JP3083648B2 - Combination of silver halide photographic material and radiation intensifying screen and silver halide photographic material - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel assembly of a silver halide photographic material and a radiation intensifying screen, and a silver halide photographic material used for the assembly. The present invention relates to a novel assembly of a silver halide photographic light-sensitive material and a radiation intensifying screen, which exhibit particularly excellent characteristics in the balance between sensitivity and image quality, and a silver halide photographic light-sensitive material used for the assembly. .

[0002]

2. Description of the Related Art In medical radiography, an image of a patient's tissue is formed by using a photographic material (silver halide photographic material) containing at least one photosensitive silver halide emulsion layer formed on a transparent support. It is prepared by recording an X-ray transmission pattern on the silver halide photographic material. The X-ray transmission pattern can be recorded by using a silver halide photographic material alone. However, since it is not desirable that the human body is exposed to a large amount of X-ray exposure, X-ray photography is usually performed by combining a silver halide photographic material with a radiographic intensifying screen. The radiographic intensifying screen is provided with a phosphor layer on the surface of the support, and the phosphor layer absorbs X-rays,
In order to convert it into visible light, which has high sensitivity for photosensitive materials,
Its use can significantly improve the sensitivity of the radiographic system.

As a method for further improving the sensitivity of an X-ray photographing system, a light-sensitive material having a photographic emulsion layer on both sides, that is, a silver halide photographic material having a silver halide photographic light-sensitive layer on the front and rear sides of a support, respectively. A method of performing X-ray photography using a photosensitive material with both sides sandwiched by a radiographic intensifying screen (sometimes referred to simply as an intensifying screen) has been developed. Various shooting methods are used. This method has been developed because a sufficient X-ray absorption cannot be achieved by using one intensifying screen. That is, even if the phosphor amount of one intensifying screen is increased to increase the amount of X-ray absorption, the visible light converted in the phosphor layer which is thickened due to the increase is scattered inside the phosphor layer. Therefore, the visible light emitted from the intensifying screen and incident on the photosensitive material disposed in contact with the intensifying screen is largely blurred. Further, since visible light generated in a deep part of the phosphor layer is hardly emitted from the phosphor layer, even if the amount of phosphor is increased unnecessarily, the effective visible light emitted from the intensifying screen does not increase. Therefore, an X-ray imaging method using two intensifying screens having a phosphor layer of an appropriate thickness increases the amount of X-ray absorption as a whole, and effectively converts visible light from the intensifying screen. Can be taken out.

As the radiation intensifying screen, a phosphor layer having a high sharpness and a low light emission and having a relatively thin phosphor layer to a screen having a low sharpness but a high light emission and a phosphor layer having a large thickness are extremely low. Various types are commercially available in a wide sensitivity range. on the other hand,
Although various silver halide photographic materials having a photographic emulsion layer on both sides are commercially available, the sensitivity series is based on the lowest sensitivity (this is the standard sensitivity).
At most, there are only two to three times as many.

In X-ray photography, the combination of an intensifying screen and a silver halide photographic light-sensitive material to be used is not specified, but when high-sensitivity photography is required, for example, In photographing, head angiography, magnifying photographing, and the like, it is common to use a combination of a high-luminance intensifying screen and a standard to high-sensitivity silver halide photographic material. When image quality is emphasized, for example, in the case of simple radiography of the chest, radiography of the stomach, and radiography of bones, a combination of an intensifying screen having a high sharpness and a silver halide photographic material having a standard sensitivity is used. Is common. Therefore, the combination of the intensifying screen and the photosensitive material on the high sensitivity side lowers the sharpness of the image (that is, the image quality is reduced), while the combination of the intensifying screen and the photosensitive material that provides high image quality has low sensitivity.

Research for finding an X-ray system excellent in balance between image quality and sensitivity has been conducted continuously until now. For example, conventionally, a combination of a blue light-emitting intensifying screen having a phosphor layer of a calcium tungstate phosphor and a silver halide photographic light-sensitive material which has not been spectrally sensitized (for example, a high-screen standard and an RX In combination with Fuji Photo Film Co., Ltd.), but recently, a green-emitting intensifying screen having a phosphor layer of a terbium-activated rare earth oxysulfide phosphor, and an ortho-spectrometer Combinations with sensitized silver halide photographic materials (eg, Glenex 4 and RXO (both trade names of Fuji Photo Film Co., Ltd.)) have been used, and both sensitivity and image quality have been improved. The results have been obtained.

[0007] In silver halide photographic materials having photographic emulsion layers on both sides, there is a problem that image quality is liable to deteriorate due to crossover light. The crossover light is emitted from the intensifying screens arranged on both sides of the photosensitive material, passes through a support of the photosensitive material (usually a thick one having a thickness of about 170 to 180 μm is used), and is exposed to light on the opposite side. Visible light that reaches the layer and reduces the image quality (especially sharpness).

Various techniques have been developed so far to reduce the above crossover light. For example, there is an invention in which a spectrally sensitized high aspect ratio tabular grain emulsion disclosed in U.S. Pat. Nos. 4,425,425 and 4,425,426 is used as a light-sensitive silver halide photographic emulsion. Is 1
It is said to decrease to 5-22%. U.S. Pat. No. 4,803,150 discloses an invention in which a microcrystalline dye layer which can be decolorized by a development treatment is provided between a support of a silver halide photographic light-sensitive material and the light-sensitive layer. To reduce the crossover to 10% or less.

On the other hand, a combination of a silver halide photographic light-sensitive material having a photographic emulsion layer on both sides and a radiographic intensifying screen is set to a specific condition to obtain an X-ray system excellent in the balance between image quality and sensitivity. Attempts have been made to get out. For example, JP-A-2-266344 and JP-A-2-266344.
Japanese Patent No. 297544 and US Pat. No. 4,803,150 disclose light characteristics (sensitivity) obtained by combining an intensifying screen (front intensifying screen) and a photosensitive layer (front photosensitive layer) on the X-ray irradiation side. The light characteristics (sensitivity) obtained by the combination of the intensifying screen on the side (rear intensifying screen) and the photosensitive layer (rear photosensitive layer) are set to be different from each other, and the combination of the former and the combination of the latter are different. An X-ray imaging system set to exhibit different contrasts is disclosed. On the other hand, in Photographic Science and Engineering, Vol. 26, No. 1 (1982), p. 40, Trimax 12 (3M Co., Ltd.) And the combination of XUD (trade name of a commercially available silver halide photographic light-sensitive material of 3M Co.) with Trim
ax4 (trade name of 3M's commercial intensifying screen)
And XD (trade name of commercially available silver halide photographic light-sensitive material manufactured by 3M) show almost the same sensitivity and sharpness (MTF), but give high NEQ (signal-to-noise ratio of output). This shows the experimental results.
This result teaches that XUD shows higher sharpness than XD, while Trimax 12 shows higher X-ray absorption than Trimax4.

[0010] As described above, research has been conducted to find an X-ray imaging system that is excellent in balance between image quality and sensitivity by various methods. However, for example, for the purpose of X-ray image diagnosis of the chest and stomach, the X-ray image forming method developed so far cannot be said to be an X-ray imaging system having sufficiently high image quality and high sensitivity. In other words, it is very important in diagnosis that an extremely fine blood vessel shadow in the lung field can be observed to the end in the chest X-ray image. However,
With the known X-ray imaging methods, the contrast in the shadow of the blood vessel is insufficient, the image is erased by the particles of the image, and the image cannot be sufficiently observed due to the blurring of the image. Similarly, in the X-ray image of the stomach, a sufficient X-ray image for diagnosis is not obtained in the depiction of the detailed stomach wall structure.

Of course, if attention is paid only to the image quality of the X-ray image,
It was possible to obtain a high quality X-ray image by using a low sensitivity silver halide photographic material in combination with a low sensitivity radiographic intensifying screen. However, when such a combination of low sensitivities is used, the amount of X-ray exposure (exposure) to the human body inevitably increases, and such a combination is not practically preferable. If the majority of the subjects are healthy people, it is necessary to avoid increasing the exposure as much as possible,
Not really available.

[0012]

SUMMARY OF THE INVENTION It is an object of the present invention to provide a novel X-ray imaging system excellent in balance between image quality and sensitivity, that is, an assembly of a silver halide photographic material and a radiation intensifying screen. Purpose.

The present invention particularly provides a novel combination of a silver halide photographic light-sensitive material and a radiographic intensifying screen which has sufficient sensitivity for practical use and can provide an X-ray image with improved image quality. The purpose is to do.

Another object of the present invention is to provide a silver halide photographic material which can be advantageously used in the above-mentioned novel X-ray photography system.

