JP4011060B2 - Resin tile - Google Patents

Resin tile Download PDF

Info

Publication number
JP4011060B2
JP4011060B2 JP2004372602A JP2004372602A JP4011060B2 JP 4011060 B2 JP4011060 B2 JP 4011060B2 JP 2004372602 A JP2004372602 A JP 2004372602A JP 2004372602 A JP2004372602 A JP 2004372602A JP 4011060 B2 JP4011060 B2 JP 4011060B2
Authority
JP
Japan
Prior art keywords
resin
fiber
combustible
tile
thermosetting resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2004372602A
Other languages
Japanese (ja)
Other versions
JP2006177078A (en
Inventor
晴次 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Otis Inc
Original Assignee
Otis Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Otis Inc filed Critical Otis Inc
Priority to JP2004372602A priority Critical patent/JP4011060B2/en
Publication of JP2006177078A publication Critical patent/JP2006177078A/en
Application granted granted Critical
Publication of JP4011060B2 publication Critical patent/JP4011060B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Description

本願発明は、軽量な屋根瓦として使用される樹脂瓦に関するものである。   The present invention relates to a resin tile used as a lightweight roof tile.

従来、古くから粘土瓦、セメント瓦等の窯業系瓦が屋根材として汎用されていた。 Traditionally, ceramic tiles such as clay tiles and cement tiles have been widely used as roofing materials.

しかしながら、かかる窯業系瓦は、重量がきわめて大きいため、屋根葺き時の作業性が悪く、かつ、建物にも大きな負荷がかかり、建物の耐久性にも悪影響を与えるという問題があった。   However, since such ceramic tiles are extremely heavy, there is a problem in that workability at the time of roofing is poor, a large load is applied to the building, and the durability of the building is adversely affected.

そこで、かかる窯業系瓦の問題点を解消するため、ガラス繊維等の不燃性繊維を含有せる不飽和ポリエステル樹脂等の熱硬化性樹脂よりなる樹脂瓦が知られている(例えば、特許文献1及び2参照。)。
特許第3454358号公報 特開2002−276082号公報
Then, in order to eliminate the problem of such ceramic tiles, resin tiles made of thermosetting resins such as unsaturated polyester resins containing non-combustible fibers such as glass fibers are known (for example, Patent Document 1 and 2).
Japanese Patent No. 3454358 JP 2002-276082 A

上記従来の樹脂瓦においては、窯業系瓦の問題点である重量が大きいという点を解消した軽量な屋根瓦として優れている。 In the above-mentioned conventional resin tile, is excellent as a lightweight roof tiles which eliminates the point that the weight is a problem of the ceramic-based tile is large.

しかしながら、かかる樹脂瓦においても、火災に遭遇した際の難燃性や、長期間の使用に際しての耐久性の点で満足すべきものであるとは言い難く、又、強度及び難燃性を向上させるために、不燃性繊維の含有量を増加させた場合には、不燃性繊維含有せる熱硬化性樹脂の成形が悪化し、汎用されている瓦形状である波板形状の樹脂瓦を円滑に製造することができないという問題があった。 However, it is difficult to say that such resin tiles are satisfactory in terms of flame retardancy when encountering a fire and durability when used for a long period of time, and improve strength and flame retardancy. for, in the case of increasing the content of incombustible fibers, molding of the thermosetting resin to contain a non-flammable fibers deteriorates, the resin tile smooth the corrugated shape is a tile shape which is generally There was a problem that it could not be manufactured.

本願発明は、かかる樹脂瓦の問題点を解消するために為されたものであり、軽量な屋根瓦として使用される樹脂瓦において、火災に遭遇した際の難燃性や、長期間の使用に際しての耐久性が優れ、又、強度及び難燃性を向上させるために、不燃性繊維の含有量を増加させても不燃性繊維を含有せる熱硬化性樹脂の成形を悪化させることなく、汎用されている瓦形状である波板形状の樹脂瓦を円滑に製造することができる樹脂瓦を提供することを課題とするものである。   The present invention was made in order to solve the problems of such resin tiles, and in resin tiles used as lightweight roof tiles, flame retardancy when encountering a fire, and long-term use In order to improve the strength and flame retardancy, it is widely used without increasing the content of the non-combustible fiber without deteriorating the molding of the thermosetting resin containing the non-combustible fiber. It is an object of the present invention to provide a resin tile that can smoothly manufacture a corrugated resin tile that is a tile shape.

本願発明は、上記課題を解決するために、請求項1においては、不燃性繊維を含有せる熱硬化性樹脂よりなる樹脂瓦であって、不燃性繊維が、不燃性繊維布の表面及び裏面に不燃性繊維片を配設してなると共に、熱硬化性樹脂が、難燃性材料を配合してなることを特徴としている。   In order to solve the above-described problems, the present invention provides a resin tile made of a thermosetting resin containing non-combustible fibers according to claim 1, wherein the non-combustible fibers are formed on the front and back surfaces of the non-combustible fiber cloth. A nonflammable fiber piece is disposed, and the thermosetting resin is formed by blending a flame retardant material.

本願発明は、請求項2においては、請求項1において、瓦形状を波板形状に形成してなることを特徴としている。   The present invention according to claim 2 is characterized in that, in claim 1, the tile shape is formed into a corrugated plate shape.

本願発明の請求項1に係る樹脂瓦おいては、不燃性繊維を構成する不燃性繊維布及び不燃性繊維片による難燃化作用と、難燃性材料を配合してなる熱硬化性樹脂による難燃化作用との相乗作用によって、優れた難燃性を発揮し、火災に遭遇した際の難燃性が優れている。 Oite resin tile according to claim 1 of the present invention, a flame-retardant effect of incombustible fabric and incombustible fiber pieces constituting the incombustible fibers, thermosetting resin obtained by blending a flame retardant material Due to the synergistic action with the flame-retarding effect of, it exhibits excellent flame retardancy and has excellent flame retardancy when encountering a fire.

又、不燃性繊維が、不燃性繊維布の表面及び裏面に不燃性繊維片を配設してなる多層繊維層よりなるので、長期間の使用に際しての耐久性が優れている。
更に又、不燃性繊維を構成する表面層及び裏面層が成形用の上型及び下型とのなじみが良い不燃性繊維片よりなると共に、補強用芯材層が、補強効果の大きな不燃性繊維布よりなるので、強度及び難燃性を向上させるために、不燃性繊維の含有量を増加させても成形用の上型及び下型とのなじみが良い不燃性繊維片の配設によって、不燃性繊維を含有せる熱硬化性樹脂の成形を悪化させることなく、汎用されている瓦形状である波板形状の樹脂瓦を円滑に製造することができる。更に、上記の通り成形用の上型及び下型とのなじみが良い不燃性繊維片の配設によって、瓦形状を波板形状に形成した樹脂瓦を円滑に製造することができる。
In addition, since the non-combustible fiber is composed of a multilayer fiber layer in which non-combustible fiber pieces are disposed on the front and back surfaces of the non-combustible fiber cloth, durability during long-term use is excellent.
Furthermore, the front layer and the back layer constituting the non-combustible fiber are made of non-combustible fiber pieces that are well-matched with the upper mold and the lower mold for molding, and the reinforcing core material layer is a non-combustible fiber having a large reinforcing effect. Because it is made of cloth, in order to improve the strength and flame retardancy, even if the content of non-combustible fibers is increased, the non-combustible fiber pieces can be made incompatible with the upper and lower molds for molding. It is possible to smoothly manufacture a corrugated resin tile, which is a commonly used tile shape, without deteriorating the molding of a thermosetting resin containing a conductive fiber. Further, as described above, the resin roof tile having the roof tile shape formed into the corrugated plate shape can be smoothly manufactured by disposing the non-combustible fiber pieces that are well adapted to the upper mold and the lower mold for molding.

以下、本願発明に係る樹脂瓦を図面とともに説明する。   Hereinafter, the resin roof according to the present invention will be described with reference to the drawings.

図1は、本願発明の樹脂瓦の一実施形態を例示した縦断面図である。   FIG. 1 is a longitudinal sectional view illustrating an embodiment of the resin roof of the present invention.

図1に例示したように、本願発明の樹脂瓦1は、不燃性繊維2を含有せる熱硬化性樹脂3よりなり、不燃性繊維2が所望枚数(図1においては、3枚)の不燃性繊維布21の表面及び裏面に、不燃性繊維片22、22を配設してなると共に、熱硬化性樹脂3が、難燃性材料31を配合してなることを特徴とするものである。   As illustrated in FIG. 1, the resin roof tile 1 of the present invention is composed of a thermosetting resin 3 containing non-combustible fibers 2, and the non-combustible number of non-combustible fibers 2 (three in FIG. 1). Incombustible fiber pieces 22 and 22 are disposed on the front and back surfaces of the fiber cloth 21, and the thermosetting resin 3 is blended with a flame retardant material 31.

