JP3113930B2 - Modularized catalyst - Google Patents

Modularized catalyst

Info

Publication number
JP3113930B2
JP3113930B2 JP05059855A JP5985593A JP3113930B2 JP 3113930 B2 JP3113930 B2 JP 3113930B2 JP 05059855 A JP05059855 A JP 05059855A JP 5985593 A JP5985593 A JP 5985593A JP 3113930 B2 JP3113930 B2 JP 3113930B2
Authority
JP
Japan
Prior art keywords
catalyst
hinge
storage frame
side walls
modularized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP05059855A
Other languages
Japanese (ja)
Other versions
JPH06269679A (en
Inventor
修 中西
章 大森
信夫 松本
正幸 竹井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Zosen Corp
Original Assignee
Hitachi Zosen Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Zosen Corp filed Critical Hitachi Zosen Corp
Priority to JP05059855A priority Critical patent/JP3113930B2/en
Publication of JPH06269679A publication Critical patent/JPH06269679A/en
Application granted granted Critical
Publication of JP3113930B2 publication Critical patent/JP3113930B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、例えば、窒素酸化物
(NOx)の接触還元用触媒やNOxの吸収除去剤とし
て使用されるハニカム形状の触媒に関し、より詳細には
これを収める収納枠の改良に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a catalyst for catalytic reduction of nitrogen oxides (NOx) and a honeycomb-shaped catalyst used as a NOx absorption / removal agent. It is about improvement.

【0002】[0002]

【従来の技術】NOxの接触還元用触媒として、平板と
波板を1枚置きに配してなる平板・波板多層構造の担体
に触媒金属が担持されてなる触媒エレメントを収納枠に
多数収納したモジュール化触媒が知られている。これ
は、上記のような触媒をモジュール化することにより取
扱いの簡便性を指向したものである。
2. Description of the Related Art As a catalyst for catalytic reduction of NOx, a large number of catalyst elements, in which a catalyst metal is carried on a carrier having a multilayer structure of a flat plate and a corrugated plate in which a flat plate and a corrugated plate are alternately arranged, are stored in a storage frame. Modularized catalysts are known. This aims at simplicity of handling by making the above-mentioned catalyst modular.

【0003】従来のモジュール化触媒は、図5に示すよ
うに、上記平板・波板多層構造の触媒エレメント(51)を
角筒状の収納枠(52)内に1個ずつ挿入して製作したもの
である。この角筒状の収納枠(52)は略正方形の4枚の側
壁を溶接により一体化したものである。
As shown in FIG. 5, a conventional modularized catalyst is manufactured by inserting the above-described catalyst elements (51) having a multilayer structure of a flat plate and a corrugated plate one by one into a rectangular cylindrical storage frame (52). Things. This rectangular tubular storage frame (52) is formed by integrating four substantially square side walls by welding.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、上記構
造のモジュール化触媒では、収納枠の寸法公差やエレメ
ントの寸法公差があるので、収納枠への触媒エレメント
の装入前にこれらの寸法を予め測定し、得られた測定値
から最適の収納枠および触媒エレメントの組合せを選定
し、これらを用いてモジュール化を行う必要があり、こ
のような寸法測定のために製作作業がはなはだ繁雑なも
のとなった。
However, in the modularized catalyst having the above structure, there are dimensional tolerances of the housing frame and dimensional tolerances of the elements. Therefore, these dimensions are measured in advance before loading the catalyst element into the housing frame. Then, it is necessary to select the optimal combination of the storage frame and the catalyst element from the obtained measured values, and to use them to make a module.The production work is extremely complicated for such dimensional measurement. Was.

【0005】また、こうして得られたモジュール化触媒
では、各触媒エレメント間の隙間および収納枠とエレメ
ントの間の隙間にガス流れ阻止用のシール材を詰め込む
ことができず、そのため脱硝効率が低い難点があった。
[0005] Further, in the modularized catalyst thus obtained, the gap between each catalyst element and the gap between the storage frame and the element cannot be filled with the sealing material for preventing the gas flow, so that the denitration efficiency is low. was there.

