JP4140840B2 - Method for manufacturing absorbent article - Google Patents

Method for manufacturing absorbent article Download PDF

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JP4140840B2
JP4140840B2 JP2003399525A JP2003399525A JP4140840B2 JP 4140840 B2 JP4140840 B2 JP 4140840B2 JP 2003399525 A JP2003399525 A JP 2003399525A JP 2003399525 A JP2003399525 A JP 2003399525A JP 4140840 B2 JP4140840 B2 JP 4140840B2
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sheet
absorbent body
pulp
layer side
upper layer
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JP2005160508A (en
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圭一郎 山下
和裕 稲見
綾子 南條
康夫 井戸
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Daio Paper Corp
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Daio Paper Corp
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Priority to JP2003399525A priority Critical patent/JP4140840B2/en
Priority to PCT/JP2004/017568 priority patent/WO2005051275A1/en
Priority to CNB2004800353205A priority patent/CN100457068C/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/539Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium characterised by the connection of the absorbent layers with each other or with the outer layers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15577Apparatus or processes for manufacturing
    • A61F13/15617Making absorbent pads from fibres or pulverulent material with or without treatment of the fibres
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • A61F13/537Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Vascular Medicine (AREA)
  • Epidemiology (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Manufacturing & Machinery (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)

Description

本発明は、主には生理用ナプキン、おりものシート、失禁パッド、医療用パッド、トイレタリー等に使用される吸収性物品であって、詳しくは吸収体を囲繞するクレープ紙を省略しながら、解繊パルプの形状保持を確実に行い、かつより少ない製造工程で製造可能な吸収性物品の製造方法に関する。 The present invention is an absorbent article mainly used for sanitary napkins, cage sheets, incontinence pads, medical pads, toiletries, etc., and more specifically, while removing the crepe paper surrounding the absorber, reliably perform the shape retention of the fiber pulp, and a method of manufacturing a manufacturable absorbent material product with fewer manufacturing steps.

従来より、パンティライナー、生理用ナプキン、失禁パッドなどの吸収性物品として、ポリエチレンシートまたはポリエチレンシートラミネート不織布などの不透液性裏面シートと、不織布または透液性プラスチックシートなどの透液性表面シートとの間に綿状パルプ等からなる吸収体を介在したものが知られている。   Conventionally, as an absorbent article such as a panty liner, sanitary napkin, incontinence pad, a liquid-impervious back sheet such as a polyethylene sheet or a polyethylene sheet-laminated nonwoven fabric, and a liquid-permeable surface sheet such as a nonwoven fabric or a liquid-permeable plastic sheet There is known an intervening absorber made of cotton-like pulp or the like.

また、前記吸収性物品においては、図6に示されるように、肌に対するドライタッチ感を満足するとともに、体液の吸収速度を速めるために、前記透液性表面シートとして多孔性プラスチックシート51(以下、メッシュシートともいう。)を使用し、前記透液性表面シート51と吸収体53との間にセカンドシートと呼ばれる親水性繊維シート52を介在したものも多く提供されている(例えば、下記特許文献1〜3等参照)。   Moreover, in the said absorbent article, as shown in FIG. 6, in order to satisfy the dry touch feeling with respect to skin and to increase the absorption speed of a bodily fluid, as the said liquid-permeable surface sheet, the porous plastic sheet 51 (henceforth) , A mesh sheet) and a hydrophilic fiber sheet 52 called a second sheet is interposed between the liquid-permeable surface sheet 51 and the absorber 53 (for example, the following patents). References 1-3).

他方で、この種の吸収性物品にも幾多の改良が重ねられ、体液の漏れを防止するために種々の手段が講じられている。これら体液漏れ防止手段の一つとして、吸収体の略中央部領域に表面側に増厚した中高部を形成して排血部へのフィット性を向上せしめるとともに、前記中高部の形状を保持するために前記中高部の周縁の外側位置に線状のエンボス加工を施すようにした吸収性物品も知られている(下記特許文献4〜6等参照)。   On the other hand, many improvements have been made to this type of absorbent article, and various measures have been taken to prevent leakage of body fluids. As one of these body fluid leakage prevention means, a middle-high part thickened on the surface side is formed in the substantially central region of the absorber to improve the fit to the blood drainage part, and the shape of the middle-high part is maintained. Therefore, an absorbent article is also known in which linear embossing is performed on the outer peripheral position of the middle-high part (see Patent Documents 4 to 6 below).

前述した各吸収性物品において、吸収体としてパルプを破砕した解繊パルプが使用されている場合には、ライン上で積繊したパルプが脱落したり、パルプ繊維の転着等による設備へ悪影響を及ぼさないように、積繊後すぐにクレープ紙によって囲繞される。この場合、中高部を有する解繊パルプ吸収体の場合には図7(A)に示されるように、一般部吸収体を構成する解繊パルプ層54と中高部吸収体を構成する解繊パルプ層55を一纏めにクレープ紙56で囲繞する態様や、一般部吸収体を構成する解繊パルプ層54をクレープ紙56で囲繞した後、同じくクレープ紙56で囲繞された中高部吸収体を構成する解繊パルプ層55をその上に積層する態様などがある。   In each of the absorbent articles described above, when defibrated pulp obtained by crushing pulp is used as an absorbent, the pulp piled up on the line may drop off, or the equipment may be adversely affected by transfer of pulp fibers, etc. It is surrounded by crepe paper immediately after the fiber pile so as not to reach. In this case, in the case of the defibrated pulp absorber having the middle and high parts, as shown in FIG. 7A, the defibrated pulp layer 54 constituting the general part absorber and the defibrated pulp constituting the middle and high part absorber. A mode in which the layers 55 are collectively surrounded by the crepe paper 56, and the defibrated pulp layer 54 constituting the general part absorbent body is surrounded by the crepe paper 56, and then the middle and high part absorbent body similarly surrounded by the crepe paper 56 is configured. There is an embodiment in which the defibrated pulp layer 55 is laminated thereon.

