JP3970678B2 - Surface treatment tool - Google Patents

Surface treatment tool Download PDF

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Publication number
JP3970678B2
JP3970678B2 JP2002127813A JP2002127813A JP3970678B2 JP 3970678 B2 JP3970678 B2 JP 3970678B2 JP 2002127813 A JP2002127813 A JP 2002127813A JP 2002127813 A JP2002127813 A JP 2002127813A JP 3970678 B2 JP3970678 B2 JP 3970678B2
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Prior art keywords
carbide
hard film
surface treatment
size
steel
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JP2002127813A
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JP2003321749A (en
Inventor
敬介 清水
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Sanyo Special Steel Co Ltd
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Sanyo Special Steel Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は、冷間工具鋼を加工後、耐焼付性、耐かじり性および耐摩耗性を高めるため浸透拡散処理を施して使用する工具に関するものである。
【0002】
【従来の技術】
従来、塑性加工技術の進歩に伴い、部品のネットシェイプ化、および被加工材の高強度化により、金型に対する負荷は増大している。このような、従来SKD11では対処できないような厳しい使用環境に適用するため、型材の見直しによる改善や各種表面処理の実施による改善がなされている。例えば特開平9−316601号公報では、400℃以上の表面処理後、高温焼戻しにより63〜66HRCの高硬さが得られる表面処理に適した冷間工具鋼が提案されている。
【0003】
また、特開平9−194992号公報では、高速度工具鋼の表面改質をPVD法やCVD法によって膜の密着性を向上させる工具鋼が提案されている。また、特開2000−129398号公報では、被覆層との密着性に優れ、かつ高い高温硬度と高耐摩耗性を維持した表面に硬質の被覆層を形成した切削工具や塑性加工工具などに用いる工具鋼が提案されている。さらに、特開2000−73142号公報では、鍛造金型、フォーミングロール、転造ダイス等に用いる64HRC以上の高温焼戻硬さが得られる高硬度冷間工具鋼およびその金型並びに工具が提案されている。
【0004】
【発明が解決しようとする課題】
しかしながら、上述した特開平9−316601号公報および特開平9−194992号公報は、V,Nb添加鋼ではなく、しかも、980〜1030℃の溶融塩浴に1〜15時間浸漬して被処理材の表面に5〜15mmの炭化物層を形成する浸透拡散処理による焼入れ、焼戻しによるものでない。また、特開2000−129398号公報は、Co,Ti添加鋼であり、高コストとなる共に靱性において劣る。一方、特開2000−73142号公報は、1000℃付近での低温焼入れであるに対し、本発明は、980〜1030℃の溶融塩浴に1〜15時間浸漬して被処理材の表面に5〜15mmの炭化物層を形成する浸透拡散処理による焼入れを行うものである。
【0005】
この場合、従来鋼SKD11などの標準的な焼入温度である1030℃よりも若干低い温度での焼入条件となるため、焼戻し後、SKD11やその改良鋼では、マトリックスの硬度は56〜60HRC程度しか得られない。また、硬質膜直下は硬質炭化物層生成の際のC供給源となり脱炭され若干軟化する。そのため、表面硬質膜とマトリックスの密着性が悪く、使用中に早期剥離により型寿命に至ってしまうという問題がある。この問題を浸透拡散処理における低温焼入れのままで62〜64HRC、さらに高温焼戻しで62〜64HRCのマトリックス硬度を得るものである。
【0006】
【課題を解決するための手段】
上述したような問題を解消するために、発明者らは鋭意開発を進めた結果、浸透拡散処理における、980〜1030℃の溶融塩浴による低温焼入条件でも62〜64HRCの高いマトリックス硬度が得られるだけでなく、炭化物の制御により、表面硬質膜とマトリックスの密着性を向上させて、硬質膜の剥離を抑制し、大幅に寿命を改善した工具および金型を提供することを目的とする。その発明の要旨とするところは、
(1)質量%で、C:0.9%超〜1.1%、Si:0.1〜2.0%、Mn:0.1〜1.5%、Cr:5.0〜7.0%、MoとWの1種または2種をMo+1/2W:3.0〜4.5%、VとNbの1種または2種をV+1/2Nb:0.5〜1.0%を含み、残部がFeおよび不可避的不純物からなる冷間工具鋼を、980〜1030℃の溶融塩浴に浸漬する浸透拡散処理による焼入後、焼戻により62〜64HRCの高硬度が得られることを特徴とする表面処理工具。
【0007】
(2)前記(1)に記載の鋼に、S:0.01〜0.10%を添加し被加工性を向上させたことを特徴とする表面処理工具。
(3)前記(1)または(2)に記載の鋼中の炭化物サイズが20μm以下、かつ、炭化物凝集部のサイズが100μm以下であることを特徴とする表面処理工具である
【0008】
以下、本発明について詳細に説明する。
本発明は、上述したように金型の表面硬質膜の早期剥離原因については、次のような理由であることを解明した。
(1)硬質膜直下の粗大炭化物、炭化物凝集部を応力集中源として、硬質膜にクラックが発生する。
(2)マトリックス硬度が不十分な場合、金型に高負荷が掛かる際の塑性変形量が大きく、硬質膜が変形に追従できずクラックが発生する。
(3)マトリックス中のC量が原因でマトリックス硬度が不十分な場合、硬質膜直下に脱炭による軟化層が生成し、上記と同様の理由でクラックが発生する。
(4)金型材の仕上げ面粗さが悪い場合、高負荷を受けた際に硬質膜で局所的に応力が掛かり、クラックが発生する。
【0009】
上述のクラックの発生を防止するためには、C量を確保する必要がある。すなわち、マトリックス中のC量が低ければ、硬質膜直下で脱炭により軟化し、早期剥離に至るからである。また、硬質膜直下に炭化物やその凝集部がある際、応力集中源となり表面硬質膜にクラックを生じ早期剥離に至ることから、一次炭化物サイズと炭化物凝集部サイズを抑える必要がある。さらに、硬質炭化物を微細分散させることにより、硬質炭化物によるマトリックスの硬度を高め、これにより、硬質膜の剥離の原因である、繰返しの高負荷を受けた際のマトリックスの変形が緩和されるため、硬質膜の変形が軽減され、クラックの発生が抑制される。また、このような炭化物の制御は、仕上げ加工時の面粗さを向上させ、硬質膜の密着性を高めるものである。
【0010】
【発明の実施の形態】
次に、本発明に係る成分組成の限定理由を説明する。
C:0.9%超〜1.1%
Cは、十分な焼入焼戻し硬さを確保するための元素であり、また、浸透拡散処理により充分な厚さの硬質膜を得て、硬質膜直下での脱炭による母材の軟化を抑制するために0.9%超必要である。しかし、1.1%を超えると焼入れ時の残留オーステナイト量が増加し硬度が低下する。従って、その範囲を0.9%超〜1.1%とした。
【0011】
Si:0.1〜2.0%
Siは、製鋼での脱酸効果、焼入れ性のために添加するが、しかし、0.1%未満では脱酸効果が不十分である。また、焼戻し時に炭化物の凝集を抑え、二次硬化を促進することから、その上限を2.0%とした。
Mn:0.1〜1.5%
Mnは、焼入れ性のために添加するが、しかし、0.1%未満ではその効果が不十分であり、また、1.5%を超えると加工性を低下させることから、その範囲を0.1〜1.5%とした。
【0012】
Cr:5.0〜7.0%
Crは、焼入れ性のために添加するが、しかし、5.0%未満ではその効果が不十分であり、また、過剰に添加すると、一次炭化物の粗大化および炭化物凝集部が形成されやすくなるため表面処理の密着性を劣化させる。従って、その範囲を5.0〜7.0%とした。
MoとWの1種または2種をMo+1/2W:3.0〜4.5%
MoとWは、焼入れ性を向上させるため、また、焼戻し時に微細な析出炭化物を形成し二次硬化に寄与する。しかし、過剰に添加すると、表面処理性を劣化させることから、Mo+1/2Wを3.0〜4.5%とした。
【0013】
VとNbの1種または2種をV+1/2Nb:0.5〜1.0%
VとNbは、焼戻し時に微細、かつ硬質な析出炭化物を形成し二次硬化に寄与する。しかし、過剰に添加すると、表面処理性を劣化させることから、V+1/2Nbを0.5〜1.0%とした。
S:0.01〜0.10%
Sは、快削性を確保するために必要な元素である。しかし、0.01%未満ではその効果が得られず、また、過剰添加は熱間加工性と靱性を低下させるため、その上限を0.10%とした。
【0014】
炭化物サイズが20μm以下、かつ、炭化物凝集部のサイズが100μm以下粗大炭化物および凝集炭化物の形成を低減し、微細で硬質な析出炭化物をマトリックス中に分散させることで、高負荷環境下における応力集中や塑性変形を抑制し、金型使用時の表面硬質膜の早期剥離を避けることが出来る。しかし、炭化物サイズが20μmを超え、かつ炭化物凝集部のサイズが100μmを超える場合は、その効果がないことから、その上限を、炭化物サイズ20μm、炭化物凝集部のサイズを100μmとした。
