JP3101567B2 - Manufacturing method of tea leaf extract powder - Google Patents

Manufacturing method of tea leaf extract powder

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Publication number
JP3101567B2
JP3101567B2 JP08122426A JP12242696A JP3101567B2 JP 3101567 B2 JP3101567 B2 JP 3101567B2 JP 08122426 A JP08122426 A JP 08122426A JP 12242696 A JP12242696 A JP 12242696A JP 3101567 B2 JP3101567 B2 JP 3101567B2
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JP
Japan
Prior art keywords
tea
leaf extract
extract powder
tea leaf
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP08122426A
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Japanese (ja)
Other versions
JPH09275903A (en
Inventor
健司 原口
秀明 和泉
宏亮 村上
貴志 南野
英樹 牧
泰子 木村
正美 大槻
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KYOTO PREFECTURE
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KYOTO PREFECTURE
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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、茶葉の成分をそのまま
有効に含有する茶葉エキス粉末の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a tea leaf extract powder which contains the components of tea leaves effectively as it is.

【0002】[0002]

【従来の技術】従来、緑茶の一般的な製造法は、摘採さ
れた茶生葉をまず蒸気によつて蒸し、茶生葉に含まれる
酸化酵素を不活性化し、その後、粗揉、揉捻、中揉、精
揉、乾燥といつた一連の工程を経て製造されており、こ
のようにして製造された茶は荒茶と呼ばれる。荒茶中に
は葉の部分と茎の部分が混在するため、さらにこれらを
選別した後、保存性の向上及び香味の付与を目的として
再び乾燥が行われ、最終的に水分率を5%以下にしたも
のが製品となる。このように茶生葉が摘採されてから、
製品になるまでに、長時間を要し、しかも人手がかかる
ため、一般に製茶加工された緑茶は生産コストが高くな
りがちである。
2. Description of the Related Art Conventionally, a general method for producing green tea is that steamed tea leaves are first steamed with steam to inactivate oxidases contained in the tea leaves, and thereafter, coarse kneading, kneading, and medium kneading are performed. The tea is produced through a series of steps such as fine rubbing and drying, and the tea thus produced is called crude tea. Since the leaves and stems are mixed in the crude tea, they are further selected and then dried again for the purpose of improving the storage stability and imparting the flavor. Finally, the water content is 5% or less. The product that was made is a product. After the fresh tea leaves are plucked in this way,
Because it takes a long time to produce a product and requires labor, generally, green tea processed for tea tends to have a high production cost.

【0003】一方、茶生葉中には多量のアミノ酸、カテ
キン、ビタミン類、カフエイン等の栄養素が含まれてお
り、これら成分による緑茶の効用については種々の報告
がなされており、近年は、人体に対して調節機能を持つ
機能性成分として注目されている。しかし、これら有効
成分も前述の緑茶製造工程において受ける加熱処理によ
つて成分含量の変性、損失等が生じ、茶生葉に多量に含
まれる各種有効成分が効率よく利用されていない。
On the other hand, green tea leaves contain a large amount of nutrients such as amino acids, catechins, vitamins, and caffeine, and various reports have been made on the effects of green tea by these components. On the other hand, it is attracting attention as a functional ingredient having a regulating function. However, these active ingredients also undergo denaturation, loss, etc. of the content of the ingredients due to the heat treatment in the above-mentioned green tea production process, and the various active ingredients contained in a large amount of fresh tea leaves are not efficiently used.

【0004】また、緑茶成分を抽出し、濃縮粉末化した
製品の多くは、すでに製茶加工された製品を原料として
いるため、前述したように原料コストが高く、しかも濃
縮時に有効成分の変性、損失が生じることが知られてい
る。
[0004] In addition, many of the products obtained by extracting and concentrating the green tea component into powder are made from tea-processed products. Therefore, as described above, the cost of the raw material is high, and at the time of concentration, the modification and loss of the active ingredient occur. Is known to occur.

