JP3297074B2 - How to seal the tip of the member - Google Patents

How to seal the tip of the member

Info

Publication number
JP3297074B2
JP3297074B2 JP08313892A JP8313892A JP3297074B2 JP 3297074 B2 JP3297074 B2 JP 3297074B2 JP 08313892 A JP08313892 A JP 08313892A JP 8313892 A JP8313892 A JP 8313892A JP 3297074 B2 JP3297074 B2 JP 3297074B2
Authority
JP
Japan
Prior art keywords
tip
coating
sealing
optical fiber
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP08313892A
Other languages
Japanese (ja)
Other versions
JPH05245932A (en
Inventor
秀樹 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Valqua Industries Ltd
Original Assignee
Nippon Valqua Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Valqua Industries Ltd filed Critical Nippon Valqua Industries Ltd
Priority to JP08313892A priority Critical patent/JP3297074B2/en
Publication of JPH05245932A publication Critical patent/JPH05245932A/en
Application granted granted Critical
Publication of JP3297074B2 publication Critical patent/JP3297074B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined

Landscapes

  • Lining Or Joining Of Plastics Or The Like (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【産業上の利用分野】本発明は、部材の先端部を熱可塑
性樹脂で確実かつ簡易に封止する方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for securely and easily sealing the tip of a member with a thermoplastic resin.

【従来の技術】部材の先端部は、種々の目的で樹脂によ
り封止する必要がある場合がある。従来、熱可塑性樹脂
で被覆した部材の先端部の封止方法としては、例えば次
のような方法が知られている。 (イ)熱可塑性樹脂チューブの先端が部材の先端より若
干長くなるように、部材をチューブで被覆し、チューブ
の先端部を熱により溶融して、部材の先端部を封止する
方法。 (ロ)熱可塑性樹脂チューブで被覆した部材の先端面
に、溶融した樹脂を加えて覆い(チューブと一体化し
て)、部材の先端部を封止する方法。 (ハ)熱可塑性樹脂被覆ケーブルの先端にとりつけた検
出素子を、熱可塑性樹脂製の蓋付きケース内に収容し、
各接合面を溶着して、先端部の検出素子を封止する方法
(実開平1−170929号公報参照)。
2. Description of the Related Art In some cases, a tip portion of a member needs to be sealed with a resin for various purposes. 2. Description of the Related Art Conventionally, for example, the following method is known as a method of sealing a distal end portion of a member covered with a thermoplastic resin. (A) A method in which the member is covered with a tube so that the end of the thermoplastic resin tube is slightly longer than the end of the member, and the end of the tube is melted by heat to seal the end of the member. (B) A method in which a molten resin is added to and covered (integrated with the tube) on the distal end surface of a member covered with a thermoplastic resin tube, and the distal end portion of the member is sealed. (C) The detection element attached to the end of the thermoplastic resin-coated cable is housed in a case with a lid made of thermoplastic resin,
A method in which the joining surfaces are welded to seal the detection element at the tip (see Japanese Utility Model Laid-Open No. 1-170929).

