JP4228549B2 - Seasoning production method - Google Patents

Seasoning production method Download PDF

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Publication number
JP4228549B2
JP4228549B2 JP2001065270A JP2001065270A JP4228549B2 JP 4228549 B2 JP4228549 B2 JP 4228549B2 JP 2001065270 A JP2001065270 A JP 2001065270A JP 2001065270 A JP2001065270 A JP 2001065270A JP 4228549 B2 JP4228549 B2 JP 4228549B2
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Japan
Prior art keywords
bonito
flavor
extract
solution
taste
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JP2001065270A
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Japanese (ja)
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JP2002262821A (en
Inventor
幸宏 松浦
素央 黒田
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Ajinomoto Co Inc
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Ajinomoto Co Inc
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Description

【0001】
【発明の属する技術分野】
本発明は、鰹節だしよりも「生臭み」「苦味」がなく、「あつみ」「こく」が強く、熱安定性の良好な、鰹節だし様の香り、風味、呈味を持つ調味料の製造方法に関する。
【0002】
【従来の技術】
鰹節だしを代表とする天然の魚節だしは、独特の呈味、風味を有するが、「生臭み」「苦味」などの好ましくない呈風味が加熱時により強くなる、また保存時にも生臭さが強くなる、あるいは腐敗しやすいなど、その安定性に問題がある。
【0003】
一方、日本特許2893839号に記載があるように、イノシン酸、ヒスチジン、グルタミン酸、乳酸、塩化ナトリウム、塩化カリウムを特定比率で含有する溶液に、液体又は超臨界炭酸ガス抽出により調製した鰹節フレーバーを配合した鰹節風味調味料を用いることで、鰹節だしの持つ問題点は改善されつつあるが、「あつみ」や「こく」といった鰹節だし呈味機能、「スッキリした香り、風味」といった鰹節だしの風味機能は満足すべき水準には至っていない。
【0004】
また、食品に「あつみ」や「こく」を付与するものとして牛肉や、鶏がら、魚介類など動物性タンパク質の抽出だしあるいは抽出エキスを用いることがあるが、加熱や保存により独特の「生臭み」が増大する等の理由で、和風だし系食品では大量に使用することができず、付与される「あつみ」や「こく」も満足されるものではなかった。
【0005】
【発明が解決しようとする課題】
前項に記載されたような、天然の鰹節だしのもつ問題点、あるいは従来技術による鰹節風味調味料のもつ問題点を解決し、だし様調味料として満足しうる「あつみ」や「こく」を付与し、熱安定性、品質の良好な鰹節だし様の風味調味料素材の製造方法に得ることを目的とする。
【0006】
【課題を解決するための手段】
本発明者は、上記課題の解決につき鋭意工夫を重ねた結果、エタノールを配合した特定比率の溶液、即ち、乳酸、ヒスチジン、イノシン酸、グルタミン酸、塩化ナトリウム、塩化カリウム、エタノールをある配合で調製した溶液に、液体または超臨界炭酸ガス抽出により調製した鰹節風味を有する抽出物(フレーバー成分)を配合することにより、鰹節だし様の呈味と香り風味を持ち、熱安定性が良好で、さらに「あつみ」や「こく」、「スッキリした香り、風味」を兼ね備える調味料が得られることを見出し、本発明を完成したものである。
