JP3412111B2 - Laundry soil treatment composition and treatment method - Google Patents

Description

The present invention relates to a soil treatment composition for laundry. The laundry can be treated by applying the composition to the soiled area before or after the normal washing process in order to at least partially remove the soil and facilitate the removal of the soil. .

It is known that solvent-water emulsions are effective as a soil pretreatment composition for both hydrophobic and hydrophilic soils.

British patent application No. A-2, published March 9, 1988
194 547 discloses mixtures of n-dodecane with short chain nonionic surfactants (Neodol 91-6) and long chain nonionic surfactants (Neodol 45-1). These compositions are in the form of liquid solutions in the form of water-in-oil or oil-in-water microemulsions, or gels. However, this application does not disclose a composition comprising a bleach activator material.

The present invention relates to a cleaning composition which is an oil-in-water or water-in-oil emulsion or solution comprising a non-aqueous hydrophobic solvent and an anionic or nonionic surfactant.

It is an object of the present invention to improve the removal of bleachable stains by applying a composition of the present invention and by applying a bleaching compound, preferably a peroxide compound.

SUMMARY OF THE INVENTION The object of the present invention is achieved by providing a cleaning composition which further comprises a bleach activator in order to enhance the cleaning performance against bleachable soils. The bleach activator is preferably at a level of 0.1 to 10% by weight of the cleaning composition. Water is preferably at a level of 5-95% by weight of the composition.

The invention also relates to a method of treating stains and stains on textile fabrics using the cleaning composition of the invention.

Detailed Description of the Invention Hydrophobic solvents are an essential feature of the compositions of the present invention. The preferred hydrophobic solvent depends on Hansen's parameters. The hydrophobic solvent defined in the present invention means that the hydrogen-bonding force parameter dH of Hansen is 18 (joule / c
m ³ ) It is considered to be a solvent of less than ^0.5 . A preferred hydrophobic solvent has a Hansen hydrogen bonding parameter dH of 12
(Joule / cm ³ ) less than ^0.5 and the Hansen polarity parameter dP is less than 8 (Joule / cm ³ ) ^0.5 .

The preferred solvent to be used has a flash point of 70 ° C. or higher, an initial boiling point of 130 ° C. or higher, preferably 145 ° C. or higher, and a freezing point of hydrocarbon of 20 ° C. or lower, and an aliphatic fatty acid ester. A mixture is included. More preferable solvents are alkanes or alkenes having a chain length of more than C7, particularly alkanes or alkenes having an average of 8 to 20 carbon atoms. Particularly preferred hydrophobic solvents are deodorized kerosene, solvent naphtha, chlorinated hydrocarbons, and terpenes.
Even more preferred are paraffin, isoparaffin,
Naphthenes, aromatic hydrocarbons, olefins, 1,1,1-trichloroethaneperchloroethylene, methylene chloride, Shelsol SS mixture (C8-C11 isoparaffin + aliphatic C7 ester 5%), D-limonene, and grid sol The product name supplied by is Grid Safe.
The solvent is used in the detergent composition of the present invention in an amount of 3 to 90% by weight, more preferably 4 to 45% by weight, and most preferably 5% by weight of the detergent composition.
Used at a level of ~ 25% by weight.

Hansen parameter dH is 18 (joules / cm ³ ) ^0.5
Other solvents below include glycol ethers, more preferably glycol ethers based on ethylene oxide, propylene oxide, or mixtures thereof. Particularly preferred are ethylene glycol monoethyl ether, propylene glycol monomethyl ether, 2-butoxy ethanol, butyl diethylene glycol ether ethanol, butoxy triglycol, butylene glycol, hexylene glycol, and propyl propanol. Such a solvent can be used in combination with a short-chain surfactant, a long-chain surfactant, or a mixture thereof, and is preferably used in combination.

In the present invention, "short chain" means a hydrophobic portion.
By a surfactant is meant a C ₆ -C ₁₁ alkyl chain. Therefore, although such a short chain surfactant is conventionally used in this field, it may have a short alkyl chain and may be of any type. Accordingly, suitable short chain surfactants for use in the present invention include C _{6 to} C ₁₁ alkyl sulfates (C _{6 to} C ₁₁ SO 4
₄ ), alkyl ether sulfate (C _{6 to} C ₁₁ (OCH ₂ CH
₂ ) eSO ₄ ), alkyl sulfonate (C _{6 to} C ₁₁ SO ₃ ), alkyl succinate (C _{6 to} C ₁₁ OOCH ₂ CH ₂ COOZ), alkyl carboxylate (C _{6 to} C ₁₁ COOM), alkyl ether carboxy Rate (C _{6 to} C ₁₁ (OCH ₂ CH ₂ ) eCOOM), alkyl sarcosinate (C _{6 to} C ₁₁ CON (CH ₃ ) R), alkyl sulfosuccinate (C _{6 to} C ₁₁ OOCCH (SO ₃ M ) CH ₂ COO
Z), amine oxide (C _{6 to} C ₁₁ RR'NO), glucose amide (C _{6 to} C ₁₁ CONR "X), alkylpyrrolidone (C _{6 to} C ₁₁₎
(C ₄ H ₆ ON), alkyl polysaccharide (C _{6 to} C ₁₁ OGg), alkyl alkoxylate (C _{6 to} C ₁₁ (OCH ₂ CH ₂ ) e (OCH ₂ CH ₂ C
H ₂ ) pOH), and betaine (C _{6 to} C ₁₁ N + (CH ₃ ) ₂ CH ₂ COO
-) Is included. In the formula in parentheses, e and p are independently 0 to
20, e + p> 0, Z is M, or R, M is H, or any such as known in the art including Na, K, Li, NH ₄ , amines. Is a counterion, X is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least three hydroxyls attached directly to the chain, or an alkoxylated derivative thereof, and R, R ′ and R ″ are C ₁ To C ₅ alkyl groups, optionally functionalized with hydroxyl groups, R and R ′ are preferably C _{1 to} C ₃ , most preferably methyl, R ″ is preferably 2-hydroxy. Ethyl or 2-hydroxypropyl, G is a saccharide, preferably glucose, g
Is 1.5-8. All of these surfactants are well known in the art. A more complete disclosure of conventional glucose amides can be found, for example, in International Patent Application No. 92-06154, and a more complete disclosure of conventional alkyl polysaccharides is
For example, it can be found in US Pat. No. 4,536,319. The composition according to the invention may comprise any one of the above-mentioned surfactants, or any combination thereof.

Preferred short chain nonionic surfactants for use in the present invention are alkyl alkoxylates of the formula _{C 6 ~C 11 (OCH 2 CH} 2) e (OCH 2 CH 2 CH 2) pOH. In the formula, e and p, which respectively represent the degree of ethoxylation and the degree of propoxylation, are independently 0.
˜20 and e + p> 0. The most preferred short chain nonionic surfactants for use in the present invention are those in which e and p are e + p = 3 to 10, particularly p is 0 and e is 3 to 8. The most preferred short-chain nonionic surfactant for use in the present invention has a short chain of 7 carbon atoms.
~ 11 hydrocarbons. The short chain nonionic surfactants preferred for use in the present invention can be prepared by methods well known to those skilled in the art, such as condensation of the corresponding alcohol and alkylene oxide,
Such a short chain surfactant is more conveniently
For example, from Sibidble, under the product name Margin Tar RC ₄ (C8EO4), from Korbu to Inventon AG / 810/050 and AG / 8
10/080 under the trade name (respectively C8～10EO5, and C8~10EO8), Dobanol shell 91-2.5 (C ₉ ~C ₁₁ EO2.
5), Dobanol 91-6 (C _{9 to} C ₁₁ EO6), Dobanol 91
It is marketed under the trade name -4-6, under the trade name Vista Chemicals under the name Vista 1012-52, and under the trade name Exxon under the name Asopol 91-4.6.

Another preferred class of short chain nonionic surfactants are secondary alcohol ethoxylates of the formula:

In the formula, (X + Y) is 2 to 10, and n indicating the number of ethoxylate groups is 1 to 7. Examples of commercially available surfactants of this type include Union Carbide's Tajtor S series.

Preferred short chain anionic surfactants for use in the present invention, C ₆ -C ₁₁ alkyl sulfates, C ₆ -C ₁₁ alkyl sulfonates, C ₆ -C ₁₁ betaines, C ₆ -C ₁₁ amine oxides, and mixtures thereof Is. Most preferred is C ₆
~C is ₈ alkyl sulfates and sulfonates. Such short-chain anionic surfactants can be prepared by well-known methods such as sulfation or sulfonation and then neutralization, but the short-chain anionic surfactants are more convenient. Fortunately, it is marketed, for example, by Rhone Poulin under the trade name Rhodapon OLS or by Witco under the trade name Witconate.

Various non-limiting examples of bleach activators suitable for use in the compositions of the present invention are described in US Pat. No. 4,915,854 issued April 10, 1990 to Mao et al., And US Pat. , 41
It is disclosed in each specification of 2,934. Nonanoyloxybenzene sulfonate (NOBS) and tetraacetylethylenediamine (TAED) activators are common, and mixtures thereof can also be used. See also US Pat. No. 4,634,551 for other common bleaching agents and activators useful in the present invention.

Highly preferred amide derived bleach activators are those having the formula:

R ¹ N (R ⁵ ) C (O) R ² C (O) L or R ¹ C (O) N (R ⁵ ) R ² C (O) L In the formula, R ¹ has about 6 to about 6 carbon atoms. An alkyl group of about 12, R ² is an alkylene having 1 to about 6 carbons, R ⁵ is H, or an alkyl of about 1 to about 10 carbons,
Aryl or alkaryl and L is any suitable leaving group. A leaving group is any group that leaves a bleach activator as a result of its nucleophilic attack by a hydrogen peroxide decomposing anion. A preferred leaving group is phenyl sulfonate.

Examples of preferred bleach activators of the above formula include, for example, those described in U.S. Pat.
(6-Octanamido-caproyl) oxybenzene sulfonate, (6-nonanamidocaproyl) oxybenzene sulfonate, (6-decanamidocaproyl)
Included are oxybenzene sulfonates, and mixtures thereof. This patent specification is hereby incorporated by reference.

Other types of bleach activators include U.S. Pat.
Included are the acylated citrate esters described in No. 2. Preferred acylated citrates are of the formula:

Wherein R ′, R ″ and R are independently selected from the group consisting of H, C _1-18 alkyl, C _1-18 alkenyl, substituted phenyl, unsubstituted phenyl, alkylphenyl, and alkenylphenyl. And R is C ₁ -C ₉ alkyl, C ₁
-C ₉ alkenyl are those selected substituted phenyl, unsubstituted phenyl, alkylphenyl, and from the group consisting of alkenyl phenyl. Mixtures of acylated citric acid esters are also included in the present invention.

For the effectiveness and stability of the peracid precursor used in the present invention, all of R ', R "and R are H in a given molecule.
It is best not to be. R is C ₁
˜C ₉ alkyl, and R ′, R ″ and R are H, C ₁ ˜
It is selected from the group consisting of C ₄ alkyl and C ₁ -C ₄ alkenyl, but it is preferred that not all R ′, R ″ and R are H. R ′, R ″ and R are Most preferably, it is methyl or ethyl.

The acylated citric acid ester according to the invention reacts with hydrogen peroxide during the bleaching operation to produce peracid and citric acid ester. The peracid generated depends on the R selected. Preferred as substituted phenyl is sulfophenyl. R is preferably a C ₁ -C ₉ alkyl.

Although not preferred, only partially esterified acylated citrates, ie R ′, R ″, or R
, Or a combination thereof is H, and all three of R ′, R ″, and R in a given molecule are not H. R ′, R ″, and A "central" diester is preferred if only one of R is H, ie if the acylated citrate is a diester. That is, it is preferred that R "is not H. If two of R ', R", and R are H, that is, the acylated citrate is a monoester, a symmetrical monoester, That is, the central monoester is preferable. That is, it is preferred that R "is not H. When using a monoester, it is preferred that the ester chain be fairly long, i.e., up to 18 carbon atoms.

Preferred as the acylated citric acid ester is acetyl triethyl citrate, trimethyl octanoyl citrate, trimethyl acetyl citrate, triethyl nonanoyl citrate, triethyl hexanoyl citrate, triethyl octanoyl citrate, trimethyl nonanoyl citrate, hexanoyl citrate. It is selected from the group consisting of trimethyl and mixtures thereof. Another class of bleach activators includes the benzoxazine type activators disclosed by Hodge et al. In US Pat. No. 4,966,723 issued Oct. 30, 1990. This patent specification is hereby incorporated by reference.
Highly preferred as a benzoxazine type activator is Is.

Yet another class of preferred bleach activators includes acyl lactam activators, especially acyl caprolactams of the formula:
And acyl valerolactam.

In the formula, R ⁶ is H or an alkyl group having 1 to about 12 carbon atoms, an aryl group, an alkoxyaryl group, or an alkaryl group. Highly preferred lactam activators include benzoylcaprolactam, octanoylcaprolactam, 3,5,5-trimethylhexanoylcaprolactam, nonanoylcaprolactam, decanoylcaprolactam, undecenoylcaprolactam, benzoylvalerolactam, octanoylvalerolactam, Included are decanoyl valerolactam, undecenoyl valerolactam, nonanoyl valerolactam, 3,5,5-trimethylhexanoyl valerolactam, and mixtures thereof. 19
See also US Pat. No. 4,545,784 issued to Sanderson on October 8, 1985. This patent specification is hereby incorporated by reference. This patent specification discloses acylcaprolactam, including benzoylcaprolactam, adsorbed on sodium perborate.

Any alkaline material is suitable for use in the present invention. Preferred as the alkaline substance are potassium hydroxide, sodium hydroxide, ammonium hydroxide, ammonium silicate, sodium bicarbonate, borax, monoethanolamine borate, monoethanolamine, triethanolamine, and mixtures thereof. What is chosen. Usually, the soil treatment composition comprises 0.1 to 10% by weight of alkaline material, preferably 0.5 to 3% by weight. The pH is preferably higher than 8, more preferably higher than 9, and most preferably higher than 10. The pH of the undiluted composition is measured by Nick's portable pH meter (Portames 752)
It was measured at.

In the present invention, the "long chain" means that the carbon number is 12, or
By a surfactant having more than 12 alkyl chains is meant.

Non-limiting examples of long chain surfactants useful in the present invention include conventional C _{12 to} C ₁₈ alkylbenzene sulfonates (“LAS”), first branched random C _{12 to} C ₂₀ alkyl sulphates ( "AS"), the formula _{CH 3 (CH 2) X (} CHOSO 3 - M +) C
H _3, and _{CH 3 (CH 2) y (} CHOSO 3 - M +) CH 2 CH 3 ( wherein, x
And (y + 1) is an integer of at least about 7, preferably at least about 9, and M is a water-solubilizing cation, especially sodium, C ₁₂ -C ₁₈ secondary (2,3) alkyl sulphate, oleyl sulphate. Unsaturated sulphates such as, C ₁₂ -C ₁₈ alkylalkoxy sulphates (“AE _X S”, especially EO 1-7 ethoxy sulphate), C ₁₂
~ C ₁₈ alkylalkoxycarboxylates (especially EO1 ~
5 ethoxycarboxylates), C ₁₂ ~C ₁₈ glycerol ethers, C ₁₂ -C ₁₈ alkyl polyglycosides and sulfated polyglycosides and their corresponding, C ₁₂ -C ₁₈ alpha - sulfonated fatty acid esters methyl ester sulfonate (MES), And oleyl sarcosinate. Conventional nonionic and amphoteric surfactants such as C ₁₂ -C ₁₈ alkyl ethoxylates (“AE”), particularly preferably
C ₁₂ -C ₁₆ fatty alcohol polyglycol ethers, or primary alcohol ethoxylated EO2～7 (especially ethoxylates, and ethoxylated / propoxylated mixture), C ₁₂
-C ₁₈ betaines, C ₁₂ -C ₁₈ sulfobetaine ( "sultaines"), C ₁₂ -C ₁₈ amine oxides, etc. may also be included in the overall compositions. C ₁₂ -C ₁₈ N-alkyl polyhydroxy fatty acid amides can also be used. Examples of typical, include C ₁₂ -C ₁₈ N-methyl glucamides.
See International Patent No. 9,206,154. Surfactants derived from other sugars, C ₁₂ ~C ₁₈ N- (3- methoxypropyl) glucamide such as, N- alkoxy polyhydroxy fatty acid amides are included. N- hexyl C ₁₂ -C ₁₈ glucamides from N- propyl can be used for low sudsing. Typical soap C ₁₂ -C ₂₀ can also be used. If high sudsing is desired, it may be used branched C ₁₂ -C ₁₆ soaps. Mixtures of anionic and nonionic surfactants are particularly useful. Other commonly useful surfactants are described in standard textbooks.

Particularly preferred in the composition according to the invention is one which comprises from 5 to 50% by weight of a mixed nonionic surfactant system consisting of a short-chain first nonionic surfactant and a long-chain second nonionic surfactant. . More preferably, the composition comprises 10-40% by weight of this mixed nonionic surfactant, most preferably 15-30% by weight. The total HLB value of the nonionic surfactant system is preferably 2-16, more preferably 8
-14, most preferably 9-10. Further, the ratio of the first surfactant and the second surfactant is preferably 1:10 to 10: 1.
And more preferably 1: 3 to 3: 1 and most preferably about 1: 1.

The detergent composition of the present invention can be used in various known conventional cleaning methods. However, a preferred cleaning method is the step of applying the detergent composition to stains and stains, the step of placing the absorbent layer adjacent to the stains and stains of the textile fabric, and applying heat to the stains and stains of the textile fabric. The step of applying pressure, or heat and pressure, to absorb some or all of stains and stains into the absorbent layer. An even more preferable washing method comprises the following steps (a) and (b).

(A) To apply the detergent composition to stains and stains and transfer the absorbent layer adjacent to the stains and stains of the textile fabric, and transfer some or all of the stains and stains to the absorbent layer. The step of applying the first means of (1), and optionally applying a peroxide bleaching agent, and then (b) applying a hydrophilic solvent or water to the stains and stains of the textile fabric to stain the textile fabric. The process of placing an absorbent layer adjacent to the stain or stain and applying heat to the stain or stain on the fabric. Heat or pressure, or both, can be applied by any means, but most preferably with a hand-held tool such as an iron. A conventional iron with a hotplate fixed to the body is highly preferred as a handheld tool. The hot plate is most commonly heated by electrical means and may have means for controlling the temperature. Water or steam may be supplied with an iron. Place the absorbent layer on a flat surface such as an ironing board, and put a woven cloth with stains or stains on the absorbent layer,
Most preferably, it is laid flat in contact with the absorbent layer.
By doing so, the iron can be easily applied to the stains and stains of the textile fabric and the stains and stains can be transferred completely or substantially completely to the absorbent layer. Ironing is preferably 40-200 ℃, more preferably 40-1
Perform at a temperature of 80 ° C.

Another tool for applying heat or pressure is a heat roller, or any other heat applicator. The roller or applicator may be equipped with a detergent composition supply means.

Suitable applicators include European Patent Application No. A
Included are steam irons with suction brushes as disclosed in 0-493348 and thermoelectric applicators as disclosed in European patent application A-0 552 397. Steam irons with atomizers, such as those disclosed in European patent application A-0 629 736, are also suitable. According to this specification, the detergent composition may be stored in an iron and delivered directly to the textile fabric by means of a sprayer.

Without wishing to be bound by theory, it is believed that hydrophobic stains first become hydrophilic by applying the detergent composition while gently rubbing in some cases. Fatty soils containing hydroxyl groups are deprotonated at high pH, which makes them more easily solubilized in detergent solutions. High
The pH also causes sol peptization of certain food stains. Dirt is effectively destroyed and is easier to remove.
The advantages of high pH can be especially seen when the stain composition is applied with another composition containing the bleaching species prior to or after application of the detergent composition. In fact, conventional peroxide bleaching techniques increase reactivity with pH. Then reapply water to the stain, optionally rubbing lightly. The soil is removed by placing the soiled woven fabric adjacent to the absorbent layer. The stain made hydrophilic by this treatment moves to the absorbent layer.

A woven fabric is anything made from cloth, including clothing such as shirts, blouses, socks, skirts, pants, jackets, underwear, and tablecloths, towels, curtains and the like. The definition of a textile fabric as used in the present invention does not include carpet or similar floor coverings.

The knitted or woven fabric used in the present invention is usually made by weaving or knitting. Synthetic fibers (eg polyester, polyamide etc.) and natural fibers from plants (eg cotton, hemp) or natural fibers from animals (eg wool) are used to make woven, knitted or other types of textiles. , Angola, silk) and many other fibers can be used. A mixture of various fibers
Commonly used.

Examples In the following examples, all compositions are by weight (unless otherwise noted)
It is represented by.

In the examples, the trade name SHERZOLE is a mixture of C8 to C11 isoparaffins containing 5% aliphatic C7 esters.

The product name Dobanol is sold by Shell,
It is an ethoxylated primary alcohol having an average degree of ethoxylation of 3.

The product name Lutensol AE21 has an average degree of ethoxylation of 21.
Is a C13-C15 ethoxylated alcohol.

The trade name Dehidol is a fatty alcohol polyglycol ether octyl with an average degree of ethoxylation of 4 sold by Henkel.

The alkyl sulfate, C6AS, has an average of 6 carbon atoms in the alkyl chain.

DTPMP is diethylenetriaminepentamethylenephosphoric acid.

Examples Examples Examples Examples 1 2 3 4 Sherzol 20-20 20 D-limonene-24 --- Sodium paraffin sulfonate 0.2 0.4 0.2 0.2 Dovanol 23-3 0.1 0.4 0.2 0.2 Dovanol 25-3 5 10 5 5 Lutensol AE21 0.3 0.6 0.3 0.3 Dehydrol C8EO4 5 10 5 − C6AS − − − 5 Sodium hydroxide 3.1 6.2 − 3.1 Monoethanolamine − − 3 − Sodium carbonate 0.7 1.4 − − Sodium bisulfite − − 1 − Citric acid 3 6 − 3 DTPMP 0.75 1.5 − 0.75 Acetyl triethyl citrate 2 4 2 2 Water Remainder Remainder Remainder Remainder In Example 4, C6-AS was converted to C8-LAS and C8-ethylhexyl A.
S, C8-octyl sulfonate, C8 dimethylamine oxide, C71EO6.5, and sodium cumene sulfonate were sequentially replaced.

  The final pH of the compositions of the examples were all 10.

A set of polycotton cloth (50 mm square) was stained with makeup cosmetics, chocolate sauce, and tomato sauce. Remove this stain in the dark at normal room temperature (about 20 ° C, 60%
RH) let me sleep for a day. Clean each dirty cloth with
It was washed by the following method.

1. The soiled area was placed directly on absorbent paper (the paper used was the absorbent core of the diaper).

2. 1 ml of the composition of Example 1 was applied to the soiled area.

3. The stained part was brushed with an ordinary electric toothbrush for 10 seconds (the toothbrush used, trade name Brown Dental d3, was for normal use in daily tooth care).

4. 1 ml of the peroxide composition of Example 5 was applied to the soiled portion, and the soiled portion was brushed again with a toothbrush.

Pressure and heat were applied for 10 seconds using an iron set at a temperature of 5.140 ° C. Commonly used to smooth out wrinkles on fabric,
Typical ironing pressure was used.

6. 1 ml of distilled water was poured on the soiled area.

7. After repeating step 5, 2 ml of distilled water was further added.

8. The cloth was dried and stretched.

Substituting the compositions of Examples 2-4 for the composition of Example 1,
This cleaning procedure was repeated on the soiled cloth.

Example 5-Peroxide composition C10 Alkylsulfate 1.2 Dovanol 23-3 1.1 Dovanol 91-10 1.6 Polyvinylpyrrolidone 0.2 Hydrogen peroxide 6.8 Isophor 12 0.5 DTPMP 0.2 Sulfuric acid pH 4 Water balance Isophor 12 It is 2-butyloctanol of Condea.

─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. ⁷ Identification code FI D06L 3/02 D06L 3/02 (56) References JP-A-63-68700 (JP, A) JP-A-5-311198 (JP , A) JP-A-4-57962 (JP, A)

Claims (15)

(57) [Claims] 1. A cleaning composition which is an oil-in-water or water-in-oil emulsion or solution comprising the following (i) and (ii), further comprising (iii) a bleach activator: A cleaning composition comprising: (I) a non-aqueous hydrophobic solvent, (ii) a first anionic or nonionic surfactant. 2. A bleach activator comprising 0.1 to 10% by weight,
The cleaning composition according to claim 1. 3. The bleach activator is an amide-derived bleach activator,
Acylated citrate bleach activator, benzoxazine type bleach activator, acyllactam bleach activator,
The cleaning composition according to claim 2, which is selected from the group consisting of: and a mixture thereof. 4. The cleaning composition according to claim 1, further comprising 5 to 95% by weight of water. 5. The Hansen hydrogen bonding parameter dH is 18
^3. Containing 3 to 90% by weight of a non-aqueous hydrophobic solvent having a (Joule / cm ³ ) of less than ^0.5 and a Hansen polar parameter dP of less than 8 (Joule / cm ³ ) ^0.5.
The cleaning composition according to. 6. The cleaning composition according to claim 5, wherein the solvent comprises a hydrocarbon having a flash point of 70 ° C. or higher, an initial boiling point of higher than 145 ° C., and a freezing point of lower than 20 ° C. . 7. The cleaning composition according to claim 6, wherein the solvent is selected from the group consisting of C _{10 to} C ₁₈ linear or branched alkanes, terpenes, and mixtures thereof. 8. The first surfactant further comprises a second surfactant having an alkyl chain having a length of C11 or less, and (iv) a second surfactant having an alkyl chain having a length of C12 or longer. The cleaning composition according to claim 1, wherein the cleaning composition comprises: 9. The second surfactant is a C _{12 to} C ₁₆ fatty alcohol polyglycol ether and has a degree of ethoxylation of 2.
9. A cleaning composition according to claim 8 which is selected from the group consisting of ethoxylated primary alcohols of ~ 7. 10. A mixed nonionic surfactant system comprising a first surfactant and a second surfactant and having a total HLB value of 2 to 16 and 5 to 50% by weight. The cleaning composition according to. 11. The cleaning composition according to claim 8, wherein the molar ratio of the first surfactant to the second surfactant is 1:10 to 10: 1. 12. The first surfactant is of the formula C ₆ -C ₁₁ (OCH ₂ C
H ₂ ) e (OCH ₂ CH ₂ CH ₂ ) pOH (wherein e + p is 3 to 10) represented by C _{6 to} C ₁₁ alkylalkoxylate, C ₆
-C ₁₁ secondary alcohol ethoxylates, C ₆ -C ₁₁ alkyl sulfonates, C ₆ -C ₁₁ alkyl sulfates, C ₆ -C ₁₁
Betaine, C ₆ -C ₁₁ amine oxides, and are those selected from the group consisting of mixtures thereof, The cleaning composition of claim 1. 13. A method for treating stains and stains on a woven fabric, which comprises the following steps. A detergent composition according to any one of the preceding claims,
The process of applying stains or stains, the step of placing the absorbent layer adjacent to the stains or stains on the textile fabric, and applying heat, pressure, or heat and pressure to the stains or stains on the textile fabric The process of absorbing some or all of the stains in the absorbent layer. 14. The method according to claim 13, comprising the following steps (a) and (b). (A) for applying a detergent composition to stains and stains, transferring the absorbent layer adjacent to the stains and stains of the textile fabric, and transferring some or all of the stains and stains to the absorbent layer The step of placing the first means, and then (b) applying a hydrophilic solvent or water to the stain or stain portion of the textile fabric, and adsorbing the absorbent layer adjacent to the stain or stain portion of the textile fabric, and Putting a second means to transfer some or all of the dirt and stains to the absorbent layer. 15. A method for transferring some or all of stains and stains to an absorbent layer is applied with a hand-held iron to apply heat to the stains and stains of the woven fabric. 15. The method of claim 14, comprising the step of applying.