JP3207511B2 - Receiving layer transfer sheet and receiving layer transfer method - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a receptor layer transfer sheet and a receptor layer transfer method, and more particularly, to a receptor layer transfer sheet and a receptor layer in which the edge line of the receptor layer transferred at the time of transfer has a clear linear shape. It relates to a transfer method.

[0002]

2. Description of the Related Art Various thermal transfer methods are known in the art. Among them, a sublimable dye is used as a recording agent, and this is carried on a base sheet such as paper or plastic film to form a thermal transfer sheet. There have been proposed methods of forming various full-color images on a transfer material such as paper or a plastic film provided with a layer. In this case, a thermal head of a printer is used as a heating means, and a large number of three or four color dots are transferred to a transfer material by heating for a very short time, and a full-color image of an original is formed by the multicolor dots. Is to reproduce. The image formed in this way is very clear because the coloring material used is a dye, and is excellent in transparency, so that the obtained image is excellent in the reproducibility and gradation of intermediate colors. It is possible to form a high-quality image which is similar to an image by offset printing or gravure printing, and is comparable to a full-color photographic image.

[0003]

The transfer material on which an image can be formed by the above method is limited to a dye-dyeable plastic sheet or a paper provided with a dye-receiving layer in advance, and is generally a plain paper. Have a problem that an image cannot be formed directly. Of course, even if it is a general plain paper, an image can be formed if a receiving layer is formed on the surface thereof,
This is generally costly, and is difficult to apply to general ready-made transfer materials such as postcards, memos, stationery, report paper, and the like. As a method for solving such problems, when an image is to be formed on a ready-made transfer receiving material such as plain paper, a method for easily forming a dye receiving layer only on a necessary portion thereof is a receiving layer transfer sheet. Is known (for example, see Japanese Patent Application Laid-Open No. 62-264994).

[0004] The transfer sheet for receiving layer as described above is formed by forming a release layer or an adhesive layer on a base sheet such as polyester film, if necessary, and forming a transfer resin layer containing at least a dye receiving layer on the surface thereof. It is formed. Using such a receptor layer transfer sheet, for example, when the receptor layer is transferred only to a predetermined area such as a postcard or a sheet of plain paper, a predetermined area is usually transferred by heating with a thermal head. for receiving layer a is formed at a relatively high film strength resin, the edge of the receiving layer a was transferred to the surface of the transfer material 11 as shown in FIG. 5 does not become clean straight, jagged When an image is formed on the entire surface of the receiving layer in this state, the edges of the image do not have a clear linear shape, are jagged or irregular, and a problem arises in that the appearance of the image is poor. Accordingly, an object of the present invention is to provide a receiving layer transfer sheet and a receiving layer transfer method in which the edge of the transferred receiving layer becomes a clean linear shape.

[0005]

The above object is achieved by the present invention described below. That is, the present invention comprises, on one surface of a base sheet, a release layer and a transferable resin layer including at least a dye-receiving layer thereon, and a coating area of the release layer.
The provided rather smaller than the coating region of the transfer resin layer, transferability tree
Heating / pressing the area above the release layer when transferring the grease layer
Receiving layer transfer sheet is characterized in that so as to transfer the transferable receptive layer, a receiving layer transfer method, characterized by using 及 beauty above receptor layer transfer sheet.

[0006]

For example, as shown in FIG. 3, by providing the release layer 7 smaller than the transferable resin layer A and providing the edge of the release layer 7 in a clean linear shape, for example, a linear shape, By applying heat and / or pressure to the area larger than the area of the release layer from the back surface of the receiving layer transfer sheet to transfer the transferable resin layer A to the material to be transferred, the transferred resin layer A becomes The transfer is performed in the same shape as the release layer 7, that is, in a linear shape, for example, a straight edge. This is because the transferable resin layer A formed in the region without the release layer is strongly bonded to the base sheet. On the other hand, as shown in Figure 5,
When the release layer 7 is formed in the same area as the transferable resin layer A, heat and / or heat is applied from the back surface of the receiving layer to a smaller area than the release layer.
Alternatively, when the transfer is performed by applying pressure, it is difficult to cut the foil of the resin layer A insufficiently and it is difficult to cut the foil in a clean linear shape, and the edge of the transferred resin layer A tends to be jagged. It is.