上記発明において、不燃性繊維2としては、例えば、ガラス繊維、カーボン繊維等を使用し、不燃性繊維布21としては、例えば、不燃性繊維2を織成してなるクロスを使用し、不燃性繊維片22としては、例えば、5〜90mm程度、好ましくは30〜60mmの短繊維に切断又は解繊されたチョップストランドを使用するのが好ましい。 In the above invention, as the incombustible fiber 2, for example, glass fiber, carbon fiber or the like is used. As the incombustible fiber cloth 21, for example, a cloth formed by weaving the incombustible fiber 2 is used. the 22, for example, about 5~90Mm, preferably preferably used chopped strand which is cut or defibrated into short fibers of 30 to 60 mm.

又、熱硬化性樹脂3としては、例えば、不飽和ポリエステル樹脂、エポキシ樹脂、フェノール樹脂等を使用し、熱硬化性樹脂3に配合する難燃性材料31としては、例えば、水酸化アルミニウム、三酸化アンチモン、ほう酸亜鉛、ほう酸バリウム等の無機化合物や、炭酸カルシウム、けい酸カルシウム、タルク、マイカ、クレー、シリカ、アルミナ、けい砂等の無機充填材や、塩素化パラフィン、塩素化ポリエチレン、テトラブロムエタン、テトラブロムビスフェノールA等のハロゲン化合物や、トリクレジルホスフェート、クレジルジフェニールホスフェート、トリフェニールホスフェート、トリオクチルホスフェート等のりん酸エステルや、トリス(クロロエチル)ホスフェート、ビス(2,3−ジブロモプロピル)−2,3ジクロロプロピルホスフェート、トリス(2,3−ジブロモプロピル)−ホスフェート等の含ハロゲンリン酸エステル等の難燃剤を使用するのが好ましい。   Further, as the thermosetting resin 3, for example, an unsaturated polyester resin, an epoxy resin, a phenol resin or the like is used, and as the flame retardant material 31 to be blended with the thermosetting resin 3, for example, aluminum hydroxide, three Inorganic compounds such as antimony oxide, zinc borate, barium borate, inorganic fillers such as calcium carbonate, calcium silicate, talc, mica, clay, silica, alumina, silica sand, chlorinated paraffin, chlorinated polyethylene, tetrabromo Halogen compounds such as ethane, tetrabromobisphenol A, phosphate esters such as tricresyl phosphate, cresyl diphenyl phosphate, triphenyl phosphate, trioctyl phosphate, tris (chloroethyl) phosphate, bis (2,3-dibromopropyl) ) -2,3 dichloropro Ruhosufeto, tris (2,3-dibromopropyl) - is preferred to use flame retardants such as halogen-containing phosphate esters such as phosphate.

又、上記本願発明の樹脂瓦1を製造する場合には、例えば、離型フィルムの上に、難燃性材料31を配合してなる熱硬化性樹脂3溶液を供給塗布し、次いで、裏面に配設する不燃性繊維片22を供給散布し、以下、順次、上記と同様の熱硬化性樹脂3溶液を供給塗布、不燃性繊維布21を供給敷設、熱硬化性樹脂3溶液を供給塗布、表面に配設する不燃性繊維片22を供給散布、上記と同様の熱硬化性樹脂3溶液を供給塗布し、離型フィルムを供給載置することによって、上記熱硬化性樹脂3及び不燃性繊維2(不燃性繊維布21、不燃性繊維片22)を離型フィルムで挟み、成形用の上型及び下型にて加熱加圧成形することにより、不燃性繊維2を含有せる熱硬化性樹脂3よりなる樹脂瓦1を製造すれば良い。   Moreover, when manufacturing the resin roof tile 1 of the present invention, for example, a thermosetting resin 3 solution containing a flame retardant material 31 is supplied and applied on a release film, and then on the back surface. The incombustible fiber pieces 22 to be disposed are supplied and dispersed, and thereafter, the same thermosetting resin 3 solution as above is supplied and applied, the incombustible fiber cloth 21 is supplied and laid, and the thermosetting resin 3 solution is supplied and applied. By supplying and spreading the non-combustible fiber pieces 22 disposed on the surface, supplying and applying the same thermosetting resin 3 solution as described above, and supplying and releasing the release film, the thermosetting resin 3 and non-combustible fibers are provided. 2 (non-combustible fiber cloth 21, non-combustible fiber piece 22) is sandwiched between release films, and thermosetting resin containing non-combustible fiber 2 is formed by heating and pressing with an upper mold and a lower mold for molding. What is necessary is just to manufacture the resin tile 1 which consists of three.

