JP3930014B2 - Skin cleanser composition - Google Patents
Skin cleanser composition Download PDFInfo
- Publication number
- JP3930014B2 JP3930014B2 JP2004355114A JP2004355114A JP3930014B2 JP 3930014 B2 JP3930014 B2 JP 3930014B2 JP 2004355114 A JP2004355114 A JP 2004355114A JP 2004355114 A JP2004355114 A JP 2004355114A JP 3930014 B2 JP3930014 B2 JP 3930014B2
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- component
- carbon atoms
- skin
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 42
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 58
- 239000000194 fatty acid Substances 0.000 claims description 58
- 229930195729 fatty acid Natural products 0.000 claims description 58
- 150000004665 fatty acids Chemical class 0.000 claims description 53
- 239000002245 particle Substances 0.000 claims description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- -1 glycol ethers Chemical class 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002775 capsule Substances 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000011324 bead Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002334 glycols Chemical class 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 235000011837 pasties Nutrition 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 125000005313 fatty acid group Chemical group 0.000 claims 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- 239000000306 component Substances 0.000 description 16
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 12
- 238000005187 foaming Methods 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 8
- 235000021357 Behenic acid Nutrition 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 229940116226 behenic acid Drugs 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 6
- 230000007794 irritation Effects 0.000 description 6
- 235000021314 Palmitic acid Nutrition 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 235000021360 Myristic acid Nutrition 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001447 alkali salts Chemical class 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 3
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000006072 paste Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- 239000004386 Erythritol Substances 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- 235000021353 Lignoceric acid Nutrition 0.000 description 2
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229940124274 edetate disodium Drugs 0.000 description 2
- 235000019414 erythritol Nutrition 0.000 description 2
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 2
- 229940009714 erythritol Drugs 0.000 description 2
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 2
- 229960004585 etidronic acid Drugs 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000758791 Juglandaceae Species 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229920000715 Mucilage Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 206010050637 Skin tightness Diseases 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007903 gelatin capsule Substances 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 230000000774 hypoallergenic effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005339 levitation Methods 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- RCAVMXODXXMCER-ASTDGNLGSA-N n,n-dimethyl-2-[2-[(e)-2-pyridin-2-ylethenyl]phenoxy]ethanamine;hydrochloride Chemical compound Cl.CN(C)CCOC1=CC=CC=C1\C=C\C1=CC=CC=N1 RCAVMXODXXMCER-ASTDGNLGSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000003232 water-soluble binding agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
本発明は、配合されている水不溶性粒子の安定性が良好な皮膚洗浄剤組成物に関する。 The present invention relates to a skin cleanser composition having good stability of water-insoluble particles incorporated therein.
従来、洗顔料などの皮膚洗浄剤として、安価で洗浄性が高く、良好な起泡性を示す脂肪酸石鹸系の皮膚洗浄剤が使用されている。そして、その原料としては、主に天然の動植物油脂である牛脂、ヤシ油、パーム油、パーム核油を加水分解して得られる脂肪酸(主成分は炭素数8〜18の飽和脂肪酸および不飽和脂肪酸)が用いられている。 2. Description of the Related Art Conventionally, fatty acid soap skin cleaners that are inexpensive, have high cleanability, and have good foaming properties have been used as skin cleansers such as facial cleansers. And as the raw material, fatty acids obtained by hydrolyzing mainly beef tallow, coconut oil, palm oil, palm kernel oil which are natural animal and plant oils and fats (main components are C8-18 saturated fatty acids and unsaturated fatty acids) ) Is used.
また、皮膚洗浄剤においては、物理的な洗浄効果やマッサージ効果を得るために、水不溶性粒子をスクラブ剤として配合することが行われており、脂肪酸石鹸と水不溶性粒子を組み合わせた洗浄剤組成物も知られている(例えば、特許文献1、特許文献2、特許文献3、特許文献4)。しかしながら、脂肪酸石鹸系の皮膚洗浄剤に水不溶性粒子を配合した場合、特に高温において、粒子が沈降又は浮上しやすく、粒子を安定に分散させた状態を保つのは困難であった。
本発明の目的は、泡立ちとすすぎ性に優れるとともに、皮膚に対して低刺激性であり、しかも水不溶性粒子の安定性が良好な皮膚洗浄剤組成物を提供することにある。 An object of the present invention is to provide a skin cleanser composition that is excellent in foaming and rinsing properties, has low irritation to the skin, and has good stability of water-insoluble particles.
