JP3978677B2 - Water sterilizer - Google Patents

Water sterilizer Download PDF

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JP3978677B2
JP3978677B2 JP2003287516A JP2003287516A JP3978677B2 JP 3978677 B2 JP3978677 B2 JP 3978677B2 JP 2003287516 A JP2003287516 A JP 2003287516A JP 2003287516 A JP2003287516 A JP 2003287516A JP 3978677 B2 JP3978677 B2 JP 3978677B2
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water
silver
electrode
copper
bacteria
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JP2005052770A (en
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拓也 古橋
敦史 枝吉
洋司 藤田
昌彦 高木
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Mitsubishi Electric Corp
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Description

この発明は水中の細菌、カビ、藻類の増殖を抑制する水の殺菌装置に関するものである。   The present invention relates to a water sterilizer that suppresses the growth of bacteria, molds and algae in water.

従来の水の殺菌装置は、金属イオン発生装置の電極が銀電極と銅電極とであり、銀電極と銅電極とのいずれかが陽極、いずれかが陰極となるように切り換え自在として成る(例えば、特許文献1参照)。   The conventional water sterilizer is configured such that the electrodes of the metal ion generator are a silver electrode and a copper electrode, and one of the silver electrode and the copper electrode is an anode and the other is a cathode (for example, switchable) , See Patent Document 1).

特開平4−90886号公報(第1−3頁、第1図)JP-A-4-90886 (page 1-3, Fig. 1)

従来の水の殺菌装置では、銅電極と銀電極には同電圧が印加されるため、銀電極の方が先に寿命になるという問題点があった。   In the conventional water sterilizer, since the same voltage is applied to the copper electrode and the silver electrode, there is a problem that the silver electrode has a lifetime first.

この発明は、上述のような課題を解決するためになられたもので、銅電極と銀電極の寿命を延長でき、殺菌、殺カビ、殺藻の各効果を有する水の殺菌装置を得るものである。   The present invention has been made to solve the above-described problems, and can provide a water sterilizer that can extend the life of copper and silver electrodes and has sterilizing, fungicidal, and algicidal effects. It is.

この発明にかかる水の殺菌装置においては、排水ポンプで汲み上げる水槽に設置され、一対の電極に電圧を印加することにより水中に金属イオンを徐放し、水中の細菌、カビ、藻類の増殖を抑制する水の殺菌装置において、前記一対の電極の陽極側には殺菌効果または殺カビ効果または殺藻効果を有する銀と銅の合金で構成された金属電極、この金属電極と直列接続される可変抵抗体を備え、前記金属電極で前記排水ポンプの吸水口を構成し、水中の細菌数やカビ数、藻類の数を検出し、この検出結果に基づき前記可変抵抗体の抵抗値を変えるものである。 In the water sterilization apparatus according to the present invention, it is installed in a water tank pumped up by a drain pump, and by applying a voltage to a pair of electrodes, metal ions are gradually released into the water, thereby suppressing the growth of bacteria, molds and algae in the water. In the water sterilization apparatus, a metal electrode made of an alloy of silver and copper having a sterilizing effect, fungicidal effect, or algicidal effect is provided on the anode side of the pair of electrodes, and a variable resistor connected in series with the metal electrode The metal electrode constitutes the water suction port of the drainage pump, detects the number of bacteria, mold, and algae in the water, and changes the resistance value of the variable resistor based on the detection result.

この発明は、排水ポンプで汲み上げる水槽に設置され、一対の電極に電圧を印加することにより水中に金属イオンを徐放し、水中の細菌、カビ、藻類の増殖を抑制する水の殺菌装置において、前記一対の電極の陽極側には殺菌効果または殺カビ効果または殺藻効果を有する銀と銅の合金で構成された金属電極、この金属電極と直列接続される可変抵抗体を備え、前記金属電極で前記排水ポンプの吸水口を構成し、水中の細菌数やカビ数、藻類の数を検出し、この検出結果に基づき前記可変抵抗体の抵抗値を変えることにより、銅電極と銀電極の寿命を延長でき、水中の微生物の殺菌に最適な金属イオンを徐放することができ、優れた殺菌、殺カビ、殺藻効果を得ることができる。また、排水ポンプ付近の水を殺菌、殺カビ、殺藻することができ、排水ポンプの詰まりを防止することができる。
The present invention is a water sterilizer that is installed in a water tank that is pumped up by a drainage pump, gradually releases metal ions into water by applying a voltage to a pair of electrodes, and suppresses the growth of bacteria, fungi, and algae in the water. On the anode side of the pair of electrodes, a metal electrode composed of an alloy of silver and copper having a bactericidal effect, fungicidal effect or algicidal effect, a variable resistor connected in series with the metal electrode, Configure the water suction port of the drainage pump, detect the number of bacteria, mold, and algae in the water, and change the resistance value of the variable resistor based on this detection result, the life of the copper electrode and silver electrode The metal ions that are optimal for sterilization of microorganisms in water can be released slowly, and excellent sterilization, fungicidal and algicidal effects can be obtained. Moreover, the water near the drainage pump can be sterilized, mold-killed, and algae killed, and the drainage pump can be prevented from being clogged.

実施の形態1.
図1はこの発明の実施の形態1を示す水の殺菌装置の模式図、図2はこの水の殺菌装置の設置模式図、図3はこの水の殺菌装置の銀濃度と菌数との関係を示す図である。
図において、銅電極1と銀電極2は水槽6に入っている水7に接触するように設置され、対向電極4との間に直流電圧を供給する電源5を接続し、設置される。銀電極2と電源5の間には抵抗体3が接続される。電源5による印加電圧は5〜25Vの直流電圧である。抵抗体3は印加電圧1Vに対し、抵抗体3が0.99V、銀電極2が0.01Vとなるように抵抗値を設定する。銅電極1と抵抗体3を介した銀電極2に直流電圧が印加されると、水7中に銅電極1からは銅イオン、銀電極2からは銀イオンが徐放される。
Embodiment 1 FIG.
FIG. 1 is a schematic diagram of a water sterilizer showing Embodiment 1 of the present invention, FIG. 2 is a schematic diagram of the installation of this water sterilizer, and FIG. 3 is a relationship between the silver concentration and the number of bacteria in this water sterilizer. FIG.
In the figure, a copper electrode 1 and a silver electrode 2 are installed so as to be in contact with water 7 contained in a water tank 6, and are installed by connecting a power source 5 for supplying a DC voltage between the counter electrode 4. A resistor 3 is connected between the silver electrode 2 and the power source 5. The voltage applied by the power source 5 is a DC voltage of 5 to 25V. The resistance value of the resistor 3 is set so that the resistor 3 is 0.99 V and the silver electrode 2 is 0.01 V with respect to the applied voltage of 1 V. When a DC voltage is applied to the silver electrode 2 via the copper electrode 1 and the resistor 3, copper ions from the copper electrode 1 and silver ions from the silver electrode 2 are gradually released into the water 7.

ここで、一般的に銅イオンには殺カビ効果、殺藻効果があり、銀イオンには殺菌効果がある。殺菌効果、殺カビ効果、殺藻効果は徐放される銅イオン濃度、銀イオン濃度に影響するため、効果が得られる濃度のイオンを徐放する必要がある。そこで、図3に示すように最小限効果が得られる濃度、すなわち3ppm以上の徐放量が得られる電圧が印加される。図3(a)は500mLの水の中に栄養分であるニュートリエントブロスを毎回10mL投入し、同時に細菌を1.0E+07cfu/mLの濃度で毎回10mL投入したときの銀濃度の違いによる菌数の変化を示すものであり、3ppm以上で効果があることがわかる。図3(b)は500mLの水の中に栄養分であるニュートリエントブロスを10mL投入し、同時に細菌を1.0E+07cfu/mLの濃度で10mL投入したときの銀濃度の違いによる菌数の経時変化を示すものであり、銀濃度1ppm、2ppmでは菌の増殖があるが、3ppmでは増殖がないことがわかる。   Here, copper ions generally have fungicidal and algicidal effects, and silver ions have a bactericidal effect. Since the bactericidal effect, fungicidal effect, and algicidal effect affect the copper ion concentration and silver ion concentration that are gradually released, it is necessary to release ions at a concentration that provides the effect. Therefore, as shown in FIG. 3, a voltage at which a minimum effect is obtained, that is, a sustained release amount of 3 ppm or more is applied. Fig. 3 (a) shows the number of bacteria due to the difference in silver concentration when 10 mL of nutrient broth, which is a nutrient, is added to 500 mL of water each time, and at the same time, 10 mL of bacteria is added at a concentration of 1.0E + 07 cfu / mL each time. It shows a change, and it can be seen that it is effective at 3 ppm or more. Fig. 3 (b) shows the change in the number of bacteria over time due to the difference in silver concentration when 10 mL of nutrient broth, which is a nutrient, is added to 500 mL of water, and at the same time, 10 mL of bacteria are added at a concentration of 1.0E + 07 cfu / mL. It can be seen that bacteria grow at silver concentrations of 1 ppm and 2 ppm, but no growth at 3 ppm.

ところで、銀電極と銅電極に同電圧を印加した場合には、銅イオンより銀イオンの方が溶出しやすいため、銀イオン濃度は高くなるが、銅イオン濃度は高くすることが困難であった。また、銀電極の方が先に溶出してしまい寿命が短くなってしまう。例えば、従来は、殺藻効果、殺カビ効果を出すために数十ppmの銅イオンを徐放する電圧を銅電極に印加すると、銀電極からは約120ppmの銀イオンが徐放されていた。そのため、過度に銀イオンが徐放され銀電極の寿命が短くなっていた。   By the way, when the same voltage is applied to the silver electrode and the copper electrode, since the silver ions are more easily eluted than the copper ions, the silver ion concentration is high, but it is difficult to increase the copper ion concentration. . In addition, the silver electrode elutes first and the life is shortened. For example, conventionally, when a voltage that gradually releases several tens of ppm of copper ions is applied to a copper electrode in order to exert an algicidal effect and a fungicidal effect, about 120 ppm of silver ions are gradually released from the silver electrode. Therefore, silver ions were excessively released, and the life of the silver electrode was shortened.

そこで、本実施形態1では、上述の問題点を解決するために、銀電極2と電源5の間に抵抗体3を接続し、印加電圧1Vに対し、抵抗体3が0.99V、銀電極2が0.01Vとなるように抵抗値を設定したため、銀イオン濃度と銅イオン濃度を最適な濃度にコントロールすることが可能である。   Therefore, in the first embodiment, in order to solve the above-described problems, the resistor 3 is connected between the silver electrode 2 and the power source 5, and the resistor 3 is 0.99 V with respect to the applied voltage 1 V, and the silver electrode Since the resistance value is set so that 2 becomes 0.01 V, the silver ion concentration and the copper ion concentration can be controlled to optimum concentrations.

以上のように、上記構成を有する水の殺菌装置では、銀電極2と電源5の間に抵抗体3を接続したため、銀イオン濃度と銅イオン濃度を最適な濃度にコントロールすることが可能であり、銀イオンによる殺菌、銅イオンによる殺カビ、殺藻効果を最も良く発揮できる。また、過度に銀イオンを溶出することがないため、銀電極と銅電極の寿命を長くすることが可能である。   As described above, since the resistor 3 is connected between the silver electrode 2 and the power source 5 in the water sterilization apparatus having the above-described configuration, the silver ion concentration and the copper ion concentration can be controlled to optimum concentrations. , Sterilization by silver ions, fungicidal effect by copper ions, and algaecidal effect can be best demonstrated. Moreover, since silver ions are not eluted excessively, it is possible to extend the lifetime of the silver electrode and the copper electrode.

実施の形態2.
図4はこの発明の実施の形態2を示す水の殺菌装置の模式図である。銅電極1と銀電極2は水槽6に入っている水7に接触するように設置され、対向電極4との間に直流電圧を供給する電源5を接続し、設置される。銀電極2と電源5の間には抵抗体3が接続される。電源5による印加電圧は5〜25Vの直流電圧である。8は、水中の例えばカビ、藻類、菌類等の微生物を検出する微生物検出手段であり、微生物検出手段8で検出した出力に基づき抵抗体3の抵抗値を変化させる。
Embodiment 2. FIG.
FIG. 4 is a schematic view of a water sterilizer showing Embodiment 2 of the present invention. The copper electrode 1 and the silver electrode 2 are installed so as to be in contact with the water 7 contained in the water tank 6, and are installed by connecting a power source 5 for supplying a DC voltage between the counter electrode 4. A resistor 3 is connected between the silver electrode 2 and the power source 5. The voltage applied by the power source 5 is a DC voltage of 5 to 25V. Reference numeral 8 denotes a microorganism detecting means for detecting microorganisms such as mold, algae, and fungi in water, and changes the resistance value of the resistor 3 based on the output detected by the microorganism detecting means 8.

