JP3909132B2 - Cosmetic additives - Google Patents
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- JP3909132B2 JP3909132B2 JP28269097A JP28269097A JP3909132B2 JP 3909132 B2 JP3909132 B2 JP 3909132B2 JP 28269097 A JP28269097 A JP 28269097A JP 28269097 A JP28269097 A JP 28269097A JP 3909132 B2 JP3909132 B2 JP 3909132B2
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Description
【０００１】
【発明の属する技術分野】
本発明は化粧品用添加剤に関するものであり、詳しくは、ポリエーテルアミド変性オルガノポリシリキサンを主成分とする貯蔵安定性、帯電防止性に優れた化粧品用添加剤であり、特に、化粧品への配合安定性に優れ、良好な使用感、表面保護性、透明配合性、帯電防止性、表面潤滑性を与え得るポリエーテルアミド変性オルガノポリシロキサンを非イオン系界面活性剤により水中に乳化してなるエマルジョン型の化粧品用添加剤に関するものである。
【０００２】
【従来の技術】
従来、繊維工業分野では柔軟剤、化粧品工業分野ではコンディショニング剤、塗料工業分野では水性インキによるピーピング防止剤などとしてシリコーンエマルジョンが使われている。水系における発泡は各種工業において、トラブルの原因となっており、特にパルプ製造工業においては廃液中に多量の発泡性物質が含まれるため、発泡が重要な問題となっている。このため、脂肪酸アミド、油溶性有機重合体、炭化水素油、脂肪からなる消泡組成物（特公昭４７−７３５９号参照）、特定量の油、急冷アミド、疎水性シリカ、重合体、乳化剤、シリコーン系界面活性剤、ホルムアルデヒドおよび水を含有する水性脱泡剤（米国特許４２２５４５６号および特開昭５６−７０３０８号参照）、有機液体、シリコーン油、疎水性シリカ、変性シリコーン油、乳化剤、水からなる消泡剤組成物（特開平６−３９２０７号参照）が提案されているが、これらは必ずしも消泡性能が充分ではなく、ピッチの発生や安定性に問題があった。また、化粧料には、皮膚の乾燥防止や毛髪表面の保護のため、油分が配合されているが、近年、軽い使用感が望まれているため、ジメチルポリシロキサンが広く使用されている。しかし、この種のジメチルポリシロキサンは、水やその他の油剤との相溶性が充分でないため、例えば、化粧料への配合が難しく、安定性が損なわれ易いという問題があった。また、独特の油性感を有し、しっとり感に欠ける、きしみ感が強い等の使用感にも問題があった。さらに、皮膚や毛髪の表面から流され易いという欠点もあった。また、これらの変性オルガノポリシロキサンとは別に、アミド変性オルガノポリシロキサンに関連する従来技術としてはポリアミド変性オルガノポリシロキサンの原料であるアミノ基含有オルガノポリシロキサンとポリオキシエチレン脂肪酸とをトルエンに溶解された組成物を繊維処理剤として使用する方法が提案されている（特開平１−３０６６８２号公報参照）。また、脂肪族アミド変性オルガノポリシロキサンと界面活性剤と水となり得るエマルジョンを衣料の洗浄剤として使用する方法が提案されている。しかし、一般に、脂肪族アミド変性ポリシロキサンは疎水性が高く貯蔵安定性に劣り、長期間保管しておくと分離・凝集等の変質を受け易いとされていることから、脂肪族アミド変性オルガノポリシロキサンそのもののエマルジョンを表面改質剤として適用する方法は実用化されておらず知られていない。
【０００３】
【発明が解決しようとする課題】
本発明者らは、上記問題を解消するために鋭意検討した結果、本発明に到達した。
即ち、本発明の目的は、ポアリエーテルアミド変性オルガノポリシロキサンを主成分とする貯蔵安定性、帯電防止性に優れたエマルジョン型の化粧品用添加剤であり、特に、化粧品への配合安定性に優れ、良好な使用感、透明配合性、表面保護性、制電防止性、表面潤滑性等の表面改質効果を与え得るエマルジョン型の化粧品用添加剤を提供することにある。
【０００４】
【課題を解決するための手段】
本発明の課題は、（Ａ）一般式：
【化１】
で表されるポリエーテルアミド変性オルガノポリシロキサン １００重量部、
（Ｂ）非イオン系界面活性剤 １〜１００重量部 および
（Ｃ）水 ３〜１０００重量部からなり、(Ａ)成分が(Ｂ)成分により(Ｃ)成分中に乳化されてなるエマルジョン組成物であり、(Ａ)成分の含有量が１０〜６０重量％の範囲内にあることを特徴とすることを特徴とする化粧品用添加剤によって達成される。
【０００５】
以下、本発明を詳細に説明する。
本発明に使用される（Ａ）成分のオルガノポリシロキサンは、
（Ａ）一般式：
【化１】
で表されるポリエーテルアミド変性オルガノポリシロキサンである。
【０００６】
このようなポリエーテルアミド変性オルガノポリシロキサンとして、具体的には次に示されるような化学構造を有する化合物が例示される。
【化７】
【０００７】