本発明者らは、脂肪酸とその塩を構成する脂肪酸組成において、炭素数16以上の脂肪酸の割合を比較的に高くすることにより、高温においても水不溶性粒子を安定に保つことができ、しかも、泡立ちとすすぎ性に優れ、皮膚に対して低刺激性の皮膚洗浄剤組成物が得られることを見出した。 The present inventors can maintain water-insoluble particles stably even at high temperatures by relatively increasing the proportion of fatty acids having 16 or more carbon atoms in the fatty acid composition constituting fatty acids and salts thereof, It has been found that a skin cleanser composition having excellent foaming and rinsing properties and low irritation to the skin can be obtained.
本発明は、次の成分(A)並びに(B):
(A)脂肪酸及びその塩を合計で20〜50質量%
(B)水不溶性粒子、
を含有し、成分(A)を構成する脂肪酸の組成が、炭素数15以下の脂肪酸と炭素数16以上の脂肪酸の質量比が20:80〜40:60であり、かつ脂肪酸の平均分子量が255以上であって、液状、クリーム状又はペースト状の形態である皮膚洗浄剤組成物を提供するものである。
The present invention includes the following components (A) and (B):
(A) 20-50 mass% of fatty acids and salts thereof in total
(B) water-insoluble particles,
And the composition of the fatty acid constituting the component (A) is such that the mass ratio of the fatty acid having 15 or less carbon atoms and the fatty acid having 16 or more carbon atoms is 20:80 to 40:60, and the average molecular weight of the fatty acid is 255 what der above, there is provided a liquid, creamy or pasty skin cleansing composition in the form.
本発明の皮膚洗浄剤組成物は、泡立ちとすすぎ性に優れるとともに、皮膚に対して低刺激性であり、しかも高温においても、水不溶性粒子の安定性が良好である。 The skin cleanser composition of the present invention is excellent in foaming and rinsing properties, is hypoallergenic to the skin, and has good stability of water-insoluble particles even at high temperatures.
本発明で用いる成分(A)の脂肪酸及びその塩を構成する脂肪酸としては、炭素数8〜24のものが用いられる。
脂肪酸塩を構成する対イオンとしては、例えばナトリウム、カリウム等のアルカリ金属、塩基性アミノ酸、有機アミン類などが挙げられる。これらのうち、アルカリ金属塩が好ましく、特に液状又はペースト状の洗浄剤組成物を得る上で、カリウム塩が好ましい。
また、脂肪酸の中和度は60〜100%、特に65〜95%、更に70〜90%であるのが、起泡性、経時安定性の点で好ましい。
As the fatty acid constituting the component (A) and the salt thereof used in the present invention, those having 8 to 24 carbon atoms are used.
Examples of the counter ion constituting the fatty acid salt include alkali metals such as sodium and potassium, basic amino acids, and organic amines. Of these, alkali metal salts are preferable, and potassium salts are particularly preferable in obtaining a liquid or pasty detergent composition.
Further, the neutralization degree of the fatty acid is preferably 60 to 100%, particularly 65 to 95%, and more preferably 70 to 90% in terms of foamability and stability over time.
脂肪酸及びその塩は、それぞれ1種以上を用いることができ、全組成中に20〜50質量%、好ましくは20〜45質量%、特に好ましくは20〜40質量%含有される。かかる範囲において、起泡性や泡質が好適であり、洗浄後の皮膚につっぱり感が生じることがない。 1 type or more can each be used for a fatty acid and its salt, and 20-50 mass% in the whole composition, Preferably it is 20-45 mass%, Most preferably, it contains 20-40 mass%. In such a range, foaming properties and foam quality are suitable, and there is no feeling of tension in the washed skin.
本発明においては、脂肪酸及びその塩を構成する脂肪酸の組成が、炭素数15以下の脂肪酸と炭素数16以上の脂肪酸の質量比が20:80〜40:60であり、好ましくは20:80〜35:65、特に好ましくは20:80〜30:70である。この範囲内であれば、十分な起泡性が得られ、高温における水不溶性粒子の経時安定性も良好である。 In the present invention, the composition of the fatty acid and its fatty acid is such that the mass ratio of the fatty acid having 15 or less carbon atoms and the fatty acid having 16 or more carbon atoms is 20:80 to 40:60, preferably 20:80 to 35:65, particularly preferably 20:80 to 30:70. If it is within this range, sufficient foaming properties can be obtained, and the temporal stability of water-insoluble particles at high temperatures is also good.
炭素数15以下の脂肪酸としては、ラウリン酸、ミリスチン酸が好ましいものとして挙げられる。
また、炭素数16以上の脂肪酸としては、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸、アラキン酸、ベヘニン酸、リグノセリン酸等が挙げられ、特にパルミチン酸、ステアリン酸、アラキン酸、ベヘニン酸が好ましい。
Preferred examples of the fatty acid having 15 or less carbon atoms include lauric acid and myristic acid.
Examples of the fatty acid having 16 or more carbon atoms include palmitic acid, stearic acid, isostearic acid, oleic acid, arachic acid, behenic acid, lignoceric acid, and the like, and palmitic acid, stearic acid, arachic acid, and behenic acid are particularly preferable. .
これらの脂肪酸の平均分子量は、255以上、特に260以上、更には265以上であるのが、高温における水不溶性粒子の経時安定性が良好であり、好ましい。 The average molecular weight of these fatty acids is preferably 255 or more, particularly 260 or more, and more preferably 265 or more, because the stability with time of the water-insoluble particles at high temperatures is good.
さらに、本発明においては、成分(A)を構成する脂肪酸の組成が、炭素数20〜24の脂肪酸が全脂肪酸中の10〜30質量%、特に12〜28質量%、更に15〜25質量%であるのが、洗浄後の皮膚にしっとり感を付与することができ、経時安定性にも優れ、起泡性や泡質も良好であり、好ましい。 Furthermore, in the present invention, the composition of the fatty acid constituting the component (A) is such that the fatty acid having 20 to 24 carbon atoms is 10 to 30% by mass, particularly 12 to 28% by mass, and further 15 to 25% by mass in the total fatty acids. Therefore, it is preferable because it can impart a moist feeling to the skin after washing, is excellent in stability over time, and has good foaming properties and foam quality.
炭素数20〜24の脂肪酸としては、炭素数20〜24の直鎖飽和脂肪酸が好ましく、アラキン酸(炭素数20)、ベヘニン酸(炭素数22)、リグノセリン酸(炭素数24)等が挙げられ、これらの1種以上が用いられる。特に、アラキン酸、ベヘニン酸が好ましい。 The fatty acid having 20 to 24 carbon atoms is preferably a linear saturated fatty acid having 20 to 24 carbon atoms, and examples thereof include arachidic acid (20 carbon atoms), behenic acid (22 carbon atoms), lignoceric acid (24 carbon atoms) and the like. One or more of these are used. In particular, arachidic acid and behenic acid are preferable.
本発明で用いる成分(B)の水不溶性粒子としては、物理的な洗浄効果やマッサージ効果、感触や外観の付与等を目的として、通常の洗浄剤組成物に用いられるものであれば特に制限されない。例えば、粉体、粒子、カプセル、ビーズ、これらの造粒物等が挙げられる。 The water-insoluble particles of the component (B) used in the present invention are not particularly limited as long as they can be used in ordinary cleaning compositions for the purpose of providing a physical cleaning effect, a massage effect, a touch and appearance. . For example, powder, particle | grains, a capsule, bead, these granulated materials, etc. are mentioned.
