JP3606954B2 - Baking repair material package and hot repair method for molten metal container using the same - Google Patents

Baking repair material package and hot repair method for molten metal container using the same Download PDF

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Publication number
JP3606954B2
JP3606954B2 JP17934595A JP17934595A JP3606954B2 JP 3606954 B2 JP3606954 B2 JP 3606954B2 JP 17934595 A JP17934595 A JP 17934595A JP 17934595 A JP17934595 A JP 17934595A JP 3606954 B2 JP3606954 B2 JP 3606954B2
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Japan
Prior art keywords
baking
repair material
repair
molten metal
container
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JP17934595A
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Japanese (ja)
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JPH094983A (en
Inventor
尚俊 安田
忠範 原
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Krosaki Harima Corp
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Krosaki Harima Corp
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Priority to JP17934595A priority Critical patent/JP3606954B2/en
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Description

【0001】
【産業上の利用分野】
本発明は、溶融金属容器の熱間補修に使用される焼付補修材の梱包体およびこれを用いた補修方法に関するものである。
【0002】
【従来の技術】
従来、転炉、AOD炉、電気炉、LF鍋などの溶融金属容器の熱間補修材として、焼付補修材が知られている(特開昭61−183176号公報など)。
焼付補修材は、溶融金属容器内に投入されると容器の残熱を受け、結合剤の軟化によって流動化し、内張りの被補修部に充填された後、結合剤の炭化あるいは硬化により焼き付けられる。この焼付補修材は不定形耐火物であるため、バッグに入れて搬送され、容器内への投入もバッグに入れた状態で行われる。バッグは残熱で焼失し、補修材の焼付けの障害にならない。
【0003】
【発明が解決しようとする課題】
しかし、焼付け補修は熱間での作業のため、焼付補修材を被補修部に正確に投入することは容易でない。被補修部から外れた位置に投入すると直ちにバックが焼失し、被補修部に到達することなくその場に焼き付けられる。
また、焼付補修材は、搬送や補修作業の効率を上げるために一バッグあたりの量を多くすると、その分、安全面からバッグの強度を大きくしなければならない。しかし、バッグは強度を大きくすると自ずと厚さが増し、容器内へ投入後、残熱を受けても容易に焼失せず、焼付補修材の軟化による充填がなされないまま硬化する。
【0004】
【課題を解決するための手段】
本発明は、焼付補修における上記従来の問題を解決したものである。
本発明は、焼付補修材を収納した焼失性コンテナバッグと、このコンテナバッグを抱持した焼失性硬質円筒よりなる焼付補修材の梱包体である。また、この焼付補修材の梱包体を、炉壁面上を転動して被補修部に到達させる溶融金属容器の熱間補修方法である。
