JP3722497B2 - Biological treatment method and biological treatment apparatus for nitrogen-containing polluted water - Google Patents
Biological treatment method and biological treatment apparatus for nitrogen-containing polluted water Download PDFInfo
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- JP3722497B2 JP3722497B2 JP10290494A JP10290494A JP3722497B2 JP 3722497 B2 JP3722497 B2 JP 3722497B2 JP 10290494 A JP10290494 A JP 10290494A JP 10290494 A JP10290494 A JP 10290494A JP 3722497 B2 JP3722497 B2 JP 3722497B2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Description
【0001】
【産業上の利用分野】
本発明は、例えば生活排水を生物処理する際、窒素を効率的に除去し得る生物処理方法及び処理装置に関する。
【0002】
【従来の技術】
従来、生活排水等の窒素含有汚濁水から生物処理によって窒素を除去するような技術として、例えば、Barthらによって開発された3段分離法が知られている。
【0003】
この方法は、図2に示すように、生活排水を第1沈殿槽51に導いて異物の沈殿除去を行い、異物の除去された生活排水を高速酸化槽52に導入してBOD成分酸化菌によってBOD(biochemical oxygen demand)物質(水中の溶存酸素を消費する物質)の酸化除去を行う。この際、アンモニア態窒素(NH4 +)は酸化されて亜硝酸(NO2 -)に変化する。
【0004】
次に第2沈殿槽53において、BOD成分酸化菌を含有する汚泥と処理排水との分離を行い、BOD成分酸化菌を含有する汚泥をBOD成分酸化菌回収配管54を介して高速酸化槽52に回収した後、処理排水を硝化槽55で硝酸菌によって生物処理すると、亜硝酸(NO2 -)は硝酸態窒素(NO3 -)まで変化する。
【0005】
そして、第3沈殿槽56において、硝酸菌を含有する汚泥と処理排水との分離を行い、硝酸菌を含有する汚泥を硝酸菌回収配管57を介して硝化槽55に回収した後、処理排水を脱窒槽58に導き、ここでは今までの工程で殆ど消費し尽くした有機物、特に脱窒菌の合成材料である炭素源を補充する。
【0006】
つまり、例えばメタノール(CH3OH)等の有機性炭素源を補充し、これを利用して硝酸を還元して窒素ガスとして空中に放出し、脱窒素を完了する。
そして、次の最終沈殿槽59において脱窒菌を含有する汚泥と処理排水との分離が行われ、脱窒菌を含有する汚泥は脱窒菌回収配管60を介して脱窒槽58に回収される。
【0007】
そして、処理排水は処理水槽61においてBOD、COD(chemical oxygen demand)、PH等のチェックを行い、一般環境下へ排水される。
尚、高速酸化槽52、硝化槽55での反応は好気性条件下であり、脱窒槽58での反応は嫌気性条件下である。
【0008】
【発明が解決しようとする課題】
ところが、かかる従来方法の場合、一度BODを除去した処理排水に再度メタノール等の有機炭素源を添加するという矛盾があり、BODの厳しい環境規制の面からシビアにコントロールする必要があるばかりでなく、装置も高度な性能のものが要求される。
【0009】
また、装置も高速酸化槽、硝化槽、脱窒槽の3種類の槽、及び3種類の回収配管が必要で大型化するとともに、高速酸化槽と硝化槽の反応は好気性条件下での反応であり、脱窒槽の反応は嫌気性条件下での反応であるため、各槽における条件のコントロールが煩雑になるという問題があった。
【0010】
【課題を解決するための手段】
本発明は、上記不具合を解消するためなされたものであり、窒素含有汚濁水中のBODと窒素の含有率の実態に着目した。
【0011】
すなわち、窒素含有汚濁水を生物処理する生物処理方法において、汚濁水中のBODと窒素の濃度が重量比で100:5〜6.5となるように窒素を基準としてBODを添加し、好気性条件下で高負荷曝気槽及び曝気槽中の微生物濃度を3,000〜6,000 mg /リットル範囲に保つようにし、定期的に、増殖するBOD成分酸化菌又は硝酸菌を脱水廃棄することにより生物処理するようにした。
【0012】
