JP3236343B2 - Continuous foaming equipment - Google Patents

Continuous foaming equipment

Info

Publication number
JP3236343B2
JP3236343B2 JP11562892A JP11562892A JP3236343B2 JP 3236343 B2 JP3236343 B2 JP 3236343B2 JP 11562892 A JP11562892 A JP 11562892A JP 11562892 A JP11562892 A JP 11562892A JP 3236343 B2 JP3236343 B2 JP 3236343B2
Authority
JP
Japan
Prior art keywords
resin particles
plate
belt
cooling
foamed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP11562892A
Other languages
Japanese (ja)
Other versions
JPH05309756A (en
Inventor
勝 落合
昭 富士栄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Original Assignee
Asahi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Corp filed Critical Asahi Kasei Corp
Priority to JP11562892A priority Critical patent/JP3236343B2/en
Publication of JPH05309756A publication Critical patent/JPH05309756A/en
Application granted granted Critical
Publication of JP3236343B2 publication Critical patent/JP3236343B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、発泡性樹脂粒子から得
られる発泡板を連続的に製造する装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an apparatus for continuously producing a foamed board obtained from foamable resin particles.

【0002】[0002]

【従来の技術】発泡性樹脂粒子を用いて発泡板を連続的
に製造する装置として、断面がほぼ矩形状をなし、プレ
ートにて囲まれたトンネル構造内側の上下面に沿って、
連続的に移動する2枚のベルトの間に発泡性樹脂粒子を
供給して、蒸気加熱装置、冷却装置を経て連続的に発泡
板を製造する装置が種々提案されている。中でも、特開
昭59ー85723号公報に開示される成形装置は、実
用的にも優れ生産機としてのポテンシャルを有するもの
である。
2. Description of the Related Art As an apparatus for continuously manufacturing a foamed board using foamable resin particles, a cross-section is substantially rectangular, and along an upper surface and a lower surface inside a tunnel structure surrounded by a plate,
Various devices have been proposed for supplying foamable resin particles between two continuously moving belts and continuously producing a foamed plate via a steam heating device and a cooling device. Above all, the molding apparatus disclosed in JP-A-59-85723 is excellent in practical use and has potential as a production machine.

【0003】[0003]

【発明が解決しようとする課題】これら従来装置では、
蒸気室からトンネル内に吹き込まれた加圧蒸気により、
フィードゾーンから連続的に供給されてくる発泡性樹脂
粒子を加熱するのであるが、同時に、装置自体の加熱を
行い、自然放熱により熱バランスが保たれるものであ
る。
In these conventional devices,
By pressurized steam blown into the tunnel from the steam room,
While the expandable resin particles continuously supplied from the feed zone are heated, the apparatus itself is heated at the same time, and the heat balance is maintained by natural heat radiation.

【0004】従って、スチームとして供給された水蒸気
は冷却され凝縮水に変化し、発泡成形体中に含有された
り、ベルト上に逐時蓄積しフィードゾーンまで逆流し発
泡性樹脂粒子の供給量に変動をきたしたり、極端な場合
には発泡性樹脂粒子の供給を阻害し、長時間に亘る安定
生産ができないという問題があった。かかる従来技術に
対して、本発明者らは連続的に安定して発泡板を製造す
る装置に付いて鋭意検討して本発明に至った。
[0004] Accordingly, the steam supplied as steam is cooled and changes into condensed water, which is contained in the foamed molded article or accumulates on the belt gradually and flows back to the feed zone to change the supply amount of the foamable resin particles. In an extreme case, there is a problem that the supply of the expandable resin particles is hindered and stable production cannot be performed for a long time. With respect to such a conventional technique, the present inventors have earnestly studied an apparatus for continuously and stably producing a foamed board, and have reached the present invention.

【0005】すなわち、本発明の課題は、発泡性樹脂粒
子を用いて連続的に発泡板を製造する装置に於いて、加
圧蒸気の凝縮水による発泡性樹脂粒子の供給阻害を受け
ず安定生産が可能な連続成形装置を提供する事にある。
[0005] That is, an object of the present invention is to provide an apparatus for continuously producing a foamed board using foamable resin particles, and to stably produce foamable resin particles without being hindered by the supply of foamable resin particles due to condensed water of pressurized steam. It is an object of the present invention to provide a continuous molding apparatus capable of performing the following.

