JP3252974B2 - Method for producing organic resin having electromagnetic wave absorbing material - Google Patents

Method for producing organic resin having electromagnetic wave absorbing material

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Publication number
JP3252974B2
JP3252974B2 JP33075391A JP33075391A JP3252974B2 JP 3252974 B2 JP3252974 B2 JP 3252974B2 JP 33075391 A JP33075391 A JP 33075391A JP 33075391 A JP33075391 A JP 33075391A JP 3252974 B2 JP3252974 B2 JP 3252974B2
Authority
JP
Japan
Prior art keywords
electromagnetic wave
absorbing material
wave absorbing
organic resin
insulating substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP33075391A
Other languages
Japanese (ja)
Other versions
JPH05167341A (en
Inventor
登 岩崎
文則 石塚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Telegraph and Telephone Corp
Original Assignee
Nippon Telegraph and Telephone Corp
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Filing date
Publication date
Application filed by Nippon Telegraph and Telephone Corp filed Critical Nippon Telegraph and Telephone Corp
Priority to JP33075391A priority Critical patent/JP3252974B2/en
Publication of JPH05167341A publication Critical patent/JPH05167341A/en
Application granted granted Critical
Publication of JP3252974B2 publication Critical patent/JP3252974B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、電磁波吸収材料を有す
る有機樹脂製造方法に関する。
The present invention relates to a method for manufacturing an organic resin having electromagnetic wave absorbing material.

【0002】[0002]

【従来の技術】図は従来の粉末状の電磁波吸収材料を
有する有機樹脂の構造とその製造方法を表した図であ
る。従来の粉末状の電磁波吸収材料を有する有機樹脂に
関しては、フェライト粉末を含んだ有機樹脂、あるいは
カーボン粉末を含んだ有機樹脂等がある。これらの有機
樹脂の構造は、粉末状の電磁波吸収材料の分布密度がほ
ぼ一様な構造である。また、これらの有機樹脂の製造方
法として、図に示すように、あらかじめ粉末状の電磁
波吸収材料602が含まれた液状あるいはフィルム状の
有機樹脂603を任意の絶縁体基板601上に塗布し、
加熱硬化することにより製造する方法が取られている。
2. Description of the Related Art FIG. 5 is a view showing a structure of a conventional organic resin having a powdery electromagnetic wave absorbing material and a method of manufacturing the same. As the conventional organic resin having a powdery electromagnetic wave absorbing material, there is an organic resin containing ferrite powder, an organic resin containing carbon powder, and the like. The structure of these organic resins is a structure in which the distribution density of the powdery electromagnetic wave absorbing material is substantially uniform. As a method for manufacturing these organic resins, as shown in FIG. 5 , a liquid or film-like organic resin 603 containing a powdered electromagnetic wave absorbing material 602 in advance is applied onto an arbitrary insulator substrate 601 and
A method of manufacturing by heating and curing is employed.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来の
粉末状の電磁波吸収材料を有する有機樹脂においては、
該電磁波吸収材料の分布密度がほぼ一様であるため、該
有機樹脂の電磁波吸収特性は樹脂全体にわたってほぼ一
様である。したがって、有機樹脂内において異なる周波
数領域の電磁波吸収特性を示す部分を実現する場合、あ
るいは、同一の周波数領域の電磁波吸収量が異なる部分
を実現する場合には、異なる電磁波吸収特性を示す少な
くとも2種類以上の有機樹脂を張り合わせるか、あるい
は、積層しなければならない。したがって、製造工程が
増加し、煩雑となるだけでなく、これらに要する費用も
多大になるという問題点があった。さらには、装置の小
型化に適さないという問題点があった。
However, in the conventional organic resin having a powdery electromagnetic wave absorbing material,
Since the distribution density of the electromagnetic wave absorbing material is substantially uniform, the electromagnetic wave absorbing characteristics of the organic resin are substantially uniform throughout the resin. Therefore, when realizing portions exhibiting electromagnetic wave absorption characteristics in different frequency regions within the organic resin, or realizing portions having different amounts of electromagnetic wave absorption in the same frequency region, at least two types exhibiting different electromagnetic wave absorption characteristics are used. The above organic resins must be laminated or laminated. Therefore, there is a problem that not only the number of manufacturing steps is increased and complicated, but also the cost required for these is increased. Further, there is a problem that the apparatus is not suitable for miniaturization.

