JP3149613U - Molten steel storage container nozzle - Google Patents

Molten steel storage container nozzle Download PDF

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JP3149613U
JP3149613U JP2009000283U JP2009000283U JP3149613U JP 3149613 U JP3149613 U JP 3149613U JP 2009000283 U JP2009000283 U JP 2009000283U JP 2009000283 U JP2009000283 U JP 2009000283U JP 3149613 U JP3149613 U JP 3149613U
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molten steel
gas blowing
passage hole
nozzle
blowing member
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顕二 知原
顕二 知原
八反田 浩勝
浩勝 八反田
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TYK Corp
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Abstract

【課題】ガス吹き部材下方の部材が損耗などしにくく且つガス吹き部材の底面からの漏鋼が防止できる溶鋼貯留容器用ノズルを提供することである。【解決手段】本考案の溶鋼貯留容器用ノズル1は、鉛直方向に貫通し、溶鋼が通過する溶鋼通過孔5を区画し、溶鋼を貯留した容器の底部に位置する溶鋼貯留容器用ノズル1であって、溶鋼通過孔5の一部を形成し、ガスを溶鋼通過孔5に供給するガス吹き通過孔をもつガス吹き部材2と、溶鋼通過孔5の一部を形成し、ガス吹き部材2の底面22と密着する密着部311をもち、溶鋼通過孔5の径がガス吹き部材2の径より大きいガス吹き部材下部3と、を有することを特徴とする。【選択図】図1It is an object of the present invention to provide a nozzle for a molten steel storage container in which a member below a gas blowing member is less likely to be worn out and steel leakage from the bottom surface of the gas blowing member can be prevented. A nozzle for a molten steel storage container according to the present invention is a nozzle for a molten steel storage container that penetrates in a vertical direction, defines a molten steel passage hole through which molten steel passes, and is located at the bottom of a container that stores molten steel. A part of the molten steel passage hole 5 is formed, a gas blowing member 2 having a gas blowing passage hole for supplying gas to the molten steel passage hole 5, and a part of the molten steel passage hole 5 are formed. The gas blowing member lower portion 3 has a close contact portion 311 that is in close contact with the bottom surface 22 of the steel plate, and the diameter of the molten steel passage hole 5 is larger than the diameter of the gas blowing member 2. [Selection] Figure 1

Description

本考案は、溶鋼を貯留した容器の底部の出鋼口に設置される溶鋼貯留容器用ノズルに関する。   The present invention relates to a nozzle for a molten steel storage container installed at a steel outlet at the bottom of a container in which molten steel is stored.

溶鋼などの溶融金属を貯留した容器の底部の出鋼口に設置され、高温の溶鋼が通過する溶鋼通過孔は、損耗抵抗、耐摩耗性、耐熱性、耐熱衝撃性や熱間強度に優れた部材を用いる。そして、溶鋼通過孔にガスを吹き出し、溶鋼通過孔内に滞留する溶鋼を撹拌することによって凝固を防ぐ構成の出鋼口がある。   The molten steel passage hole installed at the bottom of the container where molten metal such as molten steel is stored and through which high temperature molten steel passes, has excellent wear resistance, wear resistance, heat resistance, thermal shock resistance and hot strength. Use members. And there exists a steel outlet of the structure which prevents solidification by blowing gas into a molten steel passage hole and stirring the molten steel which retains in a molten steel passage hole.

例えば、図4に示されるように、溶鋼通過孔91にガスを吹き出すガス吹き部材92は、出鋼口13の鉛直方向の一部に設けられる。この出鋼口13は、溶鋼が貯留されている容器11の底部12に差し込まれている上ノズル94から鉛直方向下方に向かって上プレート93、スライドゲート14、及び下ノズル16によって構成されている。ガス吹き部材92は、上プレート93に嵌め込まれており、ガス吹き部材92の上方外周部分と底面とがモルタルなどで接着されている。そして、接着されていない外周にエア溝(図示略)が形成されており、エア溝にガスが供給され、ガス吹き部材92からガスが吹き出す。   For example, as shown in FIG. 4, the gas blowing member 92 that blows gas into the molten steel passage hole 91 is provided in a part in the vertical direction of the steel outlet 13. The steel outlet 13 is constituted by an upper plate 93, a slide gate 14, and a lower nozzle 16 that extend downward in the vertical direction from an upper nozzle 94 inserted into the bottom 12 of the container 11 in which molten steel is stored. . The gas blowing member 92 is fitted into the upper plate 93, and the upper outer peripheral portion and the bottom surface of the gas blowing member 92 are bonded with mortar or the like. An air groove (not shown) is formed on the outer periphery that is not bonded, gas is supplied to the air groove, and gas is blown out from the gas blowing member 92.

