JP3964918B2 - Refractory double-layer pipe fittings - Google Patents

Description

  The present invention relates to a fireproof two-layer pipe joint used for a connecting portion when connecting a fireproof two-layer pipe straight pipe composed of an inner pipe and a fireproof outer pipe covering the inner pipe.

  Water / drainage pipes, gas pipes, power distribution pipes, etc. penetrate through fire prevention compartments of building structures. In particular, rigid polyvinyl chloride pipes are widely used for water supply / distribution pipes. However, it has been obliged to use fire-resistant materials such as metal and cement mortar for these pipe materials and joint materials when connecting them according to the Building Standard Law. Based on this regulation, cement mortar, water glass, metallic band, etc. at the joint between the inner pipe made of synthetic resin such as hard vinyl chloride pipe and the fireproof double-layer pipe straight pipe made of cladding tube such as fiber reinforced mortar Incombustible inorganic fiber gaskets are used.

  However, in a so-called wet joint method using cement or water glass as a main raw material, the joint material applied to the joint may be cured with time to cause cracks and peeling, thereby inducing dropout of the joint material. In addition, deterioration due to carbonation may be caused, and it may be difficult to secure a function as a stable joint treatment over a long period of time, which may cause a problem in durability. When a paste-like joint material filled into a tube or tape-like is used, the waterproof property is poor, and there is a problem that it softens due to rain water.

  On the other hand, in the dry joint method that uses a metal joint cover at the joint of a refractory double-layer pipe straight pipe, the dimensional shape is set in advance. It may be difficult to cope with the shape deformation based on the above, resulting in problems in workability. Moreover, since heat insulation is inferior, it may condense and corrode a metal especially when used for a water supply pipe.

  Furthermore, since these joint methods are implemented after the piping work to the building is completed, the work space is limited, it is difficult to secure a uniform joint processing function that is cumbersome and there is a risk of overlooking the joint processing part. is there. In addition, the construction period may be prolonged, which may increase the cost. In addition, there is a risk of causing damage to the straight pipe of the refractory double-layer pipe due to the change in length of the straight pipe of the refractory double-layer pipe due to the earthquake, vibration and moisture of the building, and temperature change.

As for the inorganic gasket, a joint structure (for example, see Patent Document 1) or a fiber material in which an annular packing made of non-flammable inorganic heat insulating fiber such as ceramic fiber, glass fiber, rock wool fiber, silica fiber or the like is interposed in a compressed state. Although there is a method of manufacturing a nonflammable fireproof packing made of an admixture and a connecting material (see, for example, Patent Document 2), these are brittle and easily broken during installation work. If the cutting method is poor, a gap may be formed in the joint, resulting in a problem in fire resistance. Further, a flexible fireproof rubber joint material made of rubber, expandable graphite, epoxy resin, and inorganic filler has been disclosed (see, for example, Patent Documents 3 and 4), but moldability and material strength are still insufficient. there were. Moreover, even if it is an inorganic annular packing or it is a flexible fireproof rubber joint material, mounting these at the construction site has been required to be improved by a rather complicated operation.
JP-A-7-301393 (second page: claims 1 to 12) Japanese Patent Laid-Open No. 10-281294 (second page: claim 1) JP 2002-181262 A (page 2: claim 1) JP 2001-348487 A (2nd page: claims 1 to 4)

  The present invention provides a thermally expandable joint material that is thermally expanded in the event of a fire, prevents smoke blockage and fire spread, solidifies the material, and has sufficient shape retention. A fire-resistant double-layer pipe joint that surrounds the outer periphery and is integrally attached to the opening end is provided.

The present invention relates to a synthetic resin in which the opening end of the inner pipe of a fireproof two-layer pipe straight pipe composed of a synthetic resin inner pipe and a fireproof outer pipe covering the inner pipe is joined to a receiving end. In a fireproof two-layer pipe joint composed of an inner pipe made of fire and an outer pipe having a fire resistance covering the inner pipe and joining the open end of the outer pipe of the fireproof double-layer pipe straight pipe to the receiving end, A heat-expandable joint material having an oxygen index of 35 or more, which surrounds the outer periphery of the receiving end portion of the inner pipe of the fireproof double-layer pipe joint and is based on a thermoplastic elastomer at the receiving end part of the outer pipe of the fireproof double-layer pipe joint A fireproof two-layer pipe joint characterized by being formed. Furthermore, the thermally expandable joint material is a thermally expandable joint material containing a thermoplastic elastomer, at least one of aluminum phosphite or boric acid, thermally expandable graphite, and aluminum hydroxide, and the thermoplastic elastomer Is a styrene-based thermoplastic elastomer comprising a polymer block mainly composed of vinyl aromatic hydrocarbon and a polymer block mainly composed of conjugated diene, and the thermally expandable joint material is made of styrene-based thermoplastic elastomer 100 A thermally expandable joint material containing 10 to 150 parts by mass of at least one of aluminum phosphite or boric acid, 5 to 100 parts by mass of thermally expandable graphite, and 10 to 200 parts by mass of aluminum hydroxide with respect to parts by mass. It is a fireproof two-layer pipe joint characterized by being.

