JP3164709B2 - Solid soft finish composition - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a powdery, granular or tablet-type solid soft finish composition having excellent dispersibility and solubility in water.

[0002]

2. Description of the Related Art As a softening agent, a liquid type in which a di-long chain alkyl type cationic softening agent is blended in an amount of 3 to 15% by weight is mainly used, but in order to achieve a higher concentration. Solid forms of the powder or tablet type have also been studied. The biggest problem when solidifying a softening agent and using it as a softening finish is that it must be easily dispersed and dissolved when put into water.

[0003] JP-A-57-193574 discloses that urea may be blended in order to improve the dispersion efficiency of cationic softening agent particles. JP-A-59-8
No. 800 is prepared by mixing a di-long-chain alkyl-type quaternary ammonium salt powder having an average particle diameter of 150 μm or less with a silica fine powder, adding a nonionic surfactant, granulating the mixture, and further adding zeolite. It is disclosed that when granulated, a granular softener having good water dispersibility can be obtained. In addition, Japanese Unexamined Patent Publication
No. 2,536,988 discloses a granular soft finish having improved dispersibility and solubility obtained by granulating a foamed composition comprising an acidic powder and an alkaline carbonate powder and a dilong chain alkyl type quaternary ammonium salt powder. Is disclosed. JP-A-63-
No. 138000 discloses that a powdery or tablet-type soft finish having improved solubility can be obtained by adsorbing a cationic soft base onto a water-soluble powder having a large oil absorption such as urea and light ash. It has been disclosed.

[0004] Further, Japanese Patent Application Laid-Open No. Hei 2-182972 discloses that
The cationic flexible base having a di long chain alkyl group, containing a quaternary ammonium salt having a mono long chain alkyl group and a urea or polyamine alkylene oxide adduct,
A solid soft finish composition with improved dispersibility is disclosed.

However, these powdery, granular or tablet-type solid soft finishes are not yet sufficiently dispersible and soluble in water, and also have a component that contributes to the softening effect of the soft-finished fiber (hereinafter referred to as "soft"). For example, the blending amount of the component (A) in JP-A-2-182972 is 30 to 60 in the soft finish composition.
Since the amount is about% by weight, it is necessary to increase the use amount in order to obtain a sufficient softening effect.

Accordingly, it has been desired to improve the concentration of the softening effect component in the soft finish composition without impairing the dispersibility and solubility of the soft finish composition in water.

[0007]

Means for Solving the Problems In view of these circumstances, the present inventors have conducted intensive studies and as a result, have found that an imidazoline compound having an amide bond or a neutralized salt thereof, or an alkylated form of the imidazoline compound has urea. Or a urea derivative,
Or, in combination with an alkylene oxide adduct of a polyamine, and further by adding an imidazoline compound having no amide bond or a neutralized salt thereof, the amount of the urea or polyamine alkylene oxide adduct that does not contribute to the softening effect is reduced. And found that the softness per weight of the soft finish composition could be improved, and the present invention was completed.

That is, the present invention provides the following (A) component, (B)
An object of the present invention is to provide a solid soft finish composition comprising a component and component (C). Component (A): a compound represented by the following general formula (I) and a neutralized salt thereof, a compound represented by the following general formula (II), and a compound represented by the following general formula (III) At least one selected.

[0009]

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[Wherein, R ¹ and R ² represent a linear or branched alkyl or alkenyl group having 10 to 26 carbon atoms which may have a hydroxyl group. ]

[0011]

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[Wherein, R ¹ and R ^{2 have the} above-mentioned meanings. R ³ represents an alkyl group having 1 to 5 carbon atoms which may have a hydroxyl group. X ^-: it represents an organic anion groups or inorganic anion groups. ]

[0013]

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[Wherein, R ¹ , R ² , R ³ , X ^{− have} the same meaning as above. Component (B): a compound represented by the following general formula (IV) and a neutralized salt thereof, a compound represented by the general formula (V), a compound represented by the following general formula (V
At least one selected from the group consisting of the compounds represented by I) and the compounds represented by the general formula (VII).

[0015]

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[Wherein, R ¹ represents the same meaning as described above. ]

[0017]

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[Wherein, R ¹ , R ³ , X ⁻ : have the above-mentioned meanings. ]

[0019]

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[Wherein, R ¹ , R ³ , and X ^{− have the} above-mentioned meanings. ]

[0021]

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[Wherein, R ¹ represents the above-mentioned meaning.

[0023] ^{Z: -NHR 3, -NR 3 R} 3 or ^{-N + R 3 R 3 R 3} X - indicates a. Here, R ³ , X ^- has the above meaning. Component (C): One or more selected from the group consisting of urea, urea derivatives, thiourea, p-toluenesulfonic acid salts, water-soluble inorganic salts, and polyether compounds. However, the total of the components (A) and (B) in the composition is 40.0%
~ 99.99% by weight, (C) component is 0.01 ~ 60.0% by weight,
The weight ratio of component (A) to component (B) is (A) / (B) = 95
/ 5 to 10/90.

Hereinafter, the present invention will be described in detail.

[Component (A)] Specific examples of the compound represented by the general formula (I) used as the component (A) of the composition of the present invention include the following compounds. .

[0026]

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As the component (A) of the composition of the present invention, a neutralized salt of the compound (I) may be used. In this case, as the acid used for neutralization, inorganic acids such as hydrochloric acid, nitric acid, phosphoric acid, and sulfuric acid;
Alternatively, organic acids having 6 or less carbon atoms such as acetic acid, lactic acid, glycolic acid, citric acid, maleic acid, and paratoluenesulfonic acid can be used.

The component (A) is represented by the above general formula (I)
Compounds represented by I) or general formula (III) can also be used.
In the compound (II) or (III), X ^- is an organic anion groups or inorganic anionic groups, such as halogen anion, phosphate anion, sulfate anion, CH ₃ SO ₄ ^-,
C ₂ H ₅ SO ₄ ⁻ , acetate anion, lactate anion, glycolate anion, citrate anion, maleate anion and paratoluenesulfonate anion.

These compounds can be obtained by alkylating compound (I) by a known method using an alkyl halogen compound such as methyl chloride or a dialkyl sulfate compound such as dialkyl sulfate. The anion group of the alkylated product thus obtained can be converted to another desired anion group by a salt exchange reaction. Examples of compounds corresponding to these are as follows.

[0030]

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[0031]

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[Component (B)] As the compound represented by the general formula (IV), which is the component (B) of the composition of the present invention, more specifically, for example, the following compounds are exemplified.

[0033]

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As the component (B) of the composition of the present invention, a neutralized salt of the compound (IV) may be used. In this case, the above (A)
Neutralization can be carried out using the same acids as described for the components. Further, an alkylated compound of the compound (IV) can be used. An example is as follows.

[0035]

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The components (A) and (B) of the present invention include the above-mentioned compound (I) in the synthesis system of compound (I).
V) may be used as long as the proportion of both is within the range specified in the present invention.

[Component (C)] The component (C) of the composition of the present invention is a member selected from the group consisting of urea, urea derivatives, thiourea, p-toluenesulfonic acid salts, water-soluble inorganic salts and polyether compounds. Or two or more. Here, the urea derivative is an N-alkyl urea substituted with an alkyl group having 1 to 5 carbon atoms, such as methyl urea and N-ethyl urea. Water-soluble inorganic salts include K ₂ CO ₃ , Na ₂ CO ₃ , NaCl,
KCl and the like.

The polyether compound is obtained by adding an alkylene oxide containing ethylene oxide as an essential component to a compound having at least three active hydrogens, and the total weight of the polyethylene oxide chains is 50% of the total weight. % Or more, preferably 80% or more, and more preferably a polyether compound or a derivative thereof having a molecular weight of 5,000 to 2,000,000. Here, the molecular weight means the weight average molecular weight.

Examples of the compound having three or more active hydrogens as a starting material of the polyoxyalkylene adduct include polyhydric alcohols such as glycerin, pentaerythritol, sorbitol, sucrose, polyglycerin, polyvinyl alcohol, and polyvinyl acetate. There are saponified compounds and the like, polyhydric phenols include phenolic resins and formalin condensates of alkylphenols, and polyamine compounds such as diethylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine, and polyethyleneimine. 3 active hydrogen
There are polyamine compounds having two or more alkanolamines such as diethanolamine. In addition, a partially amidated product or an N-alkyl-substituted polyamine which is a derivative of these polyamines or diethanolamines and which has three or more active hydrogens remaining can also be used. The production of a polyether compound which is a polyoxyalkylene adduct can be easily carried out by adding an alkylene oxide essentially containing ethylene oxide to a compound having three or more active hydrogens by a usual method. Among them, especially ethylene oxide (hereinafter abbreviated as EO) alone or EO and propylene oxide (hereinafter P)
(Abbreviated as O) or a partially block-like additive is preferable, and the order of addition may be any order. However, it is better to add EO after adding PO first, and then it is preferable to add EO. can get.