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will now be described in more detail with reference to preferred embodiments. One example of the receiving layer transfer sheet of the present invention is, as schematically shown in FIG. 1, a transfer resin layer including a release layer 7 and at least a dye receiving layer 2 on one side of a base sheet 1. A, and the coating area of the release layer 7 is smaller than the transferable resin layer A. In addition, if necessary, the bubble-containing layer 3 and the intermediate layer 4
And an adhesive layer 5, and a heat-resistant lubricating layer 6 can be further provided. These intermediate layers or adhesive layers can also contain cells and / or blowing agents. In one example of the receiving layer transfer sheet of the present invention as described above, as shown in FIG. 2A and FIG. 2B which is a cross-sectional view taken along the line XX, the release layer 7 is indicated by a dotted line on one surface of the base sheet 1. It is formed by providing a resin layer A having the same width as that of the base sheet thereon. By applying heat and / or pressure from the back surface of the receiving layer transfer sheet to a large area equal to or larger than the release layer using a thermal head or the like,
When the resin layer A is transferred to the surface of No. 1, as shown in FIG.
The resin layer A having a clean linear shape, for example, a straight edge, is transferred onto the surface of the transfer material 11.

In the example of FIG. 2, instead of transferring the resin layer A continuously, for example, as shown in FIG. a line may become jagged as shown in Figure 5. In such a case, a rectangular release layer 7 is formed on the base sheet 1 as shown in FIGS. 3A and 3B, and the transferable resin layer A is provided on the entire surface of the base sheet 1 (of course, the resin layer A May be discontinuously provided as long as the area is larger than the release layer 7 instead of the entire surface.) When heat and / or pressure is applied from the back surface of the receiving layer transfer sheet to a large area equal to or larger than the release layer to transfer the resin layer A to the transfer target material 11, the edges are clear as shown in FIG. 3c. The linear resin layer A is transferred to the transfer material 11. Or in the present invention as described, the transfer resin layer A is not good by providing a degree wide 0.5mm or more than the width of the peeling layer 7.

As the base sheet used in the receiving layer transfer sheet of the present invention, the same base sheet as used in the conventional thermal transfer sheet can be used as it is,
Others can also be used and are not particularly limited. Specific examples of preferred substrate sheets include, for example, thin paper such as glassine paper, condenser paper, and paraffin paper, polyester, polypropylene, cellophane, polycarbonate, cellulose acetate, polyethylene, polyvinyl chloride, polystyrene, nylon, polyimide, and polyvinylidene chloride. And a plastic sheet such as an ionomer or a base sheet obtained by combining these with the paper. These base sheets 1 are provided in a region where the release layer 7 does not exist.
It is preferable to use a resin that has been subjected to an easy adhesion treatment so as to adhere well to the resin layer A. The thickness of the base sheet can be appropriately changed depending on the material so that the strength and heat resistance thereof are appropriate, but the thickness is preferably 3 to 1
00 μm. Prior to the formation of the receiving layer, the release layer 7 is formed on the surface of the base sheet to a predetermined width or a predetermined size. The release layer 7 is made of a water-soluble resin, a hydrophilic resin, waxes,
It is formed from a release agent such as silicone wax, silicone resin, fluorine resin, and acrylic resin. The formation method may be the same as the formation method of the receptor layer described below, and the thickness is 0.1 to 5 μm.
A degree is enough. If a matte receiving layer is desired after the transfer, various particles can be included in the release layer.

Dye receiving layer 2 formed on the surface of the release layer
Is for receiving the sublimable dye transferred from the thermal transfer sheet after transferring the receiving layer to an arbitrary material to be transferred, and maintaining the formed image. Examples of the resin for forming the dye receiving layer include polyolefin resins such as polypropylene, vinyl chloride-vinyl acetate copolymer, polyvinyl chloride, halogenated polymers such as polyvinylidene chloride, polyvinyl acetate, and polyacryl ester. Such as vinyl polymers, polyethylene terephthalate, polyester resins such as polybutylene terephthalate, polystyrene resins, polyamide resins, copolymer resins of olefins such as ethylene and propylene and other vinyl monomers,
Examples thereof include cellulose resins such as ionomers and cellulose diacetates, and polycarbonates. Particularly preferred are vinyl resins and polyester resins.

Preferred release agents used by mixing with the above resins include silicone oil, phosphate ester surfactants, fluorine surfactants, etc., but silicone oil is preferred. As the silicone oil, a modified silicone oil such as epoxy-modified, alkyl-modified, amino-modified, carboxyl-modified, alcohol-modified, fluorine-modified, alkylaralkyl-polyether-modified, epoxy / polyether-modified, or polyether-modified is preferred. One or more release agents are used. or,
The amount of the release agent to be added is preferably 0.5 to 30 parts by weight based on 100 parts by weight of the resin for forming the dye receiving layer. If the addition amount is not satisfied, problems such as fusion of the thermal transfer sheet and the dye receiving layer or reduction in printing sensitivity may occur. By adding such a releasing agent to the dye receiving layer, the releasing agent bleeds out on the surface of the receiving layer after transfer to form a releasing layer.

The receptor layer is formed by dissolving the above-mentioned resin with the necessary additives such as a release agent on the surface of the release layer and dissolving it in an appropriate organic solvent or dispersing it in an organic solvent or water. The dispersion thus formed is formed by applying and drying the dispersion having a size larger than that of the release layer by a forming means such as a gravure printing method, a screen printing method, and a reverse roll coating method using a gravure plate. In the formation of the dye receiving layer, a filler such as kaolin clay, calcium carbonate, or fine powdered silica can be added for the purpose of improving the foil cutting of the receiving layer. The dye-receiving layer formed as described above may have any thickness, but is generally 1 to 5
The thickness is 0 μm. Further, such a dye receiving layer is preferably a continuous coating, but may be formed as a discontinuous coating using a resin emulsion or a resin dispersion.

Further, an intermediate layer 4 may be formed on the surface of the receiving layer. Such an intermediate layer is, for example, coated with a solution of a resin having good coatability such as a polyamide resin, an acrylic resin, a vinyl chloride resin, an ethylene-vinyl acetate copolymer resin, a vinyl chloride-vinyl acetate copolymer resin, and a polyester resin. By drying, preferably 0.1
It is formed to a thickness of about 10 μm. By forming such an intermediate layer, it is possible to prevent irregularities and pinholes from being generated in the dye-receiving layer due to the foaming or expansion of the bubble-containing layer described later, and furthermore, the strength and adhesion of the receiving layer. Also improve. The bubble-containing layer which may be formed on the intermediate layer or the dye-receiving layer is, for example, a coating liquid containing a thermoplastic resin such as a polyurethane resin, an acrylic resin, a polyethylene resin, butadiene rubber, or an epoxy resin as a binder. It is formed by applying and drying a mixture containing air bubbles and / or a foaming agent. The bubble-containing layer may or may not be partially expanded or foamed with the foam or the foaming agent after the formation of the layer. The foaming agent used is a decomposable foaming agent such as dinitropentamethylenetetramine, diazoaminobenzene, azobisisobutyronitrile, azodicarbonamide, which decomposes upon heating to generate gases such as oxygen, carbon dioxide, and nitrogen. Any known foaming agent such as microballoons obtained by microencapsulating a low-boiling liquid such as butane and pentane with a resin such as polyvinylidene chloride and polyacrylonitrile can be used. Microballoons and the like coated with a white pigment can also be used effectively.

The amount of the foaming agent or foam used is preferably such that the transferable resin layer becomes about 1.1 to 4 times as thick when heated to 90 ° C. to 120 ° C. preferable. When the foaming rate (expansion rate) is less than 1.1, the cushioning property is insufficient. On the other hand, when the foaming rate (expansion rate) exceeds 4 times, the bubble-containing layer and the base sheet are not sufficiently bonded. It is not preferable because the adhesiveness becomes insufficient. Particularly preferred blowing agents are the microballoons which can be foamed or expanded at a relatively low temperature, the microballoons coated with the foam and the white pigment, for example, various grades available from Matsumoto Yushi Pharmaceutical Co., Ltd. Yes, any can be used in the present invention. The thickness of these bubble-containing layers is 2
About 80 μm is preferable.