【発明が解決しようとする課題】しかしながら、前記従
来の(イ)〜(ハ)の封止方法では、封止先端部におい
て、部材と樹脂被覆との間に空気を含むかあるいは含む
場合が多い。また、部材が熱により変形、変質しやすい
ものである場合には、前記従来の方法では、部材が直接
に熱の悪影響を受けることになる。さらに、特に前記
(イ)及び(ロ)の方法では樹脂が一旦溶解するので、
例えば結晶化しやすい透明な樹脂を使用して封止する場
合には、冷却速度により結晶化度が変化し、透明性を失
なうことがある。特に、前記従来の方法を例えば光ファ
イバーセンサーの封止に適用した場合、先端面の樹脂被
覆との間に空気を含むと、光ファイバーセンサーの屈折
率が変化し光量の損失が大きくなる。また、ファイバー
の融点は熱可塑性樹脂の融点より低い場合が多いので、
ファイバーの熱による変形、変質等の障害を生じやす
い。被覆樹脂が結晶化して透明性を失うと、光ファイバ
ーセンサーとしての機能を果たさなくなる。本発明は、
このような前記従来の問題点を解決して、部材が特定の
機能を持っている場合、例えばセンサーのような場合で
も、その機能を損なうことなく、先端面を持つ部材の先
端部を確実かつ簡易に封止する方法を提供することを目
的とする。
However, in the conventional sealing methods (a) to (c), air is often contained between the member and the resin coating at the sealing tip portion. . In the case where the member is easily deformed or deteriorated by heat, the member is directly affected by the heat in the conventional method. Further, in particular, in the methods (a) and (b), since the resin is once dissolved,
For example, when sealing is performed using a transparent resin that is easily crystallized, the degree of crystallinity changes depending on the cooling rate, and transparency may be lost. In particular, when the above-mentioned conventional method is applied to, for example, sealing of an optical fiber sensor, if air is contained between the optical fiber sensor and the resin coating on the distal end surface, the refractive index of the optical fiber sensor changes and the loss of light quantity increases. Also, since the melting point of the fiber is often lower than the melting point of the thermoplastic resin,
The fiber is liable to cause obstacles such as deformation and deterioration due to heat. If the coating resin crystallizes and loses transparency, it will no longer function as an optical fiber sensor. The present invention
In order to solve the above-mentioned conventional problems, if the member has a specific function, for example, even in the case of a sensor, without impairing the function, the tip of the member having the tip surface can be securely and securely placed. It is an object to provide a method for easily sealing.