なお、上記樹脂瓦1の製造に際しては、所望する強度に応じて、不燃性繊維布21を複数枚(図1においては、3枚)配設しても良く、かつ、複数枚の不燃性繊維布21を配設する場合には、上記不燃性繊維布21の供給敷設、熱硬化性樹脂3溶液の供給塗布を複数回繰り返して複数枚の不燃性繊維布21を配設すれば良い。   In the production of the resin tile 1, a plurality of non-combustible fiber cloths 21 (three in FIG. 1) may be disposed according to the desired strength, and a plurality of non-combustible fibers are provided. In the case where the cloth 21 is provided, the supply of the noncombustible fiber cloth 21 and the supply and application of the thermosetting resin 3 solution may be repeated a plurality of times to provide a plurality of noncombustible fiber cloths 21.

又、上記樹脂瓦1の製造に際しては、波板、平板等、所望する形状を有し、かつ、厚み3〜6mm等、所望する強度に応じた厚みを有する樹脂瓦1を製造すれば良い。   Further, when the resin roof tile 1 is manufactured, it is only necessary to manufacture the resin roof tile 1 having a desired shape such as a corrugated plate or a flat plate and having a thickness corresponding to a desired strength such as a thickness of 3 to 6 mm.

上記本願発明の樹脂瓦1においては、不燃性繊維2を構成する不燃性繊維布21及び不燃性繊維片22の不燃性に基因する難燃化作用と、難燃性材料31を配合してなる熱硬化性樹脂3の難燃性に基因する難燃化作用との相乗作用によって、優れた難燃性を発揮し、火災に遭遇した際の難燃性が優れている。   In the resin roof tile 1 of the invention of the present application, the flame retardant action caused by the non-flammability of the non-flammable fiber cloth 21 and the non-flammable fiber piece 22 constituting the non-flammable fiber 2 and the flame retardant material 31 are blended. Due to the synergistic effect with the flame retarding action due to the flame retardancy of the thermosetting resin 3, it exhibits excellent flame retardancy and is excellent in flame retardancy when encountering a fire.

又、不燃性繊維2が、不燃性繊維布21の表面及び裏面に不燃性繊維片22を配設してなる多層繊維層よりなるので、長期間の使用に際しての耐久性が優れている。   Further, since the non-combustible fiber 2 is composed of a multilayer fiber layer in which the non-combustible fiber pieces 22 are arranged on the front and back surfaces of the non-combustible fiber cloth 21, durability during long-term use is excellent.

更に又、不燃性繊維2を構成する表面層及び裏面層が成形用の上型及び下型とのなじみが良い不燃性繊維片22よりなると共に、補強用芯材層が、補強効果の大きな不燃性繊維布21よりなるので、強度及び難燃性を向上するために、不燃性繊維2を含有せる熱硬化性樹脂3の成形性を悪化させることなく、良好な成形性が要求される汎用されている瓦形状である波板形状の樹脂瓦1を円滑に製造することができる。   Furthermore, the surface layer and the back layer constituting the non-combustible fiber 2 are made of non-combustible fiber pieces 22 that are well-matched with the upper mold and the lower mold for molding, and the reinforcing core material layer is a non-combustible material having a large reinforcing effect. In order to improve strength and flame retardancy, it is widely used that requires good moldability without deteriorating the moldability of the thermosetting resin 3 containing the non-flammable fiber 2. It is possible to smoothly manufacture the corrugated resin tile 1 which is the tile shape.

本願発明の樹脂瓦の一実施形態を例示した縦断面図である。It is the longitudinal cross-sectional view which illustrated one Embodiment of the resin roof of this invention.