[0015]

SUMMARY OF THE INVENTION The present invention provides a radiation image-forming assembly comprising a silver halide photographic light-sensitive material and two radiation intensifying screens respectively disposed on the front and rear sides of the light-sensitive material. (1) At least one of the radiographic intensifying screens
25% or more for X-rays with X-ray energy of 80KVp
(Preferably, more than 32.8%) shows the absorption of con
Trust transfer function (CTF) is 1 spatial frequency / mm
0.79 or more, and 0.3 at a spatial frequency of 3 lines / mm
6 is a radiographic intensifying screen is more, (2) silver halide photographic light-sensitive material has a structure which is equipped with a silver halide photographic light-sensitive layers respectively on the front side and rear side of the support, at least among the One photosensitive layer has the same wavelength as the main emission peak wavelength of the radiation intensifying screen defined in the above (1), and is exposed to monochromatic light having a half width of 15 ± 5 nm. using the developing solution temperature 35 ° C., and developed with a developing time of 25 seconds, measured after peeling off the photosensitive layer in the exposed surface on the opposite side, the concentration obtained by the photosensitive layer, a 0.5 to lowest concentration It has a sensitivity so that the exposure required to reach the added value is 0.010 lux-second to 0.035 lux-second. Developer composition 21 g potassium hydroxide 63 g potassium sulfite 10 g boric acid 25 g hydroquinone 25 g triethylene glycol After 1 liter by addition of 20 g 5-nitroindazole 0.2g glacial acetic acid 10 g 1-phenyl-3-pyrazolidone 1.2 g 5-methylbenzotriazole 0.05g Glutaraldehyde 5g Potassium bromide 4g water, the pH10.02 Adjusting, furthermore, between the support and at least one photosensitive layer.
In the meantime, the microcrystalline dye particles that are decolorized in the above development process
And (3) a light-sensitive layer on the rear side of the silver halide photographic light-sensitive material for light emitted from a radiation intensifying screen disposed in front of the silver halide photographic light-sensitive material. And a radiation intensifying screen, wherein the crossover radiated to the surface is 10% or less.
The present invention also provides a silver halide photographic light-sensitive material having a configuration in which a silver halide photographic light-sensitive layer is provided on each of a front side and a rear side of a support, which is used in combination with the above-described radiation intensifying screen. One of the photosensitive layers has the same wavelength as the main emission peak wavelength of the radiation intensifying screen, and is exposed to monochromatic light having a half width of 15 ± 5 nm. After developing at a temperature of 35 ° C. and a developing time of 25 seconds, the photosensitive layer on the side opposite to the exposed surface was peeled off and measured, and the density obtained in the photosensitive layer was reduced to a value obtained by adding 0.5 to the minimum density. Has a sensitivity of 0.010 lux-second to 0.035 lux-second, and furthermore, the support and at least one photosensitive layer
In the meantime, the microcrystalline dye particles that are decolorized in the above development process
A silver halide photographic light-sensitive material is also provided with a dye layer comprising the same and a crossover of 10% or less.

The combination of the silver halide photographic light-sensitive material of the present invention and a radiographic intensifying screen has, as described above, a high sensitivity radiographic intensifying screen having a specific range of sensitivity and crossover. The present invention provides a novel X-ray imaging system which is excellent in the balance between image quality and sensitivity by such a specific combination. is there. That is, in the combination of the silver halide photographic light-sensitive material and the radiation intensifying screen of the present invention, the distribution of the respective sensitivities is defined. If the sensitivity of the assembly is fixed and the amount of X-ray absorption is extremely large, and a high-sensitivity intensifying screen is used in combination with a low-sensitivity photosensitive material, the granularity of the obtained image is extremely good. However, sharpness is significantly reduced. In this case, even if a low-sensitivity photosensitive material having a high sharpness with sufficiently reduced crossover is used, the obtained image does not have sufficient sharpness, and a diagnostically preferable X-ray image is obtained. No. Conversely, when a low-sensitivity intensifying screen with low X-ray absorption and a standard or high-sensitivity photosensitive material are used in combination, a high sharpness X
Although a line image is obtained, the granularity is deteriorated, and the X-ray image is not preferable for diagnosis.

According to the study of the present inventors, in a combination of a silver halide photographic light-sensitive material and a radiographic intensifying screen,
It has been found that the optimum distribution of the sensitivity between the intensifying screen and the photosensitive material varies depending on the sensitivity level of the assembly, the size of the test object, and the like. However, as a result of further research, it was found that a photosensitive material having a high sharpness with reduced crossover was used, and that the amount of phosphor was increased to such an extent that an acceptable sharpness level could be maintained as an intensifying screen. It has been found that when the amount of line absorption is increased, a high-quality X-ray image can be obtained with sufficient sensitivity.

The preferred level of sharpness depends on the size of the subject. In the clinical evaluation of the chest and stomach, when expressed in terms of the physical quantity of the modulation transfer function (MTF), the spatial frequency is 0.5 lines / mm (lp / mm) to 3 lines / mm.
The modulation transfer function over mm is important and its value is
It is 0.65 or more in mm and 0.22 or more in 2 lines / mm. There is also a limit on the sensitivity of the assembly. This is because if an assembly with high sensitivity is selected, even if the combination has the most preferable balance, high image quality for diagnosing the chest and the like cannot be obtained. Conversely, a low-sensitivity assembly is not preferable due to the problem of X-ray exposure.

Next, the radiation intensifying screen used in the present invention will be described in detail. The radiation intensifying screen used in the assembly of the present invention can be easily obtained by producing the radiation intensifying screen having the sensitivity specified in the present invention by a conventionally known radiation intensifying screen manufacturing technique. For an example of an intensifying screen,
Research Disclosure, Item 18431,
See section IX.

The radiographic intensifying screen has, as a basic structure, a support and a phosphor layer formed on one surface thereof. The phosphor layer is a layer in which the phosphor is dispersed in a binder (binder). In general, a transparent protective film is provided on the surface of the phosphor layer opposite to the support (the surface not facing the support) so that the phosphor layer is chemically altered or Protects against physical shock.

Preferred as the phosphor used in the radiation intensifying screen of the present invention are those represented by the following general formula. M _(w−n) M ′ _n O _w X (M is metallic yttrium, lanthanum, gadolinium,
Or at least one of lutetium, M ′ is at least one of rare earth elements, preferably dysprosium, erbium, europium, holmium, neodymium, praseodymium, samarium, cerium , terbium, thulium, or ytterbium, and X is An intermediate chalcogen (S, Se, or Te) or a halogen, n is from 0.0002 to 0.2, and w is 1 when X is a halogen, and when X is a chalcogen Is 2.

Specific examples of the radiation intensifying phosphor preferably used in the radiation intensifying screen of the present invention include the following phosphors. Terbium-activated rare earth oxysulfide-based phosphor [Y ₂ O ₂ S:
Tb, Gd ₂ O ₂ S: Tb, La ₂ O ₂ S: Tb,
(Y, Gd) ₂ O ₂ S: Tb, (Y, Gd) ₂ O ₂ S:
Tb, Tm, etc.], terbium-activated rare earth oxyhalide-based phosphors (LaOBr: Tb, LaOBr: Tb,
Tm, LaOCl: Tb, LaOCl: Tb, Tm, G
dOBr: Tb, GdOCl: Tb, etc., thulium-activated rare earth oxyhalide-based phosphor (LaOBr: T
m, LaOCl: Tm, etc.). Among the above-mentioned phosphors, a terbium-activated gadolinium oxysulfide (oxysulfide) -based phosphor may be particularly preferably used for the radiation intensifying screen of the present invention. Terbium-activated gadolinium oxysulfide phosphors are disclosed in US Pat.
No. 704 has a detailed description.

The application of the phosphor layer on the support is generally carried out by using a coating method under normal pressure as described below. That is, a coating solution is prepared by mixing and dispersing a particulate phosphor and a binder in an appropriate solvent, and this coating solution is irradiated with radiation under normal pressure using a coating means such as a doctor blade, a roll coater, or a knife coater. After directly applying on the support of the sensitive screen, the solvent is removed from the coating film, or the coating solution is applied in advance on a temporary support such as a glass plate under normal pressure, and then the solvent is removed from the coating film. The phosphor layer is formed on the support by removing it to form a phosphor-containing resin thin film, peeling the thin film from the temporary support and joining the thin film to the support of the radiation intensifying screen. .

The radiographic intensifying screen used in the present invention can be produced by the usual method as described above. It is preferable that the phosphor is manufactured by increasing the filling rate of the phosphor (that is, reducing the porosity in the phosphor layer).