【0004】本発明の目的は、電磁波吸収材料の分布密
度を変化させた有機樹脂実現するための簡便な製造方
法を提案することにある。
[0004] It is an object of the present invention to provide a distribution density of electromagnetic wave absorbing material .
It is to propose a simple manufacturing method for realizing the organic resin of varying degrees.

【0005】[0005]

【0006】[0006]

【0007】[0007]

【0008】[0008]

【課題を解決するための手段】 発明は、任意の絶縁体
基板上に液状の有機樹脂の上方より、粉末状の電磁波吸
収材料を噴射し、該絶縁体基板と該電磁波吸収材料との
間に、電場あるいは磁場を印加することにより、該電磁
波吸収材料の噴射軌跡を制御し、液状の有機樹脂内へ到
達する時の材料の分布密度を変化させ、しかる後に、加
熱硬化させることを特徴とする電磁波吸収材料を有する
有機樹脂の製造方法である
According to the present invention, a powdery electromagnetic wave absorbing material is sprayed onto an arbitrary insulating substrate from above a liquid organic resin, and a gap between the insulating substrate and the electromagnetic wave absorbing material is formed. In addition, by applying an electric or magnetic field, the injection trajectory of the electromagnetic wave absorbing material is controlled, the distribution density of the material when reaching the liquid organic resin is changed, and then, the material is cured by heating. This is a method for producing an organic resin having an electromagnetic wave absorbing material .

【0009】更に、本発明は、任意の絶縁体基板の上方
より、粉末状の有機樹脂と粉末状の電磁波吸収材料を噴
射し、該絶縁体基板と該電磁波吸収材料との間に、電場
あるいは磁場を印加することにより、該電磁波吸収材料
の噴射軌跡を制御し、絶縁体基板上へ該有機樹脂と該電
磁波吸収材料を積層させ、該有機樹脂に対する電磁波吸
収材料の分布密度を変化させ、しかる後に、加熱硬化さ
せることを特徴とする電磁波吸収材料を有する有機樹脂
の製造方法である。
Further, according to the present invention, a powdery organic resin and a powdery electromagnetic wave absorbing material are sprayed from above an arbitrary insulating substrate, and an electric field or an electromagnetic field is applied between the insulating substrate and the electromagnetic wave absorbing material. By applying a magnetic field, the injection trajectory of the electromagnetic wave absorbing material is controlled, the organic resin and the electromagnetic wave absorbing material are laminated on an insulating substrate, and the distribution density of the electromagnetic wave absorbing material with respect to the organic resin is changed. This is a method for producing an organic resin having an electromagnetic wave absorbing material, which is characterized in that the organic resin is heated and cured later.

【0010】なわち、本発明では絶縁体基板上に形
成した粉末状の電磁波吸収材料を有する有機樹脂の製造
において、電場あるいは磁場を印加することにより、該
有機樹脂内における該電磁波吸収材料の分布密度を変化
させ、所望の電磁波吸収特性を示す有機樹脂の構造とす
ることにより、上記問題点の解決を図っている。
[0010] ie, in the present invention is a manufacturing <br/> organic resin having a powdered electromagnetic wave absorption material formed on an insulating substrate, by applying an electric field or a magnetic field, in the organic the resin The above-mentioned problem is solved by changing the distribution density of the electromagnetic wave absorbing material to obtain a structure of an organic resin exhibiting desired electromagnetic wave absorbing characteristics.

