JP4059129B2 - Heat crystallization equipment for saturated polyester hollow body - Google Patents

Heat crystallization equipment for saturated polyester hollow body Download PDF

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Publication number
JP4059129B2
JP4059129B2 JP2003105258A JP2003105258A JP4059129B2 JP 4059129 B2 JP4059129 B2 JP 4059129B2 JP 2003105258 A JP2003105258 A JP 2003105258A JP 2003105258 A JP2003105258 A JP 2003105258A JP 4059129 B2 JP4059129 B2 JP 4059129B2
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Japan
Prior art keywords
hollow body
heating
saturated polyester
mouth
neck
Prior art date
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Expired - Fee Related
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JP2003105258A
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Japanese (ja)
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JP2004306512A (en
Inventor
祐樹 鷲崎
悟 根本
昌広 石川
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Toyo Seikan Kaisha Ltd
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Toyo Seikan Kaisha Ltd
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Priority to JP2003105258A priority Critical patent/JP4059129B2/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42Component parts, details or accessories; Auxiliary operations
    • B29C49/64Heating or cooling preforms, parisons or blown articles
    • B29C49/68Ovens specially adapted for heating preforms or parisons
    • B29C49/6835Ovens specially adapted for heating preforms or parisons using reflectors

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  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Description

【0001】
【産業上の利用分野】
本発明は、飽和ポリエステル中空体の加熱結晶化装置に関し、さらに詳しくは、ポリエチレンテレフタレート等の飽和ポリエステルよりなる有底プリフォームもしくはボトル,カップ等の、キャップ等で密封されるべき口頸部を加熱結晶化する、飽和ポリエステル中空体の加熱結晶化装置に関する。
【0002】
【従来の技術】
飽和ポリエステルよりなるボトルは、通常射出成形等による形成された無定形組織の有底プリフォームを、口頸部となるべき部分を残して、2軸延伸ブロー成形することによって製造される。
この種のボトルは、肩部,胴部及び底部が分子配向されており、透明性,ガスバリヤー性,強度,耐衝撃性等の容器特性に優れ、さらに、これらの肩部,胴部及び底部をヒートセットしたボトルは、熱間充填した場合に、これらの部分が収縮による変形が起こり難いという利点を有している。
【0003】
ところで、容器の口頸部は無定形組織のままであるので、熱間充填の際に口頸部全体もしくはねじ部等は変形し、密封性が損なわれやすい。
この欠点を解消するため、プリフォーム又は容器の口頸部を加熱して結晶化することにより、口頸部の硬度や耐熱性を向上させる技術が提案されている。さらに、この際、他の加熱手段に比べ、近赤外線ヒータを採用することにより口頸部の内外面が均一に加熱することができることが提案されている(特許文献1)。
