JP3679395B2 - Manufacturing method of resin molded body reinforced with back surface - Google Patents
Manufacturing method of resin molded body reinforced with back surface Download PDFInfo
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- JP3679395B2 JP3679395B2 JP2002327028A JP2002327028A JP3679395B2 JP 3679395 B2 JP3679395 B2 JP 3679395B2 JP 2002327028 A JP2002327028 A JP 2002327028A JP 2002327028 A JP2002327028 A JP 2002327028A JP 3679395 B2 JP3679395 B2 JP 3679395B2
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- molded body
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Description
【0001】
【発明の属する技術分野】
この発明は、浴槽、洗面ボール、貯水槽その他の容器状の樹脂成形体の製造方法に関し、特に表側用の樹脂成形体と繊維強化樹脂(FRP)層を積層一体化して補強するという裏面補強された樹脂成形体の製造方法に関する。
【0002】
【従来の技術】
一般に、浴槽や洗面ボールなどの裏面が繊維補強された合成樹脂成型品は、良質の質感ある表面を構成するアクリル樹脂などの熱可塑性樹脂成型品を、予め真空成型や圧空成型によって形成しておき、次いで熱可塑性樹脂成型品の強度を向上させるために、その裏面に合成樹脂およびガラス繊維などの補強繊維材料(ガラス予備成型品:プリフォームであってもよい。)を沿わせて雄型と裏型の間で型締めし、さらに加熱成型を行なって一体成型している。
【0003】
図4および図5を参照して、具体的に、FRPで補強された樹脂成形体の製造工程を説明する。
【0004】
まず、材料の熱可塑性樹脂板(図外)に対し、設計された型10を用いて真空成形または圧空成形をして浴槽などの成形体表側を薄肉の熱可塑性樹脂成形品11として作製しておき、次いで、別途用意した雌型12と雄型13とからなる注型成型用の型(キャビティー)内に熱可塑性樹脂成形品11と補強用繊維材14等を両方収容して、雌型12と雄型13とを組み合わせて型締めし、形成された密閉空間(セル)内にゲート15から重合硬化性樹脂原料を注入し、これを重合硬化させた後、脱型する周知のFRP積層成形工程によって製造されている(例えば、特許文献1参照。)。
【0005】
【特許文献1】
特開平11−291333号公報(段落「0009」、「0021」、図1、図3)
【0006】
【発明が解決しようとする課題】
しかし、上記した従来のFRP積層の成形工程では、熱可塑性樹脂成形品と補強用繊維材等を収容し、裏型と雄型を組み合わせて型締めし、形成された密閉空間(セル)内にゲートから重合硬化性樹脂原料を注入し、プリフォームを加圧する工程が必要であるために、強度の高い裏型と雄型とからなる一対の型が必要であり、これでは型の製造費用やガラス補強用繊維材に樹脂を予め含浸させたプリフォームなどの作製工程にコストが多くかかるので、製造工程の簡略化が困難であった。
【0007】
また、浴槽などの大型の成型品を製造する際に、大きな型を用いながら移動させることは困難であるから、ライン生産工程が困難であり、大量生産を行なうことは容易でなかった。
【0008】
また、強度の高い裏型と雄型の設計変更は困難であるから、新しいデザインに素早く対応する応答性が充分ではなく、特に成型品の肉厚変更でも新しい型の準備が必要となり、設計変更の要請に簡単かつ速やかに対応できなかった。
【0009】
そこで、この発明の課題は、上記した問題点を解決して製造工程における成型用の型の数を減らすことができ、さらには設計変更の要請に即応でき、また補強用繊維材に対して含浸量が均一で注型を確実におこなうことができ、もって製造コストの低減に役立つ裏面補強された樹脂成形体の製造方法とすることである。
【0010】
【課題を解決するための手段】