【0011】[0011]

【実施例】以下、本発明を実施例により更に具体的に説
明するが、本発明はこれら実施例に限定されない。実施例1 図1は本発明による粉末状の電磁波吸収材料を有する有
機樹脂の構造を示した図であって、任意の絶縁体基板1
01上に形成された有機樹脂103内における粉末状の
電磁波吸収材料102の分布密度が曲線104に示すよ
うに連続的に変化した有機樹脂の構造である。
EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples. Embodiment 1 FIG. 1 is a view showing a structure of an organic resin having a powdery electromagnetic wave absorbing material according to the present invention, and shows an arbitrary insulating substrate 1.
This is a structure of the organic resin in which the distribution density of the powdery electromagnetic wave absorbing material 102 in the organic resin 103 formed on the substrate 01 changes continuously as shown by a curve 104.

【0012】以下に、この構造を実現するための製造方
法例について述べる
Hereinafter, an example of a manufacturing method for realizing this structure will be described .

【0013】・製造方法例1は、図1に示された構造を実現するための第の製
造方法例を表した図である。液状の有機樹脂403を塗
布した任意の絶縁体基板401((a)参照)の上方よ
り、粉末状の電磁波吸収材料402を噴射する。ここ
で、電磁波吸収材料402は負に帯電しているものとす
る。この時、絶縁体基板401と電磁波吸収材料402
との間に、電磁波吸収材料402の分布密度を変化させ
る方向と平行に電場Eを印加することにより、電磁波吸
収材料402の噴射軌跡を電場Eの正の方向へ移動する
ように制御する((b)参照)。あるいは、電磁波吸収
材料402の分布密度を変化させる方向と垂直に磁場H
を印加することにより、電磁波吸収材料402の噴射軌
跡を紙面の表から裏へ印加された磁場Hと垂直な方向へ
移動するように制御する((b)参照)。これにより、
液状の有機樹脂403へ到達した時の電磁波吸収材料4
02の分布密度が連続的に変化し((c)参照)、しか
る後に有機樹脂403を加熱硬化させることにより、所
望の電磁波吸収特性分布を示す有機樹脂を製造する。こ
の方法により形成した有機樹脂の電磁波吸収特性は曲線
408に示される通りである((d)参照)。
[0013] and manufacturing method Example 1 FIG. 3 is a diagram showing a first manufacturing method example for realizing the structure shown in FIG. A powdery electromagnetic wave absorbing material 402 is sprayed from above an arbitrary insulating substrate 401 (see (a)) coated with a liquid organic resin 403. Here, it is assumed that the electromagnetic wave absorbing material 402 is negatively charged. At this time, the insulator substrate 401 and the electromagnetic wave absorbing material 402
By applying the electric field E in parallel with the direction in which the distribution density of the electromagnetic wave absorbing material 402 is changed, the injection trajectory of the electromagnetic wave absorbing material 402 is controlled to move in the positive direction of the electric field E ((( b)). Alternatively, the magnetic field H is perpendicular to the direction in which the distribution density of the electromagnetic wave absorbing material 402 is changed.
Is controlled so as to move the ejection trajectory of the electromagnetic wave absorbing material 402 in a direction perpendicular to the magnetic field H applied from the front to the back of the paper (see (b)). This allows
Electromagnetic wave absorbing material 4 when it reaches liquid organic resin 403
02 continuously changes (see (c)), and then the organic resin 403 is cured by heating to produce an organic resin having a desired electromagnetic wave absorption characteristic distribution. The electromagnetic wave absorption characteristics of the organic resin formed by this method are as shown by a curve 408 (see (d)).

