JP3700585B2 - Color filter substrate, color filter substrate manufacturing method, and liquid crystal display device using the same - Google Patents

Color filter substrate, color filter substrate manufacturing method, and liquid crystal display device using the same Download PDF

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Publication number
JP3700585B2
JP3700585B2 JP2001022967A JP2001022967A JP3700585B2 JP 3700585 B2 JP3700585 B2 JP 3700585B2 JP 2001022967 A JP2001022967 A JP 2001022967A JP 2001022967 A JP2001022967 A JP 2001022967A JP 3700585 B2 JP3700585 B2 JP 3700585B2
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Japan
Prior art keywords
color filter
liquid crystal
crystal display
filter
filter substrate
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Expired - Fee Related
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JP2001022967A
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Japanese (ja)
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JP2002228824A (en
Inventor
秀樹 松川
浩治 井上
由雄 谷口
久典 山口
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Panasonic Corp
Panasonic Holdings Corp
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Panasonic Corp
Matsushita Electric Industrial Co Ltd
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  • Optical Filters (AREA)

Description

【0001】
【発明の属する技術分野】
本発明はパーソナルコンピュータ、ワードプロセッサ、モニターディスプレイなどのOA機器や携帯型の情報通信機器などに用いられる液晶表示素子、またそれに用いられるカラーフィルタとその製造方法に関する。
【0002】
【従来の技術】
元来、液晶表示素子は受光素子であるため、光源を要する透過型、外光を利用する反射型、反射型と透過型の両方の機能を有する半透過型の3種類がある。特に、半透過型における従来からの液晶表示素子の構成は図4で示すように、内側に透明な表示電極を有する対向する一対2枚の透明基板1a、1bと、各々その外側にフィルム位相差板13a,13bと、そのフィルム位相差板13a,13bと透明基板1a、1bを挟んで一対の偏光板5a、5bと入射光の反対側にハーフミラー板14を設けて液晶表示素子を構成している。カラー対応では上側の透明基板1aの内側にはカラーフィルタ2を形成している。そして、ハーフミラー板の外側にはバックライト8を設置する。STNモードの場合は、フィルム位相差板13は1枚または2枚を用いており、配置個所も透明基板1a、1bの上側、下側、または上下ともに配置し、リタデーションなどを考慮し求める特性に応じて最適化する。TFTのTNモードの場合はフィルム位相差板13を必要としない。
【0003】
従来の構成で用いられているハーフミラー板14は偏光板5b上に形成される、−Ag合金からなる薄膜であり、その膜厚を50nmとする。このような薄膜を用いると、反射型ではバックライト8をオフ状態にし、ハーフミラーを反射板として扱い、周囲の外光により液晶パネルの表示を見ることができる。また、透過型ではバックライト8をオンすることにより、バックライト8の光量が液晶パネルを透過することにより、液晶パネルの表示を見ることができる。このようにして、ハーフミラー14の特長を活かすことで、反射型と透過型とを兼用することができる。
【0004】
【発明が解決しようとする課題】
しかしながら、従来の半透過型液晶パネルでは、反射板が透過性を持っているため、透過型としての使用時には黒レベルが浮くことでコントラストの低下が起こり、はっきりした表示が得られなかった。また反射型としての使用時には、明るい表示を得るための十分な反射率を得られないという課題があった。
【0005】
そこで、液晶パネルの一つの画素に透過部と反射部とを設けることで、上記課題を解決できるが、カラーフィルタ層が全て同じ厚みでは、透過的な厚みが異なるために生じる表示特性に不具合感があった。
【0006】
【課題を解決するための手段】
この目的を達成するため本発明は、液晶が挟持される、対向する一対の基板のうちいずれか一方の基板上には、複数色のカラーフィルタ層が特定のパターンで画素配列され、他方の基板には、画素単位の中に外光を反射する反射部分と、バックライト光を透過する透過部分とが形成された液晶表示素子であって、前記カラーフィルタ層は、各色において、前記反射部分に対向する 1 つの反射対向フィルタ部分と、前記透過部分に対向する 1 つの透過対向フィルタ部分とからなり、前記反射対向フィルタ部分の膜厚は前記透過対向フィルタ部分の膜厚よりも薄く、かつ、隣り合う色同士のカラーフィルタ層の隣接部分は、隣り合う色同士の前記反射対向フィルタ部分と前記透過対向フィルタ部分とが隣接したものであることを特徴とする液晶表示素子である。
【0016】
このような構成により、簡易にカラーフィルタを製造でき、また、そのカラーフィルタを用いることで明るく、コントラストがよい、かつ色再現性のある液晶表示素子を得ることができる。
【0017】
【発明の実施の形態】
以下、本発明の実施の形態を示す液晶表示素子とその製造方法について、図面を参照にしながら説明する。
【0018】
(実施の形態1)
図1は半透過型液晶表示素子の構成図である。まず、透明基板1aの内側は赤(R)、緑(G)、青(B)からなるカラーフィルタ2を形成している。色についてはイエロー(Y)、シアン(C)、マゼンタ(M)でもよく、複数の色からなる。また、図1で示すように、1画素が透過部3と反射部4からできている。透過部3は従来の透過型液晶パネルと同じ構成になっており、表示側から偏光板5a、透明基板1a、カラーフィルタ2a、透明電極6a、液晶層7、透明電極6b、透明基板1b、偏光板5bの順になる。外側からはバックライト8により照射した光線が透過部3を通過し、表示側に出射されて、液晶層7のシャッター機能のスイッチングにより文字や映像が表示される。
【0019】
一方、同じ画素の反射部4の構成は表示側から偏光板5a、カラーフィルタ2b、透明電極6a、液晶層7、反射電極9、散乱形状膜10、透明基板1bからなる。表示側から照射された光線は液晶パネルの反射部4の液晶層7を通過し、反射電極9で反射し、元の液晶層7を通過して二度目の透明電極6aとカラーフィルタ2bを通過する。その際、液晶層7のスイッチングにより文字や映像を表示することができる。
【0020】
図2で示すように、カラーフィルタ2を通過する回数が反射部4では2回、透過部3で1回となる。しかし、両者のカラーフィルタ2の濃度は同じであるため、反射部4は濃くなり、透過部3では薄くなる。本発明では、この問題を解決するため、透過部3のカラーフィルタ2の膜厚が反射部4のものより厚く設計している。理想では透過部3は反射部4の2倍の厚みとするのが相応しい。また、カラーフィルタ2の使われるすべての色に、この方法を適用すればよい。
【0021】
また、図1で述べた散乱形状膜10は透過性を有する場合は透過部3にも位置しても良い。また、図3で示すような前方散乱膜10を用いた場合でも、画素を透過部3と反射部4に分割するとカラーフィルタ2の構成は上記と同じように反射部4は薄く、透過部3は厚くするとよい。その他の構成では、散乱膜10をカラーフィルタ2の内側に設けたり、或いはカラーフィルタ2そのものに散乱機能を含めた場合でもカラーフィルタ2の膜厚は、反射部4は薄く、透過部3は厚くするとよい。
【0022】
