JP3178246B2 - Reprocessing method and recycling equipment for plastic waste with coating film - Google Patents

Reprocessing method and recycling equipment for plastic waste with coating film

Info

Publication number
JP3178246B2
JP3178246B2 JP12241494A JP12241494A JP3178246B2 JP 3178246 B2 JP3178246 B2 JP 3178246B2 JP 12241494 A JP12241494 A JP 12241494A JP 12241494 A JP12241494 A JP 12241494A JP 3178246 B2 JP3178246 B2 JP 3178246B2
Authority
JP
Japan
Prior art keywords
coating film
plastic
coated
plastic waste
pulverized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP12241494A
Other languages
Japanese (ja)
Other versions
JPH07329062A (en
Inventor
忠義 猪飼
勲 坂田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Motor Corp filed Critical Toyota Motor Corp
Priority to JP12241494A priority Critical patent/JP3178246B2/en
Publication of JPH07329062A publication Critical patent/JPH07329062A/en
Application granted granted Critical
Publication of JP3178246B2 publication Critical patent/JP3178246B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は塗膜付プラスチック廃品
の再生処理方法と再生処理装置に関し、さらに詳しく
は、塗膜付プラスチック廃品から補修材を有する塗膜付
プラスチック廃品を分離する方法と分離する装置に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an apparatus for reclaiming plastic waste with a coating film, and more particularly to a method and a method for separating a plastic waste film with a repair material from a plastic waste film. To a device that

【0002】[0002]

【従来の技術】従来、プラスチック廃品に塗装された塗
膜は、通常三次元編目状に架橋して硬化されており熱で
溶融しないし、溶媒などにも溶解しない。このため従来
この塗膜は、機械的に削り取られて除去されていた。し
かしながら、この方法では複雑な立体面をもつ部品では
塗膜の除去に時間がかかるうえに、完全に除去できない
ため、塗膜付プラスチック廃品の再生処理には適してい
ない。
2. Description of the Related Art Conventionally, a coating film applied to a plastic waste product is usually crosslinked and cured in a three-dimensional stitch shape and is not melted by heat, nor is it dissolved in a solvent or the like. For this reason, conventionally, this coating film was mechanically scraped off and removed. However, in this method, it takes a long time to remove the coating film from a part having a complicated three-dimensional surface, and cannot completely remove the coating film.

【0003】そこで従来より熱硬化性樹脂で塗装された
プラスチック廃品の他の再生処理方法として、国際特許
公開番号WO93/01232号公報に開示されるよう
な技術がある。これは図12に示されるように、まず1
00にてバンパ等の塗膜付プラスチック廃品を粉砕す
る。次に110にて、粉砕された塗膜付プラスチック粉
末に適当な処理液を接触させることにより、加水分解さ
せて塗膜成分を低分子化させる。低分子化を行った後、
120にて脱水処理を行い、130で低分子化され脱水
処理された分解塗膜付プラスチック粉末を溶融、混練し
て分解塗膜成分を微細に分散させる。こうして塗膜成分
は成形用再生樹脂組成物内に微細に分散されるので、衝
撃強度の低下が少なく新材と同等程度の衝撃強度の再生
プラスチック製品を得ることができる。
[0003] Therefore as other playback processing method of the plastic waste which has been coated with a thermosetting resin conventionally, there is a technology disclosed in Japanese International Patent Publication No. WO93 / 01232. This is, as shown in FIG.
At 00, the plastic waste with a coating film such as a bumper is crushed. Next, at 110, a suitable treatment liquid is brought into contact with the pulverized plastic powder with a coating film to hydrolyze it to lower the molecular weight of the coating film component. After reducing the molecular weight,
A dehydration treatment is performed at 120, and the degraded plastic powder with a degraded coating that has been depolymerized at 130 is melted and kneaded to finely disperse the degraded coating film components. In this way, the coating film component is finely dispersed in the reclaimed resin composition for molding, so that it is possible to obtain a recycled plastic product having little impact strength reduction and an impact strength equivalent to that of a new material.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、パテや
ウレタン塗料等の補修材にて補修された塗膜付プラスチ
ック廃品は、上記の再生処理方法を用いてもパテやウレ
タン塗料が異物として塗膜中に残る。これは補修材であ
るパテやウレタン等は加水分解により分解されないた
め、加水分解により分解されて低分子化されるという作
用が起きないためである。このように従来の方法では、
加水分解により補修材は低分子化されずに塗膜上に残留
してしまうので、塗膜上に補修材が残されたままで塗膜
付プラスチック廃品を混練し、成形用再生樹脂組成物の
形成が行われる。そしてこの補修材は混練時に溶融され
ず、成形用再生樹脂組成物中又は表面に異物として残っ
てしまうため、形成された成形用再生樹脂組成物は、力
学的性質が低下したり、意匠面に異物を配した製品とな
ってしまう。特に成形用再生樹脂組成物の力学的性質の
低下は衝撃強度の低下として顕著に表れ、また意匠面の
悪化は表面品質に悪影響を及ぼすので、上記方法にて再
生させた成形用樹脂組成物は、衝撃強度及び表面品質を
要しないものに限定しなければならない。
However, plastic waste with a coating film repaired with a repair material such as putty or urethane paint has a problem in that even if the above-mentioned reprocessing method is used, the putty or urethane paint remains as a foreign substance in the coating film. Remains. This is because the putty, urethane, and the like, which are repair materials, are not decomposed by hydrolysis, so that the action of being decomposed by hydrolysis to reduce the molecular weight does not occur. Thus, in the conventional method,
Since the repair material remains on the coating film without being depolymerized due to hydrolysis, the plastic waste with the coating film is kneaded with the repair material remaining on the coating film to form a recycled resin composition for molding. Is performed. And since this repair material is not melted at the time of kneading and remains as a foreign substance in or on the surface of the reclaimed resin composition for molding, the formed reclaimed resin composition for molding has reduced mechanical properties, It becomes a product with foreign substances. In particular, the decrease in the mechanical properties of the regenerated resin composition for molding is remarkably exhibited as a decrease in impact strength, and the deterioration of the design surface adversely affects the surface quality. , Impact strength and surface quality are not required.

【0005】そこで所定の衝撃強度を有する樹脂製品の
再生を上記混練方法で行うために、補修材をプラスチッ
ク廃品から分離、除去する必要がある。しかしながら、
再生可能な樹脂製品か否かを簡易に見分けることは、極
めて難しい。例えば、アセトン等の有機溶剤に塗膜と補
修材の付いたプラスチック廃品を浸漬又は塗布すれば、
ウレタン塗料は剥離するので、容易に見分けることが可
能である。しかし、揮発性の高い液体であるためこの有
機溶剤の処理は密閉系での処理が必須となり、コストが
高くなるという問題を生じていた。
[0005] Therefore the regeneration of the resin product having a predetermined impact strength in order to perform the above kneading method, separating the repairing material from plastic waste, it is necessary to divided. However,
It is extremely difficult to easily determine whether a resin product is renewable. For example, if you immerse or apply plastic waste with a coating and repair materials in an organic solvent such as acetone,
Since the urethane paint peels off, it can be easily identified. However, since the liquid is a highly volatile liquid, the treatment of the organic solvent must be performed in a closed system, which raises a problem that the cost increases.

