JP3984065B2 - Fixative for wig - Google Patents
Fixative for wig Download PDFInfo
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- JP3984065B2 JP3984065B2 JP2002031847A JP2002031847A JP3984065B2 JP 3984065 B2 JP3984065 B2 JP 3984065B2 JP 2002031847 A JP2002031847 A JP 2002031847A JP 2002031847 A JP2002031847 A JP 2002031847A JP 3984065 B2 JP3984065 B2 JP 3984065B2
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Description
【0001】
【発明の属する技術分野】
本発明は、カツラ用固定剤に関し、更に詳しくは、カツラ等の基体を頭皮、額部および頭髪部局所に接着させるための固定剤に関する。
【0002】
【従来の技術】
従来、局所的に頭髪の薄くなった部分を隠す方法として、カツラ等の擬似毛髪を、その薄毛部分に被着させる方法がある。このようなカツラを用いて薄毛部分を隠す方法においては、通常、カツラと頭皮或いは毛髪とを固定する必要があり、固定する方法としては、ヘアピンのような器具を用いて固定させる方法、両面テープにより固定させる方法、或いは専用の接着剤を用いて接着させる方法がとられている。特に、薄毛部分の面積が大きかったり、また境界部に毛髪のない前頭部の薄毛を隠すには、接着剤が汎用されている。一般に市販されているこれらカツラ用の接着剤は、、木工用ボンド等に代表される家庭用の接着剤であるアクリル酸と酢酸ビニルの共重合体やそのエマルジョンが主成分として使用されている。
【0003】
【発明が解決しようとする課題】
しかしながら、これらアクリル酸と酢酸ビニルの共重合体は、酢酸ビニル特有のビニル臭を有しており、使用時に不快感を与え、また、乾燥後は耐水性が高く簡単に取ることが出来ず、剥がすときに痛みを生じたりしていた。更に、使用時に糸を引く特性を有していたり、毛髪や衣服に付着すると通常の洗髪や洗濯で接着剤固形物を取ることができないという欠点を有していた。そのため、不快な臭いがせず、容易に剥がすことができ、毛髪や衣服に誤って付着しても簡単に洗い落とせ、かつ乾燥性や粘着性・接着性に優れたカツラ用の接着剤が強く望まれていた。
【0004】
【課題を解決するための手段】
そこで、本発明者は、前記従来技術の問題点を解決しようと試み、鋭意研究した結果、ポリビニルピロリドン系水溶性高分子とアニオン性水溶性高分子とを含有することを特徴とするカツラ用固定剤を含有することを特徴とするカツラ用固定剤によって、不快な臭いがせず、容易に剥がすことができ、糸曳き性もなく、毛髪や衣服に誤って付着しても簡単に洗い落とせ、かつ乾燥性や粘着性・接着性に優れたカツラ用固定剤が得られることを見出し、本発明を完成するに至った。
【0005】
【発明の実施の形態】
すなわち、本発明は、ポリビニルピロリドン系水溶性高分子とアニオン性水溶性高分子とを含有することを特徴とするカツラ用固定剤を含有することを特徴とするカツラ用固定剤にある。
【0006】
本発明で用いられるポリビニルピロリドン系水溶性高分子は、ビニルピロリドン骨格を有する高分子化合物であり、一般に化粧料に用いられるものであれば特に限定されないが、具体例を挙げれば、
(1)ビニルピロリドンを基本とする単位で構成されるポリビニルピロリドン(例えばBASF社製のルビスコ−ルK−30,ルビスコ−ルK−90、ISP社製のPVP K30,PVP K90)、
(2)ビニルピロリドン及び酢酸ビニルを基本とする単位で構成されるビニルピロリドン・酢酸ビニル共重合体(例えばBASF社製のルビスコ−ルVA、ヘンケル社製のナズナB、ISP社製のPVP/VA)、