【0006】この発明は、上記の点に鑑み、簡単な作業
で製作でき、しかも高い脱硝効率を確保できるモジュー
ル化触媒を提供することを目的とする。
In view of the above, an object of the present invention is to provide a modular catalyst that can be manufactured by a simple operation and that can ensure high denitration efficiency.

【0007】[0007]

【課題を解決するための手段】この発明によるモジュー
ル化触媒は、上記目的を達成すべく工夫されたもので、
ヒンジ(1) で連結した4枚の側壁(2) よりなる角筒状の
収納枠(3) と、周面に緩衝材(4) を巻き付けた複数の触
媒エレメント(5) とを用意し、収納枠(3) の少なくとも
1つのヒンジ連結部を解放し、同枠内に所要数の触媒エ
レメント(5) を配して4枚の側壁(2) で締め付け、解放
ヒンジを連結してなるものである。
The modular catalyst according to the present invention has been devised to achieve the above object.
Prepare a rectangular cylindrical storage frame (3) consisting of four side walls (2) connected by a hinge (1), and a plurality of catalyst elements (5) around which a cushioning material (4) is wound. At least one hinge connection part of the storage frame (3) is released, the required number of catalyst elements (5) are arranged in the frame, and the release hinges are connected by fastening with four side walls (2). It is.

【0008】触媒エレメント(5) は、例えば、角筒(12)
内に平板状のセラミックスペーパー(7) と波板状のセラ
ミックスペーパー(8) を1枚置きに配してなる平板・波
板多層構造の担体に触媒金属が担持されてなるものであ
る。ただし、平板および波板の材質はセラミックスペー
パーに限定されない。
The catalyst element (5) is, for example, a square tube (12)
The catalyst metal is carried on a carrier having a multilayer structure of a flat plate and a corrugated plate, in which a flat ceramic paper (7) and a corrugated ceramic paper (8) are arranged alternately. However, the material of the flat plate and the corrugated plate is not limited to ceramic paper.

【0009】収納枠(3) の底部には、通常、グレーチン
グ状の受け部材(10)が配置され、側壁(2) の内の1つま
たは2つが受け部材(10)の側面に固定されている。そし
て、複数の触媒エレメント(5) は受け部材(10)に受けら
れている。この受け部材(10)の設置により組立完了後の
収納枠(3) に強度が付与されるため、側壁(2) の厚みを
薄くすることができる。
At the bottom of the storage frame (3), a grating-shaped receiving member (10) is usually arranged, and one or two of the side walls (2) are fixed to the side surface of the receiving member (10). I have. The plurality of catalyst elements (5) are received by a receiving member (10). By installing the receiving member (10), strength is given to the storage frame (3) after assembly is completed, so that the thickness of the side wall (2) can be reduced.

【0010】[0010]

【実施例】つぎに、この発明を具体的に説明するため
に、この発明の実施例を示す。
Next, an embodiment of the present invention will be described in order to specifically explain the present invention.

【0011】実施例1 図1から図3において、まず、ヒンジ(1) で連結した4
枚の側壁(2) よりなる角筒状の収納枠(3) を用意する
(縦横:1m×1m)。各側壁(2) は略正方形のスチー
ル板よりなる。収納枠(3) の少なくとも1つのヒンジ連
結部は、そのヒンジロッド(6) をヒンジ筒部(13)から抜
き取ることにより解放しておく。
Embodiment 1 In FIG. 1 to FIG. 3, first, the four parts connected by a hinge (1) are used.
A rectangular cylindrical storage frame (3) composed of two side walls (2) is prepared (length and width: 1 mx 1 m). Each side wall (2) is made of a substantially square steel plate. At least one hinge connecting portion of the storage frame (3) is released by extracting the hinge rod (6) from the hinge tube (13).

【0012】収納枠(3) の底部には、グレーチング状の
受け部材(10)が配置され、側壁(2)の内の1つまたは2
つが受け部材(10)の側面にボルトナットまたはリベット
(11)で固定されている。
At the bottom of the storage frame (3), a grating-shaped receiving member (10) is arranged, and one or two of the side walls (2) are provided.
One bolt or nut or rivet on the side of the receiving member (10)
Fixed at (11).

【0013】他方、図2に示す多数の触媒エレメント
(5) を用意する(1辺の長さが100〜500mmの正
方形または長方形断面を有する)。これは、角筒(12)内
に平板状のセラミックスペーパー(7) と波板状のセラミ
ックスペーパー(8) を1枚置きに配してなる平板・波板
多層構造の担体に触媒金属が担持されてなるものであ
る。触媒エレメント(5) は縦長の直方体をなし、その周
面にスポンジ状の緩衝材(4) が巻き付けてある。そし
て、1つの角部を解放した収納枠(3) の内部に16個の
触媒エレメント(5) を密着状に配し、受け部材(10)に受
けさせる。ついで、これら触媒エレメント(5) を4枚の
側壁(2) で締め付ける。最後に、解放ヒンジの筒部(13)
を重ね合わせ、同筒部(13)にヒンジロッド(6) を差し込
むことによりこのヒンジを連結する。こうして、モジュ
ール化触媒(9) が得られる。
On the other hand, a number of catalyst elements shown in FIG.
(5) is prepared (having a square or rectangular cross section with a side length of 100 to 500 mm). This is because the catalyst metal is supported on a flat / corrugated multi-layered carrier in which a flat ceramic paper (7) and a corrugated ceramic paper (8) are placed in a square cylinder (12). It has been done. The catalyst element (5) has a vertically long rectangular parallelepiped shape, and a sponge-like cushioning material (4) is wound around its peripheral surface. Then, 16 catalyst elements (5) are arranged in close contact with the inside of the storage frame (3) having one corner opened, and received by the receiving member (10). The catalyst elements (5) are then fastened with four side walls (2). Finally, the tubular part of the release hinge (13)
The hinges are connected by inserting a hinge rod (6) into the cylindrical portion (13). Thus, a modular catalyst (9) is obtained.

【0014】実施例2 図4において、2枚の側壁(2) をヒンジ(1) でくの字状
に連結し、これの内側に触媒エレメント(5) を配する。
ついで、残りの2枚の側壁(2) を触媒エレメント(5) の
残りの側面に当てがい同エレメント(5) に押し付ける。
最後に、側壁(2) のヒンジの筒部(13)を重ね合わせ、同
筒部(13)にヒンジロッド(6) を差し込むことによりヒン
ジを連結する。こうして、モジュール化触媒が得られ
る。
Embodiment 2 In FIG. 4, two side walls (2) are connected in a V-shape with a hinge (1), and a catalyst element (5) is arranged inside this.
Then, the remaining two side walls (2) are applied to the remaining side surfaces of the catalyst element (5) and pressed against the same element (5).
Finally, the hinge portion (13) of the side wall (2) is overlapped, and the hinge is connected by inserting the hinge rod (6) into the cylindrical portion (13). Thus, a modular catalyst is obtained.

【0015】その他の点は実施例1と同じである。The other points are the same as the first embodiment.

【0016】[0016]

【発明の効果】この発明によるモジュール化触媒は、収
納枠(3) の少なくとも1つのヒンジ連結部を解放してお
き、同枠内に所要数の触媒エレメント(5) を配して4枚
の側壁(2) で締め付け、解放ヒンジを連結してなるもの
であるので、簡単な作業でモジュール化触媒を製作する
ことができる。
According to the modularized catalyst of the present invention, at least one hinge connection portion of the storage frame (3) is released, and a required number of catalyst elements (5) are arranged in the frame to provide four catalyst elements. Since the fastening hinge and the release hinge are connected by the side wall (2), a modularized catalyst can be manufactured by a simple operation.

【0017】また、各触媒エレメント(5) の周面には緩
衝材(4) が巻き付けてあるので、収納枠や触媒エレメン
トに寸法公差があってもこれらの公差を緩衝材(4) に吸
収させ、また、収納枠とエレメントの間の熱膨脹差も緩
衝材(4) に吸収させることができる。その結果、各触媒
エレメント間の隙間および収納枠とエレメントの間の隙
間をなくし脱硝効率の向上を果たすことができる。
Further, since the cushioning material (4) is wound around the peripheral surface of each catalyst element (5), even if the storage frame and the catalyst element have dimensional tolerances, these tolerances are absorbed by the cushioning material (4). In addition, the difference in thermal expansion between the storage frame and the element can be absorbed by the cushioning material (4). As a result, it is possible to eliminate the gap between the catalyst elements and the gap between the storage frame and the element, thereby improving the denitration efficiency.

【図面の簡単な説明】[Brief description of the drawings]

【図1】実施例1のモジュール化触媒の製作状態を示す
斜視図である。
FIG. 1 is a perspective view showing a state in which a modular catalyst of Example 1 is manufactured.

【図2】モジュール化触媒の底部構造を示す垂直断面図
である。
FIG. 2 is a vertical sectional view showing a bottom structure of the modular catalyst.

【図3】触媒エレメントを示す一部切欠斜視図である。FIG. 3 is a partially cutaway perspective view showing a catalyst element.

【図4】実施例2のモジュール化触媒の製作状態を示す
斜視図である。
FIG. 4 is a perspective view showing a state in which a modular catalyst of Example 2 is manufactured.

【図5】従来のモジュール化触媒の製作状態を示す斜視
図である。
FIG. 5 is a perspective view showing a state in which a conventional modular catalyst is manufactured.

【符号の説明】[Explanation of symbols]

(1) ヒンジ (2) 側壁 (3) 収納枠 (4) 緩衝材 (5) 触媒エレメント (6) ヒンジロッド (9) モジュール化触媒 (10)受け部材 (13)ヒンジ筒部 (1) Hinge (2) Side wall (3) Storage frame (4) Buffer material (5) Catalyst element (6) Hinge rod (9) Modularized catalyst (10) Receiving member (13) Hinge cylinder

───────────────────────────────────────────────────── フロントページの続き (72)発明者 竹井 正幸 大阪市此花区西九条5丁目3番28号 日 立造船株式会社内 (56)参考文献 特開 昭56−84621(JP,A) 実開 昭63−130714(JP,U) (58)調査した分野(Int.Cl.7,DB名) B01J 21/00 - 38/74 B01D 53/86 B01D 53/94 F01N 3/28 B01D 46/00 - 46/54 ──────────────────────────────────────────────────続 き Continuation of front page (72) Inventor Masayuki Takei 5-3-28 Nishikujo, Konohana-ku, Osaka-shi Inside Tachibana Shipbuilding Co., Ltd. (56) References JP-A-56-84621 (JP, A) 63-130714 (JP, U) (58) Fields investigated (Int. Cl. 7 , DB name) B01J 21/00-38/74 B01D 53/86 B01D 53/94 F01N 3/28 B01D 46/00- 46/54

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 ヒンジ(1) で連結した4枚の側壁(2) よ
りなる角筒状の収納枠(3) と、周面に緩衝材(4) を巻き
付けた複数の触媒エレメント(5) とを用意し、収納枠
(3) の少なくとも1つのヒンジ連結部を解放し、同枠内
に所要数の触媒エレメント(5) を配して4枚の側壁(2)
で締め付け、解放ヒンジを連結してなるモジュール化触
媒。
1. A rectangular cylindrical storage frame (3) consisting of four side walls (2) connected by a hinge (1), and a plurality of catalyst elements (5) wound around a cushioning material (4) on the peripheral surface. And prepare the storage frame
At least one hinge connection of (3) is released, and the required number of catalyst elements (5) are arranged in the same frame and four side walls (2)
A modular catalyst consisting of a hinge and a release hinge connected.
JP05059855A 1993-03-19 1993-03-19 Modularized catalyst Expired - Fee Related JP3113930B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP05059855A JP3113930B2 (en) 1993-03-19 1993-03-19 Modularized catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP05059855A JP3113930B2 (en) 1993-03-19 1993-03-19 Modularized catalyst

Publications (2)

Publication Number Publication Date
JPH06269679A JPH06269679A (en) 1994-09-27
JP3113930B2 true JP3113930B2 (en) 2000-12-04

Family

ID=13125224

Family Applications (1)

Application Number Title Priority Date Filing Date
JP05059855A Expired - Fee Related JP3113930B2 (en) 1993-03-19 1993-03-19 Modularized catalyst

Country Status (1)

Country Link
JP (1) JP3113930B2 (en)

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Also Published As

Publication number Publication date
JPH06269679A (en) 1994-09-27

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