ところで、出鋼口13は、スライドゲート14がスライドし、溶鋼通過孔91がスライドゲート用耐火物プレート15に遮られ、連通しない出鋼停止状態では、ガス吹き部材92からガスが吹き出されることで上ノズル94と上プレート93の溶鋼通過孔91に滞留している溶鋼を撹拌して凝固を防止している。また、下ノズル16の下部に図示しない浸漬ノズルが取り付けられて溶鋼の連続鋳造が行われる場合には、溶鋼通過孔91が連通する出鋼状態でガスが少量吹き出されることで浸漬ノズル内孔面へのアルミナの析出と付着とを防止している。   By the way, in the steel outlet 13, when the slide gate 14 slides, the molten steel passage hole 91 is blocked by the slide gate refractory plate 15, and gas is blown out from the gas blowing member 92 in a state where the steel outlet is stopped without communication. The molten steel staying in the molten steel passage hole 91 of the upper nozzle 94 and the upper plate 93 is agitated to prevent solidification. Moreover, when the immersion nozzle which is not shown in figure is attached to the lower part of the lower nozzle 16, and a continuous casting of molten steel is performed, a small amount of gas is blown out in the state where the molten steel passage hole 91 communicates, so that the immersion nozzle inner hole Precipitation and adhesion of alumina on the surface are prevented.

しかし、出鋼状態において溶鋼通過孔5内を溶鋼が流れる勢いでモルタルなどの接着部分に接触するとモルタルなどが溶損しやすい。モルタルなどが溶損すると、漏鋼したり、またガス吹き部材92の外周側に溶鋼が到達してエア溝を閉鎖してしまい、ガスが吹き出せなくなるという問題が生じる。出鋼停止状態及び出鋼状態で所定のガスが吹き出されないと、浸漬ノズルへのアルミナ付着、溶鋼通過孔5の閉鎖、アルミナが剥離して鋼の鋳片に入り欠陥になるなどの問題が生じ、最悪操業が停止しまうことになる。   However, when the molten steel comes into contact with an adhesive portion such as mortar with the momentum of the molten steel flowing through the molten steel passage hole 5 in the steel output state, the mortar is likely to be melted. When the mortar or the like is melted, there is a problem that the steel leaks or the molten steel reaches the outer peripheral side of the gas blowing member 92 and closes the air groove so that the gas cannot be blown out. If the predetermined gas is not blown out in the steel output stop state and the steel output state, problems such as adhesion of alumina to the immersion nozzle, closing of the molten steel passage hole 5, peeling of the alumina and entering the steel slab and causing defects occur. The worst operation will be stopped.

本考案は、上記課題に鑑みてなされたもので、ガス吹き部材とガス吹き部材下部との密着部分に溶鋼が流れ込みにくく接着材の溶損が防止できる溶鋼貯留容器用ノズルを提供することを解決すべき課題とする。   The present invention has been made in view of the above problems, and solves the problem of providing a nozzle for a molten steel storage container that can prevent molten steel from flowing into a close contact portion between a gas blowing member and a lower portion of the gas blowing member and prevent the adhesive from being melted. It should be a challenge.

上記課題を解決するための請求項1に係る考案の構成上の特徴は、鉛直方向に貫通する溶鋼が通過する溶鋼通過孔を区画し、前記溶鋼を貯留した容器の底部に位置する溶鋼貯留容器用ノズルであって、
前記溶鋼通過孔の一部を形成し、ガスを前記溶鋼通過孔に供給するガス吹き通過孔をもつガス吹き部材と、
前記溶鋼通過孔の一部を形成し、前記ガス吹き部材の底面と密着する密着部をもち、前記溶鋼通過孔の径が前記ガス吹き部材の径より大きいガス吹き部材下部と、
を有することを特徴とすることである。
The structural feature of the device according to claim 1 for solving the above-mentioned problem is that a molten steel storage container is defined at a bottom portion of a container in which a molten steel passage hole through which molten steel penetrating in the vertical direction passes is stored. Nozzle for
Forming part of the molten steel passage hole, and a gas blowing member having a gas blowing passage hole for supplying gas to the molten steel passage hole;
Forming a part of the molten steel passage hole, having a close contact portion in close contact with the bottom surface of the gas blowing member, a gas blowing member lower portion having a diameter of the molten steel passage hole larger than the diameter of the gas blowing member;
It is characterized by having.