[Soft Finish Composition] In the soft finish composition of the present invention, the blending amounts of the components (A), (B) and (C) are determined by the sum of the components (A) and (B). Is 40.0 ~
99.99% by weight, component (C) is 0.01 to 60.0% by weight,
The weight ratio of component (A) to component (B) is (A) / (B) = 95
/ 5 to 10/90. If the compounding ratio is out of this range, the object of the present invention cannot be achieved. The mixing ratio of the components (A) and (B) is preferably 60.0 to 99.99% by weight in the composition, and the component (C) is preferably 0.01 to 4% by weight.
0.0% by weight, the weight ratio of component (A) to component (B) is (A)
/ (B) = 95/5 to 50/50, more preferably the total amount of the components (A) and (B) in the composition is 75 to 95% by weight, and the component (C) is 5 to 25% by weight. %, (A) component and (B)
The weight ratio of the components is (A) / (B) = 90/10 to 70/30.

The method for preparing the solid soft finish composition of the present invention containing the components (A), (B) and (C) is not particularly limited. After the components are melted, mixed, cooled and solidified, a method of pulverizing and pulverizing may be used.

Further, in the composition of the present invention, the dissolution and solubility in water is maintained at an extremely excellent level, and the composition is improved in caking (consolidation) resistance when stored for a long period of time; An inorganic powder (hereinafter, referred to as a component (D)) can be further blended as a carrier for absorbing the fragrance. Here, an example of the component (D) is as follows.

Amorphous silica compound A compound having silica as a main skeleton is preferable. As the second component, Al ₂ O ₃ , M ₂ O (where M is an alkali metal), MeO (where Me is an alkaline earth metal) A compound containing such as is preferred. Further, not only two elements but also three elements, four elements, and the like are preferably used. Specifically, the following (i) to (iii)
Are exemplified.

(I) As a material containing silica as a main component, Tokusil NR, PR, trade name, manufactured by Tokuyama Soda Co., Ltd.
AL-1, Nipsil N, a trade name of Nippon Silica Co., Ltd.
S, Nip Seal NA-R, Nip Seal ES, trade names made by Degussa SIPERNAT 22, SIPERNAT 50, DUROSIL,
ZEOSIL 45 and TIXOSIL 38, trade names manufactured by Korea and France Chemical Company, and Carplex 100, trade name manufactured by Shionogi Pharmaceutical Co., Ltd. (Ii) As those containing calcium silicate as a main component,
HUBERS ORB 600 manufactured by Huber Corporation. (Iii) As those containing aluminosilicate as a main component,
Examples thereof include those represented by the general formula (v) or (vi), and examples thereof include Aluminum Silicate P820 (trade name, manufactured by Degussa Corporation) and TIXOLEX 25 (trade name, manufactured by Han France Chemical Co., Ltd.). x (M ₂ O) · Al ₂ O ₃ · y (SiO ₂ ) · w (H ₂ O) (v) [wherein, M represents an alkali metal such as sodium and potassium. x, y, w: Indicates the number of moles of each component within the following numerical range. 0.2 ≦ x ≦ 2.0 0.5 ≦ y ≦ 10.0 w ≧ 0] x (M ₂ O) ・ y (M ₂ O) ・ Al ₂ O ₃・ z (SiO ₂ ) ・ w (H ₂ O) (vi) Medium, Me: alkaline earth metals such as calcium and magnesium. x, y, z, w: Indicates the number of moles of each component within the following numerical range. 0.001 ≦ x ≦ 0.1 0.2 ≦ y ≦ 2.0 0.5 ≦ z ≦ 10.0 w ≧ 0].

Crystalline silica compound (i) A crystalline layered silicate represented by the general formula (vii).

M ₂ Si _a O _{(2a + 1)} · b (H ₂ O) (vii) [wherein, M is as defined above.

A, b: numbers satisfying 1.5 ≦ a ≦ 4 and 0 ≦ b ≦ 25. The method for producing the present silicate is described, for example, in JP-A-60-22789.
No. 5 discloses a method for producing the same, which is generally obtained by firing amorphous glassy sodium silicate at 200 to 1000 ° C. to make it crystalline. For details of the synthesis method,
For example, Phys. Chem. Glasses., 7, 127-138 (1966), Z. K
ristallogr., 129, 396-404 (1969).

The crystalline phyllosilicate is available from Hoechst AG under the trade name of Na-SKS # 6 (δ-Na ₂ Si ₂ O ₅ ).
In the present invention, those having a particle size of 10 to 500 μm can be used, and those having a particle size of 10 to 300 μm are preferred.

(Ii) A synthetic crystalline silicate represented by the general formula (viii) or a hydrate thereof. hM ₂ O.iSiO ₂ .jMeO (viii) [wherein, M, Me: has the above meaning. h, i, j: each indicates a positive number, i / h = 0.5 to 2.0 j / h = 0.005 to 1.0. The synthetic crystalline silicate represented by the general formula (viii) can be obtained, for example, by the method described in Japanese Patent Application No. 4-361399. In Raman scattering spectra for a range of 900cm ^-1 ~1200cm ^-1 Among these, at least 970 ± 20 cm ^-1
Those which show a main shift peak are preferred.

(Iii) Zeolite For example, Chemical Dictionary (Kyoritsu Shuppan Co., Ltd., 26th printing, 1963)
Year)).

(Iv) Smectite For example, Chemical Dictionary (Kyoritsu Shuppan Co., Ltd., 26th printing, 1964)
Year)) in the section of “Montmorillon cough”. Also, as a commercial product, for example,
"Bengel" (trade name, manufactured by Toyoko Junko Co., Ltd.), "Benton LT" (trade name, manufactured by NL Chemicals, Inc.), "Kunipia G" (trade name, manufactured by Kunimine Industries, Ltd.) It is possible.

Calcium silicate An example of the product is Fluorite R (trade name, manufactured by Tokuyama Soda Co., Ltd.).

Magnesium silicate calcium carbonate Callite KT manufactured by Shiraishi Industry Co., Ltd. is exemplified.

Magnesium carbonate An example is magnesium TT manufactured by Tokuyama Soda Co., Ltd.

Pearlite (Perlite) Perlite 4159 manufactured by Daikarite Orient Co., Ltd.
Is exemplified.

The particle size of the component (D) is 10 to 500 μm,
Preferably it is 10 to 300 μm.

When the component (D) is incorporated into the composition, the weight ratio of the total amount of the components (A), (B) and (C) to the component (D) is [(A) + (B) +
(C)] / (D) = 70 / 30-100 / 0, preferably 80 /
It is blended so as to be 20 to 99.5 / 0.5, more preferably 90/10 to 99.0 / 1.0.

The amount of the component (D) in the composition of the present invention is
When the ratio is more than 70/30, the content of the components (A) and (B), which are softener bases, is reduced, so that the amount of the softener composition used by consumers per use increases, which is preferable. Absent.

When the component (D) is blended in the composition of the present invention, usually, a powder of a mixture comprising the components (A), (B) and (C) is mixed with the component (D). In that case, various mixers, such as a Henschel mixer, a ribbon blender, and a Loedige mixer, can be used.

Further, in the composition of the present invention, at least one fragrant compound selected from the group consisting of groups (G) and (H) is blended in order to suppress the peculiar odor of the soft finish base. be able to.

Group (G): a compound having a total carbon number of 7 to 20 and having an aldehyde group or a ketone group directly bonded to an aromatic ring. Group (H): a cinnamic aldehyde having a total carbon number of 9 to 20. Derivatives.

Examples of the compounds corresponding to the group (G) are as follows.

[0063]

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[0064]

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[0065]

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Examples of compounds corresponding to the group (H) are as follows.

[0067]

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These fragrant compounds are incorporated in the composition of the present invention in an amount of 0.001 to 3.0% by weight, preferably 0.01 to 1.0% by weight. If the amount is more than 3.0% by weight, it is not preferable from an economic viewpoint. If the amount is less than 0.001% by weight, the effect of suppressing the odorous component accompanying the softener base is insufficient.

In the composition of the present invention, it is needless to say that the fragrance compound can be used in combination with a known fragrance substance used in the fragrance composition.

In the composition of the present invention, when a combination of fragrant compounds, that is, a fragrance composition is blended, it may be added separately from the component (D), but preferably the fragrance composition is added to the component (D). And mix. When the fragrance composition is incorporated into the composition of the present invention by such a method, the odor of the composition is maintained in a good state even when the composition of the present invention is stored for a long period of time.

The solid soft finish composition of the present invention may contain, in addition to the above components, a bactericide, an antibacterial agent, an antioxidant, a fragrance, a pigment, a dye, a fluorescent brightener, and an iron-slipper. Alternatively, a silicone compound for obtaining an antifoaming effect, a salt, a water-soluble salt such as ammonium chloride, calcium chloride or the like can be added.

The composition of the present invention may be in the form of powder, granules, granules or tablet. Further, it may be supported on a water-insoluble sheet-like article (for example, nonwoven fabric, sponge, cloth, etc.).

[0073]

The solid soft finish composition of the present invention exhibits excellent dispersibility and dissolution in water, and has a sufficient softening effect in a small amount.