【0005】[0005]

【発明が解決しようとする課題】そこで、本発明は、茶
生葉の成分を、変性又は損失することなく、有効に含
み、しかも簡単に緑茶飲料又は食品添加物として利用で
きる茶葉エキス粉末の製造法を提供することを課題とす
る。
SUMMARY OF THE INVENTION Accordingly, the present invention provides a method for producing a tea leaf extract powder which contains the components of fresh tea leaves effectively without denaturation or loss and can be easily used as a green tea beverage or food additive. The task is to provide

【0006】[0006]

【課題を解決するための手段】本発明者らは、通常の緑
茶製造工程を経ることなく、茶生葉に含有されるアミノ
酸、カテキン、ビタミン類、カフエイン等の各種有効成
分を効率よく粉末化すべく鋭意検討を重ねた結果、茶生
葉を蒸して酸化酵素を不活性化した後、急冷し、細断し
た茶葉を圧搾して得られる搾汁液を乾燥することによっ
て、上記課題を解決しうることを見出し、本発明を完成
するに至った。
Means for Solving the Problems The present inventors aimed at efficiently powdering various active ingredients such as amino acids, catechins, vitamins, and caffeine contained in fresh tea leaves without going through a normal green tea production process. As a result of intensive studies, after steaming green tea leaves to inactivate oxidase, quenching, and drying the juice obtained by squeezing the shredded tea leaves can solve the above problem. As a result, the present invention has been completed.

【0007】本発明では、前述の如くして得た茶葉の搾
汁液を、真空凍結乾燥して、アミノ酸、カテキン、カフ
ェイン及びビタミンCを重量比率で3〜19:9〜2
2:1〜6:1〜4の割合で含む粉末を得ることを特徴
とするものである。
In the present invention, the juice of tea leaves obtained as described above is freeze-dried in a vacuum, and amino acids, catechin, caffeine and vitamin C are contained in a weight ratio of 3-19: 9-2.
It is characterized in that a powder containing a ratio of 2: 1 to 6: 1 to 4 is obtained.

【0008】この製品は、前述の如き茶葉の成分と共に
食品粉末化基材を含むものであってよく、この粉末化基
材としては、例えばデキストリン類を使用することがで
きる。
[0008] The product may contain a powdered food base together with the above-mentioned components of tea leaves. As the powdered base, for example, dextrins can be used.

【0009】かかる茶葉エキス粉末は、茶生葉を蒸して
酸化酵素を不活性化した後、冷却し、細断した茶葉を、
圧搾し、その搾汁液を乾燥することによって得られる
が、デキストリン類等の粉末化基材を添加する場合に
は、上記搾汁液に、該搾汁液の固形分1重量部当たり0.
1〜4重量部(好ましくは0.3〜2重量部)の割合で加
え、真空凍結乾燥等により乾燥して粉末化するのがよ
い。
Such tea leaf extract powder is obtained by steaming raw tea leaves to inactivate oxidase, then cooling and shredding the tea leaves.
It is obtained by squeezing and drying the squeezed liquid.When a powdered base such as dextrins is added, the squeezed liquid is added in an amount of 0.
It is preferable to add 1 to 4 parts by weight (preferably 0.3 to 2 parts by weight) and dry it by vacuum freeze drying or the like to powder.

【0010】本発明に用いる原料茶生葉は、どのような
品種のものでもよく、また玉露、てん茶用として被覆栽
培されたものや煎茶用として露天栽培されたもののいず
れであってもよい。なお、摘採時期も一番茶、二番茶、
三番茶の何れの時期のものを用いてもよい。
[0010] The raw tea leaves used in the present invention may be of any varieties, and may be any of those cultivated by coating for Gyokuro and Tencha, and those cultivated by open-air for Sencha. In addition, plucking time is also the first tea, second tea,
You may use whatever time of the 3rd tea.

【0011】本発明の製品の代表的な製法は、茶生葉
(約75〜80%の水分を含有する)を高温の蒸気、例
えば約80〜100℃の水蒸気で30〜90秒熱処理
し、熱処理した茶葉を急冷後、茶葉を細断し、圧搾袋に
詰め、100〜170kgf/cm2 の圧力で圧搾し、
得られる搾汁液(固形分5〜10%)1重量部に対して
デキストリンからなる粉末化基材0.01〜0.1重量
部を加え、真空凍結乾燥するものである。
A typical method of producing the product of the present invention is to heat-treat fresh tea leaves (containing about 75 to 80% moisture) with high-temperature steam, for example, steam at about 80 to 100 ° C. for 30 to 90 seconds. After quenching the tea leaves, the tea leaves are shredded, packed in a squeeze bag, and squeezed at a pressure of 100 to 170 kgf / cm 2 ,
Dextrin is added in an amount of 0.01 to 0.1 part by weight to 1 part by weight of the obtained juice (solid content: 5 to 10%), followed by freeze-drying in vacuum.