(3)ビニルピロリドン,アクリル酸及びアルキルアクリル酸を基本とする単位で構成されるビニルピロリドン・アクリル酸・アルキルアクリル酸共重合体(例えばISP社製のAcrylidone LM)、
(4)ビニルピロリドン及びジメチルアミノエチルメタクリル酸を基本とする単位で構成されるポリビニルピロリドン・ジメチルアミノエチルメタクリル酸共重合体(例えばPhoenix社製のPecogel S−1120)、
(5)ビニルピロリドン,ジメチルアミノエチルメタクリル酸及びウレタンを基本とする単位で構成されるポリビニルピロリドン・ジメチルアミノエチルメタクリル酸・ポリウレタン共重合体(例えばPhoenix社製のPecogel GC−310,Pecogel GC−1110)、
(6)ビニルピロリドン及びジメチルアミノプロピルアクリルアミドを基本とする単位で構成されるビニルピロリドン・ジメチルアミノプロピルアクリルアミド共重合体(例えばISP社製のACP−1163)、
(7)ビニルピロリドン及びウレタンを基本とする単位で構成されるポリビニルピロリドン・ポリウレタン共重合体(例えばPhoenix社製のPecogel H−12,Pecogel H−115)等が使用される。
【0007】
本発明においては、これらポリビニルピロリドン系水溶性高分子の中から、一種類又は二種以上を用いることができ、また、接着力や高分子化合物の溶解性の点で、ポリビニルピロリドン、ビニルピロリドン・酢酸ビニル共重合体が好ましい。また、ポリビニルピロリドン系水溶性高分子の配合量は、接着力付与の目的で、通常5〜80質量%(以下、単に%と記する)、好ましくは、10〜50%配合される。5%未満では、十分な接着力を得ることができず、また80%を超えると溶解させることが困難となったり、また組成物の粘性が上昇し、塗布しにくくなるなどの使用感に問題が生じる場合がある。
【0008】
本発明で用いられるアニオン性水溶性高分子は、ポリビニルピロリドン系水溶性高分子と組み合わせることにより、糸曳き性を防止するとともに、カツラとの接着性を向上させたり、粘性を向上させて使用時の垂れ落ち等を防止するものである。アニオン性水溶性高分子としては、一般に化粧料に用いられるものであれば特に限定されないが、具体例を挙げれば、
(1)ペンタエリスチル,スクロース又はプロピレンのエーテルで架橋したカルボキシビニルポリマー(例えばB.F.グッドリッチ社製のカーボポール、3Vシグマ社製のシンタレン、和光純薬社製のハイビスワコー)、
(2)アクリル酸とメタクリル酸アルキルを基本とする単位で構成されるアクリル酸・メタクリル酸アルキル共重合体(例えばB.F.グッドリッチ社製のPEMULEN)、
(3)アクリル酸及びメタクリル酸から選ばれる少なくとも1種を基本とする単位で構成されるアクリル樹脂(例えば互応化学社製のプラスサイズ、大阪有機社製のアニセット、三菱化学社製のダイヤホールド)、
(4)酢酸ビニル及びクロトン酸を基本とする単位で構成される酢酸ビニル・クロトン酸共重合体(例えばNSC社製のレジン28−1310)、
(5)アクリル酸及びネオデカン酸ビニルを基本とする単位で構成される高分子(例えばNSC社製のレジン28−2930)、
(6)アクリル酸及びアルキルアクリルアミドを基本とする単位で構成されるアクリル酸アルキル共重合体(例えばNSC社製のバーサクリル、BASF社製のウルトラホールド)、
(7)メチルビニルエーテルマレイン酸を基本とする単位で構成されるビニルメチルエーテル・マレイン酸ブチル共重合体(例えばISP社製のガントレッツ)等が挙げられる。
【0009】
本発明においては、これらアニオン性水溶性高分子の中から、一種類又は二種以上を用いることができ、また、ポリビニルピロリドン系水溶性高分子との相溶性及び増粘性の点で、カルボキシビニルポリマー、アクリル酸・メタクリル酸アルキル共重合体、アクリル樹脂が好ましい。また、アニオン性水溶性高分子の配合量は、好ましくは、0.5〜50%、更に好ましくは、1〜30%である。0.5%未満では、糸曳き性を解消することができず、また50%を超えると溶解させることが困難となったり、また組成物の粘性が上昇して塗布できないなどの使用上の問題を生じる場合がある。