【課題を解決するための手段】このような目的を達成す
るため、本発明の封止方法は、部材の先端面以外の表面
に熱可塑性樹脂の被覆を設け、次いで前記被覆の先端部
と、この先端部の周囲形状と同じ形状の熱可塑性樹脂板
とを融着した後、冷却して成る部材先端部の封止方法で
あって、前記被覆の先端部と前記樹脂板との融着を、前
記被覆の先端部より僅かに大きな凹部を有するヒートブ
ロックを加熱し、前記凹部に、凸面断熱スペーサーを凸
面が外向きになるように挿入し、次いで、前記樹脂板を
挿入してその端部を溶融した後、前記被覆を有する部材
の先端部を挿入して前記樹脂板に押圧することにより、
行なうことを特徴とする。本発明の方法により封止する
部材は、先端面とそれ以外の表面を持つ柱状体、筒状体
等の物体であり、先端面が平面あるいはなだらかな凸面
を持つものが好ましい。具体的には、前記形状を持つ透
過型あるいは反射型の光ファイバーセンサー、温度セン
サー等の各種センサー等を挙げることができる。熱可塑
性樹脂の被覆は、部材の先端面以外の表面に、先端から
僅かにはみ出すように設けるのが好ましい。本発明にお
ける熱可塑性樹脂としては、ポリオレフィン樹脂等の公
知の熱可塑性樹脂はいずれも使用することができるが、
耐熱性、耐化学薬品性、透明性等の点から、融点302
〜310℃のテトラフルオロエチレンとパーフルオロア
ルキルビニルエーテルとの共重合体(以下PFAとい
う。)、融点253〜282℃のテトラフルオロエチレ
ンとヘキサフルオロプロピレンとの共重合体等の熱溶融
性フッ素樹脂が好ましい。熱可塑性樹脂板は、樹脂被覆
を有する部材の先端部の周囲形状と同じ形状を持ちかつ
前記熱可塑性樹脂と同じ樹脂の板であり、それより少し
大きいものが好ましい。凸面断熱スペーサーは、凸面を
持ち、かつこの凸面に囲まれる部分に空間が存在するよ
うにしたステンレス鋼(SUS)、アルミニウム等製の
断熱材であり、ヒートブロックの凹部の底からの熱の伝
達を防害するためのものである。ヒートブロックは、凸
面断熱スペーサー、熱可塑性樹脂板、及び部材の先端部
を収容するための凹部を有し、熱可塑性樹脂の融点以上
の温度、好ましくはそれより少し高い温度に加熱する。
ヒートブロックの凹部は部材の先端部等をスムースに挿
入でき、樹脂板と融着でき、かつ部材の先端部と凹部内
周壁との隙間への送風等により融着部を急速に冷却でき
る程度の大きさ、すなわち樹脂被覆を有する部材の先端
部より僅かに大きい程度のものである。
In order to achieve the above object, a sealing method according to the present invention comprises providing a coating of a thermoplastic resin on a surface other than a front end surface of a member, and then, A method of sealing a distal end portion of a member formed by fusing a thermoplastic resin plate having the same shape as the peripheral shape of the distal end portion and then cooling, wherein the fusion between the distal end portion of the coating and the resin plate is performed. Heating a heat block having a recess slightly larger than the tip of the coating, inserting a convex heat insulating spacer into the recess so that the convex surface faces outward, and then inserting the resin plate into the end. After melting, by inserting the tip of the member having the coating and pressing against the resin plate,
It is characterized by performing. The member to be sealed by the method of the present invention is an object such as a columnar body or a cylindrical body having a front end surface and other surfaces, and preferably has a flat front end surface or a gentle convex surface. Specifically, various types of sensors such as a transmission type or reflection type optical fiber sensor having the above-mentioned shape, a temperature sensor, and the like can be mentioned. It is preferable that the coating of the thermoplastic resin is provided on a surface other than the front end surface of the member so as to slightly protrude from the front end. As the thermoplastic resin in the present invention, any known thermoplastic resin such as a polyolefin resin can be used,
In terms of heat resistance, chemical resistance, transparency, etc., the melting point is 302.
A heat-fusible fluororesin such as a copolymer of tetrafluoroethylene and perfluoroalkyl vinyl ether (hereinafter referred to as PFA) at a temperature of 310310 ° C. and a copolymer of tetrafluoroethylene and hexafluoropropylene at a melting point of 253-282 ° C. preferable. The thermoplastic resin plate is a plate having the same shape as the peripheral shape of the distal end portion of the member having the resin coating and the same resin as the thermoplastic resin, and is preferably slightly larger than that. The convex heat insulating spacer is a heat insulating material made of stainless steel (SUS), aluminum, or the like having a convex surface and having a space in a portion surrounded by the convex surface, and transmitting heat from the bottom of the concave portion of the heat block. It is for preventing damage. The heat block has a convex heat insulating spacer, a thermoplastic resin plate, and a concave portion for accommodating the distal end of the member, and heats to a temperature higher than the melting point of the thermoplastic resin, preferably slightly higher.
The concave part of the heat block has such an extent that the tip part of the member can be inserted smoothly, can be fused to the resin plate, and the fused part can be rapidly cooled by blowing air to the gap between the tip part of the member and the inner wall of the concave part. It is of a size that is slightly larger than the tip of the member having the resin coating.

【作用】本発明の方法は、凸面断熱スペーサーを使用し
ているので、ヒートブロックの凹部の内周壁からの熱は
速やかに伝達されるが、凹部の底と凸面との間に空気が
存在し空気の熱伝導率は低いため、凹部の底からの熱の
伝達はおさえられる。そのため、凹部に凸面断熱スペー
サー、次に樹脂板を挿入すると、樹脂板の外周端部がま
ず加熱され、そこから溶融しはじめる。次いで、被覆を
有する部材の先端部を凹部に挿入し樹脂板に押圧する
と、樹脂板はまずその中央部がスペーサーの凸部により
圧迫されて、次いで押圧と共に樹脂板は凸面断熱スペー
サーに沿って変形されて部材先端部との間の空気が確実
に排出されると共に、その端部が部材の被覆先端部と融
着する。また、凹部の底からの熱の伝達がおさえられて
いるため、樹脂板の端部以外の部分は直ちには溶融せ
ず、その透明性は損なわれない。さらに、熱を伝えたく
ない部材の側への熱の伝達もおさえられ、例えばPFA
よりはるかに低い融点の樹脂で被覆されたファイバーな
どの部材構成素材の熱による変形等の障害も防止するこ
とができる。そして、融着後の冷却により、樹脂板の中
央部が溶融する前に、その端部を固めることができるの
で、封止した部材の凹部からの引き上げに支障がなく、
従って、被覆した樹脂の先端面にピンホール等を生じな
い。
In the method of the present invention, the heat from the inner peripheral wall of the concave portion of the heat block is quickly transmitted since the convex heat insulating spacer is used, but air exists between the concave bottom and the convex surface. Since the thermal conductivity of air is low, the transfer of heat from the bottom of the recess is suppressed. Therefore, when the convex heat insulating spacer and then the resin plate are inserted into the concave portion, the outer peripheral end portion of the resin plate is heated first and then starts to melt. Next, when the tip of the member having the coating is inserted into the recess and pressed against the resin plate, the center of the resin plate is first pressed by the convex portion of the spacer, and then the resin plate is deformed along with the convex heat insulating spacer with the pressing. As a result, the air between the member and the tip of the member is reliably discharged, and the end of the member is fused with the coating tip of the member. In addition, since heat transfer from the bottom of the concave portion is suppressed, portions other than the end portion of the resin plate are not immediately melted, and the transparency is not impaired. In addition, the transfer of heat to the side of the member that does not want to transfer heat is also suppressed.
Obstacles such as deformation due to heat of a component material such as fiber coated with a resin having a much lower melting point can also be prevented. And, by cooling after fusion, before the central portion of the resin plate is melted, the end portion can be solidified, so that there is no problem in lifting the sealed member from the concave portion,
Therefore, a pinhole or the like does not occur on the tip surface of the coated resin.

