の幅方向の中央部分に位置する非水膨張性ゴムからなる複合構造を有し、上記水膨張性ゴムシール材の幅方向の一方の端部から略中央部にかけてV字形状切り抜き部の加工、略中央部が連結された状態と成るように他方の端部から切れ目又は切り抜き加工を施し、該一方の端部のV字形状切り抜き部の断面にゴム系硬化接着剤を塗布し、該断面を接合すると共に、他方の端部の切れ目又は切り抜き部の開口部に水膨張性ゴムの未加硫ゴム材料を充填し、加熱プレスして該接着剤を硬化させ、および未加硫ゴム材料を加硫させることを特徴とする曲がり部を有する水膨張性ゴムシール材の成形方法である。
【0006】
また、本発明は、上記水膨張性ゴムシール材の幅方向の一方の端部から略中央部にかけてV字形状切り抜き部の加工、略中央部が連結された状態と成るように他方の端部から切れ目又は切り抜き加工を施し、該一方の端部のV字形状切り抜き部の断面にゴム系硬化接着剤を塗布し、該断面を接合し、加熱により接着剤を硬化させた後、他方の端部の切れ目又は切り抜き部の開口部に水膨張性ゴムの未加硫ゴム材料を充填し、加熱プレスして未加硫ゴム材料を加硫させることを特徴とする曲がり部を有する水膨張性ゴムシール材の成形方法である。
【0007】
本発明において使用されるゴム系硬化接着剤としては、塩素化天然ゴム、クロロプレンゴム、クロロスルフォン化ポリエチレン、ポリブタジエンゴム等のゴム成分と、テトラメチルチウラムジスルフィド、テトラメチルチウラムモノスルフィド等の低温硬化剤、フェノール樹脂、レゾール樹脂、イソシアネート等の硬化剤成分からなる2液の溶剤タイプのものを挙げることができる。これらの中でも、主剤がクロロプレンゴム系成分10〜20重量%でとなるように溶剤で希釈されたもの、硬化剤がMDI、TDI等のイソシアネート10〜40重量%となるようる溶剤で希釈さた2液タイプのものが好ましい。このような2液タイプのクロロプレンゴム・イソシアネート系硬化接着剤としては、各種の市販品を利用することができ、具体的には、横浜ゴム社製のQパック、バンドー化学社製のサンパットS、チップトップジャパン社製のSC2000、パング社製のPANGOFOL HARTER等を挙げることができる。
【0008】
【発明の実施の形態】
本発明に用いられる水膨張性ゴムシール材は、クロロプレンゴム、スチレン・ブタジエンゴム、イソプレンゴム、EPDMゴム等の各種合成ゴムを主成分とし、これに、ポリアクリル酸系、イソブチレン・無水マレイン酸系、ウレタン系、ポリビニルアルコール系等の各種水膨張性樹脂の1種又は2種以上を配合し、金属酸化物、イオウ系化合物などの加硫剤や加硫促進剤、充填剤、着色剤、軟化剤等の各種添加剤を配合した水膨張性ゴム組成物と、上記の水膨張性ゴム組成物より水膨張性樹脂を除いた非水膨張性ゴム組成物とを共押出成形し、加硫工程を経て製造される複合型のものが用いられる。
【0009】
上記の複合型水膨張性ゴムシール材の形状は、図1のシール材Aおよびシール材Bに示したとおり、裏面側の幅方向の中央部分に位置する非水膨張性ゴム1からなる補強層と水膨張性ゴム2からなる本体部分との複合構造を有している。
シール材Aは、上面がフラット形状となっており、シール材Bは、二つの半円形の凸条3を有している。
【0010】
次に図1のシール材Aを例にして、平面的に曲がり部を有する水膨張性ゴムシール材の成形方法を図2ないし図3に示す。
図2において、シール材Aは、複合構造のものを押出成形さた後、加硫されたもので、幅方向の一方の端部から略中央部にかけてV字形状に切り抜き部5の加工が施され、かつ、略中央部が連結された状態と成るように他方の端部から略U字形状の切り抜き部6の加工が施され、該一方の端部のV字形状に切り抜き部の断面4に2液タイプのクロロプレンゴム・イソシアネート系硬化接着剤を塗布し、該断面を接合すると共に、図3に示すように他方の端部の切り抜き部6の開口部に水膨張性ゴムの未加硫ゴム材料7を充填し、加熱プレスで該接着剤を硬化させ、および未加硫ゴム材料を加硫して曲がり部を有する水膨張性ゴムシール材を成形した。
【0011】
また、上記水膨張性ゴムシール材の幅方向の一方の端部から略中央部に達するV字形状に切り抜き部4の加工が施され、略中央部が連結された状態と成るように他方の端部から略U字形状の切り抜き部6の加工が施され、該一方の端部のV字形状に切り抜き部の断面4に2液タイプのクロロプレンゴム・イソシアネート系硬化接着剤を塗布し、該断面を接合し、加熱により接着剤を硬化させた後、他方の端部の切れ目又は切り抜き部の開口部6に水膨張性ゴムの未加硫ゴム材料7を充填し、加熱プレスで未加硫ゴム材料を加硫して曲がり部を有する水膨張性ゴムシール材を成形してもよい。
【0012】
上記の他方の端部の切り抜き部6の形状はV字形状やW字形状など各種の形状でもよく、また、単にカッターで切れ目を入れたものでもよく、その開口部に水膨張性ゴムの未加硫ゴム材料7を充填し、加熱プレスで未加硫ゴム材料を加硫させることによって同様の製品を成形することができる。また、未加硫ゴム材料の一部を非水膨張性ゴムに置き換えてもよい。
【0013】
【発明の効果】
以上、述べたように、水膨張性ゴムシール材の複合構造を曲がり部においても備えているので補強効果のあるシール材とすることができ、V字形状の切り抜き部の断面の接着剤としてゴム系硬化接着剤を用いているので加工時間が短く、可撓性や水膨張性を損なわない曲がり部を有する水膨張性ゴムシール材を成形することができる。
【図面の簡単な説明】
【図1】本発明に使用される水膨張性ゴムシール材の断面図である。
【図2】両端部に切り抜き部が加工された水膨張性ゴムシール材の斜視図である。
【図3】他方の端部に形成し切り抜き部の開口部に未加硫ゴム材料を充填された曲がり部を有する水膨張性ゴムシール材の斜視図である。
【符号の説明】
1・・・非水膨張性ゴム
2・・・水膨張性ゴム
3・・・半円形の凸条
4・・・一方の端部に形成されたV字形状の切り抜き部の断面
5・・・一方の端部に形成されたV字形状の切り抜き部
6・・・他方の端部に形成されたU字形状の切り抜き部
7・・・充填された未加硫ゴム材料
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for molding a water-swellable rubber seal material applied to a seal groove having a curved portion in a plane on at least one joint surface of a segment having a joint surface composed of a piece surface and a ring surface for constructing a shield tunnel. Is.
