JP3924190B2 - Manufacturing method of wood-based composite material - Google Patents

Manufacturing method of wood-based composite material Download PDF

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JP3924190B2
JP3924190B2 JP2002108247A JP2002108247A JP3924190B2 JP 3924190 B2 JP3924190 B2 JP 3924190B2 JP 2002108247 A JP2002108247 A JP 2002108247A JP 2002108247 A JP2002108247 A JP 2002108247A JP 3924190 B2 JP3924190 B2 JP 3924190B2
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wood
composite material
density
heating
based composite
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JP2003300204A (en
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勝仁 高橋
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Sekisui Chemical Co Ltd
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Sekisui Chemical Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は木質系複合材料の製造方法に関する。
【0002】
【従来の技術】
木質系複合材料、例えば、細長い木質材片と結合材の混和物を長手方向に向きを揃えて積層し、加圧・加熱処理することで得られる木質系構造材料(例えば、特公昭50−17512)や木質材片を長さ方向に積層し、マット状にしてから加圧・加熱処理することによって得られる木質系構造材料が知られている(特許登録公報2527761号)。
【0003】
上記木質系材料を加熱・加圧処理する工程において、熱盤により挟み込んでプレスする所謂、伝熱方式による加熱処理の場合、厚みの厚い木質系複合材料の場合は熱盤と接触している表層部分の密度が高く、中心に向かうにつれて密度が低くなる傾向がある。これは熱盤に接触している木質材片が熱により軟化し圧縮されるが、中心部では木質材片の軟化が遅れるため圧縮量が小さくなることが原因であり、得られる木質系複合材料は厚み方向に均質な物に比べると曲げ強度の物性は良くなる。しかしながら、熱伝導による加熱のため厚みのある物を製造する場合、加熱処理に時間がかかってしまい、処理時間が長すぎると表層付近の木質材片が劣化してしまう恐れがある。
【0004】
一方、加熱に蒸気噴射を用いる蒸気プレス方式では、材料の中心まで一気に熱が伝わるため均質な物を短時間で作成することが可能であるが、伝熱プレスのような厚み方向で表層の密度が高く、中心の密度が低い密度分布をもった複合材料を作ることは困難であり、曲げ強度の物性は伝熱方式ほど良くない。
【0005】
【発明が解決しようとする課題】
本発明の目的は、上記従来の木質系複合材料の製造方法上の問題点に鑑みて、なされたものであり、その目的とするところは短時間で厚み方向に密度分布を持った木質系複合材料の製造を可能にする方法を提供することにある。
【0006】
【課題を解決するための手段】
本発明は、細長い木質材片と結合剤の混和物からなりかつ細長い木質材片が、一方向に配向しながら積層することにより木質系マットを形成し、このマットを加熱・加圧工程を経て成形する木質系複合材料の製造方法において、上記加熱・加圧工程が、伝熱方式による加熱・加圧処理を行った後に蒸気噴射方式による加熱処理を行う工程を含むことを特徴とする木質系複合材料の製造方法である。
【0007】
上記木質材片の樹種としては、スギ、ヒノキ、スプルース、ファー、ラジアータパイン等の針葉樹、シラカバ、アピトン、カメレレ、センゴンラウト、アスペン等の広葉樹が挙げられるが、これら森林から生産される植物材料だけでなく、竹、コウリャンといった森林以外で生産される植物材料をも含めることが出来る。
【0008】
利用出来る形態としては、上記樹種の丸太、間伐材等の生材料、工場や住宅建築現場で発生する端材、部材輸送後に廃棄される廃パレット材、建築解体時に発生する解体廃材等が挙げられる。上記原材料を1mmから数百mm程度に細片化したものであれば適用出来る。
【0009】
上記原材料を細長い木質材片に加工する方法としては、ハンマーミル、表面に刃物のついたロールを回転させて木材を破砕する一軸破砕機、回転刃がかみ合った構造の二軸もしくは多軸破砕機等の破砕機が使用されるが、ベニヤ加工したものをスティック状にするロータリーカッター、丸太等を回転刃で切削してストランドにするフレーカー等も使用出来る。特に原料としてリサイクル材を使用する場合、異物が混入し易く刃の耐久性が高いという点で破砕機が好ましい。
【0010】
上記の方法で得られた細長い木質材片はサイズのばらつきがあるので、分級工程によって所定サイズの木質材片を得る。この分級方法としては、ローラースクリーン方式や振動メッシュ方式、風選方式等があり、必要に応じて使い分ければ良い。
【0011】
上記分級された細長い木質材片は、含水率を一定範囲に調整して置くことが好ましい。含水率を一定にすることで生産時の成形品の品質ばらつきがなくなる。好ましい含水率としては0〜14%である。
【0012】
上記分級され含水率を調整された細長い木質材片は、上記結合剤と混合される。結合剤の混和量は、木質材片の密度、形状、表面状態にもよるが、通常は木質材料片の重量に対して、1〜20重量%が好ましい。
【0013】
上記結合剤としては、フェノール樹脂、尿素樹脂、イソシアネート、合板やパーティクルボードに用いられる木材工業用の接着剤等が挙げられ、これらの結合剤は、単独又は複数を併用しても良い。
【0014】
上記木質材片と結合剤の混和手段としては、木質材片と結合剤をヘンシェルミキサーのようなミキサーに投入し混合する方法が挙げられるが、結合剤が液体の場合はコンベア上やドラムブレンダー内等で木質材片に対し、スプレー等の塗布手段を用いることにより、木質材片の表面に結合剤を付着させると、均一で安定した強度の構造材が得られる。
【0015】
上記木質材片と結合剤の混和物は、一定方向へ配向しながら積層することにより木質系マットを形成する。具体的には木質材片を型の中に投入し、積層することで行うことが出来る。一方向に配向させるには、一定間隔に分割されたフォーミング型や、オリエンテッドストランドボード(OSB)等の製造で用いられるディスクオリエンター等の配向積層装置が用いられる。
【0016】
本発明は、上記木質系マットを加熱・加圧成形することにより木質系複合材料を製造するが、加熱・加圧成形に用いられる方式としては木質材片の表面から熱盤等により内部に熱を伝える伝熱方式、及び材料内部を直接加熱する蒸気噴射方式を用いる。伝熱方式による加熱・加圧処理を行った後に蒸気噴射方式による加熱処理を行うことにより表層部分の密度が高く、中心に向かうにつれて密度が低くなる木質系複合材料が得られると共に、短時間で加熱・加圧処理が出来る。
【0017】
上記加熱条件は、100〜250℃が好ましい。また、圧力条件は、1〜10MPaが好ましい。また、加熱・加圧処理時間は、結合剤が硬化する時間だけ行えば良い。
【0018】
【発明の実施の形態】
(実施例1)
以下のプロセスにより木質系複合材料からなる成形体を作成した。
木材廃棄物処理業者から購入したボード用木質材片を、ウェブローラー方式の分級機(ウェブローラースクリーン、たいへい社製)を用いて、厚み1〜15mmの木質材片に分級し、上記木質材片を加熱オーブン(50℃、24時間)にて含水量調整した(含水量は 5.2%)。
【0019】
次に、ドラムブレンダーを用いて上記木質材片と結合剤をブレンドした。まず、ドラムブレンダーに木質材片を投入し、結合剤としてイソシアネート系接着剤(木質材片に対して5%)を塗布した。次にブレンドされた結合剤と木質材片を木質材片の供給装置に投入し、フォーミング(配向・積層)を行った。フォーミング金型は、縦2000mm、横500mm、高さ100mmであり、金属製の配向板(鋼、厚み2mm)を用いて、50mm間隔に10等分した。これにより厚さ約100mmの木質系マットを得た。
【0020】
次に、フォーミング金型を取り外して木質系マットを加熱プレス機へ投入した。上記加熱プレス機には縦2500mm、横500mm、高さ150mmの金型を用い、伝熱タイプ(川崎油工社製、300tプレス機)を用いた。上記伝熱方式による処理条件は、温度180℃、圧力3MPaで5分間行った。その後、加圧力は一定条件で、0.9MPa、180℃の蒸気を噴射し、その蒸気圧を1分間保持して木質系複合材料の成形体を得た。次に前記成形体を6面カットし、1500×400×25mmの成形体を得た。前記成形体断面を観察したところ、表層部の密度は約0.8、中心部の密度は約0.7で全体としての密度は0.75であった。
【0021】
(実施例2)
上記実施例1において、伝熱方式による加熱・加圧処理の後、一旦圧力を抜いて0.9MPaの蒸気噴射をすると同時に再び加圧を開始し、180℃、3MPaにて伝熱方式にて成形したこと以外は実施例1と同様にして木質系複合材料の成形体を得た。成形品の断面を観察したところ表層部の密度は約0.8、中心部の密度は約0.7、全体としての密度は0.76であった。
【0022】
(比較例1)
伝熱方式による加熱・加圧処理を行わなかったこと以外は、実施例1と同様に行った。すなわち、0.9MPa、180℃の蒸気を噴射し、蒸気圧を1分間保持して木質系複合材料の成形体を得た。成形品は密度分布がなく全体に均質で密度は、0.76であった。
【0023】
(比較例2)
実施例1において、伝熱方式による処理時間を30分間行い、その代わりに蒸気噴射方式による加熱・加圧処理は行わなかったこと以外の条件は実施例1と同様にして木質系複合材料の成形体を得た。断面を観察したところ表層部の密度が0.8程度、中心部の密度が約0.7で全体としては密度が0.75であった。上記サンプルの曲げ強度、弾性率を評価して、その結果を表1に示した。尚、密度、曲げ強度、曲げ弾性率の測定は、JIS Z2101に準拠し測定した。
【0024】
【表1】

Figure 0003924190
【0025】
【発明の効果】
蒸気噴射が可能なプレス機を用いて、所定の時間伝熱方式による加熱・加圧処理を行った後、さらに蒸気噴射方式で加熱・加圧処理を行ったことで、表層付近の木質材片が劣化することなく、厚み方向で表層の密度が高く中心の密度が低い密度分布をもった木質系複合材料を短時間で作ることが可能となる。
従って、表層の密度が高く、中心の密度が低い密度分布をもった複合材料を短時間で得ることが出来、これらは曲げ強度の高い成形体としての特性を有するものである。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for producing a wood-based composite material.
[0002]
[Prior art]
A wood-based composite material, for example, a wood-based structural material (for example, Japanese Patent Publication No. 50-17512) obtained by laminating a mixture of elongated wood material pieces and a binding material in the longitudinal direction, and applying pressure and heat treatment. ) And a wood-based structural material obtained by laminating wooden material pieces in the length direction, forming a mat, and then applying pressure and heat treatment (Japanese Patent No. 2527761).
[0003]
In the process of heating / pressurizing the above wood-based material, in the case of heat treatment by the so-called heat transfer method in which the wood material is sandwiched and pressed by a hot plate, in the case of a thick wood-based composite material, the surface layer in contact with the hot platen The density of the part is high, and the density tends to decrease toward the center. This is because the wooden piece in contact with the hot plate is softened and compressed by heat, but in the center the softening of the wooden piece is delayed and the amount of compression is reduced. Compared to a material that is homogeneous in the thickness direction, the physical properties of the bending strength are improved. However, when a thick product is produced due to heating by heat conduction, the heat treatment takes time, and if the treatment time is too long, the wood material pieces near the surface layer may be deteriorated.
[0004]
On the other hand, in the steam press method using steam injection for heating, heat is transferred to the center of the material at a stretch, so it is possible to create a homogeneous product in a short time, but the density of the surface layer in the thickness direction as in the heat transfer press However, it is difficult to produce a composite material having a high density and a density distribution with a low center density, and the physical properties of bending strength are not as good as those of the heat transfer system.
[0005]
[Problems to be solved by the invention]
The object of the present invention has been made in view of the above problems in the conventional method for producing a wood-based composite material, and the object of the present invention is a wood-based composite having a density distribution in the thickness direction in a short time. The object is to provide a method enabling the production of materials.
[0006]
[Means for Solving the Problems]
The present invention comprises a mixture of elongated wooden pieces and a binder, and the elongated wooden pieces are laminated while being oriented in one direction to form a wooden mat, and this mat is subjected to a heating and pressing process. In the method for producing a wood-based composite material to be molded, the heating / pressurizing step includes a step of performing a heat treatment by a steam injection method after performing a heating / pressurization treatment by a heat transfer method. It is a manufacturing method of a composite material.
[0007]
Tree species of the above-mentioned wood lumber include conifers such as cedar, cypress, spruce, fur, and radiatapine, and broad-leaved trees such as birch, apton, chamelere, sengonlaut, and aspen, but only plant materials produced from these forests In addition, plant materials produced outside the forest, such as bamboo and sorghum, can also be included.
[0008]
Available forms include logs of the above tree species, raw materials such as thinned wood, scraps generated at factories and residential building sites, waste pallet materials discarded after transportation of members, demolition waste materials generated at the time of building demolition, etc. . Any material can be used as long as the raw material is cut into pieces of about 1 mm to several hundred mm.
[0009]
As a method of processing the above raw materials into elongated wooden pieces, a hammer mill, a uniaxial crusher that crushes wood by rotating a roll with a blade on the surface, a biaxial or multiaxial crusher with a structure in which rotating blades are engaged However, it is also possible to use a rotary cutter that makes a veneer processed stick into a stick shape, a flaker that cuts a log or the like with a rotary blade into a strand, and the like. In particular, when a recycled material is used as a raw material, a crusher is preferable in that foreign matters are easily mixed and the durability of the blade is high.
[0010]
Since the elongated wooden piece obtained by the above method has a variation in size, a wooden piece of a predetermined size is obtained by a classification process. As the classification method, there are a roller screen method, a vibrating mesh method, a wind selection method, and the like, which may be used properly as necessary.
[0011]
It is preferable that the classified and slender wood pieces are placed with the moisture content adjusted to a certain range. By keeping the moisture content constant, there is no variation in the quality of the molded product during production. A preferable water content is 0 to 14%.
[0012]
The long and slender wood pieces that have been classified and adjusted in water content are mixed with the binder. Although the amount of the binder to be mixed depends on the density, shape and surface state of the wood piece, it is usually preferably 1 to 20% by weight with respect to the weight of the wood piece.
[0013]
Examples of the binder include phenol resins, urea resins, isocyanates, wood industry adhesives used for plywood and particle boards, and these binders may be used alone or in combination.
[0014]
Examples of the means for mixing the wood piece and the binder include a method in which the wood piece and the binder are put into a mixer such as a Henschel mixer and mixed. However, when the binder is liquid, it is on a conveyor or in a drum blender. When a binder is attached to the surface of the wood material piece by using an application means such as spray on the wood material piece, etc., a structural material having a uniform and stable strength can be obtained.
[0015]
The mixture of the wood piece and the binder is laminated while being oriented in a certain direction to form a wood mat. Specifically, it can be performed by putting wooden pieces into a mold and laminating them. In order to orient in one direction, an orientation laminating apparatus such as a forming type divided at regular intervals or a disk orienter used in the manufacture of an oriented strand board (OSB) or the like is used.
[0016]
In the present invention, a wood-based composite material is produced by heating and pressure-molding the above-mentioned wood-based mat. As a method used for heating and pressure-molding, heat is applied from the surface of the wood material piece to the inside by a hot platen or the like. A heat transfer system that transmits heat and a steam injection system that directly heats the inside of the material are used. By performing heat treatment and heat treatment by heat transfer method and then heat treatment by steam injection method, the density of the surface layer part is high, and a wood-based composite material that decreases in density toward the center is obtained, and in a short time Heating and pressurization can be performed.
[0017]
As for the said heating conditions, 100-250 degreeC is preferable. The pressure condition is preferably 1 to 10 MPa. The heating / pressurizing treatment time may be performed only for the time during which the binder is cured.
[0018]
DETAILED DESCRIPTION OF THE INVENTION
Example 1
A molded body made of a wood-based composite material was prepared by the following process.
Using the web roller type classifier (web roller screen, manufactured by Taihei Co., Ltd.), the wooden piece of board purchased from a wood waste disposal contractor is classified into a wooden piece of 1 to 15 mm in thickness, and the above wooden piece The water content of the piece was adjusted in a heating oven (50 ° C., 24 hours) (water content was 5.2%).
[0019]
Next, the wooden piece and the binder were blended using a drum blender. First, a wooden piece was put into a drum blender, and an isocyanate adhesive (5% with respect to the wooden piece) was applied as a binder. Next, the blended binder and the wood piece were put into a wood piece supply apparatus, and forming (orientation / laminating) was performed. The forming mold had a length of 2000 mm, a width of 500 mm, and a height of 100 mm, and was divided into 10 equal portions at intervals of 50 mm using a metal orientation plate (steel, thickness 2 mm). As a result, a woody mat having a thickness of about 100 mm was obtained.
[0020]
Next, the forming mold was removed and the wood mat was put into a heating press. A metal mold having a length of 2500 mm, a width of 500 mm, and a height of 150 mm was used as the heating press machine, and a heat transfer type (300 t press machine manufactured by Kawasaki Yoko Co., Ltd.) was used. The treatment conditions by the heat transfer method were 5 minutes at a temperature of 180 ° C. and a pressure of 3 MPa. Thereafter, 0.9 MPa, 180 ° C. steam was injected under a constant pressure, and the vapor pressure was maintained for 1 minute to obtain a molded body of a wood-based composite material. Next, the molded body was cut into six faces to obtain a molded body of 1500 × 400 × 25 mm. When the cross section of the molded product was observed, the density of the surface layer portion was about 0.8, the density of the central portion was about 0.7, and the overall density was 0.75.
[0021]
(Example 2)
In Example 1 above, after the heating / pressurizing process by the heat transfer method, the pressure is once released and 0.9 MPa of steam is injected, and at the same time, pressurization is started again, and the heat transfer method is performed at 180 ° C. and 3 MPa. Except that it was molded, a wood-based composite material molded body was obtained in the same manner as in Example 1. When the cross section of the molded product was observed, the density of the surface layer portion was about 0.8, the density of the central portion was about 0.7, and the overall density was 0.76.
[0022]
(Comparative Example 1)
It carried out similarly to Example 1 except not having performed the heating and pressurizing process by the heat-transfer system. That is, 0.9 MPa, 180 ° C. steam was injected, and the vapor pressure was maintained for 1 minute to obtain a molded body of a wood-based composite material. The molded product had no density distribution and was homogeneous throughout, and the density was 0.76.
[0023]
(Comparative Example 2)
In Example 1, the processing time by the heat transfer method is performed for 30 minutes, and the molding of the wood-based composite material is performed in the same manner as in Example 1 except that the heating / pressurizing process by the steam injection method is not performed. Got the body. When the cross section was observed, the density of the surface layer portion was about 0.8, the density of the central portion was about 0.7, and the density as a whole was 0.75. The bending strength and elastic modulus of the sample were evaluated, and the results are shown in Table 1. In addition, the measurement of a density, bending strength, and a bending elastic modulus was measured based on JISZ2101.
[0024]
[Table 1]
Figure 0003924190
[0025]
【The invention's effect】
Using a press machine capable of steam injection, after heating and pressurizing treatment by heat transfer method for a predetermined time, and further by heating and pressurizing treatment by steam injection method, wood material pieces near the surface layer It is possible to make a wood-based composite material having a density distribution in which the surface layer density is high and the center density is low in the thickness direction without deterioration.
Accordingly, a composite material having a density distribution with a high surface layer density and a low density at the center can be obtained in a short time, and these have properties as a molded article having a high bending strength.

Claims (1)

細長い木質材片と結合剤の混和物からなりかつ細長い木質材片が、一方向に配向しながら積層することにより木質系マットを形成し、このマットを加熱・加圧工程を経て成形する木質系複合材料の製造方法において、
上記加熱・加圧工程が、伝熱方式による加熱・加圧処理を行った後に蒸気噴射方式による加熱処理を行う工程を含むことを特徴とする木質系複合材料の製造方法。
A wood system consisting of a mixture of elongated wood pieces and a binder, and the elongated wood pieces are laminated while being oriented in one direction to form a wood-based mat, and this mat is formed through a heating and pressing process. In the method for producing a composite material,
The method for producing a wood-based composite material, wherein the heating / pressurizing step includes a step of performing a heat treatment by a steam injection method after performing a heating / pressurization treatment by a heat transfer method.
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EA019400B1 (en) * 2010-02-24 2014-03-31 Научно-Исследовательское Учреждение "Институт Прикладных Физических Проблем Им. А.Н. Севченко" Белорусского Государственного Университета (Ниипфп Им. А.Н. Севченко Бгу) Method for fabricating heat-insulating polymer composite
EA019401B1 (en) * 2010-02-24 2014-03-31 Научно-Исследовательское Учреждение "Институт Прикладных Физических Проблем Им. А.Н. Севченко" Белорусского Государственного Университета (Ниипфп Им. А.Н. Севченко Бгу) Method for fabricating constructive polymer composite

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