JP3152189U - Non-woven fabric for disinfecting cotton - Google Patents

Non-woven fabric for disinfecting cotton Download PDF

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JP3152189U
JP3152189U JP2009002985U JP2009002985U JP3152189U JP 3152189 U JP3152189 U JP 3152189U JP 2009002985 U JP2009002985 U JP 2009002985U JP 2009002985 U JP2009002985 U JP 2009002985U JP 3152189 U JP3152189 U JP 3152189U
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cotton
disinfecting
fiber
nonwoven fabric
fibers
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吉田 典古
典古 吉田
良樹 山川
良樹 山川
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Unitika Ltd
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Abstract

【課題】消毒液を含浸した際に適度な厚みを保持し、かつ、繊維が脱落しにくい消毒綿用不織布を提供する。【解決手段】日本薬局方アルコール等の消毒液を含浸させて消毒綿として用いるための消毒綿用不織布であって、三次元的な立体捲縮を有するポリエステル複合繊維とセルロース系繊維とを構成繊維し、構成繊維同士が相互に交絡することによって一体化してなるスパンレース不織布からなるセルロース系繊維が木綿繊維であることが好ましい。【選択図】図1Disclosed is a non-woven fabric for disinfecting cotton that retains an appropriate thickness when impregnated with a disinfecting solution, and that prevents fibers from dropping off. A non-woven fabric for disinfecting cotton that is impregnated with a disinfecting solution such as Japanese Pharmacopoeia alcohol to be used as disinfecting cotton, comprising a polyester composite fiber having three-dimensional steric crimps and a cellulosic fiber. And it is preferable that the cellulosic fiber which consists of a spunlace nonwoven fabric formed by integrating the constituent fibers by intertangling each other is a cotton fiber. [Selection] Figure 1

Description

本考案、皮膚を消毒する際に用いる消毒綿用不織布に関するものである。   The present invention relates to a disinfecting cotton nonwoven fabric used for disinfecting skin.

従来より、アルコール等の消毒液を含浸させた脱脂綿は、例えば、注射する部位の皮膚を殺菌消毒するために用いられている。また、皮膚や粘膜等に付いた血、膿又は体液等を拭き取って、当該部位を殺菌消毒する際にも用いられている。脱脂綿が用いられる理由は、吸水性が高く薬液を吸収・保持しやすいこと、肌触りが良いこと、天然繊維である木綿繊維からなるので人体に優しいこと等が挙げられる。また、最近では、脱脂綿に限らず、不織布等の基材に消毒液を含浸させたものが用いられており、脱脂綿や不織布等の基材を特定の大きさにカットしたカット綿にアルコール等の消毒液を含浸した消毒綿が所定の枚数積層された積層消毒綿をプラスチック製の密閉容器に収容しておき、使用時に密閉容器のふたを開けて必要枚数の消毒綿を取り出し、再度、ふたを閉じるようにしたものが用いられている(特許文献1)。   Conventionally, absorbent cotton impregnated with an antiseptic solution such as alcohol has been used to sterilize and disinfect the skin at the site of injection, for example. It is also used when sterilizing and disinfecting the site by wiping blood, pus or body fluids attached to the skin or mucous membrane. The reason why absorbent cotton is used is that it is highly water-absorbent and easily absorbs and retains a chemical solution, that it is soft to the touch, and that it is made of cotton fibers that are natural fibers, so that it is gentle to the human body. In addition, recently, not only absorbent cotton, but also non-woven fabric and other base materials impregnated with a disinfectant have been used. Place a predetermined number of layers of disinfectant cotton impregnated with disinfectant solution in a plastic airtight container, open the lid of the airtight container during use, take out the required number of disinfectant cotton, and re-cover the lid. What was made to close is used (patent document 1).

このようなカット綿として用いられている不織布としては、木綿繊維同士が水流交絡してなるものが挙げられる。この不織布は、繊維同士が交絡しているため、拭き取りの際に繊維が脱落しにくいという利点がある。しかしながら、木綿繊維同士が緊密に交絡しているため、消毒液を含浸した消毒綿の厚みは薄くなり嵩高性に劣り、使用時においては、一度に数枚のカット綿を消費してしまうことになる。   Examples of the nonwoven fabric used as such cut cotton include those in which cotton fibers are hydroentangled with each other. Since this nonwoven fabric is entangled with each other, there is an advantage that the fibers are difficult to fall off during wiping. However, since cotton fibers are closely entangled with each other, the thickness of the disinfecting cotton impregnated with the disinfecting solution becomes thin and inferior in bulk, and in use, several cut cottons are consumed at a time. Become.