The sensitivity of the radiation intensifying screen basically depends on the total luminescence of the phosphor contained in the panel.
The total amount of light emission depends not only on the emission luminance of the phosphor itself but also on the content of the phosphor in the phosphor layer. A high content of the phosphor also means that absorption of radiation such as X-rays is large, so that higher sensitivity can be obtained and at the same time, image quality (particularly, granularity) is improved.
On the other hand, when the phosphor content in the phosphor layer is constant, the layer thickness can be reduced as the phosphor particles are more densely packed, so that the spread of emitted light due to scattering is reduced. And a relatively high sharpness can be obtained.

In order to manufacture the above-mentioned radiographic intensifying screen, a) a step of forming a phosphor sheet comprising a binder and a phosphor, and b) placing the phosphor sheet on a support, And bonding the phosphor sheet on a support while compressing at a temperature equal to or higher than the softening temperature or the melting point of the phosphor sheet.

First, the step a) will be described. The phosphor sheet serving as the phosphor layer of the radiation intensifying screen is prepared by applying a coating solution in which the phosphor is uniformly dispersed in a binder solution onto a temporary support for forming the phosphor sheet, drying, and temporarily supporting the phosphor sheet. It can be manufactured by removing it from the body. That is, first, in a suitable organic solvent, a binder and phosphor particles are added,
Stir and mix to prepare a coating solution in which the phosphor is uniformly dispersed in the binder solution.

As the binder, the softening temperature or melting point is 3
A thermoplastic elastomer at 0 ° C to 150 ° C is used alone or together with another binder polymer. Since the thermoplastic elastomer has elasticity at normal temperature and becomes fluid when heated, it is possible to prevent the phosphor from being damaged by the pressure at the time of compression. Examples of the thermoplastic elastomer include polystyrene, polyolefin, polyurethane, polyester, polyamide, polybutadiene, ethylene / vinyl acetate copolymer , polyvinyl chloride, natural rubber, fluororubber, polyisoprene, chlorinated polyethylene, Styrene-butadiene rubber, silicone rubber and the like can be mentioned. The component ratio of the thermoplastic elastomer in the binder may be not less than 10% by weight and not more than 100% by weight, but the binder may be composed of as many thermoplastic elastomers as possible, especially 100% by weight. preferable.

Examples of the solvent for preparing the coating solution include lower alcohols such as methanol, ethanol, n-propanol and n-butanol; hydrocarbons containing chlorine atoms such as methylene chloride and ethylene chloride; acetone, methyl ethyl ketone and methyl isobutyl ketone. Ketones such as methyl acetate, ethyl acetate and butyl acetate; esters of lower fatty acids such as methyl acetate; lower alcohols; ethers such as dioxane, ethylene glycol monoethyl ether and ethylene glycol monomethyl ether; and mixtures thereof. The mixing ratio between the binder and the phosphor in the coating solution varies depending on the characteristics of the intended radiographic intensifying screen, the type of the phosphor, and the like. In general, the mixing ratio between the binder and the phosphor is from 1: 1 to 1: 1. 1: 100
(Weight ratio), and particularly preferably in the range of 1: 8 to 1:40 (weight ratio).

The coating solution contains a dispersant for improving the dispersibility of the phosphor in the coating solution, and a binding force between the binder and the phosphor in the formed phosphor layer. Various additives such as a plasticizer for improvement may be mixed. Examples of dispersants used for such purposes include phthalic acid, stearic acid, caproic acid, and lipophilic surfactants. Examples of the plasticizer include triphenyl phosphate, tricresyl phosphate,
Phosphoric acid esters such as diphenyl phosphate; phthalic acid esters such as diethyl phthalate and dimethoxyethyl phthalate; glycolic acid esters such as ethyl phthalylethyl glycolate and butyl phthalyl butyl glycolate; and triethylene glycol and adipic acid Examples include polyesters, polyesters of polyethylene glycol and aliphatic dibasic acids such as polyesters of diethylene glycol and succinic acid, and the like. Next, the coating solution containing the phosphor and the binder prepared as described above is uniformly applied to the surface of the temporary support for forming a sheet to form a coating film of the coating solution. This coating operation can be performed by using ordinary coating means, for example, a doctor blade, a roll coater, a knife coater, or the like.

The temporary support is, for example, glass, a metal plate,
Alternatively, it can be arbitrarily selected from known materials as a support for the radiation intensifying screen. Examples of such materials include films of plastic substances such as cellulose acetate, polyester, polyethylene terephthalate, polyamide, polyimide, triacetate, polycarbonate, aluminum foil, metal sheets such as aluminum alloy foil, ordinary paper, baryta paper, resin Pigment paper containing pigments such as coated paper and titanium dioxide,
Paper was sized with polyvinyl alcohol, alumina, zirconia, magnesia, or plate or sheet of ceramics such as titania and the like. A coating solution for forming a phosphor layer is applied on the temporary support, dried, and then peeled off from the temporary support to form a phosphor sheet to be a phosphor layer of the radiographic intensifying screen. Therefore, it is preferable to apply a release agent on the surface of the temporary support in advance so that the formed phosphor sheet can be easily peeled off from the temporary support.

Next, step b) will be described. First, a support for a phosphor sheet formed as described above is prepared.
This support can be arbitrarily selected from the same materials as the temporary support used when forming the phosphor sheet.

In a known radiographic intensifying screen, the phosphor layer is used to enhance the bond between the support and the phosphor layer or to improve the sensitivity or image quality (sharpness, granularity) of the radiographic intensifying screen. A polymer material such as gelatin is applied to the surface of the support on which the surface is provided to form an adhesion-imparting layer, or a light-reflective layer made of a light-reflective material such as titanium dioxide, or a light-absorbing material such as carbon black It is known to provide a light absorption layer made of The support used in the present invention can also be provided with these various layers, and the configuration thereof can be arbitrarily selected according to the desired purpose and application of the radiographic intensifying screen. The phosphor sheet obtained in step a) is placed on a support, and then the phosphor sheet is bonded to the support while compressing at a temperature equal to or higher than the softening temperature or the melting point of the binder.

In this way, by utilizing the method of compressing the phosphor sheet without previously fixing it on the support, the sheet can be spread thinly, and not only can the phosphor be prevented from being damaged, but also the sheet can be compressed. As compared with the case where the pressure is fixed and pressurized, a high phosphor filling rate can be obtained even with the same pressure. Examples of the compression apparatus used for the compression processing of the present invention include generally known apparatuses such as a calender roll and a hot press. For example,
The compression treatment by a calender roll is performed by placing the phosphor sheet obtained in step a) on a support and passing the phosphor sheet at a constant speed between rollers heated to a temperature higher than the softening temperature or melting point of the binder. However, the compression device used in the present invention is not limited to these devices, and may be any device capable of compressing the above-mentioned sheet while heating it. The compression pressure is preferably 50 kgw / cm ² or more.

In a usual radiographic intensifying screen,
As described above, the transparent protective film for physically and chemically protecting the phosphor layer is provided on the surface of the phosphor layer opposite to the side in contact with the support. Such a transparent protective film is preferably provided also for the radiation intensifying screen of the present invention. The thickness of the protective film is generally in the range of about 0.1 to 20 μm. The transparent protective film is, for example, a cellulose derivative such as cellulose acetate or nitrocellulose;
Alternatively, a solution prepared by dissolving a transparent polymer such as polymethyl methacrylate, polyvinyl butyral, polyvinyl formal, polycarbonate, polyvinyl acetate, or a synthetic polymer such as a vinyl chloride / vinyl acetate copolymer in a suitable solvent is used as a fluorescent light. It can be formed by a method of applying to the surface of the body layer. Alternatively, a plastic sheet made of polyethylene terephthalate, polyethylene naphthalate, polyethylene, polyvinylidene chloride, polyamide, and the like; and a protective film forming sheet such as a transparent glass plate are separately formed, and an appropriate adhesive is applied to the surface of the phosphor layer. It can also be formed by a method such as bonding by using.

As the protective film used in the radiation intensifying screen of the present invention, a film formed by a coating film containing a fluorine-based resin soluble in an organic solvent is particularly preferable. The fluorine-based resin refers to a polymer of an olefin containing fluorine (fluoroolefin) or a copolymer containing an olefin containing fluorine as a copolymer component. The film formed by the coating film of the fluororesin may be crosslinked. Protective film made of fluororesin removes dirt such as plasticizer that leaks out of the film when it comes into contact with other materials or X-ray films, etc. There are advantages that can be. When a fluorine-based resin soluble in an organic solvent is used as the material for forming the protective film, a film prepared by dissolving the resin in an appropriate solvent is applied and dried to easily form a film. That is, the protective film is formed by uniformly applying a protective film forming material coating solution containing a fluorine-based resin soluble in an organic solvent to the surface of the phosphor layer using a doctor blade or the like, and drying this. This protective film may be formed simultaneously with the formation of the phosphor layer by simultaneous multi-layer coating.