【0005】
【作用】
本発明によれば、焼付補修材の自重による迫り圧でコンテナバッグとそれを抱持した硬質円筒とが強固に一体化し、コンテナバッグは特に厚手のものを用いなくても硬質円筒によって梱包体全体として十分な強度を備える。これにより、例えば積み重ねての保管あるいは移送が可能など、取扱いの便宜上あるいは作業安全上きわめて好ましい。
【0006】
また、硬質円筒によって外形が円柱状をなしていることから、内張り補修時において、容器の壁面上を転動によって被補修部の凹部に到達させることができる。例えば、転炉などは横倒させた状態で補修が行われるが、炉を立て直す際の傾動を利用すれば、焼付補修材の梱包体は外力を加えなくても転動し、自ずと被損傷部の凹部に到達する。
【0007】
この転動の際に梱包体は高温の壁面と接触するが、本発明の焼付補修材の梱包体は硬質円筒によって耐熱保護され、円柱形状を保った状態で被損傷部に到達する。そして、焼付補修材の梱包体は被補修部に到達すると残熱を受けて硬質円筒およびコンテナバッグが焼失すると共に、焼付補修材が軟化による流動によって被補修部に充填後、焼付けられる。
【0008】
溶融金属容器の残熱は一般に1000℃前後の高温のため、硬質円筒はその厚さにかかわらず焼失するが、厚さが大き過ぎると焼失が遅れる。その場合は、硬質円筒の上部および/または下部を開放部しておけば、焼付補修材はその開放部から軟化流出し、硬質円筒の焼失が遅れても焼付補修材が流出しないまま硬化することはない。
【0009】
【実施例】
図に基づいて本発明の実施例を説明する。図1およびは図2は、本発明実施例による焼付補修材の梱包体であって、図1は斜視図、図2は正面断面図である。図1および図2の焼付補修材の梱包体(1)において、コンテナバッグ(2)への焼付補修材(3)の収納は、コンテナバッグ(2)を焼失性硬質円筒(4)に入れた状態で行うのが好ましい。
【0010】
収納した焼付補修材(3)の自重による迫り圧によってコンテナバッグ(2)と焼失性硬質円筒(4)とは強固に一体化するので、移送の際には、例えばコンテナバッグ(2)に取り付けた吊り紐(5)による吊り下げで行ってもよい。
焼付補修材(3)の材質は、従来の焼付補修材と特に変わらない。すなわち、耐火性骨材に対し、タール、合成樹脂、ケイ酸塩、リン酸塩などの結合剤を添加したものである。結合剤の割合は焼付材全体に対する内掛けで例えば5〜50wt%とし、この範囲内で結合剤の種類、残熱温度などを考慮して決定する。
【0011】
結合剤は、その熱軟化で焼付補修材を流動化して被補修部に充填させた後、炭化あるいは硬化することで焼付補修材を被補修部に焼付ける効果をもつ。
タールの具体例は、ピッチ、アスファルトなどである。合成樹脂の具体例はフェノール樹脂、フラン樹脂、エポキシ樹脂、メラミン樹脂、尿素樹脂、キシレン樹脂である。これらのタールまたは合成樹脂は、必要により、溶剤を添加して使用してもよい。ケイ酸塩はメタケイ酸ナトリウム−9水塩、リン酸塩はリン酸水素2ナトリウム12水塩などの結晶水を含むものである。
【0012】
焼付補修材(3)に使用する耐火骨材は、例えばアルミナ、シリカ、アルミナ−シリカ、マグネシア、カルシア、マグネシア−カルシア、スピネル、ジルコン、ジルコニア、炭素、炭化珪素、窒化物、クロムなどの耐火材から選ばれる一種または二種以上を主材とする。中でも、耐食性に優れたマグネシア、カルシア、マグネシア−カルシアなどの塩基性が好ましい。また、これらを主材とした炉材使用後品を骨材の一部または全部を用いてもよい。その粒度は、密充填組織が得られるように、粗粒、中粒、微粒に調整する。キレツ防止などを目的として、一部を粒径30mm前後の粗大粒子にしてもよい。
【0013】
この焼付補修材(3)には、さらに硬化促進剤、硬化遅延剤、焼結剤、金属粉、酸化防止剤、分散剤、有機質ファイバー、無機質ファイバー、金属質ファイバーなどを添加してもよい。
焼付補修材(3)を収納するコンテナバッグ(2)の材質は従来材質と特に変わりなく、例えば通常の市販品のポリプロピレン製、塩化ビニール製、合成・天然ゴム製、布製などの軟質かつ可撓性を有するものとする。厚さは、例えば0.5mm以下である。
【0014】
焼失性硬質円筒(4)は紙、プラスチックなどの易燃性とする。経済性の面から紙製が好ましい。その寸法は、内蔵する焼付補修材の量に合わせて、例えば内径300〜1200mm、高さ400〜1500mmとする。厚さは、耐熱性と保形能を付与させるために、例えば2〜15mm、好ましく3〜6mmである。
焼失性硬質円筒(4)は、例えば水平断面が四角形のものであっても、可撓性によって、収納した焼付補修材の迫り圧で円筒形状になるものであれば、最初から円筒形状のでなくてもよい。
【0015】
焼失性硬質円筒(4)の上部および下部は覆ってもよいが、図のように開放した場合は、硬質円筒(4)の焼失が遅れても焼付補修材(3)はその開放部から早期に流出させることができる。また、硬質円筒(4)の上部および下部は覆う場合は、厚さを薄くするなどによって容易に焼失する材質で行うのが好ましい。
図3は、本発明の焼付補修材の梱包体(1)を用いた溶融金属容器の熱間補修方法を模式的に示したもである。
【0016】
A図のとおり、焼付補修材の梱包体(1)はシュート(7)などを介して溶融金属容器(6)の上方開口部から壁面上に投入する。ついで、押し棒による外力あるいは壁面の傾斜を利用して転動させ、被補修部に到達させる。この場合、溶融金属容器(6)が転炉、取鍋などのように傾動可能な場合、B図のとおり、容器の立て直し際の傾倒を利用すると、焼付補修材の梱包体(1)は被補修部である凹部に自ずから到達する。
【0017】
つぎに、本発明実施例による焼付補修材の梱包体およびこれを用いた熱間補修方法の実機試験を示す。
厚さ5mm×内径800mm×高さ1000mmの紙管よりなる焼失性硬質円筒に厚さ0.3mmのポリプロピレン製コンテナバッグを収納し、次いでこのコンテナバッグに焼結マグネシアクリンカー80wt%、ピッチ20wt%よりなる焼付補修材を1t内臓させ、焼付補修材の梱包体を得た。焼付補修材は不定形耐火物であるが、硬質円筒の補強によって積み重ねが可能となり、保管あるいは移送に好都合であった。
【0018】
また、転炉の熱間補修において、横傾させた転炉の側壁に前記の焼付補修材の梱包体をシュートで投下し、側壁の傾斜面を利用して側壁下部の被補修部に焼付補修材の梱包体を到達させた。炉壁の残熱は1200〜1400℃であり、焼付補修材は被補修部に到達後、コンテナバッグの焼失によって梱包体内の硬質円筒から軟化流出すると共に、硬質円筒も焼失した。そして、焼付補修材はピッチの炭化で被補修部に焼付けられ、炉内張りの補修を行うことができた。
【0019】
【効果】
本発明による効果を列挙すれば以下のとおりである。
▲1▼焼付補修材の自重による迫り圧でコンテナバッグとそれを抱持した硬質円筒とが強固に一体化し、しかも硬質円筒によって梱包体全体として十分な強度を備えたことで、例えば積み重ねての保管あるいは移送が可能など、取扱いの便宜上あるいは作業安全上きわめて好ましい。
▲2▼焼付補修材が硬質円筒によって外形が円柱状をなしていることから、内張り補修時において、壁面上を転動して被補修部に到達させることができる。例えば転炉、取鍋などの傾動可能な溶融金属容器では、容器を立て直す際の傾動を利用すれば、焼付補修材の梱包体は外力を加えなくても転動し、自ずと非補修部に到達する。
【0020】
▲3▼壁面上を転動の際に梱包体は高温の壁面と接触するが、焼付補修材の梱包体は硬質円筒によって耐熱保護され、円柱形状を保つことで、転動によって被補修部に到達させることができる。
▲4▼硬質円筒の上部および/または下部を開放しておくと、硬質円筒の焼失が遅れる場合でも、焼付補修材をこの開放部から早期に流出させることができる。
【図面の簡単な説明】
【図1】本発明実施例の焼付補修材の梱包体の斜視図。
【図2】本発明実施例の焼付補修材の梱包体の断面図。
【図3】本発明の焼付補修材の梱包体を用いた溶融金属容器の熱間補修方法を示す。
【符号の説明】
1 焼付補修材の梱包体
2 コンテナバッグ
3 焼付補修材
4 焼失性硬質円筒
5 吊り紐
6 溶融金属容器
7 シュート
[0001]
[Industrial application fields]
TECHNICAL FIELD The present invention relates to a package of a repairing material for baking used for hot repair of a molten metal container and a repair method using the same.
[0002]
[Prior art]
Conventionally, baking repair materials are known as hot repair materials for molten metal containers such as converters, AOD furnaces, electric furnaces, and LF pans (JP-A 61-183176, etc.).
When the baking repair material is put into the molten metal container, it receives the residual heat of the container, fluidizes due to softening of the binder, fills the repaired portion of the lining, and then is baked by carbonization or curing of the binder. Since this baking repair material is an irregular refractory material, it is transported in a bag and put into the container in a state where it is also put in the bag. The bag burns out due to residual heat and does not interfere with the repair material.
[0003]
[Problems to be solved by the invention]
However, since the baking repair is a hot work, it is not easy to accurately put the baking repair material into the repaired part. Immediately after being put in a position outside the repaired part, the bag is burnt out and burned in place without reaching the repaired part.
Moreover, if the amount per bag is increased in order to increase the efficiency of conveyance and repair work, the strength of the bag must be increased from the viewpoint of safety. However, when the strength is increased, the bag naturally increases in thickness, and after being put into the container, it does not easily burn out even if it receives residual heat, and is cured without being filled by softening of the baking repair material.
[0004]
[Means for Solving the Problems]
The present invention solves the above-mentioned conventional problems in the repair of baking.
The present invention is a package for a baking repair material comprising a burnable container bag containing a baking repair material and a burnable hard cylinder holding the container bag. Moreover, it is the hot repair method of the molten metal container which rolls the packing body of this baking repair material on a furnace wall surface, and reaches | attains a to-be-repaired part.
[0005]
[Action]
According to the present invention, the container bag and the rigid cylinder holding the container bag are tightly integrated by the squeezing pressure due to the weight of the baking repair material, and even if the container bag is not particularly thick, the entire packaging body is formed by the rigid cylinder. With sufficient strength. Thereby, for example, it is very preferable in terms of handling convenience or work safety such that stacking and storage are possible.
[0006]
In addition, since the outer shape of the hard cylinder is columnar, it is possible to reach the concave portion of the repaired portion by rolling on the wall surface of the container during lining repair. For example, the converter is repaired in a state where it is laid down, but if the tilting when the furnace is rebuilt is used, the package of the repair material for baking will roll without any external force and will naturally be damaged. Reach the recess.
[0007]
During this rolling, the packing body comes into contact with the high-temperature wall surface, but the packing body of the baking repair material of the present invention is protected against heat by the hard cylinder and reaches the damaged part while maintaining the columnar shape. When the package of the baking repair material reaches the repaired part, the hard cylinder and the container bag are burned by receiving residual heat, and the repaired material is baked after filling the repaired part by the flow of softening.
[0008]
Since the residual heat of the molten metal container is generally a high temperature around 1000 ° C., the hard cylinder is burned out regardless of its thickness, but if the thickness is too large, the burning is delayed. In that case, if the upper and / or lower part of the hard cylinder is opened, the baking repair material will soften and flow out of the opening, and even if the burning of the hard cylinder is delayed, the baking repair material will harden without flowing out. There is no.
[0009]
【Example】
Embodiments of the present invention will be described with reference to the drawings. FIG. 1 and FIG. 2 are packing bodies of a repairing material for baking according to an embodiment of the present invention, FIG. 1 is a perspective view, and FIG. 2 is a front sectional view. In the package (1) of the baking repair material of FIG. 1 and FIG. 2, the storage of the baking repair material (3) in the container bag (2) is performed by placing the container bag (2) in the burnable hard cylinder (4). It is preferable to carry out in the state.
[0010]
The container bag (2) and the burnable hard cylinder (4) are firmly integrated with each other by the pressure of the stored baking repair material (3) due to its own weight. For example, when transported, the container bag (2) is attached to the container bag (2). You may carry out by hanging with the hanging string (5).
The material of the baking repair material (3) is not particularly different from the conventional baking repair material. That is, a binder such as tar, synthetic resin, silicate, and phosphate is added to the refractory aggregate. The ratio of the binder is, for example, 5 to 50 wt% as an inner portion of the entire baking material, and is determined in consideration of the type of binder, the residual heat temperature, and the like within this range.
[0011]
The binder has the effect of burning the repaired material to be repaired by carbonizing or hardening after the fluidized softening material is filled in the repaired part by thermal softening.
Specific examples of tar include pitch and asphalt. Specific examples of the synthetic resin are phenol resin, furan resin, epoxy resin, melamine resin, urea resin, and xylene resin. These tars or synthetic resins may be used after adding a solvent, if necessary. Silicates include crystallization water such as sodium metasilicate-9 hydrate and phosphates such as disodium hydrogen phosphate 12 hydrate.
[0012]
The refractory aggregate used for the baking repair material (3) is, for example, refractory materials such as alumina, silica, alumina-silica, magnesia, calcia, magnesia-calcia, spinel, zircon, zirconia, carbon, silicon carbide, nitride, chromium, etc. The main material is one or more selected from Of these, basics such as magnesia, calcia, and magnesia-calcia, which are excellent in corrosion resistance, are preferable. Moreover, you may use a part or all of aggregate for the goods after using furnace materials which made these the main materials. The particle size is adjusted to coarse particles, medium particles, and fine particles so that a close packed structure can be obtained. For the purpose of preventing cracks, a part of the particles may be coarse particles having a particle size of about 30 mm.
[0013]
The baking repair material (3) may further contain a curing accelerator, a curing retarder, a sintering agent, a metal powder, an antioxidant, a dispersant, an organic fiber, an inorganic fiber, a metallic fiber, and the like.
The material of the container bag (2) for storing the baking repair material (3) is not particularly different from the conventional material. For example, it is soft and flexible such as a normal commercially available product made of polypropylene, vinyl chloride, synthetic / natural rubber, or cloth. It shall have the property. The thickness is, for example, 0.5 mm or less.
[0014]
The burnable hard cylinder (4) is made of a flammable material such as paper or plastic. Paper is preferable from the viewpoint of economy. The dimensions are, for example, an inner diameter of 300 to 1200 mm and a height of 400 to 1500 mm in accordance with the amount of the built-in baking repair material. The thickness is, for example, 2 to 15 mm, preferably 3 to 6 mm, in order to impart heat resistance and shape retention.
The burnout hard cylinder (4) is not a cylindrical shape from the beginning, for example, even if the horizontal cross section has a rectangular shape, as long as it has a cylindrical shape due to the squeezing pressure of the stored baking repair material due to its flexibility. May be.
[0015]
The upper and lower parts of the burnable hard cylinder (4) may be covered, but when opened as shown in the figure, even if the hard cylinder (4) burns out later, the seizure repair material (3) is removed from the open part at an early stage. Can be drained into. Moreover, when covering the upper part and the lower part of a hard cylinder (4), it is preferable to carry out with the material which burns down easily by reducing thickness.
FIG. 3 schematically shows a hot repair method for a molten metal container using the packing body (1) of the baking repair material of the present invention.
[0016]
As shown in FIG. A, the packing body (1) of the repair material for baking is put on the wall surface from the upper opening of the molten metal container (6) through the chute (7). Next, it rolls using the external force by the push rod or the inclination of the wall surface to reach the repaired part. In this case, when the molten metal container (6) can be tilted as in a converter, ladle, etc., as shown in Fig. B, if the tilting when the container is rebuilt is used, the packing body (1) for the repairing material for baking is covered. It naturally reaches the recess that is the repair part.
[0017]
Next, an actual machine test of a packing body for a repairing material for bake according to an embodiment of the present invention and a hot repairing method using the same is shown.
A container container made of polypropylene having a thickness of 0.3 mm is accommodated in a burnable hard cylinder made of a paper tube having a thickness of 5 mm, an inner diameter of 800 mm, and a height of 1000 mm. Next, the sintered magnesia clinker is 80 wt% and the pitch is 20 wt%. The resulting baking repair material was incorporated in 1 t to obtain a package of the baking repair material. Although the baking repair material is an irregular refractory, it can be stacked by reinforcement of a hard cylinder, which is convenient for storage or transportation.
[0018]
Also, in hot repair of the converter, the packaging body of the above-mentioned baking repair material is dropped with a chute on the side wall of the converter, which is tilted sideways, and the repaired part is repaired by using the inclined surface of the side wall to repair the lower part of the side wall. The package of materials was reached. The residual heat of the furnace wall was 1200 to 1400 ° C., and the baking repair material reached the part to be repaired and then softened and flowed out of the hard cylinder in the package due to the burning of the container bag, and the hard cylinder was also burned out. The baking repair material was baked onto the repaired portion by pitch carbonization, and the furnace lining could be repaired.
[0019]
【effect】
The effects of the present invention are enumerated as follows.
(1) The container bag and the hard cylinder holding the container bag are tightly integrated by the pressure of the baking repair material due to its own weight, and the entire package has sufficient strength. It is extremely preferable in terms of handling convenience and work safety, such as storage and transfer.
(2) Since the baked repair material is a hard cylinder and the outer shape is cylindrical, it can roll on the wall surface to reach the repaired part during lining repair. For example, in the case of tiltable molten metal containers such as converters and ladles, if the tilting when the container is rebuilt is used, the package of the baking repair material rolls without applying external force and naturally reaches the non-repaired part. To do.
[0020]
(3) While rolling on the wall surface, the packing body comes into contact with the hot wall surface, but the packing body of the repair material for baking is protected against heat by a hard cylinder, and by maintaining the columnar shape, the rolling body can be repaired by rolling. Can be reached.
{Circle around (4)} If the upper and / or lower portions of the hard cylinder are opened, the seizing repair material can flow out from the open portion at an early stage even when the burning of the hard cylinder is delayed.
[Brief description of the drawings]
FIG. 1 is a perspective view of a packing body for a baking repair material according to an embodiment of the present invention.
FIG. 2 is a cross-sectional view of a packing body for a baking repair material according to an embodiment of the present invention.
FIG. 3 shows a hot repair method for a molten metal container using a packing body for a repairing material according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Packing body of repair material 2 Container bag 3 Repair material 4 Burning hard cylinder 5 Suspension string 6 Molten metal container 7 Chute

Claims (4)

焼付補修材を収納した焼失性コンテナバッグと、このコンテナバッグを抱持した焼失性硬質円筒よりなる焼付補修材の梱包体。A package of a burn-in repair material comprising a burn-out container bag containing a bake repair material and a burn-out hard cylinder holding the container bag. 焼失性硬質円筒の上方および/または下方が開放されている請求項1記載の焼付補修材の梱包体。The packing body of the baking repair material according to claim 1, wherein an upper and / or lower portion of the burnable hard cylinder is open. コンテナバッグに吊り紐を設けた請求項1または2記載の焼付補修材の梱包体。The packing body of the repair material for baking according to claim 1 or 2, wherein a hanging strap is provided on the container bag. 請求項1、2または3記載の焼付補修材の梱包体を、炉壁面上を転動して被補修部に到達させる溶融金属容器の熱間補修方法。The hot repair method of the molten metal container which rolls the package body of the baking repair material of Claim 1, 2, or 3 on a furnace wall surface, and arrives at a to-be-repaired part.
JP17934595A 1995-06-21 1995-06-21 Baking repair material package and hot repair method for molten metal container using the same Expired - Fee Related JP3606954B2 (en)

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JP17934595A JP3606954B2 (en) 1995-06-21 1995-06-21 Baking repair material package and hot repair method for molten metal container using the same

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