【0006】本発明は上記実情に鑑みてなされたもので
あり、塗膜に含まれるメラミン架橋を加水分解すること
で塗膜に生じる粘着性により、塗膜付プラスチック廃品
と加水分解しない補修材を有するプラスチック廃品とを
分離、除去して、安価に成形用再生樹脂組成物を得るこ
とを課題とするものである。
[0006] The present invention has been made in view of the above-mentioned circumstances, and the adhesiveness generated in the coating film by hydrolyzing the melamine cross-linking contained in the coating film makes it possible to use a plastic waste with a coating film and a repair material that does not hydrolyze. It is an object of the present invention to separate and remove waste plastic having the resin and obtain a reclaimed resin composition for molding at low cost.

【0007】[0007]

【課題を解決するための手段】上記課題を解決するため
の本発明の請求項1の手段は、メラミン架橋を有する塗
膜と、パテ又はウレタン塗料からなる補修材とが塗布さ
れた塗膜付プラスチック廃品を再生処理する方法であっ
て、塗膜付プラスチック廃品を粉砕して粉砕材とする粉
砕工程と、粉砕材を加水分解処理して塗膜のメラミン架
橋を切り塗膜を低分子化させることによって塗膜に粘着
性を生じさせる粘着性付与工程と、加水分解された粉砕
材を粘着性を生じる塗膜付プラスチック粉砕材と粘着性
を生じない補修材を有する粉砕材に分離する分離工程と
を有することを特徴とするものである。
Means for Solving the Problems According to a first aspect of the present invention, there is provided a film having a coating film having a melamine crosslink and a repair material made of a putty or urethane coating. This is a method of regenerating plastic waste, in which a pulverizing step is performed by pulverizing the coated plastic waste into a pulverized material, and hydrolyzing the pulverized material to cut melamine crosslinks in the coated film to reduce the molecular weight of the coated film. And a separation step of separating the hydrolyzed pulverized material into a pulverized plastic material with a coating film that produces tackiness and a pulverized material having a repair material that does not produce tackiness. And characterized in that:

【0008】また本発明の請求項2の手段は、メラミン
架橋を有する塗膜と、パテ又はウレタン塗料からなる補
修材とが塗布された塗膜付プラスチック廃品を粉砕して
粉砕材とする粉砕手段と、粉砕材を加水分解する加水分
解手段とを備える塗膜付プラスチック廃品の再生処理装
置において、加水分解され粘着性を生じる塗膜付プラス
チック粉砕材を粘着させる付着部材と、付着部材に対向
して配置され加水分解された塗膜付プラスチック粉砕材
を付着部材とで挟持するように付着部材に向かって進退
可能な圧着部材とを備えることを特徴とするものであ
る。
A second aspect of the present invention is a pulverizing means for pulverizing a plastic waste with a coated film coated with a coating film having a melamine crosslink and a repair material composed of a putty or urethane paint to obtain a pulverized material. And a coating waste plastic recycling apparatus having a hydrolysis means for hydrolyzing the pulverized material, wherein an adhesion member for adhering the coated plastic pulverized material that is hydrolyzed and gives tackiness, And a pressure-contact member capable of moving back and forth toward the adhering member so that the hydrolyzed plastic pulverized material with the coating film arranged and hydrolyzed is held between the adhering member.

【0009】さらに請求項3の発明は、メラミン架橋を
有する塗膜とパテ又はウレタン塗料からなる補修材とが
塗布され、かつ粉砕された後加水分解された塗膜付プラ
スチック廃品の再生処理装置において、前記粉砕されか
つ加水分解された塗膜付プラスチック廃品を挟み込んで
走行するとともに粘着性の塗膜付プラスチック廃品を粘
着させる一対のベルトが、互いに平行にかつ接近して配
置されていることを特徴とするものである。
[0009] further to the third aspect invention, the melamine cross-linking
And the repair material consisting of putty or urethane paint
Coated and ground and then hydrolyzed
In the recycling equipment for stick waste,
Sandwiched between the hydrolyzed plastic waste with a coating
While traveling, sticky plastic coated plastic waste
A pair of belts to be worn
It is characterized by being placed .

【0010】[0010]

【作用】請求項1記載の再生処理方法によると、初めに
粉砕工程でメラミン架橋を有する塗膜と、パテ又はウレ
タン塗料からなる補修材とが塗布された塗膜付プラスチ
ック廃品を粉砕して粉砕材とする。次に粘着性付与工程
で粉砕された粉砕材を加水分解処理することにより塗膜
中のメラミン架橋が分解されて塗膜成分は低分子化さ
れ、同時に加水分解された塗膜は粘着性を生じる。しか
しながら、塗膜付プラスチック廃品に塗布されるパテ又
はウレタン塗料からなる補修材中には加水分解で切られ
るメラミン架橋が存在しないので、補修材を有する粉砕
材は粘着性を生じない。そして分離工程で低分子化され
粘着性を生じた塗膜付プラスチック粉砕材はこの粘着性
で加水分解された塗膜を有するプラスチック粉砕材と、
加水分解されない補修材を有するプラスチック粉砕材と
は分離される。
According to the reproduction processing method of the action] according to claim 1, a coating film having a melamine cross-linked with <br/> grinding process initially, the film-coated plastic waste to a repair material is applied consisting of putty or urethane coating Pulverize to a crushed material. Next, by hydrolyzing the pulverized material pulverized in the tackifying step, the melamine crosslinks in the coating film are decomposed, the components of the coating film are reduced in molecular weight, and at the same time, the hydrolyzed coating film produces tackiness. . However, since there is no melamine crosslink that is cut by hydrolysis in the repair material composed of the putty or urethane paint applied to the plastic waste with a coating film, the pulverized material having the repair material does not have tackiness. And the plastic crushed material with a coating film that has been reduced in molecular weight in the separation step and has become sticky is a plastic crushed material having a coating film hydrolyzed with this stickyness,
It is separated from the pulverized plastic with the repair material that is not hydrolyzed.