【0004】
また、従来のヒータユニットは、反照射側半面にセラミックコーティングの施された近赤外ヒータと、反射板とから構成されている。
この近赤外ヒータは、反射板の曲面領域のほぼ中央部の、上下方向の二箇所に併設してある。また、反射板は、円筒を中心軸に沿って二つ割りした曲面とこの曲面の両端部から接線方向に延長されたトンネル形状を採用していた。
このような形状とすることにより、近赤外線ヒータから照射された照射光は、セラミックコーティングや反射板に反射され、又は反射されることなく直接に被加熱部に放射されていた(特許文献2)。
【0005】
【特許文献1】
特公平5−9261号公報
【特許文献2】
特公平6−22876号公報
【0006】
ところで、飽和ポリエステルを結晶化させるために加熱すると、微量のオリゴマー(ポリエステルの熱分解により生成する低分子量物)が発生する。
このオリゴマーは、加熱されたポリエステル製中空体の口頸部から大気中に放出され、低温の物体と接触すると、その表面で凝固し白色物質として付着する。
また、ヒータユニットの反射板は、ほこり等の異物が付着すると、光の反射率が低下するので、効率よく照射光を活用するために、常に、清浄な鏡面状態を維持することが要求されている。
【0007】
【発明が解決しようとする課題】
しかしながら、従来の結晶化装置においては、連続して搬送されて加熱結晶化されるポリエステル製中空体の口頸部から発生するオリゴマーの蒸気がヒータユニット内に充満していた。このため、オリゴマーが反射板に付着し、エネルギー効率が低下し、ランニングコストの低減を図ることができないといった問題があった。
また、反射板へのオリゴマーの付着量が経時的に増すことにより、光の照射効率が変化し、この変化に応じて、近赤外ヒータの出力制御や、ポリエステル製中空体の口頸部と近赤外ヒータとの距離、位置を調整する煩わしさがあった。
さらに、反射板に付着したオリゴマーは容易に除去できないものであり、除去するには、生産ラインを止めて掃除したり新品の反射板と交換しなければならず、ライン停止により生産性が低下するといった問題があった。
【0008】
また、発生したオリゴマーを強制的に単に吸引するだけでは、ヒータユニット部の温度が低下し、一定の加熱温度を維持できないといった問題があった。すなわち、排気による冷却効果を制御する必要があった。
【0009】
本発明は、上記問題を解決すべく、ヒータユニットにおいてオリゴマー、ほこり等の異物を吸引して反射板に付着するのを防止し、また精度よく口頸部を温度制御することの可能な飽和ポリエステル中空体の加熱結晶化装置の提供を目的とする。
【0010】
【課題を解決するための手段】
この目的を達成するために、本発明の請求項1記載の飽和ポリエステル中空体の加熱結晶化装置は、飽和ポリエステル中空体の口頸部に、ヒータユニットからの光を照射し加熱することにより、前記口頸部を結晶化させる飽和ポリエステル中空体の加熱結晶化装置であって、前記口頸部を覆う遮蔽部材と、加熱された前記口頸部周囲の空気を、前記遮蔽部材の内部から強制的に排気する排気手段とを具備した構成としてある。
このようにすると、口頸部を加熱した際に発生するオリゴマーを含んだ熱気を効率よく排気することができる。
【0011】
また、本発明の請求項2記載の飽和ポリエステル中空体の加熱結晶化装置は、前記排気手段に、排気量調節手段を設けた構成としてある。
このようにすると、加熱領域の温度調節を容易にかつ精度よく行うことができる。
【0012】
また、本発明の請求項3記載の飽和ポリエステル中空体の加熱結晶化装置は、前記遮蔽部材を、前記飽和ポリエステル中空体を保持するホルダーを部分的に覆うように形成し、前記ホルダー側から吸気し反ホルダー側へ排気する構成としてある。
このようにすると、オリゴマーがホルダーに付着するのを防止することができるとともに、ホルダーの温度上昇を防止することができる。
【0013】
【発明の実施の形態】
以下、本発明の好適な実施形態について、図面を参照して説明する。
図1は、本発明にかかる飽和ポリエステル中空体の加熱結晶化装置の実施形態における要部の構成を説明するための概略断面図を示している。
同図において、加熱結晶化装置1は、飽和ポリエステル中空体の口頸部であるペットボトルのプリフォーム10の口部11に、近赤外線ヒータ313からの照射光20を照射し加熱することにより、口部11を結晶化させるヒータユニット30を備えている。
また、本実施形態の加熱結晶化装置1は、上述した従来のプリフォーム結晶化装置の加熱部として使用される。
【0014】
加熱結晶化装置1は、上述した加熱部とほぼ同様の構造としてあり、遮蔽板317の上板に排気口60が形成され、さらに、排気ダクト61が取り付けられている。
【0015】
また、この排気ダクト61は、送風装置(図示せず)と接続されており、加熱領域321内のオリゴマーを含んだ熱気を強制的に排気する。
なお、送風装置は、特に限定されるものではなく、たとえば、各ヒータユニット30に設けられた小型の送風装置でもよい。また、全てのヒータユニット30の排気をまとめて行なうことのできる大型の送風装置でもよい。さらに、専用の送風装置を設けなくても、たとえば、加熱結晶化装置1が設置される工場に備え付けられた共通の排気管に排気ダクト61を接続した構成としてもよく、すなわち、強制的に排気が行なわれる構成であればよい。