[0002]
[Prior art]
The segments that make up the shield tunnel are fixedly connected to the piece surface and ring surface with a connecting bracket, but depending on the type of connecting bracket, the seal groove may not be provided near the inside of the tunnel. A seal groove having a bent portion in a plane is provided so as to avoid the portion.
Thus, as a sealing material used for a segment in which the sealing groove has a curved portion in a plane, conventionally, a portion corresponding to the planar curved portion is formed by press molding and joined to a linear portion, A straight portion was installed in the mold, and a flat bent portion was used in which an unvulcanized water-expandable rubber material was added and integrated by hot press molding.
[0003]
[Problems to be solved by the invention]
In the above-described method, a non-water-swellable material that serves as a reinforcing layer for a water-swellable rubber sealing material having a composite structure made of a water-swellable rubber and a non-water-swellable rubber located at the center in the width direction on the back side. There is a drawback in that the rubber does not have a continuous configuration and the advantages of the composite structure cannot be utilized.
[0004]
OBJECT OF THE INVENTION
In order to solve the above-described problems, an object of the present invention is to provide a method for processing a water-swellable rubber sealing material having a reinforcing layer to which a non-water-swellable rubber is connected even in a planarly bent portion. .
[0005]
[Means for Solving the Problems]
The present invention relates to a method for forming a water-expandable rubber seal material applied to a seal groove having a bent portion in a plane on at least one joint surface of a segment having a joint surface composed of a piece surface and a ring surface constituting a shield tunnel. there are, have a composite structure consisting of a non-aqueous swellable rubber aqueous expandable rubber seal member is positioned in the body portion and the back side width direction center portion of which consists of water swellable rubber, of the water-swellable rubber sealing material and facilities for the processing of the cut-out portion of the V-shape from one end portion in the width direction toward the substantially central portion, subjected to cuts or cutting process from the other end in such a way that state that a substantially central portion is connected, the one of rubber curing adhesive is applied to the cross section of the cutout portion of the V-shaped end, with joining the cross section, unvulcanized water-swellable rubber in the opening of the cuts or cutouts of the other end Rubber Charges filled with heated press and the adhesive was cured, and an unvulcanized rubber material molding method water swellable rubber sealing member having a curved portion, characterized in that to vulcanization.
