JP4209229B2 - Sludge treatment method - Google Patents

Sludge treatment method Download PDF

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Publication number
JP4209229B2
JP4209229B2 JP2003078052A JP2003078052A JP4209229B2 JP 4209229 B2 JP4209229 B2 JP 4209229B2 JP 2003078052 A JP2003078052 A JP 2003078052A JP 2003078052 A JP2003078052 A JP 2003078052A JP 4209229 B2 JP4209229 B2 JP 4209229B2
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JP
Japan
Prior art keywords
sludge
quicklime
cement
vehicle
containing material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2003078052A
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Japanese (ja)
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JP2004284866A (en
Inventor
明生 西田
透 足立
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Ube Corp
Original Assignee
Mitsubishi Materials Corp
Ube Industries Ltd
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Priority to JP2003078052A priority Critical patent/JP4209229B2/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2/00Lime, magnesia or dolomite
    • C04B2/02Lime
    • C04B2/04Slaking
    • C04B2/06Slaking with addition of substances, e.g. hydrophobic agents ; Slaking in the presence of other compounds
    • C04B2/066Making use of the hydration reaction, e.g. the reaction heat for dehydrating gypsum; Chemical drying by using unslaked lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Sludge (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、各種汚泥をセメント原料の一つとして使用する汚泥の処理方法に関する。具体的には、特定の車両及び生石灰含有物質を用いることにより、各種汚泥を効率的に脱水処理し、運搬、貯蔵等を容易にする方法に関する。
【0002】
【従来の技術】
汚泥の処理方法としては、既に種々の方法が提案されているが、セメント原料としての使用は、処理可能量が非常に大きく、かつ資源の再利用が可能という利点を有する。これらの中でも、各種汚泥に生石灰含有物質を混合後、セメント原料に使用する技術が種々開発されている。この方法は、有望なものであるが、含水率の高い汚泥をその発生源から、処理地であるセメント工場に運ぶのには種々の問題がある。
例えば、特許文献1には、脱水処理設備を車両に搭載することにより、含水率を下げて移動可能とし、複数の中小規模の汚泥処理施設において1つの脱水処理設備を共用し、設備の稼働率を上げると共に、処理コストを削減する技術が開示されている。この方法は、汚泥運搬の観点からは有効な方法であるが、脱水処理設備を搭載した他への流用が困難な特殊な車両を新たに必要とするだけでなく、脱水処理設備を搭載した車両と搬送用車両の2種類の車両を用意する必要があった。また、積み替え作業回数も多く、実用上、改善を要するものであった。
【0003】
【特許文献1】
特開平11−42500号公報
【0004】
【発明が解決しようとする課題】
本発明は、特殊車両を必要とせず、且つ積み替え回数の少ないセメント原料用汚泥運搬方法の提供を目的とする。
【0005】
【課題を解決するための手段】
本発明者は、コンクリート運搬に一般的に使用されている生コンクリート用アジテーター車の利用が、上記課題を解決した方法となることを見出し、本発明を完成した。
すなわち、本発明は、生石灰含有材料を生コンクリート用アジテーター車で汚泥発生場所に搬送し、同所にて汚泥を受入れた後、生石灰含有材料と汚泥とを混合しながらセメント製造工場に搬送し、該搬送された生石灰含有材料と汚泥との混合物を、セメント原料の一種として使用することを特徴とする汚泥の処理方法に関する。
また、本発明は、上記発明における生石灰含有材料として、セメント製造装置のプレヒーター部分より取出された仮焼中間原料を使用することを特徴とする汚泥の処理方法に関する。