Since the soft finish composition of the present invention is in a solid form, its volume is smaller than that of a liquid product, so that it is easy to carry and has the advantage of taking up little space.

[0075]

EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to these examples.

The components (A), (B) and (C) shown in Table 1 were melt-mixed, pulverized and powdered. Flexibility was evaluated by the following method using a powder having a particle size that passed through a sieve having an opening of 1000 μm and did not pass through a sieve having an opening of 200 μm. The components (A) and (B) are shown below.

[0077]

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[0078]

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Note) (V-1): Compound obtained by alkylating compound (IV-1) with dimethyl sulfate at a molar ratio of 1: 1 (reaction temperature: 50 to 60 ° C.). (VI-1): a compound obtained by alkylating dimethyl sulfate (reaction temperature: 50 to 60 ° C.) at a molar ratio of 1: 1 with the compound (IV-2).

<Flexibility test method> (1) A commercially available cotton towel was repeatedly washed five times with a commercially available detergent attack (registered trademark, manufactured by Kao Corporation) to remove the treating agent attached to the towel. Using 1 g of the cotton towel treated as described above, 2 g of the powder of the soft finish composition shown in Table 1 was used and stirred at 3.5 ° DH hard water, 25 ° C., and a bath ratio of 1/30 for 5 minutes. Did. The treated towel was air-dried at room temperature, and then left in a thermo-hygrostat at 25 ° C. and 65% RH for 24 hours.

(2) The above-mentioned treated towels were compared with a cotton towel treated with a 5% aqueous dispersion of each component (A) such that the concentration of component (A) was the same as that of the above-mentioned treated towels. The flexibility was compared by a pair and evaluated according to the following evaluation criteria. +2 Softer than control +1 Slightly softer than control 0 Same as control -1 Slightly softer than control -2 Softer than control These results are shown in Table 1.

[0082]

[Table 1]

In Table 1, “PO / EO” of component (C)
“(3/7)” means that the average addition mole number of propylene oxide is 3 and the average addition mole number of ethylene oxide is 7.

Continuation of the front page (56) References JP-A-2-182972 (JP, A) JP-A-5-230761 (JP, A) JP-A-3-287867 (JP, A) JP-A 2-1479 (JP) , A) JP-A-2-2422973 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) D06M 13/00-15/715 D06M 23/08

Claims (2)

(57) [Claims] 1. The following components (A), (B) and (C)
A solid soft finish composition comprising a component. Component (A): a compound represented by the following general formula (I) and a neutralized salt thereof, a compound represented by the following general formula (II), and a compound represented by the following general formula (III) At least one selected. Embedded image [Wherein, R ¹ and R ² represent a linear or branched alkyl or alkenyl group having 10 to 26 carbon atoms, which may have a hydroxyl group. [Chemical formula 2] [Wherein, R ¹ and R ² represent the above-mentioned meanings. R ³ represents an alkyl group having 1 to 5 carbon atoms which may have a hydroxyl group. X ^-: it represents an organic anion groups or inorganic anion groups. [Chemical formula 3] [Wherein, R ¹ , R ² , R ³ , and X ^{− have the} above-mentioned meanings. Component (B): a compound represented by the following general formula (IV) and a neutralized salt thereof, a compound represented by the general formula (V),
At least one selected from the group consisting of the compounds represented by I) and the compounds represented by the general formula (VII). Embedded image [Wherein, R ^{1 has} the meaning described above. [Chemical formula 5] [Wherein, R ¹ , R ³ , and X ^{− have the} above-mentioned meanings. [Formula 6] [Wherein, R ¹ , R ³ , and X ^{− have the} above-mentioned meanings. [Formula 7] [Wherein, R ¹ represents the same meaning as described above. ^{Z: -NHR 3, -NR 3 R} 3 or ^{-N + R 3 R 3 R 3} X - indicates a. Where R
^3, X ^- have the same meanings as defined above. Component (C): One or more selected from the group consisting of urea, urea derivatives, thiourea, p-toluenesulfonic acid salts, water-soluble inorganic salts, and polyether compounds. However, the total of the components (A) and (B) in the composition is 40.0%
~ 99.99% by weight, (C) component is 0.01 ~ 60.0% by weight,
The weight ratio of component (A) to component (B) is (A) / (B) = 95
/ 5 to 10/90. 2. The polyether compound is a polyether compound having a molecular weight of 5,000 to 2,000,000 obtained by adding an alkylene oxide having 2 to 4 carbon atoms including ethylene oxide to a compound having at least three active hydrogens, and The solid soft finish composition according to claim 1, wherein the total weight of the polyoxyethylene chain portion is 50% by weight or more of the total weight of the polyether compound.