本発明に使用される（Ｂ）成分の乳化剤は、ポリオキシアルキレンアルキルエーテル，ポリオキシアルキレンアルキルフェノールエーテル，ポリオキシアルキレンアルキルエステル，ポリオキシアルキレンソルビタンアルキルエステル等の非イオン系界面活性剤である。非イオン系界面活性剤は、１種単独で使用してもよく、２種またはそれ以上を組み合わせたものを使用してもよい。本成分の配合量は(Ａ)成分１００重量部に対して１〜１００重量部の範囲である。
【０００８】
(Ｃ)成分の水は、(Ａ)成分を(Ｂ)成分の存在下で分散させるための分散媒となるものである。本成分の配合量は、(Ａ)成分１００重量部に対して３〜１０００重量部である。
【０００９】
また、本発明のポリエーテルアミド変性オルガノポリシロキサンを非イオン系界面活性剤により水中に乳化させてなる化粧品用添加剤には、上記(Ａ)成分，(Ｂ)成分，(Ｃ)成分に加えて、必要に応じて本発明の目的を損なわない範囲で、他の任意成分を配合することができる。例えば、酸化防止剤、ｐＨ調製剤、殺菌剤、増粘剤、防腐剤等がある。尚、本発明の化粧品用添加剤に各種の添加剤を加えて、化粧品を製造する場合、あるいは本発明の化粧品用添加剤を化粧品に添加配合してそれらの表面改質特性を向上させる場合には、本発明の化粧品用添加剤の含有量が０.１〜 ９９.９重量％の範囲内、好ましくは１〜９９重量％の範囲内になるようにすればよい。
【００１０】
本発明のポリエーテルアミド変性オルガノポリシロキサンを非イオン系界面活性剤により水中に乳化させてなる混合物において、(Ａ)成分の含有量は、１０〜６０重量％の範囲内にあることが必要である。
【００１１】
以上のような本発明の化粧品用添加剤は、それ自体が表面感触性，表面保護性，表面潤滑性，貯蔵安定性に優れ、長期間に渡って変質することがなく、化粧品への配合安定性に優れているので、これらへ添加配合すればその表面改質特性を大幅に向上させることができる。したがって、化粧品の各種表面特性を向上させるための、化粧品用添加剤として有用である。
【００１２】
【実施例】
以下、実施例および応用例により本発明を詳細に説明する。なお、評価方法を下記に記す。粘度は２５℃における測定値であり、ｃｓはセンチストークスである。
【００１３】
○貯蔵安定性試験
調製した化粧品用添加剤または化粧料５０ｃｃを透明ガラスびんに入れ、５０℃の温度条件下で１日間静置した後、その状態を目視により観察した。評価基準は次の通りである。
貯蔵安定性評価基準
Ａ：均一であり、変化がなかった。
Ｂ：わずかにオイル状物が分離した。
Ｃ：オイル状物が分離した。
Ｄ：オイル粒が発生して分離した。
○帯電防止性試験
長さ１５ｃｍの毛髪１５ｇを束ね、調製した化粧品用添加剤または化粧料を全体に塗布し、ついで３０秒間流水ですすいだ後、タオルで水気をふき取った。次いで、ドライヤーで乾燥させ、塩化ビニル樹脂板で１００回擦り、毛髪の状態を以下の評価基準で評価した。
帯電防止性評価基準
Ａ：毛髪が広がらなかった。
Ｂ：毛髪がやや広がった。
Ｃ：毛髪が広がった。
Ｄ：毛髪が逆立った。
○皮膚化粧料使用感試験
パネラー１０人の前腕内側に調製した化粧品用添加剤または化粧料を均一に塗布し、皮膚の柔軟性、平滑性および油性感について以下の評価基準で官能評価した。
評価基準
Ａ：非常に良好であった。
Ｂ：やや良好であった。
Ｃ：やや悪かった。
Ｄ：非常に悪かった。
○毛髪化粧料使用感試験
長さ１５ｃｍの毛髪１５ｇを束ね、調製した化粧品用添加剤または化粧料を全体に塗布し、ついで３０秒間流水ですすいだ後、タオルで水気をふき取った。次いで、櫛で湿潤状態の毛髪を梳いてきしみ感を以下の評価基準で官能評価した。次にタオルで水気をふき取った毛髪をドライヤーで乾燥した後、毛髪の柔軟性、平滑性および油性感について以下の評価基準で官能評価した。
評価基準
Ａ：非常に良好であった。
Ｂ：やや良好であった。
Ｃ：やや悪かった。
Ｄ：非常に悪かった。
【００１４】
【実施例１】
【化１１】
で示されるポリエーテルアミド変性オルガノポリシリキサンを８５ｇ、ポリオキシエチレン（５）アルキルエーテル１５ｇ、ポリオキシエチレン（７）アルキルエーテル３０ｇをかくはん機を付した１Ｌビーカーに入れ、かくはんしながら水４７０ｇを徐々に加え、エマルジョン組成物である化粧品用添加剤を得た。得られたエマルジョン組成物は透明な化合物で、室温１ヶ月後も分離、凝集は見られず安定であった。
【００１５】
【比較例１】
実施例１において、ポリエーテルアミド変性オルガノポリシリキサンの代わりに
【化１２】
で示されるアミノ変性オルガノポリシロキサンを用いた以外は実施例１と同様にして、エマルジョン組成物である化粧品用添加剤を得た。得られたエマルジョン組成物は白濁状であったが、室温１ヶ月後も分離、凝集は見られず安定であった。
【００１６】
【比較例２】
実施例１において、ポリエーテルアミド変性オルガノポリシリキサンの代わりに粘度２００ｃｓのジメチルポリシリキサンを用いた以外は実施例１と同様にして、エマルジョン組成物である化粧品用添加剤を得た。得られたエマルジョン組成物は乳化安定性に劣り、調整後１時間で、油相が分離した。
【００１７】
【応用例１】
実施例１のエマルジョン組成物１０重量部、ステアリン酸０.５重量部、セタ ノール１.５重量部、ワセリン３重量部、ラノリンアルコール２重量部、ポリオ キシエチレン（１０）モノオレート２重量部、プロピレングリコール３重量部、トリエタノールアミン１重量部、水７５重量部を均一に混合して皮膚化粧料を調製した。次いで、この皮膚化粧料の貯蔵安定性試験、帯電防止性試験、皮膚化粧料としての使用感試験を行った。これらの測定結果を後述する表１に示した。
【００１８】
【比較応用例１】
応用例１において実施例１のエマルジョン組成物の代わりに比較例１のエマルジョン組成物を配合した以外は応用例１と同様にして皮膚化粧料を調製した。この皮膚化粧料の特性を応用例１と同様にして評価し、それらの測定結果を後述する表１に示した。
【００１９】
【比較応用例２】
応用例１において実施例１のエマルジョン組成物の代わりに比較例２のエマルジョン組成物を配合した以外は応用例１と同様にして皮膚化粧料を調製した。この皮膚化粧料の特性を応用例１と同様にして評価し、それらの測定結果を後述する表１に示した。
【００２０】
【表１】
【応用例２】
実施例１のエマルジョン組成物４重量部、塩化ステアリルトリメチルアンモニウム４重量部、セタノール３重量部、プロピレングリコール５重量部、水８４重量部を均一に混合して毛髪化粧料を調製した。次いで、この毛髪化粧料の貯蔵安定性試験、帯電防止性試験、毛髪化粧料としての使用感試験を行った。これらの測定結果を後述する表２に示した。
【００２２】
【比較応用例３】
応用例２において実施例１のエマルジョン組成物の代わりに比較例１のエマルジョン組成物を配合した以外は応用例２と同様にして毛髪化粧料を調製した。この毛髪化粧料の特性を応用例２と同様にして評価し、それらの測定結果を後述する表２に示した。
【００２３】
【比較応用例４】
応用例２において実施例１のエマルジョン組成物の代わりに比較例２のエマルジョン組成物を配合した以外は応用例２と同様にして毛髪化粧料を調製した。この毛髪化粧料の特性を応用例２と同様にして評価し、それらの測定結果を後述する表２に示した。
【００２４】
【表２】
表１、２に示されるように、実施例のエマルジョン組成物を添加した皮膚化粧料、毛髪化粧料は、良好な使用感を示し、安定性にも優れている。
【００２６】
【応用例３】
実施例１で得られたエマルジョン組成物の貯蔵安定性試験、帯電防止性試験、毛髪化粧料としての使用感試験を行った。これらの測定結果は次の通りであった。
貯蔵安定性 Ａ
帯電防止剤 Ａ
柔 軟 性 Ａ
平 滑 性 Ｂ
油 性 感 Ａ
【００２７】
【発明の効果】
本発明のエマルジョン組成物からなる化粧品用添加剤は、それ自体が表面感触性、表面保護性、表面潤滑性、帯電防止性に優れ、長期間にわたって変質することがないという特徴を有し、また化粧品への配合安定性に優れ良好な使用感、透明配合性、表面保護性、制電防止性、表面潤滑性等の表面改質効果を与え得るという特徴を有する。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to cosmetic additives, particularly, the storage stability as a main component polyetheramide-modified organopolysiloxane policy Riki San is an excellent cosmetic additive antistatic properties, in particular, cosmetics excellent formulation stability, good feeling, surface protection, transparency miscibility, antistatic properties, and emulsifying the polyetheramide-modified organopolysiloxane may provide surface lubricity to the water by a nonionic surfactant It is related with the emulsion type cosmetic additive which becomes.
[0002]
[Prior art]
Conventionally, silicone emulsions are used as a softening agent in the textile industry, a conditioning agent in the cosmetics industry, and a peeping prevention agent using aqueous ink in the paint industry. Foaming in an aqueous system is a cause of trouble in various industries, and particularly in the pulp manufacturing industry, foaming is an important problem because a large amount of foaming substances are contained in the waste liquid. For this purpose, a defoaming composition comprising a fatty acid amide, an oil-soluble organic polymer, a hydrocarbon oil, a fat (see Japanese Examined Patent Publication No. 47-7359), a specific amount of oil, a quenched amide, a hydrophobic silica, a polymer, an emulsifier, Aqueous defoaming agent containing silicone surfactant, formaldehyde and water (see US Pat. No. 4,225,456 and JP-A-56-70308), organic liquid, silicone oil, hydrophobic silica, modified silicone oil, emulsifier, water There have been proposed antifoaming compositions (see JP-A-6-39207), but these have not always had sufficient antifoaming performance and have had problems with pitch generation and stability. In addition, oils are blended in cosmetics in order to prevent skin dryness and protect the hair surface, but dimethylpolysiloxane has been widely used in recent years because a light usability is desired. However, since this type of dimethylpolysiloxane is not sufficiently compatible with water and other oil agents, there is a problem that, for example, it is difficult to blend into cosmetics and stability is easily lost. In addition, there was a problem in the feeling of use such as a unique oily feeling, lack of moist feeling, and a strong squeaky feeling. Furthermore, there was also a drawback that it was easily washed away from the surface of the skin or hair. In addition to these modified organopolysiloxanes, as a conventional technique related to amide-modified organopolysiloxane, amino group-containing organopolysiloxane and polyoxyethylene fatty acid, which are raw materials for polyamide-modified organopolysiloxane, are dissolved in toluene. A method of using the above composition as a fiber treating agent has been proposed (see JP-A-1-306682). Further, a method has been proposed in which an emulsion capable of becoming an aliphatic amide-modified organopolysiloxane, a surfactant, and water is used as a cleaning agent for clothing. In general, however, aliphatic amide-modified polysiloxanes are highly hydrophobic and inferior in storage stability and are subject to alterations such as separation and aggregation after long-term storage. A method of applying an emulsion of siloxane itself as a surface modifier has not been put into practical use and is not known.
[0003]
[Problems to be solved by the invention]
The inventors of the present invention have arrived at the present invention as a result of intensive studies to solve the above problems.
It is an object of the present invention, the storage stability as a main component Po ants polyetheramide-modified organopolysiloxane, an excellent emulsion cosmetic additive antistatic properties, in particular, formulation stability in cosmetics It is an object of the present invention to provide an emulsion-type cosmetic additive that is excellent in surface roughness, has a good feeling of use, a transparent compounding property, a surface protection property, an antistatic property, a surface lubricity, and the like.
[0004]
[Means for Solving the Problems]
The subject of this invention is (A) General formula:
[Chemical 1]
100 parts by weight of a polyetheramide-modified organopolysiloxane represented by
(B) of a non-ionic surfactant 1-100 parts by weight and (C) water 3-1000 parts by weight, (A) component (B) ingredients (C) comprising been ized milk in component emulsion It is a composition and is achieved by a cosmetic additive characterized in that the content of component (A) is in the range of 10 to 60 % by weight.
[0005]
Hereinafter, the present invention will be described in detail.
The organopolysiloxane of component (A) used in the present invention is
(A) General formula:
[Chemical 1]
Is a polyetheramide-modified organopolysiloxane represented by the formula:
[0006]
Specific examples of such polyetheramide-modified organopolysiloxane include compounds having the following chemical structure.
[Chemical 7]
[0007]
Used in the present invention component (B) emulsifying agents, polyoxyalkylene alkyl ethers, polyoxyalkylene alkylphenol ethers, polyoxyalkylene alkyl esters, are nonionic surfactants such as polyoxyalkylene sorbitan alkyl ester le . A nonionic surfactant may be used individually by 1 type, and may use what combined 2 or more types . The amount of this component is in the range of 1 to 100 parts by weight per 100 parts by weight of component (A).
[0008]
The water of component (C) serves as a dispersion medium for dispersing component (A) in the presence of component (B). The amount of this component is 3 to 1000 parts by weight per 100 parts by weight of component (A).
[0009]
Furthermore, the cosmetic additive comprising by ized milk in water by polyetheramide-modified organopolysiloxane of the nonionic surfactant of the present invention, the above (A), (B) component, (C) component In addition to the above, other optional components can be blended as necessary within the range not impairing the object of the present invention. Examples include antioxidants , pH adjusters , bactericides , thickeners , preservatives and the like . Incidentally, the addition of various additives to the cosmetic additive of the present invention, when the production of cosmetic products, or improve their surface modification characteristics cosmetic additives of the present invention was added to and blended in cosmetics In such a case, the content of the cosmetic additive of the present invention may be in the range of 0.1 to 99.9% by weight, preferably in the range of 1 to 99% by weight.
[0010]
In the mixing product obtained ized milk in water by polyetheramide-modified organopolysiloxane of the nonionic surfactant of the present invention, the content of the component (A), to be within the scope of 10 to 60 wt% is necessary.
[0011]
Cosmetic additives of the present invention as described above are themselves surface texture, surface protection, surface lubricity, excellent storage stability, without change in properties over a long period of time, to reduction粧products Since the blending stability is excellent, the surface modification characteristics can be greatly improved by adding and blending them. Therefore, for improving various surface characteristics of a cosmetic, it is useful as cosmetic additives.
[0012]
【Example】
Hereinafter, the present invention will be described in detail by way of examples and application examples . The evaluation method is described below. The viscosity is a measured value at 25 ° C., and cs is centistokes.
[0013]
Storage stability test The prepared cosmetic additive or cosmetic 50 cc was placed in a transparent glass bottle and allowed to stand at 50 ° C. for 1 day, and the state was observed visually. The evaluation criteria are as follows.
Evaluation criteria for storage stability A: Uniform and no change.
B: An oily substance slightly separated.
C: Oily matter separated.
D: Oil particles were generated and separated.
○ Antistatic test 15 g of hair having a length of 15 cm was bundled, the prepared cosmetic additive or cosmetic was applied to the whole, then rinsed with running water for 30 seconds, and then wiped off with a towel. Subsequently, it was dried with a dryer, rubbed 100 times with a vinyl chloride resin plate, and the state of the hair was evaluated according to the following evaluation criteria.
Antistatic property evaluation criteria A: The hair did not spread.
B: The hair spread slightly.
C: The hair spread.
D: The hair was standing upside down.
○ Skin cosmetic use feeling test Cosmetic additives or cosmetics prepared on the inner forearms of 10 panelists were uniformly applied, and the skin was softly, smooth and oily according to the following evaluation criteria.
Evaluation criteria A: Very good.
B: Slightly good.
C: Slightly bad.
D: It was very bad.
○ Hair cosmetic use feeling test 15 g of hair having a length of 15 cm was bundled, the prepared cosmetic additive or cosmetic was applied to the whole, then rinsed with running water for 30 seconds, and then wiped off with a towel. Subsequently, the wet feeling of the hair was combed with a comb and sensory evaluation was performed according to the following evaluation criteria. Next, after wiping off the moisture with a towel, the hair was dried with a drier and then subjected to sensory evaluation on the following evaluation criteria for the flexibility, smoothness and oiliness of the hair.
Evaluation criteria A: Very good.
B: Slightly good.
C: Slightly bad.
D: It was very bad.
[0014]
[ Example 1 ]
Embedded image
Into a 1 L beaker equipped with a stirrer, 85 g of a polyetheramide-modified organopolysiloxane represented by the following formula: 15 g of polyoxyethylene (5) alkyl ether and 15 g of polyoxyethylene (7) alkyl ether were added. Gradually added to obtain a cosmetic additive as an emulsion composition. The obtained emulsion composition was a transparent compound and was stable without separation or aggregation even after 1 month at room temperature.
[0015]
[ Comparative Example 1 ]
In Example 1 , instead of the polyetheramide-modified organopolysiloxane,
A cosmetic additive as an emulsion composition was obtained in the same manner as in Example 1 except that the amino-modified organopolysiloxane represented by the formula ( 1) was used. The obtained emulsion composition was cloudy, but was stable with no separation or aggregation after 1 month at room temperature.
[0016]
[ Comparative Example 2 ]
A cosmetic additive as an emulsion composition was obtained in the same manner as in Example 1 except that dimethylpolysiloxane having a viscosity of 200 cs was used in place of the polyetheramide-modified organopolysiloxane in Example 1 . The obtained emulsion composition was inferior in emulsion stability, and the oil phase separated in 1 hour after preparation.
[0017]
[ Application Example 1 ]
10 parts by weight of the emulsion composition of Example 1 , 0.5 parts by weight of stearic acid, 1.5 parts by weight of ethanol, 3 parts by weight of petrolatum, 2 parts by weight of lanolin alcohol, 2 parts by weight of polyoxyethylene (10) monooleate, propylene glycol A skin cosmetic was prepared by uniformly mixing 3 parts by weight, 1 part by weight of triethanolamine and 75 parts by weight of water. Then, the skin cosmetic of the storage stability test, the antistatic property test was conducted usability testing as a skin cosmetic. These measurement results are shown in Table 1 described later.
[0018]
[Comparative Application Example 1 ]
In Application Example 1, except that blending of the emulsion composition of Comparative Example 1 in place of the emulsion composition of Example 1 was prepared to skin cosmetic as in Application Example 1. The properties of this skin cosmetic were evaluated in the same manner as in Application Example 1, and the measurement results are shown in Table 1 described later.
[0019]
[Comparative Application Example 2 ]
In Application Example 1, except that blending of the emulsion composition of Comparative Example 2 in place of the emulsion composition of Example 1 was prepared to skin cosmetic as in Application Example 1. The properties of this skin cosmetic were evaluated in the same manner as in Application Example 1, and the measurement results are shown in Table 1 described later.
[0020]
[Table 1]
[ Application 2 ]
A hair cosmetic was prepared by uniformly mixing 4 parts by weight of the emulsion composition of Example 1 , 4 parts by weight of stearyltrimethylammonium chloride, 3 parts by weight of cetanol, 5 parts by weight of propylene glycol, and 84 parts by weight of water. Was then carried out the hair cosmetic composition of the storage stability test, the antistatic property test, a feeling test of a hair cosmetic. These measurement results are shown in Table 2 described later.
[0022]
[Comparative Application Example 3 ]
In Application Example 2 except that blended emulsion composition Comparative Example 1 in place of the emulsion composition of Example 1 was prepared hair cosmetic in the same manner as in Application Example 2. The properties of this hair cosmetic were evaluated in the same manner as in Application Example 2, and the measurement results are shown in Table 2 described later.
[0023]
[Comparative Application Example 4 ]
A hair cosmetic was prepared in the same manner as in Application Example 2 except that the emulsion composition of Comparative Example 2 was added instead of the emulsion composition of Example 1 in Application Example 2 . The properties of this hair cosmetic were evaluated in the same manner as in Application Example 2, and the measurement results are shown in Table 2 described later.
[0024]
[Table 2]
As shown in Tables 1 and 2, the skin cosmetics and hair cosmetics to which the emulsion compositions of Examples were added showed a good feeling of use and excellent stability.
[0026]
[ Application 3 ]
The emulsion composition obtained in Example 1 was subjected to a storage stability test, an antistatic property test, and a usability test as a hair cosmetic. These measurement results were as follows.
Storage stability A
Antistatic agent A
Softness A
Smoothness B
Oiliness A
[0027]
【The invention's effect】
The cosmetic additive comprising the emulsion composition of the present invention is itself excellent in surface feel, surface protection, surface lubricity, and antistatic properties, and has the characteristics that it does not deteriorate over a long period of time. It has excellent blending stability in cosmetics , and has a feature that it can give surface modification effects such as good usability , transparent blending property, surface protection property, antistatic property, surface lubricity .
Claims (1)
で表されるポリエーテルアミド変性オルガノポリシロキサン １００重量部、
（Ｂ）非イオン系界面活性剤 １〜１００重量部 および
（Ｃ）水 ３〜１０００重量部からなり、(Ａ)成分が(Ｂ)成分により(Ｃ)成分中に乳化されてなるエマルジョン組成物であり、(Ａ)成分の含有量が１０〜６０重量％の範囲内にあることを特徴とする化粧品用添加剤。(A) General formula:
100 parts by weight of a polyetheramide-modified organopolysiloxane represented by
(B) of a non-ionic surfactant 1-100 parts by weight and (C) water 3-1000 parts by weight, (A) component (B) ingredients (C) comprising been ized milk in component emulsion A cosmetic additive, wherein the content of the component (A) is in the range of 10 to 60 % by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28269097A JP3909132B2 (en) | 1997-04-21 | 1997-09-30 | Cosmetic additives |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9-117575 | 1997-04-21 | ||
| JP11757597 | 1997-04-21 | ||
| JP28269097A JP3909132B2 (en) | 1997-04-21 | 1997-09-30 | Cosmetic additives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH115905A JPH115905A (en) | 1999-01-12 |
| JP3909132B2 true JP3909132B2 (en) | 2007-04-25 |
Family
ID=26455670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28269097A Expired - Fee Related JP3909132B2 (en) | 1997-04-21 | 1997-09-30 | Cosmetic additives |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3909132B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3909131B2 (en) * | 1997-04-21 | 2007-04-25 | 東レ・ダウコーニング株式会社 | Cosmetic additives |
| JP3909143B2 (en) * | 1997-04-21 | 2007-04-25 | 東レ・ダウコーニング株式会社 | Cosmetic base |
| AU2003282524B2 (en) * | 2002-10-10 | 2007-06-14 | The Procter & Gamble Company | Hair conditioning composition comprising thickening polymer and cationic surfactant |
| GB0503864D0 (en) * | 2005-02-25 | 2005-04-06 | Dow Corning | Siloxane copolymers |
| JP2020015914A (en) * | 2014-12-15 | 2020-01-30 | ヌーリオン ケミカルズ インターナショナル ベスローテン フェノーツハップＮｏｕｒｙｏｎ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． | Weather resistant aqueous wood coating agent |
| KR20170092683A (en) * | 2014-12-15 | 2017-08-11 | 아크조 노벨 케미칼즈 인터내셔널 비.브이. | Weatherproof aqueous wood coatings |
-
1997
- 1997-09-30 JP JP28269097A patent/JP3909132B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH115905A (en) | 1999-01-12 |
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