【0014】なお、電磁波吸収材料402が正に帯電し
ている場合には、電場Eあるいは磁場Hをそれぞれ逆の
方向に印加すれば、曲線408で示される特性が得られ
る。 ・製造方法例2は、図1に示された構造を実現するための第の製
造方法例を表した図である。任意の絶縁体基板501の
上方より、粉末状の有機樹脂513と粉末状の電磁波吸
収材料502を噴射する。ここで、電磁波吸収材料50
2は負に帯電し、また有機樹脂513は電気的に中性で
あるものとする。この時、絶縁体基板501と電磁波吸
収材料502との間に、電磁波吸収材料502の分布密
度を変化させる方向と平行に電場Eを印加することによ
り、電磁波吸収材料502の噴射軌跡を電場Eの正の方
向へ移動するように制御する((a)参照)。あるい
は、電磁波吸収材料502の分布密度を変化させる方向
と垂直に磁場Hを印加することにより、電磁波吸収材料
502の噴射軌跡を紙面の表から裏へ印加された磁場H
と垂直な方向へ移動するように制御する((a)参
照)。これにより、絶縁体基板501上へ有機樹脂51
3と電磁波吸収材料502が積層し、有機樹脂511に
対する電磁波吸収材料502の分布密度が連続的に変化
し((b)参照)、しかる後に有機樹脂511を加熱硬
化させることにより所望の電磁波吸収特性分布を示す有
機樹脂を製造する。この方法により形成した有機樹脂の
電磁波吸収特性は曲線508に示される通りである
((c)参照)。実施例2 図2は本発明による粉末状の電磁波吸収材料を有する有
機樹脂の他の構造を示した図であって、任意の絶縁体基
板201上に形成された有機樹脂203内における粉末
状の電磁波吸収材料202が有機樹脂203の平面内に
おいて部分的に分布している有機樹脂の構造である。図
2において、A−B間における電磁波吸収材料202の
分布密度は曲線204に示される通りである。
When the electromagnetic wave absorbing material 402 is positively charged, the characteristics shown by the curve 408 can be obtained by applying the electric field E or the magnetic field H in opposite directions. And manufacturing method Example 2 FIG. 4 is a diagram showing a second manufacturing method example for realizing the structure shown in FIG. A powdery organic resin 513 and a powdery electromagnetic wave absorbing material 502 are sprayed from above an arbitrary insulator substrate 501. Here, the electromagnetic wave absorbing material 50
2 is negatively charged, and the organic resin 513 is electrically neutral. At this time, by applying an electric field E between the insulator substrate 501 and the electromagnetic wave absorbing material 502 in a direction parallel to the direction in which the distribution density of the electromagnetic wave absorbing material 502 is changed, the ejection trajectory of the electromagnetic wave absorbing material 502 is changed. Control is performed so as to move in the positive direction (see (a)). Alternatively, by applying a magnetic field H perpendicular to the direction in which the distribution density of the electromagnetic wave absorbing material 502 is changed, the ejection trajectory of the electromagnetic wave absorbing material 502 can be changed from the front to the back of the paper.
Is controlled so as to move in a direction perpendicular to the direction (see (a)). Thereby, the organic resin 51 is deposited on the insulator substrate 501.
3 and the electromagnetic wave absorbing material 502 are laminated, and the distribution density of the electromagnetic wave absorbing material 502 with respect to the organic resin 511 changes continuously (see (b)). Thereafter, the organic resin 511 is heated and cured to obtain desired electromagnetic wave absorbing characteristics. An organic resin exhibiting distribution is produced. The electromagnetic wave absorption characteristics of the organic resin formed by this method are as shown by a curve 508 (see (c)). Example 2 FIG. 2 is a view showing another structure of an organic resin having a powdery electromagnetic wave absorbing material according to the present invention, and shows a powdery organic resin 203 formed on an arbitrary insulating substrate 201. This is a structure of the organic resin in which the electromagnetic wave absorbing material 202 is partially distributed in the plane of the organic resin 203. In FIG. 2, the distribution density of the electromagnetic wave absorbing material 202 between A and B is as shown by a curve 204.

【0015】この構造を実現するための製造方法につい
て述べると、実施例1の製造方法例およびとほぼ同
様で、粉末状の電磁波吸収材料202の分布密度を部分
的にするため、電磁波吸収材料202の噴射源をノズル
状として数カ所に限定するか、あるいは、絶縁体基板上
あるいはその上方へ電磁波吸収材料202の分布密度に
対応したマスクを設けた後、噴射を行えばよい。
The manufacturing method for realizing this structure is substantially the same as the manufacturing methods 1 and 2 of the first embodiment, and the distribution density of the powdery electromagnetic wave absorbing material 202 is partially reduced. Therefore, the injection source of the electromagnetic wave absorbing material 202 may be limited to a few nozzles, or a mask corresponding to the distribution density of the electromagnetic wave absorbing material 202 may be provided on or above the insulating substrate, and then the injection may be performed. .

【0016】[0016]

【発明の効果】以上説明したように、本発明によれば、
粉末状の電磁波吸収材料を有する有機樹脂を1種類だけ
用いて、有機樹脂内において異なる周波数領域の電磁波
吸収特性を示す部分、あるいは、同一の周波数領域の電
磁波吸収量が異なる部分を一回の製造工程により実現す
ることができる。さらに、製造に要する費用も低減し、
装置の小型化にも適する。
As described above, according to the present invention,
Using only one type of organic resin having a powdery electromagnetic wave absorbing material, manufacturing a part of the organic resin that shows electromagnetic wave absorption characteristics in different frequency ranges or a part with the same amount of electromagnetic wave absorption in the same frequency range It can be realized by a process. In addition, manufacturing costs are reduced,
Also suitable for miniaturization of equipment.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に係る粉末状の電磁波吸収材料を有する
有機樹脂の構造の一例を示す概念図である。
FIG. 1 is a conceptual diagram showing an example of the structure of an organic resin having a powdery electromagnetic wave absorbing material according to the present invention.

【図2】本発明に係る粉末状の電磁波吸収材料を有する
有機樹脂の構造の他の例を示す概念図である。
FIG. 2 is a conceptual diagram showing another example of the structure of an organic resin having a powdery electromagnetic wave absorbing material according to the present invention.

【図3】図1に示す構造を実現するための第1の製造方
法例を示す説明図である。
FIG. 3 is an explanatory view showing a first example of a manufacturing method for realizing the structure shown in FIG. 1;

【図4】図1に示す構造を実現するための第2の製造方
法例を示す説明図である。
FIG. 4 is an explanatory view showing a second example of a manufacturing method for realizing the structure shown in FIG. 1;

【図5】従来の粉末状の電磁波吸収材料を有する有機樹
脂の構造とその製造方法を示す概念図である。
FIG. 5 shows a conventional organic tree having a powdery electromagnetic wave absorbing material.
It is a conceptual diagram which shows the structure of fat and its manufacturing method.

【符号の説明】[Explanation of symbols]

101,201401,501,601 絶縁体基
板 102,202402,502,602 粉末状の
電磁波吸収材料 103,203403,603 液状の有機樹脂 513 粉末状の有機樹脂 104,204 粉末状の電磁波吸収材料の分布密度
を表す曲線 08,508 電磁波吸収特性を表す曲線
101 , 201 , 401 , 501 , 601 Insulating substrate 102 , 202 , 402 , 502 , 602 Powdered electromagnetic wave absorbing material 103 , 203 , 403 , 603 Liquid organic resin 513 Powdered organic resin 104, 204 Powdered curve representing the curve 4 08,508 electromagnetic wave absorption characteristics representing the distribution density of the electromagnetic wave absorbing material

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平2−91997(JP,A) 特開 昭63−141397(JP,A) 特開 平3−217082(JP,A) 特開 昭59−230714(JP,A) 特開 平2−254798(JP,A) 特開 昭62−112400(JP,A) 特開 平3−259599(JP,A) 特開 昭61−189699(JP,A) 特開 平1−220899(JP,A) 特開 昭56−53156(JP,A) 特開 昭54−53148(JP,A) 特開 平3−44100(JP,A) 特開 平1−292896(JP,A) 特開 平2−55129(JP,A) 特開 昭59−110199(JP,A) 実開 昭64−13197(JP,U) (58)調査した分野(Int.Cl.7,DB名) H01Q 17/00 B32B 7/02 104 C09D 5/00 - 5/32 H05K 9/00 H01F 1/12 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-2-91997 (JP, A) JP-A-63-141397 (JP, A) JP-A-3-217082 (JP, A) JP-A-59-1984 230714 (JP, A) JP-A-2-254798 (JP, A) JP-A-62-112400 (JP, A) JP-A-3-259599 (JP, A) JP-A-61-189699 (JP, A) JP-A-1-220899 (JP, A) JP-A-56-53156 (JP, A) JP-A-54-53148 (JP, A) JP-A-3-44100 (JP, A) JP-A-1-292896 (JP, A) JP-A-2-55129 (JP, A) JP-A-59-110199 (JP, A) JP-A-64-13197 (JP, U) (58) Fields investigated (Int. Cl. 7) , DB name) H01Q 17/00 B32B 7/02 104 C09D 5/00-5/32 H05K 9/00 H01F 1/12

