JP3621231B2 - Gasket material - Google Patents

Gasket material Download PDF

Info

Publication number
JP3621231B2
JP3621231B2 JP17312097A JP17312097A JP3621231B2 JP 3621231 B2 JP3621231 B2 JP 3621231B2 JP 17312097 A JP17312097 A JP 17312097A JP 17312097 A JP17312097 A JP 17312097A JP 3621231 B2 JP3621231 B2 JP 3621231B2
Authority
JP
Japan
Prior art keywords
rubber
cork
layer
gasket material
synthetic rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP17312097A
Other languages
Japanese (ja)
Other versions
JPH111680A (en
Inventor
宏泰 青井
隆 難波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Uchiyama Manufacturing Corp
Original Assignee
Uchiyama Manufacturing Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uchiyama Manufacturing Corp filed Critical Uchiyama Manufacturing Corp
Priority to JP17312097A priority Critical patent/JP3621231B2/en
Publication of JPH111680A publication Critical patent/JPH111680A/en
Application granted granted Critical
Publication of JP3621231B2 publication Critical patent/JP3621231B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【0001】
【発明の属する技術分野】
本発明は、開口部を有する二部材間に介在せしめてその部材間の密封をなすガスケット材に関しており、具体的には、シール性、防音性、及び防振性等に優れるガスケット材に関する。
【0002】
【従来の技術】
従来、密封必要部材間に装着してその密封をなさしめるガスケット材にあっては、圧縮性及び成形性に優れる合成ゴム材料、あるいはこの合成ゴム材料に適度の粒度に粉砕形成されたコルク粒を混練して形成したコルク粒入り合成ゴム材料などが採用されているが、昨今のエンジンの軽量化、高熱化、高回転化に伴い、高い圧縮性、高強度性、耐熱性などが求められており、これに対応するためには価格的及び成型的には不利となるが材料特性に優れるアクリルゴムが多く採用されるようになり現在ではガスケット材の主流となっている。
【0003】
【発明が解決しようとする課題】
しかしながら、エンジンのコンパクト化、高出力化に伴いさらに高い圧縮性とか高強度性の向上が望まれており、高性能な材料によるガスケットが検討されている。
このような状況にあって、要求される性能を満たし価格的に優位なガスケット材料としてはシリコーンゴム、フロロシリコーンゴム、あるいはフッ素ゴムなどが知られているが、シリコーンゴム系は耐エンジン油性に劣り、フッ素ゴムは極端なコストアップにつながるなどのマイナス面を有している。
【0004】
また、アクリルゴム、シリコーンゴム、あるいはフッ素ゴムなどを種々ブレンドしたブレンドゴムや、新規なゴム材料で前記の耐熱性あるいは低価格性等の諸要求を満足させるものは未だ開発されていない。
一方、コルク材料においては、圧縮性材料として横流れの少ないガスケット材として使用されているが、ヘタリを発生させるため大きな荷重を加えることができず、さらに強度が弱いため薄板状の製品を造形することができない。
本発明はこのような欠点を解消し、密封性に優れかつ防音、防振性に富むガスケット材を提供しようとするものである。
【0005】
【課題を解決しようとする手段】
本発明は図面によって詳述すると、図1に示すように、内燃機関用のガスケットあるいは冷凍機用ガスケット等に使用されるガスケット材(A)であって、図2に示すように未加硫の合成ゴム(1)と粒度5〜30メッシュ程度に粉砕精製したコルク粒(2)とを混練してゴムシート(3)を形成し、形成したゴムシート(3)の両面へ接着剤を塗布した天然繊維あるいは合成繊維からなる不織布(4)を配置してこれを加圧・加熱条件下で加硫成型せしめ、中層部にコルクリッチとなるコルク層(5)を形成し、その両側に不織布 層(6)を配置して、該不織布層(6)の内にコルク粒(2)を絡ませ、その両外表面に合成ゴム(1)を滲出させてゴム層(7)を形成したことを特徴としている。
【0006】
【発明の実施の形態】
本発明のガスケット材(A)は、図2に示すように合成ゴム(1)にコルク粒(2)を混練したゴムシート(3)とそのゴムシート(3)に適合できる接着剤を塗布した不織布(4)とを両側面に重ね合せ、これをプレス機等で加硫接着せしめてガスケット材(A)を形成する。
この加硫接着時に、ゴムシート(3)は不織布(4)と共に圧縮されると密度の低い不織布(4)の側へ流れ込もうとするが、内含するコルク粒(2)は不織布(4)の複雑に絡み合う繊維のフィルター作用によってその移動流出が阻止されて内にそのまま残り、反対に浸透・透過力に優れる合成ゴム(1)の一部は不織布(4)を透過し表面側まで滲み出て加硫硬化される。
ここで中部にコルクリッチのコルク層(5)が形成され、これを両側から不織布層(6)で挟んでゴム層(7)が形成される。
この加硫成型の際、合成ゴム(1)の加硫反応が進むと同時に不織布(4)に塗布した接着剤と化学結合を形成させ強固に一体化されたガスケット材(A)が得られる。このような作用によってより強固な結合が形成される。
【0007】
【実施例】
本発明のガスケット材(A)の合成ゴム(1)としては、ニトリルゴム、アクリルゴム、スチレンブタジエンゴム、クロロブタジエンゴム、ブチルゴム、シリコーンゴム、あるいはフッ素ゴム等を挙げることができる。
次に、コルク粒(2)としては、天然のコルク樹皮を粉砕機に投入しこれを細かく粉砕した後、5〜30メッシュ程度の粒度に精製せしめて用いるもので、その特性は、軽量で強い弾力性と高い圧縮回復力を有して熱絶縁性及び振動吸収性さらには遮音性などに優れる特徴を持っている。
また、不織布(4)としては、ポリエステル繊維、ポリアミド繊維、ポリプロピレン繊維、アクリル繊維、アラミド繊維、などの合成繊維、またはガラス繊維、セラミックス繊維、炭素繊維などが挙げられ、その厚みは約10〜200μm、秤量が約20〜100g/m、引っ張り強さが約1〜10kg/cmのものが用いられる。
【0008】
本発明は、図1に示す合成ゴム(1)にコルク粒(2)を混練したゴムシート(3)と接着剤を塗布した複数の不織布(4)とからなるガスケット材(A)であって、これを加硫成型して一体化せしめるとき、用いられたゴム材の種類に応じて、例えば温度150゜C〜250゜C、締め圧0.5〜40kg/cm、成型時間1〜60分間の加圧・加熱条件下で加硫成型せしめれば、明確に層状に形成されたコルク層(5)と不織布層(6)とゴム層(7)からなるガスケット材(A)が得られる。
【0009】
本発明では、前記の通りその表面は内側の合成ゴムの滲出によってゴム層(7)で覆われるが、前記合成ゴム(1)と不織布(4)の結合によって、比較的硬度が高く引張り横流れしない強度の大きい層を形成しており、中部のコルク層(5)の満足できる圧縮性、及び前記表面側に位置するゴム層の良好な密着性によって苛酷な密封条件に耐え得る高い密封性能を発揮するものとなっている。
【0010】
以下、表1によって本発明のガスケット材と従来のコルク粒入りゴム材との特性比較を表わす。
表1
【0011】
【発明の効果】
本発明では、ゴム材にコルク材を混入せしめ不織布(4)をもって多層に形成することにより、コルク材の特性である圧縮時の横流れの少ない特性とゴム材の圧縮荷重を除去すると直ちに基形状に復元する良好な復元性を引き出し、また不織布(4)と合成ゴム(1)とを絡ませたことによって引っ張り強度などの機械的特性を向上させる。この高い機械的強度によって締付け面圧を高めることができ密封性能を飛躍的に向上させる。また、高い機械的強度は薄板状のガスケット材の造形が可能となる。
【図面の簡単な説明】
【図1】本発明の一実施例を示す断面図である。
【図2】本発明の他の実施例を示す断面図である。
【符号の説明】
A ガスケット材
1 合成ゴム
2 コルク粒
3 ゴムシート
4 不織布
5 コルク層
6 不織布層
7 ゴム層