一方、近年はバッグへの収容性や携帯性、装着性などの点から薄型吸収性物品も種々提供されている。この薄型吸収性物品の吸収体としては、例えば高吸水性樹脂を混入したパルプ繊維をシート状に加工したもの(以下、パルプシートともいう。)を用いたものが多く使用されているが、このパルプシートからなる吸収体に中高部を形成する場合にも、クレープ紙で囲繞された解繊パルプをその上に積層する態様が多く採られている。
特開平7−328060号公報 特開平8−117277号公報 特開平10−272152号公報 特開平10−328233号公報 特開平11−358号公報 特開平11−33054号公報
On the other hand, in recent years, various thin absorbent articles have been provided from the viewpoints of bag accommodation, portability, and wearability. As an absorbent body of this thin absorbent article, for example, a material using a pulp fiber mixed with a superabsorbent resin into a sheet (hereinafter also referred to as a pulp sheet) is often used. In the case where the middle and high portions are formed in the absorbent body made of a pulp sheet, many embodiments are employed in which defibrated pulp surrounded by crepe paper is laminated thereon.
JP-A-7-328060 JP-A-8-117277 JP-A-10-272152 JP 10-328233 A Japanese Patent Laid-Open No. 11-358 JP-A-11-33054

前述のように、吸収体として解繊パルプを使用する場合には、ラインからの脱落や設備への転着等を防止するとともに、形状保持のためにクレープ紙によって囲繞されているのが一般的である。しかしながら、従来一般の吸収性物品は、本発明者等による知見によれば、親水性繊維シート:拡散速度1.07cm/秒、クレープ紙:0.25cm/秒、パルプ+ポリマー:0.38cm/秒というように、中間のクレープ紙において拡散速度が低くなっているため、使用上の点から下記のような問題が発生していた。
(1)経血量が少ない場合、経血は表面シートを通過してクレープ紙まで到達するが、吸収体本体に移行する量は少なく、大部分の経血は吸収体本体に移行するまでの間、クレープ紙上に残ったままとなっている。その結果、使用時の姿勢が横向きなどの場合、経血はクレープ紙上を液流れし、経血がナプキン端部まで到達した後、横漏れが発生することになる。
(2)経血量が多い場合、クレープ紙から吸収体本体への移行が少ないため、入ってくる経血の大部分は吸収体本体に移行せず、表面シート又はクレープ紙間に溜まる。そして、入ってくる経血量が表面シート又はクレープ紙間における体液保留量を越えれば、経血は表面シート下に流入することはできず、表面シート上を液流れし、横漏れが発生することになる。
As described above, when defibrated pulp is used as an absorbent body, it is generally surrounded by crepe paper to prevent falling off of the line and transfer to equipment and to maintain the shape. It is. However, according to the knowledge of the present inventors, a conventional general absorbent article has a hydrophilic fiber sheet: diffusion rate of 1.07 cm 3 / sec, crepe paper: 0.25 cm 3 / sec, pulp + polymer: 0. Since the diffusion speed is low in the intermediate crepe paper as 38 cm 3 / sec, the following problems have occurred from the point of use.
(1) When the amount of menstrual blood is small, menstrual blood passes through the top sheet and reaches the crepe paper, but the amount that shifts to the absorber body is small, and most menstrual blood is transferred to the absorber body. Meanwhile, it remains on the crepe paper. As a result, when the posture at the time of use is sideways, menstrual blood flows on the crepe paper, and after menstrual blood reaches the end of the napkin, side leakage occurs.
(2) When the amount of menstrual blood is large, there is little transfer from the crepe paper to the absorbent body, so that most of the incoming menstrual blood does not move to the absorbent body and accumulates between the top sheet or the crepe paper. And if the amount of menstrual blood that enters exceeds the amount of body fluid retained between the top sheet or crepe paper, menstrual blood cannot flow under the top sheet, but liquid flows over the top sheet, causing side leakage. It will be.

一方で、前記解繊パルプをクレープ紙で囲繞する場合には、前記囲繞工程が必要になり製造工程が複雑になるとともに、クレープ紙の資材コストが多く掛かるようになるため、その分製造コストも高くなる問題があった。   On the other hand, when the defibrated pulp is surrounded by crepe paper, the surrounding process becomes necessary and the manufacturing process becomes complicated, and the material cost of the crepe paper increases. There was a problem of getting higher.

そこで、本発明の主たる課題は、解繊パルプを囲繞するクレープ紙を省略することにより、資材コストの低減を図るとともに、体液の迅速な吸収を図るようにしながらも、製造工程にて前記解繊パルプの形状保持を確実に行い、かつその資材ロス及び設備の悪影響を無くすとともに、より少ない製造工程で製造を可能とした吸収性物品の製造方法を提供することにある。 Therefore, the main problem of the present invention is to omit the crepe paper surrounding the defibrated pulp, thereby reducing the material cost and promptly absorbing the body fluid, but also in the manufacturing process. reliably perform the shape retention of the pulp, and with eliminating the adverse effect of the material losses and equipment, to provide fewer manufacturing process enables the manufacture and the manufacturing method for absorbent products products.