[0006]
The present invention, on the other hand in such a way that state in which facilities the processing of the cut-out portion of the V-shape toward the substantially central portion from one end portion in the width direction of the water-swellable rubber sealing member, a substantially central portion is connected end subjected to cuts or cutting process from a rubber-based curing adhesive is applied to the cross section of the cutout portion of the V-shape at one end said, joining the cross section, after curing the adhesive by heating the unvulcanized rubber material of the water-swellable rubber was filled into the openings of the cuts or cutouts of the other end, it has a bend, characterized in that for vulcanizing the heated press to unvulcanized rubber material This is a method for forming a water-swellable rubber seal material.
[0007]
Examples of rubber-based curing adhesives used in the present invention include rubber components such as chlorinated natural rubber, chloroprene rubber, chlorosulfonated polyethylene, and polybutadiene rubber, and low-temperature curing agents such as tetramethylthiuram disulfide and tetramethylthiuram monosulfide. And a two-component solvent type comprising a curing agent component such as a phenol resin, a resol resin, or an isocyanate. Among these, the main component is diluted with a solvent such that the chloroprene rubber-based component is 10 to 20% by weight, and the curing agent is diluted with a solvent such that MDI, TDI and the like isocyanate are 10 to 40% by weight. A two-component type is preferred. As such a two-pack type chloroprene rubber / isocyanate-based curing adhesive, various commercially available products can be used. Specifically, a Q-pack manufactured by Yokohama Rubber Co., a Sunpatt S manufactured by Bando Chemical Co., Ltd., Examples include SC2000 manufactured by Chip Top Japan, PANGOFOL HARTER manufactured by Pang, and the like.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
The water-swellable rubber seal material used in the present invention is mainly composed of various synthetic rubbers such as chloroprene rubber, styrene / butadiene rubber, isoprene rubber, EPDM rubber, etc., and includes polyacrylic acid, isobutylene / maleic anhydride, One or more of various water expandable resins such as urethane and polyvinyl alcohol are blended, and vulcanizing agents such as metal oxides and sulfur compounds, vulcanization accelerators, fillers, colorants, and softening agents. A water-swellable rubber composition containing various additives such as the above and a non-water-swellable rubber composition obtained by removing the water-swellable resin from the water-swellable rubber composition described above, A composite type manufactured through the process is used.
[0009]
The shape of the composite water-expandable rubber sealing material is such that, as shown in the sealing material A and the sealing material B in FIG. 1, a reinforcing layer made of the non-water-expandable rubber 1 located in the center portion in the width direction on the back side It has a composite structure with a main body portion made of water-expandable rubber 2.
The sealing material A has a flat upper surface, and the sealing material B has two semicircular ridges 3.
[0010]
Next, taking the sealing material A of FIG. 1 as an example, a method for forming a water-swellable rubber sealing material having a bent portion in plan view is shown in FIGS.
In FIG. 2, the sealing material A is a composite structure extruded and then vulcanized, and the cutout portion 5 is processed into a V shape from one end in the width direction to the substantially central portion. In addition, a substantially U-shaped cutout portion 6 is processed from the other end portion so that the substantially central portion is connected, and a cross-section 4 of the cutout portion is formed into a V shape at the one end portion. A two-component type chloroprene rubber / isocyanate-based curing adhesive is applied to each other, and the cross sections are joined together. The rubber material 7 was filled, the adhesive was cured with a hot press, and the unvulcanized rubber material was vulcanized to form a water-expandable rubber seal material having a bent portion.
[0011]
Further, the cutout portion 4 is processed into a V shape that reaches the substantially central portion from one end portion in the width direction of the water-expandable rubber seal material, and the other end is formed so that the substantially central portion is connected. A substantially U-shaped cut-out portion 6 is processed from the portion, and a two-component type chloroprene rubber / isocyanate-based cured adhesive is applied to the cross-section 4 of the cut-out portion in a V-shape at one end thereof. After the adhesive is cured by heating, the uncured rubber material 7 of the water-expandable rubber is filled in the opening 6 of the cut or cut-out portion at the other end, and the unvulcanized rubber is filled with a heating press. A water-expandable rubber seal material having a bent portion may be formed by vulcanizing the material.
[0012]
The shape of the cut-out portion 6 at the other end may be various shapes such as a V shape and a W shape, or may be simply cut with a cutter. A similar product can be formed by filling the vulcanized rubber material 7 and vulcanizing the unvulcanized rubber material with a heating press. Further, a part of the unvulcanized rubber material may be replaced with non-water-expandable rubber.
[0013]
【The invention's effect】
As described above, since the composite structure of the water-expandable rubber seal material is also provided at the bent portion, it can be used as a seal material having a reinforcing effect, and can be used as an adhesive for the cross section of the V-shaped cutout portion. Since a cured adhesive is used, a processing time is short, and a water-swellable rubber seal material having a bent portion that does not impair flexibility and water-swellability can be formed.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a water-expandable rubber seal material used in the present invention.