【0011】請求項2記載の再生処理装置を用いると、
第1に粉砕手段にてメラミン架橋を有する塗膜と、パテ
又はウレタン塗料からなる補修材とが塗布された塗膜付
プラスチック廃品を粉砕して粉砕材とする。次に加水分
解手段にて粉砕された塗膜付プラスチック粉砕材を加水
分解させて、塗膜中のメラミン架橋を切ることで塗膜に
粘着性を生じさせる。次に圧着部材を付着部材に向かっ
て進行させ、加水分解された粉砕材を付着部材と圧着部
材とで挟持し、加水分解によって生じた粘着力にて付着
部材又は圧着部材に塗膜付プラスチック粉砕材を粘着さ
せる。付着部材又は圧着部材に塗膜付プラスチック粉砕
材を粘着させた後、圧着部材を付着部材から退行させて
離間し、付着部材又は圧着部材に粘着されていない補修
材を有する粉砕材を落下させる。次いで付着部材又は圧
着部材に粘着された塗膜付プラスチック粉砕材を掻き取
ることにより、加水分解された塗膜を有するプラスチッ
ク廃品と加水分解されない補修材を有する粉砕材とを分
離する。
According to the reproduction processing device of the second aspect,
First, a plastic waste with a coating film coated with a coating film having melamine crosslinks and a repair material made of a putty or a urethane paint by a pulverizing means is pulverized into a pulverized material. Next, the plastic crushed material with a coating film pulverized by the hydrolysis means is hydrolyzed, and the melamine crosslinks in the coating film are cut off, whereby the coating film is made sticky. Next, the pressing member is advanced toward the attaching member, and the hydrolyzed crushed material is sandwiched between the attaching member and the pressing member. Adhere the material. After the plastic crushed material with a coating film is adhered to the adhesion member or the pressure-bonding member, the pressure-bonded member is retreated from the adhesion member and separated therefrom, and the crushed material having a repair material not adhered to the adhesion member or the pressure-bonding member is dropped. Then, the plastic crushed material with a coating film adhered to the attaching member or the pressure-bonding member is scraped off, thereby separating the plastic waste having the hydrolyzed coating film from the crushed material having the non-hydrolyzed repair material.

【0012】請求項3記載の再生処理装置においては、
再生される塗膜付プラスチック廃品は、予め粉砕され、
かつ加水分解される。その結果、粘着性の生じている塗
膜付プラスチック粉砕材と粘着性のない補修材とが混在
している状態となっている。このように処理された塗膜
付プラスチック廃品が、一対のベルトの間に投入され
と、粘着性の生じている塗膜付プラスチック粉砕材がベ
ルトに粘着する一方、補修材はベルトに付着しない。そ
のため、ベルトが走行し、互いに平行になって対向して
いる箇所を過ぎると、各ベルトが離間するので、粘着性
のない補修材がベルトの間から排出され、これに対して
粘着性のある塗膜付プラスチック粉砕材が、ベルトに粘
着したままとなり、その結果、ベルトから粘着された塗
膜付プラスチック粉砕材を掻き取ることにより、加水分
解された塗膜を有するプラスチック廃品と加水分解され
ない補修材を有する粉砕材とが分離される。
[0012] In reproduction processing equipment according to the third aspect,
Recycled plastic waste with paint film is crushed in advance,
And it is hydrolyzed. As a result,
A mixture of crushed plastic with film and non-sticky repair material
It is in the state of doing. Coating treated in this way
Plastic waste is thrown between a pair of belts.
And plastic ground material with a coating film
The repair material does not adhere to the belt while sticking to the belt. So
Because the belts run and are parallel to each other
The belts are separated from each other after passing
Unrepaired material is discharged from between the belts,
Sticky coated plastic crushed material adheres to the belt
The belt, resulting in tacky paint from the belt.
By scraping the plastic crushed material with membrane,
Plastic waste with unwrapped coating and hydrolyzed
Crushed material with no repair material is separated.

【0013】[0013]

【実施例】本発明の加水分解処理により粘着性が生じる
過程を以下に示す。アクリル−メラミン樹脂の加水分解
の分解機構を図1に示す。アクリル−メラミン樹脂αは
加水分解にてジメチルエーテル結合α1が切られ、アク
リル樹脂βとメラミン樹脂γに分解される。例えばアク
リル−メラミン系樹脂であるクリア(SFX1610)
の塗膜を膜厚35μmとなるようにアルミニウム基板に
塗布し、加水分解処理を行う。図1に示すように、加水
分解によりクリアの成分であるアクリル−メラミン樹脂
αのメラミン架橋であるジメチルエーテル結合α1が切
れて、アクリル樹脂βとメラミン樹脂γに分解される。
この場合の加水分解前のアクリル−メラミン樹脂の赤外
線吸収スペクトルの分布は図2、加水分解後のアクリル
−メラミン樹脂の赤外線吸収スペクトルの分布は図3に
それぞれ示される。図2の横軸は波数(単位がcm-1
を示し、縦軸は吸光度である。この加水分解は、図2に
示される上記樹脂の加水分解前の赤外線吸収スペクトル
の分布と図3に示される加水分解後の赤外線吸収スペク
トルの分布との比較から、波数1080cm-1付近のエ
ーテル結合の赤外線吸収スペクトルの吸収量の減少より
推定される。さらにこのエーテル結合が減少しているこ
とから、塗膜に粘着性を生じていることが推定される。
EXAMPLES The process by which stickiness is produced by the hydrolysis treatment of the present invention is described below. FIG. 1 shows the decomposition mechanism of hydrolysis of the acryl-melamine resin. The acryl-melamine resin α is hydrolyzed to break the dimethyl ether bond α1, and is decomposed into an acrylic resin β and a melamine resin γ. For example, an acrylic-melamine resin clear (SFX1610)
Is applied to an aluminum substrate so as to have a film thickness of 35 μm, and a hydrolysis treatment is performed. As shown in FIG. 1, the dimethylether bond α1, which is a melamine crosslink of the acrylic-melamine resin α, which is a clear component, is broken by hydrolysis, and is decomposed into an acrylic resin β and a melamine resin γ.
In this case, the distribution of the infrared absorption spectrum of the acrylic-melamine resin before hydrolysis is shown in FIG. 2, and the distribution of the infrared absorption spectrum of the acrylic-melamine resin after hydrolysis is shown in FIG. 3, respectively. The horizontal axis in FIG. 2 is the wave number (the unit is cm -1 ).
And the vertical axis is the absorbance. This hydrolysis from a comparison of the distribution of the infrared absorption spectrum after hydrolysis shown in distribution and Figure 3 of the infrared absorption spectrum before hydrolysis of the resin shown in FIG. 2, an ether bond at around wave number 1080 cm -1 Is estimated from the decrease in the amount of absorption in the infrared absorption spectrum. Further, since this ether bond is reduced, it is presumed that the coating film is tacky.