【0012】このようにして得た製品は、ビタミンCを
0.4重量%以上含有し、しかもアミノ酸、カテキン、カ
フェイン及びビタミンCを重量比率で3〜19:9〜2
2:1〜6:1〜4の割合で含む茶葉エキス粉末で、従
来になく茶に含まれる成分を効率よく含有する、非常に
保存性に優れたものとなる。かかる製品は、水又は湯で
溶かすだけで、通常の緑茶と同様の飲料として味わうこ
とができ、また、栄養分に富んだ食品添加物としても広
範に利用できるものとなる。
The product thus obtained contains vitamin C
It contains not less than 0.4% by weight and contains amino acids, catechins, caffeine and vitamin C in a weight ratio of 3-19: 9-2.
It is a tea leaf extract powder containing at a ratio of 2: 1 to 6: 1 to 4, which contains a component contained in tea more efficiently than ever before and has extremely excellent preservability. Such a product can be tasted as a beverage similar to ordinary green tea simply by dissolving it in water or hot water, and can be widely used as a food additive rich in nutrients.

【0013】本発明で得られた代表的な製品の組成を示
すと次の通りである。 茶葉エキス粉末中の重量比率(%) デキストリン アミノ酸 カテキン カフェイン ビタミンC (1) 0 3.6-18.4 17.5-21.9 3.9-6.0 2.2-3.7 (2) 9-80 0.7-18.2 3.5-21.7 0.8-5.9 0.4-3.7
The composition of a typical product obtained by the present invention is as follows. Weight ratio in tea leaf extract powder (%) Dextrin amino acid catechin caffeine vitamin C (1) 0 3.6-18.4 17.5-21.9 3.9-6.0 2.2-3.7 (2) 9-80 0.7-18.2 3.5-21.7 0.8-5.9 0.4- 3.7

【0014】なお、前述の如き製法において、蒸熱処理
後の茶葉に酵素(セルラーゼ、マセロチーム又はこれら
の混合物)を添加することにより、カテキンやカフェイ
ン等を更に効率よく抽出し、より有効成分に富んだ茶葉
エキス粉末を製造することもできる。ただし、この場
合、蒸熱処理後の茶葉1重量部に対して、酵素を0.00
05〜0.01重量部程度添加するのが好ましく、また、
圧搾袋に詰めた後30〜60分間ときおり攪拌しながら
放置した後に、圧搾し、粉末化基材を添加、乾燥するの
がよい。
In the above-mentioned production method, by adding an enzyme (cellulase, macerozyme or a mixture thereof) to the tea leaves after steaming, catechin, caffeine and the like can be extracted more efficiently, and the active ingredients are richer. Tea leaf extract powder can also be produced. However, in this case, the enzyme was added to 0.00 parts of the tea leaves after steaming treatment at 0.00 parts by weight.
It is preferable to add about 0.05 to 0.01 parts by weight,
It is preferred that after filling in a squeeze bag, the mixture is left for 30 to 60 minutes with occasional stirring, then squeezed, a powdered base material added and dried.

【0015】[0015]

【発明の実施の形態】次に、本発明を実施例によつてさ
らに詳細に説明する。 実施例1 一番茶期に摘採された煎茶用茶生葉12.3kg(we
t重量)を水蒸気で50秒間蒸した。急冷後、葉を粉砕
機で細断し、圧搾袋に詰め、圧搾機を用いて170kg
f/cm2 の圧力で20分間圧搾した。濃緑色で粘性の
ある搾汁液が3.6kg得られた。搾汁液(固形分10
%)1重量部に対して0.03重量部のデキストリンか
らなる粉末化基材を加え、真空凍結乾燥を行い、茶葉エ
キス粉末0.38kgを得た。この茶葉エキス粉末の成
分含量を下表に示す。
Next, the present invention will be described in more detail by way of examples. Example 1 12.3 kg of fresh tea leaves for sencha picked at the first tea stage (we
t weight) was steamed with steam for 50 seconds. After quenching, the leaves are shredded with a crusher, packed in a squeeze bag, and 170 kg using a squeeze machine.
It was squeezed at a pressure of f / cm 2 for 20 minutes. 3.6 kg of a dark green viscous juice was obtained. Squeezed juice (solid content 10
%) 1 part by weight of a powdered base material comprising 0.03 parts by weight of dextrin was added thereto, followed by vacuum freeze-drying to obtain 0.38 kg of tea leaf extract powder. The following table shows the component contents of this tea leaf extract powder.

【0016】茶葉エキス粉末の成分含有量(%) アミノ酸 カテキン カフエイン ビタミンC 14.6 13.9 4.1 2.9 Component Content (%) of Tea Leaf Extract Powder Amino Acid Catechin Caffeine Vitamin C 14.6 13.9 4.1 2.9

【0017】実施例2 二番茶期に摘採された煎茶用茶生葉18.3kg(we
t重量)を水蒸気で50秒間蒸した。急冷後、葉を粉砕
機で細断し、圧搾袋に詰め、圧搾機を用いて170kg
f/cm2 の圧力で20分間圧搾した。濃緑色で粘性の
ある搾汁液が11.1kg得られた。搾汁液(固形分1
0%)1重量部に対して0.02重量部のデキストリン
からなる粉末化基材を加え、真空凍結乾燥を行い、茶葉
エキス粉末0.73kgを得た。この茶葉エキス粉末の
成分含量を下表に示す。
Example 2 18.3 kg of green tea leaves for sencha picked during the second tea stage (we
t weight) was steamed with steam for 50 seconds. After quenching, the leaves are shredded with a crusher, packed in a squeeze bag, and 170 kg using a squeeze machine.
It was squeezed at a pressure of f / cm 2 for 20 minutes. 11.1 kg of a dark green viscous juice was obtained. Juice (solid content 1
(0%) A powdered base material composed of 0.02 parts by weight of dextrin was added to 1 part by weight, and vacuum freeze-drying was performed to obtain 0.73 kg of tea leaf extract powder. The following table shows the component contents of this tea leaf extract powder.

【0018】茶葉エキス粉末の成分含有量(%) アミノ酸 カテキン カフエイン ビタミンC 3.3 16.4 4.5 2.1 Ingredient Content (%) of Tea Leaf Extract Powder Amino Acid Catechin Caffeine Vitamin C 3.3 16.4 4.5 2.1

【0019】実施例1及び2に示す如く、本発明によれ
ば、通常の緑茶製造工程を経ることなく、茶生葉に含ま
れる各種有効成分を多量に含んだ茶葉エキス粉末を得る
ことができる。しかも、この製品は、保存性にすぐれて
おり、サラサラした状態の粉末であるため、取扱が容易
で、容易に湯水に溶解するため、茶がらの出ない簡易イ
ンスタントテイーとしても使用できる。さらに、カテキ
ン、ビタミンC等の抗酸化作用を持つ化学成分を高含量
に含むため、酸化防止剤としての活用が期待できる。
As shown in Examples 1 and 2, according to the present invention, a tea leaf extract powder containing a large amount of various active ingredients contained in fresh tea leaves can be obtained without going through a normal green tea production process. Moreover, since this product has excellent storage stability and is a powder in a smooth state, it is easy to handle and easily dissolves in hot and cold water, so that it can be used as a simple instant tea without tea leaves. Furthermore, since it contains a high content of chemical components having an antioxidant effect such as catechin and vitamin C, it can be expected to be used as an antioxidant.

【0020】そこで、本発明の製品の酸化防止性を確認
するために、下記の実施例3及び4を実施した。 実施例3 市販のサラダ油1重量部に対して、実施例2で得た茶葉
エキス粉末を0.01重量部添加し、101℃で加熱し
た場合の過酸化物価を経時的に測定した。その結果を、
茶葉エキス粉末を添加しない場合と比較して、下表に示
す。 過酸化物価(meq/kg) 本発明品1%添加 無 添 加 開始時 1 1 20時間後 18 33 40時間後 43 61 70時間後 62 182 80時間後 85 229 100時間後 218 279
Therefore, in order to confirm the antioxidant property of the product of the present invention, the following Examples 3 and 4 were carried out. Example 3 0.01 part by weight of the tea leaf extract powder obtained in Example 2 was added to 1 part by weight of a commercially available salad oil, and the peroxide value when heated at 101 ° C. was measured over time. The result is
The results are shown in the table below in comparison with the case where the tea leaf extract powder was not added. Peroxide value (meq / kg) No addition of 1% of the product of the present invention At the start of addition 11 20 hours 18 33 40 hours 43 61 70 hours 62 182 80 hours 85 229 100 hours 218 279

【0021】実施例4 β−カロチン溶液に実施例2の茶葉エキス粉末を100
0ppm濃度で添加したものと、添加しないものを、日
の良く当たる場所に静置し、それぞれ経時的にβ−カロ
チン残存率を測定した。その結果を下表に示すが、本発
明の茶葉エキス粉末を添加したものは、54時間経過後
もβ−カロチン残存率が63%で、液体が黄色に保たれ
ていたのに対し、無添加のものはβ−カロチン残存率が
8%となり、溶液は無色となった。 β−カロチン残存率(%) 本発明品 1000ppm添加 無 添 加 開始時 100 100 6時間後 82 12 24時間後 80 12 30時間後 72 12 54時間後 63 8
Example 4 The tea leaf extract powder of Example 2 was added to a β-carotene solution in 100 parts.
Those added at a concentration of 0 ppm and those not added were allowed to stand still in a well-lit place, and the residual ratio of β-carotene was measured with time. The results are shown in the following table. In the case where the tea leaf extract powder of the present invention was added, the β-carotene residual ratio was 63% after 54 hours, and the liquid was kept yellow. The solution had a β-carotene residual ratio of 8%, and the solution was colorless. β-carotene residual ratio (%) The product of the present invention 1000 ppm No addition 100 100 6 hours after 82 12 24 hours 80 12 30 hours 72 12 54 hours 638

【0022】[0022]

【発明の効果】本発明の製品は、粉末であり、しかも茶
葉の成分を効率よく含有しているため、保存性よく、ま
た大部分が水溶性であるため、どこでも湯水で溶解する
だけで容易に緑茶として味わうことができるものであ
る。また、緑茶の各種有効成分を活用した食品添加物又
は保健食品としても広範に活用できる。更に、カテキ
ン、ビタミンC等の抗酸化作用を持つ化学成分を高含量
に含むため、食品の酸化防止剤としても利用できる。
EFFECT OF THE INVENTION The product of the present invention is a powder, and contains tea leaf components efficiently, so that it has good preservability, and since most of it is water-soluble, it can be easily dissolved anywhere with hot and cold water. It can be enjoyed as green tea. Further, it can be widely used as a food additive or health food utilizing various active ingredients of green tea. Furthermore, since it contains a high content of chemical components having an antioxidant effect such as catechin and vitamin C, it can be used as an antioxidant for food.

フロントページの続き (72)発明者 南野 貴志 京都府城陽市寺田林ノ口11番地の64 京 都府職員住宅305号 (72)発明者 牧 英樹 京都府京都市南区唐橋赤金町60番地の1 グランシティ京都713号 (72)発明者 木村 泰子 京都府京都市伏見区桃山町大島38番地の 2 桃山南団地12−401号 (72)発明者 大槻 正美 京都府宇治市宇治蔭山48番地 (56)参考文献 特開 昭59−125843(JP,A) 特公 昭38−9045(JP,B1) (58)調査した分野(Int.Cl.7,DB名) A23F 3/00 Continued on the front page (72) Inventor Takashi Minamino 11 Kyoto No.1, Terada Hayashinoguchi, Joyo-shi, Kyoto No. 305 Kyoto Metropolitan Government Residential House No. 305 (72) Inventor Hideki Maki 60-1, Karagashi-Akaganecho, Minami-ku, Kyoto, Kyoto, Japan Grand City Kyoto No. 713 (72) Inventor Yasuko Kimura Kyoto Prefecture, Fushimi-ku, Kyoto 38-Oshima 38 Momoyama South Complex 12-401 (72) Inventor Masami Otsuki 48 Uji Kageyama, Uji City, Kyoto Prefecture (56) References JP-A-59-125843 (JP, A) JP-B-38-9405 (JP, B1) (58) Fields investigated (Int. Cl. 7 , DB name) A23F 3/00

Claims (4)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 茶生葉を蒸して酸化酵素を不活性化した
後、冷却し、細断した茶葉を、圧搾し、得られる搾汁液
を真空凍結乾燥して、アミノ酸、カテキン、カフェイン
及びビタミンCを重量比率で3〜19:9〜22:1〜
6:1〜4の割合で含む粉末を得ることを特徴とする茶
葉エキス粉末の製造法。
The present invention relates to the following steps: 1. Steaming raw tea leaves to inactivate oxidase, cooling, pressing the shredded tea leaves, and freeze-drying the obtained juice to obtain amino acids, catechins, caffeine and vitamins. C in a weight ratio of 3-19: 9-22: 1-1
6. A method for producing a tea leaf extract powder, comprising obtaining a powder containing 6: 1 to 4 at a ratio.
【請求項2】 前記細断した茶葉の圧搾が、100〜1
70kgf/cm2 の圧力で実施されることを特徴とする
請求項1の茶葉エキス粉末の製造法。
2. The squeezing of the shredded tea leaves is from 100 to 1
2. The method for producing a tea leaf extract powder according to claim 1, wherein the method is carried out at a pressure of 70 kgf / cm 2 .
【請求項3】 前記搾汁液に、デキストリン類を、搾汁
液の固形分1重量部当たり0.1〜4重量部の割合で加
え、真空凍結乾燥することを特徴とする請求項1又は2
の茶葉エキス粉末の製造法。
3. The squeezed liquid is added with dextrins in a ratio of 0.1 to 4 parts by weight per 1 part by weight of the solid content of the squeezed liquid, and vacuum freeze-dried.
Production method of tea leaf extract powder.
【請求項4】 前記粉末がビタミンCを0.4重量%以上
含有することを特徴とする請求項1〜3いずれか1項の
茶葉エキス粉末の製造法。
4. The method for producing a tea leaf extract powder according to claim 1, wherein the powder contains 0.4% by weight or more of vitamin C.
JP08122426A 1996-04-18 1996-04-18 Manufacturing method of tea leaf extract powder Expired - Fee Related JP3101567B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP08122426A JP3101567B2 (en) 1996-04-18 1996-04-18 Manufacturing method of tea leaf extract powder

Publications (2)

Publication Number Publication Date
JPH09275903A JPH09275903A (en) 1997-10-28
JP3101567B2 true JP3101567B2 (en) 2000-10-23

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2315017C (en) * 1997-12-16 2011-10-11 Genencor International, Inc. Novel egiii-like enzymes, dna encoding such enzymes and methods for producing such enzymes
IT1301871B1 (en) * 1998-07-24 2000-07-07 Marlegreen Holding S A PROCEDURE FOR THE PRODUCTION OF POWDER OR LEAF AT REDUCED WORKPLANT AND PLANT
JP3126963B1 (en) 1999-08-05 2001-01-22 株式会社海研 Production method of fine powder tea
US8088429B2 (en) * 2003-12-02 2012-01-03 Kao Corporation Package drink
GB2450076B (en) * 2007-05-17 2012-09-26 Sis Science In Sport Ltd Nutritional composition
EA201070566A1 (en) 2007-11-05 2010-10-29 Унилевер Н.В. METHOD OF CLEANING TEA CONNECTIONS
ATE554658T1 (en) 2007-11-05 2012-05-15 Unilever Nv METHOD FOR PRODUCING LEAF TEA
ES2391061T3 (en) 2007-11-05 2012-11-21 Unilever N.V. Tea products manufacturing procedure
CN102781248B (en) 2010-03-25 2015-05-27 荷兰联合利华有限公司 Process for manufacturing tea products
KR20230165837A (en) * 2021-04-08 2023-12-05 더 코카콜라 컴파니 Freeze-dried beverage solids
JP7354178B2 (en) * 2021-04-08 2023-10-02 ザ コカ・コーラ カンパニー Freeze-dried beverage solids

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