JP3983044B2 - Fluorine resin lining tank - Google Patents
Fluorine resin lining tank Download PDFInfo
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- JP3983044B2 JP3983044B2 JP2001368803A JP2001368803A JP3983044B2 JP 3983044 B2 JP3983044 B2 JP 3983044B2 JP 2001368803 A JP2001368803 A JP 2001368803A JP 2001368803 A JP2001368803 A JP 2001368803A JP 3983044 B2 JP3983044 B2 JP 3983044B2
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- Prior art keywords
- lining
- tank
- fluororesin
- lid
- lining material
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Description
【0001】
【発明の属する技術分野】
本発明は、薬液等を収容するタンクに用いて好適なフッ素樹脂ライニングタンクの改良に関する。
【0002】
【従来の技術】
従来、各種薬液や溶剤等の腐食性液体を取り扱う薬液用タンクには、金属外装缶体の内側に、耐熱性、耐化学薬品性、純粋性等において他の合成樹脂に比べて著しく優れた特性を有するフッ素樹脂ライニング材として設けたフッ素樹脂ライニングタンクが多用されている。
【0003】
前記フッ素樹脂ライニングタンクには、筒形の胴部とその筒口を覆う蓋部とに分割された金属外装缶体に、片面にガラスクロスを溶着したライニングシート、または片面にケミカルエッチング処理したライニングシートを接着剤を介して貼り付け、胴部と蓋部をフランジを介してボルトで固定するA型タイプ(缶体分割型、ライニングシート接着型)と、回転成形等で予め筒袋状に成形したフッ素樹脂ライニング材を、その外側から前記分割金属外装缶体で覆い、前記ライニング材と金属外装缶体とは接着せず、分割された胴部と蓋部との連結部を溶接固定で一体化するB型タイプ(缶体一体型、ライニングシート非接着型)がある。
【0004】
【発明が解決しようとする課題】
前記A型タイプのフッ素樹脂ライニングタンクでは、胴部と蓋部にそれぞれ設けられたフランジを介してボルトで固定されるが、フランジ部のコストが非常に高く、外装缶体のコストアップとなるばかりでなく、ライニングシートを金属外装缶体(胴部および蓋部)の内側に貼り付ける接着作業に手間がかかり、これもコストアップとなってしまう。
また、接着剤で貼り付けたライニングシート同士の継ぎ目部分を溶接で一体化する必要があるが、溶接箇所は母材であるライニングシート部分に比べて機械的強度に劣る。
【0005】
したがって、何らかの原因でライニングシートに大きな応力がかかった場合、溶接箇所に亀裂やピンホールが発生してしまうおそれがある。また溶接工程で溶接部分に異物等が混入することもあり、この異物によって亀裂やピンホールが発生したり、フッ素樹脂特有の純粋性を低下させる原因となるおそれがある。
【0006】
一方、前記B型タイプのフッ素樹脂ライニングタンクにあっては、胴部と蓋部に分割された金属外装缶体で筒袋状のライニング材の周囲を覆い、分割された胴部と蓋部の連結部分を溶接固定で一体化する。
したがって上記B型タイプは、A型タイプにおけるフランジ部を必要とせず、かつライニングシート材の接着およびライニングシート同士の溶接も省けるので、コストを削減できる。
しかし、ライニング材の外側で分割された胴部と蓋部の連結部分を溶接する場合、その熱でライニングシート材が破損・溶融するおそれがある。
【0007】
そこで上記B型タイプの問題点を解消するものとして、図4に示す構造のフッ素樹脂ライニングタンクが提案されている。
図4において、1は筒袋状に成形されたフッ素樹脂ライニング材、2はライニング材を覆う金属外装缶体を形成している筒形の胴部、2aは筒形胴部の下側筒口を延長してなる筒形脚部、2bは筒形脚部2a内に嵌挿可能とした同心状の帽状蓋部であり、前記筒形脚部2a内に帽状蓋部2bを嵌挿したあと、両者の下端部全周を溶接固定して一体化する。2cはその溶接部である。
【0008】
上記構造によれば、缶体の胴部と蓋部を連結する溶接部がライニングシートから離れているので、ライニング材が溶接熱で破損・溶融するおそれはない。
しかし、上記構造では金属外装缶体の構成材料が増え、加工手数がかかるので、それがコストアップの原因となる。
【0009】
また、ある容量以上で、ある圧力以上で使用するタンク(圧力容器)構造は、厚生労働省労働局の労働安全衛生法によって定められており、ライニングタンクの外装缶も例外ではない。フッ素樹脂ライニングタンクは、薬液をタンクに貯めて窒素加圧により外部に排出する方法で使用されることが多く、ほとんどが労働安全衛生法の第2種圧力容器に該当する。この第2種圧力容器とは、タンク容量40L以上、使用圧力0.2MPa以上のタンクが該当し、規格に定められた構造で製作し特定機関の検査に合格しなくてはならない。
【0010】
前述した従来のB型タイプのタンクの構造では、外装缶体の胴部と蓋部の溶接部分が、図4のような場所にあり、タンク内部に圧力がかかった場合に、この部分に圧力が集中しやすく変形しやすい。したがって耐圧構造としては不十分である。またこの構造は、規格に定められた構造ではないため、第2種圧力容器となる場合は、従来のA型タイプのライニングタンクで対応している。