【0014】本発明の再生処理装置の第1実施例を図4
乃至図6を用いて以下に示す。図4は本発明の装置の第
1実施例の概略を示すものである。本実施例の再生処理
装置の主な構成は、塗膜付プラスチック廃品を図示しな
い粉砕手段で粉砕して形成した粉砕材1を、その上面に
載置させる付着部材としての受け台2と、受け台2に対
向して設けられ、受け台2に向かって進退可能な圧着部
材3とである。圧着部材3は、図示しない駆動手段にて
図4の矢印で示す左回り向きに回転可能とされている。
図5に受け台2又は圧着部材3に粘着される塗膜付プラ
スチック粉砕材Pと、粘着されない補修材を有する粉砕
材Hとを示す。塗膜付プラスチック粉砕材Pは、成形用
樹脂組成物本体21と、成形用樹脂組成物本体21表面
に塗布され、メラミン架橋を有する物質からなる塗膜2
2とからなる。一方粘着されない補修材を有する粉砕材
Hは、成形用樹脂組成物本体21と、メラミン架橋を有
する物質からなる塗膜22と、塗膜22表面の損傷部2
2aを補修するエポキシ樹脂又はポリエステル樹脂を主
成分とするパテ24と、塗膜22と補修材24とを被覆
するように塗布されたウレタン塗料23からなる。塗膜
付プラスチック粉砕材Pは塗膜22が露出しており、ウ
レタン塗料23、パテ24を有する粉砕材Hは、塗膜2
2が露出されていない。図6は、加水分解処理により粘
着性を生じた塗膜22同士が粘着した塗膜付プラスチッ
ク粉砕材Pが受け台2と圧着部材3とで挟持される時の
拡大図を示している。
FIG. 4 shows a first embodiment of the reproducing apparatus according to the present invention.
6 to FIG. FIG. 4 schematically shows a first embodiment of the apparatus of the present invention. The main configuration of the reclaiming apparatus of the present embodiment includes a receiving table 2 as an attachment member for placing a crushed material 1 formed by crushing plastic waste with a coating film by crushing means (not shown) on an upper surface thereof; And a crimping member 3 that is provided to face the table 2 and that can move forward and backward toward the receiving table 2. The pressing member 3 is rotatable counterclockwise as indicated by an arrow in FIG. 4 by driving means (not shown).
FIG. 5 shows a pulverized plastic material P with a coating film adhered to the cradle 2 or the pressure bonding member 3 and a pulverized material H having a non-adherent repair material. The plastic pulverized material P with a coating film is formed of a resin composition main body 21 and a coating film 2 which is applied to the surface of the resin composition main body 21 and has a melamine crosslinking property.
Consists of two. On the other hand, the crushed material H having a non-sticking repair material is composed of a molding resin composition body 21, a coating film 22 made of a substance having melamine cross-linking, and a damaged portion 2 on the surface of the coating film 22.
2a is composed of a putty 24 mainly composed of an epoxy resin or a polyester resin for repairing the resin 2a, and a urethane paint 23 applied so as to cover the coating film 22 and the repairing material 24. The crushed material H having the urethane paint 23 and the putty 24 is the same as the crushed material 2 having the urethane paint 23 and the putty 24 exposed.
2 is not exposed. FIG. 6 is an enlarged view when the coated plastic crushed material P to which the coating films 22 having been tackified by the hydrolysis treatment are adhered is sandwiched between the pedestal 2 and the pressure bonding member 3.

【0015】以下に図4乃至図6を用いて第1実施例の
作用を説明する。図示しない粉砕手段にて粉砕され、加
水分解手段にて加水分解処理を施され塗膜成分中のメラ
ミン架橋が加水分解により粘着性を帯びた塗膜付プラス
チック粉砕材1を受け台2の上面に載置させる。この際
粉砕して得られる粉砕材の粒径は、8〜10mmが好ま
しい。次いで圧着部材3を受け台2に向かって所定距離
進行させ、受け台2と圧着部材3とで塗膜付プラスチッ
ク粉砕材1を挟持する。こうして、塗膜22中のメラミ
ン架橋の分解によって生じた粘着力により塗膜付プラス
チック粉砕材Pは、受け台2又は圧着部材3の何れかに
粘着する。塗膜付プラスチック粉砕材Pは図5に示すよ
うにその表面上にメラミン架橋を有する物質からなる塗
膜22を有するので、加水分解処理により粘着性を生
じ、この粘着力で受け台2又は圧着部材3に粘着する。
次いで図4の圧着部材3を図示しない駆動手段にて矢印
の左回り向きに回転させ、塗膜付プラスチック粉砕材P
にせん断力を生じさせる。このせん断力は図6の塗膜付
プラスチック粉砕材P1に矢印で示す左向きにかけら
れ、塗膜付プラスチック粉砕材P2 には矢印で示す右向
きにせん断力がかかる。これに伴って粘着性を持つ塗膜
22は離間して受け台2又は圧着部材3に粘着される。
この時受け台2と圧着部材3とが離間する距離tは、塗
膜付プラスチック粉砕材1の平均粒径よりも大きく平均
粒径の2倍よりも小さいのが好ましい。
The operation of the first embodiment will be described below with reference to FIGS. Pulverized plastic crushed material 1 with a coating film, which is crushed by crushing means (not shown), subjected to a hydrolysis treatment by a hydrolysis means, and the melamine crosslinks in the coating film components become tacky due to hydrolysis, Place. At this time, the particle size of the pulverized material obtained by pulverization is preferably from 8 to 10 mm. Next, the pressing member 3 is advanced toward the receiving table 2 by a predetermined distance, and the coated plastic crushed material 1 is held between the receiving table 2 and the pressing member 3. In this manner, the plastic pulverized material with a coating film P adheres to either the pedestal 2 or the pressure-bonding member 3 due to the adhesive force generated by the decomposition of the melamine bridge in the coating film 22. As shown in FIG. 5, the coated plastic crushed material P has a coating film 22 made of a substance having melamine crosslinks on its surface. It adheres to the member 3.
Next, the pressing member 3 of FIG. 4 is rotated counterclockwise by an arrow by driving means (not shown) to
To generate a shearing force. The shear force is applied to the left indicated by the arrow in the film-coated plastic crushed material P1 in FIG. 6, the film-coated plastic crushed material P 2 shearing force is applied to the right of the arrow. Along with this, the adhesive coating film 22 is separated and adheres to the receiving table 2 or the pressure-bonding member 3.
At this time, it is preferable that the distance t between the pedestal 2 and the pressure bonding member 3 is larger than the average particle diameter of the plastic crushed material 1 with a coating film and smaller than twice the average particle diameter.