また、生物処理装置において、汚濁水から異物を沈殿除去させる第1沈殿槽と、この第1沈殿槽に続く原水槽に取付けられた測定装置により検出したBODと窒素の濃度に基づいて重量比でBOD:窒素を100:5〜6.5となるように窒素を基準としてBODを添加する原水槽と、BODを添加した汚濁水を好気性条件下でBOD成分酸化菌又は硝酸菌で生物処理する高負荷曝気槽及び曝気槽と、生物処理した汚濁水とBOD成分酸化菌又は硝酸菌を含む汚泥とを分離する第2沈殿槽を設け、分離したBOD成分酸化菌又は硝酸菌を含む汚泥を前記高負荷曝気槽及び曝気槽に返送し、好気性条件下で前記高負荷曝気槽及び曝気槽中の微生物濃度を3,000〜6,000 mg /リットル範囲に保つようにし、定期的に、増殖するBOD成分酸化菌又は硝酸菌を脱水廃棄するとともに、生物処理した汚濁水を外部に排水するようにした。
【0013】
【作用】
BODを生物処理で除去する時の有機排水中のBODと窒素の一般的な消費関係は、100:5(重量比)であることは広く知られている。
一方、実際の有機排水中の含有窒素量は、上記消費率より格段に多い。
【0014】
そこで、窒素を除去するにあたり、上記消費関係に基づき実際の窒素含有量を基準にしてBODの量を増加させて確実に窒素を除去するよう図る。
【0015】
ここで、BOD物質(水中の溶存酸素を消費する物質)は、a.好気性菌によって分解される有機性物質と、b.硝化菌によって硝化されるアンモニア態窒素、亜硝酸態窒素などがあるが、本案でのBODの量の増加は、メチルアルコール又はエチルアルコール等の有機炭素源の補充により、またはBODの高い他の水を利用するようにしている。
【0016】
そして、好気性条件下でBOD成分酸化菌又は硝酸菌により生物処理し、高負荷曝気槽と曝気槽の2段曝気により窒素(主にアンモニアまたは硝酸態窒素)をBOD成分酸化菌又は硝酸菌内に効率良く取り込む。
【0017】
そして、定期的に増殖したBOD成分酸化菌又は硝酸菌を脱水廃棄(焼却又は埋立て処理)して、例えば処理排水中の窒素濃度を10mg/リットル以下にする。
【0018】
【実施例】
本発明の窒素含有汚濁水の生物処理方法及び生物処理装置の実施例について添付した図面に基づき説明する。
図1は本発明の生物処理を示す処理工程図である。
【0019】
本発明の生物処理は、すべての工程を好気性条件下で処理出来るようにしたものであり、図1に示すように、生活排水を第1沈殿槽1に導いて異物を沈殿除去させた後、原水槽2において濃度測定を行うようにしている。
【0020】
すなわち、原水槽2には、BOD濃度と窒素濃度を測定することの出来る測定装置3が設けられており、この測定装置3によって測定したBOD濃度と窒素濃度の測定結果に基づき、両者の一般的な消費関係を基準にして不足分のBOD(有機炭素源)をメチルアルコール又はエチルアルコールなどを補充することで補う。
【0021】
そして実施例の場合、原水槽2中のBOD濃度と窒素濃度が夫々200mg/リットルと40mg/リットル、つまりBOD:窒素が100:20であった。
そこで各条件での効果を確認するため、実施例ではメチルアルコール等の有機炭素源の補充量を変えて、BOD濃度が500mg/リットル(BOD:窒素=100:8)、600mg/リットル(BOD:窒素=100:6.7)、700mg/リットル(BOD:窒素=100:5.7)、800mg/リットル(BOD:窒素=100:5)、850mg/リットル(BOD:窒素=100:4.7)となるよう5種のサンプルで実験した。
【0022】
次に、各サンプルごと高負荷曝気槽4においてエアレーション法と液中攪拌を併用し、高速曝気を行う。そしてこの曝気は汚泥が沈降しないよう充分な曝気強度で行い、同時にBOD成分酸化菌或いは硝酸菌により生物処理する。
そして、前記高負荷曝気槽4で処理した後のBOD濃度と窒素濃度の測定値を表1に示す。
【0023】
【表1】
【0024】
次に、更に下流の曝気槽5でエアレーション法と液中攪拌によって曝気し、同様にBOD成分酸化菌或いは硝酸菌により生物処理する。
そして、同様に曝気槽5で処理した後のBOD濃度と窒素濃度の測定値も表1に示す。
【0025】
次に、第2沈殿槽6でBOD成分酸化菌又は硝酸菌を含む汚泥と処理排水を分離し、BOD成分酸化菌又は硝酸菌を含む汚泥はBOD成分酸化菌又は硝酸菌回収配管7を介して高負荷曝気槽4と曝気槽5に返送する。
そして、例えば高負荷曝気槽4及び曝気槽5中の微生物濃度を3,000〜6,000mg/リットル範囲に保つようにし、定期的に、増殖するBOD成分酸化菌又は硝酸菌を脱水廃棄する。
【0026】
この際、高負荷曝気槽4への返送汚泥量は、除去したいBOD量により決まり、一定ではない。
【0027】
一方、処理排水は処理槽8に導き、BOD、COD、PH、全窒素等をチェックして一般環境下に排水する。