このようにすると、口部11から発生するオリゴマーを含んだ熱気を、遮蔽板319や遮蔽板317と接触させずに、あるいは、ほとんど接触させずに効率よく排気することができ、オリゴマーが、遮蔽板319や遮蔽板317に付着するのをほぼ防ぐことができる。
【0016】
また、加熱結晶化装置1は、排気口60から熱気が排気されると、ヒータユニット30と遮蔽板317の隙間341,ヒータユニット30とホルダー210の隙間342,及びホルダー210と遮蔽板317の隙間344から、常温の外気が加熱領域321に吸い込まれる。これにより、加熱領域321内の温度を制御することができる。
ここで、好ましくは、排気ダクト61に排気量調節手段としてバルブ62を設けるとよい。このようにすると、排気量を調節することにより、加熱領域321の温度調節を容易にかつ精度よく行なうことができ、すなわち、排気による冷却効果を積極的に活用できる。
なお、排気量調節手段として、通常、バタフライバルブ等のバルブ62が使用されるが、これに限定されるものではなく、たとえば、回転数制御可能な送風装置を使用してもよい。
【0017】
また、遮蔽板317は、加熱領域321内のオリゴマーを含んだ熱気を、外部に漏らすことなく、すなわち、効率よく排気ダクト61から排気することができる。
さらに、遮蔽板317が口部11を覆うことにより、加熱領域321を保温することができる。また、遮蔽板317の外側表面を耐熱断熱部材で覆うとよく、これにより、加熱領域321を保温する効果が向上し、エネルギー効率をさらに改善することができる。
【0018】
このように、本実施形態の加熱結晶化装置1によれば、口部11から発生するオリゴマーを確実に回収することができるので、たとえば、遮蔽板317や遮蔽板319にオリゴマーが付着するのを防ぎ、エネルギー効率の低下を防止できる。
また、加熱結晶化装置1は、加熱領域321の周辺にオリゴマーが付着するのを防ぎ、清浄な状態に維持することができ、口部11にオリゴマーその他の異物が付着することもない。さらに、バルブ62を設け排気量を調節することにより、加熱領域321内の温度を容易に調節することができる。
【0019】
以上、本発明の飽和ポリエステル中空体の加熱結晶化装置について、好ましい実施形態を示して説明したが、本発明は、上述した実施形態にのみ限定されるものではなく、本発明の範囲で種々の変更実施が可能であることは言うまでもない。
また、加熱対象は、ペットボトルのプリフォーム10の口部11に限定されるものではなく、たとえば、ペットボトル以外の容器等の口頸部でもよい。
【0020】
さらに、加熱領域321から吸い込んだ熱気は、通常、外気に開放されるが、これに限定されるものではなく、たとえば、フィルターを介して、熱気に含まれるオリゴマーその他の異物を除去した後、再び、加熱領域321に循環させる構成としてもよく、このようにすると、加熱領域321の温度低下を抑制することができ、エネルギー効率をさらに向上させることができる。
【0021】
【発明の効果】
以上詳細に説明したように、本発明における飽和ポリエステル中空体の加熱結晶化装置によれば、加熱領域内の熱気を強制的に排気することにより、口頸部から発生するオリゴマーを効率よく除去することができる。また、オリゴマーが反射板に付着しないので、長期間使用しても反射率が低下せず、エネルギー効率が低下するといった不具合を回避することができる。
また、熱気の排気量を調節することにより、加熱領域内の温度をより精度よく制御することができ、安定した加熱条件を実現でき、口頸部をより均一に結晶化させることができる。
【図面の簡単な説明】
【図1】図1は、本発明にかかる飽和ポリエステル中空体の加熱結晶化装置の実施形態における要部の構成を説明するための概略断面図を示している。
【符号の説明】
1 加熱結晶化装置
10 プリフォーム
11 口部
20 照射光
30 ヒータユニット
60 排気口
61 排気ダクト
62 バルブ
210 ホルダー
313 近赤外線ヒータ
317 遮蔽板
319 遮蔽板
321 加熱領域
341,342,344 隙間
[0001]
[Industrial application fields]
The present invention relates to a heated crystallization apparatus for a saturated polyester hollow body, and more specifically, a bottomed preform made of a saturated polyester such as polyethylene terephthalate or a mouth and neck portion to be sealed with a cap such as a bottle or cup. The present invention relates to a heated crystallization apparatus for a saturated polyester hollow body to be crystallized.
