JP4109819B2 - Process for producing shrimp with improved texture and transparency - Google Patents

Process for producing shrimp with improved texture and transparency Download PDF

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Publication number
JP4109819B2
JP4109819B2 JP2000238274A JP2000238274A JP4109819B2 JP 4109819 B2 JP4109819 B2 JP 4109819B2 JP 2000238274 A JP2000238274 A JP 2000238274A JP 2000238274 A JP2000238274 A JP 2000238274A JP 4109819 B2 JP4109819 B2 JP 4109819B2
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Prior art keywords
shrimp
alkaline solution
transparency
texture
earth metal
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JP2002051693A (en
JP2002051693A5 (en
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嘉 越川
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Nichirei Foods Inc
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Nichirei Foods Inc
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Description

【0001】
【発明の属する技術分野】
本発明は、冷凍や冷蔵エビ、惣菜用エビ、冷凍、冷蔵又は常温のエビ加工食品等に用いるエビ類の製造方法に関し、更に詳細には、冷凍保存後若しくは加熱調理後においても優れた歩留りを維持し、エビ本来の食感が低下することを抑制することができると共に、外観状に生じる透明感を抑えることができる、食感及び透明感を改良したエビ類の製造方法に関する。
【0002】
【従来の技術】
従来、冷凍エビ、冷蔵エビ等を販売する場合に、エビの外観を食欲がそそられる鮮やかな赤色に発色させるために、生エビ又は解凍エビをアルカリ溶液に浸漬させる方法が行なわれている。また、これら冷凍エビや冷蔵エビに加えて、グラタン、ピザ等のエビを用いた、冷蔵、冷凍又は常温のエビ加工食品に用いられるエビの食感や調理後の歩留りを改善するために、生エビ又は解凍エビをアルカリ溶液等に浸漬させたり、アルカリ剤を付着させた後に加熱調理する方法等が行なわれている。
例えば、以下に示す方法等が提案され、実施されている。
(1)エビ等を、水酸化カリウム、水酸化ナトリウム、炭酸ナトリウム、炭酸カリウム又は水酸化カルシウムを含むpH10〜13のアルカリ性水溶液により処理することにより、カロチノイド系色素を赤色に発色させる生の状態でのエビ等の発色方法(特許第2607204号)、(2)乳清由来の無機塩類をその主成分として含み、炭酸ナトリウム又は炭酸カリウムのpH調整剤により溶液全体のpHをアルカリ性に保持した前処理剤に水産物を浸漬して、該水産物の歩留り等を改善する方法(特許第2957826号)、(3)L−アルギニンや貝殻焼成カルシウムを配合した処理液にエビ類を接触させてエビ類の発色及び食感を改良する方法(特開平10−57019号公報)、(4)生のむきエビに、炭酸カルシウム、塩化カルシウム、乳酸カルシウム等のカルシウム製剤と食塩とを配合した後、加熱処理を行って食感や歩留りの低下を防止するエビの加熱処理方法(特開平9−98746号公報)。
しかし、これら従来の方法においては、必ずしも歩留りの向上が十分とは言えず、それに伴う食感の更なる改善が望まれている。加えて、従来の方法においては、鮮やかな赤色に発色させた場合であっても、本来のエビが有する外観とは異なる透明感が生じることが多く、この透明感は加熱処理を行った場合にも残り、消費者に対して違和感を与えるという問題がある。
【0003】
【発明が解決しようとする課題】
本発明の目的は、歩留りの低下等に伴う食感の低下を抑制すると共に、エビ本来の外観ではない透明感が生じることを抑え、且つ加熱処理する以前であっても食欲がそそられる鮮やかな赤色に発色させることができる食感及び透明感を改良したエビ類の製造方法を提供することにある。
【0004】
【課題を解決するための手段】
本発明者らは、上記課題を解決するため鋭意検討した。その結果、生エビ又は解凍エビを処理するアルカリ溶液に、特定の炭酸塩と、クエン酸3ナトリウムと、2価のアルカリ土類金属塩とを加え、且つこのアルカリ溶液による処理を特定時間行うことにより上記課題が解決できること、更には、特定の2価のアルカリ土類金属塩を、クエン酸3ナトリウムを含むアルカリ溶液に含ませることによりその効果が更に顕著になることを見出し本発明を完成した。
すなわち本発明によれば、生エビ又は解凍エビを、pH10.25〜10.96のアルカリ溶液に接触させる工程(A)を含み、該アルカリ溶液が、炭酸ナトリウム、炭酸水素ナトリウム及び炭酸カリウムからなる群より選択される少なくとも1種と、クエン酸3ナトリウムと、乳酸カルシウム、塩化カルシウム及び塩化マグネシウムからなる群より選択される1種又は2種以上の2価のアルカリ土類金属塩と、水とを含み、且つアルカリ溶液に接触させる時間が10〜24時間であることを特徴とする食感及び透明感を改良したエビ類の製造方法が提供される。
【0005】
【発明の実施の形態】
以下本発明を更に詳細に説明する。