【0006】[0006]

【課題を解決するための手段】本発明の上記課題は、断
面がほぼ矩形状をなし、プレートにて囲まれたトンネル
構造内側の上下面に沿って、連続的に移動する2枚の小
孔を有するベルトの間に発泡性樹脂粒子を供給して、蒸
気加熱装置、冷却装置を経て連続的に発泡板を製造する
装置に於いて、フィードゾーン下側のプレートに凝縮水
の排水路を設ける事によって得られる。
SUMMARY OF THE INVENTION The object of the present invention is to provide two small holes which are substantially rectangular in cross section and move continuously along the upper and lower surfaces inside a tunnel structure surrounded by plates. In the apparatus for supplying foamable resin particles between the belts having the same and continuously producing a foamed plate through a steam heating device and a cooling device, a drainage channel for condensed water is provided in a plate below a feed zone. Gained by things.

【0007】すなわち、発泡性樹脂粒子(1)の供給装
置(2)、蒸気加熱装置(3)、冷却装置(4)を備
え、断面がほぼ矩形状をなし、プレート(5)に囲まれ
たトンネル構造(6)の中を、トンネル内側の上下面に
沿って2枚の小孔を有するベルト(7)が同一方向に同
一速度で連続的に移動する発泡成形装置であり、フィー
ドゾーン(8)の下側プレートには凝縮水の排水路
(9)が設けられている。供給装置からベルト上に供給
される発泡性樹脂粒子群はベルトと共にトンネル内を連
続的に移動して、蒸気加熱装置からベルトの小孔を通じ
て吹き込まれた加圧蒸気が発泡性樹脂粒子間に進入して
発泡性樹脂粒子の加熱膨張を効率的に行い、発泡性樹脂
粒子同士を融着させ発泡板が形成される。蒸気加熱装置
から吹き込まれた加圧蒸気はフィードゾーン近傍で凝縮
水となるが、この凝縮水は下側ベルトの小孔を通じてフ
ィードゾーンの下側プレートに設けられている凝縮水の
排水路に流れ込む為凝縮水のベルト上への蓄積がなくな
り発泡性樹脂粒子の供給阻害もなくなるので安定生産が
可能となる。蒸気加熱装置により一体成形された発泡板
はベルトと共に移動しながら冷却装置により冷却され冷
却固化し発泡板が得られる。
That is, the apparatus is provided with a supply device (2) for the expandable resin particles (1), a steam heating device (3), and a cooling device (4), and has a substantially rectangular cross section and is surrounded by a plate (5). A belt (7) having two small holes continuously moves at the same speed in the same direction in the tunnel structure (6) along the upper and lower surfaces inside the tunnel. The lower plate is provided with a drainage channel (9) for condensed water. The foaming resin particles supplied from the supply device to the belt move continuously in the tunnel together with the belt, and pressurized steam blown from the steam heating device through the small holes of the belt enters between the foaming resin particles. As a result, the expandable resin particles are efficiently heated and expanded, and the expandable resin particles are fused together to form a foamed plate. The pressurized steam blown from the steam heating device becomes condensed water in the vicinity of the feed zone, and the condensed water flows through a small hole of the lower belt into a drainage channel of the condensed water provided on the lower plate of the feed zone. Therefore, there is no accumulation of condensed water on the belt, and there is no hindrance to the supply of the expandable resin particles, so that stable production is possible. The foam plate integrally formed by the steam heating device is cooled by the cooling device while moving together with the belt, and is cooled and solidified to obtain a foam plate.

【0008】発泡性樹脂粒子(1)は、熱可塑性合成樹
脂であって、特にその種類を限定するものではないが、
通常ポリスチレン系、ポリオレフィン系、ポリ塩化ビニ
リデン系の発泡性樹脂粒子であって、発泡倍率が5〜6
0倍のいわゆる予備発泡粒子を用いる。特に、高断熱性
能を要求する場合は、ハイドロクロロフルオロカーボ
ン、ハイドロフルオロカーボン等を発泡剤として含有し
ている塩化ビニリデン系合成樹脂を基材樹脂とした発泡
性樹脂粒子を使用する事が好ましい。
The expandable resin particles (1) are a thermoplastic synthetic resin, and the type thereof is not particularly limited.
Usually polystyrene-based, polyolefin-based, polyvinylidene chloride-based expandable resin particles having an expansion ratio of 5 to 6
Zero times so-called pre-expanded particles are used. In particular, when high heat insulation performance is required, it is preferable to use foamable resin particles using a vinylidene chloride-based synthetic resin containing hydrochlorofluorocarbon, hydrofluorocarbon, or the like as a foaming agent as a base resin.

【0009】供給装置(2)は、ベルト上に均一に発泡
性樹脂粒子を供給できる装置で有れば特に限定するもの
ではない。蒸気加熱装置(3)は、発泡性樹脂粒子を加
熱して一体成形するものであり、熱源としては、加圧蒸
気を用いベルトの小孔を通じて発泡性樹脂粒子群内に吹
き込まれる。
The supply device (2) is not particularly limited as long as it is a device capable of uniformly supplying the expandable resin particles onto the belt. The steam heating device (3) heats and integrally forms the expandable resin particles, and is blown into the expandable resin particle group through small holes of the belt using a pressurized steam as a heat source.

【0010】冷却装置(4)は、加熱一体成形された発
泡板の温度を2次膨張を起こさない温度まで冷却する目
的を持ち、冷却方法としては、水による直接冷却よりも
冷却板を用いた間接冷却が好ましい。何故ならば、水に
よる直接冷却を行うと冷却後に乾燥装置が必要となり好
ましくない。冷却板を冷却するための冷媒としては、圧
縮空気、冷却水等が用いられる。
The cooling device (4) has a purpose of cooling the temperature of the foam plate integrally formed by heating to a temperature at which secondary expansion does not occur. As a cooling method, a cooling plate is used rather than direct cooling with water. Indirect cooling is preferred. This is because direct cooling with water is not preferable because a drying device is required after cooling. As a refrigerant for cooling the cooling plate, compressed air, cooling water, or the like is used.

【0011】プレート(5)は、トンネル構造を形成す
るものであって、トンネル内での発泡性樹脂粒子の膨張
圧に耐える強度を有していなければならない。通常肉厚
のアルミ板等の金属板を用いる。なおプレート内側に
は、ベルトあるいは発泡板との摩擦抵抗を減少させるた
めに、ポリテトラフルオロエチレンの板状体を介するか
あるいはポリテトラフルオロエチレンが塗布されている
ことが好ましい。
The plate (5) forms a tunnel structure and must have a strength to withstand the expansion pressure of the expandable resin particles in the tunnel. Usually, a metal plate such as a thick aluminum plate is used. Preferably, the inside of the plate is coated with a polytetrafluoroethylene plate or coated with polytetrafluoroethylene in order to reduce the frictional resistance with the belt or the foamed plate.

【0012】断面がほぼ矩形状のトンネル構造(6)と
は、トンネルの入り口形状及び出口形状がほぼ矩形状を
なすものであって、トンネルの入り口から出口までの断
面寸法は同一であってもよいが、加熱ゾーンの厚み方向
の寸法に対してトンネル入り口側の厚み方向の寸法を大
きくすることが好ましい。何故ならば、トンネル入り口
側の厚み方向の寸法を大きくする事によって、トンネル
内を移動する発泡性樹脂粒子群は厚み方向に圧縮を受け
るため、充填された発泡性樹脂粒子間の空隙率が低下
し、加熱成形時の膨張力が付加されて発泡性樹脂粒子同
士の融着性が向上するので、より高性能の発泡パネルが
得られる。
The tunnel structure (6) having a substantially rectangular cross section is one in which the entrance and exit shapes of the tunnel are substantially rectangular, and the sectional dimensions from the entrance to the exit of the tunnel are the same. It is preferable that the dimension in the thickness direction on the tunnel entrance side be larger than the dimension in the thickness direction of the heating zone. Because, by increasing the dimension in the thickness direction at the tunnel entrance side, the expandable resin particles moving in the tunnel are compressed in the thickness direction, and the porosity between the filled expandable resin particles decreases. However, the expansion force at the time of heat molding is applied to improve the fusion property between the expandable resin particles, so that a foam panel with higher performance can be obtained.

【0013】2枚のベルト(7)は、各々エンドレス状
をなし、トンネル内側の上下面に沿って、引き取りロー
ラーにより同一方向・同一速度で移動する。ベルトの材
質は、スチールベルト、ゴムベルトあるいは織布等が用
いられ通常スチールベルトを用いる。ベルトには小孔が
設けられていおり、該小孔は加熱ゾーンに於ける加圧蒸
気の吹き込みと、フィードゾーンに於ける凝縮水を排水
路に排出する役目をなす。小孔の大きさ、数、配列等に
付いては任意に設定できるが、穴径0.3〜2.0m
m、ピッチ5〜50mm、の小孔を千鳥状に配列する事
が好ましい。穴径が0.3mm以下では加圧蒸気の通気
抵抗が増し蒸気効率が悪化するし、凝縮水の排出効率も
悪化する。穴径が2.0mm以上になると発泡性樹脂粒
子の小粒子が小孔から漏れたりあるいは発泡板の表面に
突起状物が残るので好ましくない。ピッチが5mm以下
になるとベルトの強度が低下し、ピッチが50mm以上
になると発泡性樹脂粒子間への加圧蒸気の進入が不十分
となり、又凝縮水の排出効率も悪化するので小孔を設け
る意味がなくなる。小孔を千鳥状に配列すると、発泡性
樹脂粒子間への加圧蒸気の進入がより均一となるので好
ましい。
Each of the two belts (7) has an endless shape and is moved in the same direction and at the same speed by a take-up roller along the upper and lower surfaces inside the tunnel. As a material of the belt, a steel belt, a rubber belt, a woven fabric, or the like is used, and a steel belt is usually used. The belt is provided with small holes, which serve to blow pressurized steam in the heating zone and discharge condensed water in the feed zone to a drain. The size, number, arrangement, etc. of the small holes can be arbitrarily set, but the hole diameter is 0.3 to 2.0 m.
It is preferable to arrange small holes having a pitch of 5 to 50 mm in a zigzag pattern. If the hole diameter is 0.3 mm or less, the ventilation resistance of the pressurized steam increases, the steam efficiency deteriorates, and the discharge efficiency of the condensed water also deteriorates. When the hole diameter is 2.0 mm or more, it is not preferable because small particles of the expandable resin particles leak from the small holes or protrusions remain on the surface of the foam plate. When the pitch is 5 mm or less, the strength of the belt is reduced. When the pitch is 50 mm or more, the penetration of pressurized steam between the expandable resin particles becomes insufficient, and the efficiency of discharging condensed water is deteriorated. It makes no sense. It is preferable to arrange the small holes in a staggered manner, because the penetration of the pressurized steam between the foamable resin particles becomes more uniform.

【0014】フィードゾーン(8)とは、概ね供給装置
下〜蒸気加熱装置手前までを指すが、蒸気加熱装置手前
に保熱ゾーンを設ける場合は保熱ゾーン手前までを指
し、厳密に区分されるものではない。排水路(9)は、
フィードゾーンの下側プレートに設けられるが、溝状あ
るいは貫通孔等を使用する。ベルトの小孔を通じて排水
路に流出する凝縮水は、任意の集水溝等を設け外部に排
水すれば良い。又、排水路を設ける位置は、概ね供給装
置下〜蒸気加熱装置手前までであるが、蒸気加熱装置に
接近しすぎると加圧蒸気も吹き出す可能性があるので、
蒸気圧力あるいは排水路の大きさにあった位置に設ける
事が必要である。溝及び貫通孔等の形状あるいは数等に
ついては排水機能を満足するものであれば任意に設定で
きる。
The feed zone (8) generally refers to a portion from below the supply device to a position immediately before the steam heating device. However, when a heat retention zone is provided in front of the steam heating device, the feed zone (8) indicates a portion immediately before the heat retention zone and is strictly divided. Not something. The drainage channel (9)
Although provided on the lower plate of the feed zone, a groove or through hole is used. Condensed water flowing out to the drainage channel through the small hole of the belt may be drained to the outside by providing an optional water collecting groove or the like. Also, the position where the drainage channel is provided is generally below the supply device to just before the steam heating device, but if it is too close to the steam heating device, pressurized steam may also be blown out,
It is necessary to provide it at a position corresponding to the steam pressure or the size of the drainage channel. The shape or number of the grooves and through-holes can be arbitrarily set as long as they satisfy the drainage function.