上記の課題を解決するために、この発明においては、表側用の樹脂成形体を設けておき、この表側用樹脂成形体の裏面に補強用繊維材を介して裏型を重ね合わせると共に、この裏型の周縁と前記表側用樹脂成形体の周縁とを密封し、次いで密封された裏型と表側用樹脂成形体との間隙を減圧した後、この減圧された間隙に液状樹脂材料を注入し、これを硬化させて前記表側用樹脂成形体と補強用繊維材とを一体化することからなる裏面補強された樹脂成形体の製造方法としたのである。
【0011】
上記した工程による裏面補強された樹脂成形体の製造方法では、密封された裏型と、予め成形しておいた表側用樹脂成形体との間隙を減圧し、その後、この間隙に液状樹脂材料を注入するので、減圧によって小体積になっている補強用繊維材に液状樹脂材料が速やかにしみこみ、これにより狭い間隙に簡単にかつ確実に液状樹脂材料を注入し均一に充填することができる。また、従来の成形方法のように、液状樹脂材料を加圧しなくてよいので、重厚かつ強固な雄雌の成形型が必要でなくなり、比較的低強度の薄肉の裏型のみで表側用樹脂成形体と補強用繊維材とを一体化させてバックアップ注型による裏面補強をすることができる。
【0012】
これにより、製造ライン工程で型を移動させながら、裏面補強された樹脂成形体を効率よく製造することができる。
また、この製造方法では、薄肉の裏型のみでバックアップ注型するから、成形・硬化時の成形体の膨張や収縮に対して型の追従性または許容量が適当にあり、脱型の際には成形体を損傷することもなく、また製品となった成形体に部分的な割れや歪がなく、高品質で安定した成形体を製造でき、歩留まりを向上させる製造方法であるともいえる。
【0013】
また、比較的広い面積の浴槽などの成形体に対して、全面にむらなく液状樹脂材料を充填するためには、上記の裏面補強された樹脂成形体の製造方法において、液状樹脂材料の注入を裏型の周縁から行ない、この裏型の周縁より中央に近い部分には裏型と表側用樹脂成形体との間隙を狭める帯状隆起部を設け、この帯状隆起部を越えないように周縁の裏型と表側用樹脂成形体との間隙に液状樹脂を一時的に滞留させることを特徴とする請求項1記載の裏面補強された樹脂成形体の製造方法とすることが好ましい。
【0014】
このようにすると、液状樹脂材料を注入したとき、直ちに裏型の中央にまでランダムに流入せず、樹脂材料は、一旦、裏型と表側用樹脂成形体との間隙を狭める帯状隆起部に堰き止められて、裏型と表側用樹脂成形体との所定体積の間隙に一時的に滞留し、次いで、その間隙内に樹脂が一杯に充填されると、一挙に帯状隆起部を越えて、その後は全周縁からほぼ同じ流速で中央に向かって流入し、キャビティー内はむらなく均一に充填される。
【0015】
また、このような作用を確実に奏するために、表側用樹脂成形体が、上面開口の容器状の表側用樹脂成形体であり、前記開口部の周縁は外向きに折り返して容器外壁に沿わせたフランジを形成し、このフランジに沿う裏型の周縁には液状樹脂材料の注入口を配置して注入する裏面補強された樹脂成形体の製造方法とすることが好ましい。
【0016】
また、設計変更の要請のうち、樹脂成形体の肉厚を簡単に調整可能な裏面補強された樹脂成形体の製造方法とするために、上記したいずれかの裏面補強された樹脂成形体の製造方法において、裏型と表側用樹脂成形体との周縁同士の密封が、裏型の周縁に設けた環状の弾性パッキングをクランプで表側用樹脂成形体に密接させることであり、前記弾性パッキングは管状であり、中空部の気圧を調整して樹脂成形体の肉厚を調整可能としたのである。
【0017】
このようにすると、弾性パッキングの管状の中空部の気圧を高めると、裏型と表側用樹脂成形体との周縁同士の間隔を広げて密封することができ、厚肉の樹脂成形体を製造することができる。また、弾性パッキングの管状の中空部の気圧を低くすると、弾性パッキングは薄く扁平状になって薄肉の樹脂成形体を製造することができる。
【0018】
【発明の実施の形態】
この発明の実施形態を以下に添付図面に基づいて説明する。
【0019】
図1〜3に示すように、実施形態の製造方法は、先ず、槽(上面開口の大型容器)状である浴槽等の表側用樹脂成形体1を、予め真空成型または圧空成型によって作製しておき、この表側用樹脂成形体1の裏面を覆う裏型2のキャビティー内の略全域にマット状のガラス繊維からなる補強用繊維材3を収容している(図1中に図示せず、図3参照。)。
【0020】
表側用樹脂成形体1は、特にその材料を限定して成形したものではなく、成形品の目的に応じて、例えばアクリル樹脂、ポリスチレン樹脂、ポリプロピレン樹脂、ABS樹脂などの周知の樹脂からなるものを使用できる。
【0021】
そして、裏型2の上に表側用樹脂成形体1を重ね合わせて、裏型2の全周縁と表側用樹脂成形体1の全周縁とを環状のゴム製弾性パッキング4と、一対の枠5およびクランプ(図示せず。)で閉じ合わせて密封し、次いで密封された裏型2と表側用樹脂成形体1との間隙を底部のチャンバー付きの排気孔6から真空ポンプ(図示せず。)で排気して減圧している。
【0022】
次いで、1気圧未満で略真空になった間隙(キャビティー)にはウレタン樹脂などの液状樹脂材料を注入口から圧力差を利用して注入し、適当量を供給して充填させ、さらに加熱等により硬化させて表側用樹脂成形体1と補強用繊維材3および樹脂とを一体化させて裏面補強された樹脂成形体を得る。
【0023】
液状樹脂材料としては、上記したウレタン樹脂の他に不飽和ポリエステル樹脂、アクリル樹脂、ビニルエステル樹脂などの周知の樹脂を選択でき、前記した表側用樹脂成形体との密着および一体化の良いものを採用すればよい。
【0024】
浴槽の表側用樹脂成形体1は、開口部の周縁が下向きから水平ヘ、外向きに折り返されてフランジ状部1aを形成しており、このフランジ状部1aに液状樹脂材料の注入口7を設けている。
【0025】
液状樹脂材料の注入口7は、裏型2の周縁に適当な間隔で配置して適当な数だけ形成すればよく(図2では4箇所形成している。)、注入口7より中央側の裏型2の周縁に沿って一周する帯状隆起部8を設け、これにより液状樹脂材料を注入した時に、帯状隆起部8より外側の裏型2と表側用樹脂成形体1との間隙に液状樹脂を一時的に滞留させ、次いで液状樹脂材料が全周縁に設けた帯状隆起部8を越えた時に、全周から一挙に裏型2の中央へ向かって略均一な流速で流入させるようにしている。
【0026】
また、裏型2と表側用樹脂成形体1との周縁同士を密封させるために、裏型2の周縁に設けた環状の弾性パッキング4を、表側用樹脂成形体1およびその上面の弾性パッキング4と一対の枠5を介してクランプ(図示せず。)で密接させている。
【0027】
弾性パッキング4は管状のゴムからなり、中空部の気圧を図外のバルブから圧縮空気などを注入して弾性パッキング4の厚みを加減し、樹脂成形体の肉厚を調整することを可能としている。
【0028】
【発明の効果】
この発明は、以上説明したように、表側用樹脂成形体の裏面を覆う裏型のキャビティー内に補強用繊維材を収容し、表側用樹脂成形体を重ね合わせ、密封された間隙を減圧して液状樹脂材料を注入および硬化させて裏面補強された樹脂成形体を製造するので、キャビティー内に樹脂材料が均一に速やかに充填され、補強用繊維材に対して含浸量が均一で品質の良い注型を確実におこなうことができ、これにより品質の向上と製造コストの低減にも役立つ裏面補強された樹脂成形体の製造方法になるという利点がある。
【0029】
また、この製法によれば、圧縮成形のための一対の強固な型が必要でなく、成型用の型数を削減して簡単に製造でき、また薄肉の型を使用できて設計変更の要請に速やかに対応でき、製品となった成形体には割れや歪がなく、高品質で安定した成形体を製造でき、歩留まりが向上する。また、製造ライン工程で型を移動させながら、裏面補強された樹脂成形体を製造効率よく大量生産できる。
【0030】
また、中空の弾性パッキングをクランプで表側用樹脂成形体に密接させてシールする方法を採用すると、中空の弾性パッキングの厚さを中空内気圧で調整することにより、樹脂成形体の肉厚を簡単に調整可能な裏面補強された樹脂成形体の製造方法となる利点がある。
【図面の簡単な説明】
【図1】実施形態の製造方法を説明する密封された裏型と表側用樹脂成形体を示す断面図
【図2】実施形態の製造方法を説明する図1の平面図
【図3】実施形態の製造方法を説明する図1の要部を拡大して示す断面図
【図4】従来の製造方法を説明する型と熱可塑性樹脂成形品の断面図
【図5】従来の製造方法を説明する雄・雌型と補強された樹脂成形体の断面図
【符号の説明】
1 表側用樹脂成形体
1a フランジ状部
2 裏型
3 補強用繊維材
4 弾性パッキング
5 一対の枠
6 排気孔
7 注入口
8 帯状隆起部
10 型
11 熱可塑性樹脂成形品
12 雌型
13 雄型
14 補強用繊維材
15 ゲート[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method of manufacturing a container-shaped resin molded body such as a bathtub, a wash bowl, a water tank, and the like. The present invention relates to a method for producing a molded resin product.
[0002]
[Prior art]
In general, synthetic resin molded products whose back side is reinforced with fibers, such as bathtubs and wash bowls, are pre-formed by vacuum molding or compressed air molding, such as acrylic resin, which constitutes a high-quality textured surface. Then, in order to improve the strength of the thermoplastic resin molded product, a reinforcing fiber material such as a synthetic resin and glass fiber (glass preformed product: may be a preform) is placed on the back surface of the male mold. The molds are clamped between the back molds, and further molded by heating and integrally molded.
[0003]
With reference to FIG. 4 and FIG. 5, the manufacturing process of the resin molding reinforced with FRP is demonstrated concretely.
[0004]
First, the thermoplastic resin plate (not shown) of the material is subjected to vacuum forming or pressure forming using the designed
[0005]
[Patent Document 1]
Japanese Patent Laid-Open No. 11-291333 (paragraphs “0009” and “0021”, FIGS. 1 and 3)
[0006]
[Problems to be solved by the invention]
However, in the conventional FRP lamination molding process described above, a thermoplastic resin molded article and a reinforcing fiber material are accommodated, and the back mold and the male mold are combined and clamped, and the formed sealed space (cell) is formed. Since a process of injecting a polymer curable resin raw material from the gate and pressurizing the preform is necessary, a pair of molds consisting of a high-strength back mold and a male mold is required. Since a manufacturing process of a preform or the like in which a glass reinforcing fiber material is pre-impregnated with a resin is costly, it is difficult to simplify the manufacturing process.
[0007]
Further, when manufacturing a large molded product such as a bathtub, it is difficult to move while using a large mold, so that the line production process is difficult and mass production is not easy.
[0008]
In addition, because it is difficult to change the design of the back mold and male mold with high strength, the responsiveness to respond quickly to the new design is not sufficient, and it is necessary to prepare a new mold even if the thickness of the molded product is changed. We were unable to respond to the request easily and quickly.
[0009]
Therefore, the object of the present invention is to solve the above-mentioned problems, reduce the number of molds for molding in the manufacturing process, and can quickly respond to a request for a design change, and impregnate the reinforcing fiber material. It is a method for producing a resin molded body reinforced with a back surface that is uniform in amount and can be reliably cast, and that is useful for reducing the production cost.
[0010]
[Means for Solving the Problems]
In order to solve the above problems, in the present invention, a front side resin molded body is provided, and a back mold is superimposed on the back surface of the front side resin molded body via a reinforcing fiber material. After sealing the peripheral edge of the mold and the peripheral edge of the front side resin molded body, and then reducing the gap between the sealed back mold and the front side resin molded body, a liquid resin material is injected into the reduced gap, This is cured to provide a method for producing a resin molded body reinforced with the back surface comprising integrating the front-side resin molded body and the reinforcing fiber material.
[0011]
In the method of manufacturing the back side reinforced resin molded body according to the above-described process, the gap between the sealed back mold and the front side molded resin body is reduced in pressure, and then a liquid resin material is placed in the gap. Since the injection is performed, the liquid resin material quickly infiltrates the reinforcing fiber material having a small volume due to the reduced pressure, so that the liquid resin material can be easily and surely injected into the narrow gap and uniformly filled. Moreover, unlike the conventional molding method, it is not necessary to pressurize the liquid resin material, so there is no need for a heavy and strong male / female mold, and only a relatively low-strength thin mold is used for front side resin molding. The back surface can be reinforced by backup casting by integrating the body and the reinforcing fiber material.
[0012]
Accordingly, the resin molded body reinforced on the back surface can be efficiently manufactured while moving the mold in the manufacturing line process.
Further, in this manufacturing method, since the back-up casting is performed only with the thin back mold, the mold followability or tolerance is appropriate for the expansion and contraction of the molded body at the time of molding and curing, and at the time of demolding Can be said to be a production method that does not damage the molded body, and does not have partial cracks or distortions in the molded body that is a product, can produce a high-quality and stable molded body, and improves the yield.
[0013]
In addition, in order to fill a liquid resin material uniformly over the entire surface of a molded body such as a bathtub having a relatively large area, the liquid resin material is injected in the above-described method for producing a resin molded body reinforced with back surface. A belt-like ridge that narrows the gap between the back mold and the front side resin molded body is provided in a portion closer to the center than the periphery of the back die, and the back of the periphery is formed so as not to cross this belt-like ridge. It is preferable to provide a method for producing a back-reinforced resin molded body according to
[0014]
In this way, when the liquid resin material is injected, the resin material does not immediately flow into the center of the back mold at random, and the resin material once dams up the belt-like ridge that narrows the gap between the back mold and the front side resin molded body. It is stopped and temporarily stays in a gap of a predetermined volume between the back mold and the front side resin molded body, and then when the resin is fully filled in the gap, it goes over the belt-like ridges at once, and then Flows from the entire periphery toward the center at almost the same flow rate, and the cavity is uniformly filled.
[0015]
Further, in order to surely exhibit such an action, the front side resin molded body is a container-shaped front side resin molded body having an upper surface opening, and the peripheral edge of the opening portion is folded outwardly along the outer wall of the container. It is preferable to provide a method of manufacturing a resin molded body reinforced with a back surface, in which a liquid resin material injection port is disposed at the periphery of the back mold along the flange.
[0016]
In addition, in order to obtain a method of manufacturing a back-side reinforced resin molded body in which the thickness of the resin molded body can be easily adjusted in a request for a design change, manufacture of any of the above-described back-side reinforced resin molded bodies. In the method, the sealing between the peripheral edges of the back mold and the front side resin molded body is to bring an annular elastic packing provided on the peripheral edge of the back mold into close contact with the front side resin molded body, and the elastic packing is tubular Thus, the thickness of the resin molded body can be adjusted by adjusting the pressure of the hollow portion.
[0017]
In this way, when the pressure of the tubular hollow portion of the elastic packing is increased, the gap between the peripheral edges of the back mold and the front side resin molded body can be widened and sealed, and a thick resin molded body is manufactured. be able to. Further, when the pressure in the tubular hollow portion of the elastic packing is lowered, the elastic packing becomes thin and flat, and a thin resin molding can be manufactured.
[0018]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below with reference to the accompanying drawings.
[0019]
As shown in FIGS. 1-3, the manufacturing method of embodiment first produces the resin molded
[0020]
The
[0021]
Then, the front-side resin molded
[0022]
Next, a liquid resin material such as urethane resin is injected from the injection port into the gap (cavity) that has become substantially vacuum at less than 1 atm, using a pressure difference, filled with an appropriate amount, further heated, etc. Is cured by integrating the front-side resin molded
[0023]
As the liquid resin material, well-known resins such as unsaturated polyester resins, acrylic resins and vinyl ester resins can be selected in addition to the urethane resins described above, and those having good adhesion and integration with the above-mentioned resin molding for the front side can be selected. Adopt it.
[0024]
The resin molded
[0025]
The liquid resin
[0026]
Further, in order to seal the peripheral edges of the
[0027]
The
[0028]
【The invention's effect】
As described above, the present invention accommodates the reinforcing fiber material in the back mold cavity covering the back surface of the front side resin molded body, overlaps the front side resin molded body, and depressurizes the sealed gap. In this way, a liquid molded material is injected and cured to produce a resin molded body that is reinforced on the back surface. Therefore, the resin material is uniformly and quickly filled into the cavity, and the amount of impregnation is uniform and the quality of the reinforcing fiber material. There is an advantage that a good casting can be surely performed, and this provides a method of manufacturing a resin molded body reinforced with a back surface that is useful for improving quality and reducing manufacturing costs.
[0029]
In addition, this manufacturing method does not require a pair of strong molds for compression molding, can be easily manufactured by reducing the number of molds for molding, and a thin-walled mold can be used to meet a design change request. It can respond promptly, and the molded product that has become a product has no cracks or distortion, and can produce a high-quality and stable molded product, which improves the yield. Moreover, the back side-reinforced resin molded body can be mass-produced with high production efficiency while moving the mold in the production line process.
[0030]
In addition, when a method is adopted in which the hollow elastic packing is tightly sealed to the front side resin molded body with a clamp and the thickness of the hollow elastic packing is adjusted by the hollow internal pressure, the thickness of the resin molded body can be simplified. There is an advantage that it is a manufacturing method of a resin molded body whose back surface is reinforced that can be adjusted.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing a sealed back mold and a front side resin molded body for explaining a manufacturing method of an embodiment. FIG. 2 is a plan view of FIG. 1 for explaining a manufacturing method of the embodiment. FIG. 4 is a cross-sectional view showing an enlarged main part of FIG. 1 for explaining the manufacturing method of FIG. 1. FIG. 4 is a cross-sectional view of a mold and a thermoplastic resin molded product for explaining a conventional manufacturing method. Sectional view of resin moldings reinforced with male and female molds [Explanation of symbols]
DESCRIPTION OF
Claims (4)
前記液状樹脂材料の注入を裏型の周縁から行ない、この裏型の周縁より中央に近い部分には裏型と表側用樹脂成形体との間隙を狭める帯状隆起部を設け、この帯状隆起部を越えないように周縁の裏型と表側用樹脂成形体との間隙に液状樹脂を一時的に滞留させることを特徴とする裏面補強された樹脂成形体の製造方法。 A front-side resin molded body is provided, and a back mold is superimposed on the back surface of the front-side resin molded body via a reinforcing fiber material, and the periphery of the back mold and the periphery of the front-side resin molded body are After sealing, and then reducing the gap between the sealed back mold and the front side resin molded body, a liquid resin material is injected into the reduced pressure gap and cured to cure the front side resin molded body and the reinforcing side In the manufacturing method of the back side reinforced resin molding that integrates the fiber material ,
The liquid resin material is injected from the periphery of the back mold, and a belt-like ridge that narrows the gap between the back mold and the front side resin molded body is provided in a portion closer to the center than the periphery of the back mold. A method for producing a back-reinforced resin molded body, characterized in that a liquid resin is temporarily retained in a gap between a back mold on the periphery and a resin molded body for front side so as not to exceed.
裏型と表側用樹脂成形体との周縁同士の密封が、裏型の周縁に設けた環状の弾性パッキングをクランプで表側用樹脂成形体に密接させることであり、前記弾性パッキングは管状であり、中空部の気圧を調整して樹脂成形体の肉厚を調整可能とした裏面補強された樹脂成形体の製造方法。 A front-side resin molded body is provided, and a back mold is superimposed on the back surface of the front-side resin molded body via a reinforcing fiber material, and the periphery of the back mold and the periphery of the front-side resin molded body are After sealing, and then reducing the gap between the sealed back mold and the front side resin molded body, a liquid resin material is injected into the reduced pressure gap and cured to cure the front side resin molded body and the reinforcing side In the method for producing a resin molded body integrated with a fiber material
Sealing between the peripheral edges of the back mold and the front side resin molded body is to bring the annular elastic packing provided on the peripheral edge of the back mold into close contact with the front side resin molded body, and the elastic packing is tubular, method of manufacturing and adjusting the air pressure in the hollow part molded resin thickness of adjustable and the back surface reinforced resin molded body.
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JP2002327028A JP3679395B2 (en) | 2002-11-11 | 2002-11-11 | Manufacturing method of resin molded body reinforced with back surface |
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JP2002327028A JP3679395B2 (en) | 2002-11-11 | 2002-11-11 | Manufacturing method of resin molded body reinforced with back surface |
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JP4833603B2 (en) * | 2005-07-15 | 2011-12-07 | 富士重工業株式会社 | Molding jig |
CN110948906A (en) * | 2019-12-09 | 2020-04-03 | 宁波市益普乐模塑有限公司 | Manufacturing process of carbon fiber automobile door outer panel |
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JPS5191965A (en) * | 1975-02-08 | 1976-08-12 | CHUKEIBUTSUNOSEIZOHOHO | |
JPS58205740A (en) * | 1982-05-26 | 1983-11-30 | Inoue Mtp Co Ltd | Mold for foaming synthetic resin |
JPS59148634A (en) * | 1983-02-15 | 1984-08-25 | Daihatsu Motor Co Ltd | Injection molding method of resin |
JPH04347626A (en) * | 1991-05-24 | 1992-12-02 | Hitachi Chem Co Ltd | Decompression molding method of frp |
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