本発明の製造方法では、生エビ又は解凍エビを、pH10.25〜10.96のアルカリ溶液に接触させる工程(A)を行なう。
前記アルカリ溶液は、炭酸ナトリウム、炭酸水素ナトリウム及び炭酸カリウムからなる群より選択される少なくとも1種と、クエン酸3ナトリウムと、特定の2価のアルカリ土類金属塩と、水とを必須に含み、必要に応じて、グルタミン酸ソーダ等のアミノ酸類、塩化ナトリウム等を含有させることができる。
【0006】
前記炭酸ナトリウム、炭酸水素ナトリウム及び炭酸カリウムからなる群より選択される少なくとも1種、並びに水の配合割合は、アルカリ溶液が上述のpHとなるように配合すれば良い。pHが8.5未満では、歩留り改善効果が期待できず、pH11.0を超える場合には後述の2価のアルカリ土類金属塩の配合を行っても改善できないほど強い透明感が生じてしまう。
【0007】
前記クエン酸3ナトリウムの配合割合は、アルカリ溶液全量に対して、0.1〜4.0質量%、特に0.3〜2.0質量%が好ましが、目的とするpHによって配合量を適宜決定することができる。0.1質量%未満では歩留り改善効果が期待できず、4.0質量%を超える場合には酸味が問題となるため好ましくない。
【0008】
前記2価のアルカリ土類金属塩は、本発明の所望の効果を有効に得るために、乳酸カルシウム、塩化カルシウム及び塩化マグネシウムからなる群より選択される1種又は2種以上を含む。特に、エビを鮮やかな赤色に発色させると共に、エビの肉質に透明感が生じることをバランス良く改善し、且つ優れた食感を維持するために塩化マグネシウムの使用が最も望ましい。
2価のアルカリ土類金属塩の配合割合は、アルカリ溶液全量に対して、0.1〜2.0質量%が好ましい。特に、後述する加熱する工程(B)を行なう場合には、該加熱を行なう前のエビを、鮮やかに発色させる必要がないので、pHが9前後と低くでき、透明感があまり高くならないために、0.1〜1.0質量%であっても良い。2価のアルカリ土類金属塩の配合割合が0.1質量%未満の場合にはエビの本来の外観にない透明感が生じる恐れがあり、2.0質量%を超える場合には食味や歩留りの低下を生じる恐れがあるので好ましくない。
【0009】
前記工程(A)において、生エビ又は解凍エビをアルカリ溶液に接触させる時間は10〜24時間、好ましくは14〜18時間である。10時間未満では、本発明の所望の効果が十分に得られず、24時間を超えても効果の向上が望めないばかりか逆に加熱歩留りが低下する恐れがあり、工程が煩雑化する。アルカリ溶液の温度は、通常、0〜10℃程度である。
前記接触は、通常、アルカリ溶液にエビを浸漬させることにより行なうことができるが、例えば、エビの表面がアルカリ溶液に常時接触するようにアルカリ溶液をエビに噴霧して放置する工程を繰返す方法等を採用することもできる。
【0010】
本発明の製造方法では、上記工程(A)の後に、得られたエビを、冷凍、冷蔵エビ、惣菜用エビ、冷凍、冷蔵又は常温のエビ加工食品等の所望のエビとするために、エビを加熱する工程(B)及び/又はエビを凍結する工程(C)を行なうことができる。これらの工程は、工程(A)により調製したエビを、液きりし、軽い洗浄等した後に行なうことができる。
【0011】
【発明の効果】
本発明の製造方法では、生エビ又は解凍エビを、特定pHを有する、クエン酸3ナトリウムと、2価のアルカリ土類金属塩とを含むアルカリ溶液に特定時間接触させるので、歩留りの低下等に伴う食感の低下を抑制すると共に、エビ本来の外観ではない透明感が生じることを抑えることができる。特に、2価のアルカリ土類金属塩として、乳酸カルシウム、塩化カルシウム、塩化マグネシウムを用いることによりその効果が顕著になる。また、加熱する前のエビであっても食欲をそそる鮮やかな赤色に発色させることができる。更に、このようなエビを本発明の方法に従って凍結や加熱することにより、食感や透明感が改善された種々のエビ製品及びエビ加工食品とすることができる。
【0012】
【実施例】
以下実施例により、本発明を更に詳細に説明するが、本発明はこれらに限定されるものではない。
実施例1
炭酸カリウム0.40質量%、炭酸ナトリウム0.6質量%、クエン酸3ナトリウム1.60質量%、塩化マグネシウム1.25質量%、塩化ナトリウム(食塩)2.50質量%及び水93.65質量%からなるpH10.25のアルカリ溶液を調製した。次いで、冷凍ムキエビ(ベトナム産)を解凍後、上記アルカリ溶液(液温5℃)に16時間浸漬させた。その後、エビをアルカリ溶液から取り出し、水洗いし、−18℃で凍結した。
アルカリ溶液へ浸漬した後のエビについて、発色、身の白さ及び身の透明感について結果を表1に示す。
発色試験:赤く鮮やかに発色したものを◎、赤く発色したものを○、僅かな発色が見られるものを△、発色していないものを×とした。
身の白さ試験:極めて白いものを◎、白いものを○、やや黄色身を帯びているものを△、黄色身を帯びているものを×とした。
身の透明感試験:透明感が全く無いものを◎、透明感がほとんどないものを○、透明感があるものを×とした。
また、エビの浸漬後の歩留りを、アルカリ溶液への浸漬前後の質量を測定することにより求めた。結果を表1に示す。
【0013】
上記で得られた凍結エビをボイルして食感及び味について専門のパネル10人によるパネル試験を行なった。評価基準は以下のとおりである。また、ボイル後のエビの歩留りを、ボイル前後のエビの質量を測定することにより求めた。それぞれの結果を表1に示す。
食感試験:適度なプリプリ感を有するものを◎、適度なプリプリ感がやや劣るものを○、やや柔らかな食感のものを△、プリプリがゼリー様のものを×とした。
味試験:適度なエビの味のものを○、苦く、不味なものを×とした。
【0014】
実施例2、3及び比較例1〜4
表1に示す組成のアルカリ溶液を用いた以外は、実施例1と同様に凍結エビ及びボイルエビを調製し、各試験を行なった。結果を表1に示す。
【0015】
【表1】

Figure 0004109819