【0015】ベルト上に供給された発泡性樹脂粒子は、
凝縮水による供給阻害を受けること無く上下のベルトに
てサンドイッチされた状態でトンネル内を連続的に移動
して、蒸気加熱装置により加熱され膨張融着して一体成
形された発泡板が形成される。ついで、発泡板はベルト
と共に移動して冷却装置により冷却される事によって発
泡板が固化し、連続して安定した発泡板の製造が可能と
なる。
The foamable resin particles supplied on the belt are
It moves continuously in the tunnel while being sandwiched by the upper and lower belts without being hindered by the supply of condensed water, and is heated and expanded and fused by the steam heating device to form an integrally molded foam plate. . Next, the foam board moves together with the belt and is cooled by the cooling device, so that the foam board is solidified, and it is possible to continuously manufacture a stable foam board.

【0016】かくして得られた発泡板は、このままでも
発泡板として使用できるのはもちろんであるが、より高
性能の発泡板とするために冷却装置をでた後に発泡板の
表面に面材を貼り合わす事も可能である。本発明による
発泡板は、連続的にほぼエンドレス状態で得られるた
め、発泡板の長さについては、裁断装置にて任意の長さ
に切断すればよい。
The foamed board thus obtained can be used as it is as a foamed board as it is. However, in order to obtain a foamed board of higher performance, a surface material is applied to the surface of the foamed board after leaving a cooling device. It is also possible to combine them. Since the foam board according to the present invention can be obtained continuously and almost in an endless state, the length of the foam board may be cut to an arbitrary length by a cutting device.

【0017】[0017]

【実施例】図1に示す装置を用いて、下記条件にて発泡
板を製造し、連続運転可能時間を計測した。計測結果を
表1に示す。 〈発泡板製造条件〉 発泡性樹脂粒子の基材樹脂 :塩化ビニリデン系合成樹
脂(旭化成工業(株)製 商品名 セルモア) 発泡性樹脂粒子の見かけ密度:40 Kg/m3 ベルトの材質 :スチールベルト ベルトの幅 :300 mm 上下ベルトの間隔 :25 mm 小孔の大きさ :0.8 mmφ 小孔のピッチ :20 mm 小孔の配列 :千鳥状 加熱源 :加圧蒸気 加熱圧力 :1.0 Kg/cm2G 冷却装置の冷媒 :冷却水 冷却水温度 :20 ℃ ラインスピード :1.0 m/min 排水路の形状及び種類 :U字溝状 排水路の大きさ及び本数 :5mm幅×5mm深さ×
5本等間隔
EXAMPLES Using the apparatus shown in FIG. 1, a foamed board was manufactured under the following conditions, and the continuous operable time was measured. Table 1 shows the measurement results. <Foam board manufacturing conditions> Base resin of expandable resin particles: Vinylidene chloride-based synthetic resin (product name: Cellmore, manufactured by Asahi Kasei Kogyo Co., Ltd.) Apparent density of expandable resin particles: 40 Kg / m 3 Material of belt: Steel belt Belt width: 300 mm Distance between upper and lower belts: 25 mm Size of small holes: 0.8 mmφ Pitch of small holes: 20 mm Array of small holes: Staggered Heating source: Pressurized steam Heating pressure: 1.0 Kg / Cm 2 G Refrigerant of cooling device: cooling water Cooling water temperature: 20 ° C. Line speed: 1.0 m / min Shape and type of drainage channel: U-shaped groove Size and number of drainage channels: 5 mm width × 5 mm depth X
5 equally spaced

【0018】[0018]

【比較例】実施例と同じ条件ではあるが、排水路を設け
ずに発泡板を製造し、連続運転可能時間を計測した。計
測結果を表1に示す。
[Comparative Example] Under the same conditions as in the example, a foam board was manufactured without providing a drainage channel, and the continuous operation time was measured. Table 1 shows the measurement results.