次に、液晶モードはSTNやTNのようなパッシブマトリクスであろうが、TFTやMIM(TFD)のようなアクティブマトリクスであっても、上記のような構成を用いれば半透過型として液晶パネルにすることができる。
【0023】
以上のように、本発明ではカラーフィルタ2の各画素の中で膜厚が2つ以上違う画素を形成し、1つの画素を反射部4と透過部3に分けて半透過型液晶パネルを形成する際に、反射部4はカラーフィルタ2の膜厚を薄くし、透過部3は厚くするものである。これにより、液晶層7を通過する光線が反射部4ではカラーフィルタ2を2回通過し、透過部3では1回通過するので、同じ濃度のカラーフィルタ2を使った場合、反射・透過の各々の色再現性が充実したものとなる。
【0024】
(実施の形態2)
次に、上記で示す1画素内で2つ以上の膜厚の違うカラーフィルタ2の製造方法について述べる。
【0025】
以下、本発明の実施の形態にもとづく液晶表示素子に用いるカラ−フィルタ2を有する透明基板1aについて図3を用いて説明する。
【0026】
まず、図3(a)に示すように、ガラス基板1a上にBM(ブラックマトリクス)11を形成する方法には、クロム膜を予め成膜してエッチングにより形成するタイプと、顔料分散樹脂ブラックレジストを用いてスピン法で形成したり、またはフィルムに顔料分散樹脂ブラックレジストを予め塗布した着色フィルムをラミネ−トして形成した後、露光・現像により、所要パタ−ン形状の樹脂BM11をパタ−ニングするタイプがある。液晶パネルの用途に応じて使いわけをすればよいが、今回は1〜2μmの樹脂BMを用いた例について説明する。
【0027】
次に、図3(b)に示すように、1画素内の膜厚の違うカラーフィルタであるRGB(R2a、2b、G2a、G2b、B2a、B2b)を上記のBM上にそれぞれ顔料レジスト膜を形成した後、露光・現像することにより所定パタ−ン形状に形成する方法を述べる。着色膜の膜厚は、完成後0.5〜2μmになるようスピン塗布条件または着色フィルム膜の膜厚を調整する。
【0028】
図3(c)に示すように、フォトマスク12を用いて露光する。この時に用いるフォトマスク12は、画素の透過部となるカラーフィルタの赤(R)の画素内透過部分は,全透過12aにし、画素の反射部となるカラーフィルタRの画素内反射部4は、ハ−フト−ン12bとした。その他の領域はブランク12cとした。このハ−フト−ンの領域12bのパタ−ン形状は、マスクのクロム膜をスリットパターン、ラインパタ−ン、ホ−ルパタ−ン、ドットパターン等を例えば5μm程度の微細パターンを用いたり、クロム膜の膜厚を薄くしたりして、露光量に応じて可変した設計することにより形成する。また、この時の露光量はカラーフィルタR2を形成する膜厚、感光性樹脂膜R2の感度より決定する。この後、現像を行うことにより、カラーフィルタR2の膜厚の違う画素を形成した。ハーフトーン12bはカラーフィルタR2bの膜厚が薄くなり、反射部4となる。また、ブランク12cはカラーフィルタR2aとなり、膜厚が厚く、透過部3を形成する。両者の膜厚差は約2倍となる。このような手順で、他の色である緑(G)、青(B)を繰り返し形成する。
【0029】
最後に,図1(d)に示すように,この基板上にITOを所要パタ−ン形状,所望膜厚に形成する。
【0030】
【発明の効果】
以上のように、本発明によれば、簡易にカラーフィルタを得られ、また、そのカラーフィルタを用いることで明るく、コントラストがよい、かつ色再現性のある液晶表示素子を得ることができる。
【図面の簡単な説明】
【図1】本発明の実施例の液晶表示素子の断面図
【図2】本発明の実施例の概念図
【図3】本発明の実施例のカラーフィルタの製造フローチャート
【図4】従来の液晶表示素子の断面図
【符号の説明】
1a、1b 透明基板
2、2a、2b カラーフィルタ
3 透過型
4 反射型
6、6a、6b 透明電極
9 反射板
10 散乱膜
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a liquid crystal display element used for OA equipment such as a personal computer, a word processor, and a monitor display, and a portable information communication equipment, a color filter used therefor, and a manufacturing method thereof.
[0002]
[Prior art]
Originally, since a liquid crystal display element is a light receiving element, there are three types: a transmissive type that requires a light source, a reflective type that uses external light, and a transflective type that has both functions of a reflective type and a transmissive type. In particular, as shown in FIG. 4, a conventional liquid crystal display element in a transflective type has a pair of opposing transparent substrates 1a and 1b each having a transparent display electrode on the inner side and a film retardation on the outer side. A plate 13a, 13b, a pair of polarizing plates 5a, 5b across the film retardation plates 13a, 13b and transparent substrates 1a, 1b, and a half mirror plate 14 on the opposite side of the incident light are provided to constitute a liquid crystal display element. ing. For color correspondence, a color filter 2 is formed inside the upper transparent substrate 1a. A backlight 8 is installed outside the half mirror plate. In the case of the STN mode, one or two film retardation plates 13 are used, and the arrangement locations are also arranged on the upper side, lower side, or upper and lower sides of the transparent substrates 1a and 1b, and the characteristics required in consideration of retardation and the like. Optimize accordingly. In the case of the TN mode of TFT, the film retardation plate 13 is not required.
[0003]
The half mirror plate 14 used in the conventional configuration is a thin film made of -Ag alloy formed on the polarizing plate 5b, and has a thickness of 50 nm. When such a thin film is used, in the reflection type, the backlight 8 is turned off, the half mirror is handled as a reflection plate, and the display on the liquid crystal panel can be viewed by ambient ambient light. In the transmissive type, when the backlight 8 is turned on, the light amount of the backlight 8 is transmitted through the liquid crystal panel, so that the display on the liquid crystal panel can be seen. In this way, by taking advantage of the characteristics of the half mirror 14, it is possible to use both a reflection type and a transmission type.
[0004]
[Problems to be solved by the invention]
However, in the conventional transflective liquid crystal panel, since the reflecting plate has transparency, when used as a transmissive type, the black level floats and the contrast is lowered, and a clear display cannot be obtained. Further, when used as a reflection type, there is a problem that a sufficient reflectance for obtaining a bright display cannot be obtained.
[0005]
Therefore, the above problem can be solved by providing a transmissive part and a reflective part in one pixel of the liquid crystal panel. However, when the color filter layers are all the same thickness, the display characteristics caused by the different transmissive thickness are not satisfactory. was there.
[0006]
[Means for Solving the Problems]
In order to achieve this object, according to the present invention, a color filter layer of a plurality of colors is arranged in a specific pattern on one of a pair of opposing substrates on which a liquid crystal is sandwiched, and the other substrate Is a liquid crystal display element in which a reflective portion that reflects external light and a transmissive portion that transmits backlight light are formed in a pixel unit, and the color filter layer is formed on the reflective portion in each color. and one reflection opposing filter portion facing consists of a single transparent opposing filter portion opposed to said transparent portion, the thickness of the reflective face filter portion thinner than the thickness of the transparent opposing filter portion and, adjacent The adjacent portion of the color filter layers of matching colors is a liquid crystal display in which the reflection facing filter portion and the transmission facing filter portion of adjacent colors are adjacent to each other It is a child.
[0016]
With such a configuration, a color filter can be easily manufactured, and a liquid crystal display element that is bright, has good contrast, and has color reproducibility can be obtained by using the color filter.
[0017]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, a liquid crystal display device and a manufacturing method thereof according to an embodiment of the present invention will be described with reference to the drawings.
[0018]
(Embodiment 1)
FIG. 1 is a configuration diagram of a transflective liquid crystal display element. First, a color filter 2 made of red (R), green (G), and blue (B) is formed inside the transparent substrate 1a. The color may be yellow (Y), cyan (C), magenta (M), and is composed of a plurality of colors. Further, as shown in FIG. 1, one pixel is made up of a transmission part 3 and a reflection part 4. The transmissive portion 3 has the same configuration as a conventional transmissive liquid crystal panel. From the display side, the polarizing plate 5a, the transparent substrate 1a, the color filter 2a, the transparent electrode 6a, the liquid crystal layer 7, the transparent electrode 6b, the transparent substrate 1b, and the polarization It becomes the order of the board 5b. From the outside, the light irradiated by the backlight 8 passes through the transmission part 3 and is emitted to the display side, and characters and images are displayed by switching the shutter function of the liquid crystal layer 7.