【0010】
本発明のカツラ用固定剤は所望により、本発明の効果を損しない範囲で、通常化粧料に一般に配合される成分、例えばエタノール、イソプロパノール等のアルコール、ラノリン誘導体、蛋白質誘導体や、メチルポリシロキサン、メチルフェニルポリシロキサン等のシリコーン油、ポリエチレングリコールの脂肪酸エステル油、ツバキ油、オリーブ油等の植物油等の油性成分、プロピレングリコール、グリセリン、ポリエチレングリコール等の保湿成分、ポリオキシエチレンアルキルエーテル等の非イオン界面活性剤、カルボキシベタイン等の両性界面活性剤、アルキルスルホン酸塩等のアニオン界面活性剤、流動パラフィン、ワセリン、スクワラン等の炭化水素、水溶性高分子物質(アニオン性、非イオン性、カチオン性のものを含む)、金属イオン封鎖剤、防腐剤、pH調整剤、ビタミン類、紫外線吸収剤、酸化防止剤、色素、香料及び噴射剤等を含むことができる。
【0011】
本発明のカツラ用固定剤は、剤型としてエアゾール、液状、乳液状、クリーム状、ゲル状等様々な剤型タイプにすることができ、特に剤型を問わない。また、刷毛などの器具を用いて皮膚,毛髪及びカツラに直接に塗布してもよいし、また手や指によって塗布してもよく、更に、ポンプミストや噴射剤を配合したスプレーにして使用部位に噴霧してもよい。
【0012】
【実施例】
次に本発明を実施例を以って詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。なお、以下の表に示す組成物の配合量は、それぞれ質量%で示す。
【0013】
▲1▼匂い、糸曳き性の試験法
5名のパネルを用いて、本発明の実施例及び比較例の組成物の匂い及び糸曳き性について官能評価を行った。尚、評価基準は以下のように設定した。
・評価基準(匂い)
◎・・・刺激臭について「なし」と答えたパネルが7人以上
○・・・刺激臭について「なし」と答えたパネルが5人以上、7人未満
△・・・刺激臭について「なし」と答えたパネルが3人以上、5人未満
×・・・刺激臭について「なし」と答えたパネルが3人未満
・評価基準(糸曳き性)
◎・・・糸曳き性について「なし」と答えたパネルが7人以上
○・・・糸曳き性について「なし」と答えたパネルが5人以上、7人未満
△・・・糸曳き性つきについて「なし」と答えたパネルが3人以上、5人未満
×・・・糸曳き性について「なし」と答えたパネルが3人未満
【0014】
▲2▼洗浄容易性試験法
日本人黒色毛髪からなる毛束(5g、15cm)に実施例及び比較例の組成物を1g塗布し、室温にて1時間乾燥させた。次いで市販のシャンプー0.5gを用いて1分間揉み洗いを行い、水で濯いだ後乾燥させた。2時間室温にて乾燥させた後、5名のパネルを用いて、固定剤の毛髪への残留性を評価した。尚、評価基準は以下のように設定した。
・評価基準(洗浄容易性)
◎・・・固定剤の残留性について「なし」と答えたパネルが7人以上
○・・・固定剤の残留性について「なし」と答えたパネルが5人以上、7人未満
△・・・固定剤の残留性について「なし」と答えたパネルが3人以上、5人未満
×・・・固定剤の残留性について「なし」と答えたパネルが3人未満
【0015】
▲3▼乾燥性試験法
25℃、湿度60%の恒温恒湿室内において、Texture Analyser(TA−XT2、Stable Micro社製)を用いて、試料0.1gについて800gの荷重をかけながら、20秒間隔で繰り返し、粘着力を測定し、粘着力が20g以下となった点を乾燥終了点として、乾燥までの時間を測定した。尚評価基準は以下のように設定した。
・評価基準(乾燥速度)
◎・・・乾燥時間が3分未満
○・・・乾燥時間が3分以上、5分未満
△・・・乾燥時間が5分以上、10分未満
×・・・乾燥時間が10分以上
【0016】
▲3▼接着力試験法
上腕内側部に試料0.5gを均一に塗布し、次いで市販のカツラ(接触面2cm×2cm)を密着させる。10分間放置して乾燥させた後に、引張強度試験機を用いて、剥離するのに必要な応力を測定した。尚評価基準は以下のように設定した。