【実施例】以下に、本発明の実施例を図面に基ずいて説
明する。図1は、本発明の一実施例の封止方法を示す断
面図である。図2は、本発明の一実施例の透過型光ファ
イバーセンサーの封止前後を示す部分断面図である。本
実施例では、まず、図2の(A)に示す、先端面が凸面
のガラスレンズ8である透過型光ファイバーセンサー1
に、その外周面を全て覆うようにPFAチューブ2を被
せ、PFAチューブ2の端部を、融着とその際の空気の
排出に支障のないように、先端から僅かにはみ出すよう
整えた。別に、PFA被覆光ファイバーセンサーの先端
部の外径とほぼ同じ外径と凸面とを持ち、かつこの凸面
と水平底面とに囲まれる部分に空間が存在するようにし
た、アルミニウム製の凸面断熱スペーサー3を用意し
た。さらに、PFA被覆光ファイバーセンサーの先端部
の外径とほぼ同じ大きさの外径を持つPFA板4を用意
した。一方、PFA被覆光ファイバーセンサーの外径よ
り僅かに大きい内径の開口部と底部とを持ち、かつ凸面
断熱スペーサー3、PFA板4及びPFA被覆光ファイ
バーセンサーの先端部を収容する深さの凹部5を有する
ヒートブロック6を、バンドヒーター7により、PFA
の融点(302〜310℃)より少し高い温度に加熱し
た。図1に示すように、ヒートブロック6の凹部5に、
凸面断熱スペーサー3を凸面が上向きになるように挿入
し、次いで直ちにPFA板4を挿入した。PFA板4の
外周端部が溶融した時直ちに、PFA被覆光ファイバー
センサーの先端部を凹部5に挿入し、PFA板4に押圧
した。両者の融着面が完全に溶融した時に、凹部5の隙
間に空気を送って、融着部を急速に冷却し固めた。融着
部が完全に固まった後、PFA被覆光ファイバーセンサ
ーを引き上げて、図2の(B)に示すように、光ファイ
バーセンサー1の先端部を完全に封止した。このPFA
により先端部を封止した光ファイバーセンサー1には、
先端被覆面との間に空気溜りがなく、透明でピンホール
も発生していなかった。このようにして封止した被覆先
端部を、必要に応じて表面を切削または研磨仕上げ加工
して製品とすることができる。図3は、本発明の一実施
例の反射型光ファイバーセンサーの封止前後を示す部分
断面図である。封止前の反射型光ファイバーセンサーの
先端部には、ファイバー9が一部露出している。図4
は、本発明の一実施例の熱電対を使用した温度センサー
の封止前後を示す断面図である。なお、本実施例の封止
に使用する熱可塑性樹脂には、熱伝導性充填剤を配合す
ることが好ましい。
Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a sectional view showing a sealing method according to one embodiment of the present invention. FIG. 2 is a partial sectional view showing a transmission type optical fiber sensor according to an embodiment of the present invention before and after sealing. In this embodiment, first, the transmission type optical fiber sensor 1 shown in FIG.
Then, the PFA tube 2 was covered so as to cover the entire outer peripheral surface thereof, and the end of the PFA tube 2 was arranged so as to slightly protrude from the tip so as not to hinder fusion and discharge of air at that time. Separately, a convex heat insulating spacer 3 made of aluminum having an outer diameter and a convex surface substantially the same as the outer diameter of the tip of the PFA-coated optical fiber sensor, and having a space in a portion surrounded by the convex surface and the horizontal bottom surface. Was prepared. Further, a PFA plate 4 having an outer diameter substantially equal to the outer diameter of the tip of the PFA-coated optical fiber sensor was prepared. On the other hand, it has an opening and a bottom having an inner diameter slightly larger than the outer diameter of the PFA-coated optical fiber sensor, and has a convex heat insulating spacer 3, a PFA plate 4, and a concave portion 5 having a depth to accommodate the tip of the PFA-coated optical fiber sensor. The heat block 6 is subjected to PFA by the band heater 7.
(302-310 ° C.). As shown in FIG. 1, in the recess 5 of the heat block 6,
The convex heat insulating spacer 3 was inserted so that the convex surface was directed upward, and then the PFA plate 4 was immediately inserted. Immediately when the outer peripheral edge of the PFA plate 4 was melted, the tip of the PFA-coated optical fiber sensor was inserted into the recess 5 and pressed against the PFA plate 4. When the fused surfaces of both were completely melted, air was sent to the gap of the concave portion 5 to rapidly cool and solidify the fused portion. After the fused portion was completely solidified, the PFA-coated optical fiber sensor was pulled up, and the tip of the optical fiber sensor 1 was completely sealed as shown in FIG. This PFA
The optical fiber sensor 1 whose tip is sealed by
There was no air pocket between the coating surface and the tip, and the coating was transparent and no pinhole was generated. The coated tip portion sealed in this way can be cut or polished as required to produce a product. FIG. 3 is a partial sectional view showing a reflection type optical fiber sensor according to one embodiment of the present invention before and after sealing. The fiber 9 is partially exposed at the tip of the reflective optical fiber sensor before sealing. FIG.
1 is a sectional view showing a temperature sensor using a thermocouple according to an embodiment of the present invention before and after sealing. In addition, it is preferable to mix a thermally conductive filler with the thermoplastic resin used for sealing in the present embodiment.

【発明の効果】以上説明した通り、本発明の方法によ
り、先端面を持つ部材の先端部を確実かつ簡易に封止す
ることができ、さらに封止した先端部が空気を含んだ
り、透明性を失ったり、ピンホールを生じることがな
い。そのため本発明により、例えば光ファイバーセンサ
ー等の特定の機能を持つ部材の先端部を封止すると、そ
の部材の持っている本来的な機能を損なうことなく先端
部を封止することができて、種々の封止目的、例えば耐
薬品性の向上を達成することができる。
As described above, according to the method of the present invention, the distal end of a member having a distal end surface can be reliably and easily sealed, and the sealed distal end contains air or transparency. Loss and no pinholes. Therefore, according to the present invention, for example, when the distal end portion of a member having a specific function such as an optical fiber sensor is sealed, the distal end portion can be sealed without impairing the original function of the member. For sealing purposes, for example, improvement in chemical resistance.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明の一実施例の封止方法を示す断面図で
ある。
FIG. 1 is a sectional view showing a sealing method according to an embodiment of the present invention.