[0019]
On the other hand, the configuration of the reflective portion 4 of the same pixel is composed of a polarizing plate 5a, a color filter 2b, a transparent electrode 6a, a liquid crystal layer 7, a reflective electrode 9, a scattering shape film 10, and a transparent substrate 1b from the display side. Light rays irradiated from the display side pass through the liquid crystal layer 7 of the reflection part 4 of the liquid crystal panel, are reflected by the reflective electrode 9, pass through the original liquid crystal layer 7 and pass through the second transparent electrode 6a and the color filter 2b. To do. At that time, characters and images can be displayed by switching the liquid crystal layer 7.
[0020]
As shown in FIG. 2, the number of times of passing through the color filter 2 is two for the reflection unit 4 and one for the transmission unit 3. However, since the density of the two color filters 2 is the same, the reflection portion 4 is dark and the transmission portion 3 is thin. In the present invention, in order to solve this problem, the thickness of the color filter 2 of the transmissive portion 3 is designed to be thicker than that of the reflective portion 4. Ideally, it is appropriate that the transmissive part 3 is twice as thick as the reflective part 4. Further, this method may be applied to all colors used in the color filter 2.
[0021]
Moreover, the scattering shape film | membrane 10 described in FIG. 1 may be located also in the permeation | transmission part 3, when it has permeability | transmittance. Further, even when the forward scattering film 10 as shown in FIG. 3 is used, when the pixel is divided into the transmission part 3 and the reflection part 4, the configuration of the color filter 2 is the same as described above, the reflection part 4 is thin, and the transmission part 3 Should be thicker. In other configurations, even when the scattering film 10 is provided inside the color filter 2 or the scattering function is included in the color filter 2 itself, the thickness of the color filter 2 is thin in the reflection portion 4 and thick in the transmission portion 3. Good.
[0022]
Next, the liquid crystal mode will be a passive matrix such as STN or TN, but even if it is an active matrix such as TFT or MIM (TFD), if the above configuration is used, it will be a transflective liquid crystal panel. can do.
[0023]
As described above, in the present invention, two or more different pixels are formed in each pixel of the color filter 2, and one pixel is divided into the reflective portion 4 and the transmissive portion 3 to form a transflective liquid crystal panel. In this case, the reflective part 4 is used to make the color filter 2 thinner and the transmissive part 3 is made thicker. As a result, the light beam that passes through the liquid crystal layer 7 passes through the color filter 2 twice in the reflection unit 4 and passes through the transmission unit 3 once. Therefore, when the color filter 2 of the same density is used, each of reflection and transmission is performed. The color reproducibility will be enhanced.
[0024]
(Embodiment 2)
Next, a method for manufacturing the color filter 2 having two or more different film thicknesses in one pixel as described above will be described.
[0025]
Hereinafter, a transparent substrate 1a having a color filter 2 used for a liquid crystal display element according to an embodiment of the present invention will be described with reference to FIG.
[0026]
First, as shown in FIG. 3A, a method of forming a BM (black matrix) 11 on a glass substrate 1a includes a type in which a chromium film is formed in advance and formed by etching, and a pigment-dispersed resin black resist. Or by laminating a colored film in which a pigment-dispersed resin black resist is previously applied to the film, and then patterning the resin BM11 having the required pattern shape by exposure and development. There is a type to ning. Although what is necessary is just to use properly according to the use of a liquid crystal panel, the example using 1-2 micrometers resin BM is demonstrated this time.
[0027]
Next, as shown in FIG. 3B, RGB (R2a, 2b, G2a, G2b, B2a, B2b), which are color filters having different film thicknesses in one pixel, are respectively formed on the BM with a pigment resist film. A method of forming a predetermined pattern by exposing and developing after formation will be described. The film thickness of the colored film is adjusted so that the film thickness of the colored film is 0.5 to 2 μm after completion.
[0028]
As shown in FIG. 3C, exposure is performed using a photomask 12. In the photomask 12 used at this time, the red (R) in-pixel transmission portion of the color filter that becomes the transmission portion of the pixel is set to the total transmission 12a, and the in-pixel reflection portion 4 of the color filter R that becomes the reflection portion of the pixel is Halftone 12b was obtained. The other areas were blanks 12c. The pattern shape of the half-tone region 12b is such that the chrome film of the mask uses a fine pattern such as a slit pattern, a line pattern, a hole pattern, a dot pattern, etc. of about 5 μm, or a chrome film. It is formed by reducing the thickness of the film and designing it so as to be variable according to the exposure amount. The exposure amount at this time is determined by the film thickness for forming the color filter R2 and the sensitivity of the photosensitive resin film R2. Thereafter, development was performed to form pixels with different thicknesses of the color filter R2. In the halftone 12b, the color filter R2b has a thin film thickness, and becomes the reflection portion 4. Further, the blank 12c becomes the color filter R2a, has a large film thickness, and forms the transmission part 3. The difference in film thickness between the two is about twice. In this procedure, other colors, green (G) and blue (B), are repeatedly formed.
[0029]
Finally, as shown in FIG. 1 (d), ITO is formed in a required pattern shape and a desired film thickness on this substrate.
[0030]
【The invention's effect】
As described above, according to the present invention, a color filter can be easily obtained, and by using the color filter, a bright liquid crystal display element with good contrast and color reproducibility can be obtained.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a liquid crystal display element according to an embodiment of the present invention. FIG. 2 is a conceptual diagram of an embodiment of the present invention. Cross section of display element 【Explanation of symbols】
1a, 1b Transparent substrate 2, 2a, 2b Color filter 3 Transmission type 4 Reflection type 6, 6a, 6b Transparent electrode 9 Reflecting plate 10 Scattering film

Claims (1)

液晶が挟持される、対向する一対の基板のうちいずれか一方の基板上には、複数色のカラーフィルタ層が特定のパターンで画素配列され、他方の基板には、画素単位の中に外光を反射する反射部分と、バックライト光を透過する透過部分とが形成された液晶表示素子であって
前記カラーフィルタ層は、各色において、前記反射部分に対向する 1 つの反射対向フィルタ部分と、前記透過部分に対向する 1 つの透過対向フィルタ部分とからなり、前記反射対向フィルタ部分の膜厚は前記透過対向フィルタ部分の膜厚よりも薄く、
かつ、隣り合う色同士のカラーフィルタ層の隣接部分は、隣り合う色同士の前記反射対向フィルタ部分と前記透過対向フィルタ部分とが隣接したものであることを特徴とする液晶表示素子。
A pixel array of a plurality of color filter layers is arranged in a specific pattern on one of a pair of opposing substrates between which a liquid crystal is sandwiched, and the other substrate has external light in a pixel unit. A liquid crystal display element in which a reflective part that reflects light and a transmissive part that transmits backlight light are formed ,
The color filter layer in each color, and one reflector facing the filter portion opposed to the reflective portion, consists of a single transparent opposing filter portion opposed to said transparent portion, the thickness of the reflective face filter portion the transmission It is thinner than the thickness of the counter filter part,
In addition, the adjacent portion of the color filter layers of adjacent colors is a liquid crystal display element in which the reflection facing filter portion and the transmission facing filter portion of adjacent colors are adjacent to each other .
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KR100750927B1 (en) * 2001-06-01 2007-08-22 삼성전자주식회사 a color filter substrate and a method for manufacturing the same, and a liquid crystal display of a reflection-transmission type including the color filter substrate
JP4749678B2 (en) * 2003-04-30 2011-08-17 サムスン エレクトロニクス カンパニー リミテッド Liquid crystal display device and manufacturing method thereof
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