【0011】
本発明は、前述した事情に鑑みてなされたもので、製造が簡易で、コストのかからないフッ素樹脂ライニングタンクを提供することを目的とする。
【0012】
【課題を解決するための手段】
本発明は、所要の形状に成形されたフッ素樹脂ライニング材を、分割された金属外装缶体で覆って構成するフッ素樹脂ライニングタンクであって、金属外装缶体の分割部分同士を溶接する箇所と前記ライニング材との間に断熱材が設けられており、前記断熱材はポリテトラフルオロエチレンのシートおよびポリイミドのシートの積層体からなり、前記積層体のポリテトラフルオロエチレンのシート側を前記金属外装缶体側に配置することを要旨としている。
【0013】
【発明の実施の形態】
本発明の好ましい実施の形態としては、図1〜図3に示すように、予め筒袋状に成形されたフッ素樹脂ライニング材Aを金属外装缶体Bで覆って構成するフッ素樹脂ライニングタンクにおいて、前記金属外装缶体Bは筒形の胴部b1とその両筒口をそれぞれ塞ぐ椀形の蓋部b2,b3とに分割された缶体を用い、上側の蓋部b2は予め胴部b1に突き合わせて溶接固定しておき、下側の蓋部b3は胴部b1に嵌め合わせ自在とし、蓋部b3を嵌め合わせる前に前記筒袋状のライニング材を胴部b1内に挿入配置すると共に、胴部b1と蓋部b3との嵌め合わせによる連結部分とライニング材Aとの間に断熱材Cを配設した状態で前記連結部分を溶接し、この溶接により胴部b1に蓋部b3を一体化する。b4は溶接部である。
【0014】
前記ライニング材Aは、PFA、PTFE等のフッ素樹脂の使用が好ましく、回転成形法、ブロー成形法、アイソスタティック成形法等の一体成形方法により、筒袋状とすることができる。
【0015】
前記ライニング材と分割缶体の連結部分との間に配設される断熱材Cは、分割缶体同士を溶接固定する際に、その溶接熱を吸収または断熱することにより、ライニング材が破損しないようにするためのものであり、融点200℃以上の有機材料または無機材料が使用される。
【0016】
融点200℃以上の有機材料としては、PTFE、PFA等のフッ素樹脂、ポリイミド樹脂、ポリエーテルエーテルケトン(PEEK)、ポリフェニレンスルフィド(PPS)、ポリエーテルイミド(PEI)等のエンジニアプラスチック類が使用できるが、耐熱性、難燃性、高融点であり、なおかつ融点以上でもゲル化して形状を保ちやすいPTFEが望ましい。さらに、上記に挙げたシートを適宜重ね合わせてもよく、そのなかでポリイミド樹脂とPTFEを重ね合わせたライニング材は、フッ素樹脂からなるライニング材と断熱材PTFEとを融着させないようにするため特に好ましい。
【0017】
一方、無機材料としてはガラス繊維、ロックウールや石綿等が使用できるが、取り扱いの面からガラス繊維マットまたはこれをクロス状にしたものが特に好ましい。
また、断熱材の厚さとしては、材料の種類によって異なるが、溶接の際の熱量を吸収したり断熱したりする厚さが必要である。例えば、断熱材としてフッ素樹脂(PTFE)を使用した場合には0.3mm以上の厚さがあることが望ましい。
【0018】
なお、図1において、Dはタンクを支持する金属支脚であり、この支脚は金属外装缶体B内にライニング材Aを入れる前に胴部b1に予め溶接固定されたものである。
【0019】
本発明のフッ素樹脂ライニングタンクの構成によれば、ライニング材と分割された金属外装缶体の連結部との間に断熱材が介在されているため、溶接箇所をライニングタンクの製造場所で行える利便性があり、かつ金属外装缶体の構成部品数を減らすことができると共に手間も削減でき、製造コストの大幅な低減化が図れる。
【0020】
【実施例】
図1〜図3に示すフッ素樹脂ライニングタンクにおいて、ライニング材Aとして、PFAを回転成形法により、厚さ約2mmの筒袋状に成形したものを用い、このライニング材Aを覆う金属外装缶体Bには、厚さ4.0mmの金属板(SUS304)で成形した胴部b1、上側の蓋部b2、下側の蓋部b3を用い、上側の蓋部b2は胴部b1に予め突き合わせ溶接固定で一体化しておき、その中に前記筒袋状のライニング材Aを挿入配置すると共に、蓋部b3が胴部b1に嵌め合わされる連結部分とライニング材の間に、厚さ0.5mmのPTFEと厚さ0.125mmのポリイミドをポリイミド系粘着テープで一体にしてなる帯状の断熱材CをPTFEが金属管体側に向くようにして接着固定しておき、次いで蓋部b3の胴部b1への嵌め合わせによる連結部分を溶接し、この溶接により蓋部b3を胴部b1に固定してライニングタンクを構成した。
【0021】
上記胴部b1と蓋部b3との連結部分を溶接するとき、連結部分とライニング材Aとの間には断熱材Cが設けられているため、溶接を行っても断熱材が熱を吸収し、かつ断熱することにより、ライニング材の温度上昇を抑え、ライニング材の破損防止に効果のあることが認められた。
また、断熱材Cのライニング材側がポリイミド層とされている場合、溶接時にライニング材と断熱材のPTFEが融着するのを防止できることが認められた。
【0022】
【発明の効果】
以上詳述したように、本発明によれば、製造が簡易で、コストのかからないフッ素樹脂ライニングタンクが得られる。
【図面の簡単な説明】
【図1】本発明の一実施例を示すフッ素樹脂ライニングタンクの正面図である。
【図2】分割された胴部と下側蓋部とを溶接で連結する部分の拡大断面図である。
【図3】前記溶接連結部分の概略構成図である。
【図4】従来のフッ素樹脂ライニングタンクの断面図である。
【符号の説明】
1 筒袋状に成形したライニング材
2 金属外装缶体
2a 筒形胴部の延長脚部
2b 帽状蓋部
2c 溶接部
A 筒袋状に成形したライニング材
B 金属外装缶体
b1 筒形の胴部
b2 上側の蓋部
b3 下側の蓋部
b4 溶接部
C 断熱材
D 金属支脚[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an improvement of a fluororesin lining tank suitable for use in a tank for storing a chemical solution or the like.
[0002]
[Prior art]
Conventionally, chemical tanks that handle corrosive liquids such as various chemicals and solvents are markedly superior to other synthetic resins in terms of heat resistance, chemical resistance, purity, etc. A fluororesin lining tank provided as a fluororesin lining material having the above has been widely used.
[0003]
In the fluororesin lining tank, a lining sheet in which a glass cloth is welded on one side to a metal outer can body divided into a cylindrical body and a lid that covers the cylinder mouth, or a lining sheet that is chemically etched on one side A-type type (can body split type, lining sheet adhesive type) in which the body portion and the lid portion are fixed with bolts via a flange, and molded in a cylindrical bag shape in advance by rotational molding or the like Cover the fluororesin lining material from the outside with the divided metal outer can body, and the lining material and the metal outer can body will not be bonded, and the connecting part of the divided body part and lid part is integrated by welding fixing There are B type types (can body integrated type, lining sheet non-adhesive type).
[0004]
[Problems to be solved by the invention]
In the A-type fluororesin lining tank, it is fixed with bolts through flanges provided on the body and the lid, respectively, but the cost of the flange is very high, which only increases the cost of the outer can body. In addition, it takes time and effort to bond the lining sheet to the inside of the metal outer can body (body portion and lid portion), which also increases the cost.
Moreover, although it is necessary to integrate the joint part of the lining sheets pasted with the adhesive by welding, the welded part is inferior in mechanical strength as compared with the lining sheet part which is the base material.
[0005]
Therefore, when a large stress is applied to the lining sheet for some reason, there is a possibility that a crack or a pinhole may occur at the welded portion. In addition, foreign matter or the like may be mixed in the welded part in the welding process, and this foreign matter may cause cracks or pinholes, or may cause a decrease in the purity unique to the fluororesin.
[0006]
On the other hand, in the B-type fluororesin lining tank, the outer periphery of the cylindrical bag-shaped lining material is covered with a metal outer can divided into a body portion and a lid portion, and the divided body portion and lid portion are separated. The connecting part is integrated by welding.
Therefore, the B-type does not require the flange portion in the A-type, and can eliminate the bonding of the lining sheet material and the welding of the lining sheets, thereby reducing the cost.
However, when welding the connecting portion of the body portion and the lid portion divided on the outside of the lining material, the lining sheet material may be damaged or melted by the heat.
[0007]
Accordingly, a fluororesin lining tank having a structure shown in FIG. 4 has been proposed as a solution to the problem of the B type.
In FIG. 4, 1 is a fluororesin lining material formed into a cylindrical bag shape, 2 is a cylindrical body forming a metal outer can covering the lining material, and 2a is a lower cylinder opening of the cylindrical body. The extended
[0008]
According to the above structure, since the welded portion connecting the body portion and the lid portion of the can body is separated from the lining sheet, there is no possibility that the lining material is damaged or melted by welding heat.
However, in the structure described above, the constituent material of the metal outer can body increases, which increases the number of processing steps, which increases the cost.
[0009]
In addition, the tank (pressure vessel) structure used at a certain capacity and above a certain pressure is stipulated by the Labor Safety and Health Law of the Labor Bureau of the Ministry of Health, Labor and Welfare, and the outer can of the lining tank is no exception. Fluoropolymer lining tanks are often used in such a way that chemicals are stored in the tank and discharged to the outside by nitrogen pressurization, and most of them correspond to Type 2 pressure vessels of the Industrial Safety and Health Act. This type 2 pressure vessel corresponds to a tank having a tank capacity of 40 L or more and a working pressure of 0.2 MPa or more, and must be manufactured in a structure defined in the standard and pass the inspection of a specific engine.
[0010]
In the structure of the conventional B type tank described above, the welded portion between the body and the lid of the outer can body is located as shown in FIG. 4, and when pressure is applied to the inside of the tank, the pressure is applied to this portion. Is easy to concentrate and deform easily. Therefore, it is insufficient as a withstand voltage structure. In addition, since this structure is not a structure defined in the standard, a conventional A-type lining tank is used when it is a second type pressure vessel.
[0011]
The present invention has been made in view of the above-described circumstances, and an object thereof is to provide a fluororesin lining tank that is easy to manufacture and inexpensive.
[0012]
[Means for Solving the Problems]
The present invention is a fluororesin lining tank configured by covering a fluororesin lining material molded into a required shape with a segmented metal exterior can body, where the segmented portions of the metal exterior can body are welded to each other; A heat insulating material is provided between the lining material and the heat insulating material is a laminate of a polytetrafluoroethylene sheet and a polyimide sheet, and the polytetrafluoroethylene sheet side of the laminate is the metal exterior. that it places the can body side is a gist.
[0013]
DETAILED DESCRIPTION OF THE INVENTION
As a preferred embodiment of the present invention, as shown in FIG. 1 to FIG. 3, in a fluororesin lining tank configured by covering a fluororesin lining material A previously formed in a cylindrical bag shape with a metal outer can body B, The metal outer can body B uses a can body that is divided into a cylindrical body b 1 and bowl-shaped lids b 2 and b 3 that respectively close both the mouths of the cylinder, and the upper lid b 2 is previously a body. part b 1 to butt leave welded, lid b 3 of the lower and freely fitted to the trunk portion b 1, barrel b the tubular bag-like lining material before fitting the lid b 3 In addition to being inserted into 1 , the connecting portion is welded in a state where a heat insulating material C is disposed between the connecting portion by fitting the body portion b 1 and the lid portion b 3 and the lining material A. Thus, the lid b 3 is integrated with the body b 1 . b 4 is a weld.
[0014]
The lining material A is preferably a fluororesin such as PFA or PTFE, and can be formed into a cylindrical bag shape by an integral molding method such as a rotational molding method, a blow molding method, or an isostatic molding method.
[0015]
The heat insulating material C arranged between the lining material and the connecting portion of the divided can bodies absorbs or insulates the welding heat when the divided can bodies are welded to each other so that the lining material is not damaged. Therefore, an organic material or an inorganic material having a melting point of 200 ° C. or higher is used.
[0016]
As the organic material having a melting point of 200 ° C. or higher, engineering plastics such as fluororesins such as PTFE and PFA, polyimide resins, polyether ether ketone (PEEK), polyphenylene sulfide (PPS), and polyetherimide (PEI) can be used. PTFE is desirable because it is heat resistant, flame retardant, and has a high melting point. Further, the above-mentioned sheets may be appropriately overlapped. Among them, the lining material in which the polyimide resin and PTFE are overlapped particularly in order not to fuse the lining material made of fluororesin and the heat insulating material PTFE. preferable.