【0019】[0019]

【表1】 [Table 1]

【0020】[0020]

【発明の効果】本発明による発泡板の連続成形装置は、
加圧蒸気の凝縮水による発泡性樹脂粒子の供給阻害を受
けず安定生産が可能で経済性に優れた発泡板の提供が可
能となる。
The apparatus for continuously forming a foamed plate according to the present invention is
It is possible to provide a foam plate that is stable and can be manufactured economically without being hindered by the supply of the expandable resin particles due to pressurized steam condensed water.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明による成形機の概要を示す本体側面図で
ある。
FIG. 1 is a main body side view showing an outline of a molding machine according to the present invention.

【図2】図1中のA−A線に沿う横断面図である。FIG. 2 is a cross-sectional view taken along line AA in FIG.

【符号の説明】 1・・発泡性樹脂粒子 2・・供給装置 3・・蒸気加熱装置 4・・冷却装置 5・・プレート 6・・トンネル構造 7・・ベルト 8・・フィードゾーン 9・・排水路 10・・集水溝 11・・引き取りローラー[Explanation of Signs] 1..Expandable resin particles 2..Supply device 3..Steam heating device 4..Cooling device 5..Plate 6 ... Tunnel structure 7 ... Belt 8 ... Feed zone 9 ... Drainage Road 10 ・ ・ Catchment groove 11 ・ ・ Recovery roller

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 断面がほぼ矩形状をなし、プレートにて
囲まれたトンネル構造内側の上下面に沿って、連続的に
移動する2枚の小孔を有するベルトの間に発泡性樹脂粒
子を供給して、蒸気加熱装置、冷却装置を経て連続的に
発泡板を製造する装置に於いて、フィードゾーン下側の
プレートに凝縮水の排水路を設けた事を特徴とする発泡
板の連続成形装置。
1. A foaming resin particle is formed between a belt having two small holes continuously moving along upper and lower surfaces inside a tunnel structure surrounded by a plate and having a substantially rectangular cross section. In a device for continuously producing a foamed board by supplying and passing through a steam heating device and a cooling device, a drainage channel for condensed water is provided in a plate below a feed zone, and the continuous forming of the foamed plate is performed. apparatus.
JP11562892A 1992-05-08 1992-05-08 Continuous foaming equipment Expired - Fee Related JP3236343B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11562892A JP3236343B2 (en) 1992-05-08 1992-05-08 Continuous foaming equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11562892A JP3236343B2 (en) 1992-05-08 1992-05-08 Continuous foaming equipment

Publications (2)

Publication Number Publication Date
JPH05309756A JPH05309756A (en) 1993-11-22
JP3236343B2 true JP3236343B2 (en) 2001-12-10

Family

ID=14667358

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11562892A Expired - Fee Related JP3236343B2 (en) 1992-05-08 1992-05-08 Continuous foaming equipment

Country Status (1)

Country Link
JP (1) JP3236343B2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3775612B2 (en) * 1996-12-24 2006-05-17 株式会社ジェイエスピー Manufacturing method and manufacturing apparatus for foam molded article
JP2005001323A (en) * 2003-06-13 2005-01-06 Mitsubishi Rayon Eng Co Ltd Heating chamber for belt machine, and belt heating method and device using the chamber
JP5124337B2 (en) * 2008-04-24 2013-01-23 積水化成品工業株式会社 Combination of sealed container containing polylactic acid-based resin expanded particles and molding die and use thereof
KR101338763B1 (en) 2009-04-28 2013-12-06 아사히 가세이 겐자이 가부시키가이샤 Device for forming thermosetting resin foam plate and method of manufacturing thermosetting resin foam plate

Also Published As

Publication number Publication date
JPH05309756A (en) 1993-11-22

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