【図2】 本発明の一実施例の透過型光ファイバーセン
サーの封止前後を示す部分断面図である。
FIG. 2 is a partial sectional view showing a transmission type optical fiber sensor according to an embodiment of the present invention before and after sealing.

【図3】 本発明の一実施例の反射型光ファイバーセン
サーの封止前後を示す部分断面図である。
FIG. 3 is a partial sectional view showing a reflection type optical fiber sensor according to an embodiment of the present invention before and after sealing.

【図4】 本発明の一実施例の温度センサーの封止前後
を示す断面図である。
FIG. 4 is a sectional view showing a temperature sensor according to an embodiment of the present invention before and after sealing.

【符合の説明】[Description of sign]

1 透過型光ファイバーセンサー 2 PFAチューブ 3 凸面断熱スぺーサー 4 PFA板 6 ヒートブロック DESCRIPTION OF SYMBOLS 1 Transmission optical fiber sensor 2 PFA tube 3 Convex heat insulating spacer 4 PFA plate 6 Heat block

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 部材の先端面以外の表面に熱可塑性樹脂
の被覆を設け、次いで前記被覆の先端部と、この先端部
の周囲形状と同じ形状の熱可塑性樹脂板とを融着した
後、冷却して成る部材先端部の封止方法であって、 前記被覆の先端部と前記樹脂板との融着を、前記被覆の
先端部より僅かに大きな凹部を有するヒートブロックを
加熱し、前記凹部に、凸面断熱スペーサーを凸面が外向
きになるように挿入し、次いで前記樹脂板を挿入してそ
の端部を溶融した後、前記被覆を有する部材先端部を挿
入して前記樹脂板に押圧することにより、行なうことを
特徴とする前記方法。
Claims: 1. A member is provided with a coating of a thermoplastic resin on a surface other than the tip end surface of a member, and then the tip portion of the coating is fused to a thermoplastic resin plate having the same shape as the peripheral shape of the tip portion. A method of sealing a tip portion of a member formed by cooling, wherein the fusion between the tip portion of the coating and the resin plate is performed by heating a heat block having a recess slightly larger than the tip portion of the coating. Then, a convex heat insulating spacer is inserted so that the convex surface faces outward, and then the resin plate is inserted and its end is melted, and then the tip end of the member having the coating is inserted and pressed against the resin plate. The method as described above.
JP08313892A 1992-03-05 1992-03-05 How to seal the tip of the member Expired - Fee Related JP3297074B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP08313892A JP3297074B2 (en) 1992-03-05 1992-03-05 How to seal the tip of the member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP08313892A JP3297074B2 (en) 1992-03-05 1992-03-05 How to seal the tip of the member

Publications (2)

Publication Number Publication Date
JPH05245932A JPH05245932A (en) 1993-09-24
JP3297074B2 true JP3297074B2 (en) 2002-07-02

Family

ID=13793847

Family Applications (1)

Application Number Title Priority Date Filing Date
JP08313892A Expired - Fee Related JP3297074B2 (en) 1992-03-05 1992-03-05 How to seal the tip of the member

Country Status (1)

Country Link
JP (1) JP3297074B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6436571B1 (en) 1998-03-06 2002-08-20 Rayovac Corporation Bottom seals in air depolarized electrochemical cells

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6436571B1 (en) 1998-03-06 2002-08-20 Rayovac Corporation Bottom seals in air depolarized electrochemical cells
US6461761B1 (en) 1998-03-06 2002-10-08 Rayovac Corporation Air depolarized electrochemical cells

Also Published As

Publication number Publication date
JPH05245932A (en) 1993-09-24

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