特開2003−285874号公報JP 2003-285874 A

本考案の目的は、消毒液を含浸した際に適度な厚みを保持し、かつ、繊維が脱落しにくい消毒綿用不織布を提供することにある。   An object of the present invention is to provide a non-woven fabric for disinfecting cotton that retains an appropriate thickness when impregnated with a disinfecting solution, and that prevents fibers from dropping off.

本考案者は、消毒綿に嵩高性を付与すべく、不織布の構成繊維として木綿繊維のみでなく、汎用のポリエステル繊維を混合してカット綿を作成した。ポリエステル繊維を混合することによって、消毒液を含浸した際のカット綿に嵩高性を付与することができたが、カット綿は十分に消毒液を含浸しているものの、見た目には消毒液を含んでいないように見える、すなわち、乾燥しているように見えるという欠点があることがわかった。そこでさらに、混合する繊維を検討したところ、特定のポリエステル繊維を用いると、消毒液を含浸した際のカット綿に適度な嵩高性を付与することができ、かつ見た目にも消毒液の含浸性を確認しうることを見出した。   In order to impart bulkiness to the disinfecting cotton, the present inventor prepared not only cotton fibers but also general-purpose polyester fibers as the non-woven fabric constituent fibers to create cut cotton. By mixing polyester fiber, it was possible to give bulkiness to the cut cotton when impregnated with the disinfectant solution, but the cut cotton was sufficiently impregnated with the disinfectant solution, but apparently contained the disinfectant solution. It has been found that there is a drawback that it appears not to be, ie it appears to be dry. Therefore, when the fibers to be mixed were examined, when a specific polyester fiber was used, it was possible to impart moderate bulkiness to the cut cotton when impregnated with the disinfecting liquid, and the impregnating ability of the disinfecting liquid was also apparent. It was found that it can be confirmed.

本考案は、日本薬局方アルコール等の消毒液を含浸させて消毒綿として用いるための消毒綿用不織布であって、三次元的な立体捲縮を有するポリエステル複合繊維とセルロース系繊維とを構成繊維し、構成繊維同士が相互に交絡することによって一体化してなるスパンレース不織布であることを特徴とする消毒綿用不織布を要旨とするものである。   The present invention is a non-woven fabric for disinfecting cotton that is impregnated with a disinfecting solution such as Japanese Pharmacopoeia alcohol and used as disinfecting cotton, comprising a polyester composite fiber having three-dimensional three-dimensional crimps and a cellulosic fiber. The gist of the nonwoven fabric for disinfecting cotton is a spunlace nonwoven fabric that is formed by integrating the constituent fibers together.

以下、本考案について、詳細に説明する。   Hereinafter, the present invention will be described in detail.

本考案の消毒綿用不織布は、特定濃度のエタノール、イソプロパノール等の日本薬局方アルコール等の消毒液を含浸させて消毒綿として用いるものである。   The nonwoven fabric for disinfecting cotton of the present invention is used as disinfecting cotton by impregnating a disinfecting solution such as Japanese Pharmacopoeia alcohol such as ethanol and isopropanol having a specific concentration.

消毒綿用不織布は、三次元的な立体捲縮を有するポリエステル系複合繊維とセルロース系繊維とを構成繊維とする。   The nonwoven fabric for disinfectant cotton uses polyester-based composite fibers having three-dimensional three-dimensional crimps and cellulose-based fibers as constituent fibers.

本考案に用いられるセルロース系繊維としては、木綿繊維、レーヨン、リヨセル等が挙げられるが、木綿繊維を用いることが好ましい。   Examples of cellulosic fibers used in the present invention include cotton fibers, rayon, lyocell, etc., but it is preferable to use cotton fibers.