The fluororesin is a polymer of a fluorine-containing olefin (fluoroolefin) or a copolymer containing a fluorine-containing olefin as a copolymer component. Examples thereof include vinyl, polyvinylidene fluoride, tetrafluoroethylene-hexafluoropropylene copolymer, and fluoroolefin-vinyl ether copolymer. Fluorocarbon resin is
Although generally insoluble in an organic solvent, a copolymer containing a fluoroolefin as a copolymer component becomes soluble in an organic solvent depending on other structural units (other than the fluoroolefin) to be copolymerized. A protective film can be easily formed by applying a solution prepared by dissolving in a solvent onto the phosphor layer and drying. Examples of such a copolymer include a fluoroolefin-vinyl ether copolymer. Further, polytetrafluoroethylene and its modified product are also soluble in a suitable fluorinated organic solvent such as a perfluoro solvent, and therefore, like the copolymer containing the above-mentioned fluoroolefin as a copolymer component, the coating is performed. Thus, a protective film can be formed.

The protective film may contain a resin other than the fluororesin, and may contain a crosslinking agent, a hardener, a yellowing inhibitor and the like. However, in order to sufficiently achieve the above object, the content of the fluororesin in the protective film is suitably at least 30% by weight, preferably at least 50% by weight, and more preferably at least 70% by weight. It is preferable that it is above. Examples of the resin other than the fluorine-based resin contained in the protective film include a polyurethane resin, a polyacryl resin, a cellulose derivative, polymethyl methacrylate, a polyester resin, and an epoxy resin.

The protective film of the intensifying screen used in the present invention may be made of either a polysiloxane skeleton-containing oligomer or a perfluoroalkyl group-containing oligomer.
Alternatively, it may be formed from a coating film containing both. The polysiloxane skeleton-containing oligomer has, for example, a dimethylpolysiloxane skeleton, preferably has at least one functional group (eg, a hydroxyl group), and has a molecular weight (weight average) of 500 to 100,000. Is preferred. In particular, the molecular weight is 1000-1
00000, more preferably 300
It is preferably in the range of 0 to 10,000. Also, a perfluoroalkyl group (eg, tetrafluoroethylene group)
The contained oligomer desirably contains at least one functional group (for example, hydroxyl group: -OH) in the molecule, and preferably has a molecular weight (weight average) of 500 to 100,000. In particular, the molecular weight is 1000-1
00000, preferably 100
It is preferably in the range of 00 to 100,000. If an oligomer containing a functional group is used, a cross-linking reaction occurs between the oligomer and the protective film-forming resin during the formation of the protective film, and the oligomer is incorporated into the molecular structure of the film-forming resin . Even if the screen is used repeatedly for a long time or the operation such as cleaning the surface of the protective film, the oligomer is not removed from the protective film, and the effect of adding the oligomer is effective for a long time. Is advantageous.
The oligomer is preferably contained in the protective film in an amount of 0.01 to 10% by weight, particularly preferably 0.1 to 2% by weight.

The protective film may contain a perfluoroolefin resin powder or a silicone resin powder. As the perfluoroolefin resin powder or the silicone resin powder, those having an average particle diameter in the range of 0.1 to 10 μm are preferable, and particularly, the average particle diameter is 0.3 to 5 μm.
Those in the range of m are preferred. The perfluoroolefin resin powder or the silicone resin powder is preferably contained in the protective film in an amount of 0.5 to 30% by weight, particularly 2 to 20% by weight based on the weight of the protective film.
And more preferably in an amount of 5 to 15% by weight.

The radiation intensifying screen used in the present invention is:
It has high sensitivity as described above, and its characteristic is that the contrast transfer function (CTF) has a spatial frequency of 1 line / m
m (lp / mm) is 0.79 or more (preferably 0.80
2 or more, more preferably 0.869 or more), and the spatial frequency three / mm (lp / mm) at 0.36 or more (preferred
0.375 or more, more preferably 0.494 or more
It is preferably prepared as shown in ( 1) above .

The radiation intensifying screen used in the present invention has a spatial frequency (1 p / mm or a line / mm value) as a characteristic, and a contrast transfer function (C).
In the graph in which TF) is plotted on the vertical axis, the following 1 p / m
1p / mm represented by a curve created by sequentially connecting points represented by the m value and the CTF value into a smooth curve
Compared to the relationship between the value and the CTF value, it is preferable that the CTF value shows a higher CTF value than the curve in all the spatial frequency regions. 1p / mm CTF 0.00 1.00 0.25 0.950 0.50 0.905 0.75 0.840 1.00 0.790 1.25 0.720 1.50 0.655 1.75 0 .595 2.00 0.535 2 . 50 0.430 3.00 0.360 3.50 0.300 4.00 0.255 5.00 0.180 6.00 0.130

The measurement and calculation of the contrast transfer function from the radiation intensifying screen to the photosensitive material can be performed using a sample obtained by printing a rectangular chart on an MRE single-sided material manufactured by Eastman Kodak Company.

A curve formed by connecting the points represented by the lp / mm value and the CTF value so as to form a smooth curve is shown in FIG. 1 in the accompanying drawings. A preferable radiographic intensifying screen having such properties can be obtained by, for example, a method in which a thermoplastic elastomer is used as a binder as described above and the phosphor layer is subjected to compression treatment.

The protective layer of the radiation intensifying screen is preferably a transparent synthetic resin layer having a thickness of 5 μm or less, formed on the phosphor layer. By using such a thin protective layer, the distance from the phosphor of the radiation intensifying screen to the silver halide photosensitive material is shortened, which contributes to the improvement of the sharpness of the obtained X-ray image.

Next, the silver halide photographic light-sensitive material used in the present invention will be described. The silver halide photographic light-sensitive material used in the present invention has a structure in which a silver halide photographic light-sensitive layer is provided on the front side and the back side of the support, respectively, as described above. Is exposed to monochromatic light having the same wavelength as the main emission peak wavelength of the high-sensitivity radiation intensifying screen defined above, and having a half width of 15 ± 5 nm, and a developer having the following composition (hereinafter referred to as a developer). , Standard developer or developer A)
A developing process was performed at a developing solution temperature of 35 ° C. and a developing time of 25 seconds. The photosensitive layer on the side opposite to the exposed surface was peeled off and measured, and the density obtained in the photosensitive layer was added to the minimum density by 0.5. The exposure required to reach the value is 0.010 lux seconds to 0.035
It has a sensitivity of lux seconds (preferably 0.012 to 0.030 lux). Developer composition Potassium hydroxide 21 g Potassium sulfite 63 g Boric acid 10 g Hydroquinone 25 g Triethylene glycol 20 g 5-Nitroindazole 0.2 g Glacial acetic acid 10 g 1-phenyl-3-pyrazolidone 1.2 g 5-methylbenzotriazole 0.05 g Glutaraldehyde 5 g After adding 4 g of potassium bromide to make 1 liter with water, the pH is adjusted to 10.02 with potassium hydroxide or glacial acetic acid as needed. And further, the above silver halide photographic material is
The crossover emitted to the photosensitive layer on the rear side of the silver halide photographic material is 10% or less (preferably 10 to 2%) with respect to the light emitted from the radiation intensifying screen disposed on the front side. It was prepared as follows.

In the method for measuring the sensitivity of a silver halide photographic light-sensitive material, the exposure light source used must match or almost match the wavelength of the main emission peak of the radiation intensifying screen used in combination. For example, when the phosphor of the radiographic intensifying screen is terbium-activated gadolinium oxysulfide, the light source for measuring the sensitivity of the silver halide photographic light-sensitive material has a wavelength of 545 nm since the peak wavelength of the main light emission is 545 nm. And light centered at As a method for obtaining monochromatic light, a method using a filter system combining an interference filter can be used. According to this method, although it depends on the combination of interference filters, it usually has a required exposure amount and a half width of 1
Monochromatic light of 5 ± 5 nm can be easily obtained. In addition,
Regardless of whether the silver halide photographic material has been subjected to the spectral sensitization treatment or not, its spectral sensitivity spectrum is continuous, and the sensitivity does not substantially change in the wavelength range of 15 ± 5 nm. it can. Examples of the exposure light source include a tungsten light source (color temperature: 2856) when the phosphor of the radiographic intensifying screen used in combination is terbium-activated gadolinium oxysulfide.
K °) and a filter having the filter characteristics shown in FIG. 2 of the accompanying drawings.