粉体としては、例えば酸化チタン、タルク、カオリン、ベントナイト、シリカ、雲母チタン等の無機粉体やシリコーンパウダー、シルクパウダー、麻繊維パウダー、セルロース又はその誘導体、澱粉等の高分子又はその誘導体等の有機粉体が挙げられる。粒子としては、クルミ、モモ核等の果実の殻や飽和溶解度以上の塩化ナトリウム等が挙げられる。カプセルとしては、寒天カプセル、ゼラチンカプセル等が挙げられる。ビーズ類としては、ポリエチレン、ポリスチレン、ナイロン、アクリル樹脂等のポリマービーズが挙げられる。 Examples of powders include inorganic powders such as titanium oxide, talc, kaolin, bentonite, silica, and mica titanium, silicone powder, silk powder, hemp fiber powder, cellulose or derivatives thereof, polymers such as starch, and derivatives thereof. Organic powder is mentioned. Examples of the particles include fruit shells such as walnuts and peach nuclei, and sodium chloride having a saturation solubility or higher. Examples of capsules include agar capsules and gelatin capsules. Examples of the beads include polymer beads such as polyethylene, polystyrene, nylon, and acrylic resin.
また、粉体や粒子を一次粒子とし、結合剤(バインダー)を用いて造粒した造粒物を用いることもできる。結合剤としては、例えばポリビニルアルコール及び/又はその誘導体、ポリ(メタ)アクリル酸アルカリ塩、(メタ)アクリル酸エステル共重合物のアルカリ塩、アクリル酸/マレイン酸共重合物のアルカリ塩、ポリビニルピロリドン等の合成品;メチルセルロース、エチルセルロース、カルボキシメチルセルロース、ヒドロキシアルキルセルロース、澱粉誘導体等の半合成品;澱粉、海草類、植物粘質物、タンパク質などの天然高分子が用いられる。このような造粒物は、洗浄中あるいはすすぎ時に物理力、水分、成分濃度、温度などの環境変化が起こることによって物理的又は化学的に崩壊し、一粒子あたりの体積が減少する崩壊性粒子であってもよい。 Further, a granulated product obtained by granulating powder or particles as primary particles and using a binder (binder) can also be used. Examples of the binder include polyvinyl alcohol and / or derivatives thereof, poly (meth) acrylic acid alkali salt, alkali salt of (meth) acrylic acid ester copolymer, alkali salt of acrylic acid / maleic acid copolymer, polyvinylpyrrolidone, and the like. Synthetic products such as; semi-synthetic products such as methyl cellulose, ethyl cellulose, carboxymethyl cellulose, hydroxyalkyl cellulose, starch derivatives; and natural polymers such as starch, seaweeds, plant mucilage, and proteins. Such granulated materials are disintegrating particles that physically or chemically disintegrate due to environmental changes such as physical force, moisture, component concentration, and temperature during washing or rinsing, and the volume per particle decreases. It may be.
崩壊性粒子としては、少なくとも一部が水不溶性である一次粒子が水溶性バインダーにより凝集してなるものが、物理的な洗浄性に優れ、使用感も良好であることから好ましく、例えば、特開2000-63899号公報、特開2000-119171号公報、特開2000-119172号公報、特開2000-229807号公報等に記載のものを用いることができる。 As the disintegrating particles, those obtained by aggregating at least a part of water-insoluble primary particles with a water-soluble binder are preferable because they have excellent physical detergency and good usability. Those described in JP 2000-63899, JP 2000-119171, JP 2000-119172, JP 2000-229807, and the like can be used.
成分(B)の水不溶性粒子は、平均粒径が0.5〜2000μm、特に1〜1000μm、更に100〜800μmであるのが、洗浄効果やマッサージ効果の点で好ましい。なお、粒径は、レーザー回折散乱法、顕微鏡法、ふるい分け法などにより測定される。 The water-insoluble particles of the component (B) preferably have an average particle size of 0.5 to 2000 μm, particularly 1 to 1000 μm, and more preferably 100 to 800 μm from the viewpoint of the cleaning effect and the massage effect. The particle size is measured by a laser diffraction scattering method, a microscope method, a sieving method, or the like.
また、水不溶性粒子の比重は特に制限されないが、例えば0.8〜5のものを用いることができる。本願発明においては、どのような比重の水不溶性粒子でも、組成物中に安定に分散させることができる。 Further, the specific gravity of the water-insoluble particles is not particularly limited, but for example, 0.8 to 5 can be used. In the present invention, water-insoluble particles having any specific gravity can be stably dispersed in the composition.
成分(B)の水不溶性粒子は、1種以上を用いることができ、全組成中に0.01〜50質量%、特に0.1〜20質量%含有されるのが、洗浄効果、マッサージ効果の点で好ましい。 One or more kinds of the water-insoluble particles of the component (B) can be used, and 0.01 to 50% by mass, particularly 0.1 to 20% by mass is contained in the total composition, and the cleaning effect and the massage effect This is preferable.
本発明の皮膚洗浄剤組成物には、更にグリコール類又はグリコールエーテル類を含有させることができる。具体的には、エチレングリコール、プロピレングリコール、1,3−ブチレングリコール、ジエチレングリコール、ジプロピレングリコール、イソプレングリコール、ポリエチレングリコール(平均分子量2000以下)、ポリプロピレングリコール(平均分子量1500以下)、ジエチレングリコールモノエチルエーテル等が挙げられ、特に、ジプロピレングリコール、ジエチレングリコールモノエチルエーテルが好ましい。 The skin cleansing composition of the present invention may further contain glycols or glycol ethers. Specifically, ethylene glycol, propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isoprene glycol, polyethylene glycol (average molecular weight 2000 or less), polypropylene glycol (average molecular weight 1500 or less), diethylene glycol monoethyl ether, etc. In particular, dipropylene glycol and diethylene glycol monoethyl ether are preferable.
これらのグリコール類又はグリコールエーテル類は、1種以上を用いることができ、全組成中に3〜30質量%、特に5〜25質量%含有させるのが、起泡性及び安定性のほか、製造時における脂肪酸とその塩の溶解性の点で好ましい。 One or more of these glycols or glycol ethers can be used, and 3 to 30% by mass, particularly 5 to 25% by mass in the total composition is produced in addition to foamability and stability. From the viewpoint of solubility of fatty acids and salts thereof at the time.
本発明の皮膚洗浄剤組成物には、更に分子中に3個以上の水酸基を有する多価アルコールを含有させることができる。具体的には、グリセリン、ソルビトール、マンニトール、エリスリトール、キシリトール、マルチトール、トレハロース、スクロース、ポリグリセリン等が挙げられ、特に、グリセリン、ソルビトール、エリスリトール、キシリトールが好ましい。 The skin cleansing composition of the present invention may further contain a polyhydric alcohol having 3 or more hydroxyl groups in the molecule. Specific examples include glycerin, sorbitol, mannitol, erythritol, xylitol, maltitol, trehalose, sucrose, polyglycerin, and the like, and glycerin, sorbitol, erythritol, and xylitol are particularly preferable.
これらの多価アルコールは、1種以上を用いることができ、全組成中に3〜30質量%、特に5〜28質量%含有させるのが、洗浄後の皮膚のつっぱり感低減やしっとり感付与の点で好ましい。 One or more kinds of these polyhydric alcohols can be used, and 3 to 30% by mass, particularly 5 to 28% by mass in the total composition can reduce the feeling of skin tightness and give a moist feeling after washing. This is preferable.
本発明の皮膚洗浄剤組成物は、水を20〜70質量%、特に25〜60質量%、更に30〜50質量%含有し、液状、クリーム状又はペースト状の形態とすることが好ましい。 The skin cleansing composition of the present invention contains water in an amount of 20 to 70% by mass, particularly 25 to 60% by mass, and further 30 to 50% by mass, and is preferably in the form of a liquid, cream or paste.
本発明の皮膚洗浄剤組成物には、前記成分以外に、通常の洗浄剤組成物に用いられる成分、例えば、脂肪酸塩以外の界面活性剤、保湿剤、油性成分、殺菌剤、抗炎症剤、防腐剤、キレート剤、増粘剤、塩類、パール化剤、香料、冷感剤、色素、紫外線吸収剤、酸化防止剤、植物エキスなどを含有させることができる。 In the skin cleanser composition of the present invention, in addition to the above components, components used in normal cleanser compositions, for example, surfactants other than fatty acid salts, moisturizers, oil components, bactericides, anti-inflammatory agents, Preservatives, chelating agents, thickeners, salts, pearlizing agents, fragrances, cooling agents, pigments, ultraviolet absorbers, antioxidants, plant extracts and the like can be contained.
本発明の皮膚洗浄剤組成物は、各成分を混合することにより製造することができ、液状ないしクリーム状、ペースト状のいずれの形態にもすることができる。使用性の点からクリーム状、ペースト状とするのが好ましい。また、洗顔料、メイク落とし、ボディシャンプー、ハンドソープ等として適用することができる。 The skin cleansing composition of the present invention can be prepared by mixing the components, liquid or cream may be in paste form any form. From the viewpoint of usability, it is preferable to use a cream or paste. Further, it can be applied as a facial cleanser, makeup remover, body shampoo, hand soap and the like.
実施例1〜9、比較例1
表1に示す組成の皮膚洗浄剤組成物を、各成分を混合することにより製造し、泡立ち、すすぎ性、刺激性及び高温安定性を評価した。結果を表1に併せて示す。
Examples 1-9, Comparative Example 1
A skin cleansing composition having the composition shown in Table 1 was produced by mixing each component, and foaming, rinsing properties, irritation and high temperature stability were evaluated. The results are also shown in Table 1.
(評価方法)
(1)泡立ち、すすぎ性、刺激性:
10名の専門パネルが各組成物を用いて洗顔試験を行い、泡立ち(泡の量)、すすぎ性(泡切れの良さ)、刺激性(つっぱり感、かさつきのなさ)を官能評価し、下記の判定基準に従い判定した。
(判定基準)
◎:専門パネル10名中、8名以上が良いと評価した。
○:専門パネル10名中、6〜7名が良いと評価した。
△:専門パネル10名中、4〜5名が良いと評価した。
×:専門パネル10名中、3名以下が良いと評価した。
(Evaluation methods)
(1) Foaming, rinsing and irritation:
A panel of 10 professionals conducted a face-wash test using each composition, and sensorially evaluated foaming (amount of foam), rinsing properties (goodness of foaming), and irritation (feeling of being sticky, not being bulky). Judgment was made according to the criteria.
(Criteria)
A: Evaluated that 8 or more out of 10 specialized panels were good.
○: Out of 10 professional panels, 6 to 7 were evaluated as good.
(Triangle | delta): Four to five persons evaluated that 10 expert panels were good.
X: Three or less persons evaluated that 10 expert panels were good.
(2)高温安定性:
各組成物を容量70mLのプラスチック容器に充填し、45℃及び50℃でそれぞれ2週間保存した後、その状態を目視にて観察し、下記の基準で評価した。
(判定基準)
◎:45℃、50℃とも、性状に変化なく、粒子の沈降、浮上はない。
○:45℃で性状に変化なく、粒子の沈降、浮上はないが、50℃では、分離、又は粒子の沈降、浮上が認められる。
×:45℃、50℃とも、分離、又は粒子の沈降、浮上が認められる。
(2) High temperature stability:
Each composition was filled in a 70 mL capacity plastic container and stored at 45 ° C. and 50 ° C. for 2 weeks, respectively, and the state was visually observed and evaluated according to the following criteria.
(Criteria)
A: At 45 ° C. and 50 ° C., there is no change in properties, and there is no sedimentation or floating of particles.
○: No change in properties at 45 ° C. and no sedimentation or floating of particles, but separation or sedimentation or floating of particles is observed at 50 ° C.
X: Separation or particle sedimentation and levitation were observed at both 45 ° C and 50 ° C.
実施例10(洗顔料)
以下に示す組成の洗顔料を常法により製造した。
脂肪酸およびその塩は33.9質量%、全脂肪酸中における炭素数20〜24の脂肪酸の割合は19質量%であり、炭素数15以下の脂肪酸:炭素数16以上の脂肪酸の質量比=27:73、脂肪酸の平均分子量は270.4である。また、脂肪酸の中和度は全脂肪酸の80%である。
Example 10 (face wash)
A face wash having the composition shown below was produced by a conventional method.
Fatty acids and salts thereof are 33.9% by mass, the ratio of fatty acids having 20 to 24 carbon atoms in all fatty acids is 19% by mass, and the mass ratio of fatty acids having 15 or less carbons: fatty acids having 16 or more carbons = 27: 73, the average molecular weight of the fatty acid is 270.4. Moreover, the neutralization degree of a fatty acid is 80% of the total fatty acid.
(成分)
ラウリン酸 2.6(質量%)
ミリスチン酸 5.2
パルミチン酸 7.0
ステアリン酸 8.7
アラキン酸 0.6
ベヘニン酸 5.0
水酸化カリウム 4.9
雲母チタン*5 0.5
ジプロピレングリコール 6.0
ジエチレングリコールモノエチルエーテル 5.0
グリセリン 10.0
ソルビトール 7.5
高重合度ポリエチレングリコール 0.02
ジブチルヒドロキシトルエン 0.1
エデト酸ニナトリウム 0.2
ヒドロキシエタンジホスホン酸 0.3
精製水 残余
*5:Timiron Starluster MP-115(メルク社製):平均粒径5μm
(component)
Lauric acid 2.6 (mass%)
Myristic acid 5.2
Palmitic acid 7.0
Stearic acid 8.7
Arachinic acid 0.6
Behenic acid 5.0
Potassium hydroxide 4.9
Mica titanium * 5 0.5
Dipropylene glycol 6.0
Diethylene glycol monoethyl ether 5.0
Glycerin 10.0
Sorbitol 7.5
High polymerization degree polyethylene glycol 0.02
Dibutylhydroxytoluene 0.1
Edetate disodium 0.2
Hydroxyethanediphosphonic acid 0.3
Purified water Residue * 5: Timiron Starluster MP-115 (Merck): Average particle size 5 μm
実施例11(ボディシャンプー)
以下に示す組成のボディシャンプーを常法により製造した。
脂肪酸およびその塩は34.5質量%、全脂肪酸中における炭素数20〜24の脂肪酸の割合は19質量%であり、炭素数15以下の脂肪酸:炭素数16以上の脂肪酸の質量比=27:73、脂肪酸の平均分子量は270.4である。また、脂肪酸の中和度は全脂肪酸の90%である。
Example 11 (body shampoo)
A body shampoo having the composition shown below was produced by a conventional method.
The proportion of fatty acids and salts thereof is 34.5% by mass, the proportion of fatty acids having 20 to 24 carbon atoms in all fatty acids is 19% by mass, and the mass ratio of fatty acids having 15 or less carbons: fatty acids having 16 or more carbons = 27: 73, the average molecular weight of the fatty acid is 270.4. Moreover, the neutralization degree of a fatty acid is 90% of the total fatty acid.
(成分)
ラウリン酸 2.6(質量%)
ミリスチン酸 5.2
パルミチン酸 7.0
ステアリン酸 8.7
アラキン酸 0.6
ベヘニン酸 5.0
水酸化カリウム 5.5
寒天カプセル(森下仁丹社製、平均粒径2000μm) 5.0
ジプロピレングリコール 11.0
グリセリン 15.0
ジブチルヒドロキシトルエン 0.1
エデト酸ニナトリウム 0.2
ヒドロキシエタンジホスホン酸 0.3
香料 適量
精製水 残余
(component)
Lauric acid 2.6 (mass%)
Myristic acid 5.2
Palmitic acid 7.0
Stearic acid 8.7
Arachinic acid 0.6
Behenic acid 5.0
Potassium hydroxide 5.5
Agar capsule (Morishita Hitotani, average particle size 2000μm) 5.0
Dipropylene glycol 11.0
Glycerin 15.0
Dibutylhydroxytoluene 0.1
Edetate disodium 0.2
Hydroxyethanediphosphonic acid 0.3
Perfume Appropriate amount of purified water
実施例10及び11で得られた皮膚洗浄剤組成物はいずれも、泡立ちとすすぎ性に優れるとともに、皮膚に対して低刺激性であり、しかも水不溶性粒子の安定性が良好である。 Each of the skin cleansing compositions obtained in Examples 10 and 11 is excellent in foaming and rinsing properties, has low irritation to the skin, and has good stability of water-insoluble particles.