【0016】一方、エポキシ樹脂又はポリエステル樹脂
を主成分とするパテ24とウレタン塗料23とを有する
粉砕材Hは、図5に示すように塗膜22がウレタン塗料
23にて被覆されているので加水分解処理で分解されに
くい。このため補修材を有する粉砕材Hは粘着性を生じ
にくく、受け台2又は圧着部材3に粘着されず、受け台
2上に載置される。圧着部材3を回転させたあと、回転
を停止させ圧着部材3を受け台2から離間させる。次い
で受け台2を反転させることにより、粘着していない補
修材を有する粉砕材Hをその自重にて落下させ、受け台
2に粘着される塗膜付プラスチック粉砕材P及び圧着部
材3の表面に粘着される塗膜付プラスチック粉砕材Pを
掻き取る。こうして掻き取った塗膜付プラスチック粉砕
材Pは、パテ24及びウレタン塗料23を含まないの
で、自動車用バンパ等の衝撃強度が必要とされる部材を
形成する成形用再生樹脂組成物として再生可能である。
On the other hand, the crushed material H having a putty 24 mainly composed of an epoxy resin or a polyester resin and a urethane paint 23 has a coating film 22 covered with the urethane paint 23 as shown in FIG. Not easily decomposed by decomposition. For this reason, the crushed material H having the repair material is unlikely to cause adhesiveness, is not adhered to the receiving table 2 or the pressure-bonding member 3, and is placed on the receiving table 2. After rotating the crimping member 3, the rotation is stopped and the crimping member 3 is separated from the receiving table 2. Next, by inverting the pedestal 2, the crushed material H having a non-adhesive repair material is dropped by its own weight, and the crushed plastic crushed material P with a coating film adhered to the pedestal 2 and the surface of the pressure-bonding member 3 are removed. The coated plastic crushed material P to be adhered is scraped off. Since the plastic crushed material P with a coating film thus scraped does not include the putty 24 and the urethane paint 23, the crushed plastic crushed material P can be recycled as a molded resin composition for forming a member requiring impact strength such as an automobile bumper. is there.

【0017】次に本発明の第2実施例を図7乃至図9を
用いて以下に示す。図7は本発明の第2実施例の装置の
概略図を示すものであり、本実施例の装置の主な構成
は、図示しない粉砕手段で粉砕され、加水分解された粉
砕材1をその上部に載置させる付着部材としての受け台
4と、受け台4に対向し受け台4に向かって進退可能に
配置される圧着部材5とからなる。また受け台4と圧着
部材5とが向き合う面上には、それぞれ互いに向き合う
ように柱状部材6が突設される。図8は、受け台4を柱
状部材6の突設する向きから見た平面図を示している。
受け台4は円形であり、柱状部材6はこの受け台4の同
心円周上に等間隔で配置され、さらに受け台4は図示し
ない駆動手段にて図8に示すよう矢印のように右向きに
回転させることができる。圧着部材5も受け台4と同じ
径の円形を呈しており、同心軸上に配置され、受け台4
の柱状部材6に接触しないように同心円周上に交互に配
置される。柱状部材6は互いにtだけ離間して配置され
ており、このtは第1実施例同様分解塗膜付プラスチッ
ク粉砕材の平均粒径よりも大きく、且つ平均粒径の2倍
よりも小さく設定されるのが好ましい。図9は本実施例
の他の形状を示すものであり、受け台4及び圧着部材5
に柱状部材6の位置に対応する部分に貫通孔7aを穿設
させたカバー部材7を受け台4と圧着部材5との互いに
対向する面に設けて構成されている。
Next, a second embodiment of the present invention will be described below with reference to FIGS. FIG. 7 is a schematic view of an apparatus according to a second embodiment of the present invention. The main configuration of the apparatus according to the second embodiment is that a pulverized material 1 pulverized by a pulverizing means (not shown) and hydrolyzed And a crimping member 5 opposed to the pedestal 4 and arranged to be able to advance and retreat toward the pedestal 4. Further, on the surface where the receiving table 4 and the pressure bonding member 5 face each other, columnar members 6 are provided so as to face each other. FIG. 8 is a plan view of the receiving base 4 as viewed from the direction in which the columnar members 6 protrude.
The cradle 4 is circular, and the columnar members 6 are arranged at equal intervals on the concentric circumference of the cradle 4, and the cradle 4 is rotated rightward as shown by an arrow in FIG. Can be done. The crimping member 5 also has a circular shape having the same diameter as the pedestal 4 and is arranged on a concentric axis.
Are alternately arranged coaxially circumference as does not touch the columnar member 6. The columnar members 6 are arranged apart from each other by t, and this t is set to be larger than the average particle diameter of the pulverized plastic material with a decomposition coating film and smaller than twice the average particle diameter as in the first embodiment. Preferably. FIG. 9 shows another shape of the present embodiment.
Is constructed by setting only the surface facing the doctor each other of the cover member 7 cradle 4 and the crimping member 5 is bored a through-hole 7a to a portion corresponding to the position of the columnar member 6.

【0018】以下に第2実施例の装置の作用を示す。粉
砕され、加水分解された粉砕材1を受け台4土に載置す
る。次いで圧着部材5を受け台4に向かって所定距離進
行させ、受け台4と圧着部材5とで挟持する。これによ
り粉末1中の塗膜付プラスチック粉砕材は、加水分解で
生じた粘着力により、受け台4又は圧着部材5の何れか
の表面又は柱状部材6に粘着される。さらに図示しない
駆動手段にて受け台4を図8の矢印で示す右回りの向き
に回転させることで粘着した塗膜付プラスチック粉砕材
にせん断力を生じさせる。第1実施例と同様に、塗膜同
士が粘着されている塗膜付プラスチック粉砕材は、この
せん断力により分離され、塗膜が受け台4又は圧着部材
5或いは柱状部材6の何れかに粘着される。次に受け台
4の回転を停止させ、圧着部材5を受け台4から離間さ
せる。次いで受け台4を反転させると、粘着性を呈さな
い補修材を有する粉砕材はその自重により落下する。こ
うして受け台4、圧着部材5さらに柱状部材6に粘着さ
れた塗膜付プラスチック粉砕材を掻き取ることにより、
パテやウレタン塗料を含まない塗膜付プラスチック粉砕
材を回収することができる。本実施例の受け台4と圧着
部材5の塗膜付プラスチック粉砕材が粘着する面の面積
の和は、第1実施例の受け台2と圧着部材3のプラスチ
ック粉砕材が粘着する面の面積の和よりも大きく形成さ
れている。これにより一度に回収する塗膜付プラスチッ
ク粉砕材の量をより多くすることができる。
The operation of the apparatus according to the second embodiment will be described below. The crushed and hydrolyzed crushed material 1 is placed on a receiving base 4. Next, the pressing member 5 is advanced toward the receiving table 4 by a predetermined distance, and is held between the receiving table 4 and the pressing member 5. Thus the film-coated plastic crushed material in the powder 1, the adhesive force generated by the hydrolysis, is adhered cradle 4 or in any one of the surface or pillars 6 of the crimping member 5. Further, a shear force is generated in the adhered plastic crushed material with a coating film by rotating the receiving table 4 in a clockwise direction indicated by an arrow in FIG. As in the first embodiment, the plastic-coated pulverized material having the coating films adhered to each other is separated by this shearing force, and the coating film is adhered to any of the cradle 4, the pressure-bonding member 5, and the columnar member 6. Is done. Next, the rotation of the receiving base 4 is stopped, and the pressure bonding member 5 is separated from the receiving base 4. Next, when the cradle 4 is turned over, the crushed material having the non-adhesive repair material falls due to its own weight. In this manner, the plastic crushed material with a coating film adhered to the receiving table 4, the pressure bonding member 5, and the columnar member 6 is scraped off.
A pulverized plastic material with a coating film that does not contain putty or urethane paint can be collected. The sum of the areas of the surfaces of the receiving base 4 and the pressure-bonding member 5 where the plastic crushed material with the coating adheres is the area of the surfaces of the receiving stand 2 and the pressing member 3 where the plastic crushed material adheres. Are formed larger than the sum of. This makes it possible to further increase the amount of the pulverized plastic material with a coating film to be collected at one time.