The standard conditions of the development processing using the above standard developer will be described in more detail as follows. Developing time: 25 seconds (21 seconds in liquid + 4 seconds outside liquid) Fixing time: 20 seconds (16 seconds in liquid + 4 seconds outside liquid, fixing solution having the following composition) Rinse: 12 seconds Squeeze and dry: 26 seconds Developing device to be used: Commercial roller transport automatic developing machine (eg,
(FPM-5000 automatic developing machine manufactured by Fuji Photo Film Co., Ltd.) (Developing tank: capacity 22 liters, liquid temperature 35 ° C.) (Fixing tank: capacity 15.5 liters, liquid temperature 25 ° C.) As the same kind of commercially available roller transport automatic developing machine Is Eastman Kodak M-6AW. Fixing solution (Fixing solution F) composition Ammonium thiosulfate (70% weight / volume) 200 ml Sodium sulfite 20 g Boric acid 8 g Disodium ethylenediaminetetraacetate (dihydrate) 0.1 g Aluminum sulfate 15 g Sulfuric acid 2 g Glacial acetic acid 22 g After making up to liters, adjust the pH to 4.2 using sodium hydroxide or glacial acetic acid as necessary.

The crossover was measured by using a single intensifying screen, placing a photographic photosensitive material having a photosensitive layer on both sides in contact with the front side of the intensifying screen, and then placing black paper on the front side of the photosensitive material. In the state where the X-rays are in contact with each other, exposure is performed by changing the X-ray irradiation amount by changing the distance between the focal spot of the X-ray generator and the intensifying screen. The exposed light-sensitive material is developed and divided into two parts. From one side, the photosensitive layer on the side in contact with the intensifying screen (back-side photosensitive layer) is peeled off, and from the other side, the opposite side is removed. The photosensitive layer (front side photosensitive layer) is peeled off. Then
The density for each exposure amount in each photosensitive layer is plotted on a graph, and a characteristic curve of each photosensitive layer is created. Then, the average value of the sensitivity difference ΔlogE between the two in the linear portion of each characteristic curve is obtained, and the crossover is calculated according to the following equation. Crossover (%) = 100 / ( antilog (Δ
logE) +1 )

Typical constitutions of the silver halide photographic light-sensitive material used in the present invention include an undercoat layer and a dye for reducing crossover on both sides (front and rear sides) of a transparent support colored blue. A layer, at least one photosensitive silver halide emulsion layer and a protective layer are formed in this order. It is desirable that each of the front and rear layers be substantially the same layer.

The support is made of a transparent material such as polyethylene terephthalate and is colored with a blue dye. As the blue dye, various dyes such as anthraquinone dyes known for coloring an X-ray photographic film can be used. Support thickness is 16
It can be appropriately selected from the range of 0 to 200 μm. An undercoat layer made of a water-soluble polymer substance such as gelatin is provided on the support in the same manner as a normal X-ray photographic film.

A dye layer for reducing crossover is provided on the undercoat layer. This dye layer is usually formed as a colloid layer containing a dye, and is desirably a dye layer that is decolorized by the development treatment defined above. In the dye layer, it is desirable that the dye is fixed at the lower part of the layer so as not to diffuse into the upper photosensitive silver halide emulsion layer or the protective layer.

Various methods for improving and fixing the decolorization of the dye in the colloid layer containing the dye as described above are known. For example, a combination of a cationic mordant and an anionic dye described in EP Patent Publication No. 211273B1, and an ethylenically unsaturated monomer having an anionic functional group described in JP-A-2-207242 added to a cationic mordant. A method in which a polymer dispersion obtained by polymerization is used as a mordant and an anionic dye is combined with the mordant, and a method using a solid microcrystalline dye (microcrystalline dye particles) described in US Pat. No. 4,803,150. is there.
Among these methods, a method using a solid microcrystalline dye is preferable. The above dye layer has a crossover of 10
% Is effective.

Examples of the anionic dye used when the dye layer is formed by a combination of a cationic mordant and an anionic dye include the following.

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Examples of solid microcrystals used when the dye layer is formed from solid microcrystals include the following.

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On the dye layer, a photosensitive silver halide emulsion layer is formed. The photosensitive silver halide emulsion used in the light-sensitive material of the present invention can be prepared by a known method. However, since the silver halide emulsion used in the present invention has a relatively low sensitivity as a silver halide emulsion for an X-ray photographic material, it is generally an emulsion composed of silver halide grains having a small size. It is preferable to use The preferred size of the silver halide grains is such that the average value of the circle equivalent diameter of the projected area is 0.3 to 0.8 μm for non-tabular grains (having an aspect ratio close to 1).
m (particularly preferably 0.5 to 0.7 μm), while the tabular grains have an aspect ratio of 5/1.
When it is 10 to 10/1, the average value of the circle-equivalent diameter of the projected area is 0.4 to 1.4 μm (particularly preferable is 0.5 to 1.
0 μm).

Other methods for reducing the sensitivity of the silver halide emulsion include a method of adding a dye and a method of reducing the degree of spectral sensitization or chemical sensitization.

The silver halide photographic light-sensitive material must have photosensitivity to the intensifying screen used together. An ordinary silver halide emulsion is sensitive to light in the range of blue light to ultraviolet light, so that light emitted from the intensifying screen is in the range of blue light to ultraviolet light (for example, sensitized screen). A case in which a calcium tungstate phosphor is used as the phosphor of the screen corresponds to this.) For example, an intensifying screen using a terbium-activated cadolinium oxysulfide phosphor that emits light having a main wavelength of 545 mm. When silver halide is used, the silver halide of the light-sensitive material needs to be spectrally sensitized to green.

A preferred silver halide emulsion for use in the silver halide photographic light-sensitive material of the present invention comprises tabular silver halide grains. That is, tabular silver halide grain emulsions are advantageous in that they have a good balance between sensitivity and graininess, good spectral sensitization characteristics, and a high ability to reduce crossover.

Various improvements have been made in the production of tabular silver halide grain emulsions in recent years, and the preparation of tabular silver halide grain emulsions used in the production of the silver halide photographic light-sensitive material of the present invention is not limited thereto. Improved technology can be used. Examples of such improved techniques include techniques for improving the pressure characteristics by a combination of reduction sensitization and a mercapto compound or a certain dye, sensitizing techniques with a selenium compound, and reducing the iodine content of the particle surface. Technology for reducing pressure marks during roller transport, and in the case of a two-layer emulsion, optimizing the silver / gelatin ratio of each layer to improve the balance between reduction of pressure marks during roller transport and dryness And the like. These technologies are disclosed in Japanese Patent Application Nos. 3-145164 and 3-22.
Nos. 8639, 2-89379, and 2-28898
Nos. 2,225,637 and 3-103639.

As described above, the silver halide photographic light-sensitive material of the present invention preferably has a dye layer which is decolorized under the above-mentioned development processing conditions. It is preferable to keep the amount of the binder used in the photosensitive layer low. That is, the amount of binder used in the photosensitive layer is 5 g.
/ M ² or less, and particularly preferably 3 g / m ² or less. On the other hand, the silver content in the photosensitive layer is 3 g.
/ M ² or less, particularly preferably 2 g / m ² or less.

The silver halide photographic light-sensitive material used in the assembly of the present invention is stepwise exposed to X-rays, and the exposure image obtained under the above-mentioned development processing conditions has an optical density (D) and an exposure amount (logE). In the characteristic curve on the orthogonal coordinates having the same coordinate axis unit length, the minimum density (Dmin) + the density 0.
The average gamma (γ) formed by the point 1 and the point of minimum density (Dmin) + density 0.5 is 0.5 to 0.9, and the point of minimum density (Dmin) + density 1.2 and minimum Concentration (Dmin)
+ The average gamma (γ) made with the point of density 1.6 is 3.2 to
Preferably, it is prepared to have a characteristic curve of 4.0. When a silver halide photographic light-sensitive material having such a characteristic curve is used in the X-ray imaging system of the present invention, X-rays having excellent photographic characteristics such as a very long leg and a high gamma in a medium density portion are obtained. A line image is obtained.
Due to this photographic characteristic, the mediastinum part with a small amount of X-ray transmission, the depiction of low-density areas such as cardiac shadows are good, and the density is easily visible even in an image of a lung field part with a large amount of X-ray transmission,
Also, there is an advantage that the contrast is improved.

The silver halide photographic light-sensitive material having the preferable characteristic curve as described above has, for example, a structure in which each of the light-sensitive layers on both sides is composed of two or more silver halide emulsion layers having mutually different sensitivities. It can be easily manufactured by the method. In particular, use a high-sensitivity emulsion for the upper layer,
For the lower layer, it is preferable to form a photosensitive layer using an emulsion having low sensitivity and high photographic characteristics. When such a two-layered photosensitive layer is used, the difference in emulsion sensitivity between the layers is 1.5 times or more, preferably 2 times or more. In addition,
The ratio of the amount of the emulsion used for forming each layer varies depending on the sensitivity difference and covering power of the emulsion used. In general, the larger the difference in sensitivity, the lower the proportion of emulsion used on the high sensitivity side. For example, when the sensitivity difference is twice, the preferred use ratio of each emulsion is, when the covering powers are substantially equal, in the range of 1:20 to 1: 5 as a high-speed emulsion and a low-speed emulsion in terms of silver amount. Is adjusted to be the value of

On the laminate of the undercoat layer and the photosensitive layer provided on both sides of the support produced as described above, a protective layer made of a water-soluble polymer material such as gelatin is provided in a conventional manner. Thus, the silver halide photographic light-sensitive material of the present invention can be obtained.

