JP3754431B2 - Photovoltaic generator - Google Patents

Description

The present invention relates to a photovoltaic power generation apparatus.
In the present specification, a pin junction is a structure in which n-type, i-type and p-type semiconductor layers are sequentially formed from the inside to the outside of a substantially spherical photoelectric conversion element or from the outside to the inside. It must be interpreted as including.

  A typical first prior art includes a photoelectric conversion element made of a crystalline silicon semiconductor wafer. In the first prior art, the process for producing the crystal is complicated and the cost is high. Also, semiconductor wafers are manufactured from single-crystal bulk through processes such as cutting, slicing, and polishing, and the process is complicated, and crystal cutting waste generated in the processes such as cutting, slicing, and polishing is reduced in volume ratio. It becomes about 50% or more and is wasted.

  Another second prior art for solving this problem is an amorphous Si (abbreviated a-Si) thin film. In this second prior art, since the photoelectric conversion layer is formed in a thin film by plasma chemical vapor deposition, steps such as cutting, slicing, and polishing from a single crystal bulk of the prior art are unnecessary, and the deposited film There is an advantage that all of the above can be used as the active layer of the device. On the other hand, the amorphous Si solar cell has a problem that due to the amorphous structure, there are a large number of crystal defects, that is, gap states, inside the semiconductor, and thus there is a light-induced degradation phenomenon and the photoelectric conversion efficiency is lowered. . In order to solve this problem, conventionally, a technology for inactivation by hydrogenation treatment has been developed, and electronic devices such as amorphous Si solar cells can be manufactured.

  However, even with such treatment, it is impossible to eliminate the effect of crystal defects. For example, amorphous Si solar cells still have a crying point that the photoelectric conversion efficiency deteriorates by about 15 to 25%.

  As a new technology to suppress photodegradation that has recently been successful, a stack type solar cell in which the photoelectric active i layer is made extremely thin and the solar cell has two or three junctions has been realized. Succeeded in controlling. It has become apparent that this photodegradation recovers from the photodegradation when the operating temperature of the solar cell is high, and a module technology that operates / operates in such a state is being developed, but it is not sufficient.

  Still another third prior art for solving such a problem is disclosed in, for example, Japanese Patent Publication No. 7-54855. In this third prior art, spherical particles having an n-type Si skin portion on a p-type Si sphere are embedded in a flat aluminum foil having a hole, and the n-type Si skin portion is etched from the back surface of the aluminum foil to the inside. The p-type Si sphere is exposed, and the exposed p-type Si sphere is connected to another aluminum foil to form a solar array.

  In the third prior art, if it is intended to reduce the cost by reducing the amount of high-purity Si used, it is necessary to reduce the outer diameter of the particles and reduce the overall average thickness. In order to improve the conversion efficiency, it is necessary to enlarge the light receiving surface, and in order to enlarge the light receiving surface, the particles are arranged close to each other, so that a large number of particles having a small outer diameter are densely packed. Must be placed and connected to the aluminum foil. As a result, the process of connecting the particles and the aluminum foil becomes complicated, and the cost is inferior.

  The object of the present invention is to reduce the amount of semiconductor material such as high-purity Si, and to facilitate mass production, that is, to enable resource-saving and energy-saving manufacturing, and to be realized at low cost. Is to provide a photovoltaic device with high efficiency and high efficiency.

  Another object of the present invention is to provide a photovoltaic device capable of increasing the concentration ratio.

The present invention includes (a) a substantially spherical shape, a first semiconductor layer and a second semiconductor layer outside the first semiconductor layer, and a part of the first semiconductor layer is exposed from the opening of the second semiconductor layer. A plurality of photoelectric conversion elements that output photovoltaic power from the first and second semiconductor layers;
(B) a support,
An electrically insulated state is formed between the first conductor and the second conductor via an electrical insulator,
A plurality of recesses whose inner surfaces are formed by the first conductor or a coating layer formed on the first conductor are formed adjacent to each other,
The open ends of the recesses are polygonal, and the open ends adjacent to each other are continuous,
A photoelectric conversion element is disposed in each recess, and the photoelectric conversion element is irradiated with reflected light from the first conductor of the recess or the coating layer formed on the first conductor,
The first conductor is electrically connected to the second semiconductor layer of the photoelectric conversion element,
The second conductor includes a support that is electrically connected to the exposed portion of the first semiconductor layer.
Further, the present invention is characterized by being provided in rows at equal pitches.

In the invention, it is preferable that the polygon is a regular hexagon.
According to the present invention, each of the plurality of substantially spherical photoelectric conversion elements is disposed in each of the plurality of recesses of the support, and the inner surface of the recess is formed by the first conductor or the coating layer formed on the first conductor. Thus, external light such as sunlight is directly applied to the photoelectric conversion element, and is reflected by the first conductor on the inner surface of the recess or the coating layer formed on the first conductor to the photoelectric conversion element. Irradiated.

  Since the photoelectric conversion elements are arranged in the recesses, they are provided with a space therebetween, that is, the photoelectric conversion elements are not densely arranged. Therefore, the number of photoelectric conversion elements can be reduced to reduce the amount of high-purity material such as Si constituting the photoelectric conversion elements, and the process of connecting the photoelectric conversion elements and the conductor of the support can be facilitated. can do.

  In addition, the plurality of recesses are formed adjacent to each other, whereby external light is reflected from the inner surface of the recess and irradiates the photoelectric conversion element, so that the light from the outside is effectively used, and the photovoltaic power of the photoelectric conversion element Can be used for the generation of Thus, the generated power per unit area facing the light source of the photoelectric conversion element of the present invention can be increased as much as possible.

  The photoelectric conversion element of the present invention may be made of a single crystal, polycrystal, or amorphous material, and may be made of silicon, compound semiconductor, or other materials. In addition, for example, it may have a Schottky barrier type, a MIS (metal-insulator-semiconductor) type, a homojunction type, a heterojunction type, and other configurations.

  The first semiconductor layer on the center side is partially exposed from the opening of the second semiconductor layer on the outer side, and the photovoltaic force generated during light irradiation is taken out from these first and second semiconductor layers. Can do. The 2nd semiconductor layer of the photoelectric conversion element arrange | positioned at the recessed part of a support body is electrically connected to the 1st conductor of a support body. The exposed portion of the first semiconductor layer inside the photoelectric conversion element is electrically connected to a second conductor provided via an electrical insulator with respect to the first conductor. In the structure in which the first conductor and the second conductor are formed in a planar shape, the plurality of photoelectric conversion elements are connected in parallel by the first and second conductors, and a large current can be derived.

  The photoelectric conversion element may be a true sphere. However, the outer surface of the photoelectric conversion element may be a substantially spherical shape other than the true sphere, even if it is not a true sphere. Although the first semiconductor layer may be formed in a substantially spherical shape, in another embodiment of the present invention, the first semiconductor layer is formed by covering the outer peripheral surface of a core body prepared in advance. Alternatively, it may have a configuration in which the vicinity of the center of the substantially spherical first semiconductor layer is a cavity.

  The opening end of the concave portion is a polygon, that is, a polygon of a triangle or more, and may be a regular hexagon having a honeycomb shape, for example.

  In particular, according to the present invention, as many recesses as possible can be formed in the area facing the light, and therefore, the reflected light from the first conductor on the inner surface of the recess can be reflected and guided to the photoelectric conversion element, The light collection ratio can be increased.

  Further, the present invention is characterized in that the opening ends adjacent to each other of the recesses are continuous in an inverted U shape.

According to the present invention, (a) the first semiconductor layer has a substantially spherical shape, has a first semiconductor layer and a second semiconductor layer outside the first semiconductor layer, and a portion of the first semiconductor layer extends from the opening of the second semiconductor layer. A plurality of photoelectric conversion elements exposed and outputting photovoltaic power from the first and second semiconductor layers;
(B) a support,
An electrically insulated state is formed between the first conductor and the second conductor via an electrical insulator,
A plurality of recesses whose inner surfaces are formed by the first conductor or a coating layer formed on the first conductor are formed adjacent to each other,
Open ends adjacent to each other of the recesses are continuous in an inverted U shape,
A photoelectric conversion element is disposed in each recess, and the photoelectric conversion element is irradiated with reflected light from the first conductor of the recess or the coating layer formed on the first conductor,
The first conductor is electrically connected to the second semiconductor layer of the photoelectric conversion element,
The second conductor includes a support that is electrically connected to the exposed portion of the first semiconductor layer.

  According to the present invention, the concave portions are connected by the inverted U-shaped bent portion, and this also makes it possible to form as many concave portions as possible in the area facing the light, and accordingly, by the first conductor on the inner surface of the concave portion. The reflected light can be reflected and guided to the photoelectric conversion element, and the condensing ratio can be increased.

Further, in the present invention, the concave portion is formed in a tapered shape toward the bottom,
The first and second semiconductor layers of the photoelectric conversion element are electrically connected to the second and first conductors, which are electrically insulated from each other, at or near the bottom of the recess, respectively. .

  According to the invention, the photoelectric conversion element has a structure in which the opening of the second semiconductor layer and a part of the first semiconductor layer exposed from the opening are in one plane.

  According to the present invention, the material of the photoelectric conversion element, particularly the amount of expensive Si used is greatly reduced, and the number of photoelectric conversion elements is further reduced to simplify the connection work process between the photoelectric conversion element and the support, In this way, productivity is improved and costs are reduced. In particular, by using the photoelectric conversion element of the present invention, it can be realized by a resource-saving and energy-saving manufacturing method. Light reflected by the first conductor forming the inner surface of the concave portion of the support or its coating layer, such as sunlight, can be irradiated to the photoelectric conversion element to effectively use the light. The first conductor or the coating layer thereof serves to reflect light and is connected to the second semiconductor layer of the photoelectric conversion element to serve to guide current. The structure of such a support is simple and the productivity is excellent.

  Further, according to the present invention, it is possible to form as many recesses as possible in the area facing the light, and therefore, the reflected light from the first conductor on the inner surface of the recesses can be reflected and guided to the photoelectric conversion element, The light collection ratio can be increased.

  FIG. 1 is an enlarged sectional view of a part of a photovoltaic device 1 according to an embodiment of the present invention, FIG. 2 is a sectional view showing the entire configuration of the photovoltaic device 1, and FIG. 3 is shown in FIG. It is a disassembled perspective view of the photovoltaic device 1 to be obtained. The photovoltaic device 1 basically has a combination 4 consisting of a plurality of photoelectric conversion elements 2 having a substantially spherical shape and a support 3 on which the photoelectric conversion elements 2 are mounted. For example, it is embedded in a filling layer 5 made of PVB (polyvinyl butyral), EVA (ethylene vinyl acetate), etc., and a transparent protective sheet 6 such as polycarbonate is disposed on the filling layer 5 on the light source side such as sunlight. Fixed. A waterproof back sheet 12 made of a synthetic resin material or the like is fixed to the surface of the filling layer 5 opposite to the protective sheet 6 (downward in FIG. 1). Thus, the overall shape of the photovoltaic device 1 is a flat plate shape.

  The photoelectric conversion element 2 includes a first semiconductor layer 7 and a second semiconductor layer 8 located outside the first semiconductor layer 7. An opening 9 is formed in the second semiconductor layer 8. A portion 10 of the first semiconductor layer 7 is exposed downward from FIG. By irradiating light 11 from above in FIG. 1, photovoltaic power is output between the first and second semiconductor layers 7 and 8 of the photoelectric conversion element 2.

  In the support 3, an electrical insulator 15 is sandwiched between the first conductor 13 and the second conductor 14, and thus the first and second conductors 13 and 14 are electrically insulated via the electrical insulator 15. Configured. The first and second conductors 13 and 14 may be, for example, an aluminum foil or other metal sheet. The electrical insulator 15 may be a synthetic resin material such as polyimide, for example, or may be made of another electrical insulating material. The plurality of recesses 17 are formed adjacent to each other, and the inner surface of the recess 17 is formed by the first conductor 13. The photoelectric conversion elements 2 are respectively disposed on the bottoms of the recesses 17.

  FIG. 4 is a plan view of a part of the support 3. The open end 18 of the recess 17 is polygonal, for example, a honeycomb-shaped regular hexagon in this embodiment, and in another embodiment of the present invention, for example, other polygons having a triangular shape or more may be used. Good. In FIG. 4, the length W1 of the opening end 18 may be 2 mm, for example. Each open end 18 adjacent to each other is continuous, that is, the concave portion 17 is connected by an inverted U-shaped bent portion 19 in FIG. As a result, as many recesses 17 as possible can be formed in the area facing the light 11, and thus the reflected light from the first conductor 13 on the inner surface of the recesses 17 can be reflected and guided to the photoelectric conversion element 2, The light collection ratio can be increased.

  The concave portion 17 is formed in a tapered shape, for example, in a parabolic shape as it reaches the bottom. At the bottom of the recess 17, the first semiconductor layer 7 of the photoelectric conversion element 2 is electrically connected to the second conductor 14 of the support 3 through the connection portion 21. The second semiconductor layer 8 of the photoelectric conversion element 2 is electrically connected to the first conductor 13 of the support 3 at the bottom of the recess or its periphery.

  FIG. 5 is a cross-sectional view showing the photoelectric conversion element 31 in a state before being mounted on the support 3 of the photoelectric conversion element 2. The photoelectric conversion element 31 of FIG. 5 has a cross-sectional structure similar to that of FIG. The first semiconductor layer 7 has a spherical shape and is made of n-type Si. The first semiconductor layer 7 may be amorphous, single crystal, or polycrystalline. The second semiconductor layer 8 formed outside the first semiconductor layer 7 is p-type Si. The second semiconductor layer 8 may be amorphous, single crystal, or polycrystalline. If the second semiconductor layer 8 has a wider optical band gap than the first semiconductor layer 7, for example, p-type a-SiC, a wide gap window effect is achieved.

In another embodiment of the present invention, the first semiconductor layer 7 shown in FIG. 5 is realized by a direct transition type semiconductor layer, for example, InAs, CuInSe ₂ , Cu (InGa) Se ₂ having n-type conductivity type, One type selected from the group consisting of CuInS, GaAs, InGaP, and CdTe may be used. A second semiconductor layer 8 is formed on the first semiconductor layer 7 formed by the direct transition semiconductor layer, and the second semiconductor layer 8 is made of a semiconductor AlGaAs, CuInSe ₂ , Cu (p) having a p-type conductivity type. InGa) Se ₂ , GaAs, AlGaP, CdTe, or a similar compound semiconductor group. Thus, a pn junction structure is formed.

  In the step of using an amorphous semiconductor for the first and second semiconductor layers 7 and 8, an i semiconductor layer 69 is formed between the first semiconductor layer 68 and the second semiconductor layer 70 as shown in FIG. A pin junction structure may be formed.

  Next, a method for manufacturing the combination 4 together with the support 3 shown in FIG. 1 using the photoelectric conversion element 31 shown in FIG. 5 will be described.

  FIG. 6 is a cross-sectional view for explaining a method of manufacturing the combination 4 having the photoelectric conversion element 2 and the support 3. After the spherical photoelectric conversion element 2 shown in FIG. 5 is manufactured, the photoelectric conversion element 2 is cut as shown in FIG. In the photoelectric conversion element 2 shown in FIG. 6, a part 10 of the first semiconductor layer 7 is exposed from the opening 9 of the second semiconductor layer 8. The opening 9 is formed in a planar shape in a range where the central angle θ1 is less than 180 °. The central angle θ1 may be 45 to 90 °, for example, and preferably 60 to 90 °. The outer diameter D1 of the photoelectric conversion element 31 may be, for example, less than 0.5 to 2 mmφ, and more preferably 0.8 to 1.2 mmφ. The inner diameter of the opening 9 is indicated by reference numeral D2. The light collection ratio x = S1 / S2 is 2 to 8 times, preferably 4 to 6 times.

  FIG. 7 is a cross-sectional view for explaining a process of cutting the spherical photoelectric conversion element 31 to form the opening 9. The upper portions of the plurality of spherical photoelectric conversion elements 31 are vacuum-sucked by the suction pads 34 and polished by the endless belt-shaped abrasive 35. The abrasive 35 is wound around rollers 36 and 37 and driven to rotate.

  Referring again to FIG. 6, in manufacturing the support 3, a first conductor 13 made of aluminum foil is prepared, and a connection hole 39 is formed in the first conductor 13. The inner diameter D3 of the connection hole 39 is less than the outer diameter D1 of the photoelectric conversion element 2 and is selected to be larger than the inner diameter D2 of the opening 9 of the second semiconductor layer 8 (D1> D3> D2). A thin plate-shaped electrical insulator 15 is prepared, and a connection hole 40 is formed in the electrical insulator 15. The inner diameter D4 of the connection hole 40 is less than the inner diameter D2 of the opening 9 of the photoelectric conversion element 2 (D2> D4). Thus, the first conductor 13 having the connection hole 39 and the electrical insulator 15 having the connection hole 40 are overlapped and bonded and integrated, and the axes of these connection holes 39 and 40 are in a straight line. Furthermore, the 2nd conductor 14 is piled up, adhere | attached and integrated, and the flat support body 3a is formed. In another embodiment of the present invention, the first conductor 13 having the connection hole 39, the electrical insulator 15 having the connection hole 40, and the second conductor 14 are simultaneously overlapped and bonded and integrated. Also good. The thicknesses of the first and second conductors 13 and 14 and the electrical insulator 15 may be 60 μm, for example. The vicinity of the opening 9 of the photoelectric conversion element 2 is fitted into the connection hole 39 and faces the connection hole 40 of the electrical insulator 15. The vicinity of the opening 9 may be placed on the first conductor 13 facing the connection hole 39.

  Referring also to FIG. 1, the outer peripheral surface surrounding the opening 9 of the second semiconductor layer 8 above the opening 9 of the photoelectric conversion element 2 and the first conductor 13 of the support 3 a or 3. A portion in the vicinity of the first connection hole 39, that is, an inner peripheral surface of the first connection hole 39 or a portion surrounding the first connection hole 39 in the vicinity of the first connection hole 39 is electrically connected. A connection portion 44 (see FIG. 1) between the outer peripheral surface of the second semiconductor layer 8 and the first conductor 13 is opposite to the first conductor 13 with respect to the peripheral portion 45 of the virtual plane including the opening 9 (see FIG. 1). This ensures that the first conductor 13 is not in electrical communication with the first conductor 7, and this connection portion 44 is parallel to the virtual plane including the opening 9 and is photoelectrically It exists on the opening 9 side (lower side in FIG. 1) than the virtual plane 47 passing through the center 46 of the conversion element 2.

  Thereafter, the flat support 3a is plastically deformed by pressing, and a plurality of recesses 17 are formed adjacent to each other. The second conductor 14 protrudes upward in FIG. 6 from the connection hole 40 of the electrical insulator 15, that is, is deformed so as to protrude through the connection hole 40 to form the connection portion 21. The height H1 of the support 3 formed in this way may be about 1 mm, for example.

Both of the electrical connection process between the first semiconductor layer 7 and the second conductor 14 and the electrical connection process between the second semiconductor layer 8 and the first conductor 13 are sequentially performed first. Or may be performed simultaneously.
The photoelectric conversion element 2 having the opening 9 is disposed in the recess 17 thus formed.

  In another embodiment of the present invention, the three-layer structure of conductor 13 / insulator 15 / conductor 14 is plastically deformed so that the recess 17 is formed, and then each of the connection holes 39, 40 described above is The support 3 may be manufactured by forming the conductor 13 and the insulator 15 using each kind of laser light.

  FIG. 8 is a simplified perspective view showing a process of disposing the photoelectric conversion element 2 in the recess 17 of the support 3. The photoelectric conversion element 2 that has been cut while being vacuum-sucked by the suction pad 34 in FIG. 7 is conveyed into the recess 17 of the support 3 with the opening 9 facing downward. Be placed. A plurality of, for example, 100 suction pads 34 are provided in a row. After the photoelectric conversion element 2 is disposed in the concave portion 17 by the suction pad 34, the support 3 is moved by one pitch of the concave portion 17 in the traveling direction 42, and the photoelectric conversion element 2 is used by using the suction pad 34 as described above. Is placed in a new recess 17. Such an operation is repeated to arrange the photoelectric conversion elements 2 in all the recesses 17. Thereafter, the photoelectric conversion element 2 is electrically connected to the support 3 at the bottom of the recess 17.

  The first semiconductor layer 7 of the photoelectric conversion element 2 is exposed at the opening 32 and is electrically connected to the connection portion 21 through the connection hole 40 of the second conductor 14. In the second semiconductor layer 8 of the photoelectric conversion element 2, the outer periphery of the upper portion of the opening 9 is electrically connected to the portion near the connection hole 39 of the first conductor 13. Each electrical connection between the first and second conductors 13 and 14 and the second and first semiconductor layers 8 and 7 of the photoelectric conversion element 2 is performed by eutectic crystal using, for example, laser light or conductive paste. Or may be electrically connected using metal bumps. Thus, electrical connection can be made without using lead-containing solder, which is preferable from the viewpoint of environmental protection.

  FIG. 9 is a perspective view illustrating a state in which the combination bodies 4 and 4b including the photoelectric conversion element 2 and the support body 3 are connected. Electrical connection is made at the planar peripheral portions 61 and 61b extending outward of the combination bodies 4 and 4b.

  FIG. 10 is an exploded cross-sectional view of the vicinity of the peripheral portions 61 and 61b of the combination bodies 4 and 4b shown in FIG. On the first conductor 13 of the support 3 of one combination 4, the second conductor 14 of the other support 3 b is overlapped and electrically connected and fixed. Thus, the photovoltaic power generated by the photoelectric conversion elements 2 for each of the plurality of supports 3 and 3b can be connected in series, so that a desired high voltage can be taken out.

  FIG. 11 is a simplified side view showing a state where the combination bodies 4, 4b, 4c are electrically connected. The peripheral part 61b of the other combination 4b is overlapped on or below the peripheral part 61 of the adjacent one of the combinations 4 and electrically connected as described above. Further, the peripheral portion 61b1 on the opposite side of the peripheral portion 61b of the combination 4b is vertically connected to and electrically connected to the peripheral portion 61c of the adjacent combination 4c. In the configuration in which one peripheral portion 61b of the combination body 4b is arranged below the peripheral portion 61b of the combination body 4 as shown in FIG. 11, the other peripheral portion 61b1 is above the peripheral portion 61c of the combination body 4c. In this way, they are connected in the form of two-tiered alternating top and bottom. The length L61 of the peripheral portions 61, 61b; 61b1, 61c overlapping in the left-right direction in FIG. 11 may be, for example, 1 mm.

  FIG. 12 is a cross-sectional view showing an electrical connection structure between adjacent combination bodies 4 and 4b. The peripheral part 61 of one combination 4 rises and the peripheral part 61b of the other combination 4b falls. The conductor 14 in the peripheral part 61 and the conductor 13 in the peripheral part 61b are electrically connected.

  FIG. 13 is a cross-sectional view showing an electrical connection state of the combination bodies 4 and 4b according to another embodiment of the present invention. This embodiment is similar to the embodiment of FIG. 12, but in this embodiment in particular, the conductor 13 of the peripheral portion 61 rising of the combination 4 is connected to the peripheral portion 61b of the combination 4b. The conductor 14 is electrically connected. According to the connection structure shown in FIGS. 12 and 13, the concave portions of the supports 3 and 3b can be brought close to each other, and as many concave portions and photoelectric conversion elements as possible can be arranged in a limited area.

  FIG. 14 is a partial cross-sectional view of a photoelectric conversion element 2 according to another embodiment of the present invention. In FIG. 14 and FIGS. 15 to 20 described later, each semiconductor layer is shown as a flat shape developed in the circumferential direction. The layers are sequentially laminated from the bottom to the top to form a spherical surface.

  In FIG. 14, the n-type microcrystalline (μc) Si layer 63, the n-type polycrystalline (poly) Si layer 64 / p-type a-SiC layer sequentially from the radially inner side to the outer side of the photoelectric conversion element. The structure has a double heterojunction layer of 65 / p type microcrystalline SiC layer 66. The structure of the photoelectric conversion element having such a pn junction is shown in Table 1.

  FIG. 15 is a cross-sectional view of a photoelectric conversion element 2 according to another embodiment of the present invention. Each of the semiconductor layers 68, 69, and 70 has the configuration shown in Table 1 above. In another embodiment of the present invention, n-type single crystal or polycrystalline Si may be used as the semiconductor layer 68 in the photoelectric conversion element 2 of FIG.

  FIG. 16 is a cross-sectional view of a photoelectric conversion element 2 according to another embodiment of the present invention. The specific configuration of each semiconductor layer is as shown in Table 1 above. In another embodiment of the present invention, the semiconductor layers 73 and 74 in FIG. 16 may be n-type crystal Si. The semiconductor layer 74 may be i-type microcrystalline Si.

  FIG. 17 is a cross-sectional view of a photoelectric conversion element 2 according to another embodiment of the present invention. The photoelectric conversion element 2 of FIGS. 17 to 20 has a two-junction stack structure. In another embodiment of the present invention, a photoelectric conversion element 2 having a stack structure of three or more junctions may be used. The specific configuration of each photoelectric conversion element 2 in FIGS. 17 to 20 is as shown in Table 2.

  In FIG. 17, an external cell 82 is formed outside the internal cell 81. The semiconductor layer 84 may be n-type amorphous Si, the semiconductor layer 85 may be p-type microcrystalline Si, and the semiconductor layer 87 may be microcrystalline SiC. The pin junction layer of the semiconductor layer 86 may be configured by sequentially stacking p-type, i-type, and n-type semiconductor layers from the radially inner side to the outer side of the photoelectric conversion element 2. In another embodiment of the present invention, the conductivity type of the semiconductor layers 84 and 85 of the internal cell 81 is reversed from that of FIG. 17, and the conductivity type of the semiconductor layers 86 and 87 of the external cell 82 is reversed from that of FIG. In the layer 86, n-type, i-type, and p-type semiconductor layers may be sequentially formed. This is as described above, and the photoelectric conversion element 2 including the pin junction layer having the other configuration. The same is true for.

  FIG. 18 is a cross-sectional view of a photoelectric conversion element 2 according to another embodiment of the present invention. The internal cell 101 and the external cell 102 are configured by stacking semiconductor layers 103 to 106; 107 to 111.

  FIG. 19 is a cross-sectional view of a photoelectric conversion element 2 according to another embodiment of the present invention. The internal cell 112 and the external cell 113 are configured by stacking semiconductor layers 114 to 117 and 118 to 122. Instead of the semiconductor layer 117, p-type amorphous SiO may be used. Similarly, the semiconductor layer 121 may be p-type amorphous SiO.

FIG. 20 is a cross-sectional view of a photoelectric conversion element 2 according to still another embodiment of the present invention. In the internal cell 124 and the external cell 125, semiconductor layers 126 to 129 and 130 to 134 are formed. Instead of the semiconductor layer 129, p-type amorphous SiO may be used.
The photoelectric conversion element 2 of the present invention may have a configuration other than the above-described configuration.

  In another embodiment of the present invention, instead of the support 3, a recess is formed by injection molding such as an electrically insulating synthetic resin material such as polycarbonate, and a conductive material such as Ni is formed on the surface thereof. May be plated to form first and second conductors to produce a support. The first and second conductors may be, for example, an aluminum foil, but may be formed by Cr plating or Ag plating. Further, these metals Ni, Cr, Al, Ag, etc. are deposited or sputtered. It may be formed. A coating layer may be formed on the first conductor, and this coating layer may be made of metal formed by plating or the like, or may be made of synthetic resin.

The following embodiments are possible for the present invention.
(1) (a) It has a substantially spherical shape, has a first semiconductor layer and a second semiconductor layer outside the first semiconductor layer, and a part of the first semiconductor layer is exposed from the opening of the second semiconductor layer. A plurality of photoelectric conversion elements that output photovoltaic power from the first and second semiconductor layers, and (b) a support body between the first conductor and the second conductor via an electrical insulator, A plurality of recesses are formed adjacent to each other, and the inner surface is formed by the first conductor or a coating layer formed on the first conductor, and a photoelectric conversion element is disposed in each recess. The reflected light from the first conductor of the recess or the coating layer formed on the first conductor is irradiated to the photoelectric conversion element, and the first conductor is electrically connected to the second semiconductor layer of the photoelectric conversion element, The second conductor includes a support that is electrically connected to the exposed portion of the first semiconductor layer. The photovoltaic device according to claim and.

(2) The photovoltaic device characterized in that the outer diameter of the photoelectric conversion element is 0.5 to 2 mmφ.
The outer diameter of the photoelectric conversion element is 0.5 to 2 mmφ, preferably 0.8 to 1.2 mmφ, or may be about 1 mmφ. As a result, the amount of high-purity Si and other materials used can be reduced sufficiently, and the generated power can be increased as much as possible. Also, the spherical photoelectric conversion element can be easily handled at the time of manufacture, and the productivity is excellent. ing.

  (3) The photovoltaic device, wherein the central angle θ1 of the opening of the second semiconductor layer is 45 to 90 °.

  As described above, by selecting the central angle θ1 to 45 to 90 °, more preferably to 60 to 90 °, the amount of the first and second semiconductor layers discarded due to the formation of the opening is reduced. Can be reduced and waste can be suppressed. In addition, by selecting the central angle θ1 in such a range of values, the area of the opening necessary for electrical connection between the first semiconductor layer and the second conductor of the support can be obtained.

  (4) The opening end of the recess formed in the support is, for example, a honeycomb-shaped polygon, each opening end adjacent to each other is continuous, and the recess is formed in a tapered shape toward the bottom. The first and second semiconductor layers of the photoelectric conversion element are electrically connected to the second and first conductors, which are electrically insulated from each other, at or near the bottom of the light source, respectively. Power generation device.

  (5) A circular first connection hole 39 is formed in the first conductor at or near the bottom of the concave portion of the support, and the electric insulator is on a straight line including the axis of the first connection hole 39. A circular second connection hole 40 having an axis is formed, and the vicinity of the opening of the photoelectric conversion element is fitted into the first connection hole 39, and the first outer peripheral surface of the opening of the second semiconductor layer and the first The end surface of the first connection hole 39 of the conductor or a portion near the end surface is electrically connected, and the portion of the first semiconductor layer exposed from the opening is connected to the second conductor via the second connection hole 40. A photovoltaic device characterized by being electrically connected.

  (6) When the outer diameter of the photoelectric conversion element is D1, the inner diameter of the opening of the second semiconductor layer is D2, the inner diameter of the first connection hole 39 is D3, and the inner diameter of the second connection hole 40 is D4. , D1> D3> D2> D4.

  The vicinity of the opening of the photoelectric conversion element is fitted into the first connection hole 39 of the first conductor, and the part of the first semiconductor layer exposed from the opening is formed on the electrical insulator of the support. It is electrically connected to the second conductor via the two connection holes 40. As a result, the first and second conductors of the support having the first conductor, the electrical insulator, and the second conductor can be easily and electrically connected to the second and first semiconductor layers of the photoelectric conversion element, respectively. become.

  Regarding the electrical connection between the second semiconductor layer and the first conductor, the outer peripheral surface above the opening 9 of the second semiconductor layer above the opening 9 in FIG. 1 and the first connection hole of the first conductor. The end surface of 39 or a portion in the vicinity of the end surface, that is, the inner peripheral surface of the first connection hole 39 and / or the portion surrounding the first connection hole 39 in the vicinity of the first connection hole 39 are electrically connected.

  The second conductor 14 may be inserted into the second connection hole 40 in the portion 10 exposed from the opening 9 of the first semiconductor layer 7, for example, raised and plastically deformed, or electrically connected, or The second conductor 14 may be electrically connected by a conductive paste provided in the second connection hole 40 or by a conductive bump such as a metal.

  Further, by selecting the outer diameter D1 and the inner diameters D2, D3, and D4 in accordance with the inequality described above, it is possible to prevent undesired electrical short-circuiting and ensure reliable electrical connection.

  (7) When the area of the opening end of the concave portion of the support is S1, and the cross-sectional area including the center of the photoelectric conversion element is S2, the light collection ratio x = S1 / S2 is selected from 2 to 8. Photovoltaic power generator.

  (8) (a) It has a substantially spherical shape, has a first semiconductor layer and a second semiconductor layer outside the first semiconductor layer, and a part of the first semiconductor layer is exposed from the opening of the second semiconductor layer. A plurality of photoelectric conversion elements that output photovoltaic power from the first and second semiconductor layers, and (b) a support body between the first conductor and the second conductor via an electrical insulator, A plurality of recesses are formed adjacent to each other, and the inner surface is formed by the first conductor or a coating layer formed on the first conductor, and a photoelectric conversion element is disposed in each recess. The reflected light from the first conductor of the recess or the coating layer formed on the first conductor is irradiated to the photoelectric conversion element, and the first conductor is electrically connected to the second semiconductor layer of the photoelectric conversion element, The second conductor includes a support electrically connected to the exposed portion of the first semiconductor layer. The outer diameter of the photoelectric conversion element is 0.5 to 2 mmφ, where the area of the opening end of the concave portion of the support is S1, and the cross-sectional area including the center of the photoelectric conversion element is S2, the light collection ratio x = S1 / S2 is selected from 2 to 8.

  (9) (a) It has a substantially spherical shape, has a first semiconductor layer and a second semiconductor layer outside the first semiconductor layer, and a part of the first semiconductor layer is exposed from the opening of the second semiconductor layer. A plurality of photoelectric conversion elements that output photovoltaic power from the first and second semiconductor layers, and (b) a support body between the first conductor and the second conductor via an electrical insulator, A plurality of recesses are formed adjacent to each other, and the inner surface is formed by the first conductor or a coating layer formed on the first conductor, and a photoelectric conversion element is disposed in each recess. The reflected light from the first conductor of the recess or the coating layer formed on the first conductor is irradiated to the photoelectric conversion element, and the first conductor is electrically connected to the second semiconductor layer of the photoelectric conversion element, The second conductor includes a support electrically connected to the exposed portion of the first semiconductor layer. When the outer diameter of the photoelectric conversion element is 0.8 to 1.2 mmφ, the area of the opening end of the concave portion of the support is S1, and the cross-sectional area including the center of the photoelectric conversion element is S2, the light collection ratio x = Photovoltaic generator characterized by selecting S1 / S2 as 4-6.

  The opening end of the concave portion of the support is, for example, a honeycomb-like polygon, and may be, for example, a hexagon. The concave portion is tapered toward the bottom, and a photoelectric conversion element is disposed on the bottom. The photoelectric conversion element is connected to each conductor of the support at the bottom of the recess or the periphery thereof. The opening end of the recess is polygonal, and each opening end is continuous, so that all the light received on the entire surface other than the position of the photoelectric conversion element on the support facing the light source such as sunlight is transferred to the photoelectric conversion element. It becomes possible to irradiate. Therefore, the condensing photoelectric conversion element can be realized by setting the condensing ratio x = S1 / S2 to 2 to 8 times, and preferably 4 to 6 times, for example. As a result, the distance between the photoelectric conversion elements can be increased as described above, the number of photoelectric conversion elements can be reduced, and the electrical connection work process with the support can be simplified. Therefore, the amount of high-purity semiconductor used as a material for the photoelectric conversion element can be reduced, and it can be implemented at low cost. The structure of the support is relatively simple, excellent in productivity, and easy to manufacture.

  For example, according to the experiment of the present inventor, in the present photovoltaic device in which a photoelectric conversion element made of substantially spherical Si is formed so that its outer diameter is 800 to 1000 μmφ, the condensing ratio x is 4 to 6 times. Then, Si having the same weight as Si constituting all the photoelectric conversion elements used in the photovoltaic device is virtually equal to the projected area on the virtual plane perpendicular to the light beam from the light source to the photovoltaic device. When converted into a flat plate having a thickness of about 90 to 120 μm, the amount of Si used per 1 W of generated power is less than 2 g. In the first prior art of the photoelectric conversion element composed of the above-described crystalline silicon semiconductor wafer, the thickness of the crystalline silicon is 350 to 500 μm, and when the slice loss is included, it is about 1 mm. Therefore, in the first prior art, the amount of Si used per 1 W of generated power is about 15 to 20 g. Therefore, the amount of Si used can be greatly reduced as compared with the first prior art described above.

  If the condensing ratio x is a value exceeding 8, the necessary number of photoelectric conversion elements can be reduced, and the amount of Si used per 1 W of generated power can be further reduced. As the condensing ratio x increases, the condensing efficiency, which is the ratio of the light energy incident on the concave portion to the light energy absorbed by the photoelectric conversion element, deteriorates, resulting in a decrease in performance.

  As described above, the outer diameter of the photoelectric conversion element is selected from 0.5 to 2 mmφ, preferably from 0.8 to 1.2 mmφ, and the light collection ratio x is selected from 2 to 8, preferably from 4 to 6. By selecting, the number of photoelectric conversion elements can be reduced, the amount of Si used per 1 W of generated power can be reduced, and the electrical connection work process between the photoelectric conversion elements and the support can be further simplified. Will be able to. Thus, the combination with the numerical value selection of the outer diameter of the photoelectric conversion element is important for reducing the number of photoelectric conversion elements and reducing the amount of Si used per 1 W of generated power.

  When the outer diameter of the photoelectric conversion element is less than 0.5 mmφ, the amount of Si used is reduced, but the required number of photoelectric conversion elements increases, and when the outer diameter exceeds 2 mmφ, Although the required number decreases, the amount of Si used increases.

  If the light collection ratio x is less than 2, the amount of Si used cannot be reduced sufficiently. If it exceeds 8, the light collection efficiency deteriorates to, for example, less than 80%, resulting in performance degradation. By selecting the condensing ratio x within the above-mentioned range, the condensing efficiency can be 80% or more, and further 90% or more.

  Thus, the outer diameter of the photoelectric conversion element and the light condensing ratio x are selected within the above-mentioned numerical range, and thereby, compared with the above-described third prior art, the required number of photoelectric conversion elements and the Si per 1 W of generated power. An excellent effect is achieved in that both of the amount used can be drastically reduced to 1/5 to 1/10.

  Moreover, in the structure which condensed with the above-mentioned condensing ratio using the amorphous Si photoelectric conversion element, the temperature of a photoelectric conversion element shall be raised compared with the photoelectric conversion element of an amorphous Si thin plate, for example, shall be 40-80 degreeC. it can. Thereby, it is possible to suppress the deterioration of the amorphous Si photoelectric conversion element and to extend the life.

  (10) As shown in FIG. 14, in the photoelectric conversion element, the second conductive type second semiconductor layer 65 having an optical band gap wider than that of the first semiconductor layer is disposed outside the first conductive type first semiconductor layer 64. A photovoltaic device which is formed and has a pn junction.

  (11) As shown in FIG. 15 and FIG. 16, the photoelectric conversion element is more optical than the amorphous intrinsic semiconductor layers 69 and 74 and the first semiconductor layer outside the first semiconductor layers 68 and 73 of one conductivity type. A photovoltaic device characterized in that amorphous second semiconductor layers 70 and 76 of the other conductivity type having a wide band gap are formed in this order and have a pin junction.

  (12) The photovoltaic device, wherein the first semiconductor layer is n-type Si and the second semiconductor layer is p-type amorphous SiC.

  (13) The photovoltaic device, wherein the n-type Si as the first semiconductor layer is n-type crystalline Si or n-type microcrystalline (μc) Si.

  A heterojunction window structure of pn or pin is constituted by different kinds of amorphous semiconductors. The optical band gap of the second semiconductor layer of the window material existing on the light incident side is made wider than that of the inner first semiconductor layer, thereby reducing the light absorption coefficient of the second semiconductor layer. The layer prevents light from being absorbed, reduces recombination of electrons and holes in the surface layer, reduces light absorption loss, and increases sensitivity on the short wavelength side to achieve a wide gap window effect, resulting in The energy conversion efficiency can be improved.

  In particular, in the pin junction structure, more optical energy can be introduced into the intrinsic semiconductor layer (i layer) that is the photovoltaic generation layer, and the sensitivity on the short wavelength side can be increased to achieve a wide gap window effect. Compared with the particles in which the n-type Si skin portion is formed outside the p-type Si sphere in the above-described prior art, an extremely superior energy conversion operation is performed.

  In the i layer of a photoelectric conversion element having a pin junction, light is absorbed to create electron-hole pairs to generate and transport a photocurrent, and the p layer and the n layer have Fermi levels representing valence electrons. It is fixed near the band and conduction band and serves to collect photogenerated carriers by creating an internal electric field that carries electrons and holes generated in the i layer to both electrodes. Thus, the energy conversion efficiency is improved.

  (14) As shown in FIG. 17, the photoelectric conversion element includes an inner cell 81 having an innermost first semiconductor layer and an outer cell formed outside the inner cell and having an outermost second semiconductor layer. A photovoltaic device comprising a cell 82 and having a stack structure.

  (15) The photovoltaic device characterized in that the internal cell 81 has a pn junction layer or a pin junction layer, and the external cell 82 has a pn junction layer or a pin junction layer.

  (16) The internal cell 81 has, in order from the inside to the outside, a first semiconductor layer 84 of one conductivity type and an amorphous and / or microcrystalline semiconductor layer 85 of the other conductivity type. A photovoltaic device comprising: an amorphous pin junction layer 86 and an amorphous or microcrystalline second semiconductor layer 87 having an optical band gap wider than that of the pin junction layer.

  (17) As shown in FIG. 18, the internal cell 101 includes, in order from the inside to the outside, a first semiconductor layer 104 having one conductivity type and amorphous and / or microcrystalline semiconductor layers 105 and 106 having the other conductivity type. The external cell 102 includes, in order from the inside to the outside, a microcrystalline semiconductor layer 107 having one conductivity type, an amorphous intrinsic semiconductor layer 108, and a second semiconductor layer 111 having a microcrystalline semiconductor type having the other conductivity type. Photovoltaic power generator.

  (18) As shown in FIG. 19, the internal cell 112 includes, in order from the inside to the outside, an amorphous first semiconductor layer 114 having one conductivity type, an amorphous intrinsic semiconductor layer 115, and an amorphous semiconductor layer 117 having the other conductivity type. The external cell 113 includes, in order from the inside to the outside, a microcrystalline semiconductor layer 118 having one conductivity type, an amorphous intrinsic semiconductor layer 119, and a second semiconductor layer 122 having a microcrystalline semiconductor type having the other conductivity type. A photovoltaic power generator.

  (19) As shown in FIG. 20, the internal cell 124 includes, in order from the inside to the outside, the amorphous first semiconductor layer 126 having one conductivity type, the intrinsic semiconductor layer 127 having a microcrystalline structure, and the other conductivity type. And an amorphous semiconductor layer 129 having an optical band gap wider than that of one semiconductor layer. The outer cell 125 includes, in order from the inside to the outside, a microcrystalline semiconductor layer 130 of one conductivity type, an amorphous intrinsic semiconductor layer 131, and the other A photovoltaic device, comprising: a second semiconductor layer 134 of microcrystalline conductivity type.

  The microcrystalline (μc) semiconductor layer has high conductivity, and the photoelectric conversion efficiency can be improved by introducing such a microcrystalline semiconductor layer between the first semiconductor layer and the pin junction layer. The amorphous pin junction layer and the heterojunction between the amorphous pin junction layer and the second semiconductor layer can effectively collect photogenerated carriers and reduce the recombination loss of photogenerated carriers. it can.

  An amorphous semiconductor is advantageous in that it is heated to, for example, 40 to 80 ° C. by receiving reflected light from the inner surface of the concave portion of the support, thereby suppressing deterioration in photoelectric conversion characteristics. Since this photoelectric conversion element is formed in a substantially spherical shape, it is possible to suppress an increase in incident energy of light per unit area for receiving direct light and reflected light, which also causes deterioration in photoelectric conversion characteristics. Will be suppressed.

(20) The photovoltaic device, wherein the first semiconductor layer is a direct transition type semiconductor layer.
(21) is direct transition type semiconductor _{layer, InAs, GaSb, CuInSe 2,} Cu (InGa) Se 2, CuInS, GaAs, InGaP, photovoltaic device, characterized in that the one member selected from the group consisting of CdTe .

  The inner first semiconductor layer can be realized by a direct transition semiconductor layer that easily absorbs light, thereby obtaining a sufficient transition probability between electrons and holes. This also increases the photoelectric conversion efficiency. Can be improved.

  (22) A plurality of supports are arranged adjacent to each other, and a peripheral portion of each support is formed to extend outward, and in this peripheral portion, the first conductor of one adjacent support and The photovoltaic device, wherein the second conductor of the other support is overlapped and electrically connected.

  (23) Each of the peripheral portions has a rising portion or a falling portion, and the rising portion or the falling portion is overlapped and electrically connected.

  At the periphery of the plurality of supports on which the photoelectric conversion elements are mounted, the first conductor of one support and the second conductor of the other support are overlapped and connected, and thus depending on the photoelectric conversion element for each support Photovoltaic power can be connected in series to extract a desired high voltage.

  As shown in FIG. 12 and FIG. 13 described above, the rising part and the falling part of the peripheral part of the support are overlapped and electrically connected, or the rising parts are connected or the falling parts are electrically connected. You may make it connect. As a result, the concave portions of the support are brought close to each other, and as many concave portions and photoelectric conversion elements as possible can be arranged in a limited area.

In particular, the outer diameter of the photoelectric conversion element is selected to be 0.5 to 2 mmφ, preferably 0.8 to 1.2 mmφ, and the condensing ratio x is selected to be 2 to 8, preferably 4 to 6, so that 3 An excellent effect that the amount of Si used per 1 W of generated power and the required number of photoelectric conversion elements can be drastically reduced to 1/5 to 1/10 as compared with the prior art can be achieved. become. By reducing the amount of Si used, the photovoltaic device can be realized at low cost, and the number of photoelectric conversion elements is reduced to simplify the electrical connection work process between the photoelectric conversion elements and the support, In this way, productivity is improved, and this also realizes an inexpensive photovoltaic device.
Therefore, a highly reliable and highly efficient photovoltaic device can be provided.

  The optical band gap of the outer amorphous second semiconductor layer is made wider than that of the first semiconductor layer on the center side to form a pn junction or pin junction, whereby the second semiconductor layer of the window material on the light incident side Thus, light can be prevented from being absorbed, recombination in the surface layer can be reduced, a wide gap window action can be achieved, and photoelectric conversion efficiency can be improved.

  Further, the energy conversion efficiency is improved by interposing a microcrystalline (μc) semiconductor layer having high conductivity between the first semiconductor layer on the center side and the pin junction layer on the outer side. Can do.

It is also possible to improve energy conversion efficiency using the direct transition type first semiconductor layer.
Moreover, manufacture of a photoelectric conversion element is easy.

It is a partial expanded sectional view of the photovoltaic device 1 of one embodiment of the present invention. 1 is a cross-sectional view illustrating the overall configuration of a photovoltaic power generation apparatus 1. It is a disassembled perspective view of the photovoltaic device 1 shown by FIG. 3 is a plan view of a part of a support body 3. FIG. It is sectional drawing which shows the photoelectric conversion element 31 in the state before mounting in the support body 3 of the photoelectric conversion element. It is sectional drawing for demonstrating the method to manufacture the combination body 4 which has the photoelectric conversion element 2 and the support body 3. FIG. It is sectional drawing for demonstrating the process of cutting the true spherical photoelectric conversion element 31, and forming the opening part 32. FIG. FIG. 6 is a simplified perspective view showing a process of placing the photoelectric conversion element 2 in the recess 17 of the support 3. It is a perspective view which shows the state to which the combination bodies 4 and 4b which have the photoelectric conversion element 2 and the support body 3 were connected. FIG. 10 is an exploded sectional view of the vicinity of the peripheral portions 61 and 61b of the combination bodies 4 and 4b shown in FIG. It is the simplified side view which shows the state which connected the combination bodies 4, 4b, and 4c electrically. It is sectional drawing which shows the electrical connection structure of the adjacent combination bodies 4 and 4b. It is sectional drawing which shows the electrical connection state of the combination bodies 4 and 4b in the other embodiment of this invention. It is sectional drawing of a part of photoelectric conversion element 2 of other form of implementation of this invention. It is sectional drawing of the photoelectric conversion element 2 of other form of implementation of this invention. It is sectional drawing of the photoelectric conversion element 2 of other form of implementation of this invention. It is sectional drawing of the photoelectric conversion element 2 of other form of implementation of this invention. It is sectional drawing of the photoelectric conversion element 2 of other form of implementation of this invention. It is sectional drawing of the photoelectric conversion element 2 of other form of implementation of this invention. It is sectional drawing of the photoelectric conversion element 2 of other embodiment of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Photovoltaic device 2 Photoelectric conversion element 3, 3b Support body 4 Combination body 7 1st semiconductor layer 8 2nd semiconductor layer 9 Opening part 10 Part 13 1st conductor 14 2nd conductor 15 Electrical insulator 17 Recessed part 18 Opening end

Claims (7)

(A) It has a substantially spherical shape, has a first semiconductor layer and a second semiconductor layer outside the first semiconductor layer, and a part of the first semiconductor layer is exposed from the opening of the second semiconductor layer. And a plurality of photoelectric conversion elements that output photovoltaic power from the second semiconductor layer,
(B) a support,
An electrically insulated state is formed between the first conductor and the second conductor via an electrical insulator,
A plurality of recesses whose inner surfaces are formed by the first conductor or a coating layer formed on the first conductor are formed adjacent to each other,
The open ends of the recesses are polygonal, and the open ends adjacent to each other are continuous,
A photoelectric conversion element is disposed in each recess, and the photoelectric conversion element is irradiated with reflected light from the first conductor of the recess or the coating layer formed on the first conductor,
The first conductor is electrically connected to the second semiconductor layer of the photoelectric conversion element,
The second conductor includes a support that is electrically connected to the exposed portion of the first semiconductor layer.   The photovoltaic device according to claim 1, wherein the polygons are provided in rows at an equal pitch.   The photovoltaic device according to claim 1, wherein the polygon is a regular hexagon.   4. The photovoltaic device according to claim 1, wherein the opening ends adjacent to each other of the recesses are continuous in an inverted U shape. 5. (A) It has a substantially spherical shape, has a first semiconductor layer and a second semiconductor layer outside the first semiconductor layer, and a part of the first semiconductor layer is exposed from the opening of the second semiconductor layer. And a plurality of photoelectric conversion elements that output photovoltaic power from the second semiconductor layer,
(B) a support,
An electrically insulated state is formed between the first conductor and the second conductor via an electrical insulator,
A plurality of recesses whose inner surfaces are formed by the first conductor or a coating layer formed on the first conductor are formed adjacent to each other,
Open ends adjacent to each other of the recesses are continuous in an inverted U shape,
A photoelectric conversion element is disposed in each recess, and the photoelectric conversion element is irradiated with reflected light from the first conductor of the recess or the coating layer formed on the first conductor,
The first conductor is electrically connected to the second semiconductor layer of the photoelectric conversion element,
The second conductor includes a support that is electrically connected to the exposed portion of the first semiconductor layer. The recess is formed in a tapered shape toward the bottom,
The first and second semiconductor layers of the photoelectric conversion element are electrically connected to the second and first conductors, which are electrically insulated from each other, at or near the bottom of the recess, respectively. The photovoltaic device according to claim 1.   The photoelectric conversion element has a configuration in which an opening of the second semiconductor layer and a part of the first semiconductor layer exposed from the opening are in one plane. A photovoltaic power generator according to one of the above.

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