JP3252166B2 - Exhaust gas treatment equipment - Google Patents
Exhaust gas treatment equipmentInfo
- Publication number
- JP3252166B2 JP3252166B2 JP11410491A JP11410491A JP3252166B2 JP 3252166 B2 JP3252166 B2 JP 3252166B2 JP 11410491 A JP11410491 A JP 11410491A JP 11410491 A JP11410491 A JP 11410491A JP 3252166 B2 JP3252166 B2 JP 3252166B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- fluidized bed
- exhaust gas
- bed reactor
- dispersion plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Description
【0001】[0001]
【産業上の利用分野】 本発明は、エンジン排ガスの処
理装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an engine exhaust gas treatment device.
【0002】[0002]
【従来技術とその課題】 例えば、ディーゼルエンジン
の排ガス中に含まれる窒素酸化物(NOx)と煤塵を除
去するための脱硝,脱塵装置は知られている。この脱硝
装置とは、触媒充填層に排ガスを通し、触媒反応により
NOxを除去する装置である。この種の脱硝装置として
は、固定層反応器と重力場の流動層反応器などが知られ
ている。(例えば、特開昭52−131970公報参
照)2. Description of the Related Art For example, a denitration and dedusting apparatus for removing nitrogen oxides (NOx) and dust contained in exhaust gas of a diesel engine is known. This denitration apparatus is an apparatus that passes exhaust gas through a catalyst packed bed and removes NOx by a catalytic reaction. As this type of denitration apparatus, a fixed bed reactor and a fluidized bed reactor in a gravitational field are known. (See, for example, JP-A-52-131970)
【0003】前者の固定層反応器には、エンジン排ガス
中に含まれている煤塵により反応器が目詰まりをおこ
し、処理能率が著しく阻害されること、触媒が劣化した
場合運転中に触媒の交換ができないなどの課題がある。[0003] In the former fixed-bed reactor, dust contained in engine exhaust gas causes clogging of the reactor, which significantly impairs the processing efficiency. There are issues such as not being able to do.
【0004】後者の重力場の流動層反応器には、エンジ
ンの負荷変化による排ガス量の変化に対応できないとい
う不都合があり、また、触媒の流動化可能なガス線速度
をうるには、分散板の面積を大きくしなければならない
ため、装置が大型化するという課題がある。The latter fluidized bed reactor in a gravitational field has a disadvantage that it cannot cope with a change in the amount of exhaust gas due to a change in engine load. Since the area of the device must be increased, there is a problem that the device becomes larger.
【0005】本発明の目的は、流動層反応器を遠心流動
層とすることにより、大きな流動化ガス線速度を得、排
ガス処理量を大きくし、装置全体の小型化が図れるとと
もに、触媒の自動供給、および、劣化触媒の自動排出を
行わせ、排ガスの脱硝反応などが高能率的に行える排ガ
スの処理装置を提供することにある。It is an object of the present invention to obtain a large fluidized gas linear velocity by using a fluidized bed reactor as a centrifugal fluidized bed, to increase the amount of exhaust gas to be treated, to reduce the size of the entire apparatus, and to automatically use a catalyst. supply and to perform the automatic ejection of the deteriorated catalyst, waste gas etc. exhaust gas denitration reaction can be performed with high efficient
And to provide a scan of the processor.
【0006】[0006]
【課題を解決するための手段】 上記目的は、エンジン
排ガスの被処理気体の導入外筒内に、円筒状の分散板を
有し、この分散板の中心軸線にそった排気管を一方端側
にもつ円筒形構造の流動層反応器を回転駆動可能に設
け、該流動層反応器の中心部に円筒状のフィルターを設
け、該フィルターと分散板間の空洞に触媒を入れ、上記
流動層反応器の他方端側に上記排気管と同一軸線の触媒
供給管を接続するとともに、この触媒供給管の反対側に
設けられ、かつ、仕切板によって排ガス導入側とは仕切
られた流動層反応器部位に触媒排出流路を設け、これに
流動層反応器に設けた触媒の排出口を連通させたことに
より達成される。Means for Solving the Problems The object of the present invention is to provide an engine
A cylindrical fluidized-bed reactor having a cylindrical dispersion plate inside the outer cylinder for introducing the gas to be treated of exhaust gas and having an exhaust pipe at one end along the central axis of the dispersion plate can be driven to rotate. And a cylindrical filter in the center of the fluidized bed reactor.