There are no particular restrictions on the emulsion sensitization method, various additives, constituent materials, development processing methods, etc. used in the production of the silver halide photographic light-sensitive material of the present invention. For example, JP-A-2-68539 Various techniques described in the following corresponding portions of JP-A-2-103037 and JP-A-2-115837 can be used.

[0076] Item said person箇plant 1 chemical sensitization methods Hei 2-68539 Patent Publication page 10 the lower left column, line 16 from the upper right column, line 13 2 antifoggants, from line 17 the page 10, lower left column Page 11, upper left column, line 7, stabilizer and page 3, lower left column, line 2 to page 4, lower left column 3 Spectral sensitizing dyes, page 4, right lower column, line 4 to page 8, lower right Column 4 Surfactant, page 11, upper left column, line 14 to page 12, upper left column, line 9 Antistatic agent 5 Matting agent, page 12, upper left column, line 10 to upper right column, line 10 Slip agent, plasticizer, page 14, lower left column, line 10 to lower right column, line 1 6 Hydrophilic colloid Same as page 12, upper right column, line 11 to lower left column, line 16 From line 17 to page 13, upper right column, line 6 8 Supports Same as page 13, upper right column, lines 7 to 20 9. Line 1 from the lower column to line 9 on the lower left column of page 14 10. Development processing method JP-A-2-103037, line 7 from page 16 upper right column to line 15 on page 19 lower left column, and JP No. 115837, page 3, lower right column, line 5 to page 6, upper right column, line 10

Next, the assembly of the present invention will be described. In the assembly of the present invention, the radiographic intensifying screen and the silver halide photographic light-sensitive material are a high-sensitivity radiographic intensifying screen exhibiting an X-ray absorption amount as defined above and a silver halide photograph in a specific range as defined above. Any combination with a photosensitive material may be used.
However, a preferable combination is that the X-ray energy is 8
A radiation intensifying screen showing an absorption of 30 to 40% with respect to X-rays of 0 KVp, and a sensitivity value defined above of 0.0
A combination with a silver halide photographic light-sensitive material having a viscosity of 12 to 0.015 lux seconds can be mentioned. According to the combination of the ranges, a high-quality X-ray image with standard sensitivity can be obtained. Further, a radiation intensifying screen showing an absorption amount of 30 to 40% with respect to X-rays having an X-ray energy of 80 KVp, and a silver halide photographic light-sensitive material having a sensitivity defined above of 0.02 to 0.03 lux-second. The combination with the material is also a preferable combination, and in this case, an X-ray image with further excellent image quality can be obtained with practically no problematic sensitivity (that is, in a range in which the X-ray exposure dose is acceptable).

In the assembly of the present invention, a silver halide photographic light-sensitive material in which the front and rear light-sensitive layers satisfy the above-mentioned sensitivity requirements and have substantially the same characteristics as each other is used. And the rear side), it is preferable to use a combination of radiation intensifying screens having the above-mentioned characteristics so as to have substantially the same characteristics. However, in order to improve the balance between the image sharpness and the sensitivity, the front intensifying screen and the rear intensifying screen are replaced with the fluorescent screen of the front intensifying screen as described in US Pat. No. 4,710,637. By reducing the body coating amount from the phosphor coating amount of the post-sensitizing screen, the balance between image quality and sensitivity can be improved.

The assembly according to the present invention has a sensitivity which does not cause a problem in practical use, and an X obtained by photography.
In order to ensure that the image quality of the line image is at a high level, the sensitivity of the assembly is set to 80 KVp, with the exposure of 0.5 to 1.5 mR when using a three-phase X-ray source, the developer defined above. It is preferable to use a silver halide photographic light-sensitive material in combination with two radiation intensifying screens so that a density of 1.0 can be obtained when the film is processed under development conditions.

Next, the measurement technique used for evaluating the assembly of the silver halide photographic material of the present invention and two radiation intensifying screens and the basis thereof will be described. As a method generally used for measuring the image efficiency of a combination of a silver halide photographic light-sensitive material used for X-ray photography and a radiation intensifying screen, quantum detection efficiency (DQ
E), and as an image measurement method for comprehensively evaluating sharpness and granularity, noise equivalent quantum (NEQ)
There is a measurement. DQE is a value obtained by dividing (signal / noise) ^binary value of an image finally formed on a photosensitive material by X-ray photography using an assembly by (signal / noise) ^binary value of input X-ray. When an ideal image is formed, its value is "1", but usually it is less than 1. On the other hand, NEQ is (signal / noise) ² of the final image.
It is a numerical value represented by a value. DQE and NEQ have a relationship represented by the following equation. DQE (ν) = NEQ (ν) / Q NEQ (ν) = {log e × γ (MTF (ν)} ² / NPS ₀ (ν) (where γ means contrast, and MTF (ν) is NPS ₀ (ν) means the output noise power spectrum, ν means the spatial frequency, and Q means the incident X-ray quantum number.)

The relationship between sensitivity and image quality can be evaluated using DQE. An assembly having a high DQE means that the balance between sensitivity and image quality is excellent. On the other hand, the quality of the final image can be evaluated using NEQ. That is, it can be determined that the higher the NEQ, the better the image quality. However, NEQ is a value meaning physical image quality evaluation, and it cannot always be said that there is a one-to-one correspondence with clinical image discrimination. This is because if there is an extreme deviation between the granularity and sharpness of an image, it is not possible to clinically provide an image with high visibility. Therefore, in order to evaluate image quality from a clinical standpoint, it is desirable to evaluate both NEQ and MTF.

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EXAMPLES [Example 1] (1) The following radiographic intensifying screens were prepared in pairs (for front and rear). HR-3: Commercial product manufactured by Fuji Photo Film Co., Ltd. HR-4: Commercial product manufactured by Fuji Photo Film Co., Ltd. HR-8: Commercial product manufactured by Fuji Photo Film Co., Ltd. HR-12: Commercial product manufactured by Fuji Photo Film Co., Ltd. Trimax12: 3M commercial product Radiation intensifying screen A (prototype A) Radiation intensifying screen B (prototype B)

1) Production of Radiation Intensifying Screen A As a coating solution for forming a phosphor sheet, a phosphor (Gd ₂ O) was used.
₂ S: Tb) 200 g, Binder A (polyurethane, manufactured by Sumitomo Bayer Urethane Co., Ltd., trade name: Desmolac TPKL)
-5-2625 [solid content 40%]) 20 g, and binder B
2 g of (nitrocellulose, nitrification degree 11.5%) was added to a methyl ethyl ketone solvent and dispersed with a propeller mixer to prepare a coating solution having a viscosity of 30 PS (25 ° C.) (binder / phosphor ratio = 1/20). ). This was coated on a polyethylene terephthalate (temporary support, thickness 180 μm) coated with a silicone release agent to a thickness of 160 μm.
And dried, and then peeled off from the temporary support to form a phosphor sheet. Separately, 90 g of a soft acrylic resin and 50 g of nitrocellulose were used as a coating solution for forming an undercoat layer.
g was added to methyl ethyl ketone and mixed and dispersed to prepare a dispersion having a viscosity of 3 to 6 PS (25 ° C.).

A thickness of 250 μm into which titanium dioxide has been kneaded.
Of polyethylene terephthalate (support) is horizontally placed on a glass plate, and the above-mentioned coating solution for forming an undercoat layer is uniformly applied on the support using a doctor blade. And the coating film was dried to form an undercoat layer on the support (thickness of coating film:
15 μm). On this, the phosphor sheet prepared first is placed, and using a calender roll, 400 Kgw / c
pressure m ^2, and subjected to pressure compression operation at a temperature of 80 ° C..

Separately, a fluorine resin (fluoroolefin / vinyl ether copolymer, manufactured by Asahi Glass Co., Ltd., trade name:
70 g of Lumiflon LF100), 25 g of a cross-linking agent (isocyanate, manufactured by Sumitomo Bayer Urethane Co., Ltd., trade name: Desmodur Z4370), 5 g of bisphenol A type epoxy resin, and an alcohol-modified silicone oligomer (having a dimethylpolysiloxane skeleton, both ends Having a hydroxyl group (carbinol group), Shin-Etsu Chemical Co., Ltd.
Co., Ltd., trade name: X-22-2809) was added to a mixed solvent of toluene and isopropyl alcohol (1: 1, volume ratio) to prepare a coating solution for forming a protective film. The above-mentioned coating solution for forming a protective film is applied using a doctor blade to the surface of a phosphor sheet that has been subjected to a pressure compression operation on the support previously,
A heat treatment was performed at 120 ° C. for 30 minutes to perform drying and heat curing to form a transparent protective film having a thickness of 3 μm. As described above, a radiographic intensifying screen A comprising a support, an undercoat layer, a phosphor layer, and a transparent protective film was manufactured.

2) Production of Radiation Intensifying Screen B The above radiation intensifying screen A was prepared except that the phosphor sheet was formed so that the thickness of the phosphor sheet was 230 μm.
Was repeated to produce a radiographic intensifying screen B comprising a support, an undercoat layer, a phosphor layer, and a transparent protective film.

(2) Measurement of Characteristics of Radiation Intensifying Screen 1) Measurement of X-ray Absorption The X-rays of the following light source were allowed to reach a sample radiation intensifying screen fixed at a position 200 cm from the tungsten anode of the target tube. Then, the amount of X-rays transmitted through the intensifying screen was measured by 50 c from the phosphor layer of the intensifying screen.
The position after m was measured using an ionizing dosimeter to determine the amount of X-ray absorption. As a reference, the X-ray dose at the above measurement position measured without passing through the intensifying screen was used. Table 1 shows the measured values of the X-ray absorption of each intensifying screen.

2) Measurement of Contrast Transfer Function (CTF) An MRE single-sided photosensitive material manufactured by Eastman Kodak Co. was placed in contact with an intensifying screen to be measured, and a rectangular chart for MTF measurement (made of molybdenum, thickness: 80 μm) , Spatial frequency: 0 lines / mm to 10 lines / mm). X
The chart was placed at a position 2 m from the X-ray tube, a light-sensitive material was placed in front of the X-ray source, and then an intensifying screen was placed. The X-ray tube used was DRX-37 manufactured by Toshiba Corporation.
It is a 24HD, which uses a tungsten target, has a focal spot size of 0.6 mm × 0.6 mm, and passes through a 3 mm aluminum equivalent material including an aperture to generate X-rays. 80KV with three phase pulse generator
Apply a voltage of p, and water 7cm with absorption almost equivalent to human body
X-rays having passed through the above filter were used as a light source. The photosensitive material after the photographing was processed by a developer RD III (manufactured by Fuji Photo Film Co., Ltd.) having the same composition as that of the above-described developer A using a roller transport type automatic developing machine (FPM-5000) manufactured by Fuji Photo Film Co., Ltd. 35 ° C. and fixer F
(Ammonium thiosulfate (70% weight / volume) 200m
l, 20 g of sodium sulfite, 8 g of boric acid, 0.1 g of disodium ethylenediaminetetraacetate (dihydrate), 15 g of aluminum sulfate, 2 g of sulfuric acid, and 22 g of glacial acetic acid to make 1 liter by adding water, and the pH was adjusted to 4 .2), and the above-described development processing was performed at a temperature of 25 ° C. to prepare a measurement sample. Note that the exposure amount at the time of the X-ray photography was adjusted so that the average value of the maximum density and the minimum density after the development processing was 1.0.

Next, the measurement sample was operated with a microdensitometer. At this time, the aperture direction is 30μ.
The concentration profile was measured at a sampling interval of 30 μm using a slit having a length of 500 μm and a direction perpendicular to the same. Repeat this operation 20 times to calculate the average value,
It was used as the concentration profile for calculating the CTF.
Thereafter, the peak of the rectangular wave at each frequency of the density profile was detected, and the density contrast at each frequency was calculated. Table 1 shows values measured for the spatial frequencies of 1 line / mm and 3 lines / mm.

3) Sensitivity measurement Using the same X-ray source as used in the CTF measurement,
Combine the Eastman Kodak MRE single-sided photosensitive material that is felt and change the amount of X-ray exposure by the distance method.
Step exposure was performed with a width of ogE = 0.15. After the exposure, the photosensitive material was developed under the same conditions as in the CTF measurement to obtain a measurement sample. The concentration of the measurement sample was measured with visible light to obtain a characteristic curve. Represents sensitivity by the reciprocal of the X-ray exposure required to obtain a concentration of dmin +1.0, an increase of a rear arrangement screens HR-4 (manufactured by Fuji Photo Film Stock
Relative sensitivity was examined with reference to a commercial product manufactured by the company (referred to as “100”). Table 1 shows the results.

Table 1 増 Intensifying screen X-ray absorption sensitivity CTF (1 / mm) CTF (3 / mm) ──────────────────────────────────── HR -3 (front side)-----0.890 0.660 HR-3 (rear side)-----0.889 0.660 HR-4 (front side)------0.850 510 HR-4 (rear side) ----- 0.850 0.506 HR-8 (front side) ----- 0.775 0.340 HR-8 (rear side) ----- 763 0.336 HR-12 (front side)-----0.773 0.294 (rear side)-----0.681 0.213 Trimax12 (front side)-----0.782 226 (rear side) --- 0.643 0.191 ──────────────────────────────────── Intensifying screen A 32. 8% 200 0.869 0.494 Intensifying screen B 43.2% 270 0.802 0.375 ──────────

(3) The following silver halide photographic material was prepared. Super HRS (commercially available from Fuji Photo Film Co., Ltd.) T-Mat M2 (commercially available from Eastman Kodak) GTU (commercially available from 3M) Silver halide photographic light-sensitive material I (prototype I) Silver halide photography Photosensitive material II (prototype II) Silver halide photographic material III (prototype III) Silver halide photographic material IV (prototype IV)

1) Preparation of silver halide photographic light-sensitive material I (Preparation of fine-particle monodispersed non-tabular grain emulsion A) 2% by weight gelatin containing 5.3 g of potassium bromide and 4 g of sodium paratoluenesulfinate To 1 liter of the solution were added 10 mg of sodium thiosulfate pentahydrate, 4 g of rodancari, and 10 cc of glacial acetic acid. 7 cc of an aqueous solution containing potassium iodide and 0.33 g of potassium iodide was added over 30 seconds. Then, 12 cc of an aqueous solution containing 1.2 g of potassium iodide was added. First, 200 cc of an aqueous solution containing 78 g of silver nitrate was added to the above solution, and then, one minute later, 200 cc of an aqueous solution containing 50.6 g of potassium bromide and 3.65 g of potassium iodide was added over a total of 15 minutes. Next, 22 cc of 25 wt% ammonia water
After aging for 10 minutes, an aqueous solution containing 117 g of silver nitrate and an aqueous solution containing 82.3 g of potassium bromide were added simultaneously over 14 minutes. In addition, the temperature of the reaction solution in all the steps was maintained at 70 ° C. The above reaction solution is washed by a flocculation method in a conventional manner, and after adding and dispersing gelatin, a thickener and a preservative at 40 ° C., the pH is adjusted to 5.
6 and pAg was adjusted to 8.9. Next, 21 mg of 4-hydroxy-6-methyl-1,3,3a, 7-tetrazaindene and 170 mg of the following sensitizing dye A were added while maintaining the reaction solution at 55 ° C., and the mixture was aged for 10 minutes. Then, sodium thiosulfate pentahydrate 9 mg, rodankari 7
7 mg and 1.6 mg of chloroauric acid were sequentially added, and 50
Aging for 4 minutes and then 4-hydroxy-6-methyl-
After addition of 70 mg of 1,3,3a, 7-tetrazaindene, the mixture was cooled to obtain a monodispersed fine-particle non-tabular grain emulsion A.

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The silver halide grains in the obtained silver halide emulsion were potato-like, and were monodisperse grains having an average projected area equivalent circle diameter of 0.60 μm and a variation coefficient of 18%.

(Preparation of Coating Solution) a) Silver halide emulsion coating solution The following substances were added to the above fine grain monodisperse non-tabular grain emulsion A in the following amounts per mole of silver halide. The addition gave an emulsion coating solution. Polymer latex (poly (ethyl acrylate / methacrylic acid) = 97/3, weight ratio) 20.0 g Hardener (1,2-bis (vinylsulfonylacetamide) ethane) 2.4 g 2,6-bis (hydroxy) Amino) -4-diethylamino-1,3,5-triazine 76 mg Sodium polyacrylate (average molecular weight 41,000) 2.1 g Sodium polystyrene sulfonate (average molecular weight 600,000) 1.0 g Dextran (average molecular weight 3.9) 10,000) 23.6 g Trimethylolpropane 9.8 g

B) Coating Solution for Forming Surface Protective Layer A coating solution having the following composition was prepared. Gelatin 1.0 g Dextran (average molecular weight 39,000) 0.228 g 4-hydroxy-6-methyl-1,3,3a, 7-tetrazaindene 0.0155 g Sodium polyacrylate (average molecular weight 41,000) 0.023g

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0.035 g of C ₁₆ H ₃₃ O (CH ₂ CH ₂ O) ₁₀ H C ₈ F ₁₇ SO ₂ N (C ₃ H ₇ ) (CH ₂ CH ₂ O) ₄ (CH ₂ ) SO ₃ Na 0005 g C ₈ F ₁₇ SO ₃ K 0.0053 g Polymethyl methacrylate particles (average particle size 3.7 μm) 0.088 g Proxel 0.006 g

(Support) Biaxially stretched thickness of 175 μm
The surface of the blue dyed polyethylene terephthalate film was subjected to corona discharge treatment, and the following components were mixed and prepared so as to have the following coating amounts (per side), using a wire bar coater, and sequentially applied. An undercoat layer consisting of two layers was formed.