【0015】
【実施例】
以下、本発明について実施例によって具体的に説明する。
供試材として、表1に示す化学成分組成の各鋼を100kg真空誘導溶解炉にて溶製し、鍛伸し、焼なましを行い供試材とした。その結果を表2に示す。スクラッチ試験は、試験片の表面硬質膜に圧子を押し付け、荷重を増加させながら引っ掻きを行い、硬質膜の割れが生じる臨界荷重を測定した。また、表3には、実機適用事例として、コールドピルガーマンドレル、自動車部品曲げプレスを示す。
実機テストでは、ともに金型の焼付き対策として、浸透拡散処理を実施した。浸透拡散処理はV系塩浴に浸漬して厚さ約10μmのVC硬質膜を得る表面硬質膜生成プロセスの一種である。コールドピルガーによる加工法は、母管の中にテーパーのついたマンドレルを挿入して、外側から特殊孔型をもったロールダイスで冷間圧延を行うものである。この実機テストではSUJ2を減面率75%で圧延し、マンドレル表面の硬質膜剥離による成品管内面へのキズの転写が確認された段階での圧延素管本数により型寿命を評価した。また、自動車部品曲げ型を作製し、被加工材として厚さ5mmのSPCCを1000tプレス機により曲げ加工した際の表面硬質膜剥離に至るまでのショット数で型寿命を評価した。
【0016】
【表1】

Figure 0003970678
【0017】
【表2】
Figure 0003970678
【0018】
【表3】
Figure 0003970678
【0019】
表2に示すように、No.1〜4は本発明例であり、No.5〜8は比較例である。比較例No.5およびNo.6の成分組成はC,Crが高く、かつMo+1/2Wの値が低く、また、V+1/2Nbの値はNo.5の場合は低く、No.5の場合は高い。しかもNo.5の場合は炭素物サイズおよび炭化物凝集部サイズが大きいため、いずれもスクラッチ臨界荷重が小さく、かつ実機テストでの型寿命が短い。比較例No.7の成分組成はCrが低く、かつMo+1/2Wの値が低く、しかも、V+1/2Nbの値は高いため、スクラッチ臨界荷重が小さく、かつ実機テストでの型寿命が短い。
【0020】
比較例No.8の成分組成はCrが高く、かつMo+1/2Wの値およびV+1/2Nbの値が低く、また、炭素物サイズおよび炭化物凝集部サイズが大きいため、いずれもスクラッチ臨界荷重が小さく、かつ実機テストでの型寿命が短い。また、マトリックス硬度はいずれも61HRC以下であることが判る。これに対し、本発明例No.1〜4のいずれも、マトリックス硬度は62HRC以上であり、かつスクラッチ臨界荷重や実機テストでの型寿命の長いことが判る。
【0021】
【発明の効果】
以上述べたように、本発明による浸透拡散処理による表面硬質膜の密着性を改善することで、硬質膜の早期剥離による廃却に至っていた金型の寿命を大幅に改善して、生産性向上とコスト低減に寄与すること大きく工業上極めて優れた効果を奏するものである。[0001]
BACKGROUND OF THE INVENTION
The present invention, after processing the cold work tool steel, seizure resistance, in which factory again and again relates to use is subjected to osmotic diffusion process for increasing the galling resistance and wear resistance resistance.
[0002]
[Prior art]
2. Description of the Related Art Conventionally, with the advance of plastic working technology, the load on a mold has increased due to the net shape of parts and the increased strength of workpieces. In order to apply to such a severe use environment that cannot be dealt with by the conventional SKD11, improvements are made by reviewing the mold material and various surface treatments. For example, Japanese Patent Application Laid-Open No. 9-316601 proposes cold tool steel suitable for surface treatment in which a high hardness of 63 to 66 HRC is obtained by high-temperature tempering after surface treatment at 400 ° C. or higher.
[0003]
Japanese Patent Laid-Open No. 9-194992 proposes a tool steel that improves the adhesion of the film by PVD or CVD for surface modification of high-speed tool steel. Japanese Patent Application Laid-Open No. 2000-129398 uses a cutting tool or a plastic working tool in which a hard coating layer is formed on a surface that has excellent adhesion to the coating layer and maintains high high-temperature hardness and high wear resistance. Tool steel has been proposed. Furthermore, Japanese Patent Application Laid-Open No. 2000-73142 proposes a high-hardness cold tool steel that can be used for forging dies, forming rolls, rolling dies, and the like that can obtain high-temperature tempering hardness of 64 HRC or higher, and its dies and tools. ing.
[0004]
[Problems to be solved by the invention]
However, the above-mentioned Japanese Patent Application Laid-Open Nos. 9-316601 and 9-194992 are not V and Nb-added steels, and are immersed in a molten salt bath at 980 to 1030 ° C. for 1 to 15 hours to be treated. It is not due to quenching or tempering by an osmotic diffusion treatment that forms a 5 to 15 mm carbide layer on the surface of the steel. Japanese Unexamined Patent Publication No. 2000-129398 is a Co and Ti-added steel, which is expensive and inferior in toughness. On the other hand, Japanese Patent Application Laid-Open No. 2000-73142 discloses low-temperature quenching at about 1000 ° C., whereas the present invention is immersed in a molten salt bath at 980 to 1030 ° C. for 1 to 15 hours to 5 Quenching is performed by osmotic diffusion treatment to form a carbide layer of ˜15 mm.
[0005]
In this case, since the quenching conditions are slightly lower than 1030 ° C. which is a standard quenching temperature of the conventional steel SKD11 or the like, the hardness of the matrix is about 56 to 60 HRC in the SKD11 and its improved steel after tempering. Can only be obtained. Further, the portion immediately below the hard film becomes a C supply source when the hard carbide layer is generated, and is decarburized and slightly softened. Therefore, the adhesion between the hard surface film and the matrix is poor, and there is a problem that the mold life is reached by early peeling during use. This problem is obtained by obtaining a matrix hardness of 62 to 64 HRC with low temperature quenching in the penetration diffusion treatment, and 62 to 64 HRC by high temperature tempering.
[0006]
[Means for Solving the Problems]
In order to solve the above-described problems, the inventors have made extensive developments, and as a result, a high matrix hardness of 62 to 64 HRC is obtained even under low temperature quenching conditions in a molten salt bath at 980 to 1030 ° C. in the permeation diffusion treatment. It is an object of the present invention to provide a tool and a mold that not only can be controlled but also improve the adhesion between the surface hard film and the matrix by controlling carbides, suppress the peeling of the hard film, and greatly improve the service life. The gist of the invention is that
(1) By mass%, C: more than 0.9% to 1.1%, Si: 0.1 to 2.0%, Mn: 0.1 to 1.5%, Cr: 5.0 to 7. 0%, Mo and W include 1 or 2 Mo + 1 / 2W: 3.0 to 4.5%, V and Nb include 1 or 2 V + 1 / 2Nb: 0.5 to 1.0% In addition, a cold work tool steel consisting of Fe and unavoidable impurities in the balance is quenched by osmotic diffusion treatment in which it is immersed in a molten salt bath at 980 to 1030 ° C., and then a high hardness of 62 to 64 HRC is obtained by tempering. Surface treatment tool.
[0007]
(2) A surface treatment tool characterized in that S: 0.01 to 0.10% is added to the steel according to (1) to improve workability.
(3) (1) or (2) is 20μm or less carbide size in the steel according, and a surface treatment tool size carbide aggregation portion and wherein the at 100μm or less.
[0008]
Hereinafter, the present invention will be described in detail.
As described above, the present invention has clarified that the cause of the early peeling of the hard surface film of the mold is as follows.
(1) Cracks are generated in the hard film using the coarse carbide and carbide aggregate portion directly below the hard film as a stress concentration source.
(2) When the matrix hardness is insufficient, the amount of plastic deformation when a high load is applied to the mold is large, and the hard film cannot follow the deformation and cracks occur.
(3) When the matrix hardness is insufficient due to the amount of C in the matrix, a softened layer by decarburization is generated immediately below the hard film, and cracks are generated for the same reason as described above.
(4) When the finished surface roughness of the mold material is poor, a stress is locally applied to the hard film when a high load is applied, and a crack is generated.
[0009]
In order to prevent the above-described cracks from occurring, it is necessary to secure the C amount. That is, if the amount of C in the matrix is low, it is softened by decarburization directly under the hard film, leading to early peeling. In addition, when there are carbides and their agglomerates directly under the hard film, it becomes a stress concentration source, causing cracks in the surface hard film and leading to early peeling, so it is necessary to suppress the primary carbide size and carbide agglomerate size. Furthermore, by finely dispersing the hard carbide, the hardness of the matrix due to the hard carbide is increased, thereby reducing the deformation of the matrix when subjected to repeated high loads, which is the cause of peeling of the hard film. The deformation of the hard film is reduced and the generation of cracks is suppressed. Moreover, such control of carbide improves the surface roughness at the time of finishing, and improves the adhesion of the hard film.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Next, the reasons for limiting the component composition according to the present invention will be described.
C: More than 0.9% to 1.1%
C is an element for ensuring sufficient quenching and tempering hardness, and obtains a hard film with sufficient thickness by osmotic diffusion treatment to suppress softening of the base material due to decarburization directly under the hard film. Over 0.9% is necessary to achieve this. However, if it exceeds 1.1%, the amount of retained austenite at the time of quenching increases and the hardness decreases. Therefore, the range was made over 0.9% to 1.1%.
[0011]
Si: 0.1 to 2.0%
Si is added for the deoxidation effect and hardenability in steelmaking. However, if it is less than 0.1%, the deoxidation effect is insufficient. Moreover, the upper limit was set to 2.0% because the agglomeration of carbides was suppressed during tempering and secondary curing was promoted.
Mn: 0.1 to 1.5%
Mn is added for hardenability. However, if it is less than 0.1%, its effect is insufficient, and if it exceeds 1.5%, the workability is lowered. It was 1 to 1.5%.
[0012]
Cr: 5.0-7.0%
Cr is added for hardenability, but if less than 5.0%, the effect is insufficient, and if added excessively, coarsening of primary carbides and carbide agglomerates tend to be formed. Deterioration of surface treatment adhesion. Therefore, the range was made 5.0 to 7.0%.
1 type or 2 types of Mo and W are Mo + 1 / 2W: 3.0-4.5%
Mo and W contribute to secondary hardening by forming fine precipitated carbides during tempering in order to improve hardenability. However, when excessively added, the surface treatment property deteriorates, so Mo + 1 / 2W was made 3.0 to 4.5%.
[0013]
One or two of V and Nb is V + 1 / 2Nb: 0.5 to 1.0%
V and Nb form fine and hard precipitated carbides during tempering and contribute to secondary curing. However, when excessively added, the surface treatment property is deteriorated, so V + 1 / 2Nb was set to 0.5 to 1.0%.
S: 0.01-0.10%
S is an element necessary for ensuring free machinability. However, if less than 0.01%, the effect cannot be obtained, and excessive addition reduces hot workability and toughness, so the upper limit was made 0.10%.
[0014]
The carbide size is 20 μm or less, and the size of the carbide agglomerate is 100 μm or less. By reducing the formation of coarse carbides and aggregated carbides and dispersing fine and hard precipitated carbides in the matrix, stress concentration under high load environment and Plastic deformation is suppressed, and early peeling of the hard surface film can be avoided when using a mold. However, when the carbide size exceeds 20 μm and the size of the carbide agglomerated part exceeds 100 μm, there is no effect. Therefore, the upper limit is set to 20 μm for the carbide size and 100 μm for the size of the carbide agglomerated part.
[0015]
【Example】
Hereinafter, the present invention will be specifically described with reference to examples.
As test materials, each steel having the chemical composition shown in Table 1 was melted in a 100 kg vacuum induction melting furnace, forged, annealed, and used as test materials. The results are shown in Table 2. In the scratch test, an indenter was pressed against the surface hard film of the test piece, scratching was performed while increasing the load, and the critical load at which cracking of the hard film occurred was measured. Table 3 shows cold pilger mandrels and automobile parts bending presses as actual machine application examples.
In the actual machine test, the penetration diffusion treatment was carried out as a countermeasure for seizing the mold. The osmotic diffusion treatment is a kind of surface hard film generation process in which a VC hard film having a thickness of about 10 μm is obtained by being immersed in a V-based salt bath. In the cold pilger processing method, a tapered mandrel is inserted into a mother pipe, and cold rolling is performed with a roll die having a special hole shape from the outside. In this actual machine test, SUJ2 was rolled at a surface reduction rate of 75%, and the die life was evaluated based on the number of rolling raw pipes at the stage where scratches were confirmed on the inner surface of the product pipe due to the hard film peeling on the mandrel surface. In addition, an automobile part bending die was produced, and the die life was evaluated by the number of shots until the surface hard film was peeled when SPCC having a thickness of 5 mm was bent by a 1000-ton press as a workpiece.
[0016]
[Table 1]
Figure 0003970678
[0017]
[Table 2]
Figure 0003970678
[0018]
[Table 3]
Figure 0003970678
[0019]
As shown in Table 2, no. 1-4 are examples of the present invention. 5-8 are comparative examples. Comparative Example No. 5 and no. The component composition of No. 6 is high in C and Cr, the value of Mo + 1 / 2W is low, and the value of V + 1 / 2Nb is No. 6. No. 5 is low, no. 5 is high. Moreover, no. In the case of No. 5, since the carbon material size and the carbide aggregate size are large, the scratch critical load is small and the mold life in the actual machine test is short. Comparative Example No. The component composition of No. 7 has a low Cr, a low value of Mo + 1 / 2W, and a high value of V + 1 / 2Nb, so that the scratch critical load is small and the mold life in the actual machine test is short.
[0020]
Comparative Example No. Since the component composition of No. 8 is high in Cr, the values of Mo + 1 / 2W and V + 1 / 2Nb are low, and the carbon size and carbide aggregate size are large, both of them have a small scratch critical load and The mold life is short. Moreover, it turns out that all matrix hardness is 61 or less HRC. In contrast, the present invention example No. It can be seen that all of Nos. 1 to 4 have a matrix hardness of 62 HRC or more, and a long mold life in a scratch critical load or an actual machine test.
[0021]
【The invention's effect】
As described above, by improving the adhesion of the surface hard film by the osmotic diffusion treatment according to the present invention, the life of the mold that has been discarded due to the early peeling of the hard film is greatly improved, and the productivity is improved. It contributes to the cost reduction and has a great industrially excellent effect.

Claims (3)

質量%で、
C:0.9%超〜1.1%、
Si:0.1〜2.0%、
Mn:0.1〜1.5%、
Cr:5.0〜7.0%、
MoとWの1種または2種をMo+1/2W:3.0〜4.5%、VとNbの1種または2種をV+1/2Nb:0.5〜1.0%を含み、残部がFeおよび不可避的不純物からなる冷間工具鋼を、980〜1030℃の溶融塩浴に浸漬する浸透拡散処理による焼入後、焼戻により62〜64HRCの高硬度が得られることを特徴とする表面処理工具。
% By mass
C: more than 0.9% to 1.1%,
Si: 0.1 to 2.0%,
Mn: 0.1 to 1.5%
Cr: 5.0 to 7.0%,
One or two kinds of Mo and W include Mo + 1 / 2W: 3.0 to 4.5%, one or two kinds of V and Nb include V + 1 / 2Nb: 0.5 to 1.0%, and the balance A surface characterized in that a high hardness of 62 to 64 HRC can be obtained by tempering after quenching by a permeation diffusion treatment in which a cold tool steel composed of Fe and inevitable impurities is immersed in a molten salt bath at 980 to 1030 ° C. Processing tool.
請求項1に記載の鋼に、S:0.01〜0.10%を添加し被加工性を向上させたことを特徴とする表面処理工具。  The surface treatment tool characterized by adding S: 0.01-0.10% to the steel of Claim 1, and improving workability. 請求項1または2に記載の鋼中の炭化物サイズが20μm以下、かつ、炭化物凝集部のサイズが100μm以下であることを特徴とする表面処理工具。  A surface treatment tool characterized in that the carbide size in the steel according to claim 1 or 2 is 20 μm or less and the size of the carbide aggregate portion is 100 μm or less.
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