本考案に用いられるポリエステル系複合繊維は、三次元的な立体捲縮を有している。ここで、三次元的な立体捲縮とは、押し込みクリンバー等によって付与される2次元の機械捲縮とは異なる態様であって、いわゆる三次元的なコイルバネ状の捲縮のことである。また、このコイルバネ状の捲縮の一部に捩れが加わった形態であってもよい。ポリエステル複合繊維の捲縮特性としては、JISL1015に規定の方法で測定した捲縮数が10〜15個/25mm、捲縮率が13〜15%であるのが好ましい。三次元的な立体捲縮を有するポリエステル系複合繊維であると、木綿繊維と良好に交絡して、かつ交絡度合いが緊密になりすぎずに、得られる不織布において嵩高性を保持することができる。また、その理由は定かではないが、消毒液を保持した際に、十分に消毒液を保持していることを見た目にも容易に判別できる。このような三次元的な立体捲縮を有するポリエステル系複合繊維としては、粘度の異なる2種のポリエステル系重合体を偏芯的に接合させ、弛緩熱処理を施すことにより、熱収縮差により三次元的な立体捲縮を発現させたものが挙げられ、市場にて入手できるものとしては、ユニチカファイバー社製の銘柄<38F>を好ましく用いる。   The polyester based composite fiber used in the present invention has a three-dimensional steric crimp. Here, the three-dimensional three-dimensional crimp is a so-called three-dimensional coil spring-shaped crimp, which is a mode different from the two-dimensional mechanical crimp provided by an indentation crimper or the like. Further, a form in which twist is added to a part of the coil spring-like crimp may be used. As the crimp characteristics of the polyester composite fiber, it is preferable that the number of crimps measured by the method prescribed in JIS L1015 is 10 to 15 pieces / 25 mm, and the crimp rate is 13 to 15%. The polyester-based composite fiber having three-dimensional steric crimps can be entangled well with the cotton fibers and the degree of entanglement does not become too tight, and the resulting nonwoven fabric can retain bulkiness. Moreover, although the reason is not certain, it can be easily discriminate | determined visually by holding | maintaining disinfecting liquid fully, when disinfecting liquid is hold | maintained. As such polyester-based composite fibers having three-dimensional steric crimps, two types of polyester polymers having different viscosities are eccentrically joined and subjected to relaxation heat treatment, so that three-dimensional As a material that can be obtained on the market, brand <38F> manufactured by Unitika Fiber is preferably used.

不織布中に含まれるポリエステル系複合繊維は、多くとも40質量%とする。ポリエステル系複合繊維の質量が40質量%を超えると、消毒綿における消毒液の保液性に劣ることとなる。一方、本考案の効果を奏するためには、不織布中には、ポリエステル系複合繊維は少なくとも10質量%以上、好ましくは20質量%以上含むこととする。   The polyester composite fiber contained in the nonwoven fabric is at most 40% by mass. When the mass of the polyester composite fiber exceeds 40% by mass, the liquid retention of the disinfectant solution in the disinfecting cotton is inferior. On the other hand, in order to achieve the effect of the present invention, the nonwoven fabric contains at least 10% by mass, preferably 20% by mass or more of polyester-based composite fiber.

本考案に用いられる構成繊維の繊維長は特に限定されないが、20〜70mm程度の短繊維を用いるとよい。   Although the fiber length of the constituent fiber used for this invention is not specifically limited, It is good to use a short fiber about 20-70 mm.

本考案における不織布は、構成繊維同士が相互に交絡することによって一体化してなるスパンレース不織布である。スパンレース不織布は、構成繊維同士が、高圧液体流の作用によって、相互に交絡することで一体化し、不織布として形態保持しているものであり、繊維同士の結合が接着剤や熱接着、熱圧着によるものでないため、肌触りが良好であり、摩擦により繊維が脱落しにくい。   The non-woven fabric in the present invention is a spunlace non-woven fabric formed by integrating constituent fibers by interlacing with each other. Spunlaced non-woven fabrics are those in which constituent fibers are entangled with each other by the action of a high-pressure liquid flow, and the shape is maintained as a non-woven fabric. Bonds between fibers are adhesive, thermal bonding, and thermocompression bonding. Therefore, the touch is good and the fibers are less likely to fall off due to friction.

本考案における不織布の目付は、特に限定しないが、適宜の大きさにカットしたカット綿が保持する消毒液の保液量を考慮すると100〜200g/m程度がよい。 The basis weight of the nonwoven fabric in the present invention is not particularly limited, but is preferably about 100 to 200 g / m 2 in consideration of the amount of disinfectant retained by the cut cotton cut into an appropriate size.

本考案の消毒用不織布は、適宜の大きさにカットされカット綿とし、このカット綿に日本薬局方アルコール等の消毒液を含浸させて消毒綿として用いる。消毒綿の大きさは、一般的にタテ・ヨコともに3cm〜5cm角の大きさがよい。また、含浸させる消毒液の量は、不織布の質量に対して400%以上の液量を保持させるとよい。得られた消毒綿は、図1に示すように、数十枚単位で積層されて適宜の大きさの容器に収容される。容器には、未使用時には、容器内がほぼ密閉できうる蓋が取り付けられたものがよい。   The non-woven fabric for disinfection of the present invention is cut into an appropriate size to obtain cut cotton, and this cut cotton is impregnated with a disinfectant such as Japanese Pharmacopoeia alcohol and used as disinfecting cotton. The size of the sanitizing cotton is generally 3 cm to 5 cm square for both vertical and horizontal. The amount of the disinfecting liquid to be impregnated is preferably 400% or more with respect to the mass of the nonwoven fabric. As shown in FIG. 1, the obtained disinfectant cotton is stacked in units of several tens of sheets and accommodated in an appropriately sized container. The container preferably has a lid attached so that the container can be substantially sealed when not in use.

本考案の消毒綿用不織布は、セルロース系繊維と三次元的な立体捲縮を有するポリエステル複合繊維とが相互に交絡することによって一体化してなるスパンレース不織布によって構成されるため、消毒液を含浸させた際に十分に消毒液を保持することができ、また、保液した状態においても嵩高性および厚みを保持しており、取扱性が良好である。   The nonwoven fabric for disinfecting cotton of the present invention is composed of a spunlace nonwoven fabric in which cellulosic fibers and polyester composite fibers having three-dimensional steric crimps are entangled with each other, so impregnated with a disinfecting solution In this case, the disinfectant can be sufficiently retained, and the bulkiness and thickness are retained even in the retained state, and the handleability is good.

本考案に係る消毒綿の収容された状態の一例を示す概略側面図である。It is a schematic side view which shows an example of the state in which the disinfecting cotton which concerns on this invention was accommodated.

以下、実施例に基づいて本考案を説明するが、本考案は実施例に限定されるものではない。   Hereinafter, although this invention is demonstrated based on an Example, this invention is not limited to an Example.

実施例1
捲縮数12個/25mm、捲縮率14%の三次元的な立体捲縮を有するポリエステル系複合繊維(繊度3.3デシテックス、繊維長51mm、ユニチカファイバー社製 銘柄<38F> ポリエチレンテレフタレートと共重合ポリエステルとが貼り合わされてなる複合短繊維)と木綿繊維(繊度1.7デシテックス、平均繊維長25mm)とをそれぞれ準備し、ポリエステル複合繊維/木綿繊維とが30/70質量%の比率で均一に混綿した後、カード機に供給して目付120g/mのカードウェブを得た。この得られたカードウェブを100メッシュのプラスチック製織物からなる移動式メッシュ状支持体上に載置させ、ノズル孔径0.14mmの噴射孔が0.5mmの一定間隔に配列された高圧水流噴射装置を用い、2.8MPaの圧力で1回、4.2MPaの圧力で1回処理した後、ウェブを反転させ、再び2.8MPaの圧力で1回、4.2MPaの圧力で1回の処理し、構成繊維同士が三次元に交絡してなるスパンレース不織布を得た。
Example 1
Polyester-based composite fiber with three-dimensional three-dimensional crimps with 12 crimps / 25 mm crimp and 14% crimp (fineness 3.3 dtex, fiber length 51 mm, brand name <38F> manufactured by Unitika Fiber Co., Ltd.) (Composite short fiber bonded with polymerized polyester) and cotton fiber (fineness 1.7 decitex, average fiber length 25 mm) are prepared, and the ratio of polyester composite fiber / cotton fiber is 30/70% by mass. And then fed to a card machine to obtain a card web having a basis weight of 120 g / m 2 . The obtained card web is placed on a movable mesh support made of a 100 mesh plastic woven fabric, and a high pressure water jet apparatus in which nozzle holes with a nozzle hole diameter of 0.14 mm are arranged at regular intervals of 0.5 mm. After processing once at a pressure of 2.8 MPa and once at a pressure of 4.2 MPa, the web is inverted, and once again at a pressure of 2.8 MPa and once at a pressure of 4.2 MPa. Thus, a spunlace nonwoven fabric in which the constituent fibers were entangled in three dimensions was obtained.

参考例1
参考例1のスパンレース不織布として、木綿繊維のみからなる目付150g/mのもの(ユニチカ社製 品番C150SA07)を用いた。
Reference example 1
As the spun lace nonwoven fabric of Reference Example 1, one having a basis weight of 150 g / m 2 consisting of only cotton fibers (product number C150SA07 manufactured by Unitika Ltd.) was used.

比較例1
実施例1で用いたポリエステル系複合繊維に替えて、捲縮数13.4個/25mm、捲縮率14.8%の二次元的な機械捲縮が付与されたポリエチレンテレフタレートからなる繊維(繊度1.45デシテックス、繊維長51mm、繊維断面形状が円形、ユニチカファイバー社製 品番<120>)を用いたこと以外は、実施例1と同様にしてスパンレース不織布を得た。
Comparative Example 1
In place of the polyester-based composite fiber used in Example 1, a fiber made of polyethylene terephthalate to which a two-dimensional mechanical crimp with a crimp number of 13.4 pieces / 25 mm and a crimp ratio of 14.8% was imparted (fineness) A spunlace nonwoven fabric was obtained in the same manner as in Example 1 except that 1.45 dtex, fiber length 51 mm, fiber cross-sectional shape was circular, and unitica fiber product number <120> was used.

比較例2
実施例1で用いたポリエステル系複合繊維に替えて、捲縮数11.5個/25mm、捲縮数率11.2%の二次元的な機械捲縮が付与されたポリエチレンテレフタレートからなる繊維(繊度1.7デシテックス、繊維長51mm、繊維断面形状が扁平率3.8の楕円形、ユニチカファイバー社製 品番<F330>)を用いたこと以外は、実施例1と同様にしてスパンレース不織布を得た。
Comparative Example 2
A fiber made of polyethylene terephthalate to which a two-dimensional mechanical crimp with a crimp number of 11.5 pieces / 25 mm and a crimp number ratio of 11.2% was applied instead of the polyester-based composite fiber used in Example 1 ( A spunlace nonwoven fabric was used in the same manner as in Example 1 except that an ellipse having a fineness of 1.7 dtex, a fiber length of 51 mm, a fiber cross-sectional shape of 3.8, and a unit number <F330> manufactured by Unitika Fiber Co., Ltd. was used. Obtained.

得られた実施例1、参考例1、比較例1〜2のスパンレース不織布について、それぞれ4cm×4cmにカットしたカット綿を50枚作成し、カット綿の目付を求めた。評価方法は以下のとおりである。   About the obtained spunlace nonwoven fabric of Example 1, Reference Example 1, and Comparative Examples 1 and 2, 50 cut cottons each cut to 4 cm × 4 cm were prepared, and the basis weight of the cut cotton was determined. The evaluation method is as follows.

目付(g/m):4cm×4cmの試料片を50枚準備し、各試料片の質量を秤量し、得られた値の平均値を単位面積当たりに換算した値を目付(g/m)とした。 Weight per unit area (g / m 2 ): 50 sample pieces of 4 cm × 4 cm were prepared, the mass of each sample piece was weighed, and the average value obtained was converted to a unit weight per unit area (g / m 2 ).

[消毒綿の評価]
上記4cm角のカット綿50枚をビーカー中に無荷重状態で積層し、試料片50枚の質量100質量部に対して525質量部の消毒液(日本薬局方消毒用エタノール)を、試料片上方よりビーカー中に投入して、消毒液を試料片に含浸させ、ビーカーを密閉し、24時間放置した。
24時間放置後の消毒綿について、厚み(μm)、質量(g)、消毒液の含浸状態の目視評価を行った。また、得られた厚みと上記目付から嵩密度(g/cc)を、消毒綿の質量と上記試料片の目付から、消毒液の比重を考慮して消毒液含浸率(%)を算出した。厚みおよび含浸状態の評価方法は以下のとおりである。
[Evaluation of disinfected cotton]
50 pieces of cut cotton of 4 cm square are laminated in a beaker in a non-load state, and 525 parts by mass of disinfectant (Japanese Pharmacopoeia disinfectant ethanol) is added above the sample piece to 100 parts by mass of 50 sample pieces. The sample was put into a beaker, the sample piece was impregnated with the disinfectant, the beaker was sealed, and left for 24 hours.
The sanitized cotton after being left for 24 hours was visually evaluated for the thickness (μm), the mass (g), and the state of impregnation with the disinfecting solution. The bulk density (g / cc) was calculated from the obtained thickness and the basis weight, and the disinfection liquid impregnation rate (%) was calculated from the mass of the disinfecting cotton and the basis weight of the sample piece in consideration of the specific gravity of the disinfecting liquid. The evaluation method of the thickness and impregnation state is as follows.

厚み(μm):JIS L 1906:2000に基づき、厚み測定器(大栄科学精機製作所社製)を用いて荷重は2kPaとして試料片毎の厚みを測定し、その平均値を消毒綿の厚み(μm)とした。 Thickness (μm): Based on JIS L 1906: 2000 , using a thickness measuring instrument (manufactured by Daiei Kagaku Seisakusho Co., Ltd.), the load is 2 kPa, the thickness of each sample piece is measured, and the average value is the thickness of disinfecting cotton (μm) ).

消毒液の含浸状態:試料片50枚(試料1〜50)について消毒液の含浸状態を目視で観察し、次の4段階で評価した。
○:試料片の表裏ともにすみずみまで見た目に濡れ感がある。
△:試料片の一部に消毒液を含んでいない箇所があるように見える。
×:試料片において、消毒液を含んでいないように見える箇所が大半を占めるように見える。
Disinfection state of disinfecting solution: The impregnation state of the disinfecting solution was visually observed on 50 sample pieces (samples 1 to 50) and evaluated in the following four stages.
◯: Both the front and back of the sample piece have a wet feeling in every appearance.
Δ: It seems that there is a part that does not contain the disinfectant in a part of the sample piece.
X: In the sample piece, it seems that most of the portions that do not appear to contain the disinfectant are occupied.

得られた消毒綿の評価について表1に、含浸状態の目視観察結果を表2に示した。   Table 1 shows the evaluation results of the obtained disinfected cotton, and Table 2 shows the results of visual observation of the impregnated state.

表1から明らかなように、従来の木綿繊維のみからなる消毒綿(参考例1)と比較して、本考案の消毒綿は、嵩高性に優れたものであった。また、消毒液を十分に含浸保持し得るものであった。また、表2から明らかなように、実施例1の消毒綿は、見た目にも消毒液が十分に含浸していると判別しうるものであった。
As is clear from Table 1, the disinfecting cotton of the present invention was superior in bulkiness as compared with the disinfecting cotton (Reference Example 1) consisting only of conventional cotton fibers. In addition, the disinfectant was sufficiently impregnated and retained. Further, as is apparent from Table 2, the disinfecting cotton of Example 1 could be discriminated as being sufficiently impregnated with the disinfecting solution.

Claims (3)

日本薬局方アルコール等の消毒液を含浸させて消毒綿として用いるための消毒綿用不織布であって、三次元的な立体捲縮を有するポリエステル複合繊維とセルロース系繊維とを構成繊維し、構成繊維同士が相互に交絡することによって一体化してなるスパンレース不織布であることを特徴とする消毒綿用不織布。   Non-woven fabric for disinfecting cotton impregnated with disinfecting liquid such as Japanese Pharmacopoeia Alcohol, comprising polyester composite fiber having three-dimensional steric crimp and cellulosic fiber, and constituting fiber A nonwoven fabric for disinfecting cotton, which is a spunlace nonwoven fabric that is integrated by interlacing each other. セルロース系繊維が木綿繊維であることを特徴とする請求項1記載の消毒綿用不織布。   2. The nonwoven fabric for disinfectant cotton according to claim 1, wherein the cellulosic fibers are cotton fibers. 請求項1または2記載の消毒綿用不織布に、該不織布の質量に対して日本薬局方アルコール等の消毒液を400質量%以上含浸している消毒綿。
A disinfecting cotton, wherein the disinfecting cotton nonwoven fabric according to claim 1 or 2 is impregnated with 400 mass% or more of a disinfecting liquid such as Japanese Pharmacopoeia alcohol with respect to the mass of the nonwoven fabric.
JP2009002985U 2009-05-08 2009-05-08 Non-woven fabric for disinfecting cotton Expired - Lifetime JP3152189U (en)

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