[0002]
[Prior art]
A bottle made of a saturated polyester is usually produced by biaxially stretching blow-molding an amorphous bottomed preform formed by injection molding or the like, leaving a portion to become the mouth and neck.
This kind of bottle has molecular orientation on the shoulder, body and bottom, and has excellent container properties such as transparency, gas barrier properties, strength and impact resistance, and these shoulder, body and bottom. The bottle heat-set has the advantage that when hot-filled, these portions are unlikely to deform due to shrinkage.
[0003]
By the way, since the mouth-and-neck portion of the container remains in an amorphous structure, the entire mouth-and-neck portion or the threaded portion is deformed during hot filling, and the sealing performance is easily lost.
In order to eliminate this defect, a technique for improving the hardness and heat resistance of the mouth and neck by heating and crystallizing the mouth or neck of the preform or the container has been proposed. Further, at this time, it has been proposed that the inner and outer surfaces of the mouth and neck can be heated uniformly by employing a near infrared heater as compared with other heating means (Patent Document 1).
[0004]
Moreover, the conventional heater unit is comprised from the near-infrared heater by which the ceramic coating was given to the counter irradiation side half surface, and the reflecting plate.
This near-infrared heater is provided in two places in the vertical direction at the substantially central portion of the curved surface area of the reflector. Further, the reflecting plate employs a curved surface obtained by dividing a cylinder into two along the central axis and a tunnel shape extending tangentially from both ends of the curved surface.
By setting it as such a shape, the irradiation light irradiated from the near-infrared heater was reflected by the ceramic coating or the reflecting plate, or was directly radiated to the heated portion without being reflected (Patent Document 2). .
[0005]
[Patent Document 1]
Japanese Patent Publication No. 5-9261 [Patent Document 2]
Japanese Examined Patent Publication No. 6-22876 [0006]
By the way, when heated to crystallize a saturated polyester, a very small amount of oligomer (low molecular weight product generated by thermal decomposition of polyester) is generated.
This oligomer is released into the atmosphere from the mouth and neck of a heated polyester hollow body, and when it comes into contact with a low-temperature object, it solidifies on the surface and adheres as a white substance.
In addition, since the reflector of the heater unit reduces the light reflectivity when foreign matter such as dust adheres, it is required to always maintain a clean mirror surface in order to efficiently use the irradiated light. Yes.
[0007]
[Problems to be solved by the invention]
However, in the conventional crystallization apparatus, the vapor of the oligomer generated from the neck and neck of the polyester hollow body that is continuously conveyed and crystallized by heating is filled in the heater unit. For this reason, there is a problem that oligomers adhere to the reflector, energy efficiency is lowered, and running cost cannot be reduced.
In addition, the amount of oligomer attached to the reflector increases with time, so that the light irradiation efficiency changes. According to this change, the output control of the near infrared heater, the mouth and neck of the polyester hollow body, There was a hassle of adjusting the distance and position with the near infrared heater.
Furthermore, oligomers adhering to the reflector cannot be easily removed. To remove them, the production line must be stopped and cleaned or replaced with a new reflector, and the productivity is reduced by stopping the line. There was a problem.
[0008]
Further, if the generated oligomer is forcibly simply sucked, there is a problem that the temperature of the heater unit is lowered and a constant heating temperature cannot be maintained. That is, it is necessary to control the cooling effect by exhaust.
[0009]
In order to solve the above problems, the present invention prevents saturated foreign substances such as oligomers and dust from adhering to the reflector in the heater unit, and can control the temperature of the mouth and neck accurately. An object of the present invention is to provide a heat crystallization apparatus for a hollow body.
[0010]
[Means for Solving the Problems]
In order to achieve this object, the saturated crystallization hollow body heat crystallization apparatus according to claim 1 of the present invention irradiates the neck and neck of the saturated polyester hollow body with light from the heater unit and heats it. An apparatus for heating and crystallizing a saturated polyester hollow body that crystallizes the mouth and neck, forcing a shielding member that covers the mouth and neck and heated air around the mouth and neck from the inside of the shielding member And an exhaust means for exhausting automatically.