The present invention also relates to a method for producing a fire-resistant double-layer pipe joint, wherein a thermally expandable joint material having an oxygen index of 35 or more, an inner tube, and a fire-resistant outer tube are integrally formed using a thermoplastic elastomer as a base material. It is.

  The thermally expandable joint material integrally attached to the fireproof two-layer pipe joint of the present invention is thermally expanded at the time of a fire to form a nonflammable fireproof layer, and the fireproof layer becomes weak even when exposed to high temperature for a long time. Difficult and has excellent fire protection performance. By being integrally attached to the joint, mistakes in forgetting to install and troublesome work are eliminated.

When applied to a 90 ° bent pipe joint, description will be made based on FIGS. 1 and 2. Reference numeral 1 denotes a fireproof double-layer pipe joint, reference numeral 2 denotes an inner pipe made of a synthetic resin such as hard vinyl chloride, and reference numeral 3 denotes A fire-resistant fiber mortar layer covering the outer periphery of the inner tube, and reference numeral 4 indicates a thermally expandable joint material formed on the outer periphery of the cylindrical receiving portion of the inner tube. The fiber mortar layer 3 is generally formed by injecting a fiber mortar between the mold and the inner tube after the inner tube 2 is installed in the mold.

In the present invention, a molded body in which a thermally expandable joint material is molded in a ring shape so that the inner diameter is the same as the outer diameter of the inner tube 2 and the outer diameter of the mortar layer 3 is the end of the inner tube 2. And then installed in the mold to form a fireproof two-layer pipe joint. The fireproof two-layer pipe joint 1 taken out from the mold is provided as a product after the fiber mortar layer 3 is cured and dried and cured.

The heat-expandable joint material of the present invention is characterized by using a thermoplastic elastomer as a base material and not undergoing a vulcanization step. The thermoplastic elastomer is not particularly limited, and examples thereof include vinyl chloride, styrene, polyolefin, and polyester elastomers. Of these, styrene-based elastomers are preferable, and styrene-based elastomers composed of a polymer block mainly composed of vinyl aromatic hydrocarbon and a polymer block mainly composed of conjugated diene are more preferable.

  In the styrene-based elastomer, examples of the vinyl aromatic hydrocarbon include styrene, p-methylstyrene, α-methylstyrene, vinylxylene, monochlorostyrene, dichlorostyrene, monobromostyrene, and the like. You may use it combining a seed or more. Of these vinyl aromatic hydrocarbons, styrene is particularly preferred. Examples of conjugated dienes include 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, and the like. These may be used alone or in combination of two or more. . Particularly preferred is 1,3-butadiene. These styrene elastomers can be produced by known anionic polymerization. The styrene content in the styrene elastomer is preferably 35% by mass or more and 90% by mass or less in order to maintain the hardness and rigidity of the thermally expandable joint material. When the amount is less than 35% by mass, the hardness and rigidity are lowered, and there may be a problem that the shape of the thermally expandable joint material molded product is deformed.

  The thermally expandable joint material preferably contains at least one of these thermoplastic elastomers, aluminum phosphite or boric acid, thermally expandable graphite, and aluminum hydroxide.

  In the present invention, it is preferable to use at least one of aluminum phosphite or boric acid as a shape stabilizer for preventing shape loss during a fire. The average particle diameter of the aluminum phosphite and boric acid used in the present invention is preferably 1 to 100 μm as measured by a laser diffraction method from the viewpoint of dispersibility.

  The content of at least one of aluminum phosphite or boric acid is preferably 10 to 150 parts by weight, more preferably 10 to 100 parts by weight, and more preferably 10 to 80 parts by weight with respect to 100 parts by weight of the thermoplastic elastomer. More preferred. If it is less than 10 parts by mass, the shape stability at the time of fire is insufficient, and if it exceeds 150 parts by mass, the moldability tends to be lowered.

Thermally expandable graphite is a powder of natural graphite, pyrolytic graphite, etc., treated with an inorganic acid such as sulfuric acid or nitric acid and a strong oxidizing agent such as concentrated nitric acid or permanganate, and maintains a graphite layered structure. Is a crystalline compound. When these are exposed to a temperature of about 200 ° C. or higher, they thermally expand 100 times or more. These natural graphite, pyrolytic graphite and other powders can be used in various types other than deoxidation treatment and further neutralization treatment.
The particle size of the thermally expandable graphite is preferably 20 to 400 mesh. If the particle size is smaller than 400 mesh, the degree of expansion of the thermally expandable graphite is small, and the resulting thermally expandable joint material may not be sufficiently thermally expanded in a fire, and if the particle size is larger than 20 mesh, the dispersibility may be deteriorated. The elasticity of the thermally expandable joint material may be reduced.