【0028】
ここで、一般環境下に排水する処理排水のBOD及び全窒素の含有を10mg/リットル以下に抑えようとする場合、前記表1から、BODと窒素の重量濃度比を100:5〜6.5にすることが必要であることが判る。
【0029】
すなわち、BOD100mg/リットルに対して窒素の含有濃度が5mg/リットル以下であると、処理排水中のBOD濃度が10mg/リットルを越えてしまう可能性があり、BOD100mg/リットルに対して窒素の含有濃度が6.5mg/リットル以上であると、処理排水中の窒素濃度が10mg/リットルを越えてしまう可能性がある。
【0030】
そして、かかる処理方法によって、好気性条件下だけで処理することが出来、条件設定等が容易になるとともに、装置の簡素化が可能である。
【0031】
【発明の効果】
以上のように本発明の窒素含有汚濁水の生物処理方法及び装置は、従来のように一旦BODを除去した処理排水に対して再度メタノール等の有機炭素源を添加していたような作業を無くすことが出来、しかも好気性条件下でのみ処理出来るため、各種条件を複雑にコントロールする必要もなくなる。
また、装置構成も従来のような複雑な処理槽を必要とせず、装置の小型化、簡素化が可能である。しかも安価に構成出来る。
【図面の簡単な説明】
【図1】本発明の生物処理の工程図
【図2】従来の生物処理の工程図
【符号の説明】
1 第1沈殿槽
2 原水槽
3 測定装置
4 高負荷曝気槽
5 曝気槽
6 第2沈殿槽
7 BOD成分酸化菌又は硝酸菌回収配管[0001]
[Industrial application fields]
The present invention relates to a biological treatment method and a treatment apparatus that can efficiently remove nitrogen, for example, when biological wastewater is biologically treated.
[0002]
[Prior art]
Conventionally, for example, a three-stage separation method developed by Barth et al. Is known as a technique for removing nitrogen from nitrogen-containing polluted water such as domestic wastewater by biological treatment.
[0003]
In this method, as shown in FIG. 2, the domestic wastewater is guided to the
[0004]
Next, in the
[0005]
Then, in the third settling
[0006]
That is, for example, an organic carbon source such as methanol (CH 3 OH) is replenished, and using this, nitric acid is reduced and released into the air as nitrogen gas to complete denitrification.
Then, the sludge containing denitrifying bacteria and the treated waste water are separated in the next
[0007]
Then, the treated wastewater is checked in the treated
The reaction in the high-
[0008]
[Problems to be solved by the invention]
However, in the case of such a conventional method, there is a contradiction that an organic carbon source such as methanol is added again to the treated wastewater from which BOD has been once removed, and not only it is necessary to control severely from the viewpoint of strict environmental regulations of BOD, The equipment is also required to have high performance.