Claims (9)
(A)脂肪酸及びその塩を合計で20〜50質量%
(B)水不溶性粒子、
を含有し、成分(A)を構成する脂肪酸の組成が、炭素数15以下の脂肪酸と炭素数16以上の脂肪酸の質量比が20:80〜40:60であり、かつ脂肪酸の平均分子量が255以上であって、液状、クリーム状又はペースト状の形態である皮膚洗浄剤組成物。 The following components (A) and (B):
(A) 20-50 mass% of fatty acids and salts thereof in total
(B) water-insoluble particles,
And the composition of the fatty acid constituting the component (A) is such that the mass ratio of the fatty acid having 15 or less carbon atoms and the fatty acid having 16 or more carbon atoms is 20:80 to 40:60, and the average molecular weight of the fatty acid is 255 or der I, liquid, creamy or pasty skin cleansing composition in the form.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004355114A JP3930014B2 (en) | 2004-12-08 | 2004-12-08 | Skin cleanser composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004355114A JP3930014B2 (en) | 2004-12-08 | 2004-12-08 | Skin cleanser composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006160673A JP2006160673A (en) | 2006-06-22 |
JP3930014B2 true JP3930014B2 (en) | 2007-06-13 |
Family
ID=36663090
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004355114A Active JP3930014B2 (en) | 2004-12-08 | 2004-12-08 | Skin cleanser composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3930014B2 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009275010A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
JP5536086B2 (en) * | 2009-10-06 | 2014-07-02 | ライオン株式会社 | Liquid skin cleanser composition |
CN102647975B (en) | 2009-12-08 | 2014-07-30 | 花王株式会社 | Skin cleansing agent |
JP5734574B2 (en) * | 2010-02-25 | 2015-06-17 | ポーラ化成工業株式会社 | Aqueous cleaning material |
JP6074492B1 (en) * | 2015-12-24 | 2017-02-01 | 資生堂ホネケーキ工業株式会社 | Granulated powder |
JP7058884B2 (en) * | 2019-04-16 | 2022-04-25 | 株式会社ナノエッグ | Skin cleansing composition |
-
2004
- 2004-12-08 JP JP2004355114A patent/JP3930014B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
JP2006160673A (en) | 2006-06-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6641825B2 (en) | Skin cleansing gel having a heating effect | |
JP5562820B2 (en) | Skin cleanser | |
US20080139433A1 (en) | Mixtures And Method For Cleaning Surfaces | |
JP2007527921A (en) | Personal cleansing composition | |
JP5522828B2 (en) | Skin cleanser | |
JP2008031187A (en) | Disintegrative particle | |
JP5923409B2 (en) | Skin cleansing composition | |
JP2011162708A (en) | Detergent composition | |
JP3930014B2 (en) | Skin cleanser composition | |
ES2347168T3 (en) | DETERGENT COMPOSITION. | |
JP2015172187A (en) | detergent composition | |
JP5923405B2 (en) | Skin cleansing composition | |
JP2005336068A (en) | Skin detergent composition | |
JP6949056B2 (en) | Skin cleanser composition | |
JP5490440B2 (en) | Skin cleanser composition | |
JP4054799B2 (en) | Skin cleanser composition | |
JP2001278778A (en) | Skin detergent | |
JP2005023069A (en) | Skin-cleansing composition | |
JP2006169453A (en) | Detergent composition | |
JP2588870B2 (en) | Detergent composition | |
JP2001199876A (en) | Skin detergent | |
JP5917204B2 (en) | Skin cleanser composition | |
JP2004189621A (en) | Powdery detergent for face washing | |
JPH11106797A (en) | Disintegrable particle and detergent composition | |
JP6881715B2 (en) | Manufacturing method of granules for skin cleansers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20061117 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20061128 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070129 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20070306 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20070307 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 3930014 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100316 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110316 Year of fee payment: 4 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110316 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120316 Year of fee payment: 5 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120316 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130316 Year of fee payment: 6 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130316 Year of fee payment: 6 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140316 Year of fee payment: 7 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |