JP3370859B2 - Waste plastic processing and power generation system - Google Patents

Waste plastic processing and power generation system

Info

Publication number
JP3370859B2
JP3370859B2 JP23751096A JP23751096A JP3370859B2 JP 3370859 B2 JP3370859 B2 JP 3370859B2 JP 23751096 A JP23751096 A JP 23751096A JP 23751096 A JP23751096 A JP 23751096A JP 3370859 B2 JP3370859 B2 JP 3370859B2
Authority
JP
Japan
Prior art keywords
pressure water
temperature
plastic
temperature high
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP23751096A
Other languages
Japanese (ja)
Other versions
JPH1080674A (en
Inventor
務 奥沢
幸雄 石垣
慎也 林
健次 山根
兼政 野間口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Showa Denko Materials Co Ltd
Original Assignee
Hitachi Chemical Co Ltd
Hitachi Ltd
Showa Denko Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd, Hitachi Ltd, Showa Denko Materials Co Ltd filed Critical Hitachi Chemical Co Ltd
Priority to JP23751096A priority Critical patent/JP3370859B2/en
Publication of JPH1080674A publication Critical patent/JPH1080674A/en
Application granted granted Critical
Publication of JP3370859B2 publication Critical patent/JP3370859B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/54Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、廃FRP等のプラ
スチック複合材料の処理・発電システムに係わり、特に
高温高圧水を利用した廃FRP等のプラスチック複合材
料の処理に好適な処理・発電システムに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a treatment / power generation system for a plastic composite material such as waste FRP, and more particularly to a treatment / power generation system suitable for the treatment of a plastic composite material such as waste FRP using high temperature and high pressure water. .

【0002】[0002]

【従来の技術】廃FRP等のプラスチック複合材料の処
理は、補強材としてガラス繊維が含まれているため処分
が難しいが、その機能性の良さから主としてFRP船及
び浴槽に使用されたため、生産量は増加の一途を辿り、
実用化された時期から耐用年の30年が経った。この結
果、使用を終えた廃FRP等のプラスチック複合材料の
処理は焦眉な問題となってきている。
2. Description of the Related Art Although it is difficult to dispose of plastic composite materials such as waste FRP because glass fiber is contained as a reinforcing material, it is mainly used for FRP ships and bathtubs due to its good functionality, and therefore the production amount. Is increasing,
Thirty years have passed since it was put into practical use. As a result, the treatment of plastic composite materials such as waste FRP that have been used up has become a serious problem.

【0003】廃FRP船の焼却装置が運輸省により開発
され、廃FRPの燃焼熱を利用するための基盤技術が開
発されてきた。
An incinerator for waste FRP ships has been developed by the Ministry of Transport, and basic technology for utilizing the combustion heat of waste FRP has been developed.

【0004】一方、廃FRP等のプラスチック複合材料
を成分に分解して再利用することができる水蒸気添加熱
分解法の研究開発も行われている。その中でも、特に高
圧の蒸気である高温高圧水特に、超臨界水を用いた水添
加熱分解法が、常圧では起こらない反応が起こりプラス
チックの原料にまで分解できるため種々の取り組みが行
われている。前者は、廃FRP等のプラスチック複合材
料を熱に換えることを主眼としているため、エネルギー
的には自立している。これに対し、後者は、原料に戻す
ことを主眼としているが、工業的に高温高圧水を製造す
るためのエネルギー源について配慮されていない。
On the other hand, research and development of a steam-added pyrolysis method, which is capable of decomposing plastic composite materials such as waste FRP into components and reusing them, have also been conducted. Among them, particularly, high-temperature high-pressure water, which is a high-pressure steam, in particular, the water-added pyrolysis method using supercritical water is capable of decomposing into a raw material of plastics because a reaction that does not occur at atmospheric pressure occurs and various efforts are being made. There is. The former aims at replacing plastic composite materials such as waste FRP with heat, and therefore is self-sustaining in terms of energy. On the other hand, the latter aims at returning to the raw material, but does not consider the energy source for industrially producing high temperature and high pressure water.

【0005】[0005]

【発明が解決しようとする課題】前述した廃FRP等の
プラスチック複合材料の燃焼処理技術は、廃FRP等の
プラスチック複合材料の処理とともに熱エネルギーを得
ることができるが、その反面、廃FRP等のプラスチッ
ク複合材料中のガラス成分等が混在したまま溶融凝固し
て燃焼残渣となるため、再利用が難しい。
The above-described combustion processing technology for the plastic composite material such as waste FRP can obtain heat energy with the processing of the plastic composite material such as waste FRP. Recycling is difficult because the glass components etc. in the plastic composite material are mixed and solidified to form combustion residues.

【0006】一方、廃FRP等のプラスチック複合材料
を高温高圧水特に、超臨界水で分解する技術は、原料に
まで分解でき再利用できる形態で得られるものの、高温
高圧水を造る熱源を確保する必要がある。又、高温高圧
水分離後の高温高圧水の熱回収及び水回収が配慮されて
いないという問題があった。
On the other hand, although the technique of decomposing plastic composite materials such as waste FRP with high temperature and high pressure water, especially supercritical water, can be obtained in a form that can be decomposed into raw materials and can be reused, but secures a heat source for producing high temperature and high pressure water. There is a need. Further, there is a problem that heat recovery and water recovery of the high temperature and high pressure water after the high temperature and high pressure water separation are not considered.

【0007】本発明の第1の目的は、廃FRP等複合プ
ラスチック以外の通常の廃プラスチックの燃焼熱を使用
して高温高圧水を造り、焼却すると未燃のガラス成分等
が残渣となる廃FRP等の複合プラスチックをその高温
高圧水で分解するという方式でプラスチックの特性に応
じて適正に処理できる廃プラスチック処理・発電システ
ムを提供することにある。
A first object of the present invention is to use waste FRP such as waste FRP to produce high-temperature high-pressure water by using the heat of combustion of ordinary waste plastics, and when incinerated, the unburned glass components and the like become residues. It is an object of the present invention to provide a waste plastic treatment / power generation system that can appropriately treat composite plastics such as the above with the high temperature and high pressure water according to the characteristics of the plastics.

【0008】本発明の第2の目的は、余剰の高温高圧水
で発電し、かつ使用後の高温高圧水で燃焼空気予熱,給
水予熱等の熱回収を行い、最終的に水を回収する廃プラ
スチック処理・発電システムを提供することにある。
A second object of the present invention is to generate power with surplus high-temperature high-pressure water, recover the heat such as combustion air preheat and feed water preheat with the high-temperature high-pressure water after use, and finally recover the water. It is to provide a plastic processing and power generation system.