・評価基準(接着力)
◎・・・剥離するのに必要な力が1kgf以上
○・・・剥離するのに必要な力が0.7kgf以上、1kgf未満
△・・・剥離するのに必要な力が0.5kgf以上、0.7kgf未満
×・・・剥離するのに必要な力が0.5kgf未満
【0017】
実施例1〜5、比較例1〜4
表1に示す組成のカツラ用固定剤を試作し、匂い、糸曳き性、洗浄容易性、乾燥性及び接着力を調べた。結果を表1に併せて示す。
【0018】
【表1】
【0019】
表1より明らかなように、本発明の成分を用いた実施例1〜5のカツラ用固定剤はいずれも優れた性能を示していた。一方、必須成分を欠いた比較例1〜3は、糸曳き性や乾燥性、接着力に劣り、また従来から使用されているアクリル酸・酢酸ビニル共重合体を用いた比較例4は、糸曳きは少ないものの、その他の項目において劣っており、本発明の効果を達成できなかった。
【0020】
以下、本発明のカツラ用固定剤のその他の処方例を実施例として挙げる。尚、これらの実施例のカツラ用固定剤についても、上記の匂い、糸曳き性、洗浄容易性、乾燥性及び接着力について検討したところ、いずれの実施例においても優れた特性を有していた。
【0021】
実施例6 カツラ固定剤(透明ジェル状タイプ)
(配合成分) 配合量(%)
1)PVP/VA S−630(ISP社製) 40.0
2)シンタレンK(3Vシグマ社製) 0.8
3)トリエタノールアミン 0.6
4)エタノール 30.0
5)イソプロピルメチルフェノール 0.1
6)グリチルリチン酸ジカリウム 0.1
7)メチルパラベン 0.1
8)香料 0.1
9)精製水 残 部
【0022】
<製造方法>2及び6を9の一部に分散する。次に1、3〜5、7、8及び9の残部を混合溶解したものを加え、ホモミキサーを用いて均一に混合溶解し、チューブ容器に充填した。
【0023】
実施例7 カツラ固定剤(透明ローションタイプ)
(配合成分) 配合量(%)
1)PVP/VA S−630(ISP社製) 20.0
2)ルビスコールK−30(BASF社製) 10.0
3)PEMULEN TR−1 0.3
(B.F.グッドリッチ社製)
4)カーボーポール981(B.F.グッドリッチ社製) 0.2
5)トリエタノールアミン 0.3
6)エタノール 20.0
7)フェノキシエタノール 0.3
8)POE(60)硬化ヒマシ油 0.1
9)精製水 残 部
【0024】
<製造方法>2及び3を9の一部に分散する。次に1、2、5〜8及び9の残部を混合溶解したものを加え、ホモミキサーを用いて均一に混合溶解し、ボトル容器に充填した。
【0025】
実施例8 カツラ固定剤(乳濁状低粘度タイプ)
(配合成分) 配合量(%)
1)PVP/VA S−630(ISP社製) 33.0
2)プラスサイズL−9650(互応化学社製) 30.0
3)エタノール 8.0
4)イソプロピルメチルフェノール 0.1
5)アンタラ430(ISP社製) 1.0
6)メチルパラベン 0.1
7)POE(60)硬化ヒマシ油 0.1
8)精製水 残 部
【0026】
<製造方法>1を8に均一溶解し、3〜7を均一に溶解したものを加え、最後に2を加えた後、ホモミキサーを用いて均一の混合分散を行い、チューブ容器に充填した。
【0027】
尚、上記処方において用いた香料は下記のものである。
【表2】
【0028】
【発明の効果】
以上記載のごとく、本発明は、不快な臭いがせず、容易に剥がすことができ、糸曳き性もなく、毛髪や衣服に誤って付着しても簡単に洗い落とせ、かつ乾燥性や粘着性・接着性に優れたカツラ用固定剤を提供することができる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a fixative for wigs, and more particularly to a fixative for adhering a substrate such as a wig to the scalp, the forehead portion, and the local hair portion.
[0002]
[Prior art]
Conventionally, as a method of concealing a locally thinned portion of hair, there is a method of attaching artificial hair such as wig to the thinned portion. In the method of hiding the thin hair portion using such a wig, it is usually necessary to fix the wig and the scalp or the hair. As a method of fixing, a method of fixing using a device such as a hairpin, double-sided tape A method of fixing by using a special adhesive or a method of bonding using a dedicated adhesive is employed. In particular, an adhesive is widely used in order to hide the thin hair of the frontal region where the area of the thin hair portion is large or the hair does not have hair at the boundary portion. In general, these adhesives for wigs that are commercially available use as a main component a copolymer of acrylic acid and vinyl acetate, which is a household adhesive typified by a bond for woodworking, or an emulsion thereof.
[0003]
[Problems to be solved by the invention]
However, these copolymers of acrylic acid and vinyl acetate have a vinyl odor peculiar to vinyl acetate, give unpleasant feeling during use, and are highly water resistant after drying and cannot be easily taken. There was pain when it was peeled off. Further, it has a characteristic that it has a characteristic of pulling a thread during use, and when it adheres to hair or clothes, it cannot be removed by ordinary hair washing or washing. Therefore, it does not smell unpleasant, can be easily peeled off, can be easily washed off even if it is accidentally attached to hair or clothing, and has a strong adhesive for wigs with excellent dryness, tackiness and adhesiveness. It was desired.
[0004]
[Means for Solving the Problems]
Accordingly, the present inventor tried to solve the problems of the prior art, and as a result of earnest research, the present inventors have fixed a wig characterized by containing a polyvinylpyrrolidone-based water-soluble polymer and an anionic water-soluble polymer. With a fixative for wig characterized by containing an agent, there is no unpleasant odor, it can be easily peeled off, there is no stringiness, it can be easily washed off even if it accidentally adheres to hair or clothes, And it discovered that the fixing agent for wigs excellent in drying property, adhesiveness, and adhesiveness was obtained, and came to complete this invention.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
That is, the present invention resides in a wig fixing agent characterized by containing a wig fixing agent characterized by containing a polyvinylpyrrolidone-based water-soluble polymer and an anionic water-soluble polymer.
[0006]
The polyvinyl pyrrolidone-based water-soluble polymer used in the present invention is a polymer compound having a vinyl pyrrolidone skeleton and is not particularly limited as long as it is generally used in cosmetics.
(1) Polyvinyl pyrrolidone composed of units based on vinyl pyrrolidone (for example, Rubiscoll K-30, Rubiscoll K-90 manufactured by BASF, PVP K30, PVP K90 manufactured by ISP),
(2) Vinylpyrrolidone / vinyl acetate copolymer composed of units based on vinylpyrrolidone and vinyl acetate (for example, Rubiscoll VA manufactured by BASF, Nazuna B manufactured by Henkel, and PVP / VA manufactured by ISP) ),
(3) Vinylpyrrolidone / acrylic acid / alkylacrylic acid copolymer composed of units based on vinylpyrrolidone, acrylic acid and alkylacrylic acid (for example, Acrylidone LM manufactured by ISP),
(4) a polyvinylpyrrolidone / dimethylaminoethyl methacrylic acid copolymer composed of units based on vinyl pyrrolidone and dimethylaminoethyl methacrylic acid (for example, Pecogel S-1120 manufactured by Phoenix),
(5) A polyvinyl pyrrolidone / dimethylaminoethyl methacrylic acid / polyurethane copolymer composed of units based on vinyl pyrrolidone, dimethylaminoethyl methacrylic acid and urethane (for example, Pecogel GC-310, Pecogel GC-1110 manufactured by Phoenix) ),
(6) Vinylpyrrolidone-dimethylaminopropylacrylamide copolymer (for example, ACP-1163 manufactured by ISP) composed of units based on vinylpyrrolidone and dimethylaminopropylacrylamide;
(7) A polyvinyl pyrrolidone / polyurethane copolymer composed of units based on vinyl pyrrolidone and urethane (for example, Pecogel H-12, Pecogel H-115 manufactured by Phoenix) is used.