Then, a catalyst is put in the cavity between the filter and the dispersion plate, and a catalyst supply pipe having the same axis as the exhaust pipe is connected to the other end of the fluidized bed reactor, and a catalyst supply pipe is provided on the opposite side of the catalyst supply pipe. This is achieved by providing a catalyst discharge flow path at a fluidized bed reactor section separated from the exhaust gas introduction side by a partition plate, and communicating the catalyst discharge port provided in the fluidized bed reactor with the catalyst discharge flow path.
【0007】[0007]
【実施例】 次に、図面について本発明実施例の詳細を
説明する。図1は縦断正面図、図2は別実施例の縦断正
面図、図3は分散板をテーパー状とした実施例の縦断正
面図である。Next, details of an embodiment of the present invention will be described with reference to the drawings. FIG. 1 is a longitudinal sectional front view, FIG. 2 is a longitudinal sectional front view of another embodiment, and FIG. 3 is a longitudinal sectional front view of an embodiment having a tapered dispersion plate.
【0008】図1の実施例についてその構成を説明する
と、1は円筒状の分散板2を有し、これの両側に端板
3,4を結合して形成せる円筒構造の流動層反応器であ
る。上記一方の端板3の中心部には軸筒5が固定してあ
り、この軸筒5の内側にはこの軸筒5の軸線と直交する
触媒6の供給流路5aが一体に形成されている。また、
上記他方の端板4の中心部には、上記軸筒5の中心軸線
と軸線が一致する排気管7の一端が固定されている。図
中8はフリーボードに設けられ、かつ、上記軸筒5,排
気管7と軸線を同じくした円筒構造のフィルターで、粉
化した触媒6やダストの排出を抑制するようにしたもの
である。The structure of the embodiment shown in FIG. 1 will be described. Reference numeral 1 denotes a fluidized bed reactor having a cylindrical structure in which a cylindrical dispersion plate 2 is formed by connecting end plates 3 and 4 to both sides thereof. is there. A shaft cylinder 5 is fixed to the center of the one end plate 3, and a supply flow path 5 a for a catalyst 6 orthogonal to the axis of the shaft cylinder 5 is integrally formed inside the shaft cylinder 5. I have. Also,
At the center of the other end plate 4, one end of an exhaust pipe 7 whose axis coincides with the central axis of the barrel 5 is fixed. In the figure, reference numeral 8 denotes a filter provided on the free board and having a cylindrical structure having the same axis as the shaft cylinder 5 and the exhaust pipe 7 to suppress the discharge of the powdered catalyst 6 and dust.
【0009】9は上記触媒6のホッパー(図示略)に連
設された触媒供給管で、この触媒供給管9の下部には水
平姿勢の触媒溜9aを一体に形成するとともに、この触
媒溜9aに軸受け10を介して上記軸筒5を回動可能に
軸支せしめる。また、上記触媒6の供給流路5aと離反
した端板4の一側に、触媒6の排出口11を設ける。こ
の排出口11は触媒流動層中に開口される。Reference numeral 9 denotes a catalyst supply pipe connected to a hopper (not shown) of the catalyst 6, and a lower part of the catalyst supply pipe 9 is integrally formed with a horizontal catalyst reservoir 9a. The shaft cylinder 5 is rotatably supported via a bearing 10. Further, a discharge port 11 for the catalyst 6 is provided on one side of the end plate 4 away from the supply flow path 5a of the catalyst 6. This outlet 11 is opened in the catalyst fluidized bed.
【0010】12は、上記流動層反応器1より径大で、
かつ、該流動層反応器1全体と、上記排気管7の一部、
および、触媒溜9aの一部を被覆するように形成した排
ガスの導入外筒で、該導入外筒12の一側には、エンジ
ンの排気管(図示略)に直結される排ガス導入管13が
設けてある。Numeral 12 is larger in diameter than the fluidized bed reactor 1 and
And the entire fluidized bed reactor 1 and a part of the exhaust pipe 7,
An exhaust gas introduction tube formed so as to cover a part of the catalyst reservoir 9a, and an exhaust gas introduction tube 13 directly connected to an exhaust pipe (not shown) of the engine is provided on one side of the introduction tube 12. It is provided.