次に動作について説明する。
微生物検出手段8でにより、水槽6に入る水7に含まれる微生物の状況(数、濃度)を検出し、抵抗体3に信号を出力する。抵抗体3は微生物検出手段8からの信号の値により抵抗値を可変し、徐放される銀濃度を制御する。ここで、菌数を検知し、その菌数に応じ抵抗値を可変する場合は、下記の式により銀濃度を制御する。
(抵抗値により変化する変数)×微生物検出結果(菌数)×電圧印加時間(定数)/水量(定数)=銀濃度
Next, the operation will be described.
The state (number and concentration) of microorganisms contained in the water 7 entering the water tank 6 is detected by the microorganism detection means 8, and a signal is output to the resistor 3. The resistor 3 varies the resistance value according to the value of the signal from the microorganism detecting means 8 and controls the silver concentration that is gradually released. Here, when the number of bacteria is detected and the resistance value is varied according to the number of bacteria, the silver concentration is controlled by the following equation.
(Variable that varies depending on resistance value) x microorganism detection result (number of bacteria) x voltage application time (constant) / water volume (constant) = silver concentration

以上のように、上記構成を有する水の殺菌装置では、微生物の状況を微生物検出手段8で検出し、抵抗体3は微生物検出手段8の出力により抵抗値を可変し、徐放される銀濃度を制御することができるため、水中の微生物の殺菌に最適な銀イオンを徐放することができる。   As described above, in the water sterilization apparatus having the above-described configuration, the state of microorganisms is detected by the microorganism detecting means 8, and the resistance value of the resistor 3 is varied according to the output of the microorganism detecting means 8, and the silver concentration is gradually released. Therefore, it is possible to control release of silver ions optimal for sterilization of microorganisms in water.

実施の形態3.
図5はこの発明の実施の形態3を示す水の殺菌装置の模式図である。銅電極1、銀電極2を排水ポンプ9の吸水口10の一部分に設置した。この場合、対向電極3は、水槽6の底面に沿って配置される。排水ポンプ9は水槽6の水7を吸い上げる働きをする。このとき、水7中に微生物が多量に繁殖しているとゲル化した微生物が排水ポンプ9の吸水口10に詰まる恐れがある。そこで、排水ポンプ9の吸水口10付近に水7中の微生物の繁殖を抑制する殺菌、殺カビ、殺藻装置を設置することにより、排水ポンプ9の詰まりを防止することができる。
Embodiment 3 FIG.
FIG. 5 is a schematic view of a water sterilizer showing Embodiment 3 of the present invention. The copper electrode 1 and the silver electrode 2 were installed in a part of the water inlet 10 of the drain pump 9. In this case, the counter electrode 3 is disposed along the bottom surface of the water tank 6. The drainage pump 9 works to suck up the water 7 in the water tank 6. At this time, if a large amount of microorganisms are propagated in the water 7, the gelled microorganisms may be clogged in the water suction port 10 of the drainage pump 9. Therefore, the clogging of the drainage pump 9 can be prevented by installing a sterilizing, fungicidal and algicidal device that suppresses the propagation of microorganisms in the water 7 near the water inlet 10 of the drainage pump 9.

ここでは、排水ポンプ9の吸水口10の一部分に銅電極1、銀電極2を設置したことにより、排水ポンプ9付近の水7を殺菌、殺カビ、殺藻することができ、排水ポンプ9の詰まりを防止することができる。具体的には、吸水口10を銀と銅の合金、または銀のみ、または銅のみで構成され、水中の金属イオン濃度が常に3ppm以上となるように銅電極1または銀電極2への印加電圧を制御する。   Here, by installing the copper electrode 1 and the silver electrode 2 in a part of the water inlet 10 of the drain pump 9, the water 7 near the drain pump 9 can be sterilized, mold-killed, and algae killed. Clogging can be prevented. Specifically, the water inlet 10 is made of an alloy of silver and copper, or only silver, or only copper, and the voltage applied to the copper electrode 1 or the silver electrode 2 so that the metal ion concentration in water is always 3 ppm or more. To control.

以上のように、上記構成を有する水の殺菌装置では、排水ポンプ9の吸水口10の一部分に銅電極1、銀電極2を設置したことにより、排水ポンプ9付近の水7を殺菌、殺カビ、殺藻することができ、排水ポンプ9の詰まりを防止することができる。   As described above, in the water sterilization apparatus having the above-described configuration, the copper electrode 1 and the silver electrode 2 are installed in a part of the water inlet 10 of the drain pump 9, thereby sterilizing and killing the water 7 near the drain pump 9. The algae can be killed, and the drainage pump 9 can be prevented from clogging.