If it does in this way, the hot air containing the oligomer which generate | occur | produces when a mouth neck part is heated can be exhausted efficiently.
[0011]
In addition, the saturated polyester hollow body heat crystallization apparatus according to claim 2 of the present invention has a configuration in which an exhaust amount adjusting means is provided in the exhaust means.
If it does in this way, the temperature adjustment of a heating area | region can be performed easily and accurately.
[0012]
In the saturated polyester hollow body heat crystallization apparatus according to claim 3 of the present invention, the shielding member is formed so as to partially cover a holder that holds the saturated polyester hollow body, and air is sucked from the holder side. However, it is configured to exhaust to the opposite holder side.
In this way, it is possible to prevent the oligomer from adhering to the holder and to prevent the temperature of the holder from rising.
[0013]
DETAILED DESCRIPTION OF THE INVENTION
Preferred embodiments of the present invention will be described below with reference to the drawings.
FIG. 1: has shown schematic sectional drawing for demonstrating the structure of the principal part in embodiment of the heating crystallization apparatus of the saturated polyester hollow body concerning this invention.
In the figure, the heat crystallization apparatus 1 irradiates and heats the irradiation light 20 from the near-infrared heater 313 to the mouth portion 11 of the preform 10 of the plastic bottle which is the mouth and neck portion of the saturated polyester hollow body, A heater unit 30 for crystallizing the mouth portion 11 is provided.
Moreover, the heat crystallization apparatus 1 of this embodiment is used as a heating part of the conventional preform crystallization apparatus described above.
[0014]
The heat crystallization apparatus 1 has substantially the same structure as the heating unit described above, and an exhaust port 60 is formed on the upper plate of the shielding plate 317, and an exhaust duct 61 is further attached.
[0015]
The exhaust duct 61 is connected to a blower (not shown) and forcibly exhausts hot air containing oligomers in the heating region 321.
The blower is not particularly limited, and may be a small blower provided in each heater unit 30, for example. Moreover, the large sized air blower which can perform exhaust_gas | exhaustion of all the heater units 30 collectively may be sufficient. Further, even if a dedicated blower is not provided, for example, an exhaust duct 61 may be connected to a common exhaust pipe provided in a factory where the heating and crystallization apparatus 1 is installed. Any configuration may be used.
If it does in this way, the hot air containing the oligomer which generate | occur | produces from the opening part 11 can be exhausted efficiently, without making it contact with the shielding board 319 and the shielding board 317, or hardly contacting, and an oligomer is shielding. Adhering to the plate 319 and the shielding plate 317 can be substantially prevented.
[0016]
Further, when hot air is exhausted from the exhaust port 60, the heat crystallization apparatus 1 has a gap 341 between the heater unit 30 and the shielding plate 317, a gap 342 between the heater unit 30 and the holder 210, and a gap between the holder 210 and the shielding plate 317. From 344, ambient temperature outside air is sucked into the heating region 321. Thereby, the temperature in the heating region 321 can be controlled.
Here, it is preferable that a valve 62 is provided in the exhaust duct 61 as an exhaust amount adjusting means. In this way, by adjusting the exhaust amount, the temperature of the heating region 321 can be adjusted easily and accurately, that is, the cooling effect by exhaust can be positively utilized.
Note that a valve 62 such as a butterfly valve is normally used as the exhaust amount adjusting means, but is not limited to this, and for example, a blower capable of controlling the rotational speed may be used.
[0017]
Further, the shielding plate 317 can exhaust the hot air containing the oligomer in the heating region 321 from the exhaust duct 61 without leaking outside, that is, efficiently.
Furthermore, when the shielding plate 317 covers the mouth portion 11, the heating region 321 can be kept warm. Moreover, it is good to cover the outer surface of the shielding board 317 with a heat-resistant heat insulation member, and thereby, the effect of keeping the heating region 321 warm is improved, and the energy efficiency can be further improved.
[0018]
Thus, according to the heat crystallization apparatus 1 of the present embodiment, the oligomer generated from the mouth portion 11 can be reliably recovered. For example, the oligomer adheres to the shielding plate 317 or the shielding plate 319. And can prevent a decrease in energy efficiency.