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for producing shrimp used in frozen or refrigerated shrimp, shrimp for side dishes, frozen, refrigerated or room temperature shrimp processed foods, and more particularly, excellent yield even after frozen storage or after cooking. The present invention relates to a method for producing shrimp with improved texture and transparency, capable of maintaining and suppressing a reduction in the original texture of shrimp, and suppressing the transparency that occurs in the appearance.
[0002]
[Prior art]
Conventionally, when selling frozen shrimp, refrigerated shrimp and the like, a method of immersing raw shrimp or thawed shrimp in an alkaline solution has been performed in order to develop a vivid red color that makes the appetite appeal. In addition to these frozen shrimp and refrigerated shrimp, in order to improve the texture and post-coating yield of shrimp used in shrimp processed foods at refrigerated, frozen or room temperature using shrimp such as gratin and pizza A method of cooking by heating after immersing shrimp or thawed shrimp in an alkali solution or adhering an alkaline agent is performed.
For example, the following methods have been proposed and implemented.
(1) In a raw state in which a carotenoid pigment is colored red by treating shrimp and the like with an alkaline aqueous solution of pH 10-13 containing potassium hydroxide, sodium hydroxide, sodium carbonate, potassium carbonate or calcium hydroxide. Coloring method for shrimp, etc. (Patent No. 2607204), (2) Pretreatment containing whey-derived inorganic salt as its main component and maintaining the pH of the whole solution alkaline with sodium carbonate or potassium carbonate pH adjuster A method for improving the yield of the marine product by immersing the marine product in the agent (Patent No. 2957826), (3) Coloring of the shrimp by bringing the shrimp into contact with a treatment solution containing L-arginine or shell calcined calcium And a method for improving the texture (JP-A-10-57019), (4) raw peeled shrimp, calcium carbonate, calcium chloride, calcium lactate After mixing the calcium preparations and brine etc., heat treatment method of shrimp subjected to heat treatment to prevent deterioration of the texture and the yield (Japanese Patent Laid-Open No. 9-98746).
However, in these conventional methods, it cannot be said that the yield is necessarily improved sufficiently, and further improvement in the texture associated therewith is desired. In addition, in the conventional method, even when the color is bright red, a translucency that is different from the appearance of the original shrimp often occurs, and this translucency is obtained when heat treatment is performed. However, there is a problem that the consumer feels uncomfortable.