前記課題を解決するために請求項1に係る本発明として、透液性表面シートと、裏面シートとの間に吸収体が介在されるとともに、前記透液性表面シートと吸収体との間に、親水性不織布からなる親水性繊維シートが配置されるとともに、前記吸収体は、高吸水性樹脂を混入したパルプ繊維を予めシート状に加工したパルプシートからなる下層側吸収体と、この下層側吸収体の略中央部上面側に積層されるとともに、クレープ紙によって囲繞されていない、解繊パルプを主とする上層側吸収体とからなる吸収性物品を得るための製造方法であって、
製造ラインの最初の工程又は別工程で、前記パルプシートからなる下層側吸収体及び親水性繊維シートの内の一方を製造ラインに繰出し、このシート上に上層側吸収体となる解繊パルプを積繊した後、前記パルプシートからなる下層側吸収体及び親水性繊維シートの内の他方で前記上層側吸収体を覆うように積層したならば、上層側吸収体の周部にニードルパンチを付与することにより前記上層側吸収体を保持した積層体を得る工程の後、前記積層体の下面側に裏面シートを積層する工程と、前記積層体の上面側に透液性表面シートを積層する工程とを含むことを特徴とする吸収性物品の製造方法が提供される。
In order to solve the above problems, as the present invention according to claim 1, an absorbent body is interposed between the liquid-permeable top sheet and the back sheet, and between the liquid-permeable top sheet and the absorbent body. , hydrophilic fiber sheet comprising hydrophilic nonwoven fabric is disposed Rutotomoni, wherein said absorbent body includes a lower layer absorbent body comprising a pulp sheet obtained by processing in advance into a sheet of pulp fibers mixed with superabsorbent resin, the lower layer side A manufacturing method for obtaining an absorbent article composed of an upper absorbent body mainly composed of defibrated pulp, which is laminated on the upper surface side of the substantially central portion of the absorbent body and is not surrounded by crepe paper,
In the first step of the production line or in another step, one of the lower layer side absorbent body and the hydrophilic fiber sheet made of the pulp sheet is fed to the production line, and the defibrated pulp to be the upper layer side absorbent body is loaded on this sheet. After fibering, if the upper layer side absorbent body is covered with the other one of the lower layer side absorbent body and the hydrophilic fiber sheet made of the pulp sheet, a needle punch is applied to the peripheral portion of the upper layer side absorbent body. After the step of obtaining the laminated body holding the upper layer side absorbent body, a step of laminating a back sheet on the lower surface side of the laminated body, and a step of laminating a liquid-permeable surface sheet on the upper surface side of the laminated body, The manufacturing method of the absorbent article characterized by including is provided.

以上詳説のとおり本発明においては、中高部を構成する解繊パルプからなる上層側吸収体をクレープ紙で囲繞するのではなく、製造工程において、前記親水性繊維シートと下層側吸収体との間に介在された3層状態時に、前記上層側吸収体の周部に付与されたニードルパンチによって、位置ズレや形状崩れがないように保持するようにしている。その結果、クレープ紙を省略したことによって、資材コストの低減を図れるようになるとともに、体液の阻害要因となっているクレープ紙が無くなったことにより体液は速やかに解繊パルプ及び吸収性シートに吸収されるようになる。また、製造ラインからクレープ紙による吸収体の囲繞工程が無くなったことにより製造工程を簡略化できるようになる。 As described in detail above, in the present invention, the upper layer absorbent body made of defibrated pulp constituting the middle and high portions is not surrounded by crepe paper, but in the production process, between the hydrophilic fiber sheet and the lower layer side absorbent body. during the three-layer state, the two Dorupanchi granted the peripheral portion of the upper absorber so as to hold so that there is no positional displacement or deformation on being interposed. As a result, material costs can be reduced by omitting crepe paper, and body fluid can be quickly absorbed by defibrated pulp and absorbent sheets due to the absence of crepe paper, which is an obstacle to body fluid. Will come to be. In addition, the manufacturing process can be simplified by eliminating the step of surrounding the absorbent body with crepe paper from the manufacturing line.

以下、本発明の実施の形態について図面を参照しながら詳述する。
図1は本発明に係る吸収性物品1の一部破断平面図であり、図2はそのII−II線矢視図である。
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
FIG. 1 is a partially broken plan view of an absorbent article 1 according to the present invention, and FIG. 2 is a view taken along the line II-II.

吸収性物品1は、主にはパンティライナー、生理用ナプキン、おりものシート、失禁パッドなどの用途に供されるもので、例えば図1に示されるように、不透液性裏面シート2と、透液性表面シート3(以下、単に表面シートともいう。)との間に、吸収体ユニット4が介在されるとともに、前記透液性表面シート3と前記吸収体ユニット4との間に、吸収拡散性、装着感、隠蔽性を向上するために親水性繊維シート7を配置した構造となっている。なお、前記吸収体ユニット4の周囲においては、前記不透液性裏面シート2と透液性表面シート3とがホットメルト接着剤等の接着手段またはヒートシールによって接合されている。   The absorbent article 1 is mainly used for applications such as panty liners, sanitary napkins, cage sheets, incontinence pads, etc., for example, as shown in FIG. An absorber unit 4 is interposed between the liquid-permeable surface sheet 3 (hereinafter, also simply referred to as a surface sheet), and absorption is performed between the liquid-permeable surface sheet 3 and the absorber unit 4. In order to improve diffusibility, wearing feeling, and concealment, a hydrophilic fiber sheet 7 is disposed. In addition, in the circumference | surroundings of the said absorber unit 4, the said liquid-impermeable back surface sheet 2 and the liquid-permeable surface sheet 3 are joined by adhesion means, such as a hot-melt-adhesive, or heat seal.

前記不透液性裏面シート2は、ポリエチレン、ポリプロピレン等の少なくとも遮水性を有するシート材が用いられるが、この他にポリエチレンシート等に不織布を積層したラミネート不織布や、さらには防水フィルムを介在して実質的に不透液性を確保した上で不織布シート(この場合には、防水フィルムと不織布とで不透液性裏面シートを構成する。)などを用いることができる。近年はムレ防止の観点から透湿性を有するものが好適に用いられる傾向にある。この遮水・透湿性シート材としては、ポリエチレンやポリプロピレン等のオレフィン系樹脂中に無機充填剤を溶融混練してシートを成形した後、一軸または二軸方向に延伸することにより得られる微多孔性シートが好適に用いられる。   The liquid-impervious back sheet 2 is made of a sheet material having at least water shielding properties, such as polyethylene and polypropylene. In addition to this, a laminated nonwoven fabric obtained by laminating a nonwoven fabric on a polyethylene sheet or the like, and further a waterproof film interposed. After substantially ensuring liquid impermeability, a nonwoven fabric sheet (in this case, a waterproof film and a nonwoven fabric constitute a liquid impervious back sheet) or the like can be used. In recent years, those having moisture permeability tend to be suitably used from the viewpoint of preventing stuffiness. The water- and moisture-permeable sheet material is a microporous material obtained by melting and kneading an inorganic filler in an olefin-based resin such as polyethylene or polypropylene to form a sheet, and then stretching in a uniaxial or biaxial direction. A sheet is preferably used.

前記表面シート3としては、無孔または有孔の不織布や多孔性プラスチックシートなどが用いられるが、本生理用ナプキン1に好適に使用される表面シートは多孔性プラスチックシートである。   As the surface sheet 3, a non-porous or perforated nonwoven fabric or a porous plastic sheet is used, and the surface sheet suitably used for the sanitary napkin 1 is a porous plastic sheet.

前記不織布を構成する素材繊維としては、たとえばポリエチレンまたはポリプロピレン等のオレフィン系、ポリエステル系、ポリアミド系等の合成繊維の他、レーヨンやキュプラ等の再生繊維、綿等の天然繊維とすることができる。また、融点の高い繊維を芯とし融点の低い繊維を鞘とした芯鞘型繊維やサイド−バイ−サイド型繊維、分割型繊維等の複合繊維も好適に用いることもできる。加工法については、スパンレース法、スパンボンド法、サーマルボンド法、メルトブローン法、ニードルパンチ法等の適宜の加工法によって得られた不織布を用いることができる。これらの加工法の内、スパンレース法は柔軟性、ドレープ性に富む点で優れ、サーマルボンド法は嵩高でソフトである点で優れている。また、エンボス加工が施しやすい点では合成繊維からなる不織布が好適に使用される。   Examples of the material fibers constituting the non-woven fabric include synthetic fibers such as olefins such as polyethylene and polypropylene, polyesters and polyamides, recycled fibers such as rayon and cupra, and natural fibers such as cotton. In addition, composite fibers such as a core-sheath fiber, a side-by-side fiber, and a split fiber that have a fiber having a high melting point as a core and a fiber having a low melting point as a sheath can also be suitably used. Regarding the processing method, a nonwoven fabric obtained by an appropriate processing method such as a spunlace method, a spunbond method, a thermal bond method, a melt blown method, or a needle punch method can be used. Among these processing methods, the spunlace method is excellent in terms of flexibility and drapeability, and the thermal bond method is excellent in terms of being bulky and soft. Moreover, the nonwoven fabric which consists of synthetic fibers is used suitably at the point which is easy to give embossing.

前記多孔性プラスチックシートの素材としては、例えばポリエチレン、ポリプロピレン等のオレフィン系樹脂が好適に使用されるが、ポリエステルや、ナイロンなどのポリアミド系樹脂、EVAなども使用することができる。この多孔プラスチック表面シート3の開孔3a、3a…の径は、0.05〜3.0mm、好ましくは0.1〜2.0mm、より好ましくは0.5〜1.5mmとし、その開孔数は100〜500個/cm、好ましくは200〜400個/cm程度とするのが望ましい。前記開孔3aを形成するには、合成樹脂シートを軟化温度付近に軟化させて、多数の開孔を有する支持体の上面に位置させた状態で、支持体の下方から吸引したり、支持体の上面から空気圧を加圧したりする方法や、合成樹脂シート素材に多数のスリットを刻印した後にシート素材を延伸して開孔させる方法などがあるが、適宜の方法によって形成することができる。 As the material for the porous plastic sheet, for example, an olefin resin such as polyethylene or polypropylene is preferably used, but a polyamide resin such as polyester or nylon, EVA, or the like can also be used. The diameter of the apertures 3a, 3a ... of the porous plastic surface sheet 3 is 0.05 to 3.0 mm, preferably 0.1 to 2.0 mm, more preferably 0.5 to 1.5 mm. The number is 100 to 500 / cm 2 , preferably about 200 to 400 / cm 2 . In order to form the openings 3a, the synthetic resin sheet is softened near the softening temperature and is positioned on the upper surface of the support having a large number of openings, and is sucked from below the support, There are a method of pressurizing air pressure from the upper surface of the sheet, a method of drawing a large number of slits in the synthetic resin sheet material, and then stretching and opening the sheet material, and it can be formed by an appropriate method.

また、前記多孔プラスチック表面シート3の場合には、開孔径にもよるが、その疎水性から開孔部から親水性繊維シート7に移行しづらい現象が見られる場合がある。そこで、多孔プラスチックシート3の裏面側に界面活性剤を1.20g/m以上の目付けで塗布し、体液が開孔3aから親水性繊維シート7に移行し易いようにするのが望ましい。 Further, in the case of the porous plastic surface sheet 3, depending on the pore diameter, there is a case where it is difficult to shift from the aperture to the hydrophilic fiber sheet 7 due to its hydrophobicity. Therefore, it is desirable to apply a surfactant with a basis weight of 1.20 g / m 2 or more to the back side of the porous plastic sheet 3 so that the body fluid can easily migrate from the apertures 3 a to the hydrophilic fiber sheet 7.

前記吸収体ユニット4は、パルプシートからなる下層側吸収体5と、この下層側吸収体5の略中央部上面側に積層された解繊パルプからなり、表面側に突出する中高部を形成するための上層側吸収体6とから構成されている。   The said absorber unit 4 consists of the lower layer side absorber 5 which consists of a pulp sheet, and the defibrated pulp laminated | stacked on the approximate center part upper surface side of this lower layer side absorber 5, and forms the middle-high part which protrudes to the surface side. The upper-layer side absorber 6 for this is comprised.

前記下層側吸収体5は、高吸水性樹脂を混入したパルプ繊維を予めシート状に加工した、所謂パルプシートであり、厚み1〜3mm、配合はパルプ繊維10〜200g/m、高吸水性樹脂0〜100g/mのものが好適に使用される。 The lower layer side absorbent body 5 is a so-called pulp sheet obtained by processing a pulp fiber mixed with a highly water-absorbent resin into a sheet shape in advance, and has a thickness of 1 to 3 mm, the composition is 10 to 200 g / m 2 of pulp fiber, and has a high water absorption property. Those having a resin of 0 to 100 g / m 2 are preferably used.

前記高吸水性樹脂としては、たとえばポリアクリル酸塩架橋物、自己架橋したポリアクリル酸塩、アクリル酸エステル−酢酸ビニル共重合体架橋物のケン化物、イソブチレン・無水マレイン酸共重合体架橋物、ポリスルホン酸塩架橋物や、ポリエチレンオキシド、ポリアクリルアミドなどの水膨潤性ポリマーを部分架橋したもの等が挙げられる。これらの内、吸水量、吸水速度に優れるアクリル酸またはアクリル酸塩系のものが好適である。前記吸水性能を有する高吸水性樹脂は製造プロセスにおいて、架橋密度および架橋密度勾配を調整することにより吸水力と吸水速度の調整が可能である。なお、高吸水性樹脂含有率が50%を超える場合にはパルプ繊維間の絡み合いが無くなり、シート強度が低下し破れや割れ等が発生し易くなる。前記下層側吸収体5の平面形状は、図示されるように、小判状としてもよいし、或いは股間部への当たりを和らげるためにフィットカット形状(ひょうたん形状)としてもよい。   Examples of the superabsorbent resin include cross-linked polyacrylate, self-crosslinked polyacrylate, saponified acrylate-vinyl acetate copolymer cross-linked product, cross-linked isobutylene / maleic anhydride copolymer, Examples include cross-linked polysulfonates, and partially cross-linked water-swellable polymers such as polyethylene oxide and polyacrylamide. Among these, those based on acrylic acid or acrylate that are excellent in water absorption and water absorption speed are preferred. In the production process of the highly water-absorbent resin having the water absorption performance, the water absorption force and the water absorption speed can be adjusted by adjusting the crosslinking density and the crosslinking density gradient. In addition, when the high water-absorbing resin content exceeds 50%, the entanglement between the pulp fibers is lost, the sheet strength is lowered, and tearing, cracking, and the like are likely to occur. The planar shape of the lower layer side absorbent body 5 may be an oval shape as shown in the figure, or may be a fit cut shape (gourd shape) in order to reduce the contact with the crotch portion.

一方、前記上層側吸収体6は、ドラム積繊機等によってパルプ原反を解繊した解繊パルプを主とする吸収体層であり、前記下側吸収体5の略中央部上面側に積層されることにより中高部吸収体を形成するものである。   On the other hand, the upper layer absorbent body 6 is an absorbent layer mainly composed of defibrated pulp obtained by defibrating a pulp original fabric with a drum fiber spreader or the like, and is laminated on the upper surface side of a substantially central portion of the lower absorbent body 5. Thus, the middle and high part absorbent body is formed.

前記パルプとしては、木材から得られる化学パルプ、溶融パルプ等のセルロース繊維や、レーヨン、アセテート等の人工セルロース繊維からなるものが挙げられ、広葉樹パルプよりは繊維長の長い針葉樹パルプの方が機能および価格の面で好適に使用される。また、上層側吸収体6の平面形状は、図示では略矩形状としたが、小判状に形成してもよい。前記上層側吸収体6の厚みは1.5〜8.0mm、好ましくは2.0〜4.0mmとするのがよい。なお、前記上層側吸収体6には積繊時に所定割合で、例えば10〜60%の割合で高吸水性樹脂の粉粒体を混入するのが望ましい。   Examples of the pulp include chemical fibers obtained from wood, cellulose fibers such as molten pulp, and artificial cellulose fibers such as rayon and acetate. Softwood pulp having a longer fiber length than hardwood pulp functions and It is preferably used in terms of price. Moreover, although the planar shape of the upper layer side absorbent body 6 is substantially rectangular in the drawing, it may be formed in an oval shape. The upper layer absorbent body 6 has a thickness of 1.5 to 8.0 mm, preferably 2.0 to 4.0 mm. In addition, it is desirable that the upper-layer absorbent body 6 is mixed with a powder of a superabsorbent resin at a predetermined rate, for example, 10 to 60% at the time of fiber stacking.

前記透液性表面シート3と吸収体ユニット4との間に配置される親水性繊維シート7は、前記透液性表面シート3上に排出された体液を移行させるために使用される。この親水性繊維シート7としては、レーヨンやキュプラ等の再生繊維、綿等の天然繊維のように素材自体に親水性を有するものを用いるか、ポリエチレンまたはポリプロピレン等のオレフィン系、ポリエステル系、ポリアミド系等の合成繊維を親水化剤によって表面処理し親水性を付与した繊維を用いることにより親水性を有するようにする。体液の逆戻りの原因の一つとして前記親水性繊維シート7の繊維間の微小空間に体液が保留され、圧力を受けた際にこの体液が表面シート3側に移行することが挙げられる。従って、前記親水性繊維シート7の繊維間空間を微小化するために3.0d以下、好ましくは2.5d以下の極細繊維からなる繊維層とすることにより体液の逆戻り防止を図るようにするのが望ましい。   The hydrophilic fiber sheet 7 disposed between the liquid-permeable surface sheet 3 and the absorbent body unit 4 is used for transferring body fluid discharged onto the liquid-permeable surface sheet 3. As the hydrophilic fiber sheet 7, a fiber having a hydrophilic property such as regenerated fiber such as rayon or cupra, natural fiber such as cotton, or an olefin-based, polyester-based, or polyamide-based material such as polyethylene or polypropylene is used. It is made to have hydrophilicity by using a surface-treated synthetic fiber such as a hydrophilizing agent and imparting hydrophilicity. One of the causes of the return of the body fluid is that the body fluid is retained in the minute space between the fibers of the hydrophilic fiber sheet 7, and this body fluid moves to the surface sheet 3 side when receiving pressure. Therefore, in order to make the space between fibers of the hydrophilic fiber sheet 7 minute, a fiber layer made of ultrafine fibers of 3.0 d or less, preferably 2.5 d or less is used to prevent the return of body fluid. Is desirable.

本吸収性物品1において、前記上層側吸収体6は、クレープ紙によって囲繞されることなく、前記親水性繊維シート7と下層側吸収体5との間に介在された3層状態時に、前記上層側吸収体6の外側隣接位置に付与された熱エンボス8,8…によって保持されているものである。   In the present absorbent article 1, the upper layer absorbent body 6 is not surrounded by crepe paper, and the upper layer is in the three-layer state interposed between the hydrophilic fiber sheet 7 and the lower layer absorbent body 5. It is hold | maintained by the heat embossing 8,8 ... given to the outer side adjacent position of the side absorber 6. FIG.

前記熱エンボス8は、前記上層側吸収体6の位置ズレや型崩れを防止するために、図示の如く、上層側吸収体6の前後左右部にそれぞれ付与されていることが望ましい。なお、図示例では、円形状の熱エンボス8を各辺毎に1つずつ付与したが、エンボス形状及びパターンは任意である。例えば、各辺に複数づつ付与してもよいし、線状の熱エンボスとすることでもよい。   The heat embossing 8 is preferably applied to the front, rear, left and right parts of the upper layer side absorbent body 6 as shown in the drawing in order to prevent displacement and deformation of the upper layer side absorbent body 6. In the illustrated example, one circular hot emboss 8 is provided for each side, but the embossed shape and pattern are arbitrary. For example, a plurality may be given to each side, or linear heat embossing may be used.

例えば、前記熱エンボス8のパターンとしては、図3(A)〜(E)に示される態様などを例示として挙げることができる。図3(A)は前記上層側吸収体6の前後にそれぞれ熱エンボス8,8を付与し、図3(B)は前記上層側吸収体6の左右にそれぞれ熱エンボス8,8を付与した例である。また、図3(C)は前記上層側吸収体6の左右にそれぞれ円形状の熱エンボス8,8を付与し、前後にそれぞれやや放射状に前後方向に延びる線状エンボス9,9…を付与した例であり、図3(D)は前記上層側吸収体6を囲むように楕円形状に線状エンボス10を付与した例であり、図3(E)は前記上層側吸収体6の前後にそれぞれ熱エンボス8,8を付与し、側部にそれぞれ長手方向に沿う直線状の線状エンボス11を付与した例である。なお、前記線状エンボス9〜11は、横漏れを抑えるために圧搾溝に沿って体液を拡散させるためのエンボスでもあり、圧搾溝部に体液が過剰に拡散するのを制御するため、圧搾面積を調整するようしてもよい。   For example, as the pattern of the heat embossing 8, the modes shown in FIGS. 3A to 3E can be exemplified. FIG. 3A shows an example in which heat embosses 8 and 8 are respectively provided before and after the upper layer absorbent body 6, and FIG. 3B shows an example in which heat embosses 8 and 8 are provided on the left and right sides of the upper layer absorbent body 6. It is. 3 (C), circular heat embosses 8 and 8 are provided on the left and right sides of the upper-layer absorbent body 6 respectively, and linear embosses 9 and 9. FIG. 3 (D) is an example in which linear embossing 10 is provided in an elliptical shape so as to surround the upper layer side absorbent body 6, and FIG. 3 (E) is shown before and after the upper layer side absorbent body 6. In this example, hot embosses 8 and 8 are provided, and linear linear embosses 11 are provided on the side portions along the longitudinal direction. The linear embosses 9 to 11 are also embosses for diffusing bodily fluids along the squeezing grooves in order to suppress side leakage, and control the squeezing area in order to control the excessive diffusion of bodily fluids in the squeezing grooves. You may adjust it.