【0011】また、上記流動層反応器1を構成する一方
の端板4側の導入外筒12には、仕切板14によって排
ガス導入側とは仕切られた触媒排出流路15が形成され
ており、この触媒排出流路15に上記触媒6の排出口1
1が連通している。上記仕切板14と、上記触媒排出流
路15を構成する外側板12aとに、夫々軸受け16,
17を介して分散板2の一側縁部、排気管7の基部が回
動可能、即ち、上記流動層反応器1は導入外筒12に対
し3点で回動可能に支持される。In addition, a catalyst discharge flow path 15 is formed in the introduction outer cylinder 12 on one end plate 4 side of the fluidized bed reactor 1 which is separated from the exhaust gas introduction side by a partition plate 14. The exhaust port 1 of the catalyst 6 is provided in the catalyst exhaust passage 15.
1 is in communication. The partition plate 14 and the outer plate 12a constituting the catalyst discharge channel 15 are respectively provided with bearings 16,
One side edge of the dispersion plate 2 and the base of the exhaust pipe 7 are rotatable via 17, that is, the fluidized bed reactor 1 is rotatably supported at three points with respect to the introduction outer cylinder 12.
【0012】また、上記排ガスの導入外筒12や流動層
反応器1は、分解可能に構成し、フィルター8の交換,
清掃などのメンテナンスが行えるようにすることは当然
である。尚、流動層反応器1を回動駆動する手段とし
て、上記排気管7にプーリー(図示略)を設け、これに
駆動伝達機構や減速機構を介してエンジンの回転軸に接
続させ、エンジンの回転数に対応した回転が流動層反応
器1に与えられるようにする。The outer cylinder 12 for introducing exhaust gas and the fluidized bed reactor 1 are configured to be decomposable, and the filter 8 can be replaced.
Naturally, maintenance such as cleaning can be performed. As means for rotating and driving the fluidized bed reactor 1, a pulley (not shown) is provided on the exhaust pipe 7, and connected to the rotation shaft of the engine via a drive transmission mechanism and a speed reduction mechanism. The rotation corresponding to the number is provided to the fluidized bed reactor 1.
【0013】次に、上記実施例の作用を説明すると、エ
ンジンが始動されると、その回転駆動は減速機構や駆動
伝達機構を介して排気管7が駆動されるとともに、流動
層反応器1を回転する。この流動層反応器1内に収容せ
る触媒6は遠心力により分散板2の内面に張りつくよう
に流動せしめられ、一方、エンジンの始動と同時に排ガ
スは非ガス導入管13が導入外筒12内に導入され、エ
ンジンによるガス圧によって排ガスは分散板2を通って
内部に入り、触媒6を流動しながら排ガスは触媒と接触
反応し、例えば、脱硝反応が行われる。Next, the operation of the above embodiment will be described. When the engine is started, its rotation is driven by the exhaust pipe 7 via a speed reduction mechanism or a drive transmission mechanism, and the fluidized bed reactor 1 is driven. Rotate. The catalyst 6 accommodated in the fluidized bed reactor 1 is caused to flow by the centrifugal force so as to stick to the inner surface of the dispersion plate 2. The exhaust gas enters the interior through the dispersion plate 2 due to the gas pressure of the engine, and the exhaust gas contacts and reacts with the catalyst while flowing through the catalyst 6, for example, a denitration reaction is performed.
【0014】脱硝反応により浄化された排ガスは、フィ
ルター8を通って排気管7より外部に放出される。ま
た、分散板2の孔径をダスト(未燃炭素)が詰らないよ
うに小径とするときは、特に図示してないが、分散板2
の外面に付着、または、付着しようとするダストをスク
レーパーによってかき落し、導入外筒12の下部に設け
たダスト回収部に捕集する。また、分散板2にダストの
通過を許す比較的大径の孔を形成した場合には、流動層
内で集塵し、集塵したダストは排ガスと反応し脱硝が可
能となる。The exhaust gas purified by the denitration reaction is discharged to the outside through an exhaust pipe 7 through a filter 8. Although not shown, when the pore size of the dispersion plate 2 is made small so as not to be clogged with dust (unburned carbon), the dispersion plate 2
The dust adhering to or adhering to the outer surface of the introductory member is scraped off by a scraper and collected in a dust collecting portion provided at a lower portion of the introduction outer cylinder 12. When a relatively large hole is formed in the dispersion plate 2 to allow the passage of dust, the dust is collected in the fluidized bed, and the collected dust reacts with exhaust gas to enable denitration.