Further, the heat crystallization apparatus 1 can prevent the oligomer from adhering to the periphery of the heating region 321 and can maintain the clean state, and the oligomer 11 and other foreign matters do not adhere to the mouth portion 11. Furthermore, the temperature in the heating region 321 can be easily adjusted by providing the valve 62 and adjusting the exhaust amount.
[0019]
As mentioned above, although the preferable embodiment was shown and demonstrated about the heating crystallization apparatus of the saturated polyester hollow body of this invention, this invention is not limited only to embodiment mentioned above, Various in the range of this invention. It goes without saying that changes can be made.
Further, the heating target is not limited to the mouth portion 11 of the preform 10 of the plastic bottle, and may be, for example, the mouth and neck portion of a container other than the plastic bottle.
[0020]
Furthermore, the hot air sucked from the heating region 321 is normally released to the outside air, but is not limited to this. For example, after removing oligomers and other foreign matters contained in the hot air through a filter, Further, it may be configured to circulate in the heating region 321, and in this way, a temperature decrease in the heating region 321 can be suppressed, and energy efficiency can be further improved.
[0021]
【The invention's effect】
As described above in detail, according to the heating and crystallization apparatus for a saturated polyester hollow body in the present invention, the oligomer generated from the mouth and neck is efficiently removed by forcibly exhausting the hot air in the heating region. be able to. In addition, since the oligomer does not adhere to the reflecting plate, it is possible to avoid the problem that the reflectance does not decrease even if it is used for a long period of time, and the energy efficiency decreases.
In addition, by adjusting the exhaust amount of hot air, the temperature in the heating region can be controlled with higher accuracy, stable heating conditions can be realized, and the mouth and neck can be crystallized more uniformly.
[Brief description of the drawings]
FIG. 1 is a schematic cross-sectional view for explaining a configuration of a main part in an embodiment of a heating and crystallization apparatus for a saturated polyester hollow body according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Heating crystallization apparatus 10 Preform 11 Mouth part 20 Irradiation light 30 Heater unit 60 Exhaust outlet 61 Exhaust duct 62 Valve 210 Holder 313 Near-infrared heater 317 Shielding board 319 Shielding board 321 Heating area 341,342,344

Claims (3)

飽和ポリエステル中空体の口頸部に、ヒータユニットからの光を照射し加熱することにより、前記口頸部を結晶化させる飽和ポリエステル中空体の加熱結晶化装置であって、
前記口頸部を覆う遮蔽部材と、
加熱された前記口頸部周囲の空気を、前記遮蔽部材の内部から強制的に排気する排気手段と
を具備したことを特徴とする飽和ポリエステル中空体の加熱結晶化装置。
A saturated crystallization hollow body heating and crystallization apparatus for crystallizing the mouth and neck by irradiating and heating light from a heater unit to the mouth and neck of a saturated polyester hollow body,
A shielding member covering the mouth and neck;
An apparatus for heating and crystallizing a saturated polyester hollow body comprising exhaust means for forcibly exhausting the heated air around the mouth and neck from the inside of the shielding member.
前記排気手段に、排気量調節手段を設けたことを特徴とする請求項1記載の飽和ポリエステル中空体の加熱結晶化装置。The apparatus for heating and crystallizing a saturated polyester hollow body according to claim 1, wherein the exhaust means is provided with an exhaust amount adjusting means. 前記遮蔽部材を、前記飽和ポリエステル中空体を保持するホルダーを部分的に覆うように形成し、前記ホルダー側から吸気し反ホルダー側へ排気することを特徴とする請求項1又は2記載の飽和ポリエステル中空体の加熱結晶化装置。3. The saturated polyester according to claim 1, wherein the shielding member is formed so as to partially cover a holder that holds the saturated polyester hollow body, and sucks air from the holder side and exhausts it to the opposite holder side. Heating crystallization equipment for hollow bodies.
JP2003105258A 2003-04-09 2003-04-09 Heat crystallization equipment for saturated polyester hollow body Expired - Fee Related JP4059129B2 (en)

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JP4831353B2 (en) * 2007-02-26 2011-12-07 東洋製罐株式会社 Blow molding machine with air conditioning
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