In the present invention, it is also preferable to provide an adhesive layer 5 in order to further improve the transferability of the transferable resin layer. These adhesive layers are formed, for example, by applying and drying a solution of a resin having good adhesiveness when heated, such as a polyamide resin, an acrylic resin, a vinyl chloride resin, a vinyl chloride-vinyl acetate copolymer resin, and a polyester resin. Preferably, it is formed to a thickness of about 0.5 to 10 μm. These adhesive layers may also contain air bubbles and / or a foaming agent to serve also as the air bubble-containing layer. In the present invention, a receiving layer having excellent whiteness can be transferred irrespective of the ground color of the material to be transferred by incorporating a filler, a white pigment, a fluorescent whitening agent and the like in at least one of the above layers. Can be given to wood.

The above example is a basic embodiment of the present invention. In the present invention, as shown in FIG. 4 , the transferable resin layer A as described above is provided on a part of the long base sheet 1. A dye layer composed of a sublimable dye, for example, a dye layer of yellow Y, magenta M and cyan C, and optionally a black Bk (not shown) is provided adjacent to the transferable resin layer, Adjacent to these dye layers, a transferable protective layer for protecting the surface of the formed image (7: release layer, 8:
Protective layer, 9: adhesive layer). In the case of such a composite thermal transfer sheet, for example, first, the resin layer A including the dye receiving layer is transferred to a necessary area of the transfer receiving material such as a postcard, and the dye is transferred to the resin layer A including the transferred receiving layer. The dye images are formed by the layers Y, M, and C (and Bk), and the protective layers (8, 9) are transferred to the surface of the formed image, and the desired image is formed by one thermal transfer sheet and one thermal transfer printer. An image can be formed on any transfer material. In such an embodiment, when it is preferable that the edge of the protective layer 8 also becomes a clean linear shape after the transfer, the relationship between the protective layer 8 and the release layer 7 is determined by the transferable resin layer A.
And the release layer 7.

Using the receiving layer transfer sheet as described above,
The transfer material to which the resin layer including the receiving layer is transferred is not particularly limited, and may be, for example, any sheet such as plain paper, woodfree paper, tracing paper, and plastic film,
Further, in terms of shape, any of cards, postcards, passports, stationery, report paper, notebooks, catalogs and the like may be used, and the present invention is particularly applicable to plain paper having a rough surface and rough paper. The transfer method of the resin layer A or the protective layer 8 can be heated to a temperature at which the receiving layer or the adhesive layer is activated, such as a general printer having a thermal head for thermal transfer, a hot stamper for a transfer foil, a heat roll, and the like. Any heating and pressurizing means may be used.

[0018]

Next, the present invention will be described more specifically with reference to examples and comparative examples. In addition, in the text, Example 1 A coating solution for a release layer having the following composition was dried on a surface of a polyester film (trade name “Lumirror”, manufactured by Toray) having a thickness of 25 μm and a width of 30 cm using a bar coater. 0g /
At a rate of m ² , as shown in FIG. 3, the coating was applied to 29 cm wide by 28 cm long at intervals of 10 mm, temporarily dried with a drier, and then dried in an oven at 100 ° C. for 30 minutes to form a release layer. Further, the following coating solution for the receiving layer was continuously applied over the entire width of the substrate sheet at a rate of 5.0 g / m ² when dried by a bar coater, and temporarily dried with a drier, and then dried in a 100 ° C. oven. After drying for 30 minutes to form a dye-receiving layer, the following coating solution for a bubble-containing layer and an adhesive layer was applied and dried at a rate of 5 g / m ^{2 in} the same manner as described above to form a dye-receiving layer. A layer was formed to obtain a receiving layer transfer sheet of the present invention. Coating liquid composition for release layer; polyvinyl alcohol resin (AH-17, manufactured by Nippon Synthetic Chemical) 100 parts Water 400 parts

Coating solution composition for receptor layer : 100 parts of vinyl chloride / vinyl acetate copolymer (VYHD, manufactured by Union Carbide) Epoxy-modified silicone (KF-393, manufactured by Shin-Etsu Chemical Co., Ltd.) 8 parts Amino-modified silicone (KS- 343, Shin-Etsu Chemical Co., Ltd.) 8 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 400 parts Coating liquid composition for adhesive layer; polymethyl methacrylate resin (BR-106, manufactured by Mitsubishi Rayon) 100 parts Foaming agent (F- 50, manufactured by Matsumoto Yushi Pharmaceutical) 15 parts Titanium oxide (TCA-888, manufactured by Tochem Products) 100 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 300 parts

Example 2 In Example 1, release layers were formed at both ends of the base sheet at a distance of 10 mm as shown in FIG.
In the same manner as in Example 1, a receiving layer transfer sheet of the present invention was obtained. Example 3 On a surface of a polyester film (trade name "Lumirror", manufactured by Toray) having a thickness of 25 μm and a width of 30 cm, a coating solution for a release layer having the following composition was dried with a bar coater at a rate of 1.0 g /
ratio to form the m ^2, horizontal 29 × vertical 28cm and distance 90c
m, a release layer was formed in the same manner as in Example 1 by using a coating solution for a release layer having the following composition.
A receiving layer and a protective layer were formed over the entire width of the film so as to cover the release layer in an area of 0 cm (the areas of both were 30 × 30 cm). The receiving layer and the protective layer were prepared by drying a coating solution having the following composition with a bar coater at a rate of 3.0 g / m ^2.
And temporarily dried with a drier, then 100 ℃
Dry in oven for 30 minutes to form. Next, an adhesive layer was formed on the surface of the receiving layer and the protective layer. The adhesive layer was formed by applying and drying at a rate of 3.0 g / m ² when dried using the following adhesive solution in the same manner as the receiving layer and the protective layer.

Composition of coating liquid for receiving layer : 100 parts of vinyl chloride / vinyl acetate copolymer resin (VYHD, manufactured by UCC) Epoxy-modified silicone (KF-393, manufactured by Shin-Etsu Chemical Co., Ltd.) 8 parts Amino-modified silicone (KP-343; Shin-Etsu Chemical Co., Ltd. 8 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 400 parts Coating liquid composition for protective layer : Vinyl chloride / vinyl acetate copolymer resin (VYHD, manufactured by UCC) 100 parts Methyl ethyl ketone / toluene (weight ratio 1) / 1) 400 parts Coating solution composition for adhesive layer : Acrylic resin (BR-106, manufactured by Mitsubishi Rayon) 100 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 300 parts Subsequently, an ink for a dye layer having the following composition was prepared. The surface of the base sheet on which the receiving layer and the protective layer are not formed has a width of 30
It was coated and dried by a gravure coater such that the dry coating amount per cm became 1.0 g / m ² to obtain a composite receiving layer transfer sheet of the present invention.

Ink composition for dye layer : Disperse dye (Kayaset Blue 714, manufactured by Nippon Kayaku) 4.0 parts Ethyl hydroxycellulose (manufactured by Hercules) 5.0 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 0 parts Dioxane 10.0 parts In the same manner, the yellow thermal transfer sheet was treated with a yellow disperse dye (Macrolex Yellow 6G, CIDisper, manufactured by Bayer AG).
se Yellow 201) and a magenta thermal transfer sheet was formed using a magenta disperse dye (CIDisperse Red 60).

Comparative Example 1 A receiving layer transfer sheet of a comparative example was formed in the same manner as in Example 1 except that the release layer and the transferable resin layer were provided on the entire surface of the substrate sheet. Example 4 On the other hand, an ink for a dye layer having the following composition was prepared, and applied to a 6 μm-thick polyethylene terephthalate film having a heat-resistant rear surface by a wire bar so as to have a dry coating amount of 1.0 g / m ^2. After drying, a few drops of silicone oil (X-41.4003A, manufactured by Shin-Etsu Silicone) were dropped on the back surface with a dropper, and then spread over the entire surface to coat the back surface to obtain a thermal transfer sheet. Ink composition for dye layer: Disperse dye (Kayaset Blue 714, manufactured by Nippon Kayaku) 4.0 parts Ethylhydroxycellulose (manufactured by Hercules) 5.0 parts Methyl ethyl ketone / toluene (weight ratio 1/1) 80.0 parts Dioxane 10.0 parts

The receiving layer transfer sheet of Example 1 and plain paper are superimposed, and heat is applied from the back of the receiving layer transfer sheet to the area larger than the release layer using a thermal head to transfer the receiving layer. Was. Next, the thermal transfer sheet was superimposed on the surface of the receiving layer, and an output of 1 W / dot, pulse width of 0.3 to 0.45 msec. Printing was performed on the entire surface of the receiving layer under the conditions of a dot density of 3 dots / mm to form a solid image, and the protective layer was transferred in the same manner. Table 1 shows the state of the edge of the cyan image obtained as described above. Example 5 An image was formed in the same manner as in Example 4 using the receiving layer transfer sheet described in Example 2, and evaluated in the same manner. The results shown in Table 1 were obtained. Example 6 Using the composite receiving layer transfer sheet of Example 3, an image was formed in the same manner as in Example 4, and evaluation was performed in the same manner. The results shown in Table 1 were obtained.

