JP3448949B2 - UV irradiation device - Google Patents

UV irradiation device

Info

Publication number
JP3448949B2
JP3448949B2 JP07367894A JP7367894A JP3448949B2 JP 3448949 B2 JP3448949 B2 JP 3448949B2 JP 07367894 A JP07367894 A JP 07367894A JP 7367894 A JP7367894 A JP 7367894A JP 3448949 B2 JP3448949 B2 JP 3448949B2
Authority
JP
Japan
Prior art keywords
ultraviolet
coating layer
web
lamp
light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP07367894A
Other languages
Japanese (ja)
Other versions
JPH07275775A (en
Inventor
敏 高橋
荒木  登
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dexerials Corp
Original Assignee
Sony Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=13525130&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JP3448949(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Sony Chemicals Corp filed Critical Sony Chemicals Corp
Priority to JP07367894A priority Critical patent/JP3448949B2/en
Publication of JPH07275775A publication Critical patent/JPH07275775A/en
Application granted granted Critical
Publication of JP3448949B2 publication Critical patent/JP3448949B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】 【0001】 【産業上の利用分野】本発明は、プラスチックフィル
ム、紙、はく離フィルム、金属箔等に設けられた紫外線
硬化型塗工層を硬化させるための紫外線照射装置。 【0002】 【従来の技術】紫外線照射装置はプラスチックフィルム
や、紙、はく離フィルム、金属箔等に設けられた紫外線
硬化型塗工層を連続的に硬化させて、シールテープや粘
着テープ、印刷物、プリント回路基板等を得るのに広く
使用されている。 【0003】図2に従来の紫外線照射装置を示す。図2
の紫外線照射装置はランプハウス21と紫外線硬化型塗
工層を設けたプラスチックフィルム等のウェブ22をラ
ンプハウス21の下に搬送するコンベヤーベルト23と
から構成されている。ランプハウス21は管状のランプ
24、ランプ24で発生した紫外線を集光するための反
射ミラー25及び不要な波長の光をカットする熱線カッ
トフィルター26からなっている。 【0004】また、特開平5−50007には紫外線発
生手段で発生した紫外線を光ファイバー中を伝播させ
て、ウェッブに均一に照射する装置が提案さている。 【0005】 【発明が解決しようとする課題】管状のランプは管の両
端の電極の放電によって紫外線を発生する。このために
紫外線の強度は管の中央部では安定しているが、両端の
電極部に近づくにつれて弱くなる分布をしている。 【0006】図2に示すような紫外線照射装置において
は、管状ランプ24はウェブ22に対して直交するよう
に配列されているので、ウェブ22に照射される紫外線
の強度は中心部と両側では異なってくる。このため、硬
化した紫外線硬化型塗工層は中心部と両側では特性にお
いて微妙な差異が生じるという問題があった。 【0007】均一な特性の塗工層を得るために管状ラン
プの中央部で照射すると、有効照射幅が狭くなり、経済
的な損失が大きくなる。管状ランプの長さを広くすれば
塗工幅も広くできるが、管の長いランプは電力の消費が
大きく、ランプの寿命も短くなるし、装置も大型化する
等好ましくない。 【0008】これに対し、特開平5−50007は紫外
線発生手段で発生した紫外線を複数の光ファイバー中を
伝播させて、ウェブ全面にに均一に照射させるので均一
な特性の塗工層が得られる。しかし光ファイバーが高価
で、紫外線が光ファイバー中を伝播する間に強度が低下
するという別な問題がある。 【0009】本発明は以上のような技術上の問題点を解
決しようとするものである。プラスチックフィルムや、
紙、はく離フィルム、金属箔等に設けられた紫外線硬化
型塗工層を連続的に硬化させる際に、ウェブの中心部及
び両側に紫外線を均一に照射し、均一な特性を有する硬
化塗工層を得るための小型でそして安価な紫外線照射装
置を提供することを目的とする。 【0010】 【問題を解決するための手段】以上の目的を達成するた
めに、本発明は、紫外線発生手段、及び紫外線発生手
段で発生した紫外線をウェブ上に設けた紫外線硬化型塗
工層に連続的に照射させるためのウェブ搬送手段を有す
る紫外線照射装置を用いて、主波長356nmの紫外線
を該紫外線硬化型塗工層に照射して約80%重合させた
後、主波長365nmの紫外線を照射して該紫外線硬化
型塗工層の硬化を完結させることを特徴とする紫外線
化方法を提供する。さらに、前記の複数の蛍光管をウエ
ブの流れ方向に平行に並列させた紫外線発生手段をウエ
ブの流れ方向に複数配列し、紫外線効果型塗工層の硬化
を速めることも可能である。 【0011】紫外線を発生する蛍光管は、高圧水銀ラン
プ、メタルハライドランプ、中圧水銀ランプや低圧水銀
ランプ等の一般の水銀ランプが使用できるが、なるべく
低出力のものが好ましい。例えば、352nmの紫外線
を選択的に発生するケミカルランプ、捕虫用蛍光ランプ
及び複写機用現像ランプ等が使用できる。 【0012】前記の紫外線発生手段を構成する該蛍光管
は、互いにできるだけ接近させ、等間隔かつ平行に配列
される。接近して並べることにより該蛍光管から発生す
る紫外線は互いに干渉し合って紫外線の強度を上げるこ
とができる。さらに、等間隔かつ平行に並べることによ
り、ウェブ上の紫外線硬化型塗工層全面に紫外線を均一
に照射することができる。蛍光管を等間隔かつ平行に並
べたユニットが一つでは紫外線硬化型塗工層の硬化が遅
い場合、該ユニットをウェブの流れ方向に複数配列して
硬化速度を高めることも簡単にできる。 【0013】該蛍光管を並列させる間隔は0mmから1
00mmが好ましい。ウェブ上に塗工された紫外線硬化
型塗工層の幅は、その両端が該ユニット中に並列させた
該蛍光管の両側の少なくとも一本をはずした内側に入る
ようにした方が該紫外線硬化型塗工層面上の紫外線強度
が均一になって好ましい。 【0014】また、ウェブ搬送手段は、従来から使用さ
れているベルトコンベヤーやロールツーロール搬送装置
等を搬送対象物に応じて選べばよい。 【0015】 【実施例】以下、この発明を図面に基づき具体的に説明
する。図1は、本発明の紫外線照射装置の実施例を示
す。主波長356nmの捕虫用蛍光ランプ1を60mm
間隔で8本並列させた紫外線発生手段4を、紫外線発生
手段4内の前記の捕虫用蛍光ランプ1がウェブの上方約
180mmにかつ流れ方向に平行になるように、3基連
続してセットした。 【0016】両面をシリコンはく離処理した厚さ50μ
m、幅200mmのポリエステルフィルムの一方の面に
下記のように調製した紫外線硬化型粘着剤組成物約60
g/m2 をロールコーターで、その塗工幅の中心線が該
ポリエステルフィルムの中心線に重なるようにして約1
20mmの幅に塗工した。 【0017】〔紫外線硬化型粘着剤組成物の調製方法〕