ところで、前記生理用ナプキン1を得るための製造手順は、概略的に、図4(ステップ1)に示されるように、先ず製造ラインの最初の工程又は別工程で、下層側吸収体5と、親水性繊維シート7との間に上層側吸収体6が介在されるとともに、前記上層側吸収体6がその外側隣接位置に付与された熱エンボス8,8…によって保持された、吸収体を含む積層体12を得た後、図4(ステップ2)に示すように、この積層体12の下面側に裏面シート2を積層し、次いで図4(ステップ3)に示すように、前記積層体の上面側に透液性表面シート3を積層する手順による。前記図4(ステップ2)と図4(ステップ3)の手順は逆であってもよい。なお、前記手順には表面側両側部にサイド不織布を配設する手順、立体ギャザーを形成する手順、弾性伸縮材を配置する手順等を含んでいてもよい。要は、前記積層体12が裏面シート2や表面シート3と組み立てられる前に、製造されていればよい。前記吸収体を含む積層体12においては、上層側吸収体6を保持するために付与される熱エンボスは透液性表面シート3によって隠蔽されるため、前記熱エンボスはどのようなパターンで付与しても外部に露出せず外観も良好となる。 By the way, the manufacturing procedure for obtaining the sanitary napkin 1 is roughly as shown in FIG. 4 (step 1). First, in the first step or another step of the manufacturing line, The upper layer side absorbent body 6 is interposed between the hydrophilic fiber sheet 7 and the upper layer side absorbent body 6 includes an absorbent body held by heat embossing 8, 8. After obtaining the laminate 12, as shown in FIG. 4 (step 2), the back sheet 2 is laminated on the lower surface side of the laminate 12, and then as shown in FIG. 4 (step 3), According to the procedure of laminating the liquid-permeable surface sheet 3 on the upper surface side. The procedure of FIG. 4 (step 2) and FIG. 4 (step 3) may be reversed. In addition, the procedure may include a procedure of disposing side nonwoven fabrics on both sides of the surface side, a procedure of forming a three-dimensional gather, a procedure of disposing an elastic elastic material, and the like. In short, the laminated body 12 may be manufactured before it is assembled with the back sheet 2 and the top sheet 3. In the laminated body 12 including the absorbent body, the heat embossing applied to hold the upper-layer absorbent body 6 is concealed by the liquid-permeable surface sheet 3. However, it is not exposed to the outside and the appearance is improved.

前記積層体12の具体的製造工程例としては、例えば図5に示されるように、パルプシート原反から下層側吸収体5となるパルプシートを繰出し、その搬送過程でドラム積繊機14において、上層側吸収体6となる解繊パルプを前記下側吸収体5上に積繊する。そして、親水性繊維シート7を前記上層側吸収体6,6…側に積層させたならば、熱エンボス付与部15において、前記上層側吸収体6,6…の外側隣接位置に熱エンボス8,8…を付与することにより吸収体を含む前記積層体12を得るようにする。この積層体12は、所定形状に裁断された後、裏面シート2の積層工程、表面シート3の積層工程へと送られる。なお、前記製造工程では、最初にパルプシートからなる下層側吸収体5を繰出しこの上に解繊パルプからなる上層側吸収体6を積繊したが、親水性繊維シート7を繰出してこの上に解繊パルプからなる上層側吸収体6を積繊し、その後に下層側吸収体5となるパルプシートを積層するようにしてもよい。   As a specific example of the manufacturing process of the laminate 12, as shown in FIG. 5, for example, a pulp sheet to be the lower layer absorbent body 5 is fed out from the pulp sheet original fabric, and the upper layer in the drum stacker 14 in the conveying process. The defibrated pulp to be the side absorbent body 6 is piled on the lower absorbent body 5. Then, if the hydrophilic fiber sheet 7 is laminated on the upper layer side absorbent bodies 6, 6..., The heat embossing 8, By giving 8 ..., the laminated body 12 including the absorber is obtained. After this laminated body 12 is cut into a predetermined shape, it is sent to the lamination process of the back sheet 2 and the lamination process of the top sheet 3. In addition, in the said manufacturing process, although the lower layer side absorber 5 which consists of a pulp sheet is first drawn out and the upper layer side absorber 6 which consists of a defibrated pulp is piled up on this, the hydrophilic fiber sheet 7 is drawn out and on this The upper layer absorbent body 6 made of defibrated pulp may be stacked, and then a pulp sheet to be the lower layer absorbent body 5 may be laminated.

〔他の形態例〕
(1)上記形態例では、透液性表面シート3の上面側からエンボスを付与することは記載していないが、この表面エンボスも任意に形成することが可能である。
(2)上記形態例では、吸収性シートとして既製の若しくはメーカーから入手が可能なパルプシートを使用するようにしたが、吸収性を有するシートであればどのようなものであってもよい。
(3)上記形態例では、親水性繊維シート7として所謂セカンドシートと呼ばれる親水性不織布を使用したが、熱融着可能な吸収性シートであればどのようなものであってもよい。
(4)上記形態例では、前記上層側吸収体6は、該上層側吸収体6の外側隣接位置(外側周部)に付与された熱エンボス8,8…によって保持されるようにしたが、前記熱エンボス8,8…は上層側吸収体6の外縁よりも内側の周部に付与するようにしてもよい。
(5)上記形態例では、前記上層側吸収体6は、該上層側吸収体6の外側隣接位置(外側周部)に付与された熱エンボス8,8…によって保持されるようにしたが、前記熱エンボス8に代えてニードルパンチによって繊維同士を絡み合わせることにより上層側吸収体6を保持するようにしてもよい。なお、この場合には、熱融着しない吸収性シートをも使用可能である。
[Other examples]
(1) Although the embossing from the upper surface side of the liquid-permeable surface sheet 3 is not described in the above embodiment, this surface embossing can be arbitrarily formed.
(2) In the above-described embodiment, a ready-made pulp sheet available from a manufacturer is used as the absorbent sheet. However, any sheet having an absorbent property may be used.
(3) In the above embodiment, a hydrophilic non-woven fabric called a so-called second sheet is used as the hydrophilic fiber sheet 7. However, any hydrophilic sheet that can be heat-sealed may be used.
(4) In the above embodiment, the upper-layer absorbent body 6 is held by the heat embossing 8, 8,... The heat embossing 8, 8,... May be applied to the inner peripheral portion of the outer edge of the upper layer absorbent body 6.
(5) In the above-described embodiment, the upper-layer absorbent body 6 is held by the heat embossing 8, 8,... Instead of the heat embossing 8, the upper layer absorbent body 6 may be held by entanglement of fibers with a needle punch. In this case, an absorptive sheet that is not thermally fused can also be used.