[0007]
In the present invention, one or more of these polyvinylpyrrolidone-based water-soluble polymers can be used, and in terms of adhesive strength and solubility of the polymer compound, polyvinylpyrrolidone, vinylpyrrolidone, A vinyl acetate copolymer is preferred. The blending amount of the polyvinylpyrrolidone-based water-soluble polymer is usually 5 to 80% by mass (hereinafter simply referred to as “%”), preferably 10 to 50% for the purpose of imparting adhesive strength. If it is less than 5%, sufficient adhesion cannot be obtained, and if it exceeds 80%, it becomes difficult to dissolve, and the viscosity of the composition increases, making it difficult to apply. May occur.
[0008]
The anionic water-soluble polymer used in the present invention, when combined with a polyvinylpyrrolidone-based water-soluble polymer, prevents stringing and improves adhesion with a wig or improves viscosity when used. This prevents dripping or the like. The anionic water-soluble polymer is not particularly limited as long as it is generally used in cosmetics.
(1) A carboxyvinyl polymer crosslinked with an ether of pentaerythryl, sucrose, or propylene (for example, carbopol manufactured by BF Goodrich, syntalene manufactured by 3V Sigma, Hibiswaco manufactured by Wako Pure Chemical Industries),
(2) an acrylic acid / alkyl methacrylate copolymer composed of units based on acrylic acid and alkyl methacrylate (for example, PEMULEN manufactured by BF Goodrich),
(3) Acrylic resin composed of units based on at least one selected from acrylic acid and methacrylic acid (for example, plus size manufactured by Kyoyo Chemical Co., Ltd., aniset manufactured by Osaka Organic Chemical Co., Ltd., diamond hold manufactured by Mitsubishi Chemical Corporation) ,
(4) Vinyl acetate / crotonic acid copolymer composed of units based on vinyl acetate and crotonic acid (for example, Resin 28-1310 manufactured by NSC),
(5) a polymer composed of units based on acrylic acid and vinyl neodecanoate (for example, Resin 28-2930 manufactured by NSC),
(6) An alkyl acrylate copolymer composed of units based on acrylic acid and alkyl acrylamide (for example, Versacryl manufactured by NSC, Ultrahold manufactured by BASF),
(7) Vinyl vinyl ether / butyl maleate copolymer composed of units based on methyl vinyl ether maleic acid (for example, GANTREZ manufactured by ISP) and the like.
[0009]
In the present invention, one or more of these anionic water-soluble polymers can be used, and carboxyvinyl can be used from the viewpoint of compatibility with a polyvinylpyrrolidone-based water-soluble polymer and thickening. Polymers, acrylic acid / alkyl methacrylate copolymers, and acrylic resins are preferred. The blending amount of the anionic water-soluble polymer is preferably 0.5 to 50%, more preferably 1 to 30%. If it is less than 0.5%, the stringiness cannot be eliminated, and if it exceeds 50%, it becomes difficult to dissolve, and the viscosity of the composition increases, so that it cannot be applied. May occur.
[0010]
The wig fixing agent of the present invention is a component generally blended in cosmetics, for example, alcohols such as ethanol and isopropanol, lanolin derivatives, protein derivatives, methylpolysiloxane, Non-ionic interfaces such as silicone oils such as methylphenylpolysiloxane, fatty acid esters such as polyethylene glycol fatty acid ester oil, camellia oil, vegetable oils such as olive oil, moisturizing ingredients such as propylene glycol, glycerin and polyethylene glycol, polyoxyethylene alkyl ether Activators, amphoteric surfactants such as carboxybetaine, anionic surfactants such as alkyl sulfonates, hydrocarbons such as liquid paraffin, petrolatum, squalane, water-soluble polymer substances (anionic, nonionic, cationic) ), Gold Sequestering agents, preservatives, pH adjusting agents, vitamins, UV absorbers, antioxidants, pigments, may include perfumes and propellants, and the like.
[0011]
The wig fixing agent of the present invention can be made into various dosage form types such as aerosol, liquid, emulsion, cream, gel, etc., and the dosage form is not particularly limited. In addition, it may be applied directly to the skin, hair and wig using tools such as a brush, or it may be applied by hand or finger, and further used as a spray containing pump mist or propellant. You may spray on.
[0012]
【Example】
EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited by this. Prior to the examples, test methods and evaluation methods employed in each example will be described. In addition, the compounding quantity of the composition shown in the following table | surfaces is each shown by the mass%.
[0013]
(1) Smell and stringiness test method Sensory evaluation was performed on the odor and stringiness of the compositions of Examples and Comparative Examples of the present invention using a panel of five persons. The evaluation criteria were set as follows.
・ Evaluation criteria (odor)
◎ ・ ・ ・ 7 or more panel responding “None” for irritating odor ○ ・ ・ ・ 5 or more panel responding “None” for irritating odor More than 3 panelists answered less than 5 people x ... Less than 3 panelists answered "None" for irritating odors. Evaluation criteria (stringiness)
◎ ・ ・ ・ Seven or more panels that answered “None” about stringing property ○ ・ ・ ・ More than 5 and less than 7 panels that answered “None” about stringing property △ ・ ・ ・ With stringing property More than 3 panelists who answered “None” for less than 5 people × ... Less than 3 panels who answered “None” for stringing properties [0014]
(2) Ease of washing test method 1 g of the compositions of Examples and Comparative Examples was applied to a hair bundle (5 g, 15 cm) consisting of Japanese black hair and dried at room temperature for 1 hour. Next, it was washed with 0.5 g of a commercial shampoo for 1 minute, rinsed with water and then dried. After drying at room temperature for 2 hours, the persistence of the fixative on the hair was evaluated using a panel of 5 persons. The evaluation criteria were set as follows.
・ Evaluation criteria (easy cleaning)
◎ ・ ・ ・ More than 7 panelists who answered “None” about fixative persistence ○ ・ ・ ・ More than 5 panels less than 7 panelists answered “None” about fixer persistence △ ・ ・ ・Three or more panels that answered “None” regarding the persistence of the fixative, and less than five people × ... Less than three panels that answered “None” regarding the persistence of the fixative
(3) Drying test method In a constant temperature and humidity room at 25 ° C. and 60% humidity, a texture analyzer (TA-XT2, manufactured by Stable Micro) was used for 20 seconds while applying a load of 800 g on 0.1 g of the sample. Repeatedly at intervals, the adhesive strength was measured, and the time until drying was measured with the point at which the adhesive strength became 20 g or less as the end point of drying. The evaluation criteria were set as follows.
・ Evaluation criteria (drying speed)
◎ ・ ・ ・ Drying time is less than 3 minutes ○ ・ ・ ・ Drying time is 3 minutes or more and less than 5 minutes Δ ・ ・ ・ Drying time is 5 minutes or more and less than 10 minutes × ・ ・ ・ Drying time is 10 minutes or more ]
(3) Adhesive strength test method 0.5 g of the sample is uniformly applied to the inner side of the upper arm, and then a commercially available wig (contact surface 2 cm × 2 cm) is adhered. After being left to dry for 10 minutes, the stress required for peeling was measured using a tensile strength tester. The evaluation criteria were set as follows.
・ Evaluation criteria (adhesive strength)
◎ ・ ・ ・ The force necessary for peeling is 1 kgf or more ○ ・ ・ ・ The force necessary for peeling is 0.7 kgf or more, less than 1 kgf Δ ・ ・ ・ The force necessary for peeling is 0.5 kgf or more, Less than 0.7 kgf × ・ ・ ・ The force required for peeling is less than 0.5 kgf.
Examples 1-5, Comparative Examples 1-4
A wig fixing agent having the composition shown in Table 1 was made as a prototype, and the odor, stringing property, ease of cleaning, drying property and adhesive strength were examined. The results are also shown in Table 1.
[0018]
[Table 1]
[0019]
As is clear from Table 1, all the fixatives for wigs of Examples 1 to 5 using the components of the present invention exhibited excellent performance. On the other hand, Comparative Examples 1 to 3 lacking essential components are inferior in stringiness, drying and adhesive strength, and Comparative Example 4 using a conventionally used acrylic acid / vinyl acetate copolymer is yarn Although there was little whispering, it was inferior in other items, and the effect of the present invention could not be achieved.