【0007】
即ち、本発明は、成分として重量比で乳酸を100として、ヒスチジンを20〜200、イノシン酸を5〜50、グルタミン酸を0.5〜100、塩化ナトリウムを5〜150、塩化カリウムを5〜100、エタノールを5〜2000の重量比率にて配合した溶液に、液体または超臨界炭酸ガス抽出により調製した鰹節風味を有する抽出物を配合することを特徴とする調味料の製造方法であり、「生臭み」や「苦味」がなく、従来技術にない「あつみ」や「こく味」、「スッキリした香り、風味」を兼ね備え、加熱時に「生臭み」や「苦味」のほとんど生じない調味料が得られることを見出し、完成したものである。またさらに、この調味料に動物性タンパク質含有エキス及び/または動物エキス中のタンパク質画分を配合することで、「生臭さ」などのクセのなく、鰹節だしらしい「あつみ」や「こく」が強化できることを見出した。
【0008】
本発明に用いる乳酸は、乳酸ナトリウム、乳酸カルシウム(無水)、乳酸カルシウム5水和塩など、および乳酸そのものを用いて添加することが可能である。ヒスチジンは、ヒスチジン塩基、ヒスチジン塩酸塩またはイノシン酸ヒスチジン塩などを用いることにより、添加することが可能である。イノシン酸は、イノシン酸ナトリウム、イノシン酸カリウム、イノシン酸カルシウム、イノシン酸ヒスチジン塩などを用いて添加することが可能である。グルタミン酸は、グルタミン酸ナトリウム、グルタミン酸カリウム、タンパク質加水分解物から得られるグルタミン酸、グルタミン酸そのものなどを用いて添加することが可能である。塩化ナトリウムは、精製塩化ナトリウム、岩塩、海水塩、ミネラル含有塩などその由来は特に限定されずに用いて添加することが可能である。塩化カリウムは、精製塩化カリウム、海水から塩化ナトリウムを製造する際に副生する「にがり」など塩化カリウムを含有する素材を用いることが可能である。エタノールは、醸造アルコールや工業的に製造されたアルコール、変性アルコールなどの食用として用いられるエタノール水溶液を用いて添加することが可能である。エタノールの比率はイノシン酸に対し5〜2000の重量比であり、調味料中のエタノール総量は0.5〜15%が好ましい。また、鰹節風味を有する抽出物は日本特許2893839号に記載されているような、鰹節粉砕品を液体あるいは超臨界炭酸ガス抽出により調製されたものを用いるが、鰹節のアルコール抽出あるいは熱水抽出により調製された鰹節風味を有する抽出物を用いることも可能である。
【0009】
また本発明に用いられる動物性タンパク質含有エキスは、魚介類や畜肉などを60℃以上の熱水等で5分間以上煮熟して抽出しただしやエキス、あるいはそれらの濃縮エキスが主に用いられるが、その他の方法でタンパク質溶液を調製して用いることも可能である。好ましくは、これらの動物性タンパク質水溶液をpH3.5〜5.5に調整することによって生じる凝集分を遠心分離などで取り出し、pHを中性にし再度溶解したものを用いるか、これを更に精製したものを再溶解したものを用いることができる。
【0010】
【発明の実施の形態】
以下、実施例によって本発明をさらに詳細に説明するが、本発明の利用範囲はこれらによって限定されるものではない。
【0011】
【実験例1】
鰹荒本節をハンマークラッシャー粉砕機で粉砕し、得られた粉砕物2kgにエタノール600gと水600gを噴霧し、液体の二酸化炭素(25℃、60気圧)で2時間抽出し、抽出物約700gを得た。得られた抽出物は良好な鰹節風味を有した。
【0012】
【実験例2】
50%乳酸ナトリウム400mg、ヒスチジン塩酸塩130mg、イノシン酸ナトリウム35mg、グルタミン酸ナトリウム4mg、塩化ナトリウム50mg、塩化カリウム60mg、エタノール2000mgを水に溶解させ、100mlに定容した。この溶液は、鰹節だし様の呈味を持つ呈味溶液であった。
【0013】
【実験例3】
熱水1000mlに生鰹可食部200gを入れ、95℃で1時間煮熟し、鰹煮汁を得た。
【0014】
【実験例4】