請求項1に係る考案においては、溶鋼通過孔の一部を形成するガス吹き部材下部の溶鋼通過孔の径が、溶鋼通過孔の一部を形成するガス吹き部材の径より大きいため、出鋼状態において、ガス吹き部材の底面と密着しているガス吹き部材下部の密着部との間に溶鋼が流れ込みにくく接着材の損耗が防止できる。よって、ガス吹き部材の外周側への溶鋼の侵入を防ぐことができるため、溶鋼通過孔に吹き出すガスを供給するエア溝の閉鎖を防止できる。   In the invention according to claim 1, since the diameter of the molten steel passage hole below the gas blowing member forming a part of the molten steel passage hole is larger than the diameter of the gas blowing member forming a part of the molten steel passage hole, In the state, it is difficult for the molten steel to flow between the bottom portion of the gas blowing member and the close contact portion of the lower portion of the gas blowing member, and the wear of the adhesive can be prevented. Therefore, since it is possible to prevent the molten steel from entering the outer peripheral side of the gas blowing member, it is possible to prevent the air groove that supplies the gas blown out to the molten steel passage hole from being closed.

本実施形態1の溶鋼貯留容器用ノズル1の構成を示す説明図である。It is explanatory drawing which shows the structure of the nozzle 1 for molten steel storage containers of this Embodiment 1. FIG. (a)は本実施形態1の溶鋼貯留容器用ノズル1の上プレート3の構成を示す上面図であり、(b)は本実施形態1の溶鋼貯留容器用ノズル1の上プレート3の構成を示す横断面図である。(A) is a top view which shows the structure of the upper plate 3 of the nozzle 1 for molten steel storage containers of this Embodiment 1, (b) is the structure of the upper plate 3 of the nozzle 1 for molten steel storage containers of this Embodiment 1. FIG. It is a cross-sectional view shown. 本実施形態1の溶鋼貯留容器用ノズル1を用いた出鋼口13の構成を示す説明図である。It is explanatory drawing which shows the structure of the steel outlet 13 using the nozzle 1 for molten steel storage containers of this Embodiment 1. FIG. 従来の出鋼口13の構成を示す説明図である。It is explanatory drawing which shows the structure of the conventional steel outlet 13.

本考案の代表的な実施形態を図1〜図3を参照して説明する。本実施形態に係る溶鋼貯留容器用ノズルは、溶融金属の溶鋼が貯留された容器の底部の出鋼口の一部として用いられる。   A representative embodiment of the present invention will be described with reference to FIGS. The nozzle for a molten steel storage container according to this embodiment is used as a part of a steel outlet at the bottom of a container in which molten steel of molten metal is stored.

(実施形態1)
本実施形態1の溶鋼貯留容器用ノズル1は、図1に示されるように、ガス吹き部材2と、上プレート(ガス吹き部材下部)3と、上ノズル4と、を有し、鉛直方向に貫通し、溶鋼が通過する溶鋼通過孔5が形成されている。
(Embodiment 1)
As shown in FIG. 1, the nozzle 1 for molten steel storage container according to the first embodiment includes a gas blowing member 2, an upper plate (lower gas blowing member) 3, and an upper nozzle 4, and in the vertical direction. A molten steel passage hole 5 through which the molten steel passes is formed.