  The content of the heat-expandable graphite can be appropriately set depending on the type of rubber, the desired expansion ratio, and the like. Usually, the use of 5 to 100 parts by mass with respect to 100 parts by mass of the rubber is preferable, and more preferably 20 ~ 80 parts by mass. If the content of the heat-expandable graphite is less than 5 parts by mass, the obtained heat-expandable joint material may not be sufficiently thermally expanded in the event of a fire, and if it exceeds 100 parts by mass, the thermal expansion ratio will be increased, but the heat obtained Physical properties such as strength of the expandable joint material also tend to be reduced.

The content of the aluminum hydroxide is preferably 10 to 150 parts by mass, more preferably 10 to 100 parts by mass, and even more preferably 10 to 80 parts by mass with respect to 100 parts by mass of the thermoplastic elastomer. If it is used in excess of 150 parts by mass, the moldability may be inferior. From the viewpoint of dispersibility, the average particle diameter of these fillers is preferably 1 to 50 μm as measured by a laser diffraction method.

The thermally expandable joint material of the present invention has an oxygen index of 35 or more. If it is less than 35, the fireproofing property at the time of fire is insufficient. The oxygen index can be adjusted by adjusting the amount of aluminum phosphite or boric acid and inorganic filler.

  The method for adjusting the heat-expandable joint material is not particularly limited, and comprises the steps of kneading the composition and forming the desired shape after blending the necessary components.

  As an apparatus for kneading the composition, there are kneading apparatuses such as conventionally known mixers, Banbury mixers, kneader mixers, and two rolls. As a device for molding the kneaded thermoplastic elastomer composition, there are conventionally known molding devices such as press molding, extrusion molding, and calendar molding. Generally, after kneading and extruding a thermoplastic elastomer composition with a rubber extruder, and then forming into a sheet of the required thickness, it may be prepared by punching or the like according to the opening diameter of the fire-resistant double-layer pipe joint, The molding method is not limited.

  The heat-expandable joint material of the present invention is combined with plasticizers, softeners, anti-aging agents, processing aids, lubricants, tackifiers, etc. used in ordinary rubber compounds, as long as the effect is not impaired. May be used. Examples of softeners and plasticizers that are effective for adjusting moldability include process oils such as paraffin and naphthene, soft paraffin and other paraffins, waxes, synthetic polymer softeners such as silicone oil and liquid polybutene. Agents, ester plasticizers such as phthalic acid, adipic acid, sebacic acid and phosphoric acid, stearic acid and its esters, alkylsulfonic acid esters and tackifiers.

  Hereinafter, the present invention will be specifically described with reference to experimental examples, but these examples do not limit the present invention. In addition, the part and% in the following description are based on a mass reference | standard.

  The components shown in Table 1 were kneaded at 120 ° C. for 3 minutes using a 3 liter kneader mixer. Subsequently, the obtained kneaded material was kneaded with a two-roll for 3 minutes to prepare a compound. Next, the compound was charged into a ring-shaped mold having a thickness of 4 mm, an outer diameter of 85 mm, and an inner diameter of 67 mm, and heated and pressed at 180 ° C. for 1 minute with a hot press machine to obtain a ring-shaped joint material. The obtained ring-shaped joint material was evaluated alone and mounted and evaluated as follows.

This joint material is attached to the opening of a fire-resistant double-layer pipe joint with an outer diameter of 85 mm using a hard PVC inner pipe with an outer diameter of 67 mm with an adhesive, and then attached to a joint mold and injected with fiber mortar to fire-resistant. A two-layer pipe joint was prepared and fire resistance was evaluated in the mounted state.

The materials used in this example are as shown below.
(1) Thermoplastic elastomer: SBS (manufactured by JSR Shell, “TR2250” styrene / butadiene = 52/48, “TR2600” styrene / butadiene = 32/68)
(2) Thermally expandable graphite: (“SS-3” manufactured by Air Water Chemical Co., Ltd., expansion start temperature 260 ° C.)
(3) Aluminum phosphite: (Tahei Chemical Industry Co., Ltd., “APA-100”)
Boric acid: (BORAX Co., Ltd.)
(4) Inorganic filler: Aluminum hydroxide ("ALH" manufactured by Kawai Lime Industry Co., Ltd.)
(5) Processing aid: Ester lubricant (manufactured by Kao Corporation, “Kaoh Wax 220”)
(6) Anti-aging agent: N- (1,3-dimethylbutyl) -N-phenyl-p-phenylenediamine (manufactured by Ouchi Shinsei Co., Ltd., “NOCRACK 6C”)
(7) Carbon black: “# 60” manufactured by Asahi Carbon Co., Ltd.
(8) Softener: Process oil (manufactured by Nippon Sun Oil Co., Ltd., “Thumper 150”)

"Examples 1-4""Comparative Examples 1-2"
In the examples and comparative examples, each characteristic of the ring joint material was evaluated and summarized in Table 1.
Thermal expansion property: A ring joint material produced by press molding to a thickness of 4 mm, an outer diameter of 85 mm, and an inner diameter of 67 mm was heat-treated in a gear oven at 300 ° C. for 30 minutes, and the expansion ratio was measured.
Shape retention property: The fireproof two-layer pipe joint integrally attached with the joint material produced in Examples and Comparative Examples was heat-treated in a gear oven at 300 ° C for 30 minutes, and then evaluated by visual observation and finger touch. Evaluation was made as “good” if the residue did not collapse even if the residue was touched with a finger, and “impossible” if the residue collapsed immediately after touching, or the residue was broken after heating.
Oxygen index: Measured using a combustion tester (Suga Test Instruments Co., Ltd., ON-1D type) according to JIS K7201.

A fireproof double-layer pipe straight pipe inserted into the fireproof double-layer pipe joint having an outer diameter of 85 mm integrally formed with the ring joint material of Example 1 was prepared. However, when the end face of the fiber mortar layer of the refractory double-layer pipe straight pipe was cut slightly diagonally and joined to the refractory double-layer pipe joint, a gap of 3 mm at maximum could be formed over a half circumference. In this state, when a flame was applied to the gap with a hand gas burner for 1 minute, the thermally expandable joint material foamed and carbonized, but no abnormality was observed in the internal hard PVC inner tube.

Next, prepare an ordinary fire-resistant double-layer pipe joint with an outer diameter of 85 mm whose outer diameter is covered with a fiber mortar layer without using a heat-expandable joint material. When a flame was applied to the gap portion with a hand gas burner for 1 minute with a gap in the inside, the internal hard PVC inner tube was burnt.

The figure which showed typically the partial cross section of the fireproof two-layer pipe joint in connection with this invention. The partial expanded sectional view which showed typically the state which attached the thermally expansible joint material in FIG.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Fireproof two-layer pipe joint 2 Hard vinyl chloride inner pipe 3 Fiber reinforced mortar outer pipe 4 Thermal expansion joint material

Claims (2)

An inner tube made of synthetic resin,
An inner pipe made of a synthetic resin in which the opening end of the inner pipe of the fireproof two-layer pipe straight pipe made of a fireproof outer pipe covering the inner pipe is joined to the receiving end,
In the fireproof two-layer pipe joint comprising the outer pipe having a fire resistance that covers the inner pipe and the open end of the outer pipe of the fireproof double-layer pipe straight pipe is joined to the receiving end.
Surrounding the outer periphery of the receiving end of the inner pipe of the refractory two-layer pipe joint and mainly having a polymer block mainly composed of vinyl aromatic hydrocarbons and a conjugated diene at the receiving end of the outer refractory two-layer pipe joint 10 to 150 parts by mass of at least one of aluminum phosphite or boric acid, 5 to 100 parts by mass of thermally expandable graphite, and 10% of aluminum hydroxide with respect to 100 parts by mass of a styrene thermoplastic elastomer composed of a polymer block. A fire-resistant two-layer pipe joint comprising a thermally expandable joint material containing ~ 200 parts by mass and having an oxygen index of 35 or more. An inner tube made of synthetic resin,
An inner pipe made of a synthetic resin in which the opening end of the inner pipe of the fireproof two-layer pipe straight pipe made of a fireproof outer pipe covering the inner pipe is joined to the receiving end,
In the fireproof two-layer pipe joint comprising the outer pipe having a fire resistance covering the inner pipe and joining the opening end of the outer pipe of the fireproof double-layer pipe straight pipe to the receiving end,
Surrounding the outer periphery of the receiving end of the inner pipe of the refractory two-layer pipe joint and mainly having a polymer block mainly composed of vinyl aromatic hydrocarbons and a conjugated diene at the receiving end of the outer refractory two-layer pipe joint 10 to 150 parts by mass of at least one of aluminum phosphite or boric acid, 5 to 100 parts by mass of thermally expandable graphite, and 10% of aluminum hydroxide with respect to 100 parts by mass of a styrene thermoplastic elastomer composed of a polymer block. A method for producing a fire-resistant double-layered pipe joint, wherein a thermally expandable joint material containing ~ 200 parts by mass and having an oxygen index of 35 or more is integrally formed at the same time when an outer pipe having fire resistance is formed on the inner pipe .

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