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a gasket material that is interposed between two members having openings and seals between the members, and more specifically, relates to a gasket material that is excellent in sealability, soundproofing properties, vibration-proofing properties, and the like.
[0002]
[Prior art]
Conventionally, in a gasket material that is installed between necessary sealing members to achieve the sealing, a synthetic rubber material excellent in compressibility and moldability, or cork grains pulverized and formed to an appropriate particle size in this synthetic rubber material is used. Synthetic rubber material containing cork grains formed by kneading has been adopted, but with the recent reduction in weight, heat and rotation of engines, high compressibility, high strength, heat resistance, etc. are required. In order to cope with this, it is disadvantageous in terms of cost and molding, but many acrylic rubbers having excellent material properties have come to be adopted, and the gasket material is now mainstream.
[0003]
[Problems to be solved by the invention]
However, as the engine becomes more compact and has higher output, higher compressibility and higher strength are desired, and gaskets made of high-performance materials are being studied.
Under such circumstances, silicone rubber, fluorosilicone rubber, or fluoro rubber is known as a cost-effective gasket material that satisfies the required performance, but silicone rubber is poor in engine oil resistance. Fluorine rubber has a negative aspect such as extreme cost increase.
[0004]
In addition, blend rubbers obtained by blending various kinds of acrylic rubber, silicone rubber, fluorine rubber, and the like, and new rubber materials that satisfy the various requirements such as heat resistance and low cost have not been developed yet.
On the other hand, in the cork material, it is used as a compressible material as a gasket material with little cross flow, but because it generates settling, a large load cannot be applied, and the strength is weak, so a thin plate product is formed I can't.
The present invention is intended to eliminate such drawbacks and to provide a gasket material that is excellent in sealing performance and rich in soundproofing and vibrationproofing.
[0005]
[Means to solve the problem]
The present invention will be described in detail with reference to the drawings. As shown in FIG. 1, a gasket material (A) used for a gasket for an internal combustion engine or a gasket for a refrigerator, etc. The rubber sheet (3) is formed by kneading the synthetic rubber (1) and the cork granules (2) pulverized and refined to a particle size of about 5 to 30 mesh, and an adhesive is applied to both sides of the formed rubber sheet (3). A non-woven fabric (4) made of natural fiber or synthetic fiber is placed and vulcanized and molded under pressure and heating conditions to form a cork rich cork layer (5) in the middle layer, and a non-woven fabric layer on both sides (6) is disposed, the cork particles (2) are entangled in the nonwoven fabric layer (6), and the rubber layer (7) is formed by exuding the synthetic rubber (1) on both outer surfaces thereof. It is said.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
As shown in FIG. 2, the gasket material (A) of the present invention was coated with a rubber sheet (3) in which cork grains (2) were kneaded with a synthetic rubber (1) and an adhesive suitable for the rubber sheet (3). The non-woven fabric (4) is superposed on both side surfaces, and this is vulcanized and bonded with a press or the like to form the gasket material (A).
At the time of this vulcanization adhesion, when the rubber sheet (3) is compressed together with the nonwoven fabric (4), the rubber sheet (3) tends to flow into the low density nonwoven fabric (4) side. ) The intricately intertwined fiber filter action prevents the migration and outflow of the fiber, leaving it as it is, and conversely, part of the synthetic rubber (1), which has excellent penetration and permeability, permeates the nonwoven fabric (4) and bleeds to the surface side. It is vulcanized and cured.
Here, a cork-rich cork layer (5) is formed in the middle part, and this is sandwiched between the nonwoven fabric layers (6) from both sides to form a rubber layer (7).
At the time of this vulcanization molding, the gasket material (A) which is firmly integrated by forming a chemical bond with the adhesive applied to the nonwoven fabric (4) at the same time as the vulcanization reaction of the synthetic rubber (1) proceeds. A stronger bond is formed by such an action.
[0007]
【Example】
Examples of the synthetic rubber (1) of the gasket material (A) of the present invention include nitrile rubber, acrylic rubber, styrene butadiene rubber, chlorobutadiene rubber, butyl rubber, silicone rubber, and fluorine rubber.
Next, as the cork grain (2), natural cork bark is put into a pulverizer and finely pulverized, then refined to a particle size of about 5 to 30 mesh, and its characteristics are lightweight and strong. It has elasticity and high compression recovery, and has excellent heat insulation, vibration absorption, and sound insulation.
Examples of the nonwoven fabric (4) include synthetic fibers such as polyester fibers, polyamide fibers, polypropylene fibers, acrylic fibers, and aramid fibers, or glass fibers, ceramic fibers, and carbon fibers, and the thickness is about 10 to 200 μm. The one having a weight of about 20 to 100 g / m 2 and a tensile strength of about 1 to 10 kg / cm 2 is used.
[0008]
The present invention is a gasket material (A) comprising a rubber sheet (3) obtained by kneading cork grains (2) to a synthetic rubber (1) shown in FIG. 1 and a plurality of nonwoven fabrics (4) coated with an adhesive. When this is vulcanized and integrated, depending on the type of rubber material used, for example, a temperature of 150 ° C. to 250 ° C., a clamping pressure of 0.5 to 40 kg / cm 2 , a molding time of 1 to 60 If vulcanization molding is performed under pressure and heating conditions for a minute, a gasket material (A) consisting of a cork layer (5), a non-woven fabric layer (6) and a rubber layer (7) that are clearly formed in layers can be obtained. .
[0009]
In the present invention, as described above, the surface is covered with the rubber layer (7) by the exudation of the inner synthetic rubber, but due to the combination of the synthetic rubber (1) and the nonwoven fabric (4), the hardness is relatively high and does not flow laterally. Forms a high-strength layer and exhibits high sealing performance that can withstand severe sealing conditions due to satisfactory compressibility of the middle cork layer (5) and good adhesion of the rubber layer located on the surface side. It is supposed to be.
[0010]
Table 1 below shows a characteristic comparison between the gasket material of the present invention and a conventional rubber material containing cork particles.
Table 1
[0011]
【The invention's effect】
In the present invention, the cork material is mixed into the rubber material and formed into a multilayer with the nonwoven fabric (4), so that when the compression property of the rubber material is removed, the shape of the cork material is reduced to the basic shape immediately after compression. Good restoring properties to restore are brought out, and mechanical properties such as tensile strength are improved by entanglement of the nonwoven fabric (4) and the synthetic rubber (1). This high mechanical strength can increase the tightening surface pressure and dramatically improve the sealing performance. In addition, a high mechanical strength enables a thin gasket material to be formed.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing an embodiment of the present invention.
FIG. 2 is a cross-sectional view showing another embodiment of the present invention.
[Explanation of symbols]
A Gasket material 1 Synthetic rubber 2 Cork grain 3 Rubber sheet 4 Non-woven fabric 5 Cork layer 6 Non-woven fabric layer 7 Rubber layer

Claims (1)

未加硫の合成ゴムと粒度5〜30メッシュ程度に精製したコルク粒とを混練してゴムシートを形成し、
形成したゴムシートの両面へ接着剤を塗布した不織布を配置してこれを加圧・加熱条件下で加硫成型せしめ、
中層部にコルクリッチのコルク層を、その両側に不織布層を配置して
前記不織布層から両外表面に合成ゴムを滲出させてゴム層を形成したことを特徴とするガスケット材。
A rubber sheet is formed by kneading unvulcanized synthetic rubber and cork granules refined to a particle size of about 5 to 30 mesh,
A non-woven fabric with adhesive applied on both sides of the formed rubber sheet is placed and vulcanized and molded under pressure and heating conditions.
A cork rich cork layer in the middle layer, and a non-woven fabric layer on both sides,
A gasket material, wherein a rubber layer is formed by extruding synthetic rubber from the nonwoven fabric layer on both outer surfaces.
JP17312097A 1997-06-12 1997-06-12 Gasket material Expired - Fee Related JP3621231B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17312097A JP3621231B2 (en) 1997-06-12 1997-06-12 Gasket material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17312097A JP3621231B2 (en) 1997-06-12 1997-06-12 Gasket material

Publications (2)

Publication Number Publication Date
JPH111680A JPH111680A (en) 1999-01-06
JP3621231B2 true JP3621231B2 (en) 2005-02-16

Family

ID=15954518

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17312097A Expired - Fee Related JP3621231B2 (en) 1997-06-12 1997-06-12 Gasket material

Country Status (1)

Country Link
JP (1) JP3621231B2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3319433B2 (en) 1999-05-12 2002-09-03 日本電気株式会社 Memory LSI failure analysis apparatus and system, method, and recording medium
JP4961543B2 (en) * 2005-05-25 2012-06-27 ジ・エコ株式会社 Natural plant composite molded body and method for producing the same
WO2019004432A1 (en) * 2017-06-30 2019-01-03 三井化学株式会社 Method for producing sealing member and member-bonding method
CN112443660B (en) * 2020-11-16 2023-04-14 中国化工株洲橡胶研究设计院有限公司 Cloth-sandwiched rubber leather cup and manufacturing method thereof
CN115214176A (en) * 2022-07-27 2022-10-21 上海芯之翼半导体材料有限公司 Processing technology of silica gel gasket and silica gel gasket

Also Published As

Publication number Publication date
JPH111680A (en) 1999-01-06

Similar Documents

Publication Publication Date Title
US7905498B2 (en) Gasket formed from various material
KR950004136B1 (en) Molded panel filter
RU2353640C2 (en) Flat sealing material in form of reinforced composite foil (composite film)
US4259096A (en) Fuel vapor adsorption type air cleaner element for internal combustion engine
US4631077A (en) Foam plastic air filter
US5286574A (en) Metal composite gasket material
US7000729B2 (en) Five-layer sound absorbing pad: improved acoustical absorber
US4214761A (en) Packing construction
US4888235A (en) Improved non-woven fibrous product
EP0440116A2 (en) Flexible graphite laminate and method for producing it
US3661401A (en) Gasket
US5306553A (en) Impregnated flat gasket and method of producing the gasket
JP3621231B2 (en) Gasket material
JP2007100933A (en) Wet friction material
EP0097279B1 (en) Method for making covers
US3158526A (en) Reinforced gasket products
JPH08258203A (en) Separate plate for control valve in automatic transmission
US1961745A (en) Laminated material
WO2001094815A1 (en) Gasket
KR101704195B1 (en) A fibrous component for vehicle exterior and a manufacturing method thereof
JPH111681A (en) Gasket material
JP3621230B2 (en) Gasket material
KR102207862B1 (en) A wet-laid non-woven fabric for hydrocarbon trap of air cleaner and its manufacturing method
JPS5916280B2 (en) composite material
JP4370707B2 (en) Speaker components

Legal Events

Date Code Title Description
A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20040810

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20041012

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20041109

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20041117

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees