JP3372735B2 - Manufacturing method of fried confectionery - Google Patents

Manufacturing method of fried confectionery

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Publication number
JP3372735B2
JP3372735B2 JP32329195A JP32329195A JP3372735B2 JP 3372735 B2 JP3372735 B2 JP 3372735B2 JP 32329195 A JP32329195 A JP 32329195A JP 32329195 A JP32329195 A JP 32329195A JP 3372735 B2 JP3372735 B2 JP 3372735B2
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JP
Japan
Prior art keywords
oil
fatty acid
texture
fried
dough
Prior art date
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JP32329195A
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Japanese (ja)
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JPH09154494A (en
Inventor
真 小池
敬子 有村
秀季 横道
優司 岡内
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Kao Corp
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Kao Corp
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Description

【発明の詳細な説明】 【0001】 【発明の属する技術分野】本発明は、油で揚げて膨化す
る菓子類の製造方法であって、特に食感の優れた膨化食
を製造する技術に関する。 【0002】 【従来の技術及び発明が解決しようとする課題】従来、
膨化を行う菓子類としては、短時間で澱粉から水分を低
減させかつ体積を膨張させ軽い食感を得るため、油で揚
げる、焼成する、エクストルーダー等の機器で加圧・混
練・成形を行い、生地を急激な温度・圧力の変化により
達成してきた。また、生地中の澱粉/小麦粉の原料種
や、組成比を変化させたり、その生地に乳化剤や糖を添
加することにより(特公昭53−39502 号、特公平7−28
641号) 、小麦粉や澱粉の物性を改良し、食感や保存性
を改良する方法が行われてきた。 【0003】特に、油を用いて膨化を行う揚げ菓子類の
製造においては、生地組成物の変更や、油ちょうの前の
乾燥工程と水分量の最適化、また揚げ温度などの変化に
より、比容積を増加(ウキを良くし)食感を改善するこ
とと、油の原料の由来による風味の変化/着香などが行
われてきた(食品の製造工程、食品技術士センター編、
p.350 、三▲秀▼書房)。 【0004】特に、油ちょう前の生地中の水分が多い
と、油ちょう時の熱エネルギーが生地の水分蒸散に使わ
れ、品温の上昇が遅くなり製品の容積が増加しにくいこ
とが、経験的にも公知であり、油ちょうや焼成前に、予
め生地を乾燥して水分を調整することで、膨化をコント
ロールしてきた(製菓辞典 p.395、p.425 朝倉書店)。
しかし、そのようなコントロールを行っても、食感を向
上させることは難しい。 【0005】 【課題を解決するための手段】本発明者は、乳化剤を生
地に添加するのでなく、油に添加して揚げることによ
り、従来とは異なる食感や外観を提供する方法を検討
し、油ちょう用油脂に特定の乳化剤を添加することによ
り食感および外観を改良できること、更にグリセリン脂
肪酸ジエステル(ジグリセリド)を併用配合することに
より、上記乳化剤を油中に安定に分散または溶解させる
ことが可能で、製造時の作業性が向上することを見出
し、本発明を完成するに至った。 【0006】即ち本発明は、グリセリン脂肪酸ジエステ
ル(ジグリセリド)を5〜50重量%、ショ糖脂肪酸ジエ
ステルとショ糖脂肪酸トリエステルを0.05〜10重量%含
有する油脂組成物を用いて、揚げ菓子生地を油ちょうす
ることを特徴とするかりんとう、揚げ煎餅、揚げあら
れ、新生あられ及びポテトチップスより選ばれる揚げ菓
子類の製造方法である。 【0007】 【発明の実施の形態】以下、本発明について詳細に説明
する。 【0008】本発明において、その効果が発揮される食
品としては、その組成(生地)中に、澱粉を主成分とし
て含むものであって、具体的には、かりんとう、揚げ煎
餅、揚げあられ、新生あられ、ポテトチップスなど、揚
げ工程を経る菓子である。効果としては、その組織の構
造や、比容積を変化させ、食感・外観・風味を改善する
ことにある。 【0009】本発明では、乳化剤としてショ糖脂肪酸エ
ステルを油脂組成物に含有せしめることにより、表面の
構造や色付きを改善し、膨化時の体積や、従来より食感
が軽く、色付きを改善すること、特に、煎餅などに望ま
れるひび割れや、クリスピー感を向上できる。また、い
ままで、比容積を向上させる為に、油の使用できる限界
に近い温度(240 ℃付近)で揚げ工程を行っていたもの
を、油温を5〜10℃低下させても従来と同等の比容積・
外観・食感を保つことができ、油の熱劣化を抑え、揚げ
菓子の風味劣化を抑制できるなどのメリットもあること
がわかった。 【0010】この作用は、揚げ工程において、油中に乳
化剤を分散させることで、油と素材の生地との界面に素
早く乳化剤が配向し、その界面張力を低下、表面積を広
げ、熱伝導を向上させるとともに、水分蒸散を促進させ
表面の組織の改良や、ひいては、生地全体の比容積を増
加させるためと考えられる。これに対し、生地中に乳化
剤を配合しても、生地粘度が高く油ちょう時に同様の効
果を発現させるためには、添加量が過多となり異味を生
じてしまう。 【0011】本発明に用いる乳化剤は、油に溶解するも
のであって、かつ、できる限りHLBの高い乳化剤が好
ましい。より具体的には、ショ糖脂肪酸エステルとして
は、ショ糖脂肪酸ジエステルまたはショ糖脂肪酸トリエ
ステルが好ましく、これらのショ糖脂肪酸エステルを含
むものであれば使用できる。その脂肪酸の組成として
は、C2〜C22 の脂肪酸のいずれでも使用できる。また長
鎖飽和脂肪酸の含量が40重量%以下で、不飽和脂肪酸と
中鎖、短鎖の脂肪酸で構成されれば、使用時の温度が、
少なくとも80℃以上であり、添加量が多くとも10重量%
以下であることから溶解性の問題はない。更に、油の室
温での保存時に乳化剤成分が、析出、沈澱を起こさない
ためには、不飽和脂肪酸の含量が30重量%以上、より好
ましくは50重量%以上であることが好ましい。 【0012】ショ糖脂肪酸エステルの油への添加量は、
効果を発現するために、ショ糖脂肪酸ジエステル及び/
またはトリエステルの総量が、0.05重量%以上、好まし
くは0.1 重量%以上の添加が必要であり、また調理時の
発煙や、異味の発生から10重量%以下が好ましい。 【0013】また、これら乳化剤を、油中に安定に分散
または、溶解させるためにグリセリン脂肪酸ジエステル
(ジグリセリド)を油中に添加することが必要である
特に、ジグリセリドの添加量が増えると乳化剤の溶解度
も上昇し、安定分散しやすくなるが、乳化剤の効果を発
揮するための必要量も増加するため、5〜50重量%、好
ましくは、5〜20重量%添加が良い。 【0014】また油の劣化を抑制するために、トコフェ
ロール(ビタミンE)や、アスコルビン酸の脂肪酸誘導
体(例えばパルミチン酸エステル、ステアリン酸エステ
ル)や、天然抗酸化成分(植物抽出成分としての茶、ロ
ーズマリーなどのハーブ、桃の葉や根塊からの抽出も
の)を添加しても良い。 【0015】油としては、植物性、動物性油脂など起源
を問わない。具体的には、菜種油、ひまわり油、とうも
ろこし油、大豆油、米油、紅花油、パーム油、ヤシ油、
牛脂、等を挙げることができる。またこれらの油脂を分
別したもの、水素添加や、エステル交換反応などにより
融点を調整したものも利用できる。 【0016】 【実施例】以下に実施例を挙げて本発明を説明するが、
本発明はこれらに限定されるものではない。又、実施例
中の%、部は重量基準である。 【0017】まず、乳化剤の調製方法について説明す
る。 〔ショ糖脂肪酸エステルの調製〕 市販のショ糖脂肪酸エステル(商品名:O−170 、三菱
化成食品(株)製)をクロロホルム−メタノールを展開
溶媒としたシリカゲルカラムにより分画し、以下のよう
な組成の乳化剤を得た。 【0018】 【表1】 【0019】〔ジグリセリドの調製〕 固定化リパーゼ(商品名:Lypozyme3A、ノボインダスト
リーA.S.(株)製)水分4%、 100gを触媒として、ナ
タネ脂肪酸 860gとグリセリン 140gを40℃、減圧下で
攪拌反応させ8時間後に、濾過、固定化酵素を除去し、
反応生成物を分子蒸留にかけ、以下の組成のジグリセリ
を得た。 【0020】 【表2】 【0021】以上のようにして得た乳化剤組成物を配合
した油脂組成物を用い、各種揚げ菓子類の調製・評価を
行った。尚、食感の評価は以下の基準で行った。 ・「カラッと感」における評価 A:油切れが良く、非常にカラッとしている。 【0022】B:油切れがやや良く、かなりカラッとし
ている。 【0023】C:油切れがやや悪く、あまりカラッとし
ない。 【0024】 D:油切れが悪く、カラッとしない。 ・「サクミ感」における評価 A:非常にサクサクとした、軽い食感。 【0025】B:かなりサクサクとしたやや軽い食感。 【0026】C:ややサクサクとした食感。 【0027】D:あまりサクサクとせずやや重い食感。 【0028】また、比容積測定の為の体積測定は、
(株)アステックス製 SELNACVM-150により測定した。
測定時の底面として、平面が得られない場合は、揚げ煎
餅を中央で切断し、2つに分けて測定を行った。 【0029】また、色相、表面の割れは、目視観察によ
り評価した。 実施例、比較例1 〔揚げ煎餅〕 うるち米より公知の方法にて生地を調製し、切断・成形
後、熱風乾燥(水分20%)−ねかせ(約14時間放置)−
第2乾燥(水分10%)にしたものを、 240℃の乳化剤
ジグリセリドを添加した菜種油(実施例)と菜種油
(比較例1)で、1分間揚げた後、その比容積、外観、
食感を比較した。結果を表3に示す。 【0030】 【表3】【0031】実施例のものは、食感が軽いだけでな
く、スダチ(生地内部の気質の大きさと揃い方)が良く
揃っていた。実施例、比較例2 〔かりんとう〕 小麦粉 400g、砂糖80g、ベーキングパウダー3g、塩
1g、水 120gを混練、耳たぶ程度の硬さにした後、ラ
ップで包み約5時間生地をねかせた。 【0032】生地をロールで圧延、4×4×50mmの大き
さに細断、成形後、30分間再度ねかせて、表4に示した
油で揚げた後、糖蜜(砂糖 160g、水60gを煮詰める)
をからめ、かりんとうを調製した。結果を表4に示す。 【0033】 【表4】 【0034】表4に示すように、本発明によれば、カラ
ッとしていて、油っぽくなくサクミがあり、軽い食感の
かりんとうを得ることができた。 実施例、比較例 〔ポテトチップス〕 ジャガイモ4ケを、水洗、水気を除去後、スライシング
し、厚さ 1.5mmに調製した。その後、再度水洗し、表面
の澱粉、溶出物を除去した後、水気をふき取った。表5
に示したように油ちょうし、評価を行った。結果を表5
に示す。 【0035】 【表5】【0036】表5に示すように、本発明によれば、サク
ミがあり、食感の軽いポテトチップスが調製できるこ
がわかった。
Description: BACKGROUND OF THE INVENTION [0001] 1. Field of the Invention
A method of manufacturing a confectionery that child class, relates to a technique for especially manufacturing excellent puffed food of texture. 2. Description of the Related Art
For confectionery that expands, pressurizing, kneading, and molding with equipment such as frying, baking, and extruder to reduce moisture from starch and expand the volume in a short time to obtain a light texture. The dough has been achieved through rapid temperature and pressure changes. Also, by changing the type of starch / wheat flour and the composition ratio of the dough, or by adding an emulsifier or sugar to the dough (JP-B-53-39502, JP-B-7-28).
No. 641), a method of improving the physical properties of flour and starch to improve the texture and the preservability has been carried out. [0003] Particularly, in the production of fried confectionery which is expanded using oil, the ratio of dough is changed by changing the dough composition, optimizing the drying step and water content before frying, and changing the frying temperature and the like. Increasing the volume (improving the uki), improving the texture, and changing the flavor / flavoring due to the origin of the oil ingredients have been carried out (food manufacturing process, edited by Food Technician Center,
p.350, Sankyu Shubo Shobo). [0004] In particular, if there is a large amount of water in the dough before frying, heat energy during frying is used to evaporate the moisture of the dough, and the rise in product temperature is slowed down, making it difficult for the product volume to increase. It has been well known in the art that the puffing has been controlled by drying the dough in advance and adjusting the water content before frying or baking (confectionery dictionary, p.395, p.425, Asakura Shoten).
However, even with such control, it is difficult to improve the texture. [0005] The present inventors have studied a method of providing a texture and appearance different from the conventional one by adding an emulsifier to oil and frying it instead of adding the emulsifier to dough. it can improve the texture and appearance by the addition of certain emulsifiers in oil for frying, further glycerin fat
In combination with fatty acid diester (diglyceride)
More stably disperse or dissolve the emulsifier in oil
It has been found that the workability during manufacturing can be improved , and the present invention has been completed. That is, the present invention provides a fried confectionery dough using an oil or fat composition containing 5 to 50% by weight of glycerin fatty acid diester (diglyceride) and 0.05 to 10% by weight of sucrose fatty acid diester and sucrose fatty acid triester. Karin tofu, fried rice cracker, fried ara
This is a method for producing fried confectionery selected from fresh hail and potato chips . Hereinafter, the present invention will be described in detail. [0008] In the present invention, foods that exert their effects are those containing starch as a main component in the composition (dough), and specifically, Karinto, fried rice crackers, fried tofu, It is a confectionery that goes through the fry process, such as hail and potato chips. The effect is to improve the texture, appearance and flavor by changing the structure and specific volume of the tissue. [0009] In the present invention, by incorporating sucrose fatty et <br/> stearyl Le as emulsifiers in the fat or oil composition, improved with structure and color of the surface, and volume during puffing, lighter texture than a conventional In addition, it is possible to improve the coloring and, in particular, to improve the cracking and crispy feeling desired for rice crackers and the like. In addition, in order to improve the specific volume, the frying process has been performed at a temperature close to the limit where oil can be used (around 240 ° C). Specific volume of
It has been found that there are merits such as the appearance and texture can be maintained, the thermal deterioration of oil can be suppressed, and the flavor deterioration of fried confectionery can be suppressed. This action is achieved by dispersing the emulsifier in the oil in the frying process, whereby the emulsifier is quickly oriented at the interface between the oil and the material dough, lowering the interfacial tension, increasing the surface area, and improving heat conduction. In addition, it is considered that water evaporation is promoted to improve the texture of the surface and eventually increase the specific volume of the whole dough. On the other hand, even if an emulsifier is blended in the dough, the dough has a high viscosity and the same effect is exhibited during frying, so that the amount of addition is excessive and an unpleasant taste is produced. The emulsifier used in the present invention is preferably one which dissolves in oil and has as high an HLB as possible. More specifically, the sucrose fatty acid ester is preferably a sucrose fatty acid diester or a sucrose fatty acid triester, and any sucrose fatty acid ester containing these sucrose fatty acid esters can be used. As the composition of the fatty acid, any of C 2 to C 22 fatty acids can be used. In addition, if the content of long-chain saturated fatty acids is 40% by weight or less and is composed of unsaturated fatty acids and medium- and short-chain fatty acids, the temperature during use will be
At least 80 ° C or higher, with the addition amount at most 10% by weight
There is no solubility problem from the following. Further, in order that the emulsifier component does not precipitate or precipitate when the oil is stored at room temperature, the content of the unsaturated fatty acid is preferably 30% by weight or more, more preferably 50% by weight or more. The amount of the sucrose fatty acid ester added to the oil is
In order to exhibit the effect, sucrose fatty acid diester and / or
Or the total amount of the triester, 0.05 wt% or more, preferably requires the addition of more than 0.1 wt%, and smoke or during cooking, have preferably 10% by weight or less from the occurrence of off-taste. In order to stably disperse or dissolve these emulsifiers in oil, it is necessary to add glycerin fatty acid diester (diglyceride) to the oil.
In particular, when the amount of diglyceride added increases, the solubility of the emulsifier also increases, and it is easy to stably disperse. However, since the necessary amount for exhibiting the effect of the emulsifier also increases, 5 to 50% by weight, preferably 5 to 20% by weight. Good weight% addition. In order to suppress the deterioration of oil, tocopherol (vitamin E), fatty acid derivatives of ascorbic acid (for example, palmitic acid ester and stearic acid ester), natural antioxidant components (tea and rose as plant extract components) Herbs such as marie, and extracts from peach leaves and root nodules) may be added. The oil may be of any origin, such as vegetable or animal fats. Specifically, rapeseed oil, sunflower oil, corn oil, soybean oil, rice oil, safflower oil, palm oil, coconut oil,
Beef tallow and the like. In addition, those obtained by separating these fats and oils, and those whose melting points are adjusted by hydrogenation or transesterification can be used. The present invention will be described below with reference to examples.
The present invention is not limited to these. The percentages and parts in the examples are on a weight basis. First, a method for preparing an emulsifier will be described. [Preparation of sucrose fatty acid ester] A commercially available sucrose fatty acid ester (trade name: O-170, manufactured by Mitsubishi Kasei Foods Co., Ltd.) was fractionated by a silica gel column using chloroform-methanol as a developing solvent, and the following fractionation was performed. An emulsifier of the composition was obtained. [Table 1] [0019] Preparation of di-glycerides] immobilized lipase (trade name: Lypozyme3A, Novo Industries AS (Ltd.)) moisture 4%, a 100g as a catalyst, a rapeseed fatty acid 860g and glycerin 140 g 40 ° C., stirred reaction under reduced pressure After 8 hours, filtration and removal of the immobilized enzyme,
The reaction product was subjected to molecular distillation to obtain diglyceride c having the following composition. [Table 2] Using the oil / fat composition containing the emulsifier composition obtained as described above, various fried confections were prepared and evaluated. The evaluation of the texture was performed according to the following criteria.・ Evaluation A in “crispness”: Good oil drainage, very crisp. B: Slightly drained and quite crisp. C: The oil drain is slightly bad, and it is not so crisp. D: The oil drain is poor, and it does not crisp. -Evaluation A in "crispness": Very crisp, light texture. B: Rather crispy and slightly light texture. C: Slightly crisp texture. D: Slightly heavy texture without too crispy. The volume measurement for the specific volume measurement is as follows.
It was measured by SELNACVM-150 manufactured by Astex.
When a flat surface could not be obtained as the bottom surface during the measurement, the fried rice cracker was cut at the center and divided into two portions for measurement. The hue and surface cracking were evaluated by visual observation. Example 1 , Comparative Example 1 [Fried rice cracker] Dough is prepared from urchin rice by a known method, cut and molded, and then dried with hot air (20% moisture)-Nekase (leave for about 14 hours)-
A material obtained by the second drying (10% moisture), and 240 ° C. emulsifiers
After frying for 1 minute with rapeseed oil (Example 1 ) and rapeseed oil (Comparative Example 1) to which diglyceride was added, the specific volume, appearance,
The texture was compared. Table 3 shows the results. [Table 3] In the case of Example 1 , only the texture was light.
Clause, you friend (How to set the size of the fabric inside of temperament) were aligned well. Example 2 , Comparative Example 2 [Karinto] 400 g of flour, 80 g of sugar, 3 g of baking powder, 1 g of salt, and 120 g of water were kneaded, and the mixture was made to have a hardness similar to that of an earlobe. The dough is rolled with a roll, cut into a size of 4 × 4 × 50 mm, formed, then spun again for 30 minutes, fried in the oil shown in Table 4, and boiled with molasses (160 g of sugar and 60 g of water). )
Was prepared, and Karinto was prepared. Table 4 shows the results. [Table 4] As shown in Table 4, according to the present invention, it was possible to obtain a light-tasting Karinto which was crisp, greasy and not oily. Example 3 and Comparative Example 3 [Potato Chips] Four potatoes were washed with water, removed of moisture, and then sliced to adjust the thickness to 1.5 mm. Thereafter, the product was washed again with water to remove starch and eluted material from the surface, and then wiped off moisture. Table 5
And then evaluated. Table 5 shows the results
Shown in [Table 5] As shown in Table 5, according to the present invention, there is Sakumi, lighter crisps of texture was Turkey Togawaka' be prepared.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 岡内 優司 茨城県鹿島郡神栖町東深芝20 花王株式 会社研究所内 (56)参考文献 特開 平2−291228(JP,A) 特開 平7−16051(JP,A) 特開 平3−4750(JP,A) 特開 昭64−39954(JP,A) 特開 平6−113742(JP,A) 特開 平6−181687(JP,A) 特開 平6−14711(JP,A) 特開 昭59−25644(JP,A) 特開 平3−292847(JP,A) 特開 昭58−209937(JP,A) 特開 平7−323293(JP,A) 特開 平1−262753(JP,A) 特表 平3−500127(JP,A) (58)調査した分野(Int.Cl.7,DB名) A23G 1/00 - 9/30 A21D 9/00 - 9/06 A23L 1/217 JICSTファイル(JOIS) 食品関連文献情報(食ネット) WPI(DIALOG) FOODLINE(DIALOG) Foods Adlibra(DIAL OG) Food Sci.&Tech.Abs (DIALOG)──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Yuji Okauchi 20 Kasumi-gun Higashi Fukashiba, Kashima-gun, Ibaraki Pref. Kao Co., Ltd. (56) References JP-A-2-291228 (JP, A) JP-A-7-16051 ( JP, A) JP-A-3-4750 (JP, A) JP-A-64-39954 (JP, A) JP-A-6-113742 (JP, A) JP-A-6-181687 (JP, A) JP-A-6-14711 (JP, A) JP-A-59-25644 (JP, A) JP-A-3-292847 (JP, A) JP-A-58-209937 (JP, A) JP-A-7-323293 (JP) , A) JP-A-1-2622753 (JP, A) JP-A-3-500127 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) A23G 1/00-9/30 A21D 9/00-9/06 A23L 1/217 JICST file (JOIS) Food-related literature information (food net) WPI (DI ALOG) FOODLINE (DIALOG) Foods Adlibra (DIAL OG) Food Sci. & Tech. Abs (DIALOG)

Claims (1)

(57)【特許請求の範囲】 【請求項1】 グリセリン脂肪酸ジエステル(ジグリセ
リド)を5〜50重量%、ショ糖脂肪酸ジエステルとショ
糖脂肪酸トリエステルを0.05〜10重量%含有する油脂組
成物を用いて、揚げ菓子生地を油ちょうすることを特徴
とするかりんとう、揚げ煎餅、揚げあられ、新生あられ
及びポテトチップスより選ばれる揚げ菓子類の製造方
法。
(57) [Claim 1] An oil or fat composition containing 5 to 50% by weight of glycerin fatty acid diester (diglyceride) and 0.05 to 10% by weight of sucrose fatty acid diester and sucrose fatty acid triester is used. Karinto, fried rice crackers, fried hail, new hail
And a method for producing fried confectionery selected from potato chips .
JP32329195A 1995-12-12 1995-12-12 Manufacturing method of fried confectionery Expired - Fee Related JP3372735B2 (en)

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JP3372735B2 true JP3372735B2 (en) 2003-02-04

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* Cited by examiner, † Cited by third party
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TWI331017B (en) 2002-09-13 2010-10-01 Kao Corp Oil or fat compositions
JP5877638B2 (en) * 2010-12-24 2016-03-08 日清オイリオグループ株式会社 Fried food
JP5855830B2 (en) * 2011-01-04 2016-02-09 理研ビタミン株式会社 Emulsifier formulation for molded potato chips and method for producing molded potato chips using the same
JP6058927B2 (en) * 2012-07-09 2017-01-11 月島食品工業株式会社 Oil composition for frying

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Publication number Priority date Publication date Assignee Title
JPS58209937A (en) * 1982-05-31 1983-12-07 Nippon Oil & Fats Co Ltd Liquid shortening
JPS5925644A (en) * 1982-08-04 1984-02-09 Kao Corp Emulsified fat and oil composition
AU1559788A (en) * 1987-05-05 1988-11-10 Procter & Gamble Company, The Sugar polyester frying mediums with improved frylife and foods dried in the frying mediums
JP2665345B2 (en) * 1988-04-12 1997-10-22 旭電化工業株式会社 Oil composition
GB8815223D0 (en) * 1988-06-27 1988-08-03 Unilever Plc Frying-fat composition
DE69008576T2 (en) * 1989-02-24 1994-09-01 Unilever Nv Use of a baking and frying fat composition.
JPH0675469B2 (en) * 1989-05-01 1994-09-28 花王株式会社 Edible oil and fat composition
JP2566835B2 (en) * 1990-04-11 1996-12-25 鐘淵化学工業株式会社 Fat composition
JPH0614711A (en) * 1992-07-01 1994-01-25 Kao Corp Oil and fat composition for heat cooking
JP3180109B2 (en) * 1992-10-06 2001-06-25 ミヨシ油脂株式会社 Fat composition for frying
JPH06181687A (en) * 1992-12-22 1994-07-05 Kao Corp Oil and fat composition for heat cooking
JP3465926B2 (en) * 1993-06-30 2003-11-10 花王株式会社 Oil composition for cooking
JPH07323293A (en) * 1994-05-30 1995-12-12 Toshiba Corp Gaseous ozone diffuser

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