【0019】尚、上記の処理を図9の装置を用いて行う
と、カバー部材7及び往状部材6に塗膜付プラスチック
粉砕材が粘着される。そして塗膜付プラスチック粉砕材
が粘着された後、カバー部材7を図9の矢印の方向に移
動させることにより、カバー部材7により柱状部材6に
粘着される塗膜付プラスチック粉砕材を容易に掻き取る
ことが可能となる。
When the above process is performed using the apparatus shown in FIG. 9, the plastic crushed material with a coating film is adhered to the cover member 7 and the forward member 6. After the coated plastic crushed material is adhered, the cover member 7 is moved in the direction of the arrow in FIG. 9 to easily scrape the coated plastic crushed material adhered to the columnar member 6 by the cover member 7. It is possible to take.

【0020】以下に請求項3の発明の実施例を図10及
び図11を用いて示す。図10はその実施例の装置の概
略を示すものであり、8aは図10の矢印の示す右回り
回転可能で所定距離離間して設けられた一対のプーリー
であり、この一対のプーリー8aにベルト9aを巻いて
第1搬送手段Aを形成する。また図10の矢印が示す左
回り回転可能に設けられた一対のプーリー8bにベルト
9bを巻いて第2搬送手段Bを形成する。
[0020] denoted by 10 and 11 the actual施例of the invention of claim 3 below. Figure 10 shows a schematic of a device for the real施例, 8a are a pair of pulleys provided in clockwise rotatable at a predetermined distance indicated by the arrow in FIG. 10, a belt of this pair of pulleys 8a The first conveying means A is formed by winding 9a. Further, a belt 9b is wound around a pair of pulleys 8b rotatably provided as indicated by arrows in FIG.

【0021】本実施例の装置は、これら第1搬送手段A
と第2搬送手段Bをその一対のプーリー8a、8bが
面に対して垂直方向に配列されるようにtだけ離間させ
て平行に設けられる。また第1搬送手段Aと第2搬送手
段Bとがそれぞれが対向するベルト9側と反対側にスク
レイパー12をその先端がベルト9a、9bに接するよ
うに設けられている。さらに第1搬送手段Aのベルト9
aと第2搬送手段Bのベルト9bとが対向する部位の鉛
直下方で下方側のプーリー8a、8bよりもさらに下側
に受皿10を配置させる。またスクレイパー12の鉛直
下方にも受皿11が配置されている。
The apparatus according to the present embodiment employs these first transport means A
When it is separated by t so as to be arranged in the vertical direction of the second conveying means B the pair of pulleys over 8a, 8b are against earth <br/> surface
Are provided in parallel . Further, the first transporting means A and the second transporting means B are provided with a scraper 12 on the opposite side to the belt 9 side facing each other such that the tips thereof contact the belts 9a and 9b. Further, the belt 9 of the first transport unit A
The tray 10 is disposed below the pulleys 8a and 8b on the lower side of the portion where the belt member 9a and the belt 9b of the second transport means B face each other. The tray 11 is also arranged vertically below the scraper 12.

【0022】つぎにその作用を以下に示す。粉砕され、
加水分解された粉砕材1は、図10の上方から第1搬送
手段Aと第2搬送手段Bの間に供給される。この第1搬
送手段Aのベルト9aと第2搬送手段Bのベルト9bに
より粉砕材1は挟持されるため、粘着力を有する塗膜付
プラスチック粉砕材Pは、ベルト9a及びベルト9bに
粘着する。そして順次図10の下方に搬送されるが、下
方側のプーリー8aとプーリー8Bの中心間を通過する
と、ベルト9aとベルト9bとで挟持されなくなるため
ベルト9a又はベルト9bに粘着されない補修材を有す
る粉砕材Hは落下して受皿10にて回収される。またベ
ルト9a及びベルト9bに粘着されて第1搬送手段Aと
第2搬送手段Bとが対向する側と反対側に搬送された塗
膜付プラスチック粉砕材Pは、スクレイパー12にて掻
き取られ受皿11にて回収される。こうして塗膜付プラ
スチック粉砕材Pと補修材を有する粉砕材Hを分離する
ことが可能となる。
Next, the operation will be described below. Crushed,
The hydrolyzed crushed material 1 is supplied between the first transport means A and the second transport means B from above in FIG. Since the pulverized material 1 is sandwiched between the belt 9a of the first transporting means A and the belt 9b of the second transporting means B, the plastic pulverized material P having an adhesive film adheres to the belts 9a and 9b. Then, it is sequentially conveyed downward in FIG. 10, but when it passes between the centers of the pulleys 8a and 8B on the lower side, it is no longer sandwiched between the belts 9a and 9b, and thus has a repair material that is not adhered to the belt 9a or the belt 9b. The crushed material H falls and is collected in the tray 10. Further, the plastic crushed material P with a coating film adhered to the belts 9a and 9b and conveyed to the opposite side of the side where the first conveying means A and the second conveying means B are opposed to each other is scraped off by the scraper 12 to receive the powder. Collected at 11. In this way, it becomes possible to separate the plastic crushed material P with a coating film and the crushed material H having a repair material.