ガス吹き部材2は、図1及び図2に示されるように、略円筒形状の部材であり、中央の貫通孔20が溶鋼貯留容器用ノズル1の溶鋼通過孔5の一部を形成し、セラミックなどを主成分とする。そして、ガス吹き部材2は、外周側から内周側の溶鋼通過孔5にガスが吹き出すことができるガス吹き通過孔(図示略)と、後述する上プレート3の密着部311と密着する鉛直方向下方の底面22と、外周面に鉛直方向の一部が内周側に窪んだ溝状のエア溝23とを有する。ガス吹き部材2は、連続気泡をもつ多孔質体あるいは放射状に貫通する孔をもつ部材が好ましく、ガス吹き通過孔が連続気泡あるいは放射状に貫通する孔である。ガス吹き通気孔は、ガス吹き部材2のエア溝23と内周面との間を連通しており、ガスの膜をまんべんなく形成するためにガス吹き部材2の内周面に均等に開口する。   As shown in FIG. 1 and FIG. 2, the gas blowing member 2 is a substantially cylindrical member, and the central through hole 20 forms a part of the molten steel passage hole 5 of the nozzle 1 for the molten steel storage container. Etc. as the main component. The gas blowing member 2 has a gas blowing passage hole (not shown) through which gas can be blown from the outer peripheral side to the molten steel passage hole 5 on the inner peripheral side, and a vertical direction in close contact with a close contact portion 311 of the upper plate 3 described later. It has a lower bottom surface 22 and a groove-shaped air groove 23 having a part in the vertical direction recessed on the inner peripheral side on the outer peripheral surface. The gas blowing member 2 is preferably a porous body having continuous bubbles or a member having holes that penetrate radially, and the gas blowing passage holes are holes that penetrate continuously or radially. The gas blowing vent communicates between the air groove 23 of the gas blowing member 2 and the inner peripheral surface, and opens uniformly on the inner peripheral surface of the gas blowing member 2 in order to form a gas film evenly.

上プレート3は、セラミック製(又は耐火物)の本体部31と、本体部31の側面を拘束する金属製の帯状の枠体32とを有し、中央部分に溶鋼貯留容器用ノズル1の溶鋼通過孔5の一部を形成し、ガス吹き部材2が上方から下方に向かって嵌め込まれる貫通孔30を有している。そして、上プレート3は、貫通孔30の周りが鉛直方向上方に若干突出した形状をしており、突出していない鉛直方向上方の平面部分に鉄板33が配置されている。本体部31は、貫通孔30に上方から嵌め込まれるガス吹き部材2の底面22とモルタル6などの接着材で密着する密着部311を有する。貫通孔30は、鉛直方向上方のガス吹き部材2が保持される部分の径より、鉛直方向下方の径が狭く形成されている。   The upper plate 3 has a ceramic (or refractory) main body 31 and a metal belt-like frame 32 that restrains the side surface of the main body 31, and the molten steel of the nozzle 1 for the molten steel storage container is provided at the center. A part of the passage hole 5 is formed, and the gas blowing member 2 has a through hole 30 into which the gas blowing member 2 is fitted downward from above. The upper plate 3 has a shape in which the periphery of the through-hole 30 slightly protrudes upward in the vertical direction, and the iron plate 33 is disposed on a flat portion on the upper side in the vertical direction that does not protrude. The main body 31 has a close contact portion 311 that is in close contact with the bottom surface 22 of the gas blowing member 2 fitted into the through hole 30 from above and an adhesive such as mortar 6. The through hole 30 is formed such that the diameter in the lower part in the vertical direction is narrower than the diameter of the part in which the gas blowing member 2 in the upper part in the vertical direction is held.

上ノズル4は、図1に示されるように、ガス吹き部材2及び上プレート3の上方に位置し、略円筒状の部材である。中央の貫通孔40が溶鋼貯留容器用ノズル1の溶鋼通過孔5の一部を形成する。上ノズル4は、セラミック(例えば、アルミナ−黒鉛質耐火物)製である。   As shown in FIG. 1, the upper nozzle 4 is positioned above the gas blowing member 2 and the upper plate 3 and is a substantially cylindrical member. The central through hole 40 forms part of the molten steel passage hole 5 of the nozzle 1 for the molten steel storage container. The upper nozzle 4 is made of ceramic (for example, alumina-graphite refractory).

溶鋼通過孔5は、上ノズル4の貫通孔40、ガス吹き部材2の貫通孔20及び上プレート3の貫通孔30が連通して形成される。溶鋼通過孔5は、上ノズル4の貫通孔40とガス吹き部材の貫通孔20部分の径がほぼ同じで、上プレート3の貫通孔30の部分がガス吹き部材の貫通孔20より径が大きい。   The molten steel passage hole 5 is formed by connecting the through hole 40 of the upper nozzle 4, the through hole 20 of the gas blowing member 2, and the through hole 30 of the upper plate 3. The molten steel passage hole 5 has substantially the same diameter of the through hole 40 of the upper nozzle 4 and the through hole 20 portion of the gas blowing member, and the diameter of the through hole 30 portion of the upper plate 3 is larger than the diameter of the through hole 20 of the gas blowing member. .

本実施形態1の溶鋼貯留容器用ノズル1は、図3に示されるように、溶融金属の溶鋼が貯留された容器11の底部12の出鋼口13の一部として用いられる。出鋼口13は、溶鋼貯留容器用ノズル1とスライドゲート14とスライドゲート用耐火物プレート15と下ノズル16とから構成される。スライドゲート用耐火物プレート15は、中央部分に溶鋼通過孔5の一部を形成する鉛直方向に貫通する孔を有し、スライドゲート14に保持されている。スライドゲート14は、上方が開口し、下方は中央部分が下方に円筒状に突出している。突出した内周側に後述する下ノズル16が嵌め込まれる。下ノズル16は、溶鋼通過孔5の一部を形成する鉛直方向に貫通する孔を有している。そして、スライドゲート14は、スライドゲート用耐火物プレート15及び下ノズル16と共にスライド用ロッド17によって鉛直方向に対して垂直にスライド移動する。出鋼口13は、このスライド移動により、容器11内の溶鋼の出鋼量の制御及び出鋼の停止を行う。図3は容器11の溶鋼が溶鋼通過孔5を通過して出鋼している状態を表しており、スライドゲート14、スライドゲート用耐火物プレート15及び下ノズル16がスライド用ロッド17によってスライド移動して、容器11の溶鋼の出鋼が停止する。   As shown in FIG. 3, the nozzle 1 for molten steel storage container according to the first embodiment is used as a part of a steel outlet 13 at the bottom 12 of a container 11 in which molten metal of molten metal is stored. The steel outlet 13 includes a molten steel storage container nozzle 1, a slide gate 14, a slide gate refractory plate 15, and a lower nozzle 16. The slide gate refractory plate 15 has a hole penetrating in the vertical direction forming a part of the molten steel passage hole 5 in the center portion, and is held by the slide gate 14. The slide gate 14 has an upper opening and a lower central portion protruding downward in a cylindrical shape. A lower nozzle 16 described later is fitted into the protruding inner peripheral side. The lower nozzle 16 has a hole penetrating in the vertical direction forming a part of the molten steel passage hole 5. The slide gate 14 slides vertically with respect to the vertical direction by the slide rod 17 together with the slide gate refractory plate 15 and the lower nozzle 16. The steel output port 13 controls the amount of steel output of the molten steel in the container 11 and stops the steel output by this sliding movement. FIG. 3 shows a state in which the molten steel in the container 11 passes through the molten steel passage hole 5, and the slide gate 14, the slide gate refractory plate 15 and the lower nozzle 16 are slid by the slide rod 17. Then, the steel out of the molten steel in the container 11 is stopped.

本実施形態1の溶鋼貯留容器用ノズル1によれば、溶鋼通過孔5の一部を形成する上プレート3の溶鋼通過孔5の径が、溶鋼通過孔5の一部を形成するガス吹き部材2の径より大きいため、出鋼状態において、ガス吹き部材2の底面22と密着している上プレート3の密着部311との間に溶鋼が流れ込みにくく接着材の損耗が防止できる。よって、ガス吹き部材3の外周側への溶鋼の侵入を防ぐことができるため、エア溝23の閉鎖を防止できる。   According to the molten steel storage container nozzle 1 of the first embodiment, the diameter of the molten steel passage hole 5 of the upper plate 3 that forms part of the molten steel passage hole 5 is a gas blowing member that forms part of the molten steel passage hole 5. Since the diameter is larger than 2, the molten steel is difficult to flow between the contact portion 311 of the upper plate 3 that is in close contact with the bottom surface 22 of the gas blowing member 2 in the steel output state, and the wear of the adhesive can be prevented. Therefore, since it is possible to prevent the molten steel from entering the outer peripheral side of the gas blowing member 3, the air groove 23 can be prevented from closing.

また、ガス吹き部材2のガス吹き通過孔は、多孔質体の連続気泡であるか又は放射状に貫通する孔であることで、溶鋼通過孔5への吹き出すガスの量が増えたり、ガスを吹き出すためのガス吹き通過孔が閉鎖しにくい。   Moreover, the gas blowing passage hole of the gas blowing member 2 is an open cell of a porous body or a hole penetrating radially, so that the amount of gas blown out to the molten steel passage hole 5 is increased or the gas is blown out. Therefore, the gas blowing passage hole is difficult to close.

また、ガス吹き部材2は、底面22が上プレート3の密着部311とモルタルによって接着されていることで、耐食性があり密着させることができる。   Further, the gas blowing member 2 has a corrosion resistance because the bottom surface 22 is bonded to the contact portion 311 of the upper plate 3 by a mortar, and can be adhered.

以上、本考案の好適な実施形態について説明したが、本考案は上記実施形態に限定されるものではない。例えば、上プレート3と上ノズル4とが別部材となっているが、一体構造の部材とすることもできる。また、出鋼口13は、スライドゲート14とスライドゲート用耐火物プレート15と下ノズル16とがスライド用ロッド17によって一緒にスライド移動するが、スライドゲート14とスライドゲート用耐火物プレート15とがスライド移動し、その下方に移動しない下固定プレートと下ノズルのある構成のものでも良い。   As mentioned above, although preferred embodiment of this invention was described, this invention is not limited to the said embodiment. For example, although the upper plate 3 and the upper nozzle 4 are separate members, they may be formed as a single member. Further, in the steel outlet 13, the slide gate 14, the slide gate refractory plate 15, and the lower nozzle 16 slide together by the slide rod 17, but the slide gate 14 and the slide gate refractory plate 15 are connected to each other. A structure having a lower fixing plate and a lower nozzle that slide and do not move downward may be used.

1:溶鋼貯留容器用ノズル、11:容器、12:底部、13:出鋼口、14:スライドゲート、
15:スライドゲート用耐火物プレート、16:下ノズル、17:スライド用ロッド、
2:ガス吹き部材、20,30,40:貫通孔、22:底面、23:エア溝、
3:上プレート(ガス吹き部材下部)、31:本体部、311:密着部、32:枠体、
4:上ノズル、
5:溶鋼通過孔、
6:モルタル。
1: Nozzle for molten steel storage container, 11: Container, 12: Bottom, 13: Steel outlet, 14: Slide gate,
15: Refractory plate for slide gate, 16: Lower nozzle, 17: Slide rod,
2: gas blowing member, 20, 30, 40: through hole, 22: bottom surface, 23: air groove,
3: upper plate (lower part of gas blowing member), 31: main body, 311: close contact, 32: frame
4: Upper nozzle,
5: Molten steel passage hole,
6: Mortar.

Claims (1)

鉛直方向に貫通し、溶鋼が通過する溶鋼通過孔を区画し、前記溶鋼を貯留した容器の底部に位置する溶鋼貯留容器用ノズルであって、
前記溶鋼通過孔の一部を形成し、ガスを前記溶鋼通過孔に供給するガス吹き通過孔をもつガス吹き部材と、
前記溶鋼通過孔の一部を形成し、前記ガス吹き部材の底面と密着する密着部をもち、前記溶鋼通過孔の径が前記ガス吹き部材の径より大きいガス吹き部材下部と、
を有することを特徴とする溶鋼貯留容器用ノズル。
It is a nozzle for a molten steel storage container that penetrates in the vertical direction, divides a molten steel passage hole through which molten steel passes, and is located at the bottom of a container that stores the molten steel,
Forming part of the molten steel passage hole, and a gas blowing member having a gas blowing passage hole for supplying gas to the molten steel passage hole;
Forming a part of the molten steel passage hole, having a close contact portion in close contact with the bottom surface of the gas blowing member, a gas blowing member lower portion having a diameter of the molten steel passage hole larger than the diameter of the gas blowing member;
The nozzle for molten steel storage containers characterized by having.
JP2009000283U 2009-01-23 2009-01-23 Molten steel storage container nozzle Expired - Lifetime JP3149613U (en)

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Publications (1)

Publication Number Publication Date
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Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010167477A (en) * 2009-01-26 2010-08-05 Tokyo Yogyo Co Ltd Nozzle for molten steel storage vessel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010167477A (en) * 2009-01-26 2010-08-05 Tokyo Yogyo Co Ltd Nozzle for molten steel storage vessel

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