[0020]
Hereinafter, other prescription examples of the fixative for wigs of the present invention will be given as examples. In addition, when the odor, stringiness, ease of washing, drying property, and adhesive strength of the wig fixing agents of these examples were examined, they had excellent characteristics in any of the examples. .
[0021]
Example 6 Wig fixative (transparent gel type)
(Blending ingredients) Blending amount (%)
1) PVP / VA S-630 (manufactured by ISP) 40.0
2) Shintalen K (manufactured by 3V Sigma) 0.8
3) Triethanolamine 0.6
4) Ethanol 30.0
5) Isopropylmethylphenol 0.1
6) Dipotassium glycyrrhizinate 0.1
7) Methyl paraben 0.1
8) Fragrance 0.1
9) Balance of purified water [0022]
<Production Method> 2 and 6 are dispersed in a part of 9. Next, what was mixed and dissolved the remainder of 1, 3-5, 7, 8 and 9 was added, mixed and dissolved uniformly using a homomixer, and filled into a tube container.
[0023]
Example 7 wig fixative (transparent lotion type)
(Blending ingredients) Blending amount (%)
1) PVP / VA S-630 (manufactured by ISP) 20.0
2) Rubiscol K-30 (manufactured by BASF) 10.0
3) PEMULEN TR-1 0.3
(BF Goodrich)
4) Carbopole 981 (manufactured by BF Goodrich) 0.2
5) Triethanolamine 0.3
6) Ethanol 20.0
7) Phenoxyethanol 0.3
8) POE (60) hydrogenated castor oil 0.1
9) Balance of purified water [0024]
<Production Method> 2 and 3 are dispersed in a part of 9. Next, what mixed and dissolved the remainder of 1, 2, 5-8, and 9 was added, and it mixed and dissolved uniformly using the homomixer, and filled the bottle container.
[0025]
Example 8 wig fixative (emulsion low viscosity type)
(Blending ingredients) Blending amount (%)
1) PVP / VA S-630 (manufactured by ISP) 33.0
2) Plus size L-9650 (manufactured by Kyoyo Chemical) 30.0
3) Ethanol 8.0
4) Isopropylmethylphenol 0.1
5) Antara 430 (manufactured by ISP) 1.0
6) Methylparaben 0.1
7) POE (60) hydrogenated castor oil 0.1
8) Balance of purified water [0026]
<Production method> 1 was uniformly dissolved in 8, 1 to 7 was uniformly dissolved, and finally 2 was added, followed by uniform mixing and dispersion using a homomixer and filling into a tube container.
[0027]
In addition, the fragrance | flavor used in the said prescription is the following.
[Table 2]
[0028]
【The invention's effect】
As described above, the present invention does not have an unpleasant odor, can be easily peeled off, has no stringiness, can be easily washed off even if it is accidentally attached to hair or clothes, and has a drying property or adhesiveness. -A fixing agent for wigs having excellent adhesiveness can be provided.
Claims (1)
Priority Applications (1)
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JP2002031847A JP3984065B2 (en) | 2002-02-08 | 2002-02-08 | Fixative for wig |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2002031847A JP3984065B2 (en) | 2002-02-08 | 2002-02-08 | Fixative for wig |
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JP3984065B2 true JP3984065B2 (en) | 2007-09-26 |
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EP1949809A1 (en) * | 2005-10-21 | 2008-07-30 | Aderans Co., Ltd. | Wig and method of producing the same |
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JP3200449B2 (en) * | 1991-08-20 | 2001-08-20 | 日本ユニカー株式会社 | Set holding hair cosmetics |
JPH06346041A (en) * | 1993-06-10 | 1994-12-20 | Showa Denko Kk | Hydrophilic tacky agent composition |
JPH0977642A (en) * | 1995-09-08 | 1997-03-25 | Shiseido Co Ltd | Hair cosmetic |
JPH10291918A (en) * | 1997-04-18 | 1998-11-04 | Kose Corp | Hair dressing agent composition |
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