[0009]
The equipment also requires three types of tanks, a high-speed oxidation tank, a nitrification tank, and a denitrification tank, and three types of recovery pipes. The reaction between the high-speed oxidation tank and the nitrification tank is a reaction under aerobic conditions. In addition, since the reaction in the denitrification tank is a reaction under anaerobic conditions, there is a problem that the control of the conditions in each tank becomes complicated.
[0010]
[Means for Solving the Problems]
The present invention has been made to solve the above problems, and has focused on the actual content of BOD and nitrogen content in nitrogen-containing polluted water.
[0011]
That is, in the biological treatment method for biologically treating nitrogen-containing polluted water, BOD is added on the basis of nitrogen so that the concentration of BOD and nitrogen in the polluted water is 100: 5 to 6.5 by weight, and the aerobic condition By keeping the microorganism concentration in the high-load aeration tank and the aeration tank in the range of 3,000 to 6,000 mg / liter under the normal condition, the BOD component oxidizing bacteria or nitrate bacteria are periodically dehydrated and discarded. It was made to process.
[0012]
Moreover, in the biological treatment apparatus, the weight ratio is based on the concentration of BOD and nitrogen detected by the first sedimentation tank that precipitates and removes foreign substances from the polluted water, and the measurement apparatus attached to the raw water tank following the first sedimentation tank. BOD: Raw water tank to which BOD is added based on nitrogen so that nitrogen is 100: 5 to 6.5, and contaminated water to which BOD is added are biologically treated with BOD component oxidizing bacteria or nitrate bacteria under aerobic conditions A second settling tank is provided for separating the high-load aeration tank and the aeration tank, the biologically treated polluted water and the sludge containing BOD component oxidizing bacteria or nitrate bacteria, and the separated sludge containing BOD component oxidizing bacteria or nitrate bacteria is Return to the high-load aeration tank and the aeration tank, and maintain the microorganism concentration in the high-load aeration tank and the aeration tank in the range of 3,000 to 6,000 mg / liter under aerobic conditions. BOD component Oxidizing bacteria or nitrate bacteria were dehydrated and discarded , and biologically treated polluted water was drained to the outside.
[0013]
[Action]
It is well known that the general consumption relationship between BOD and nitrogen in organic wastewater when removing BOD by biological treatment is 100: 5 (weight ratio).
On the other hand, the amount of nitrogen contained in the actual organic wastewater is much larger than the above consumption rate.
[0014]
Therefore, when removing nitrogen, the amount of BOD is increased on the basis of the actual nitrogen content based on the above consumption relation, and nitrogen is surely removed.
[0015]
Here, the BOD substance (substance that consumes dissolved oxygen in water) is a. An organic substance that is degraded by aerobic bacteria; b. There are ammonia nitrogen and nitrite nitrogen that are nitrified by nitrifying bacteria, but the increase in the amount of BOD in this proposal is due to supplementation of organic carbon sources such as methyl alcohol or ethyl alcohol, or other water with high BOD. To use.
[0016]
And it is biologically treated with BOD component oxidizing bacteria or nitrate bacteria under aerobic conditions, and nitrogen (mainly ammonia or nitrate nitrogen) is converted into BOD component oxidizing bacteria or nitrate bacteria by two-stage aeration of high load aeration tank and aeration tank. Efficiently.
[0017]
Then, the BOD component oxidizing bacteria or nitrate bacteria that have periodically grown are dehydrated and discarded (incinerated or landfilled), for example, to reduce the nitrogen concentration in the treated wastewater to 10 mg / liter or less.
[0018]
【Example】
Embodiments of a biological treatment method and biological treatment apparatus for nitrogen-containing contaminated water according to the present invention will be described with reference to the accompanying drawings.
FIG. 1 is a process diagram showing the biological treatment of the present invention.
[0019]
The biological treatment of the present invention is such that all steps can be treated under aerobic conditions, and as shown in FIG. 1, after the domestic wastewater is guided to the first settling tank 1 and foreign matter is precipitated and removed. The concentration is measured in the
[0020]
In other words, the
[0021]
In the case of the examples, the BOD concentration and the nitrogen concentration in the
Therefore, in order to confirm the effect under each condition, the replenishment amount of an organic carbon source such as methyl alcohol was changed in the examples, and the BOD concentration was 500 mg / liter (BOD: nitrogen = 100: 8), 600 mg / liter (BOD: Nitrogen = 100: 6.7), 700 mg / liter (BOD: nitrogen = 100: 5.7), 800 mg / liter (BOD: nitrogen = 100: 5), 850 mg / liter (BOD: nitrogen = 100: 4.7) The experiment was conducted with five types of samples.
[0022]
Next, high-speed aeration is performed in the high-load aeration tank 4 for each sample by using both the aeration method and stirring in the liquid. This aeration is performed with sufficient aeration intensity so that sludge does not settle, and at the same time, biological treatment is performed with BOD component oxidizing bacteria or nitrate bacteria.
Table 1 shows measured values of BOD concentration and nitrogen concentration after treatment in the high-load aeration tank 4.
[0023]
[Table 1]
[0024]
Next, aeration is performed in the aeration tank 5 further downstream by aeration and agitation in the liquid, and biological treatment is similarly performed with BOD component oxidizing bacteria or nitrate bacteria.
And the measured value of BOD density | concentration and nitrogen concentration after processing with the aeration tank 5 similarly is also shown in Table 1.
[0025]
Next, the sludge containing the BOD component oxidizing bacteria or nitrate bacteria and the treated waste water are separated in the
Then, for example, the microorganism concentration in the high-load aeration tank 4 and the aeration tank 5 is kept in the range of 3,000 to 6,000 mg / liter, and the BOD component oxidizing bacteria or nitrate bacteria that grow are periodically dehydrated and discarded.
[0026]
At this time, the amount of sludge returned to the high-load aeration tank 4 is determined by the amount of BOD to be removed and is not constant.
[0027]
On the other hand, the treated wastewater is guided to the treatment tank 8 and checked for BOD, COD, PH, total nitrogen, etc., and discharged into the general environment.
[0028]
Here, when the content of BOD and total nitrogen in the treated wastewater discharged into the general environment is to be suppressed to 10 mg / liter or less, the weight concentration ratio of BOD to nitrogen is 100: 5 to 6.5 from Table 1 above. It turns out that it is necessary to make it.
[0029]
That is, if the nitrogen concentration is 5 mg / liter or less with respect to 100 mg / liter of BOD, there is a possibility that the BOD concentration in the treated wastewater will exceed 10 mg / liter, and the nitrogen content concentration with respect to 100 mg / liter of BOD. If it is 6.5 mg / liter or more, the nitrogen concentration in the treated wastewater may exceed 10 mg / liter.
[0030]
Such a processing method makes it possible to perform processing only under aerobic conditions, making it easy to set conditions and simplifying the apparatus.
[0031]
【The invention's effect】
As described above, the biological treatment method and apparatus for nitrogen-containing polluted water of the present invention eliminates the work of adding an organic carbon source such as methanol to the treated wastewater from which BOD has been removed once as in the prior art. In addition, since it can be processed only under aerobic conditions, it is not necessary to control various conditions in a complicated manner.
Also, the apparatus configuration does not require a complicated treatment tank as in the prior art, and the apparatus can be reduced in size and simplified. Moreover, it can be configured at low cost.
[Brief description of the drawings]
FIG. 1 is a flowchart of biological treatment of the present invention. FIG. 2 is a flowchart of conventional biological treatment.
1
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JP10290494A JP3722497B2 (en) | 1994-05-17 | 1994-05-17 | Biological treatment method and biological treatment apparatus for nitrogen-containing polluted water |
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JP10290494A JP3722497B2 (en) | 1994-05-17 | 1994-05-17 | Biological treatment method and biological treatment apparatus for nitrogen-containing polluted water |
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JP3722497B2 true JP3722497B2 (en) | 2005-11-30 |
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