実験例3でえられた煮汁500mlに塩酸を加えpH4.2に調整し、遠心分離により沈殿物を湿重量で11mg得た。この沈殿物10mgに水100mlを加えて分散させ、水酸化ナトリウムを加えてpH7.0に調整して鰹煮汁タンパク質溶液を得た。
【0015】
【実験例5】
鰹荒本節を鰹節削り機で削り、得られた削り節40gに沸騰水1000mlを加えて1分間後にろ布でろ過し、鰹節だしを得た。
【0016】
【実施例1】
実験例2で得られた呈味溶液に、実験例1で得た鰹節風味を有する抽出物を0.1%加えることにより、スッキリした鰹節様の香り、風味、味を持つ溶液を得た。
【0017】
実験例5で得られた天然の鰹節だしは90℃、2時間の加熱をすると、生臭みや苦味が生成し、独特の「あつみ」や「こく」が弱まったのに対し、上記呈味溶液に鰹節風味を有する抽出物を加えて得られた溶液は、90℃、2時間の加熱後も「生臭み」や「苦味」がほとんどなく良好な味、風味を有し、香りもスッキリしていた。従って、本発明により得られた溶液は天然の鰹節だしより熱安定性の良いものであることがわかった。
【0018】
【実施例2】
実験例2で得られた呈味溶液に、実験例1で得た鰹節風味を有する抽出物を0.1%加え、さらに実験例3で得られた鰹煮汁を1%加えることにより、鰹節様の香り、風味、味、「あつみ」を持つ溶液を得た。
【0019】
実験例5で得られた天然の鰹節だしは、121℃、10分間の加熱をすると、「苦味」が強まり、独特の「あつみ」や「こく」が弱まったのに対し、上記呈味溶液に鰹節風味を有する抽出物と鰹煮汁を加えて得られた溶液は、121℃、10分間の加熱後も「苦味」が強まることがなく、鰹節だしらしい「あつみ」や「こく」、「スッキリした香り」を維持していた。従って、本発明により得られた溶液は天然の鰹節だしより熱安定性の良いものであることがわかった。
【0020】
【実施例3】
実験例2で得られた呈味溶液に、実験例1で得た鰹節風味を有する抽出物を0.1%加え、さらに実験例4で得られた鰹煮汁タンパク質溶液を1%加えることにより、鰹節様の香り、風味、味、「あつみ」を持つ溶液を得た。
【0021】
実験例5で得られた天然の鰹節だしは、130℃、1分間の加熱をすると、苦味が強まり、独特の「あつみ」や「こく」が弱まったのに対し、上記呈味溶液に鰹節フレーバーと鰹煮汁タンパク質を加えて得られた溶液は、130℃、1分間の加熱後も苦味が強まることがなく、鰹節だしらしい「あつみ」や「こく」、「スッキリした香り」を維持していた。従って、本発明により得られた溶液は天然の鰹節だしより熱安定性の良いものであることがわかった。
【0022】
【実施例4】
実験例2の中でエタノールのみを除外した呈味溶液に、実験例1で得た鰹節風味を有する抽出物を0.1%加えたものは、90℃、10分間の加熱後に鰹節だしらしい「スッキリした香り、風味」が消失し、フレッシュな鰹節だし様の特徴が弱まったのに対し、実験例2で得られた呈味溶液に、実験例1で得た鰹節風味を有する抽出物を0.1%加えた得られた溶液は、90℃、10分間の加熱後も、鰹節だしらしい「スッキリした香り、風味」を保持し、フレッシュな鰹節だし様の特徴を維持していた。従って、本発明により得られた溶液は、エタノールを添加しないものより熱安定性の良いものであることがわかった。
【0023】
【発明の効果】
以上に示したように、乳酸、ヒスチジン、イノシン酸、グルタミン酸、塩化ナトリウム、塩化カリウム、エタノールをある配合で調製した溶液に、液体または超臨界炭酸ガス抽出により調製した鰹節風味を有する抽出物を配合する、好ましくはさらに動物性タンパク質を含有するエキスを配合することにより、鰹節だし様の呈味と香り風味を持ち、熱安定性が良好で、さらに「あつみ」や「こく」、「スッキリした香り、風味」を兼ね備える調味料が得ることができる。
[0001]
BACKGROUND OF THE INVENTION
The present invention is a production of a seasoning that has no odor, bitter taste, strong atsumi and koku, and good thermal stability, and has a bonito soup-like scent, flavor and taste. Regarding the method.