[0017]
On the other hand, glass fibers, rock wool, asbestos, and the like can be used as the inorganic material, but a glass fiber mat or a cloth-like one is particularly preferable in terms of handling.
Moreover, as thickness of a heat insulating material, although it changes with kinds of material, the thickness which absorbs the heat | fever amount in the case of welding or insulates is required. For example, when fluororesin (PTFE) is used as the heat insulating material, it is desirable that the thickness be 0.3 mm or more.
[0018]
In FIG. 1, D is a metal support that supports the tank, and this support is welded and fixed to the body b 1 in advance before the lining material A is put into the metal outer can body B.
[0019]
According to the configuration of the fluororesin lining tank of the present invention, since the heat insulating material is interposed between the lining material and the connecting portion of the divided metal outer can body, it is convenient to perform welding at the lining tank manufacturing site. In addition, the number of components of the metal outer can body can be reduced and labor can be reduced, and the manufacturing cost can be greatly reduced.
[0020]
【Example】
In the fluororesin lining tank shown in FIGS. 1 to 3, a metal outer can body covering the lining material A is used as the lining material A by using a PFA molded in a cylindrical bag shape by a rotational molding method. B uses a barrel b 1 , an upper lid b 2 , and a lower lid b 3 formed of a metal plate (SUS304) having a thickness of 4.0 mm, and the upper lid b 2 is a barrel b. 1 is previously integrated by butt welding and fixing, and the cylindrical bag-shaped lining material A is inserted and disposed therein, and the lid portion b 3 is fitted between the body portion b 1 and the connecting portion between the lining material and the lining material. Then, a strip-shaped heat insulating material C made by integrating PTFE with a thickness of 0.5 mm and polyimide with a thickness of 0.125 mm with a polyimide-based adhesive tape is bonded and fixed so that the PTFE faces the metal tube side, and then the lid trunk portion b 1 of part b 3 Welding the connecting portion due to alignment fit, to constitute a lining tank by fixing the lid portion b 3 to the trunk portion b 1 by welding.
[0021]
When the connecting part between the body part b 1 and the lid part b 3 is welded, since the heat insulating material C is provided between the connecting part and the lining material A, the heat insulating material heats even when welding is performed. By absorbing and insulating, it was confirmed that the temperature rise of the lining material was suppressed and the lining material was prevented from being damaged.
Moreover, when the lining material side of the heat insulating material C was made into the polyimide layer, it was recognized that it can prevent that the lining material and PTFE of a heat insulating material melt | fuse at the time of welding.
[0022]
【The invention's effect】
As described above in detail, according to the present invention, it is possible to obtain a fluororesin lining tank that is simple to manufacture and inexpensive.
[Brief description of the drawings]
FIG. 1 is a front view of a fluororesin lining tank showing an embodiment of the present invention.
FIG. 2 is an enlarged cross-sectional view of a portion where a divided body portion and a lower lid portion are connected by welding.
FIG. 3 is a schematic configuration diagram of the weld connection portion.
FIG. 4 is a cross-sectional view of a conventional fluororesin lining tank.
[Explanation of symbols]
1 cylinder bag-like molded into the lining material 2 metal outer can
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001368803A JP3983044B2 (en) | 2001-12-03 | 2001-12-03 | Fluorine resin lining tank |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001368803A JP3983044B2 (en) | 2001-12-03 | 2001-12-03 | Fluorine resin lining tank |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2003170994A JP2003170994A (en) | 2003-06-17 |
JP3983044B2 true JP3983044B2 (en) | 2007-09-26 |
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JP6375688B2 (en) | 2013-05-20 | 2018-08-22 | セントラル硝子株式会社 | Pumping container, storage method using the pumping container, and liquid transfer method using the pumping container |
KR101962759B1 (en) * | 2017-09-20 | 2019-03-27 | 세미플론 주식회사 | A chemical tank provided with a reinforcing support for reinforcing the lining weak portion of the inner wall of the fluororesin lining tank |
JP7173061B2 (en) * | 2020-01-20 | 2022-11-16 | トヨタ自動車株式会社 | High-pressure tank manufacturing method |
CN116329841B (en) * | 2023-04-12 | 2024-05-10 | 山东辉腾防腐设备有限公司 | Welding device for processing steel lining tetrafluoro storage tank |
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