3,5,5トリメチルヘキシルアクリレート90gとア
クリル酸10gからなるモノマー混合液100gにアク
リルゴム(トアクロンPS220、東亜ペイント社)5
gを攪拌機容器で48時間攪拌して溶解し、0.18P
a・sの粘稠溶液を得た。さらに、液にノニルフェノキ
シジプロピレングライコールアクリレート(M−11
7、東亜合成化学工業社)10g、分子量312のヒド
ロキシピバリン酸ネオペンチルグライコールジアクリレ
ート(KAYARAD MANDA日本化薬社)を0.
0005モル(0.156g)及びアセトフェノン系光
開始剤2−ヒドロキシ−2−メチル−1−フェニルプロ
パン−1−オン(ダロキュア1173、メルク社)0.
02gを添加して約30分間攪拌し紫外線硬化型粘着剤
組成物を得た。 【0018】次に両面をシリコンはく離処理したポリエ
ステルフィルムの一方の面に前記の紫外線硬化型粘着剤
組成物約60g/m2 を塗工し、塗工層の上に片面のみ
シリコンはく離処理した50μm、幅200mmの透明
なポリエステルフィルムのはく離処理を積層し、積層物
を粘着剤層の厚みが0.06mmになるように調節した
ロールの間を通し、前記の紫外線照射手段内を8本並列
させた捕虫用蛍光ランプの中心の2本が塗工層の上にく
るようにし、毎分1メートルの速度で搬送し、次に主波
長365nmの高圧水銀ランプの紫外線を連続に照射し
て両面粘着テープを製造した。 【0019】一本の捕虫用蛍光ランプの発する光は、光
の強度が0.5mw/cm2 程度の肉眼で凝視できるほ
ど微弱であるが、複数集めて干渉させると2mw/cm
2 以上の強度の光となり、下記の評価結果に見られるよ
うに、本紫外線照射装置は短時間で紫外線重合を行わせ
ることができ小型で安価な紫外線照射装置となることが
分かった。得た両面接着テープの特性は下記のように評
価した。 【0020】〔接着力〕被着材として、280番の耐水
研磨紙で研磨した厚さ2mm、幅30mm、長さ120
mmのステンレス板と厚さ0.025mmのポリイミド
フィルム(デュポン社製、カプトン100H)を使用し
た。 【0021】両面粘着テ−プを幅20mm、長さ100
mmに切断し、片面はく離処理のポリエステルフィルム
を剥がしてステンレス板に仮貼付する。次にもう一方の
ポリエステルフィルムを剥がして該ポリイミドフィルム
を載置し、80℃ 5kgf/cm2 で10秒間圧着し
た。 【0022】接着試験片を153℃に調整した空気循環
オ−ブンの中に入れ、250時間、500時間、750
時間、1000時間後に取り出し、23℃において18
0度方向に毎分300mmの速度で引き剥がし、接着強
度を測定した。 【0023】その結果、初期の接着強度は、1.9kg
f/2cmであり、250時間後、500時間後、75
0時間後、1000時間後の接着強度は、各々2.1k
gf/2cm、1.8kgf/2cm、1.8kgf/
2cm、1.8kgf/2cmで接着強度の低下がなか
った。 【0024】〔耐熱保持力〕JIS Z 0237の保
持力の測定方法に準じて行った。被着材としては、28
0番の耐水研磨紙で研磨した厚さ2mmのステンレス板
と厚さ0.05mmのアルミニウム箔を使用した。接着
面積は、ステンレス板に対しては25×25mm、アル
ミニウム箔に対しては幅25mm長さ50mmとした。 【0025】│接着方法は接着力測定用試験片の作製に
準じて行なった。接着後、1kgfの│重をアルミ箔側
から垂直にかけ、180℃に1時間放置した後の接着部
のズレの大きさを測定した。ほとんどズレが発生せず、
耐熱保持力も優れた両面粘着テープであった。 【0026】本実施例では捕虫用蛍光ランプ群からなる
紫外線照射装置でのみ紫外線硬化型粘着剤組成物塗工層
を硬化させたが、この場合タックが少し低めになる傾向
がある。本紫外線照射装置では紫外線硬化型粘着剤組成
物塗工層を約80%重合させた後、主波長365nmの
高圧水銀灯ランプの紫外線を照射して重合を完結させる
方法とれば、タックも増し、重合時間も短縮でき経済的
である。 【効果】 ウェブ上に設けた紫外線硬化型塗工層面に均一に紫外
線を照射できるので、幅方向の中央部と両側で硬化塗工
層の特性に差異が発生しない。 小型で安価な紫外線照射装置が得られ、維持費も安価
である。 紫外線強度の小さい捕虫用蛍光ランプを使用するので
人体への影響が小さい。 ユニットの増減が簡単でラインスピードの調節が簡単
に行える。
Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an ultraviolet irradiation apparatus for curing an ultraviolet-curable coating layer provided on a plastic film, paper, a release film, a metal foil or the like. . 2. Description of the Related Art An ultraviolet irradiation apparatus continuously cures an ultraviolet-curable coating layer provided on a plastic film, paper, a peeling film, a metal foil, or the like to form a sealing tape, an adhesive tape, a printed material, or the like. Widely used to obtain printed circuit boards and the like. FIG. 2 shows a conventional ultraviolet irradiation apparatus. FIG.
The ultraviolet irradiating apparatus comprises a lamp house 21 and a conveyor belt 23 for conveying a web 22 such as a plastic film provided with an ultraviolet-curable coating layer under the lamp house 21. The lamp house 21 includes a tubular lamp 24, a reflection mirror 25 for condensing ultraviolet rays generated by the lamp 24, and a heat ray cut filter 26 for cutting off light of an unnecessary wavelength. Japanese Patent Application Laid-Open No. H5-50007 proposes an apparatus for propagating ultraviolet rays generated by ultraviolet ray generating means through an optical fiber and uniformly irradiating a web. [0005] A tubular lamp generates ultraviolet light by discharging electrodes at both ends of the tube. For this reason, the intensity of the ultraviolet light is stable at the central portion of the tube, but becomes weaker as it approaches the electrode portions at both ends. In the ultraviolet irradiation apparatus as shown in FIG. 2, since the tubular lamps 24 are arranged so as to be orthogonal to the web 22, the intensity of