[0002]
[Prior art]
Natural fish bouillon stock, such as bonito stock, has a unique taste and flavor, but unpleasant flavors such as `` raw odor '' and `` bitter taste '' become stronger when heated, and the raw odor is also preserved during storage. There are problems with its stability, such as becoming stronger or prone to corruption.
[0003]
On the other hand, as described in Japanese Patent No. 2893839, a solution containing inosinic acid, histidine, glutamic acid, lactic acid, sodium chloride, potassium chloride in a specific ratio is blended with bonito flavor prepared by liquid or supercritical carbon dioxide extraction By using the dried bonito flavoring seasoning, the problems of bonito soup stock are being improved, but bonito soup flavoring functions such as “Atsumi” and “Koku” and “fresh fragrance, flavor” Has not reached a satisfactory level.
[0004]
In addition, animal foods such as beef, chicken, and seafood may be extracted or extracted to add “atsumi” or “koku” to foods. "Increased", etc., could not be used in large quantities in Japanese-style soup-type foods, and the "Atsumi" and "Koku" provided were not satisfactory.
[0005]
[Problems to be solved by the invention]
Solves the problems of natural bonito soup stock, as described in the previous section, or the problems of traditional bonito flavor seasonings, and gives "Atsumi" and "Koku" that are satisfactory as soup-like seasonings And it aims at obtaining in the manufacturing method of the flavor seasoning raw material of the bonito-dashi-like taste with favorable heat stability and quality.
[0006]
[Means for Solving the Problems]
As a result of intensive efforts to solve the above problems, the present inventor prepared a solution in a specific ratio containing ethanol, that is, lactic acid, histidine, inosinic acid, glutamic acid, sodium chloride, potassium chloride, and ethanol with a certain composition. By blending the solution with an extract with a bonito flavor (flavor component) prepared by liquid or supercritical carbon dioxide extraction, it has a bonito soup-like taste and fragrance, good thermal stability, The present invention has been completed by finding that a seasoning having both “Atsumi”, “Koku”, and “Natural fragrance and flavor” can be obtained.
[0007]
That is, the present invention provides lactic acid as a component at a weight ratio of 100, histidine from 20 to 200, inosinic acid from 5 to 50, glutamic acid from 0.5 to 100, sodium chloride from 5 to 150, potassium chloride from 5 to 100. , A method for producing a seasoning comprising blending an extract having a bonito flavor prepared by liquid or supercritical carbon dioxide extraction into a solution in which ethanol is blended at a weight ratio of 5 to 2000, There is no “odor” or “bitterness”, and there are “atsumi”, “kokumi”, “clean fragrance, and flavor” that are not found in the conventional technology, and a seasoning that produces almost no “fresh smell” or “bitterness” when heated is obtained. Is found and completed. Furthermore, by adding the animal protein-containing extract and / or the protein fraction in the animal extract to this seasoning, there is no habit such as “fresh odor” and the “atsumi” and “koku” that are typical of bonito are strengthened. I found out that I can do it.