この発明の実施の形態1を示す水の殺菌装置の模式図である。It is a schematic diagram of the water sterilizer which shows Embodiment 1 of this invention. この発明の実施の形態1を示す水の殺菌装置の設置模式図である。It is an installation schematic diagram of the water sterilizer which shows Embodiment 1 of this invention. この発明の実施の形態1を示す水の殺菌装置の銀濃度と菌数との関係を示す図である。It is a figure which shows the relationship between the silver concentration of the water sterilizer which shows Embodiment 1 of this invention, and the number of bacteria. この発明の実施の形態2を示す水の殺菌装置の模式図である。It is a schematic diagram of the water sterilizer which shows Embodiment 2 of this invention. この発明の実施の形態3を示す水の殺菌装置の模式図である。It is a schematic diagram of the water sterilizer which shows Embodiment 3 of this invention.

符号の説明Explanation of symbols

1 銅電極、 2 銀電極、 3 抵抗体、 4 対向電極、 5 電源、 6 水槽、 7 水、 8 微生物検出手段、 9 排水ポンプ、 10 吸水口。   DESCRIPTION OF SYMBOLS 1 Copper electrode, 2 Silver electrode, 3 Resistor, 4 Counter electrode, 5 Power supply, 6 Water tank, 7 Water, 8 Microorganism detection means, 9 Drain pump, 10 Water inlet

Claims (2)

排水ポンプで汲み上げる水槽に設置され、一対の電極に電圧を印加することにより水中に金属イオンを徐放し、水中の細菌、カビ、藻類の増殖を抑制する水の殺菌装置において、前記一対の電極の陽極側には殺菌効果または殺カビ効果または殺藻効果を有する銀と銅の合金で構成された金属電極、この金属電極と直列接続される可変抵抗体を備え、前記金属電極で前記排水ポンプの吸水口を構成し、水中の細菌数やカビ数、藻類の数を検出し、この検出結果に基づき前記可変抵抗体の抵抗値を変えることを特徴とする水の殺菌装置。 In a water sterilization apparatus that is installed in a water tank pumped up by a drainage pump and releases a metal ion into water by applying a voltage to the pair of electrodes, thereby suppressing the growth of bacteria, mold, and algae in the water. On the anode side, a metal electrode composed of an alloy of silver and copper having a bactericidal effect, fungicidal effect or algicidal effect, and a variable resistor connected in series with the metal electrode, the metal electrode of the drainage pump is provided. A water sterilizer comprising a water inlet, detecting the number of bacteria, mold and algae in water, and changing the resistance value of the variable resistor based on the detection result. 排水ポンプで汲み上げる水槽に設置され、一対の電極に電圧を印加することにより水中に金属イオンを徐放し、水中の細菌、カビ、藻類の増殖を抑制する水の殺菌装置において、前記一対の電極の陽極側には殺菌効果または殺カビ効果または殺藻効果を有する銀と銅の合金で構成された金属電極を備え、前記金属電極で前記排水ポンプの吸水口を構成し、水中の金属イオン濃度が常に3ppm以上となるように前記一対の電極への印加電圧を制御することを特徴とする水の殺菌装置。 In a water sterilization apparatus that is installed in a water tank pumped up by a drainage pump and releases a metal ion into water by applying a voltage to the pair of electrodes, thereby suppressing the growth of bacteria, mold, and algae in the water. Provided on the anode side is a metal electrode made of a silver and copper alloy having a bactericidal effect, fungicidal effect or algicidal effect, and the metal electrode constitutes the water suction port of the drainage pump, and the metal ion concentration in water is A water sterilizer characterized by controlling the voltage applied to the pair of electrodes so as to be always 3 ppm or more .
JP2003287516A 2003-08-06 2003-08-06 Water sterilizer Expired - Lifetime JP3978677B2 (en)

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JP5425007B2 (en) * 2010-07-16 2014-02-26 三菱電機株式会社 Water sterilization method, water sterilizer, and air conditioner, hand dryer and humidifier using water sterilizer
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RU2482072C1 (en) * 2011-09-12 2013-05-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Орловский государственный аграрный университет" (ФГБОУ ВПО Орел ГАУ) Water ionisation apparatus
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