【0023】本実施例についても、第1搬送手段Aと第
2搬送手段Bを離間させる距離tは粉砕され、加水分解
された粉末1の平均粒径よりも大きく、且つ、平均粒径
の2倍よりも小さくするのが最も好ましい。また、塗膜
付プラスチック粉末1にせん断力を与えるため、プーリ
ー8aとプーリー8bとの回転速度に速度差を設ける。
こうして第1実施例と同様に塗膜付プラスチック粉末に
速度差に伴い発生するせん断力を与えて、塗膜22同士
が粘着している塗膜付プラスチック粉末Pについてもそ
のせん断力にて分離することができるので、塗膜付プラ
スチック粉末Pを回収する量をさらに増やすことが可能
となる。またプーリー8a同士及びプーリー8b同士の
それぞれを地面に対して垂直方向に離間して配列する以
外に、地面に対して所定の鋭角度で傾斜した方向に離間
させて配列することも可能である。
Also in this embodiment, the distance t for separating the first conveying means A and the second conveying means B is larger than the average particle diameter of the pulverized and hydrolyzed powder 1 and the average particle diameter is 2 times. Most preferably less than twice. In order to apply a shearing force to the plastic powder 1 with a coating film,
Providing a speed difference to the rotational speed of the over 8a and a pulley over 8b.
Thus, similarly to the first embodiment, the shear force generated due to the speed difference is given to the coated plastic powder, and the coated plastic powder P to which the coated films 22 are adhered is also separated by the shear force. Therefore, the amount of the plastic powder P with a coating film to be collected can be further increased. Also between the pulley over 8a and between pulleys 8b
Following each be arranged at a distance from each other in vertical direction with respect to the ground plane
Outside, separated in the direction inclined at a predetermined acute angle with respect to the ground
Rukoto be arranged by is also possible.

【0024】図11は第3実施例をさらに改良して、第
3のプーリー81a、81bを追加してベルト9a、9
bを略三角形状に巻き掛けて走行させ、図10の水平方
向のスクレイパー12の位置を離間させたものである。
これとともに図10の装置よりも受皿10と受皿11の
距離が大きくなる。これにより塗膜付プラスチック粉砕
材Pと補修材を有する粉砕材Hとの回収位置がより離間
されたので、塗膜付プラスチック粉砕材Pと補修材を有
する粉砕材Hとの混入を防ぐことが可能となる。さらに
一対のプーリー8aの間と一対のプーリー8bの間に、
ベルトに平行となるようにベルトガイド13を配置させ
ることにより、ベルト9aとベルト9bの間隔tを一定
とすることが可能となる。
FIG. 11 shows a further improvement of the third embodiment, in which belts 9a, 9b are added by adding third pulleys 81a, 81b.
b is wound around in a substantially triangular shape and run, and the position of the scraper 12 in the horizontal direction in FIG. 10 is separated.
At the same time, the distance between the pan 10 and the pan 11 becomes larger than in the apparatus of FIG. As a result, the collecting positions of the coated plastic crushed material P and the repaired crushed material H are further separated, so that the mixing of the coated plastic crushed material P and the repaired crushed material H can be prevented. It becomes possible. Further, between the pair of pulleys 8a and between the pair of pulleys 8b,
By arranging the belt guide 13 so as to be parallel to the belt, the interval t between the belt 9a and the belt 9b can be made constant.

【0025】[0025]

【発明の効果】本発明の請求項1記載の塗膜付きプラス
チック廃品の再生処理方法によれば、始めに塗膜付プラ
スチック廃品を粉砕し、加水分解して塗膜に含まれるメ
ラミン架橋を切ることにより塗膜に粘着力を生じさせ
る。塗膜に粘着性が生じる際、粉砕材中に含まれる補修
材はメラミン架橋を有さないので粘着性を生じない。こ
うして加水分解後に粉砕材を任意の部材に接触させ、パ
テやウレタン塗料から粘着性を呈さない補修材を有する
粉砕材と、加水分解により粘着性を生じた塗膜付プラス
チック粉砕材とを安価に分離することが可能となる。
According to the method for reclaiming plastic waste with a coated film according to the first aspect of the present invention, the plastic waste with a coated film is first crushed and hydrolyzed to cut melamine crosslinks contained in the coated film. This causes the coating film to become tacky. When the coating film becomes tacky, the repairing material contained in the pulverized material does not have melamine cross-linking and thus does not produce tackiness. Thus, after the hydrolysis, the crushed material is brought into contact with an arbitrary member, and a crushed material having a repair material that does not exhibit tackiness from a putty or a urethane paint, and a crushed plastic coated material that has become tacky due to hydrolysis are inexpensively prepared. It becomes possible to separate.

【0026】また本発明の請求項2記載の塗膜付プラス
チック廃品の再生処理装置によれば、塗膜付プラスチッ
ク廃品を粉砕して粉砕材とし、この粉砕材を加水分解処
理したのち付着部材と圧着部材とで挟持する。これによ
り塗膜の粘着性により付着部材又は圧着部材に粘着させ
る。そして粘着性を有する塗膜付プラスチック粉砕材を
付着部材又は圧着部材に粘着させた後、互いに離間させ
ることにより粘着しない補修材を有する粉砕材を落とし
て、補修材を有する粉砕材と塗膜付プラスチック粉砕材
とを分離することを可能とする。
According to a second aspect of the present invention, there is provided an apparatus for reclaiming plastic waste with a coating film, which crushes the plastic waste material with a coating film into a pulverized material, hydrolyzes the pulverized material, and adheres to the adhered member. It is clamped between the crimping members. Thereby, the adhesion of the coating film is caused to adhere to the adhesion member or the pressure-bonding member. Then, after the coated plastic crushed material having the adhesive property is adhered to the adhesion member or the pressure-bonded member, the crushed material having the repair material that does not adhere by dropping apart from each other is dropped, and the crushed material having the repair material and the coated material are coated. It is possible to separate it from plastic crushed material.

【0027】さらに本発明の請求項3記載の塗膜付のプ
ラスチック廃品の再生処理装置によれば、粉砕しかつ加
水分解処理した塗膜付プラスチック廃品を、互いに平行
に配置された一対のベルトの間に投入すると、粘着性の
生じている塗膜付プラスチック廃品がベルトに付着する
一方、パテなどによって粘着性が生じていない粉砕材が
ベルトに挟まれた状態となる。その結果、ベルトが走行
することにより、粘着性のない粉砕材がベルトによる挟
持が解けてベルトの間から排出され、これに対して粘着
性のある塗膜付プラスチック廃品はベルトに付着したま
まとなるので、加水分解された塗膜を有するプラスチッ
ク廃品と加水分解されない補修材を有する粉砕材とを分
離することができる。
Further, according to the apparatus for reclaiming plastic waste with a coating film according to the third aspect of the present invention, it is pulverized and processed.
Water-decomposed coated plastic waste products are parallel to each other
When inserted between a pair of belts placed in
Generated plastic waste with coating adheres to the belt
On the other hand, crushed material that does not have stickiness due to putty etc.
It is in a state of being sandwiched by the belt. As a result, the belt runs
By doing so, the non-sticky pulverized material is pinched by the belt.
The paper is released from between the belts and sticks to it.
Waste plastic with a coating film adheres to the belt.
Plastics with hydrolyzed coatings
Waste and pulverized material with non-hydrolyzed repair material
Can be released.

【図面の簡単な説明】[Brief description of the drawings]

【図1】塗膜成分中のアクリル−メラミン架橋点の分解
を示す図である。
FIG. 1 is a diagram showing the decomposition of acryl-melamine crosslinking points in coating film components.

【図2】加水分解前のSFX1610の赤外線吸収スペ
クトルを示す。
FIG. 2 shows an infrared absorption spectrum of SFX1610 before hydrolysis.

【図3】加水分解後のSFX1610の赤外線吸収スペ
クトルを示す。
FIG. 3 shows an infrared absorption spectrum of SFX1610 after hydrolysis.

【図4】本発明の第1実施例の装置の概略を示す正面図
である。
FIG. 4 is a front view schematically showing the apparatus according to the first embodiment of the present invention.

【図5】本発明の塗膜付プラスチック粉砕材と、補修材
を有する粉砕材を示すモデル図である。
FIG. 5 is a model diagram showing a pulverized material having a coating film and a pulverized material having a repair material according to the present invention.

【図6】本発明の塗膜付プラスチック粉砕材の塗膜同士
が粘着されて付着部材と圧着部材とで挟持されたモデル
図を示す。
FIG. 6 is a model diagram in which coating films of the plastic pulverized material with a coating film of the present invention are adhered to each other and sandwiched between an adhesion member and a pressure bonding member.

【図7】本発明の第2実施例の装置の概略を示す正面図
である。
FIG. 7 is a front view schematically showing an apparatus according to a second embodiment of the present invention.

【図8】図7のD方向から見た平面図である。FIG. 8 is a plan view seen from a direction D in FIG . 7 ;

【図9】本発明の第2実施例にさらに改良を加えた正面
図である。
FIG. 9 is a front view in which a second embodiment of the present invention is further improved.

【図10】本発明の第3実施例の装置の概略を示す正面
図である。
FIG. 10 is a front view schematically showing an apparatus according to a third embodiment of the present invention.

【図11】本発明の第3実施例にさらに改良を加えた正
面図である。
FIG. 11 is a front view obtained by further improving the third embodiment of the present invention.

【図12】従来の加水分解による塗膜付プラスチック廃
品のリサイクル工程を示す略図である。
FIG. 12 is a schematic view showing a conventional process of recycling plastic waste with a coating film by hydrolysis.

【符号の説明】[Explanation of symbols]

1 加水分解された塗膜付プラスチック粉末 2 受台 3 圧着部材 P 塗膜付プラスチック粉砕材 H 補修材を有する粉砕材 DESCRIPTION OF SYMBOLS 1 Hydrolyzed plastic powder with a coating film 2 Cradle 3 Crimping member P Plastic crushed material with a coating film H crushed material having a repair material

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】メラミン架橋を有する塗膜と、パテ又はウ
レタン塗料からなる補修材とが塗布された塗膜付プラス
チック廃品を再生処理する方法であって、前記塗膜付プ
ラスチック廃品を粉砕して粉砕材とする粉砕工程と、該
粉砕材を加水分解処理して前記塗膜のメラミン架橋を切
り前記塗膜を低分子化させることによって前記塗膜に粘
着性を生じさせる粘着性付与工程と、加水分解された前
記粉砕材を粘着性を生じる塗膜付プラスチック粉砕材と
粘着性を生じない補修材を有する粉砕材に分離する分離
工程とを有することを特徴とする塗膜付プラスチック廃
品の再生処理方法。
1. A method for reclaiming plastic waste with a coating film on which a coating film having a melamine bridge and a repair material comprising a putty or a urethane paint are applied, wherein the plastic waste material with a coating film is crushed. A pulverizing step of making the pulverized material, a tackifying step of causing the coated film to become tacky by hydrolyzing the pulverized material to cut melamine crosslinks of the coating film and to reduce the molecular weight of the coating film, Separating the hydrolyzed pulverized material into a coated pulverized material having a tackiness and a pulverized material having a non-adhesive repair material. Processing method.
【請求項2】メラミン架橋を有する塗膜と、パテ又はウ
レタン塗料からなる補修材とが塗布された塗膜付プラス
チック廃品を粉砕して粉砕材とする粉砕手段と、該粉砕
材を加水分解する加水分解手段とを備える塗膜付プラス
チック廃品の再生処理装置において、 加水分解され粘着性を生じる塗膜付プラスチック粉砕材
を粘着させる付着部材と、該付着部材に対向して配置さ
れ加水分解された前記塗膜付プラスチック粉砕材を前記
付着部材とで挟持するように該付着部材に向かって進退
可能な圧着部材とを備えることを特徴とする塗膜付プラ
スチック廃品の再生処理装置。
2. A pulverizing means for pulverizing a plastic waste with a coating film coated with a coating film having a melamine crosslink and a repair material made of a putty or urethane paint to obtain a pulverizing material, and hydrolyzing the pulverizing material. An apparatus for regenerating a coated plastic waste provided with a hydrolysis means, comprising: an adhesive member for adhering a pulverized plastic coated material that is hydrolyzed to give a tackiness; and an adhesive member disposed opposite to the adhesive member and hydrolyzed. An apparatus for reclaiming plastic waste with a coating film, comprising: a pressure-bonding member that can advance and retreat toward the adhesion member so as to sandwich the plastic crushed material with the coating film with the adhesion member.
【請求項3】メラミン架橋を有する塗膜とパテ又はウレ
タン塗料からなる補修材とが塗布され、かつ粉砕された
後加水分解された塗膜付プラスチック廃品の再生処理装
置において、 前記粉砕されかつ加水分解された塗膜付プラスチック廃
品を挟み込んで走行するとともに粘着性の塗膜付プラス
チック廃品を粘着させる一対のベルトが、互いに平行に
かつ接近して配置されていることを特徴とする塗 膜付プ
ラスチック廃品の再生処理装置。
3. A coating film having a melamine crosslink and putty or urea.
Repair material consisting of tin paint was applied and crushed
Reprocessing equipment for post-hydrolyzed coated plastic waste
In location, the ground and hydrolyzed film-coated plastic waste
Plus with sticky coating while traveling with products sandwiched
A pair of belts that stick tic waste
A recycling apparatus for waste plastics with a coating film, which is disposed close to the apparatus.
JP12241494A 1994-06-03 1994-06-03 Reprocessing method and recycling equipment for plastic waste with coating film Expired - Fee Related JP3178246B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12241494A JP3178246B2 (en) 1994-06-03 1994-06-03 Reprocessing method and recycling equipment for plastic waste with coating film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12241494A JP3178246B2 (en) 1994-06-03 1994-06-03 Reprocessing method and recycling equipment for plastic waste with coating film

Publications (2)

Publication Number Publication Date
JPH07329062A JPH07329062A (en) 1995-12-19
JP3178246B2 true JP3178246B2 (en) 2001-06-18

Family

ID=14835232

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12241494A Expired - Fee Related JP3178246B2 (en) 1994-06-03 1994-06-03 Reprocessing method and recycling equipment for plastic waste with coating film

Country Status (1)

Country Link
JP (1) JP3178246B2 (en)

Also Published As

Publication number Publication date
JPH07329062A (en) 1995-12-19

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