【0015】一方、触媒供給管9の触媒溜9aにある触
媒6は、遠心力の作用で軸筒5の供給流路5aを経て流
動層に供給される。また、反応により劣化し粉状化した
触媒6は、排出口11からとび出し、触媒排出流路15
を経て回収せしめられる。On the other hand, the catalyst 6 in the catalyst reservoir 9a of the catalyst supply pipe 9 is supplied to the fluidized bed through the supply flow path 5a of the barrel 5 by the action of centrifugal force. Further, the catalyst 6 that has been deteriorated and powdered by the reaction jumps out of the outlet 11, and becomes a catalyst discharge channel 15.
Can be recovered through
【0016】図2に示す実施例は、図1に示した触媒の
供給流路5aに代え、軸筒5の口径より大径の円板18
をステー19にて対向的に配設したものである。このよ
うに構成することにより、遠心力の作用で流動層反応器
1内に流入する触媒6は、円周方向に均一に供給され
る。図1の実施例と同一構造部分には、同一の符号を付
すことによって構成の詳細な説明は省略する。また、一
部を除き作用も図1のものと略同様であるので、詳細な
作用説明は省略する。In the embodiment shown in FIG. 2, a disk 18 having a diameter larger than the diameter of the barrel 5 is used instead of the catalyst supply flow path 5a shown in FIG.
Are oppositely arranged at the stay 19. With this configuration, the catalyst 6 flowing into the fluidized bed reactor 1 by the action of the centrifugal force is uniformly supplied in the circumferential direction. The same components as those in the embodiment of FIG. 1 are denoted by the same reference numerals, and a detailed description of the configuration will be omitted. Also, the operation is substantially the same as that of FIG. 1 except for a part, and therefore, detailed description of the operation is omitted.
【0017】図3に示す実施例は、図1に示した実施例
において、分散板2aをテーパー形状としたもので、排
出口11から劣化した粉状の触媒6が効率よく排出され
るようにしたものである。また、図1と同一構造部分に
は、同一の符号を付すことによって構成の詳細な説明は
省略する。更に、分散板2aの作用以外は図1の実施例
と作用が略同一であるので、詳細な作用説明は省略す
る。The embodiment shown in FIG. 3 is different from the embodiment shown in FIG. 1 in that the dispersion plate 2a has a tapered shape so that the deteriorated powdery catalyst 6 can be efficiently discharged from the discharge port 11. It was done. Further, the same reference numerals are given to the same structural parts as those in FIG. 1 and the detailed description of the configuration is omitted. Further, the operation is substantially the same as that of the embodiment of FIG. 1 except for the operation of the dispersing plate 2a, and a detailed explanation of the operation will be omitted.
【0018】触媒を選択することにより、脱塵は勿論の
こと、脱硝,脱硫,脱塩などの分解化学反応が可能で、
その利用分野は広い。By selecting a catalyst, not only dedusting but also decomposing chemical reactions such as denitration, desulfurization and desalination are possible.
Its field of use is wide.
【0019】[0019]
【発明の効果】 上述のように本発明の構成によれば、
次のような効果が得られる。 (a)流動層反応器を排ガス雰囲気中に回転可能とした
ことにより、流動層を遠心流動層とすることができ、従
って、従来の重力場の流動層に比べて大きな流動化ガス
線速度が得られ、排ガス処理量を大きくしうることか
ら、装置全体の小型化が図れ自動車などへの搭載も可能
となり、排ガスによる公害問題も合理的に解消しうる。 (b)流動層反応前の駆動源として、エンジンの回転動
力を用いることにより、エンジンの回転数に応じた排ガ
ス量が効率よく処理できる。 (c)触媒の供給と、劣化して粉状化した触媒の排出交
換が自動的に行われ、排ガスの反応器における脱硝など
が高能率的に行える。According to the configuration of the present invention as described above,
The following effects can be obtained. (A) Since the fluidized bed reactor is rotatable in an exhaust gas atmosphere, the fluidized bed can be a centrifugal fluidized bed. Therefore, the fluidized gas linear velocity is larger than that of a conventional fluidized bed in a gravitational field. As a result, since the amount of exhaust gas treatment can be increased, the entire apparatus can be downsized and can be mounted on an automobile or the like, and the pollution problem due to exhaust gas can be rationally solved. (B) By using the rotational power of the engine as the drive source before the fluidized bed reaction, the amount of exhaust gas corresponding to the engine speed can be efficiently processed. (C) The supply of the catalyst and the discharge and exchange of the degraded and powdered catalyst are automatically performed, so that the exhaust gas can be efficiently denitrated in the reactor.