以下に、本発明を詳細に説明する。
【0006】
【発明の実施の形態】
本発明における汚泥とは、下水処理汚泥、屎尿処理施設で排出される汚泥、家庭排水処理汚泥、産業排水処理汚泥、浚渫汚泥等の一般的に汚泥と称するもの全てを指し、これ等は全て本発明の方法の適用対象となる。
【0007】
本発明におけるアジテーター車とは、生コンクリート工場で製造した生コンクリートを打設現場へ運搬する為に一般的に用いられている車両である。運搬中におけるコンクリートの材料分離を防止する為に、コンクリートを回転容器内で攪拌する装置を積載しており、本発明における、汚泥と生石灰含有材料の混合に好適に使用できる。
本発明の目的には、上記攪拌装置の装着さえあれば十分目的が達せられるが、運送中の臭気拡散防止の為、投入口に脱臭装置を具備していれば、更に好適である。
【0008】
更に、汚泥発生場所よっては、汚泥のアジテーター車への移送に適し搬送装置を持たないところも在るため、アジテーター車にはベルトコンベアー等の汚泥投入装置を具備しているのが好ましい。
【0009】
本発明で使用出来る生石灰含有材料としては、石灰石の焼成により得られる通常の生石灰が使用可能であるが、セメント製造装置のプレヒーター部分より取出された仮焼中間原料(以下、仮焼中間原料という。)の使用が経済的であるのに加え、セメント工場内で入手可能という点で好ましい。仮焼中間原料とは、セメント原料焼成装置のプレヒーター部分より取り出される、生石灰を主成分とする固形物であり、一般的には、セメント製造装置のプレヒーター部分である最下段のサイクロンの下部出口付近に設けられた分取ダンパーより抜き出すことにより得られる。
【0010】
アジテーター車への生石灰含有材料の積載は、当該原料の調達が可能である処であれば何処でも行うことが出来るが、セメント製造工場で実施するのが、当然、好ましい。尚、生石灰含有材料の積載は、生コンクリートプラントにおける生コンの積載と同一の方法で行うことが出来る。
生石灰含有材料を搭載したアジテーター車は、汚泥発生現場まで運転されるが、運転中は、生コンクリート搬送とは異なり、積載された生石灰含有材料の攪拌は必要ではない。
【0011】
汚泥発生現場では、車載のベルトコンベアー或いは汚泥発生個所に設置された搬送装置を使用して汚泥を、アジテーター車に搬送し、搭載されている生石灰含有材料との攪拌を開始する。
汚泥と含生石灰材料の配合比は、含水量、含有成分種等の汚泥特性、及び、脱水材である生石灰含有量、粒径等、含生石灰材料種に依存して決めることになるが、混合攪拌後の混合物の状態がケーキ状となる様な配合比とするのが好ましい。具体的には、例えば、生石灰材料として仮焼中間原料、汚泥として含水率75%の下水汚泥を、それぞれ使用した場合、混合比としては、生石灰材料1質量部に対して、汚泥10質量部程度が好ましい。また、攪拌速度としては、アジテーター車の通常の回転速度である1分当たり1〜10回の回転速度が使用出来る。
汚泥を積載後のアジーテーター車は、攪拌混合を続けながら、セメント製造工場に戻ることになる。
以下では、具体例を示し、本発明を更に詳細に説明する。
【0012】
【実施例】
セメント工場のプレヒーターの最下段サイクロン下部から分取した仮焼中間原料を300Kg、小型アジテータ車(公称4t車、内容量1.75m)に積載した。用いたアジテーター車は、生コンクリート搬送用として一般的に用いられるものである。
【0013】
仮焼中間原料を積載したアジテーター車を、セメント工場から約7km離れた下水汚泥貯留地まで運転した。
【0014】
下水汚泥貯留地において、含水率75%の下水汚泥を、3000Kgベルトコンベアーでアジテーター車に投入した。投入後、アジテーター車のドラムを回転しながら、セメント工場に戻った。
【0015】
セメント工場において、アジテーター車により移動中に混合した仮焼中間原料と下水汚泥との混合物の温度は約80℃であった。また、粒状であり、運搬、輸送等における取扱性も良好であった。
【0016】
セメント工場において、仮焼中間原料と下水汚泥との混合物は、一般の生コンクリートの排出方法と同様の方法で車載回転容器から取り出し、セメント製造原料の一つとして他の通常のセメント製造原料として用いたところ、何等問題も無くセメント製造が可能であった。
【0017】
【発明の効果】
本発明の方法によれば、汚泥発生地からの汚泥の運搬に、生コンクリート用アジテーター車を利用することにより、専用の特殊車輌としないことから新たな設備投資の必要が無く汚泥を処理することが出来る。又、混合・運搬が一つの車輌で行なえることから積み替え回数を低減出来るだけでなく、運搬時間を混合に使うことも可能であり、時間的なロス無く、効率的に汚泥を処理することが可能である。
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a sludge treatment method using various sludges as one of cement raw materials. Specifically, the present invention relates to a method of efficiently dehydrating various sludges by using a specific vehicle and quicklime-containing material, and facilitating transportation, storage, and the like.
[0002]
[Prior art]
Various methods for treating sludge have already been proposed, but use as a cement raw material has the advantage that the amount that can be treated is very large and the resources can be reused. Among these, various technologies have been developed for use in cement raw materials after mixing quicklime-containing materials with various sludges. Although this method is promising, there are various problems in carrying sludge having a high water content from its source to a cement factory as a treatment site.
For example, Patent Document 1 discloses that a dehydration facility is mounted on a vehicle so that the moisture content can be lowered and moved, and a single dewatering facility is shared among a plurality of small and medium-sized sludge treatment facilities. And a technique for reducing the processing cost is disclosed. This method is effective from the viewpoint of transporting sludge, but it requires not only a special vehicle that is difficult to divert to other equipment equipped with dewatering equipment, but also a vehicle equipped with dewatering equipment. It was necessary to prepare two types of vehicles: a vehicle for transportation. In addition, the number of times of transshipment was large, and practical improvements were required.
[0003]
[Patent Document 1]
Japanese Patent Laid-Open No. 11-42500
[Problems to be solved by the invention]
An object of this invention is to provide the sludge conveyance method for cement raw materials which does not require a special vehicle and has few transshipments.
[0005]
[Means for Solving the Problems]
The present inventor has found that the use of an agitator vehicle for ready-mixed concrete, which is generally used for transporting concrete, can be a method for solving the above problems, and has completed the present invention.
That is, the present invention transports quicklime-containing material to a place where sludge is generated with an agitator car for ready-mixed concrete, and after receiving the sludge at the same place, transports it to a cement manufacturing plant while mixing the quicklime-containing material and sludge, The present invention relates to a method for treating sludge, characterized in that the transported mixture of quicklime-containing material and sludge is used as a kind of cement raw material.
Moreover, this invention relates to the processing method of the sludge characterized by using the calcining intermediate raw material taken out from the preheater part of the cement manufacturing apparatus as the quicklime containing material in the said invention.
The present invention is described in detail below.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
The sludge in the present invention refers to all generally called sludge such as sewage treatment sludge, sludge discharged from sewage treatment facilities, domestic wastewater treatment sludge, industrial wastewater treatment sludge, wastewater sludge, etc. It becomes an object of application of the method of the invention.
[0007]
The agitator vehicle in the present invention is a vehicle that is generally used for transporting ready-mixed concrete manufactured in a ready-mixed concrete factory to a setting site. In order to prevent material separation of the concrete during transportation, a device for stirring the concrete in the rotating container is loaded, which can be suitably used for mixing sludge and quicklime-containing material in the present invention.
For the purpose of the present invention, the above-mentioned purpose can be sufficiently achieved as long as the above-mentioned stirring device is mounted. However, it is more preferable that a deodorizing device is provided at the inlet in order to prevent odor diffusion during transportation.
[0008]
Furthermore, depending on the place where the sludge is generated, there are some places that do not have a transfer device suitable for the transfer of sludge to the agitator vehicle. Therefore, the agitator vehicle is preferably provided with a sludge charging device such as a belt conveyor.
[0009]
As the quicklime-containing material that can be used in the present invention, normal quicklime obtained by calcining limestone can be used, but a calcined intermediate raw material (hereinafter referred to as a calcined intermediate raw material) taken out from a preheater part of a cement manufacturing apparatus. In addition to being economical, it is preferred in that it is available in a cement plant. The calcined intermediate raw material is a solid material mainly composed of quicklime extracted from the preheater portion of the cement raw material firing device, and is generally the lower part of the lowermost cyclone that is the preheater portion of the cement manufacturing device. It is obtained by extracting from a preparative damper provided near the outlet.
[0010]
The loading of the quicklime-containing material on the agitator vehicle can be performed anywhere as long as the raw material can be procured, but it is naturally preferable to implement it in a cement manufacturing plant. The loading of the quicklime-containing material can be performed by the same method as the loading of the ready-mixed concrete in the ready-mixed concrete plant.
The agitator vehicle loaded with the quicklime-containing material is operated up to the sludge generation site, but during the operation, unlike the quick concrete conveyance, it is not necessary to agitate the loaded quicklime-containing material.
[0011]
At the sludge generation site, the sludge is transported to an agitator vehicle using a vehicle-mounted belt conveyor or a transport device installed at the sludge generation site, and stirring with the loaded quicklime-containing material is started.
The mixing ratio of sludge and lime-containing material is determined depending on the hydrated lime material type such as water content, sludge characteristics such as contained species, and the content and particle size of dehydrated lime. The mixing ratio is preferably such that the state of the mixture after stirring becomes a cake. Specifically, for example, when a calcined intermediate raw material is used as the quicklime material and sewage sludge having a water content of 75% is used as the sludge, the mixing ratio is about 10 parts by mass with respect to 1 part by mass of the quicklime material. Is preferred. Moreover, as a stirring speed, the rotational speed of 1-10 times per minute which is the normal rotational speed of an agitator wheel can be used.
After loading the sludge, the agitator vehicle will return to the cement manufacturing plant while continuing to stir and mix.
Below, a specific example is shown and this invention is demonstrated in detail.
[0012]
【Example】
The calcined intermediate raw material separated from the lower part of the lower cyclone of the preheater at the cement factory was loaded on a 300 kg, small agitator car (nominal 4t car, internal capacity 1.75m 3 ). The agitator vehicle used is generally used for transporting ready-mixed concrete.
[0013]
An agitator vehicle loaded with calcined intermediate material was driven to a sewage sludge storage site about 7 km away from the cement plant.
[0014]
In the sewage sludge storage area, sewage sludge with a moisture content of 75% was introduced into an agitator vehicle by a 3000 Kg belt conveyor. After the launch, he returned to the cement factory while rotating the drum of the agitator car.
[0015]
In the cement factory, the temperature of the mixture of the calcined intermediate raw material and the sewage sludge mixed during movement by the agitator car was about 80 ° C. Moreover, it was granular and the handling property in conveyance, transportation, etc. was also favorable.
[0016]
In a cement factory, the mixture of calcined intermediate raw material and sewage sludge is removed from the on-vehicle rotating container in the same manner as ordinary ready-mixed concrete discharge methods, and used as another normal cement manufacturing raw material as one of the cement manufacturing raw materials. As a result, cement production was possible without any problems.
[0017]
【The invention's effect】
According to the method of the present invention, by using a concrete agitator vehicle for transporting sludge from the sludge generation site, the sludge can be treated without the need for new equipment investment because it is not a dedicated special vehicle. I can do it. Also, since mixing and transportation can be performed with a single vehicle, not only can the number of reloads be reduced, but transportation time can also be used for mixing, and sludge can be treated efficiently without loss of time. Is possible.

Claims (2)

生石灰含有材料を生コンクリート用アジテーター車で汚泥発生場所に搬送し、同所にて汚泥を受入れた後、生石灰含有材料と汚泥とを混合しながらセメント製造工場に搬送し、該搬送された生石灰含有材料と汚泥との混合物を、セメント原料の一種として使用することを特徴とする汚泥の処理方法。Quicklime containing material is transported to a place where sludge is generated with an agitator car for quick concrete, and after receiving the sludge there, it is transported to a cement manufacturing plant while mixing the quicklime containing material and sludge, and the transported quicklime is contained A method for treating sludge, comprising using a mixture of material and sludge as a kind of cement raw material. 生石灰含有材料として、セメント製造装置のプレヒーター部分より取出された仮焼中間原料を使用することを特徴とする請求項1記載の汚泥の処理方法。The sludge treatment method according to claim 1, wherein a calcined intermediate raw material taken out from a preheater portion of a cement manufacturing apparatus is used as the quicklime-containing material.
JP2003078052A 2003-03-20 2003-03-20 Sludge treatment method Expired - Fee Related JP4209229B2 (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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JP4209229B2 true JP4209229B2 (en) 2009-01-14

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Country Status (1)

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