JP3688794B2 - Manufacturing method of solid lubricant sealed bearing - Google Patents

Manufacturing method of solid lubricant sealed bearing Download PDF

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Publication number
JP3688794B2
JP3688794B2 JP3937196A JP3937196A JP3688794B2 JP 3688794 B2 JP3688794 B2 JP 3688794B2 JP 3937196 A JP3937196 A JP 3937196A JP 3937196 A JP3937196 A JP 3937196A JP 3688794 B2 JP3688794 B2 JP 3688794B2
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Japan
Prior art keywords
molecular weight
bearing
solid lubricant
mixture
manufacturing
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JP3937196A
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Japanese (ja)
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JPH09227885A (en
Inventor
光成 麻生
英信 三上
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NTN Corp
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NTN Corp
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【0001】
【発明の属する技術分野】
この発明は、転がり軸受等の軸受内に固形潤滑剤を封入した固形潤滑剤封入軸受の製造方法に関する。
【0002】
【従来の技術】
従来、軸受に用いられる潤滑油及びポリエチレンからなる固形潤滑剤として、米国特許第3,541,011号公報、米国特許第3,547,819号公報、米国特許第3,729,415号公報等に開示されている。
【0003】
【発明が解決しようとする課題】
しかしながら、上記潤滑油にポリエチレンの粉末を用いた潤滑剤は、混合した段階では固液混合体であるため、これを軸受に注入する製造工程において、軸受より漏れるので、加熱固化が完了までシール装置が必要となり、製造工程が煩雑になる問題がある。
【0004】
そこで、この発明の課題は、上記問題点を解決し、固形潤滑剤を封入する軸受の製造方法において、固化前の潤滑剤を容易に軸受内に保持できる製造方法を提供することにある。
【0005】
【課題を解決するための手段】
上記の課題を解決するため、この発明においては、潤滑油と、高分子量ポリオレフィン粉末又は超高分子量ポリオレフィン粉末との混合物を90〜120℃に加熱して半固形状化し、これを軸受内部に注入した状態で上記高分子量ポリオレフィン又は超高分子量ポリオレフィンのゲル化点以上の温度に加熱し、その後冷却、固化することからなる固形潤滑剤封入軸受の製造方法を採用したのである。
【0006】
潤滑油に、高分子量ポリオレフィン粉末又は超高分子量ポリオレフィン粉末を混合したものを90〜120℃に加熱したので、この混合物はグリース状となり、軸受に注入しやすく、また注入された上記混合物は、軸受より漏れを生じない。
【0007】
【発明の実施の形態】
以下、この発明の実施形態を説明する。
この発明における高分子量ポリオレフィン粉末又は超高分子量ポリオレフィン粉末は、ポリエチレン、ポリプロピレン、ポリブテンの高分子量体又は超高分子量体、若しくはこれらの共重合体の高分子量体又は超高分子量体からなる粉末でよい。また、粘度法により測定される重量平均分子量は、高分子量体では1×105 〜1×106 、超高分子量体では1×106 〜5×106 である。このような重量平均分子量の範囲にあるポリオレフィンは、剛性、保油性において優れ、高温に加熱してもほとんど流動することがない。このような超高分子量ポリオレフィン粉末の市販品として、三井石油化学社製:ミペロンを使用することができる。
【0008】
また、この発明における潤滑油は、各種の潤滑油を用いることができ、例として、鉱油、合成炭化水素油、ポリアルキルグリコール油、ジエステル油、ポリオールエステル油、リン酸エステル油、ポリフェニルエーテル油等があげられる。
【0009】
この発明における固形潤滑剤中の、高分子量ポリオレフィン粉末又は超高分子量ポリオレフィン粉末の配合割合は、特に限定されるものではないが、95〜5重量%が好ましく、この範囲で上記固形潤滑剤組成物の所要の離油度、粘り強さ及び硬さに対応させて増減させて配合することができる。ただし、上記高分子量ポリオレフィン又は超高分子量ポリオレフィンの量が多いほど、ゲル化点以上の温度に加熱し、その後冷却、固化させた後のゲルの硬さが大きくなる。
【0010】
この発明の固形潤滑剤注入軸受の製造方法は、上記潤滑油と上記高分子量ポリオレフィン粉末又は超高分子量ポリオレフィン粉末を混合し、固液の懸濁状態とし、この状態で90〜120℃に加熱する。この加熱により、潤滑油はポリオレフィン粉末の増稠作用を受け、上記混合物は、半固形状態、すなわち、グリース状態となる。
【0011】
次いで、90〜120℃に保持してグリース状のまま、軸受内に注入する。その注入の方法は、例えば、図1(a)(b)に示されるように、ベアリングの内輪1と外輪2の間で二枚の帯板からなる保持器3がリベット4によって重ねて固定されている部分に、いわゆるスポットパック状に注入するものや、図2(a)(b)に示されるように、ベアリングの内輪1と外輪2の間全体に、いわゆるフルパック状に状に充填するものがあげられる。
【0012】
上記グリース状の混合物が注入された状態では、混合物は半固形状であって、シール装置がなくても軸受外に流出することはない。したがって、この状態の軸受全体を、上記高分子量ポリオレフィン粉末又は超高分子量ポリオレフィン粉末がゲル化を起こす温度以上の温度に加熱し、その後、冷却、固形化することにより、上記グリース状物が固形化して固形潤滑剤となり、固形潤滑剤封入軸受が製造される。
【0013】
【実施例】
〔実施例1〜7〕
超高分子量ポリオレフィン(重量平均分子量200万、三井石油化学社製:ミペロン)、及び表1に記載の各潤滑油を原材料として、表1に示す配合割合(重量%)で常温で混合し、次いで混合を続けながら100℃に加熱した。上記混合物がグリース状になってから、ラジアル玉軸受(NTN社製:6204)に、図1に示すスポットパック状、または図2に示すフルパック状に注入した。その後、170℃まで加熱し、冷却して混合物を固形状化させた軸受を製造した。
【0014】
〔比較例1〜6〕
超高分子量ポリオレフィン(重量平均分子量200万、三井石油化学社製:ミペロン)、及び表1に記載の各潤滑油を原材料として、表1に示す配合割合(重量%)で混合し、ラジアル玉軸受(NTN社製:6204)に、図1に示すスポットパック状、または図2に示すフルパック状に注入しようとした。しかし、上記混合物が漏れてしまい、軸受内に注入することができず、固形潤滑剤の注入された軸受を製造できなかった。
【0015】
【表1】

Figure 0003688794
【0016】
【発明の効果】
この発明によれば、潤滑油に、高分子量ポリオレフィン粉末又は超高分子量ポリオレフィン粉末を混合したものを半固形状態で軸受内に注入し、その後加熱固化したので、固化前の潤滑剤を容易に軸受内に保持できるようになり、また注入された半固形状の潤滑剤は、軸受より漏れないので、製造工程を簡略化でき、注入作業も容易になる。また、上記混合物はグリース状なので、軸受内に種々の形状で注入できる利点もある。
【図面の簡単な説明】
【図1】(a)実施例で製造した固形潤滑剤封入軸受の平面図
(b)(a)の一部拡大断面図
【図2】(a)実施例で製造した他の固形潤滑剤封入軸受の平面図
(b)(a)の一部拡大断面図
【符号の説明】
1 内輪
2 外輪
3 保持器
4 リベット
5 固形潤滑剤
6 転動体[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for manufacturing a solid lubricant sealed bearing in which a solid lubricant is sealed in a bearing such as a rolling bearing.
[0002]
[Prior art]
Conventionally, as solid lubricants made of lubricating oil and polyethylene used for bearings, US Pat. No. 3,541,011, US Pat. No. 3,547,819, US Pat. No. 3,729,415, etc. Is disclosed.
[0003]
[Problems to be solved by the invention]
However, since the lubricant using polyethylene powder as the lubricating oil is a solid-liquid mixture at the mixing stage, it leaks from the bearing in the manufacturing process of injecting the lubricant into the bearing. There is a problem that the manufacturing process becomes complicated.
[0004]
Accordingly, an object of the present invention is to solve the above-described problems and provide a manufacturing method in which a lubricant before solidification can be easily held in a bearing in a manufacturing method of a bearing in which a solid lubricant is enclosed.
[0005]
[Means for Solving the Problems]
In order to solve the above problems, in the present invention, a mixture of lubricating oil and high molecular weight polyolefin powder or ultrahigh molecular weight polyolefin powder is heated to 90 to 120 ° C. to be semi-solid, and this is injected into the bearing. In this state, a method for producing a solid lubricant-enclosed bearing is adopted, in which the polymer is heated to a temperature equal to or higher than the gel point of the high molecular weight polyolefin or ultrahigh molecular weight polyolefin, and then cooled and solidified.
[0006]
A mixture of high molecular weight polyolefin powder or ultrahigh molecular weight polyolefin powder mixed with lubricating oil was heated to 90 to 120 ° C., so that this mixture became grease-like and easy to inject into the bearing. Less leaks.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below.
The high molecular weight polyolefin powder or ultrahigh molecular weight polyolefin powder in the present invention may be a powder comprising a high molecular weight body or ultrahigh molecular weight body of polyethylene, polypropylene, or polybutene, or a high molecular weight body or ultrahigh molecular weight body of these copolymers. . The weight average molecular weight measured by the viscosity method is 1 × 10 5 to 1 × 10 6 for the high molecular weight material, and 1 × 10 6 to 5 × 10 6 for the ultra high molecular weight material. A polyolefin having such a weight average molecular weight is excellent in rigidity and oil retention, and hardly flows even when heated to a high temperature. As a commercial product of such ultra-high molecular weight polyolefin powder, Miteron Petrochemical Co., Ltd. Miperon can be used.
[0008]
In addition, various lubricating oils can be used as the lubricating oil in the present invention, for example, mineral oil, synthetic hydrocarbon oil, polyalkyl glycol oil, diester oil, polyol ester oil, phosphate ester oil, polyphenyl ether oil. Etc.
[0009]
The blending ratio of the high molecular weight polyolefin powder or the ultrahigh molecular weight polyolefin powder in the solid lubricant in the present invention is not particularly limited, but is preferably 95 to 5% by weight, and the solid lubricant composition is within this range. The amount of oil can be increased or decreased in accordance with the required degree of oil separation, tenacity and hardness. However, as the amount of the high molecular weight polyolefin or the ultra high molecular weight polyolefin increases, the hardness of the gel after being heated to a temperature equal to or higher than the gel point and then cooled and solidified increases.
[0010]
In the method for producing a solid lubricant injection bearing according to the present invention, the lubricating oil and the high molecular weight polyolefin powder or ultrahigh molecular weight polyolefin powder are mixed to form a solid-liquid suspension, and heated to 90 to 120 ° C. in this state. . By this heating, the lubricating oil is subjected to a thickening action of the polyolefin powder, and the above mixture becomes a semi-solid state, that is, a grease state.
[0011]
Next, the mixture is poured into the bearing while maintaining a grease state while maintaining the temperature at 90 to 120 ° C. For example, as shown in FIGS. 1 (a) and 1 (b), the injection method is such that a cage 3 composed of two strips is overlapped and fixed between rivets 4 between an inner ring 1 and an outer ring 2 of the bearing. As shown in FIGS. 2A and 2B, the entire portion between the inner ring 1 and the outer ring 2 of the bearing is filled in a so-called full pack shape. Things can be raised.
[0012]
When the grease-like mixture is injected, the mixture is semi-solid and does not flow out of the bearing without a sealing device. Therefore, the entire bearing in this state is heated to a temperature equal to or higher than the temperature at which the high molecular weight polyolefin powder or the ultrahigh molecular weight polyolefin powder causes gelation, and then cooled and solidified to solidify the grease-like material. Thus, a solid lubricant encapsulated bearing is manufactured.
[0013]
【Example】
[Examples 1-7]
Using ultra-high molecular weight polyolefin (weight average molecular weight 2 million, manufactured by Mitsui Petrochemical Co., Ltd .: Mipperon) and each lubricating oil listed in Table 1 as raw materials, they were mixed at room temperature at the blending ratio (% by weight) shown in Table 1, and then Heated to 100 ° C. with continued mixing. After the mixture became grease-like, it was poured into a radial ball bearing (NTN Corp .: 6204) in a spot pack shape shown in FIG. 1 or a full pack shape shown in FIG. Then, the bearing which heated to 170 degreeC and cooled and solidified the mixture was manufactured.
[0014]
[Comparative Examples 1-6]
Radial ball bearings by mixing ultra-high molecular weight polyolefin (weight average molecular weight 2 million, manufactured by Mitsui Petrochemical Co., Ltd .: Mipperon) and each lubricating oil listed in Table 1 at the blending ratio (% by weight) shown in Table 1. (NTN Co., Ltd .: 6204) tried to be injected into the spot pack shape shown in FIG. 1 or the full pack shape shown in FIG. However, the mixture leaked and could not be injected into the bearing, and a bearing into which a solid lubricant was injected could not be manufactured.
[0015]
[Table 1]
Figure 0003688794
[0016]
【The invention's effect】
According to the present invention, a mixture of high-molecular-weight polyolefin powder or ultra-high-molecular-weight polyolefin powder mixed with lubricating oil is injected into the bearing in a semi-solid state and then heated and solidified. The semi-solid lubricant that has been injected can be prevented from leaking from the bearing, so that the manufacturing process can be simplified and the injection operation can be facilitated. Further, since the mixture is in the form of grease, there is an advantage that it can be injected into the bearing in various shapes.
[Brief description of the drawings]
1A is a plan view of a solid lubricant encapsulated bearing manufactured in an embodiment. FIG. 1B is a partially enlarged cross-sectional view of FIG. 2A. FIG. 2A is another solid lubricant encapsulated in an embodiment. Plan view of bearing (b) Partial enlarged sectional view of (a) [Explanation of symbols]
1 Inner ring 2 Outer ring 3 Cage 4 Rivet 5 Solid lubricant 6 Rolling element

Claims (1)

潤滑油と、重量平均分子量が1×10 5 〜1×10 6 ポリオレフィン粉末又は重量平均分子量が1×10 6 〜5×10 6 ポリオレフィン粉末との混合物を90〜120℃に加熱して半固形状化し、これをシール装置を有さない軸受内部に注入し、次いでこの軸受全体を、上記の重量平均分子量が1×10 5 〜1×10 6 ポリオレフィン又は重量平均分子量が1×10 6 〜5×10 6 ポリオレフィンのゲル化点以上の温度に加熱し、その後冷却、固化することからなる固形潤滑剤封入軸受の製造方法。Lubricating oil and semi by heating a mixture of polyolefin powder of polyolefin powder or a weight average molecular weight of weight average molecular weight of 1 × 10 5 ~1 × 10 6 is 1 × 10 6 ~5 × 10 6 to 90 to 120 ° C. solid was Joka, which was injected into the bearing without a sealing device, then the entire bearing, polyolefin or weight-average molecular weight of weight average molecular weight of above 1 × 10 5 to 1 × 10 6 of 1 × 10 A method for producing a solid lubricant-enclosed bearing comprising heating to a temperature equal to or higher than the gelling point of 6 to 5 × 10 6 polyolefin, followed by cooling and solidification.
JP3937196A 1996-02-27 1996-02-27 Manufacturing method of solid lubricant sealed bearing Expired - Lifetime JP3688794B2 (en)

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JP3688794B2 true JP3688794B2 (en) 2005-08-31

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