the ultraviolet light applied to the web 22 is different between the central portion and both sides. Come. For this reason, there is a problem that the cured ultraviolet curable coating layer has a slight difference in characteristics between the central portion and both sides. When irradiation is performed at the center of the tubular lamp in order to obtain a coating layer having uniform characteristics, the effective irradiation width is reduced, and the economic loss is increased. If the length of the tubular lamp is increased, the coating width can be increased. However, a lamp having a long tube consumes a large amount of electric power, shortens the life of the lamp, and increases the size of the apparatus. On the other hand, in Japanese Patent Laid-Open No. 5-50007, the ultraviolet light generated by the ultraviolet light generating means is propagated through a plurality of optical fibers and uniformly irradiates the entire surface of the web, so that a coating layer having uniform characteristics can be obtained. However, there is another problem that the optical fiber is expensive and the intensity is reduced while the ultraviolet light propagates through the optical fiber. The present invention is to solve the above technical problems. Plastic film,
When continuously curing an ultraviolet-curable coating layer provided on paper, a release film, a metal foil, etc., the center portion and both sides of the web are uniformly irradiated with ultraviolet rays, and a cured coating layer having uniform properties. It is an object of the present invention to provide a small and inexpensive ultraviolet irradiation device for obtaining the ultraviolet ray. [0010] To achieve the above object, according to solve the problems, the present invention provides an ultraviolet generating means, and an ultraviolet-curable coating layer provided with ultraviolet rays generated by the ultraviolet rays generating means on the web UV light having a main wavelength of 356 nm by using an ultraviolet irradiation device having a web conveying means for continuously irradiating the web
Was irradiated to the UV-curable coating layer to polymerize about 80%.
After that, ultraviolet rays having a main wavelength of 365 nm are irradiated to cure the ultraviolet rays.
UV hard and wherein the to complete the curing of the mold coating layer
Provide a method of conversion . Furthermore, it is also possible to arrange a plurality of ultraviolet ray generating means in which a plurality of the fluorescent tubes are arranged in parallel in the web flow direction in the web flow direction to accelerate the curing of the ultraviolet effect type coating layer. As a fluorescent tube for generating ultraviolet light, a general mercury lamp such as a high-pressure mercury lamp, a metal halide lamp, a medium-pressure mercury lamp, or a low-pressure mercury lamp can be used, but a lamp with a low output is preferable. For example, a chemical lamp that selectively generates 352 nm ultraviolet light, a fluorescent lamp for trapping insects, a developing lamp for a copying machine, and the like can be used. The fluorescent tubes constituting the ultraviolet ray generating means are arranged as close to each other as possible, at equal intervals and in parallel. By arranging closely, the ultraviolet rays generated from the fluorescent tubes can interfere with each other and increase the intensity of the ultraviolet rays. Furthermore, by arranging them at equal intervals and in parallel, the entire surface of the ultraviolet-curable coating layer on the web can be uniformly irradiated with ultraviolet rays. When the curing of the ultraviolet curable coating layer is slow with only one unit in which the fluorescent tubes are arranged in parallel at equal intervals, it is easy to increase the curing speed by arranging a plurality of such units in the flow direction of the web. The interval at which the fluorescent tubes are arranged in parallel is from 0 mm to 1 mm.
00 mm is preferred. The width of the UV-curable coating layer coated on the web is preferably such that both ends are inside the fluorescent tubes arranged in parallel in the unit with at least one of both sides removed. It is preferable because the ultraviolet intensity on the surface of the mold coating layer becomes uniform. As the web transport means, a conventionally used belt conveyor, roll-to-roll transport device or the like may be selected according to the transport target. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be specifically described below with reference to the drawings. FIG. 1 shows an embodiment of the ultraviolet irradiation apparatus of the present invention. Insect fluorescent lamp 1 with a main wavelength of 356 nm
Eight ultraviolet light generating means 4 arranged in parallel at intervals were set in succession so that the insect trapping fluorescent lamp 1 in the ultraviolet light generating means 4 was approximately 180 mm above the web and parallel to the flow direction. . Both sides are silicon-peeled to a thickness of 50 μm
m, a UV-curable pressure-sensitive adhesive composition prepared as follows on one side of a polyester film having a width of 200 mm.
g / m 2 with a roll coater so that the center line of the coating width is overlapped with the center line of the polyester film.
It was applied to a width of 20 mm. [Preparation method of UV-curable pressure-sensitive adhesive composition]
Acrylic rubber (Taclon PS220, Toa Paint Co.) was added to 100 g of a monomer mixture solution consisting of 90 g of 3,5,5 trimethylhexyl acrylate and 10 g of acrylic acid.
g in a stirrer container for 48 hours to dissolve,
A viscous solution of as was obtained. Further, nonylphenoxydipropylene glycol acrylate (M-11) was added to the solution.
7, Toa Gosei Chemical Industry Co., Ltd.) 10 g, neopentylglycol hydroxypivalate diacrylate having a molecular weight of 312 (KAYARAD MANDA Nippon Kayaku Co., Ltd.) was added to 0.1 g.
0005 mol (0.156 g) and acetophenone photoinitiator 2-hydroxy-2-methyl-1-phenylpropan-1-one (Darocur 1173, Merck)
After adding 02 g and stirring for about 30 minutes, an ultraviolet-curable pressure-sensitive adhesive composition was obtained. Next, about 60 g / m 2 of the above-mentioned UV-curable pressure-sensitive adhesive composition was applied to one surface of a polyester film having both surfaces subjected to silicon release treatment, and 50 μm of only one surface was subjected to silicon release treatment on the coating layer. A transparent polyester film having a width of 200 mm was peeled off, and the laminate was passed between rolls adjusted so that the thickness of the pressure-sensitive adhesive layer was 0.06 mm. So that the center two of the trapped fluorescent lamps are on the coating layer, transported at a rate of 1 meter per minute, and then continuously irradiated with ultraviolet light from a high-pressure mercury lamp with a main wavelength of 365 nm to adhere to both sides. Tape was manufactured. The light emitted from one fluorescent lamp for catching insects is so weak that the light intensity can be stared by the naked eye having a light intensity of about 0.5 mw / cm 2.
The intensity of the light was 2 or more, and as can be seen from the evaluation results below, it was found that the present ultraviolet irradiation apparatus was capable of performing ultraviolet polymerization in a short time and was a small and inexpensive ultraviolet irradiation apparatus. The properties of the obtained double-sided adhesive tape were evaluated as follows. [Adhesive Strength] As an adherend, a 2 mm thick, 30 mm wide, 120 mm long ground with a water-resistant abrasive paper of No. 280
mm stainless steel plate and a 0.025 mm-thick polyimide film (Kapton 100H, manufactured by DuPont) were used. A double-sided adhesive tape is 20 mm wide and 100 mm long.
mm, and peeled off the polyester film on one side, and temporarily attached to a stainless steel plate. Next, the other polyester film was peeled off, and the polyimide film was placed thereon and pressed at 80 ° C. at 5 kgf / cm 2 for 10 seconds. The adhesive test piece was placed in an air circulation oven adjusted to 153 ° C., and was subjected to 250 hours, 500 hours, and 750 hours.
Time, remove after 1000 hours, 18
The film was peeled off at a rate of 300 mm per minute in the 0 degree direction, and the adhesive strength was measured. As a result, the initial adhesive strength was 1.9 kg.
f / 2 cm, and after 250 hours, 500 hours, 75
The adhesive strength after 0 hour and after 1000 hours is 2.1k each.
gf / 2cm, 1.8kgf / 2cm, 1.8kgf /
At 2 cm and 1.8 kgf / 2 cm, there was no decrease in adhesive strength. [Heat-resistant holding power] The holding power was measured in accordance with the measuring method of the holding power in JIS Z 0237. As the adherend, 28
A 2 mm thick stainless steel plate polished with No. 0 water-resistant abrasive paper and a 0.05 mm thick aluminum foil were used. The bonding area was 25 × 25 mm for a stainless steel plate and 25 mm in width and 50 mm in length for an aluminum foil. The bonding method was performed in accordance with the preparation of the test piece for measuring the adhesive force. After bonding, a | weight of 1 kgf was applied vertically from the aluminum foil side, and the size of the displacement of the bonded portion after being left at 180 ° C. for 1 hour was measured. There is almost no displacement,
It was a double-sided pressure-sensitive adhesive tape with excellent heat retention. In the present embodiment, the coating layer of the ultraviolet-curable pressure-sensitive adhesive composition was cured only by an ultraviolet irradiation apparatus comprising a group of fluorescent lamps for trapping insects. In this case, the tack tends to be slightly lower. In this ultraviolet irradiation apparatus, if the method of polymerizing about 80% of the coating layer of the ultraviolet-curable pressure-sensitive adhesive composition and irradiating the ultraviolet rays of a high-pressure mercury lamp with a main wavelength of 365 nm to complete the polymerization, the tack increases and the polymerization increases. Time can be shortened and it is economical. [Effect] Since the surface of the ultraviolet-curable coating layer provided on the web can be uniformly irradiated with ultraviolet rays, there is no difference in the properties of the cured coating layer between the central portion in the width direction and both sides. A small and inexpensive ultraviolet irradiation device can be obtained, and the maintenance cost is also low. Since the fluorescent lamp for catching insects with low ultraviolet intensity is used, the influence on the human body is small. The number of units can be easily increased and decreased, and the line speed can be easily adjusted.

【図面の簡単な説明】 【図1】本発明の紫外線照射装置 【図2】従来の紫外線照射装置 【符号の説明】 1 蛍光管 2 ウェブ 3 紫外線硬化型塗工層 4 紫外線発生手段 21 ランプハウス 22 ウェブ 23 ベルトコンベヤー 24 紫外線ランプ 25 反射ミラー 26 熱線カットフィルター[Brief description of the drawings] FIG. 1 is an ultraviolet irradiation apparatus of the present invention. FIG. 2 shows a conventional ultraviolet irradiation apparatus. [Explanation of symbols] 1 fluorescent tube 2 Web 3 UV curable coating layer 4 Ultraviolet ray generating means 21 Lamp House 22 Web 23 Belt conveyor 24 UV lamp 25 Reflection mirror 26 Heat ray cut filter

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平3−169338(JP,A) 特開 昭52−8686(JP,A) 特開 昭59−36569(JP,A) 特開 平6−167714(JP,A) 特開 平6−135120(JP,A) (58)調査した分野(Int.Cl.7,DB名) B05C 9/12 B01J 19/12 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-3-169338 (JP, A) JP-A-52-8686 (JP, A) JP-A-59-36569 (JP, A) 167714 (JP, A) JP-A-6-135120 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) B05C 9/12 B01J 19/12

Claims (1)

(57)【特許請求の範囲】 【請求項1】 紫外線発生手段、及び紫外線発生手段
で発生した紫外線をウェブ上に設けた紫外線硬化型塗工
層に連続的に照射させるためのウェブ搬送手段を有す
紫外線照射装置を用いて、主波長356nmの紫外線を
該紫外線硬化型塗工層に照射して約80%重合させ
後、主波長365nmの紫外線を照射して該紫外線硬化
型塗工層の硬化を完結させることを特徴とする紫外線硬
化方法。
(57) [Claims] 1. means for generating ultraviolet light, andTheUV generation means
UV curable coating with UV generated on the web
Web transport means to continuously irradiate the layerHaveTo
Using an ultraviolet irradiation device,UV light with a main wavelength of 356nm
For the UV-curable coating layerIrradiateAbout80%polymerizationLetWas
rear,Dominant wavelength of 365 nmIrradiation with ultraviolet light to cure the ultraviolet light
UV curing, which completes the curing of the mold coating layer
Method.
JP07367894A 1994-04-13 1994-04-13 UV irradiation device Expired - Lifetime JP3448949B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP07367894A JP3448949B2 (en) 1994-04-13 1994-04-13 UV irradiation device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP07367894A JP3448949B2 (en) 1994-04-13 1994-04-13 UV irradiation device

Publications (2)

Publication Number Publication Date
JPH07275775A JPH07275775A (en) 1995-10-24
JP3448949B2 true JP3448949B2 (en) 2003-09-22

Family

ID=13525130

Family Applications (1)

Application Number Title Priority Date Filing Date
JP07367894A Expired - Lifetime JP3448949B2 (en) 1994-04-13 1994-04-13 UV irradiation device

Country Status (1)

Country Link
JP (1) JP3448949B2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4675882B2 (en) 2004-02-04 2011-04-27 日東電工株式会社 Illumination device, light irradiation device using the same, and method for producing photoreaction product sheet using the device
JP5110779B2 (en) * 2005-07-21 2012-12-26 日東電工株式会社 Method and apparatus for producing photoreaction product sheets
JP6042704B2 (en) * 2012-11-16 2016-12-14 大倉工業株式会社 Curing method of active energy ray-curable substance and active energy ray irradiation device
KR102375170B1 (en) * 2018-09-20 2022-03-16 산진 옵토일렉트로닉스 (쑤저우) 컴퍼니 리미티드 Method for producing film

Also Published As

Publication number Publication date
JPH07275775A (en) 1995-10-24

Similar Documents

Publication Publication Date Title
JP3995267B2 (en) Coating preparation method
US5658630A (en) Multilayer foamed pressure sensitive adhesive agent and method for production thereof
KR101078535B1 (en) Multi-Stage Irradiation Process for Producing of Acrylic Based Adhesive
JP2002517569A (en) Free radical polymerization method
US20040219457A1 (en) Optical recording materials
JP3448949B2 (en) UV irradiation device
WO2004078460A1 (en) Method for adhering plastic
JP3493731B2 (en) Double-sided pressure-sensitive adhesive tape and method for producing the same
JP2988549B2 (en) Manufacturing method of double-sided adhesive tape
WO1994014912A1 (en) Multilayer foamed pressure sensitive adhesive agent and method for production thereof
US4295948A (en) Photocurable adhesive from acrylic acid, acrylamide, dimethylaminoethyl methacrylate, benzophenone and methyl ethyl ketone
KR20080044270A (en) Adhesive composition and articles made therefrom
JPH03294376A (en) Printing roll and tacky sheet for printing roll
JPS5956471A (en) Preparation of double-faced adhesive tape
JPH0625625A (en) Production of double-sided tape
JP3634875B2 (en) UV curable adhesive composition
JP3227162B2 (en) Method and apparatus for curing ultraviolet-curable material
JPH07330815A (en) Method for photopolymerization and apparatus for photopolymerization used for the same reaction
JPH08157781A (en) Preparation of pressure-sensitive adhesive material
JPH0411610A (en) Photopolymerizable composition
JPH07278502A (en) Ultraviolet-curing type tacky agent composition and double-sided tacky tape
JPH0489879A (en) Pressure-sensitive adhesive tape, production of plastic lens using the same, double-coated pressure-sensitive adhesive tape, and its use
JPH0934130A (en) Removing method for resist and adhesive sheet used therefor
KR20110073088A (en) Resin composition for optical film, optical film using the same and method for preparing thereof
JP2016007597A (en) Method and device of manufacturing photo-reaction product sheet

Legal Events

Date Code Title Description
R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080711

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080711

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090711

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090711

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100711

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110711

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110711

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120711

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120711

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130711

Year of fee payment: 10

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term