[0003]
[Problems to be solved by the invention]
The object of the present invention is to suppress a decrease in texture caused by a decrease in yield, etc., to suppress the appearance of transparency that is not the original appearance of shrimp, and to produce a vivid appetite even before heat treatment An object of the present invention is to provide a method for producing shrimp with improved texture and transparency that can be colored red.
[0004]
[Means for Solving the Problems]
The present inventors diligently studied to solve the above problems. As a result, a specific carbonate, trisodium citrate, and a divalent alkaline earth metal salt are added to an alkaline solution for treating raw shrimp or thawed shrimp, and treatment with this alkaline solution is performed for a specific time. The present invention was completed by finding that the above-mentioned problems can be solved by the above, and that the effect is further enhanced by including a specific divalent alkaline earth metal salt in an alkaline solution containing trisodium citrate. .
That is, according to the present invention, the method includes a step (A) of bringing raw shrimp or thawed shrimp into contact with an alkaline solution having a pH of 10.25 to 10.96 , and the alkaline solution is made from sodium carbonate, sodium bicarbonate and potassium carbonate. At least one selected from the group consisting of trisodium citrate, one or more divalent alkaline earth metal salts selected from the group consisting of calcium lactate, calcium chloride and magnesium chloride , and water And a method for producing shrimp with improved texture and transparency, characterized in that the time of contact with an alkaline solution is 10 to 24 hours.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
The present invention will be described in detail below.
In the production method of the present invention, the step (A) of bringing raw shrimp or thawed shrimp into contact with an alkaline solution having a pH of 10.25 to 10.96 is performed.
The alkaline solution essentially includes at least one selected from the group consisting of sodium carbonate, sodium bicarbonate and potassium carbonate, trisodium citrate, a specific divalent alkaline earth metal salt, and water. If necessary, amino acids such as sodium glutamate, sodium chloride and the like can be contained.
[0006]
What is necessary is just to mix | blend the at least 1 sort (s) selected from the group which consists of the said sodium carbonate, sodium hydrogencarbonate, and potassium carbonate, and water so that an alkaline solution may become above-mentioned pH. If the pH is less than 8.5, the yield improving effect cannot be expected. If the pH exceeds 11.0, a transparency that is so strong that it cannot be improved even if a divalent alkaline earth metal salt described later is added is produced. .
[0007]
The mixing ratio of the trisodium citrate is an alkali solution the total amount, 0.1 to 4.0 wt%, although not preferred in particular 0.3 to 2.0 wt%, the amount depending on the pH of interest Can be appropriately determined. If it is less than 0.1% by mass, the yield improving effect cannot be expected, and if it exceeds 4.0% by mass, acidity becomes a problem, which is not preferable.
[0008]
The divalent alkaline earth metal salt includes one or more selected from the group consisting of calcium lactate, calcium chloride, and magnesium chloride in order to effectively obtain the desired effect of the present invention . In particular, the use of magnesium chloride is most desirable in order to develop shrimp in a bright red color, improve the balance of the shrimp meat quality in a well-balanced manner, and maintain an excellent texture.
The blending ratio of the divalent alkaline earth metal salt is preferably 0.1 to 2.0% by mass with respect to the total amount of the alkaline solution. In particular, when performing the heating step (B) described later, it is not necessary to vividly develop the shrimp before the heating, so that the pH can be lowered to around 9, and the transparency is not so high. 0.1-1.0 mass% may be sufficient. If the blending ratio of the divalent alkaline earth metal salt is less than 0.1% by mass, the shrimp may not have the original appearance of transparency, and if it exceeds 2.0% by mass, the taste and yield This is not preferable because there is a risk of lowering.
[0009]
In the step (A), the time for bringing the raw shrimp or the thawed shrimp into contact with the alkaline solution is 10 to 24 hours, preferably 14 to 18 hours. If it is less than 10 hours, the desired effect of the present invention cannot be sufficiently obtained, and if it exceeds 24 hours, the improvement of the effect cannot be expected, and conversely, the heating yield may be lowered, and the process becomes complicated. The temperature of the alkaline solution is usually about 0 to 10 ° C.
The contact can usually be performed by immersing shrimp in an alkaline solution. For example, a method of repeating the step of spraying and leaving the alkaline solution on the shrimp so that the surface of the shrimp is always in contact with the alkaline solution, etc. Can also be adopted.
[0010]
In the production method of the present invention, after the step (A), the obtained shrimp is made into shrimp, frozen, chilled shrimp, vegetable shrimp, frozen, refrigerated or room temperature shrimp processed food, etc. The step (B) of heating and / or the step (C) of freezing shrimp can be performed. These steps can be performed after the shrimp prepared in step (A) is drained and lightly washed.
[0011]
【The invention's effect】
In the production method of the present invention, raw shrimp or thawed shrimp is brought into contact with an alkaline solution having a specific pH and containing trisodium citrate and a divalent alkaline earth metal salt for a specific time. While suppressing the accompanying fall of the food texture, it can suppress that the transparent feeling which is not a shrimp original appearance arises. In particular, the divalent alkaline earth metal salts, calcium lactate, calcium chloride, its effect becomes remarkable by the use of chloride magnesium. Also, even shrimp before pressurized heat can be colored in bright red appetizing. Furthermore, by freezing or heating such shrimp according to the method of the present invention, various shrimp products and shrimp processed foods with improved texture and transparency can be obtained.
[0012]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
Example 1
Potassium carbonate 0.40 mass%, sodium carbonate 0.6 mass%, trisodium citrate 1.60 mass%, magnesium chloride 1.25 mass%, sodium chloride (salt) 2.50 mass% and water 93.65 mass% % Alkaline solution with a pH of 10.25 was prepared. Next, frozen mussel (Vietnam) was thawed and immersed in the alkaline solution (liquid temperature 5 ° C.) for 16 hours. Thereafter, shrimp were taken out from the alkaline solution, washed with water, and frozen at -18 ° C.
Table 1 shows the results of color development, whiteness of the body, and transparency of the shrimp after being immersed in the alkaline solution.
Color development test: A red and vividly colored one was marked with ◎, a red colored one was marked with ○, a slight color was seen with Δ, and a non-colored one was marked with ×.
Whiteness test: ◎ for extremely white, ◯ for white, △ for slightly yellowish, and x for yellowish.
Transparency test: “A” indicates that there is no transparency, “B” indicates that there is little transparency, and “B” indicates that there is transparency.
Moreover, the yield after immersion of shrimp was calculated | required by measuring the mass before and behind immersion in an alkaline solution. The results are shown in Table 1.
[0013]
The frozen shrimp obtained above was boiled and a panel test was conducted by 10 professional panels on the texture and taste. The evaluation criteria are as follows. Moreover, the yield of shrimp after boiling was determined by measuring the mass of shrimp before and after boiling. The results are shown in Table 1.
Texture test: A sample having an appropriate pre-feel, ◯, a sample having a slightly poor texture, Δ, a sample having a slightly soft texture, and × indicating a jelly-like sample.
Taste test: A sample with a moderate shrimp taste was marked with ○, and a bitter and tasteless sample was marked with ×.
[0014]
Examples 2 and 3 and Comparative Examples 1 to 4
Frozen shrimp and boiled shrimp were prepared and tested in the same manner as in Example 1 except that the alkaline solution having the composition shown in Table 1 was used. The results are shown in Table 1.
[0015]
[Table 1]
Figure 0004109819

Claims (3)

生エビ又は解凍エビを、pH10.25〜10.96のアルカリ溶液に接触させる工程(A)を含み、該アルカリ溶液が、炭酸ナトリウム、炭酸水素ナトリウム及び炭酸カリウムからなる群より選択される少なくとも1種と、クエン酸3ナトリウムと、乳酸カルシウム、塩化カルシウム及び塩化マグネシウムからなる群より選択される1種又は2種以上の2価のアルカリ土類金属塩と、水とを含み、且つアルカリ溶液に接触させる時間が10〜24時間であることを特徴とする食感及び透明感を改良したエビ類の製造方法。 Contacting the raw or thawed shrimp with an alkaline solution having a pH of 10.25 to 10.96 , wherein the alkaline solution is at least selected from the group consisting of sodium carbonate, sodium bicarbonate and potassium carbonate An alkaline solution comprising one kind, trisodium citrate, one or more divalent alkaline earth metal salts selected from the group consisting of calcium lactate, calcium chloride and magnesium chloride , and water A method for producing shrimps with improved texture and transparency, characterized in that the time of contact with the food is 10 to 24 hours. 2価のアルカリ土類金属塩の配合割合が、アルカリ溶液全量に対して、0.1〜2.0質量%であることを特徴とする請求項1に記載の製造方法。2. The production method according to claim 1, wherein the blending ratio of the divalent alkaline earth metal salt is 0.1 to 2.0 mass% with respect to the total amount of the alkali solution. 工程(A)の後に、エビを加熱する工程(B)及び/又はエビを凍結する工程(C)を含むことを特徴とする請求項1又は2に記載の製造方法。The method according to claim 1 or 2, further comprising a step (B) of heating the shrimp and / or a step (C) of freezing the shrimp after the step (A).
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