符号の説明Explanation of symbols

1 樹脂瓦
2 不燃性繊維
21 不燃性繊維布
22 不燃性繊維片
3 熱硬化性樹脂
31 難燃性材料
DESCRIPTION OF SYMBOLS 1 Resin tile 2 Non-combustible fiber 21 Non-combustible fiber cloth 22 Non-combustible fiber piece 3 Thermosetting resin 31 Flame-retardant material

Claims (1)

不燃性繊維を含有せる熱硬化性樹脂よりなる樹脂瓦であって、不燃性繊維が、不燃性繊維布の表面及び裏面に不燃性繊維片を配設してなると共に、熱硬化性樹脂が、難燃性材料を配合してなり、更に、瓦形状を波板形状に形成してなることを特徴とする樹脂瓦。 It is a resin tile made of a thermosetting resin containing incombustible fibers, and the incombustible fibers are formed by disposing incombustible fiber pieces on the front and back surfaces of the incombustible fiber cloth, and the thermosetting resin, A resin roof tile comprising a flame retardant material and further formed into a corrugated plate shape .
JP2004372602A 2004-12-24 2004-12-24 Resin tile Expired - Fee Related JP4011060B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004372602A JP4011060B2 (en) 2004-12-24 2004-12-24 Resin tile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004372602A JP4011060B2 (en) 2004-12-24 2004-12-24 Resin tile

Publications (2)

Publication Number Publication Date
JP2006177078A JP2006177078A (en) 2006-07-06
JP4011060B2 true JP4011060B2 (en) 2007-11-21

Family

ID=36731433

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004372602A Expired - Fee Related JP4011060B2 (en) 2004-12-24 2004-12-24 Resin tile

Country Status (1)

Country Link
JP (1) JP4011060B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101021273B1 (en) 2009-03-19 2011-03-11 씨엠알기술연구원(주) Fiber Reinforcing Panel with Flame-proof Fabric, Manufacturing method, and Concrete structure Reinforcing method using thereof
KR101035514B1 (en) 2009-03-19 2011-05-23 유암이엔씨(주) Fire Retardant Composite Fiber Reinforcing Panel including Safety Belt, Manufacturing Method, and Concrete Structure Reinforcing Method using thereof
CN103821282B (en) * 2014-02-28 2017-01-11 北京东方雨虹防水技术股份有限公司 Asphalt tile

Also Published As

Publication number Publication date
JP2006177078A (en) 2006-07-06

Similar Documents

Publication Publication Date Title
EP2221335B1 (en) Nonflammable transparent fiber-reinforced resin sheet and process for production of the same
KR101900749B1 (en) Nonflammable composite panel for exterior finish of buildings and manufacturing method thereof
JP2004100228A (en) Noncombustible heat insulating panel
KR101556901B1 (en) Insulator for building
JP4011060B2 (en) Resin tile
KR100332827B1 (en) Structure and manufacturing method of noncombustible building panel reinforced glass fiber and phenol resin
JP2007008002A (en) Flame-retardant lightweight board
KR100443057B1 (en) An incombustible sheet and manufacturing method of the same
KR102181215B1 (en) Eco-friendly quasi-noncombustible exterior material based on ceramic
JP2006177077A (en) Resin-based roof material
JPS59114050A (en) Incombustible inorganic decorative board
KR101451178B1 (en) Method for fabricating nonflammable carbon fiber hard panels
KR20180120300A (en) High strength magnesium oxide composite panel using carbon fiber grid technology and manufacturing method thereof
KR101831372B1 (en) Decoration floor panel having eco-friendly, non-inflammable and anti-curling property
KR100452486B1 (en) An incombustible sheet and manufacturing method of the same using incombustible resin composition
KR200412102Y1 (en) The panel for resistance to flame in building
JP4034313B2 (en) Resin tile
KR101373627B1 (en) Vermiculite board, composite panel and its manufacturing method
KR200419439Y1 (en) Flame retardant polyester fiber board
JP2006193998A (en) Laminated roofing tile
JP7217437B2 (en) Interior panel and method for manufacturing interior panel
KR102282772B1 (en) Manufacturing method of sandwich panel of fire-resistant and stone panel having thereof
JP2009185557A (en) Resin roofing material
CN219528226U (en) Carbon fiber reinforced poplar-based composite board with flame retardant function
KR102142227B1 (en) Manufacturing method of flame retardant insulation sheet and flame retardant insulation sheet manufactured by thereof

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20061011

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20061219

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070219

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20070807

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20070904

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100914

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110914

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110914

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120914

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130914

Year of fee payment: 6

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees