JP3454930B2 - Resin coating material - Google Patents
Resin coating materialInfo
- Publication number
- JP3454930B2 JP3454930B2 JP20032094A JP20032094A JP3454930B2 JP 3454930 B2 JP3454930 B2 JP 3454930B2 JP 20032094 A JP20032094 A JP 20032094A JP 20032094 A JP20032094 A JP 20032094A JP 3454930 B2 JP3454930 B2 JP 3454930B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- parts
- weight
- coating material
- solid lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Description
【０００１】[0001]
【産業上の利用分野】この出願発明は、ゴム、プラスチ
ックの低摩擦、高耐摩耗性を向上するための樹脂被覆材
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin coating material for improving low friction and high abrasion resistance of rubber and plastic.
【０００２】[0002]
【従来の技術】固体潤滑剤を含有するゴム、プラスチッ
クの低摩擦、高耐摩耗性を向上するための樹脂被覆材は
これまで知られている。2. Description of the Related Art Resin coating materials for improving low friction and high wear resistance of rubbers and plastics containing a solid lubricant have been known so far.
【０００３】[0003]
【発明が解決すべき課題】しかし、これらの樹脂被覆材
は、満足な低摩擦係数が得られず、とくにガラスなどの
場合には、異音の発生、スティックスリップの発生があ
り、さらには耐久性の面でも問題があった。However, these resin coating materials do not provide a satisfactory low coefficient of friction, and in the case of glass or the like, abnormal noise or stick-slip occurs, and the durability is further improved. There was also a problem in terms of sex.
【０００４】[0004]
【課題を解決するための手段】この出願発明は、このよ
うな従来技術の欠点を解決するものであり、シリコーン
ゴムおよび固体潤滑剤を含有することによりゴム、プラ
スチックの低摩擦、高耐摩耗性を向上するための樹脂被
覆材を提供することを目的とする。この出願発明者等
は、このような目的を達成するために種々の方法を検討
した結果、固体潤滑剤を含有する樹脂にシリコーンゴム
を添加することにより低摩擦、高耐摩耗性を向上するこ
とを見いだし、この出願発明を完成した。The present invention solves the above-mentioned drawbacks of the prior art. By containing a silicone rubber and a solid lubricant, the rubber and the plastic have low friction and high wear resistance. It aims at providing the resin coating material for improving. The inventors of the present application have studied various methods for achieving such an object, and as a result, have improved low friction and high wear resistance by adding silicone rubber to a resin containing a solid lubricant. They found out and completed the invention of this application.
【０００５】この出願発明で用いられるシリコーンゴム
としては、加硫したものを粉砕し、粒径が３〜５μｍの
ものが好ましい。配合量は、樹脂１００重量部に対し
て、５〜５０重量部が使用され、１０〜３０重量部が好
ましい。３０重量部を越えると、塗膜の強度が低下し、
耐摩耗性が低下することがある。また、１０重量部未満
になると、低摩擦が得られにくくなることがある。As the silicone rubber used in the present invention, a vulcanized one is preferably crushed and has a particle size of 3 to 5 μm. The compounding amount is 5 to 50 parts by weight, preferably 10 to 30 parts by weight, based on 100 parts by weight of the resin. If it exceeds 30 parts by weight, the strength of the coating film decreases,
The wear resistance may decrease. If it is less than 10 parts by weight, it may be difficult to obtain low friction.
【０００６】この出願発明で用いられる固体潤滑剤とし
ては、鉱物ＭｏＳ2、ポリテトラフルオロエチレン、グ
ラファイト、窒化ホウ素等があげられ、ポリテトラフル
オロエチレンがとくに好ましい。樹脂としては、ポリウ
レタン樹脂、水酸基含有フッ素樹脂、ウレタン変性エポ
キシ樹脂、ジグリシジルエステル、シリコーン樹脂等が
あげられ、ポリウレタン樹脂、シリコーン樹脂が好まし
く、ゴムに対する密着性、ゴムの伸びに対する追随性に
優れる。配合量は、樹脂１００重量部に対して、５０〜
３００重量部が使用され、８０〜２４０重量部が好まし
い。Examples of the solid lubricant used in the invention of the present application include minerals MoS 2 , polytetrafluoroethylene, graphite, boron nitride and the like, and polytetrafluoroethylene is particularly preferable. Examples of the resin include a polyurethane resin, a hydroxyl group-containing fluororesin, a urethane-modified epoxy resin, a diglycidyl ester, a silicone resin, and the like. A polyurethane resin and a silicone resin are preferable, and they have excellent adhesion to rubber and excellent followability to elongation of rubber. The compounding amount is 50 to 100 parts by weight of the resin.
300 parts by weight are used, preferably 80 to 240 parts by weight.
【０００７】この出願発明の樹脂被覆材は、樹脂を溶剤
で希釈し、その溶液中にシリコーンゴムおよび固体潤滑
剤を混合し、分散させることにより製造する。The resin coating material of the present invention is produced by diluting a resin with a solvent and mixing and dispersing a silicone rubber and a solid lubricant in the solution.
【０００８】この出願発明の樹脂被覆材を使用する場合
には、予め混合しておいた固体潤滑剤に硬化剤を加えた
後、ゴムにスプレー、ディッピング、刷毛塗り等により
コーティング後、加熱硬化する。コーティングは、膜厚
が５〜５０μｍが好ましく、１０〜１５μｍがとくに好
ましい。加熱硬化は、５０〜１５０℃で３０〜６０分が
好ましく、８０〜１００℃で３０分がとくに好ましい。When the resin coating material of the present invention is used, a curing agent is added to a solid lubricant which has been mixed in advance, and then the rubber is coated by spraying, dipping, brushing, etc., and then cured by heating. . The coating preferably has a film thickness of 5 to 50 μm, particularly preferably 10 to 15 μm. The heat curing is preferably at 50 to 150 ° C. for 30 to 60 minutes, particularly preferably at 80 to 100 ° C. for 30 minutes.
【０００９】硬化剤としては、ポリイソシアネート、ポ
リアミドアミン、脂肪族ポリアミン、脂環族ジアミン、
第三級アミンが好ましく、ポリイソシアネートがとくに
好ましい。As the curing agent, polyisocyanate, polyamidoamine, aliphatic polyamine, alicyclic diamine,
Tertiary amines are preferred and polyisocyanates are especially preferred.
【００１０】この出願発明の被覆材で被覆するゴムとし
ては、天然ゴム、エチレン−プロピレンゴム、ニトリル
ゴム、スチレン−ブタジエンゴム、クロロプレンゴム、
フッ素ゴム、アクリルゴム等があげられ、天然ゴム、エ
チレン−プロピレンゴム、ニトリルゴムがとくに好まし
い。The rubber coated with the coating material of the present invention includes natural rubber, ethylene-propylene rubber, nitrile rubber, styrene-butadiene rubber, chloroprene rubber,
Fluorine rubber, acrylic rubber and the like are mentioned, and natural rubber, ethylene-propylene rubber and nitrile rubber are particularly preferable.
【００１１】この出願発明の被覆材で被覆するプラスチ
ックとしては、塩化ビニル、ポリウレタン、ナイロン
６、ナイロン６６、ナイロン８、ナイロン１１、ナイロ
ン６１０その他があるが、塩化ビニル、ポリウレタン、
ナイロンがとくに好ましい。以下、実施例によりこの出
願発明を具体的に説明する。Examples of plastics coated with the coating material of the present invention include vinyl chloride, polyurethane, nylon 6, nylon 66, nylon 8, nylon 11, nylon 610, and others.
Nylon is especially preferred. Hereinafter, the present invention will be specifically described with reference to examples.
【００１２】[0012]
実施例１
ポリウレタン樹脂（Ｄ６−４３９ 大日本インキ化学工
業（株））１００重量部をメチルエチルケトン３５０重
量部で希釈し、その溶液中にシリコーンゴム１０重量
部、ポリテトラフルオロエチレン（ＫＴＬ−８Ｆ
（株）喜多村）１４０重量部、グラファイト（日本黒鉛
工業（株））３．５重量部を混合し、分散させることに
より樹脂被覆材を製造する。この樹脂被覆材に硬化剤
（ＤＮ９８０ 大日本インキ化学工業（株））６０重量
部を加え、スプレーで膜厚１５μｍをニトリルゴムシー
トに（硬さＪＩＳＡ６０ 厚さ１ｍｍ）コーティング
し、８０℃で３０分間硬化した。この摺動部材は、初期
摩擦係数が０．２０であり、耐久回数は１８３０００で
あった。なお、試験方法はつぎのとおりである。ＦＡＬ
ＥＸ試験機（ＴＹＰＥ ＬＦＷ−１）による、ブロック
に作製試料を張り付け未処理のリングと摺動させる。滑
り速度３０ｃｐｍ、荷重２０Ｌｂｓ、角度９０゜の往復
動の潤滑下で初期摩擦係数を求める。また、摩擦係数が
０．５を越える時点のサイクル数を耐久回数とする。Example 1 100 parts by weight of a polyurethane resin (D6-439 Dainippon Ink and Chemicals, Inc.) was diluted with 350 parts by weight of methyl ethyl ketone, and 10 parts by weight of silicone rubber and polytetrafluoroethylene (KTL-8F) were added to the solution.
140 parts by weight of Kitamura Co., Ltd. and 3.5 parts by weight of graphite (Nippon Graphite Industry Co., Ltd.) are mixed and dispersed to produce a resin coating material. To this resin coating material, 60 parts by weight of a curing agent (DN980, Dainippon Ink and Chemicals, Inc.) was added, and a nitrile rubber sheet was coated with a film having a thickness of 15 μm by spraying (hardness JISA60 thickness 1 mm), and at 80 ° C. for 30 minutes. Cured. This sliding member had an initial friction coefficient of 0.20 and a durability count of 183,000. The test method is as follows. FAL
An EX tester (TYPE LFW-1) is used to attach the prepared sample to the block and slide it with an untreated ring. The initial friction coefficient is determined under the condition of a sliding speed of 30 cpm, a load of 20 Lbs, and reciprocating lubrication at an angle of 90 °. Further, the number of cycles when the friction coefficient exceeds 0.5 is defined as the number of durability cycles.
【００１３】実施例２〜８
実施例１のシリコーンゴム、固体潤滑剤を下記のように
して樹脂摺動部材を製造した。その結果はつぎのとおり
である。Examples 2 to 8 A resin sliding member was manufactured by using the silicone rubber and the solid lubricant of Example 1 as follows. The results are as follows.
【００１４】 実施例 シリコーンコ゛ム 固 体 潤 滑 剤 (wt%) 摺動特性 (wt%) PTFE MoS 2 黒鉛 合計 初期 耐久性 2 20.0 130 3.5 133.5 0.19 185000 3 30.0 120 3.5 123.5 0.19 183000 4 25.0 150 70 220.0 0.20 170000 5 15.0 170 70 240.0 0.20 169000 6 10.0 60 20 80.0 0.22 175000 7 20.0 60 20 80.0 0.21 178000 8 30.0 60 20 80.0 0.21 180000Example Silicone rubber Solid lubricant (wt%) Sliding property (wt%) PTFE MoS 2 Graphite Total initial durability 2 20.0 130 3.5 133.5 0.19 185000 3 30.0 120 3.5 123.5 0.19 183000 4 25.0 150 70 220.0 0.20 170000 5 15.0 170 70 240.0 0.20 169000 6 10.0 60 20 80.0 0.22 175000 7 20.0 60 20 80.0 0.21 178000 8 30.0 60 20 80.0 0.21 180000
【００１５】実施例９
水酸基含有フッ素樹脂（Ｋ−７０２ 大日本インキ化学
工業（株））１００重量部をメチルエチルケトン４００
重量部、トルエン２００重量部で希釈し、その溶液中に
シリコーンゴム１０重量部、ポリテトラフルオロエチレ
ン（ＫＴＬ−８Ｆ （株）喜多村）１４０重量部、グラ
ファイト（日本黒鉛工業（株）） ３．５重量部を混合
し、分散させることにより樹脂被覆材を製造する。この
樹脂被覆材に硬化剤（ＤＮ９８０ 大日本インキ化学工
業（株））１２重量部を加え、スプレーで膜厚１５μｍ
をニトリルゴムシートに（硬さＪＩＳＡ６０ 厚さ１ｍ
ｍ）コーティングし、８０℃で３０分間硬化した。この
摺動部材は、初期摩擦係数が０．２０であり、耐久回数
は９４０００であった。Example 9 100 parts by weight of a hydroxyl group-containing fluororesin (K-702, Dainippon Ink and Chemicals, Inc.) was added to methyl ethyl ketone 400.
10 parts by weight of silicone rubber, 140 parts by weight of polytetrafluoroethylene (KTL-8F Kitamura Co., Ltd.), graphite (Nippon Graphite Industry Co., Ltd.) 3.5 parts by weight. A resin coating material is manufactured by mixing and dispersing parts by weight. To this resin coating material, 12 parts by weight of a curing agent (DN980, Dainippon Ink and Chemicals, Inc.) was added, and the film thickness was 15 μm by spraying.
On a nitrile rubber sheet (hardness JISA60 thickness 1m
m) Coated and cured at 80 ° C for 30 minutes. This sliding member had an initial friction coefficient of 0.20 and a durability count of 94,000.
【００１６】実施例１０〜１５
実施例９のシリコーンゴム、固体潤滑剤を下記のように
して樹脂摺動部材を製造した。その結果はつぎのとおり
である。Examples 10 to 15 Silicone rubber and solid lubricant of Example 9 were manufactured as follows to manufacture resin sliding members. The results are as follows.
【００１７】 実施例 シリコーンコ゛ム 固 体 潤 滑 剤 (wt%) 摺動特性 (wt%) PTFE MoS 2 黒鉛 合計 初期 耐久性 10 20.0 130 3.5 133.5 0.18 95000 11 30.0 120 3.5 123.5 0.16 93000 12 25.0 150 70 220.0 0.20 89000 13 25.0 170 70 240.0 0.19 87000 14 25.0 60 20 80.0 0.19 90000 15 30.0 60 20 80.0 0.18 88000Example Silicone gum Solid lubricant (wt%) Sliding property (wt%) PTFE MoS 2 Graphite Total initial durability 10 20.0 130 3.5 133.5 0.18 95000 11 30.0 120 3.5 123.5 0.16 93000 12 25.0 150 70 220.0 0.20 89000 13 25.0 170 70 240.0 0.19 87000 14 25.0 60 20 80.0 0.19 90000 15 30.0 60 20 80.0 0.18 88000
【００１８】実施例１６
ウレタン変性エポキシ樹脂（Ｒ−１３６２ ＡＣＲ
（株））６：ジグリシジルエステル（ＩＰＵ−２２Ｇ
岡村製油（株））４の割合の１００重量部をメチルエチ
ルケトン５００重量部で希釈し、その溶液中にシリコー
ンゴム１０重量部、ポリテトラフルオロエチレン（ＫＴ
Ｌ−８Ｆ （株）喜多村）１４０重量部、グラファイト
（日本黒鉛工業（株））３．５重量部を混合し、分散さ
せることにより樹脂被覆材を製造する。この樹脂被覆材
に硬化剤（ＴＸＡ５２５ 富士化成工業（株））６０重
量部を加え、スプレーで膜厚１５μｍをニトリルゴムシ
ートに（硬さＪＩＳＡ６０ 厚さ１ｍｍ）コーティング
し、８０℃で３０分間硬化した。この摺動部材は、初期
摩擦係数が０．１９であり、耐久回数は１１００００で
あった。Example 16 Urethane-modified epoxy resin (R-1362 ACR
Ltd. 6: Diglycidyl ester (IPU-22G
100 parts by weight of Okamura Oil Co., Ltd. 4 was diluted with 500 parts by weight of methyl ethyl ketone, and 10 parts by weight of silicone rubber and polytetrafluoroethylene (KT) were added to the solution.
A resin coating material is manufactured by mixing and dispersing 140 parts by weight of L-8F Kitamura Co., Ltd. and 3.5 parts by weight of graphite (Nippon Graphite Industry Co., Ltd.). To this resin coating material, 60 parts by weight of a curing agent (TXA525, Fuji Kasei Kogyo Co., Ltd.) was added, and a nitrile rubber sheet having a film thickness of 15 μm was coated by spraying (hardness JISA60 thickness 1 mm) and cured at 80 ° C. for 30 minutes. . This sliding member had an initial friction coefficient of 0.19 and a durability count of 110000.
【００１９】実施例１７〜２２
実施例１６のシリコーンゴム、固体潤滑剤を下記のよう
にして樹脂摺動部材を製造した。その結果はつぎのとお
りである。Examples 17 to 22 Resin sliding members were produced by using the silicone rubber and the solid lubricant of Example 16 as follows. The results are as follows.
【００２０】 実施例 シリコーンコ゛ム 固 体 潤 滑 剤 (wt%) 摺動特性 (wt%) PTFE MoS 2 黒鉛 合計 初期 耐久性 17 20.0 130 3.5 133.5 0.14 120000 18 30.0 120 3.5 123.5 0.16 100000 19 25.0 150 70 220.0 0.18 95000 20 25.0 170 70 240.0 0.18 93000 21 25.0 60 20 80.0 0.19 98000 22 20.0 60 20 80.0 0.18 95000Example Silicone gum Solid lubricant (wt%) Sliding property (wt%) PTFE MoS 2 Graphite Total initial durability 17 20.0 130 3.5 133.5 0.14 120000 18 30.0 120 3.5 123.5 0.16 100000 19 25.0 150 70 220.0 0.18 95000 20 25.0 170 70 240.0 0.18 93000 21 25.0 60 20 80.0 0.19 98000 22 20.0 60 20 80.0 0.18 95000
【００２１】[0021]
【発明の効果】この出願発明は、シリコーンゴムおよび
固体潤滑剤を含有することによりゴム、プラスチックの
低摩擦、高耐摩耗性を向上するための樹脂被覆材を提供
するものであり、とくにガラスなどの場合の、異音の発
生、スティックスリップの発生を防止し、さらには耐久
性の面でも優れた樹脂被覆材を提供することができウェ
ザーストリップ、グラスラン、オイルシール、パッキ
ン、ワイパーブレード等に利用される。INDUSTRIAL APPLICABILITY The present invention provides a resin coating material for improving low friction and high abrasion resistance of rubber and plastic by containing silicone rubber and a solid lubricant, and particularly glass and the like. In the case of, it can prevent the generation of abnormal noise and stick-slip, and can provide a resin coating material that is also excellent in terms of durability. Used for weather strips, glass runs, oil seals, packings, wiper blades, etc. To be done.
フロントページの続き (56)参考文献 特開 平５−269437（ＪＰ，Ａ) 特開 平２−274763（ＪＰ，Ａ) 特開 昭63−248860（ＪＰ，Ａ) 特開 平４−85369（ＪＰ，Ａ) 特開 平５−25420（ＪＰ，Ａ) 国際公開92／018560（ＷＯ，Ａ１) (58)調査した分野(Int.Cl.7，ＤＢ名) C08J 7/04 - 7/06 C08L 1/00 - 101/16 C09D 1/00 - 201/10 Continuation of the front page (56) Reference JP-A-5-269437 (JP, A) JP-A-2-274763 (JP, A) JP-A-63-248860 (JP, A) JP-A-4-85369 (JP , A) JP-A-5-25420 (JP, A) International Publication 92/018560 (WO, A1) (58) Fields investigated (Int.Cl. 7 , DB name) C08J 7 /04-7/06 C08L 1 / 00-101/16 C09D 1/00-201/10
Claims (4)
脂とを含有し、 前記樹脂は、ポリウレタン樹脂、水酸基含有フッ素樹脂
及びシリコーン樹脂のいずれかであり、固体潤滑剤は、
少なくともポリテトラフルオロエチレンを含有し、鉱物
ＭｏＳ 2 又はグラファイトからなり、 当該樹脂１００重量部に対して、前記シリコーンゴム粒
子１０〜３０重量部および前記固体潤滑剤８０〜２４０
重量部を含有する、ゴム、プラスチックの低摩擦、高耐
摩耗用被覆材。1. A silicone rubber particle, a solid lubricant, and a resin are contained, and the resin is any of a polyurethane resin, a hydroxyl group-containing fluororesin and a silicone resin, and the solid lubricant is
Minerals containing at least polytetrafluoroethylene
MoS consists of two or graphite, with respect to the resin 100 parts by weight, said silicone rubber particles 10-30 parts by weight of the solid lubricant 80 to 240
A low friction and high wear resistance coating material for rubber and plastic containing parts by weight.
脂とを含有し、 前記樹脂は、ウレタン変性エポキシ樹脂であり、固体潤
滑剤は、少なくともポリテトラフルオロエチレンを含有
し、鉱物ＭｏＳ2又はグラファイトからなり、 当該樹脂１００重量部に対して、前記シリコーンゴム粒
子１０〜３０重量部および前記固体潤滑剤８０〜２４０
重量部を含有する、ゴム、プラスチックの低摩擦、高耐
摩耗用被覆材。2. A silicone rubber particle, a solid lubricant, and a resin, wherein the resin is a urethane-modified epoxy resin, the solid lubricant contains at least polytetrafluoroethylene, and the mineral MoS 2 or 10 to 30 parts by weight of the silicone rubber particles and 80 to 240 parts of the solid lubricant based on 100 parts by weight of the resin.
A low friction and high wear resistance coating material for rubber and plastic containing parts by weight.
ｍである、請求項１又は２に記載の被覆材。3. The silicone rubber particles have a particle size of 3 to 5 μm.
The coating material according to claim 1 or 2 , which is m.
硬化膜を備える、被覆体。4. comprises a cured film of the coating material according to any one of claims 1 to 3 covering body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20032094A JP3454930B2 (en) | 1994-08-03 | 1994-08-03 | Resin coating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20032094A JP3454930B2 (en) | 1994-08-03 | 1994-08-03 | Resin coating material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0848800A JPH0848800A (en) | 1996-02-20 |
| JP3454930B2 true JP3454930B2 (en) | 2003-10-06 |
Family
ID=16422348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20032094A Expired - Lifetime JP3454930B2 (en) | 1994-08-03 | 1994-08-03 | Resin coating material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3454930B2 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2749851B1 (en) | 1996-06-13 | 2000-02-25 | Valeo Systemes Dessuyage | METHOD FOR MANUFACTURING A PROFILE HAVING A SURFACE LAYER REDUCING THE COEFFICIENT OF FRICTION WITH A GLASS SURFACE TO BE WIPED AND WIPING BLADE OBTAINED BY SUCH A PROCESS |
| FR2749852B1 (en) * | 1996-06-13 | 2004-01-23 | Valeo Systemes Dessuyage | SOLUTION FOR REALIZING A COATING ON A PROFILE, WIPING BLADE COATED WITH SUCH A SOLUTION, METHOD FOR COATING A PROFILE WITH SUCH A COATING AND WIPING BLADE COATED WITH A COATING, OBTAINED BY SUCH A PROCESS |
| JPH1095314A (en) * | 1996-09-20 | 1998-04-14 | Ntn Corp | Wiper blade and its manufacture |
| KR100502117B1 (en) * | 2001-07-26 | 2005-07-20 | 정용득 | The rubber coating soluting on metal and nonmetal plate |
| DE10226752A1 (en) * | 2002-06-14 | 2004-01-08 | Robert Bosch Gmbh | Wiper blade for windshield wipers and method for producing the same |
| US7247673B2 (en) | 2003-04-30 | 2007-07-24 | National Starch And Chemical Investment Holding Corporation | Waterbased high abrasion resistant coating |
| NL1024027C2 (en) * | 2003-07-31 | 2005-02-01 | Tno | Slip varnish. |
| JP4945075B2 (en) * | 2004-11-30 | 2012-06-06 | アクロス株式会社 | Coating composition and rubber seal member |
| EP1895208B1 (en) | 2005-06-21 | 2012-07-04 | NOK Corporation | Oil seal and process for producing the same |
| CA2623553C (en) | 2007-08-17 | 2013-01-15 | Adm 21 Co., Ltd. | Composition for coating wiper blade rubbers, coating method using the same and wiper blade rubbers made therefrom |
| CN102482516A (en) | 2009-08-21 | 2012-05-30 | 道康宁东丽株式会社 | Coating composition for sliding members |
| JP6108727B2 (en) * | 2012-08-29 | 2017-04-05 | アトムメディカル株式会社 | Packing for incubator window and incubator |
| JP6114180B2 (en) * | 2013-12-27 | 2017-04-12 | トヨタ自動車株式会社 | Coating composition for sliding member |
| CN109608709A (en) * | 2018-10-30 | 2019-04-12 | 浙江海啊汽车用品有限公司 | A kind of nano automobile chair cover material and its manufacturing method |
| CN110054943B (en) * | 2019-04-11 | 2020-11-24 | 华南理工大学 | Molybdenum disulfide nano coating for reducing friction coefficient and abrasion of rubber surface and preparation method thereof |
-
1994
- 1994-08-03 JP JP20032094A patent/JP3454930B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0848800A (en) | 1996-02-20 |
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