FIG. 2 is a perspective view of a water-expandable rubber seal material in which cutout portions are processed at both ends.
FIG. 3 is a perspective view of a water-expandable rubber seal material having a bent portion formed at the other end portion and filled with an unvulcanized rubber material at the opening of the cutout portion.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Non-water-expandable rubber 2 ... Water-expandable rubber 3 ... Semi-circular protruding item | line 4 ... Section 5 of the V-shaped cut-out part formed in one edge part ... V-shaped cutout portion 6 formed at one end portion ... U-shaped cutout portion 7 formed at the other end portion ... filled unvulcanized rubber material

Claims (2)

ピース面及びリング面からなる接合面を有するシールドトンネルを構築するセグメントの少なくとも一つの接合面において平面的に曲がり部を有するシール溝に適用される水膨張性ゴムシール材の成形方法であって、該水膨張性ゴムシール材が水膨張性ゴムからなる本体部分と裏面側の幅方向の中央部分に位置する非水膨張性ゴムからなる複合構造を有し、上記水膨張性ゴムシール材の幅方向の一方の端部から略中央部にかけてV字形状切り抜き部の加工、略中央部が連結された状態と成るように他方の端部から切れ目又は切り抜き加工を施し、該一方の端部のV字形状切り抜き部の断面にゴム系硬化接着剤を塗布し、該断面を接合すると共に、他方の端部の切れ目又は切り抜き部の開口部に未加硫ゴム材料を充填し、加熱プレスして該接着剤を硬化させ、および未加硫ゴム材料を加硫させることを特徴とする曲がり部を有する水膨張性ゴムシール材の成形方法。 A method for forming a water-expandable rubber seal material applied to a seal groove having a bent portion in a plane on at least one joint surface of a segment that constructs a shield tunnel having a joint surface composed of a piece surface and a ring surface , have a composite structure water swellable rubber seal member is made of a non-aqueous swellable rubber located on the body portion and the back side width direction center portion of which consists of water swellable rubber, one of the width direction of the water-swellable rubber sealing material from the end to facilities the processing of the cut-out portion of the V-shape toward the substantially central portion, subjected to cuts or cutting process from the other end in such a way that state that a substantially central portion is connected, at one end said of the rubber curing adhesive is applied to the cross section of the cutout portion of the V-shaped, with joining the cross section, filled with unvulcanized rubber material in the openings of the cuts or cutouts of the other end, heat press Adhesive is cured, and the molding method of the water-swellable rubber sealing material an unvulcanized rubber material having a curved portion, characterized in that to vulcanized Te. ピース面及びリング面からなる接合面を有するシールドトンネルを構築するセグメントの少なくとも一つの接合面において平面的に曲がり部を有するシール溝に適用される水膨張性ゴムシール材の成形方法であって、該水膨張性ゴムシール材が水膨張性ゴムからなる本体部分と裏面側の幅方向の中央部分に位置する非水膨張性ゴムからなる複合構造を有し、上記水膨張性ゴムシール材の幅方向の一方の端部から略中央部にかけてV字形状切り抜き部の加工、略中央部が連結された状態と成るように他方の端部から切れ目又は切り抜き加工を施し、該一方の端部のV字形状切り抜き部の断面にゴム系硬化接着剤を塗布し、該断面を接合し、加熱により接着剤を硬化させた後、他方の端部の切れ目又は切り抜き部の開口部に未加硫ゴム材料を充填し、加熱プレスして未加硫ゴム材料を加硫させることを特徴とする曲がり部を有する水膨張性ゴムシール材の成形方法。 A method for forming a water-expandable rubber seal material applied to a seal groove having a bent portion in a plane on at least one joint surface of a segment that constructs a shield tunnel having a joint surface composed of a piece surface and a ring surface , have a composite structure water swellable rubber seal member is made of a non-aqueous swellable rubber located on the body portion and the back side width direction center portion of which consists of water swellable rubber, one of the width direction of the water-swellable rubber sealing material from the end to facilities the processing of the cut-out portion of the V-shape toward the substantially central portion, subjected to cuts or cutting process from the other end in such a way that state that a substantially central portion is connected, at one end said of the rubber curing adhesive is applied to the cross section of the cutout portion of the V-shape, by joining the cross section, after curing the adhesive by heating, the unvulcanized the opening of the cuts or cutouts of the other end Rubber Molding process of water-swellable rubber sealing member having a curved portion, characterized in that fee was filled, thereby vulcanizing the heated press to unvulcanized rubber material.
JP25980099A 1999-09-14 1999-09-14 Method for forming water-swellable rubber seal material Expired - Fee Related JP4282174B2 (en)

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