【0009】本発明の第3の目的は、エネルギー源を確
保するとともに、廃FRP等のプラスチック複合材料を
含む廃プラスチックが有する未利用エネルギーを利用す
る廃プラスチック処理・発電システムを提供することに
ある。
A third object of the present invention is to provide a waste plastic treatment / power generation system which secures an energy source and utilizes the unused energy of waste plastic containing a plastic composite material such as waste FRP. .

【0010】[0010]

【課題を解決するための手段】上記目的を達成するた
め、本発明の廃プラスチック処理・発電システムは、以
下のように構成した。ガラス繊維等の強化材の入った複
合プラスチックを高温高圧水で分解する高温高圧水分解
装置と、通常の廃プラスチックを熱分解する熱分解装
置、この熱分解装置で発生した流体燃料中から有害ガス
及び煤塵を除去する除去装置,除去装置より出てきた流
体燃料を燃焼させて高温高圧水を造るための熱源を造る
燃焼器、この燃焼器での燃焼熱で高温高圧水を造るボイ
ラー,高温高圧水で発電する蒸気タービンによる発電シ
ステムから構成する。さらに、純水製造装置を設け、高
温高圧水分解装置を経た高温高圧水及び分解した気液混
合物を熱分解装置の熱源にし、燃焼空気予熱,補給水予
熱,給水予熱,廃FRP予熱,蒸気タービン再熱、また
は蒸気タービン抽気加熱等で熱回収した後、復水して水
を回収し純水製造装置で純水にして補給水または廃FR
Pを供給する際のスラリーの母液として供給する。
In order to achieve the above object, the waste plastic treatment / power generation system of the present invention is configured as follows. High-temperature high-pressure water decomposition equipment that decomposes composite plastics containing glass fiber and other reinforcing materials with high-temperature high-pressure water, thermal decomposition equipment that decomposes ordinary waste plastics, and harmful gas from the fluid fuel generated by this thermal decomposition equipment. And a device for removing soot and dust, a combustor that creates a heat source for combusting the fluid fuel that comes out of the device to create high-temperature high-pressure water, a boiler that creates high-temperature high-pressure water by the heat of combustion in this combustor, high-temperature high-pressure It consists of a power generation system using a steam turbine that generates water. Furthermore, a pure water production device is provided, and the high temperature and high pressure water that has passed through the high temperature and high pressure water decomposition device and the decomposed gas-liquid mixture are used as the heat sources of the thermal decomposition device, and combustion air preheating, makeup water preheating, feed water preheating, waste FRP preheating, steam turbine After recovering heat by reheating or steam turbine extraction heating, etc., condensate is used to collect water and make pure water in a pure water production device to make up water or waste FR.
It is supplied as the mother liquor of the slurry when P is supplied.

【0011】また、ガラス繊維等の強化材の入った複合
プラスチックを高温高圧水で分解する高温高圧水分解装
置と、通常の廃プラスチックを熱分解する熱分解装置、
この熱分解装置で発生した流体燃料中から有害ガス及び
煤塵を除去する除去装置,除去装置より出てきた流体燃
料を燃焼させてガスタービンを駆動するための燃焼器,
燃焼器の燃焼ガスで駆動するガスタービン発電システ
ム,ガスタービンの排熱で高温高圧水を造るボイラー,
高温高圧水で発電する蒸気タービンによる発電システム
から構成する。さらに、純水製造装置を設け、高温高圧
水分解装置を経た高温高圧水及び分解した気液混合物を
熱分解装置の熱源にし、燃焼空気予熱,補給水予熱,給
水予熱,廃FRP予熱,蒸気タービン再熱、または蒸気
タービン抽気加熱等で熱回収した後、復水して水を回収
し純水製造装置で純水にして補給水または廃FRPを供
給する際のスラリーの母液として供給する。
Further, a high-temperature and high-pressure water decomposing device for decomposing a composite plastic containing a reinforcing material such as glass fiber with high-temperature and high-pressure water, and a thermal decomposition device for decomposing ordinary waste plastics,
A removal device for removing harmful gas and dust from the fluid fuel generated by this thermal decomposition device, a combustor for driving the gas turbine by burning the fluid fuel discharged from the removal device,
Gas turbine power generation system driven by combustion gas of combustor, boiler that produces high temperature and high pressure water by exhaust heat of gas turbine,
It consists of a power generation system using a steam turbine that uses high-temperature, high-pressure water to generate power. Furthermore, a pure water production device is provided, and the high temperature and high pressure water that has passed through the high temperature and high pressure water decomposition device and the decomposed gas-liquid mixture are used as the heat sources of the thermal decomposition device, and combustion air preheating, makeup water preheating, feed water preheating, waste FRP preheating, steam turbine After recovering heat by reheating or steam turbine extraction heating, etc., the water is condensed to collect water, which is then made into pure water in a pure water production apparatus and supplied as makeup water or a mother liquor of the slurry when supplying waste FRP.

【0012】[0012]

【発明の実施の形態】以下、本発明の一実施例について
図面を参照して説明する。図1は、本実施例のシステム
構成図である。
BEST MODE FOR CARRYING OUT THE INVENTION An embodiment of the present invention will be described below with reference to the drawings. FIG. 1 is a system configuration diagram of the present embodiment.

【0013】図1に示すように、本実施例の廃プラスチ
ック熱分解流体燃料利用の廃FRP高温高圧水分解処理
・発電システムは、大きく分けて蒸気タービン系統及び
高温高圧水利用系統から構成されている。
As shown in FIG. 1, a waste FRP high-temperature high-pressure water decomposition treatment / power generation system using waste plastic pyrolysis fluid fuel of this embodiment is roughly divided into a steam turbine system and a high-temperature high-pressure water utilization system. There is.

【0014】本実施例のシステムは、廃プラスチック3
1を熱分解するための熱分解装置24,熱分解装置24
に熱分解用空気を供給する空気系統29,熱分解装置2
4に熱分解用蒸気を供給する蒸気系統28,熱分解装置
24に熱分解用の熱を与える熱交換器32,熱分解装置
24からの有害ガス,煤塵を除去する有害ガス・煤塵除
去装置25,熱分解装置24で生成した流体燃料を燃焼
させる燃焼器と燃焼熱を排熱回収する機器が一体となっ
た排熱回収装置27,排熱回収装置27内で燃焼熱を回
収して給水から蒸気を作るためのエコノマイザー,蒸発
器及び過熱器からなるボイラー5,排熱回収装置27内
に設置され燃焼用空気1を予熱する空気予熱器46,ボ
イラー5から出た水蒸気により駆動される蒸気タービン
33,蒸気タービン33によって駆動され発電する発電
機34,蒸気タービン33の出口から排出される蒸気を
復水する復水器12,復水器12の復水と純水製造装置
15からの補給水を流入する復水タンク11,復水タン
ク11からの水を予熱する復水予熱器39,復水予熱器
39で予熱された復水を脱気する脱気器9,脱気器9に
注入する蒸気タービン33からの蒸気タービン抽気10
を加熱する加熱器23,脱気器9からの水をボイラー5
に給水する給水ポンプ8,蒸気タービンの高温高圧水抽
気35の量をコントロールするバルブ4,蒸気タービン
33の高温高圧水抽気35の変動分を逃がすためのバル
ブ13,バルブ13を通った蒸気を復水する復水器1
6,高温高圧水分解装置19で利用する蒸気をコントロ
ールするためのバルブ7,蒸気タービン33の高温高圧
水抽気35を用いる高温高圧水分解装置19,高温高圧
水分解装置19に廃FRP等のプラスチック複合材料1
8を供給するために水タンク50からの水と廃FRP等
のプラスチック複合材料18を混合してスラリー状に調
製する調製タンク17,調製タンク17から高温高圧水
分解装置19に水と廃FRP等のプラスチック複合材料
の混合スラリーを供給するためのスラリー供給ポンプ4
1,高温高圧水分解装置19を出た高温高圧水と分解物
との混合物44をガスと固液に分けるガス分離器20,
ガス分離器20を出た高温高圧水・ガス混合物45の一
部で分離対象の廃FRP等のプラスチック複合材料混合
液を加熱する熱交換器37,ガス分離器20を出た高温
高圧水・ガス混合物45の一部を加熱器23と復水予熱
器39の熱源とした後水を蓄える水タンク50,水タン
ク50の水を純水にする純水製造装置15及び純水製造
装置15の水を復水タンク11に供給する純水供給ポン
プ14,燃焼用空気1を排熱回収装置27内に送り込む
送風機3、送風機3から出てきた空気を予熱する空気予
熱器46から主として構成されている。
The system according to the present embodiment is composed of waste plastic 3
Thermal decomposition device 24 for thermally decomposing 1 and thermal decomposition device 24
Air system 29 for supplying thermal decomposition air to the thermal decomposition apparatus 2
4, a steam system 28 for supplying thermal decomposition steam, a heat exchanger 32 for providing thermal decomposition heat to the thermal decomposition device 24, a harmful gas / dust removal device 25 for removing harmful gas and dust from the thermal decomposition device 24. An exhaust heat recovery device 27 in which a combustor for burning the fluid fuel generated by the thermal decomposition device 24 and a device for recovering the exhaust heat of the combustion heat are integrated, and the combustion heat is recovered in the exhaust heat recovery device 27 from the water supply. Boiler 5 consisting of an economizer for producing steam, an evaporator and a superheater 5, an air preheater 46 installed in the exhaust heat recovery device 27 to preheat the combustion air 1, and steam driven by steam emitted from the boiler 5 Turbine 33, generator 34 driven by steam turbine 33 to generate electric power, condenser 12 for condensing steam discharged from the outlet of steam turbine 33, condensate of condenser 12 and replenishment from pure water production apparatus 15. water The inflowing condensate tank 11, the condensate preheater 39 for preheating the water from the condensate tank 11, the deaerator 9 for deaerating the condensate preheated by the condensate preheater 39, and the deaerator 9 are injected. Steam turbine extraction 10 from the steam turbine 33
Water from the heater 23 and the deaerator 9 for heating the boiler 5
To control the amount of the high temperature high pressure water extraction 35 of the steam turbine 4, a valve 13 for releasing the fluctuation of the high temperature high pressure water extraction 35 of the steam turbine 33, and the steam that has passed through the valve 13 is recovered. Water condenser 1
6, a valve 7 for controlling steam used in the high-temperature high-pressure water decomposition device 19, a high-temperature high-pressure water decomposition device 19 using the high-temperature high-pressure water extraction 35 of the steam turbine 33, a high-temperature high-pressure water decomposition device 19 plastic such as waste FRP Composite material 1
Preparation tank 17 for preparing water in a slurry form by mixing water from the water tank 50 and plastic composite material 18 such as waste FRP to supply 8 and water and waste FRP from the preparation tank 17 to the high-temperature high-pressure water decomposition apparatus 19. Slurry supply pump 4 for supplying mixed slurry of plastic composite material of
1, a gas separator 20 for separating a mixture 44 of high-temperature high-pressure water leaving the high-temperature high-pressure water decomposer 19 and a decomposed product into a gas and a solid-liquid,
Heat exchanger 37 for heating a plastic composite material mixture such as waste FRP to be separated with a part of the high temperature / high pressure water / gas mixture 45 leaving the gas separator 20, the high temperature / high pressure water / gas leaving the gas separator 20 A water tank 50 for storing water after using a part of the mixture 45 as a heat source for the heater 23 and the condensate preheater 39, a pure water producing device 15 for converting the water in the water tank 50 into pure water, and water for the pure water producing device 15 It mainly comprises a pure water supply pump 14 for supplying the condensate tank 11, a blower 3 for feeding the combustion air 1 into the exhaust heat recovery device 27, and an air preheater 46 for preheating the air discharged from the blower 3. .

【0015】このように構成された本実施例のシステム
は、次のように動作する。熱分解装置24においては、
空気系統29から供給される予熱空気と蒸気系統28か
ら供給される蒸気が注入された状態で熱交換器32で与
えられる熱源により、温度を最高350から450℃に
保ち廃プラスチック31の熱分解を行う。この熱分解に
より発生した流体燃料から有害ガス・煤塵除去装置25
で煤塵及び塩素ガス等腐食性ガスを除去し、クリーンな
燃料として排熱回収装置27で燃焼させ、ボイラー5で
高温高圧水を発生させる。このとき、熱分解装置24に
組み込まれた熱交換器32の熱源としては、ガス分離器
20を出たガス等混合高温高圧水のうち高温高圧水管路
21を通る高温高圧水を利用する。この高温高圧水は熱
源として利用された後は、加熱器23,復水予熱器39
を経て復水し水タンク50に還流する。
The system of the present embodiment thus constructed operates as follows. In the thermal decomposition device 24,
The preheated air supplied from the air system 29 and the steam supplied from the steam system 28 are injected into the heat exchanger 32 to maintain the temperature at a maximum of 350 to 450 ° C. to thermally decompose the waste plastic 31. To do. Device 25 for removing harmful gas and dust from the fluid fuel generated by this thermal decomposition
The soot dust and the corrosive gas such as chlorine gas are removed by using the exhaust heat recovery device 27 as clean fuel, and the boiler 5 generates high temperature and high pressure water. At this time, as the heat source of the heat exchanger 32 incorporated in the thermal decomposition device 24, the high temperature high pressure water passing through the high temperature high pressure water pipe line 21 of the mixed high temperature high pressure water containing gas etc. from the gas separator 20 is used. After this high-temperature high-pressure water is used as a heat source, the heater 23, the condensate preheater 39
Condensate is returned to the water tank 50 via the water.

【0016】燃焼用空気1は、送風機3により送風さ
れ、排熱回収装置27内にある空気予熱器46を経て加
熱された後、排熱回収装置27と熱分解装置24に供給
され、熱分解装置24で発生した流体燃料と合流して燃
焼する。この燃焼で発生した高温の燃焼ガスによりボイ
ラー5が加熱され蒸気を発生する。このとき、温度と圧
力を一定値、374.1℃,22.5MPa以上に設定す
ると、蒸気でありながら密度が高いため水の性質も備え
た超臨界水という水蒸気が発生する。前述したように、
この高温高圧水(超臨界水)は、高反応性を示し、通常
の水蒸気で分解が起こりにくいものも分解を促進する効
果がある。ここで、圧力は、ボイラー5への給水ポンプ
8で、温度はボイラー5の部分で昇温して臨界条件を満
たすように制御される。但し、実際には550℃程度,
25MPa程度に設定する。
The combustion air 1 is blown by the blower 3, heated through the air preheater 46 in the exhaust heat recovery device 27, and then supplied to the exhaust heat recovery device 27 and the thermal decomposition device 24 for thermal decomposition. The fluid fuel generated in the device 24 joins and burns. The high temperature combustion gas generated by this combustion heats the boiler 5 to generate steam. At this time, if the temperature and the pressure are set to constant values, 374.1 ° C. and 22.5 MPa or more, supercritical water, which is a vapor, has a high density, and thus has the property of water. As previously mentioned,
This high-temperature high-pressure water (supercritical water) has a high reactivity, and it has an effect of promoting decomposition even if it is difficult to decompose with ordinary steam. Here, the pressure is controlled by the water supply pump 8 to the boiler 5, and the temperature is controlled so that the temperature rises in the portion of the boiler 5 and the critical condition is satisfied. However, in practice,
It is set to about 25 MPa.

【0017】ボイラー5で生成した高温高圧水は蒸気管
路6を通って蒸気タービン33に供給され、蒸気タービ
ン33を駆動する。この蒸気タービン33の回転によ
り、これに連動している発電機34も発電する。蒸気タ
ービン33から排出された蒸気は、復水器12で水にな
り、復水タンク11で補給水を加えられ、復水予熱器3
9で予熱されて脱気器9に入る。脱気器9では、蒸気タ
ービン33の蒸気タービン抽気10を加熱器23により
昇温して注入し復水からの脱気を行う。脱気された水
は、給水ポンプ8により、ボイラー5に還流する。ま
た、蒸気タービン33の高温高圧水抽気35の量をバル
ブ4で調整しつつ、高温高圧水分解装置19で必要な高
温高圧水量をバルブ7及び13で調整して余剰な高温高
圧水は復水器16で復水し、復水タンク11に入る。
The high-temperature high-pressure water generated in the boiler 5 is supplied to the steam turbine 33 through the steam pipe 6 and drives the steam turbine 33. Due to the rotation of the steam turbine 33, the generator 34 that is interlocked with the steam turbine 33 also generates power. The steam discharged from the steam turbine 33 becomes water in the condenser 12, and makeup water is added to the condensate tank 11, so that the condenser preheater 3
It is preheated at 9 and enters the deaerator 9. In the deaerator 9, the steam turbine extraction air 10 of the steam turbine 33 is heated by the heater 23 and injected to deaerate the condensed water. The degassed water is returned to the boiler 5 by the water supply pump 8. Further, while adjusting the amount of the high temperature and high pressure water extraction gas 35 of the steam turbine 33 with the valve 4, the amount of high temperature and high pressure water required in the high temperature and high pressure water decomposition device 19 is adjusted with the valves 7 and 13, and excess high temperature and high pressure water is condensed. Condensate is returned to the condensate tank 11 by the vessel 16.

【0018】一方、高温高圧水利用系統は、次のように
動作する。廃FRP等のプラスチック複合材料のスラリ
ー調製タンク17で廃FRP等のプラスチック複合材料
と水とを混ぜスラリー化してスラリー供給ポンプ41で
高温高圧水分解装置19に送り出す。この際、廃FRP
等のプラスチック複合材料スラリーを熱交換器37で超
臨界状態に近い状態にして供給する。高温高圧水分解装
置19では、蒸気タービン33の高温高圧水抽気35
(抽気点の条件が、高温高圧水の条件を満たしている高
温高圧水抽気35)を導入して、熱交換器37で超臨界
状態に近い状態になった廃FRP等のプラスチック複合
材料スラリーを高温高圧水分解して原料及びガスに分解
する。
On the other hand, the high temperature and high pressure water utilization system operates as follows. A plastic composite material such as waste FRP and the like is mixed in a slurry preparation tank 17 of the plastic composite material such as waste FRP and water to form a slurry, and the slurry is supplied to a high temperature and high pressure water decomposition apparatus 19 by a slurry supply pump 41. At this time, the waste FRP
A plastic composite material slurry such as the above is supplied in a state close to a supercritical state by the heat exchanger 37. In the high-temperature high-pressure water decomposition device 19, the high-temperature high-pressure water extracted from the steam turbine 33
(High-temperature high-pressure water extraction 35 whose extraction point condition satisfies the high-temperature high-pressure water condition) is introduced to remove a plastic composite material slurry such as waste FRP that has been in a state close to a supercritical state by the heat exchanger 37. High-temperature high-pressure water decomposes into raw materials and gas.

【0019】分解された物質および高温高圧水との混合
物をガス分離器20でガス(以下、ガス等混合高温高圧
水という)と固液混合物に分離する。このガス等混合高
温高圧水の一部は、熱交換器37で廃FRP等のプラス
チック複合材料スラリーを超臨界状態に近い状態に昇温
するための熱源として使われた後、熱を奪われて復水し
水タンク50に還流する。また、ガス分離器20を出た
ガス等混合高温高圧水のうち熱交換器37供給分以外
は、高温高圧水管路21を通り、加熱器23で蒸気ター
ビン抽気10に熱を与え、さらに、復水予熱器39で復
水に熱を与えた後、高温高圧水自身は復水し水タンク5
0に還流する。
The gas separator 20 separates the mixture of the decomposed substance and the high-temperature high-pressure water into a gas (hereinafter, referred to as gas-mixed high-temperature high-pressure water) and a solid-liquid mixture. A part of this high-temperature and high-pressure water mixed with gas is used as a heat source for raising the temperature of the plastic composite material slurry such as waste FRP to a state close to a supercritical state in the heat exchanger 37, and then heat is taken away. Condensed water is returned to the water tank 50. In addition, the high temperature and high pressure water mixed with the gas, etc., which has exited the gas separator 20, except for the portion supplied to the heat exchanger 37, passes through the high temperature and high pressure water pipeline 21, and heats the steam turbine bleed air 10 by the heater 23. After heating the condensate with the water preheater 39, the high temperature and high pressure water itself condenses and the water tank 5
Reflux to 0.

【0020】水タンク50で両系統のガス等混合高温高
圧水は復水した状態で合流し、一部は廃FRP等のプラ
スチック複合材料のスラリー調製タンク17へスラリー
調製用の水として再循環する。水タンク50中の水で廃
FRP等のプラスチック複合材料スラリー調製タンク1
7へ供給される以外の水は純水製造装置へ送られ、純水
処理後に給水ポンプ14により補給水として復水タンク
11に供給され再循環する。
In the water tank 50, the high-temperature and high-pressure water mixed with gases of both systems joins in a condensed state, and a part thereof is recirculated to the slurry preparation tank 17 of the plastic composite material such as waste FRP as slurry preparation water. . Tank for preparing plastic composite material slurry such as waste FRP with water in the water tank 50 1
Water other than that supplied to No. 7 is sent to the pure water producing apparatus, and after the pure water treatment, is supplied to the condensate tank 11 as makeup water by the water supply pump 14 and recirculated.

【0021】廃プラスチックを燃料とする場合、そのま
ま燃焼させると塩化ビニール等に含まれる塩素によりボ
イラー管腐食の原因となる塩化水素が発生し蒸気温度を
300℃,30気圧程度に制限しなくてはならなくなり、
高温高圧水の製造が難しくなる。本実施例では、これを
避けるため、廃プラスチックを使用後、高温高圧水の熱
を利用して熱分解して低温の流体燃料を発生させ、この
流体燃料から煤塵と塩化水素を除去し、燃焼の燃料とす
る。この燃料の燃焼により製造される高温高圧水が蒸気
タービンに入り蒸気タービンを駆動する。このとき、蒸
気タービンより抽気した高温高圧水を高温高圧水処理装
置に入れ、高温高圧水特有の性質である高反応性を利用
して廃FRP等のプラスチック複合材料を原料にまで分
解する。廃FRP等のプラスチック複合材料を分解した
後の高温高圧水を、通常の廃プラスチックの熱分解装置
の熱源,燃焼空気の予熱,蒸気タービン系統の給水予
熱,抽気再熱,抽気加熱,補給水及び廃FRPの予熱で
回収するとともに復水して水を回収することにより、廃
FRP等のプラスチック複合材料を含む廃プラスチック
を効率的に処理し廃FRP等のプラスチック複合材料原
料を得るばかりでなく水も電力も得ることができる。こ
のように、燃料費の不要な廃プラスチックを燃焼するの
で、低コストで処理できる。その結果、水回収及び熱回
収を行い熱利用率を高くでき、また、補給水もほとんど
不要であり、必要なものは燃料であるので経済的な運転
ができる。
When waste plastics are used as fuel, if they are burned as they are, chlorine contained in vinyl chloride, etc. generates hydrogen chloride which causes corrosion of the boiler tube, resulting in a steam temperature change.
We have to limit it to 300 degrees Celsius, 30 atmospheres,
It becomes difficult to produce high temperature and high pressure water. In this embodiment, in order to avoid this, after the waste plastic is used, the heat of the high-temperature high-pressure water is used to thermally decompose it to generate a low-temperature fluid fuel, and the dust and hydrogen chloride are removed from this fluid fuel, and the combustion is performed. Use as fuel. The high-temperature high-pressure water produced by the combustion of this fuel enters the steam turbine and drives the steam turbine. At this time, the high-temperature and high-pressure water extracted from the steam turbine is put into a high-temperature and high-pressure water treatment apparatus, and the high reactivity which is a characteristic of the high-temperature and high-pressure water is utilized to decompose the plastic composite material such as waste FRP into a raw material. High-temperature high-pressure water after decomposing plastic composite materials such as waste FRP is used as a heat source for ordinary waste plastic thermal decomposition equipment, combustion air preheating, steam turbine system feed water preheating, extraction reheating, extraction heating, make-up water and By recovering the water by preheating the waste FRP and recovering the water, the waste plastic containing the plastic composite material such as the waste FRP can be efficiently processed to obtain the raw material of the plastic composite material such as the waste FRP. And electricity can be obtained. Thus, since the waste plastic which does not require the fuel cost is burned, it can be processed at a low cost. As a result, water recovery and heat recovery can be performed to increase the heat utilization rate, make-up water is almost unnecessary, and fuel is required, so economical operation can be performed.

【0022】図2は、図1に示す実施例の変形例であ
り、熱分解装置24の部分を、プラスチックを熱分解す
るのに蒸気系統28を添加しないで分解するシステムで
ある。本例によれば、熱分解に蒸気を使用しないので、
クローズドループで廃プラスチックをクリーン燃料化し
て廃FRP等のプラスチック複合材料を処理でき、しか
も発電できるので低コストで環境に優しく資源の節約が
図れるシステムが実現できる。
FIG. 2 shows a modification of the embodiment shown in FIG. 1, which is a system for decomposing the part of the thermal decomposition device 24 without thermally adding the steam system 28 to thermally decompose the plastic. According to this example, since steam is not used for pyrolysis,
It is possible to realize a system that is low-cost, environment-friendly and resource saving because it can process waste plastics as a clean fuel in a closed loop to process plastic composite materials such as waste FRP and generate electricity.

【0023】図3は、図1の変形例で図1の実施例と異
なる点は、高温高圧水を作製するに際し廃プラスチック
の熱分解流体燃料の燃焼熱を直接使わずにガスタービン
を駆動して発電した後、その排ガスを使って高温高圧水
を作製する点である。すなわち、図1に示す構成に圧縮
機52,ガスタービン49、及び発電電動機48を追加
したもので、燃焼用空気1を空気予熱器46で予熱し、
それを圧縮機52で圧縮した後、燃焼器38に入れ、プ
ラスチックの熱分解流体燃料と混合させて燃焼させる。
燃焼後の燃焼ガスをガスタービン49に入れて発電電動
機48を駆動し発電する。このとき、ガスタービン49
の排ガスを排熱回収装置27に入れボイラー5で高温高
圧水を発生させる。
FIG. 3 is a modification of FIG. 1 and differs from the embodiment of FIG. 1 in that when producing high-temperature high-pressure water, the gas turbine is driven without directly using the combustion heat of the pyrolysis fluid fuel of waste plastic. This is the point of producing high-temperature high-pressure water using the exhaust gas after power generation. That is, the compressor 52, the gas turbine 49, and the generator motor 48 are added to the configuration shown in FIG. 1, and the combustion air 1 is preheated by the air preheater 46,
After it is compressed by the compressor 52, it is put into the combustor 38 and mixed with the pyrolytic fluid fuel of plastic to be burned.
The combustion gas after combustion is put into the gas turbine 49 to drive the generator motor 48 to generate electricity. At this time, the gas turbine 49
The exhaust gas is put into the exhaust heat recovery device 27, and high-temperature high-pressure water is generated by the boiler 5.

【0024】このように、廃プラスチックを使用後、高
温高圧水の熱を利用して熱分解して低温の流体燃料を発
生させ、この流体燃料から煤塵と塩化水素を除去し、燃
焼の燃料とする。この燃料の燃焼熱で直接に高温高圧水
を製造するのでなく、まずガスタービンを駆動して発電
し、さらに、このガスタービンの排熱により製造される
高温高圧水が蒸気タービンに供給し、蒸気タービンを駆
動する。このとき、蒸気タービンより抽気した高温高圧
水を高温高圧水処理装置に入れ、高温高圧水特有の性質
である高反応性を利用して廃FRP等のプラスチック複
合材料を原料にまで分解する。このとき、廃FRP等の
プラスチック複合材料を分解した後の高温高圧水を、熱
分解装置の熱源,燃焼空気の予熱,蒸気タービン系統の
給水予熱,抽気再熱,抽気加熱,補給水及び廃FRPの
予熱で回収するとともに復水して水を回収することによ
り、廃FRP等のプラスチック複合材料を含む廃プラス
チックを効率的に処理し廃FRP等のプラスチック複合
材料原料ばかりでなく水も電力も得ることができる。こ
のように、燃料費の不要な廃プラスチックを燃焼するの
で、低コストで廃FRP等のプラスチック複合材料が処
理できる。このように、図1の実施例に比べ燃焼温度の
高いものに対し図1の実施例3よりも効率的な運転がで
きる。
As described above, after the waste plastic is used, the heat of the high-temperature high-pressure water is used to pyrolyze it to generate a low-temperature fluid fuel, soot and hydrogen chloride are removed from this fluid fuel, and the combustion fuel is used. To do. Rather than directly producing high-temperature high-pressure water by the heat of combustion of this fuel, the gas turbine is first driven to generate electricity, and the high-temperature high-pressure water produced by the exhaust heat of this gas turbine is supplied to the steam turbine to generate steam. Drive the turbine. At this time, the high-temperature and high-pressure water extracted from the steam turbine is put into a high-temperature and high-pressure water treatment apparatus, and the high reactivity which is a characteristic of the high-temperature and high-pressure water is utilized to decompose the plastic composite material such as waste FRP into a raw material. At this time, the high-temperature high-pressure water after decomposing the plastic composite material such as waste FRP is used as the heat source of the thermal decomposition device, the preheating of the combustion air, the feed preheating of the steam turbine system, the extraction reheating, the extraction heating, the makeup water and the waste FRP. By recovering the water by preheating and condensing the water, the waste plastic containing the plastic composite material such as the waste FRP can be efficiently processed and not only the raw material of the plastic composite material such as the waste FRP but also water and electric power can be obtained. be able to. Thus, since the waste plastic which does not require the fuel cost is burned, the plastic composite material such as the waste FRP can be processed at low cost. As described above, it is possible to perform more efficient operation than that of the third embodiment shown in FIG. 1 even though the combustion temperature is higher than that of the third embodiment shown in FIG.

【0025】図4は、図3に示す実施例の変形例で、熱
分解装置24の部分が、プラスチックを熱分解するのに
蒸気系統28を添加しないで分解するシステムである。
この例によれば、熱分解に蒸気を使用しないのでクロー
ズドループで廃プラスチックをクリーン燃料化して廃F
RP等のプラスチック複合材料を処理でき、しかも発電
できるので低コストで環境に優しく資源の節約が図れる
システムが実現できる。
FIG. 4 shows a modification of the embodiment shown in FIG. 3, in which the thermal decomposition device 24 is a system for decomposing plastics without adding the steam system 28 to thermally decompose the plastics.
According to this example, since steam is not used for thermal decomposition, waste plastic is converted to clean fuel in a closed loop and waste F
Since a plastic composite material such as RP can be processed and power can be generated, it is possible to realize a system that is low cost, environment-friendly, and can save resources.

【0026】[0026]

【発明の効果】以上、本発明によれば、廃プラスチック
の熱分解による生成燃料または通常の市販燃料の燃焼熱
により発電及び廃FRP等の焼却の困難な複合プラスチ
ックの分解の有力手段である高温高圧水を作成でき、さ
らに分解に使用した高温高圧水の熱及び水並びに複合プ
ラスチック原料の混合物も回収できるので、高効率・低
コストで信頼性の高い廃プラスチック処理・発電システ
ムを提供することができる。
As described above, according to the present invention, the high temperature, which is an effective means for generating power and decomposing composite plastics such as waste FRP, which are difficult to incinerate, by the combustion heat of the fuel produced by the thermal decomposition of waste plastics or ordinary commercial fuels. Since high-pressure water can be created and the heat and water of the high-temperature high-pressure water used for decomposition and the mixture of water and the composite plastic raw material can also be collected, it is possible to provide a highly efficient, low-cost and highly reliable waste plastic treatment and power generation system. it can.

【0027】特に、廃プラスチックを燃料化する場合
は、無料の燃料である廃プラスチックの燃焼熱で作成す
る高温高圧水で、分解の難しい複合プラスチック廃材を
分解するばかりでなく電力も獲得できるので、各種廃プ
ラスチックの処理が有機的にかつ低コストにできるとい
う特徴がある。
In particular, when the waste plastic is used as a fuel, high temperature and high pressure water produced by the combustion heat of the waste plastic, which is a free fuel, can not only decompose the difficult-to-decompose composite plastic waste but also obtain electric power. There is a feature that various kinds of waste plastics can be treated organically and at low cost.

【0028】又、高温高圧水分解と発電及び廃プラスチ
ックと廃FRP等のプラスチック複合材料が相互補完の
形で有機的に結びついているため、使用後の高温高圧水
の持つエネルギー及び質量が回収でき、発電もでき、か
つ廃プラスチックをクリーン化して使用できる。
Further, since the high temperature and high pressure water decomposition and the power generation and the waste plastic and the plastic composite material such as the waste FRP are organically connected to each other in a mutually complementary form, the energy and mass of the high temperature and high pressure water after use can be recovered. It can also generate power and can be used by cleaning waste plastic.

【0029】又、高温高圧水分解で廃FRP等のプラス
チック複合材料もクリーンな原料に還元できるので環境
に優しく高効率な廃FRP等のプラスチック複合材料,
廃プラスチック処理・発電システムを提供することがで
きる。
Also, since plastic composite materials such as waste FRP can be reduced to clean raw materials by high temperature high pressure water decomposition, environmentally friendly and highly efficient plastic composite materials such as waste FRP,
It is possible to provide a waste plastic processing and power generation system.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例のシステムの系統図である。FIG. 1 is a systematic diagram of a system according to an embodiment of the present invention.

【図2】図1の変形例のシステムの系統図である。FIG. 2 is a system diagram of a system of a modified example of FIG.

【図3】図1の変形例のシステムの系統図である。FIG. 3 is a system diagram of a modified system of FIG.

【図4】図3の変形例のシステムの系統図である。FIG. 4 is a system diagram of a system of a modified example of FIG.

【符号の説明】[Explanation of symbols]

1…燃焼用空気、2…燃料、3…送風機、4,7,13
…バルブ、5…ボイラー、6…蒸気管路、8,14…給
水ポンプ、9…脱気器、10…蒸気タービン抽気、11
…復水タンク、12,16…復水器、15…純水製造装
置、17…スラリー調製タンク、18…廃FRP等のプ
ラスチック複合材料、19…高温高圧水分解装置、20
…ガス分離器、21…高温高圧水管路、23…加熱器、
24…熱分解装置、25…有害ガス・煤塵除去装置、2
7…排熱回収装置、28…蒸気系統、29…空気系統、
31…廃プラスチック、32,37…熱交換器、33…
蒸気タービン、34…発電機、35…高温高圧水抽気、
38…燃焼器、39…復水予熱器、41…スラリー供給
ポンプ、42…スラリー、44…高温高圧水・分解物混
合物、45…高温高圧水・ガス混合物、46…空気予熱
器、48…発電電動機、49…ガスタービン、50…水
タンク、52…圧縮機。
1 ... Combustion air, 2 ... Fuel, 3 ... Blower, 4, 7, 13
... Valve, 5 ... Boiler, 6 ... Steam line, 8,14 ... Water supply pump, 9 ... Deaerator, 10 ... Steam turbine extraction, 11
... condensate tank, 12, 16 ... condenser, 15 ... pure water production apparatus, 17 ... slurry preparation tank, 18 ... plastic composite material such as waste FRP, 19 ... high temperature and high pressure water decomposition apparatus, 20
... Gas separator, 21 ... High-temperature high-pressure water conduit, 23 ... Heater,
24 ... Thermal decomposition device, 25 ... Hazardous gas / dust removal device, 2
7 ... Exhaust heat recovery device, 28 ... Steam system, 29 ... Air system,
31 ... Waste plastic, 32, 37 ... Heat exchanger, 33 ...
Steam turbine, 34 ... Generator, 35 ... High temperature and high pressure water extraction,
38 ... Combustor, 39 ... Condensate preheater, 41 ... Slurry supply pump, 42 ... Slurry, 44 ... High temperature high pressure water / decomposition mixture, 45 ... High temperature high pressure water / gas mixture, 46 ... Air preheater, 48 ... Power generation Electric motor, 49 ... Gas turbine, 50 ... Water tank, 52 ... Compressor.

フロントページの続き (51)Int.Cl.7 識別記号 FI F23G 7/12 B09B 3/00 303E (72)発明者 石垣 幸雄 茨城県日立市幸町三丁目1番1号 株式 会社 日立製作所 日立工場内 (72)発明者 林 慎也 東京都三鷹市新川6丁目38番1号 運輸 省船舶技術研究所内 (72)発明者 山根 健次 東京都三鷹市新川6丁目38番1号 運輸 省船舶技術研究所内 (72)発明者 野間口 兼政 茨城県日立市東町四丁目13番1号 日立 化成工業株式会社 山崎工場内 (56)参考文献 特開 平9−157663(JP,A) 特開 平9−31473(JP,A) 特開 平8−261424(JP,A) 特開 平8−252824(JP,A) 特開 平7−279622(JP,A) (58)調査した分野(Int.Cl.7,DB名) C08J 11/00 - 11/28 B09B 3/00 - 5/00 C10G 1/10 Continuation of front page (51) Int.Cl. 7 Identification code FI F23G 7/12 B09B 3/00 303E (72) Inventor Yukio Ishigaki 3-1-1 Sachimachi, Hitachi City, Ibaraki Hitachi Co., Ltd. (72) Shinya Hayashi, 6-38-1, Shinkawa, Mitaka City, Tokyo, within the Research Institute for Ship Technology, Ministry of Transportation (72) Kenji Yamane, 6-38-1, Shinkawa, Mitaka City, Tokyo (72) ) Inventor Kanemasa Nomaguchi 4-13-1, Higashi-cho, Hitachi-shi, Ibaraki Yamazaki factory, Hitachi Chemical Co., Ltd. (56) References JP-A-9-157663 (JP, A) JP-A-9-31473 (JP, A) JP-A-8-261424 (JP, A) JP-A-8-252824 (JP, A) JP-A-7-279622 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) ) C08J 11/00-11/28 B09B 3/00-5/00 C10G 1/10

Claims (8)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】プラスチックの燃焼熱を利用して高温高圧
水を生成する高温高圧水生成装置と、プラスチックを含
む複合材またはプラスチックを前記高温高圧水生成装置
で生成された高温高圧水の一部で熱分解する高温高圧水
分解装置と、前記高温高圧水生成装置で生成された高温
高圧水の一部により駆動される蒸気タービンを備えたこ
とを特徴とする廃プラスチック処理・発電システム。
1. A high-temperature high-pressure water generator for generating high-temperature high-pressure water using combustion heat of plastic, and a composite material or plastic containing plastic, part of the high-temperature high-pressure water generated by the high-temperature high-pressure water generator. A waste plastic treatment / power generation system comprising: a high-temperature high-pressure water decomposing device for thermally decomposing in 1. and a steam turbine driven by a part of the high-temperature high-pressure water generated by the high-temperature high-pressure water generating device.
【請求項2】前記高温高圧水分解装置で使用した高温高
圧水から熱回収する熱回収手段を備えた請求項1に記載
の廃プラスチック処理・発電システム。
2. The waste plastic treatment and power generation system according to claim 1, further comprising heat recovery means for recovering heat from the high temperature and high pressure water used in the high temperature and high pressure water decomposition apparatus.
【請求項3】プラスチックを分解して得た液体燃料の燃
焼熱を利用して高温高圧水を生成する高温高圧水生成装
置と、プラスチックを含む複合材またはプラスチックを
前記高温高圧水生成装置で生成された高温高圧水の一部
で熱分解する高温高圧水分解装置と、前記高温高圧水生
成装置で生成された高温高圧水の一部により駆動される
蒸気タービンを備えたことを特徴とする廃プラスチック
処理・発電システム。
3. A high-temperature and high-pressure water generator for generating high-temperature and high-pressure water by using combustion heat of liquid fuel obtained by decomposing plastic, and a composite material containing plastic or plastic is generated by the high-temperature and high-pressure water generator. Characterized by comprising a high-temperature high-pressure water decomposition apparatus for thermally decomposing a portion of the high-temperature high-pressure water generated, and a steam turbine driven by a part of the high-temperature high-pressure water generated by the high-temperature high-pressure water generation apparatus. Plastic processing and power generation system.
【請求項4】前記高温高圧水分解装置で使用した高温高
圧水から熱回収する熱回収手段を備えた請求項3に記載
の廃プラスチック処理・発電システム。
4. The waste plastic treatment / power generation system according to claim 3, further comprising heat recovery means for recovering heat from the high temperature and high pressure water used in the high temperature and high pressure water decomposition apparatus.
【請求項5】前記プラスチックを分解して流体燃料化す
るに際し、熱分解もしくは水添分解するものである請求
項4に記載の廃プラスチック処理・発電システム。
5. The waste plastic treatment / power generation system according to claim 4, wherein when the plastic is decomposed into a fluid fuel, it is thermally decomposed or hydrolyzed.
【請求項6】前記蒸気タービンの高圧段からの抽気を高
温高圧水分離装置で使用した高温高圧水で再熱して前記
蒸気タービンの低圧段に供給する請求項4に記載の廃プ
ラスチック処理・発電システム。
6. The waste plastic treatment and power generation according to claim 4, wherein the extracted air from the high-pressure stage of the steam turbine is reheated by the high-temperature high-pressure water used in the high-temperature high-pressure water separator and supplied to the low-pressure stage of the steam turbine. system.
【請求項7】液体燃料の燃焼熱で高温高圧水を生成する
高温高圧水生成装置と、プラスチックを含む複合材また
はプラスチックを前記高温高圧水生成装置で生成された
高温高圧水の一部で熱分解する高温高圧水分解装置と、
前記高温高圧水生成装置で生成された高温高圧水の一部
により駆動される蒸気タービンを備え、前記高温高圧水
分解装置で使用した高温高圧水から熱回収する熱回収手
段を設けたことを特徴とする廃プラスチック処理・発電
システム。
7. A high-temperature high-pressure water generator for generating high-temperature high-pressure water by the heat of combustion of liquid fuel, and a composite material or plastic containing plastic is heated by a part of the high-temperature high-pressure water generated by the high-temperature high-pressure water generator. A high-temperature high-pressure water decomposition device that decomposes,
A steam turbine driven by a part of the high-temperature high-pressure water generated by the high-temperature high-pressure water generator is provided, and heat recovery means for recovering heat from the high-temperature high-pressure water used in the high-temperature high-pressure water decomposer is provided. Waste plastic processing and power generation system.
【請求項8】プラスチックを分解して得た液体燃料の燃
焼熱で、もしくは液体燃料の燃焼により駆動されるガス
タービンと、該ガスタービンの排ガスで高温高圧水を生
成する高温高圧水生成装置と、プラスチックを含む複合
材またはプラスチックを前記高温高圧水生成装置で生成
された高温高圧水の一部で熱分解する高温高圧水分解装
置と、前記高温高圧水生成装置で生成された高温高圧水
の一部により駆動される蒸気タービンを備え、高温高圧
水分解装置で使用した高温高圧水から熱回収することを
特徴とする廃プラスチック処理・発電システム。
8. A gas turbine driven by combustion heat of liquid fuel obtained by decomposing plastic or by combustion of liquid fuel, and a high-temperature high-pressure water generator for generating high-temperature high-pressure water from exhaust gas of the gas turbine. A high-temperature high-pressure water decomposer for thermally decomposing a plastic-containing composite material or plastic with a part of the high-temperature high-pressure water generated by the high-temperature high-pressure water generator, and high-temperature high-pressure water generated by the high-temperature high-pressure water generator A waste plastic treatment and power generation system that is equipped with a steam turbine that is partly driven and that recovers heat from the high-temperature high-pressure water used in the high-temperature high-pressure water decomposition device.
JP23751096A 1996-09-09 1996-09-09 Waste plastic processing and power generation system Expired - Fee Related JP3370859B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23751096A JP3370859B2 (en) 1996-09-09 1996-09-09 Waste plastic processing and power generation system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23751096A JP3370859B2 (en) 1996-09-09 1996-09-09 Waste plastic processing and power generation system

Publications (2)

Publication Number Publication Date
JPH1080674A JPH1080674A (en) 1998-03-31
JP3370859B2 true JP3370859B2 (en) 2003-01-27

Family

ID=17016397

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23751096A Expired - Fee Related JP3370859B2 (en) 1996-09-09 1996-09-09 Waste plastic processing and power generation system

Country Status (1)

Country Link
JP (1) JP3370859B2 (en)

Cited By (1)

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US6464797B1 (en) 1999-07-28 2002-10-15 Ricoh Company, Ltd. Method of separating electrophotographic carrier compositions and recycling the compositions
US20110136057A1 (en) 2009-12-08 2011-06-09 Kazumi Ohtaki Method for treating electrophotographic carrier, method for producing electrophotographic carrier, core material and carrier
KR102096290B1 (en) * 2019-11-13 2020-04-02 (주)효천 Heat recovery equipment for electric power generation system using a renewable energy
KR102563035B1 (en) * 2021-10-05 2023-08-04 윤영식 System for recycling waste plastic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020044248A1 (en) * 2018-08-28 2020-03-05 Reliance Industries Limited A method for catalytic conversion of waste plastic into liquid fuel
US11319493B2 (en) 2018-08-28 2022-05-03 Reliance Industries Limited Method for catalytic conversion of waste plastic into liquid fuel

Also Published As

Publication number Publication date
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