【図1】 本発明装置の縦断正面図である。FIG. 1 is a vertical sectional front view of the device of the present invention.
【図2】 別実施例の縦断正面図である。FIG. 2 is a longitudinal sectional front view of another embodiment.
【図3】 更に別実施例の縦断正面図である。FIG. 3 is a longitudinal sectional front view of still another embodiment.
1 流動層反応器 2 分散板 2a 分散板 3 端板 4 端板 5 軸筒 5a 供給流路 6 触媒 7 排気管 9 触媒供給管 9a 触媒溜 11 排出口 12 排ガスの導入外筒 13 排ガス導入管 14 仕切板 15 触媒排出流路 18 円板 DESCRIPTION OF SYMBOLS 1 Fluidized bed reactor 2 Dispersion plate 2a Dispersion plate 3 End plate 4 End plate 5 Shaft 5a Supply flow path 6 Catalyst 7 Exhaust pipe 9 Catalyst supply pipe 9a Catalyst reservoir 11 Outlet 12 Exhaust gas introduction outer cylinder 13 Exhaust gas introduction pipe 14 Partition plate 15 Catalyst discharge channel 18 Disk
Claims (1)
内に、円筒状の分散板を有し、この分散板の中心軸線に
そった排気管を一方端側にもつ円筒形構造の流動層反応
器を回転駆動可能に設け、該流動層反応器の中心部に円
筒状のフィルターを設け、該フィルターと分散板間の空
洞に触媒を入れ、上記流動層反応器の他方端側に上記排
気管と同一軸線の触媒供給管を接続するとともに、この
触媒供給管の反対側に設けられ、かつ、仕切板によって
排ガス導入側とは仕切られた流動層反応器部位に触媒排
出流路を設け、これに流動層反応器に設けた触媒の排出
口を連通させたことを特徴とする排ガスの処理装置。1. A fluidized bed having a cylindrical structure having a cylindrical dispersion plate in an outer cylinder for introducing a gas to be treated of engine exhaust gas and having an exhaust pipe on one end side along a central axis of the dispersion plate. A reactor is rotatably driven, and a circle is formed at the center of the fluidized bed reactor.
A cylindrical filter is provided, and the space between the filter and the dispersion plate is provided.
A catalyst is placed in the cavity, and a catalyst supply pipe having the same axis as the exhaust pipe is connected to the other end of the fluidized bed reactor. The catalyst supply pipe is provided on the opposite side of the catalyst supply pipe, and a partition plate is provided on the exhaust gas introduction side. An exhaust gas treatment apparatus characterized in that a catalyst discharge flow path is provided in a partitioned fluidized bed reactor portion, and a catalyst discharge port provided in the fluidized bed reactor is communicated with the catalyst discharge flow path.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11410491A JP3252166B2 (en) | 1991-04-18 | 1991-04-18 | Exhaust gas treatment equipment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11410491A JP3252166B2 (en) | 1991-04-18 | 1991-04-18 | Exhaust gas treatment equipment |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04322725A JPH04322725A (en) | 1992-11-12 |
JP3252166B2 true JP3252166B2 (en) | 2002-01-28 |
Family
ID=14629221
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11410491A Expired - Fee Related JP3252166B2 (en) | 1991-04-18 | 1991-04-18 | Exhaust gas treatment equipment |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3252166B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180076317A1 (en) * | 2008-12-25 | 2018-03-15 | Rohm Co., Ltd. | Semiconductor device |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2814342B2 (en) * | 1993-12-16 | 1998-10-22 | 川崎重工業株式会社 | Centrifugal fluidized bed dust collection method and apparatus |
CN116099357B (en) * | 2023-04-15 | 2023-06-09 | 山西清凯环保工程有限公司 | SCR denitration system |
-
1991
- 1991-04-18 JP JP11410491A patent/JP3252166B2/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180076317A1 (en) * | 2008-12-25 | 2018-03-15 | Rohm Co., Ltd. | Semiconductor device |
US10693001B2 (en) * | 2008-12-25 | 2020-06-23 | Rohm Co., Ltd. | Semiconductor device |
Also Published As
Publication number | Publication date |
---|---|
JPH04322725A (en) | 1992-11-12 |
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