本発明に係る吸収性物品1の一部破断平面図である。It is a partially broken top view of the absorbent article 1 which concerns on this invention. そのII−II線矢視図である。It is the II-II arrow directional view. (A)〜(E)はそれぞれ熱エンボスの形成パターン図である。(A)-(E) are the formation pattern figures of a heat embossing, respectively. 本吸収性物品1の製造手順図である。It is a manufacturing procedure figure of this absorbent article 1. 積層体12を得るための製造工程例図である。FIG. 4 is a manufacturing process example diagram for obtaining a laminated body 12. 従来の吸収性物品50の一部破断斜視図である。It is a partially broken perspective view of the conventional absorbent article 50. クレープ紙による嵩高吸収体の囲繞例を示す図である。It is a figure which shows the example of the surrounding of the bulky absorber by a crepe paper.

符号の説明Explanation of symbols

1…吸収性物品、2…不透液性裏面シート、3…透液性表面シート、4…吸収体ユニット、5…下層側吸収体(パルプシート)、6…上層側吸収体(解繊パルプ)7…親水性繊維シート、8…熱エンボス   DESCRIPTION OF SYMBOLS 1 ... Absorbent article, 2 ... Liquid-impermeable back sheet, 3 ... Liquid-permeable surface sheet, 4 ... Absorber unit, 5 ... Lower layer side absorber (pulp sheet), 6 ... Upper layer side absorber (defibrated pulp) 7 ... Hydrophilic fiber sheet, 8 ... Hot emboss

Claims (1)

透液性表面シートと、裏面シートとの間に吸収体が介在されるとともに、前記透液性表面シートと吸収体との間に、親水性不織布からなる親水性繊維シートが配置されるとともに、前記吸収体は、高吸水性樹脂を混入したパルプ繊維を予めシート状に加工したパルプシートからなる下層側吸収体と、この下層側吸収体の略中央部上面側に積層されるとともに、クレープ紙によって囲繞されていない、解繊パルプを主とする上層側吸収体とからなる吸収性物品を得るための製造方法であって、
製造ラインの最初の工程又は別工程で、前記パルプシートからなる下層側吸収体及び親水性繊維シートの内の一方を製造ラインに繰出し、このシート上に上層側吸収体となる解繊パルプを積繊した後、前記パルプシートからなる下層側吸収体及び親水性繊維シートの内の他方で前記上層側吸収体を覆うように積層したならば、上層側吸収体の周部にニードルパンチを付与することにより前記上層側吸収体を保持した積層体を得る工程の後、前記積層体の下面側に裏面シートを積層する工程と、前記積層体の上面側に透液性表面シートを積層する工程とを含むことを特徴とする吸収性物品の製造方法
A liquid-permeable topsheet, with the absorber is interposed between the back sheet, between the liquid-pervious topsheet and the absorbent body, the hydrophilic fiber sheet comprising hydrophilic nonwoven fabric is disposed Rutotomoni, The absorbent body is laminated on a lower layer side absorbent body made of a pulp sheet in which pulp fibers mixed with a superabsorbent resin are previously processed into a sheet shape, and on the upper surface side of a substantially central portion of the lower layer side absorbent body, and crepe paper A manufacturing method for obtaining an absorbent article composed of an upper absorbent body mainly composed of defibrated pulp, which is not surrounded by
In the first step of the production line or in another step, one of the lower layer side absorbent body and the hydrophilic fiber sheet made of the pulp sheet is fed to the production line, and the defibrated pulp to be the upper layer side absorbent body is loaded on this sheet. After fibering, if the upper layer side absorbent body is covered with the other one of the lower layer side absorbent body and the hydrophilic fiber sheet made of the pulp sheet, a needle punch is applied to the peripheral portion of the upper layer side absorbent body. After the step of obtaining the laminated body holding the upper layer side absorbent body, a step of laminating a back sheet on the lower surface side of the laminated body, and a step of laminating a liquid-permeable surface sheet on the upper surface side of the laminated body, The manufacturing method of the absorbent article characterized by including this.
JP2003399525A 2003-11-28 2003-11-28 Method for manufacturing absorbent article Expired - Fee Related JP4140840B2 (en)

Priority Applications (3)

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JP2003399525A JP4140840B2 (en) 2003-11-28 2003-11-28 Method for manufacturing absorbent article
PCT/JP2004/017568 WO2005051275A1 (en) 2003-11-28 2004-11-26 Absorbent article and method of manufacturing the same
CNB2004800353205A CN100457068C (en) 2003-11-28 2004-11-26 Absorbent article and method of manufacturing the same

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WO2006134906A1 (en) * 2005-06-14 2006-12-21 Daio Paper Corporation Absorbent article
JP4954502B2 (en) * 2005-06-14 2012-06-20 大王製紙株式会社 Absorbent articles
JP5094173B2 (en) * 2007-03-20 2012-12-12 花王株式会社 Absorbent article and manufacturing method thereof
JP6158992B2 (en) * 2015-08-17 2017-07-05 大王製紙株式会社 Absorbent articles
CN110731863A (en) * 2019-11-15 2020-01-31 深圳市棉芯科技有限公司 glue-free needle-punched absorption core and sanitary product containing the same

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JPS5555703Y2 (en) * 1976-01-30 1980-12-24
JPS5813223U (en) * 1981-07-16 1983-01-27 ユニ・チヤ−ム株式会社 sanitary napkins
JPS61106151A (en) * 1984-10-30 1986-05-24 ユニ・チヤ−ム株式会社 Absorbing body in sanitary article
JP2538253Y2 (en) * 1990-11-30 1997-06-11 株式会社資生堂 Sanitary napkin
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JP4261120B2 (en) * 2002-04-05 2009-04-30 株式会社日本吸収体技術研究所 Absorber comprising bypass channel member and absorbent product using the same

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CN100457068C (en) 2009-02-04
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JP2005160508A (en) 2005-06-23

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