[0025]

[Table 1]

[0026]

According to the present invention as described above, for example, as shown in FIG. 3, the release layer 7 is provided smaller than the transferable resin layer A,
In addition, by providing the edge of the release layer 7 in a clean linear shape, heat and / or pressure is applied to the area larger than the area of the release layer from the back surface of the receiving layer transfer sheet by a thermal head or the like. When the layer A is transferred to the material to be transferred, the transferred resin layer A is transferred in the same shape as the release layer 7, that is, the edge is formed in a clean linear shape. This is because the transferable resin layer A formed in the region without the release layer is strongly bonded to the base sheet. On the other hand, as shown in FIG. 5 , when the release layer 7 is formed in the same area as the transferable resin layer A, heat and / or pressure is applied from the back surface of the receiving layer to a smaller area than the release layer. If the transfer is performed, it is difficult to cut the foil of the resin layer A insufficiently and it is difficult to cut the foil in a clean linear shape, and the edge of the transferred resin layer A tends to be jagged.

[Brief description of the drawings]

FIG. 1 is a diagram schematically illustrating a cross section of a receiving layer transfer sheet of the present invention.

FIG. 2 is a diagram schematically illustrating a receptor layer transfer sheet of the present invention and a method of using the same.

FIG. 3 is a diagram schematically illustrating a receptor layer transfer sheet of the present invention and a method of using the same.

FIG. 4 is a diagram schematically illustrating a cross section of another example of the receiving layer transfer sheet of the present invention.

FIG. 5 shows a conventional receptor layer transfer sheet and a method of using the same.
FIG.

[Explanation of symbols]

 1: Base sheet 2: Receptive layer 3: Bubble-containing layer 4: Intermediate layer 5: Adhesive layer 6: Heat-resistant lubricating layer 7: Release layer 8: Protective layer 9, 10: Adhesive layer 11: Transfer material Y : Yellow dye layer M: Magenta dye layer Y: Cyan dye layer

Continuation of the front page (56) References JP-A-63-17089 (JP, A) JP-A-1-225591 (JP, A) JP-A-1-122485 (JP, A) JP-A-64-87390 (JP) JP-A-1-160682 (JP, A) JP-A-64-27996 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) B41M 5/38-5/40 B44C 1/17

Claims (7)

(57) [Claims] 1. A transfer sheet comprising a release layer and a transferable resin layer containing at least a dye-receiving layer provided on one side of a substrate sheet, and a coating region of the release layer is coated with the transferable resin layer. provided rather smaller than the region, the Upon transfer of the transfer resin layer
Transfer the transferable receiving layer by heating / pressing over the area over the release layer
A transfer sheet for a receiving layer, characterized in that the transfer sheet is formed. 2. The receiving layer transfer sheet according to claim 1, wherein the transferable resin layer includes an adhesive layer and / or an intermediate layer. 3. The receiving layer transfer sheet according to claim 2 , wherein the adhesive layer contains air bubbles and / or a foaming agent. 4. A transferable resin layer comprising a white pigment, a fluorescent whitening agent,
The receiving layer transfer sheet according to claim 1, further comprising an additive such as a filler. 5. The receiving layer transfer sheet according to claim 1, wherein at least one color dye layer is provided on the transfer resin layer in a plane-sequential manner . 6. The receiving layer transfer sheet according to claim 1, wherein a transfer resin layer including at least a protective layer is further provided in a face-sequential manner. 7. The transferable resin layer surface of the receiving layer transfer sheet according to claim 1 is superimposed on the surface of a material to be transferred, and heat and / or pressure is applied from the back surface of the receiving layer transfer sheet over an area not less than the release layer. And transferring the transferable resin layer to a material to be transferred.