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 任意の絶縁体基板上に液状の有機樹脂の
上方より、粉末状の電磁波吸収材料を噴射し、該絶縁体
基板と該電磁波吸収材料との間に、電場あるいは磁場を
印加することにより、該電磁波吸収材料の噴射軌跡を制
御し、液状の有機樹脂内へ到達する時の材料の分布密度
を変化させ、しかる後に、加熱硬化させることを特徴と
する電磁波吸収材料を有する有機樹脂の製造方法。
1. An electromagnetic wave absorbing material in a powder form is sprayed onto an arbitrary insulating substrate from above a liquid organic resin, and an electric field or a magnetic field is applied between the insulating substrate and the electromagnetic wave absorbing material. By controlling the ejection trajectory of the electromagnetic wave absorbing material, changing the distribution density of the material when it reaches the liquid organic resin, and thereafter, heating and curing, the organic resin having the electromagnetic wave absorbing material Manufacturing method.
【請求項2】 任意の絶縁体基板の上方より、粉末状の
有機樹脂と粉末状の電磁波吸収材料を噴射し、該絶縁体
基板と該電磁波吸収材料との間に、電場あるいは磁場を
印加することにより、該電磁波吸収材料の噴射軌跡を制
御し、絶縁体基板上へ該有機樹脂と該電磁波吸収材料を
積層させ、該有機樹脂に対する電磁波吸収材料の分布密
度を変化させ、しかる後に、加熱硬化させることを特徴
とする電磁波吸収材料を有する有機樹脂の製造方法。
2. A powdery organic resin and a powdery electromagnetic wave absorbing material are sprayed from above an arbitrary insulating substrate, and an electric field or a magnetic field is applied between the insulating substrate and the electromagnetic wave absorbing material. By controlling the ejection trajectory of the electromagnetic wave absorbing material, the organic resin and the electromagnetic wave absorbing material are laminated on an insulating substrate, the distribution density of the electromagnetic wave absorbing material with respect to the organic resin is changed, and then, heat curing is performed. A method for producing an organic resin having an electromagnetic wave absorbing material.
JP33075391A 1991-12-13 1991-12-13 Method for producing organic resin having electromagnetic wave absorbing material Expired - Fee Related JP3252974B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33075391A JP3252974B2 (en) 1991-12-13 1991-12-13 Method for producing organic resin having electromagnetic wave absorbing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33075391A JP3252974B2 (en) 1991-12-13 1991-12-13 Method for producing organic resin having electromagnetic wave absorbing material

Publications (2)

Publication Number Publication Date
JPH05167341A JPH05167341A (en) 1993-07-02
JP3252974B2 true JP3252974B2 (en) 2002-02-04

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Family Applications (1)

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Country Status (1)

Country Link
JP (1) JP3252974B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5493132B2 (en) * 2010-12-07 2014-05-14 防衛省技術研究本部長 Radio wave absorber and design method thereof
EP4350442A2 (en) * 2018-08-21 2024-04-10 Laird Technologies, Inc. Patterned materials and films and systems and methods for making the same
CN109906028A (en) * 2019-04-26 2019-06-18 南京大学 A kind of wave absorbing patch and preparation method thereof

Also Published As

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