[0008]
The lactic acid used in the present invention can be added using sodium lactate, calcium lactate (anhydrous), calcium lactate pentahydrate, etc., and lactic acid itself. Histidine can be added by using histidine base, histidine hydrochloride, inosinic acid histidine salt, or the like. Inosinic acid can be added using sodium inosinate, potassium inosinate, calcium inosinate, histidine inosinate, or the like. Glutamic acid can be added using sodium glutamate, potassium glutamate, glutamic acid obtained from a protein hydrolyzate, glutamic acid itself, or the like. The origin of sodium chloride can be added without being particularly limited, such as purified sodium chloride, rock salt, sea salt, mineral-containing salt. As potassium chloride, it is possible to use a material containing potassium chloride such as refined potassium chloride or “nigiri” which is produced as a by-product when sodium chloride is produced from seawater. Ethanol can be added using an aqueous ethanol solution used for foods such as brewed alcohol, industrially produced alcohol, and denatured alcohol. The ratio of ethanol is 5 to 2000 by weight with respect to inosinic acid, and the total amount of ethanol in the seasoning is preferably 0.5 to 15%. In addition, an extract having a bonito flavor is prepared by liquid or supercritical carbon dioxide extraction of a bonito pulverized product as described in Japanese Patent No. 2889339, but it is obtained by alcohol extraction or hot water extraction of bonito. It is also possible to use an extract having a prepared bonito flavor.
[0009]
In addition, the animal protein-containing extract used in the present invention is obtained by simmering and extracting fish and shellfish or livestock meat in hot water at 60 ° C. or higher for 5 minutes or more. However, extracts or concentrated extracts thereof are mainly used. However, it is also possible to prepare and use a protein solution by other methods. Preferably, the aggregate produced by adjusting these animal protein aqueous solutions to pH 3.5 to 5.5 is removed by centrifugation or the like, and the pH is neutralized and dissolved again or further purified. What dissolved the thing again can be used.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, the utilization range of this invention is not limited by these.
[0011]
[Experiment 1]
鰹 Aramoto clause is pulverized with a hammer crusher pulverizer, 2 g of the obtained pulverized product is sprayed with 600 g of ethanol and 600 g of water, extracted with liquid carbon dioxide (25 ° C., 60 atm) for 2 hours, and about 700 g of extract is obtained. Obtained. The resulting extract had a good bonito flavor.
[0012]
[Experimental example 2]
50% sodium lactate 400 mg, histidine hydrochloride 130 mg, sodium inosinate 35 mg, sodium glutamate 4 mg, sodium chloride 50 mg, potassium chloride 60 mg and ethanol 2000 mg were dissolved in water and made up to a volume of 100 ml. This solution was a taste solution having a taste like bonito soup stock.
[0013]
[Experiment 3]
200 g of ginger edible portion was put in 1000 ml of hot water and boiled and ripened at 95 ° C. for 1 hour to obtain boiled soup.
[0014]
[Experimental Example 4]
Hydrochloric acid was added to 500 ml of the boiled juice obtained in Experimental Example 3 to adjust the pH to 4.2, and the precipitate was obtained in a wet weight of 11 mg by centrifugation. 100 mg of water was added to 10 mg of the precipitate to disperse, and sodium hydroxide was added to adjust the pH to 7.0 to obtain a boiled soup protein solution.
[0015]
[Experimental Example 5]
The koji Aramoto kushi was shaved with a koji shaving machine, and 1000 ml of boiling water was added to 40 g of the kneading knot, and filtered with a filter cloth after 1 minute to obtain a koji kashi stock.
[0016]
[Example 1]
By adding 0.1% of the extract having the bonito flavor obtained in Experimental Example 1 to the taste solution obtained in Experimental Example 2, a solution having a refreshing bonito-like fragrance, flavor and taste was obtained.
[0017]
The natural bonito stock obtained in Experimental Example 5 was heated at 90 ° C. for 2 hours to produce a raw odor and bitterness, while the characteristic “Atsumi” and “Koku” were weakened. The solution obtained by adding the extract with bonito flavor had a good taste and flavor and a refreshing fragrance even after heating at 90 ° C. for 2 hours, with almost no “fresh smell” or “bitter taste”. . Therefore, it was found that the solution obtained by the present invention has better thermal stability than natural bonito stock.
[0018]
[Example 2]
By adding 0.1% of the extract having the bonito flavor obtained in Experimental Example 1 to the taste solution obtained in Experimental Example 2, and further adding 1% of the bonito soup obtained in Experimental Example 3, A solution with aroma, flavor, taste and “Atsumi” was obtained.
[0019]
The natural bonito broth obtained in Experimental Example 5 was heated at 121 ° C. for 10 minutes, while its “bitterness” became stronger and the unique “Atsumi” and “Koku” became weaker. The solution obtained by adding the extract with bonito flavor and bonito soup does not increase the “bitterness” after heating at 121 ° C. for 10 minutes, and the “atsumi”, “koku”, “refreshing” The scent was maintained. Therefore, it was found that the solution obtained by the present invention has better thermal stability than natural bonito stock.
[0020]
[Example 3]
By adding 0.1% of the extract having the bonito flavor obtained in Experimental Example 1 to the taste solution obtained in Experimental Example 2, and further adding 1% of the bonito soup protein solution obtained in Experimental Example 4, A solution with bonito-like fragrance, flavor, taste and “Atsumi” was obtained.
[0021]
The natural bonito stock obtained in Experimental Example 5 was heated at 130 ° C. for 1 minute, but its bitterness became stronger and the unique “Atsumi” and “Koku” were weakened. And the solution obtained by adding the soy sauce protein did not increase the bitterness after heating at 130 ° C for 1 minute, and maintained the “atsumi”, “koku”, and “fresh fragrance” that are typical of bonito. . Therefore, it was found that the solution obtained by the present invention has better thermal stability than natural bonito stock.
[0022]
[Example 4]
A sample obtained by adding 0.1% of the extract having the bonito flavor obtained in Experimental Example 1 to the taste solution excluding only ethanol in Experimental Example 2 seems to be bonito after heating at 90 ° C. for 10 minutes. The “fresh fragrance and flavor” disappeared and the characteristics of fresh bonito soup were weakened. On the other hand, the extract with the bonito flavor obtained in Experimental Example 1 was added to the taste solution obtained in Experimental Example 2. The solution obtained by adding 1% retained the “fresh fragrance and flavor” that was typical of bonito after heating at 90 ° C. for 10 minutes and maintained the characteristics of fresh bonito. Therefore, it was found that the solution obtained according to the present invention was better in thermal stability than that without adding ethanol.
[0023]
【The invention's effect】
As shown above, lactic acid, histidine, inosinic acid, glutamic acid, sodium chloride, potassium chloride, and a solution prepared by mixing with ethanol are combined with an extract with bonito flavor prepared by liquid or supercritical carbon dioxide extraction In addition, by adding an extract containing animal protein, it has the taste and fragrance flavor of bonito soup, has good heat stability, and is also good for “Atsumi”, “Koku”, “Natural scent” , Flavor "can be obtained.

Claims (1)

成分として重量比で乳酸を100として、ヒスチジンを20〜200、イノシン酸を5〜50、グルタミン酸を0.5〜100、塩化ナトリウムを5〜150、塩化カリウムを5〜100、エタノールを5〜2000の比率で含有する溶液に、液体または超臨界炭酸ガス抽出により調製した鰹節風味を有する抽出物を配合し、動物性タンパク質水溶液のpHを3.5〜5.5に調整することにより分画される成分を配合し、かつ調味料中のエタノール総量が0.5〜15%であることを特徴とする調味料の製造方法。As a component, lactic acid is 100 by weight, histidine is 20 to 200, inosinic acid is 5 to 50, glutamic acid is 0.5 to 100, sodium chloride is 5 to 150, potassium chloride is 5 to 100, and ethanol is 5 to 2000. The extract containing a liquid or supercritical carbon dioxide gas-extracted extract with a bonito flavor is blended with the solution containing the ratio of the above and the pH of the aqueous animal protein solution is adjusted to 3.5 to 5.5. And the total amount of ethanol in the seasoning is 0.5 to 15% .
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JP4579168B2 (en) * 2006-02-27 2010-11-10 花王株式会社 Container liquid seasoning
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