A) Undercoating lower layer Butadiene / styrene copolymer latex (butadiene / styrene weight ratio = 31/69) 0.322 g / m ² 2,4-dichloro-6-hydroxy-s-triazine sodium salt 8.4 mg / M ²

[0102]

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[0103]

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B) Undercoating upper layer (dye layer) Gelatin 300 mg / m ² Polyethylene acrylate 20 mg / m ² C ₁₂ H ₂₅ O (CH ₂ CH ₂ O) ₁₀ H 4 mg / m ²

[0105]

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Polymethyl methacrylate particles (average particle size 2.5 μm) 2.5 mg / m ² Magenta dye A

[0107]

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The above magenta dye was made into a dispersion in a microcrystalline state by the following preparation method and added to a gelatin solution. 20 g of the dye, 200 g of a 1% by weight aqueous solution of carboxymethylcellulose and 287 g of water were mixed, and the diameter was 2 m.
5,000 with an Eiger mill (manufactured by Eiger Japan Co., Ltd.) using zirconium oxide (ZrO ₂ ) beads of
The mixture was treated for 8 hours under the condition of rpm to obtain a dye dispersion having an average particle size of 0.37 μm.

(Photosensitive Material) The above-mentioned silver halide emulsion coating solution and the coating solution for forming the surface protective layer were sequentially coated on each side of the above-mentioned support having a double-sided undercoat layer by a simultaneous multi-layer method. A silver halide photographic light-sensitive material I having a silver halide emulsion layer and a surface protective layer formed thereon was produced. The coating amount was such that the silver amount was 2 g / m ² per side for the silver halide emulsion coating solution, and the gelatin amount was 1 g / m ² per side for the coating solution for forming the surface protective layer. I made it.

2) Preparation of silver halide photographic light-sensitive material II (Preparation of fine grain monodispersed tabular grain emulsion B) 6.0 g of potassium bromide and 5.0 g of gelatin were added to 1 liter of water. Was stirred and maintained at 55 ° C., and 30 cc of an aqueous silver nitrate solution (5.5 g of silver nitrate) and 33 cc of an aqueous solution containing 9.4 g of potassium bromide were added thereto over 45 seconds by a double jet method. Next, the solution is cooled to 62 ° C.
To 60 cc of silver nitrate aqueous solution (silver nitrate 11.1).
g) was added over 12 minutes. Next, 6 cc of a 25% aqueous ammonia solution was added, and the mixture was physically aged at the same temperature for 5 minutes, and then 5.6 cc of 100% acetic acid was added. Next, an aqueous solution of 150.0 g of silver nitrate and an aqueous solution of potassium bromide were added thereto over 25 minutes by a control double jet method while keeping the above solution at pAg8. Further, to this solution, 15 cc of a 2N aqueous solution of potassium thiocyanate and silver iodide particles having a diameter of 0.07 μm were added so as to be 0.1 mol% with respect to the silver amount of the liquid to be added. The resulting mixture was left at the same temperature for 5 minutes for physical ripening, and then the temperature was lowered to 35 ° C. According to the above-mentioned method, halogenation including monodisperse tabular grains having a total silver iodide content of 0.1 mol%, an equivalent projected circle area equivalent diameter of 0.70 μm, a thickness of 0.12 μm, and a variation coefficient of 16.8%. A silver emulsion was obtained. Thereafter, salts were removed by a sedimentation method. The emulsion was heated to 40 ° C again, and gelatin 41
g and 1.4 g of phenoxyethanol and 0.8 g of sodium polystyrene sulfonate as a thickener,
PH 5.90 with sodium hydroxide and silver nitrate solution, pAg
Adjusted to 7.90. Next, the silver halide was chemically sensitized while stirring the emulsion at 56 ° C. That is, silver iodide fine particles were added to the above emulsion at a ratio of 0.05 mol%, and thiourea dioxide was added in an amount of 0.1 mol%.
After the addition of mg, reduction sensitization was performed by maintaining the state for 10 minutes. Next, 430 mg of the above-mentioned sensitizing dye A was added to the reduction-sensitized emulsion, and sodium thiosulfate and the following selenium sensitizer were added at a molar ratio of 6: 4.

[0111]

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Finally, chloroauric acid and potassium thiocyanate were added to the processed emulsion, and after 40 minutes, the mixture was cooled to 35 ° C. to obtain monodispersed fine grain tabular grain emulsion B.

(Photosensitive Material) The silver halide emulsion coating solution prepared by the same method as described above except that the fine grain monodisperse non-tabular grain emulsion A was changed to the fine grain monodisperse tabular grain emulsion B described above, The same coating solution for forming a surface protective layer as described above is sequentially applied to each side of the same support having a double-sided undercoat layer by a simultaneous multilayer method, and a silver halide emulsion layer and a surface protective layer are formed on both sides. Silver halide photographic material II
Was manufactured. However, the coating amount was adjusted so that the silver amount was 1.5 g / m ² per one side for the silver halide emulsion coating solution.

3) Preparation of silver halide photographic light-sensitive material III (Preparation of tabular grain emulsion C) In 1 liter of water, 4.5 g of potassium bromide, 20.6 g of gelatin, and thioether [HO (CH ₂ ) _2] S (CH ₂ ) ₂ S (CH ₂ ) ₂
2.5 CC of a 5% aqueous solution of OH] was added thereto, and while stirring the mixture at 65 ° C, an aqueous solution containing 3.43 g of silver nitrate, 2.97 g of potassium bromide, and 0% of potassium iodide were added. After adding an aqueous solution containing 0.36 g by a double jet method for 7 seconds, 0.1 mg of thiourea dioxide having the following structure was added.

[0115]

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Next, the temperature of the mixture was raised to 70 ° C.
After adding 18 cc of an aqueous ammonia solution of 100%
Neutralization was performed by adding 17 cc of acetic acid.
3.43 g of the aqueous solution was added over 35 minutes by the control double jet method while maintaining the potential at pAg 8.2. The flow rate at this time was adjusted so that the flow rate at the end of the addition was 2.6 times the flow rate at the start of the addition. After the addition was completed, 15 cc of a 2N aqueous solution of potassium thiocyanate was added to the mixture, and 38.5 g of a 1% aqueous solution of potassium iodide was added over 30 seconds. Thereafter, the temperature of the mixture was lowered to 35 ° C., the soluble salts were removed by sedimentation, the temperature was raised to 40 ° C., gelatin and phenoxytanol were added, and the pH was raised to 6.50 with sodium hydroxide and potassium bromide. And pAg was adjusted to 8.20. Next, the temperature of the mixture was raised to 56 ° C., and then 0.05 mg of thiourea dioxide was added. After stirring this mixture for 20 minutes as it is, 4-hydroxy-1,3,3a, 7-tetrazaindene 154
10 minutes after that, 5 minutes of the sensitizing dye A was added.
Then, after 5 minutes, sodium chloride was added to the solution.
44 g were added. After another 10 minutes, 3.3 mg of sodium thiosulfate pentahydrate, 11 mg of potassium thiocyanate
8 mg and then 2 mg of chloroauric acid were added, and after 70 minutes, the mixture was quenched and solidified to obtain a tabular grain emulsion C. In the obtained emulsion C, 99.5% of the total projected area of all grains is composed of grains having an aspect ratio of 3 or more, and the average projected circle area equivalent diameter of all grains having an aspect ratio of 3 or more is 1.35 μm. The standard deviation was 22.3%, the average thickness was 0.200 μm, and the aspect ratio was 6.8.

(Sensitive material) A silver halide emulsion coating solution prepared by the same method as described above, except that the fine-particle monodispersed non-tabular grain emulsion A was changed to the above-mentioned tabular grain emulsion C, was used. A coating solution for forming a surface protective layer is sequentially coated on each side of the same support having a double-sided undercoat layer by the simultaneous multilayer method, and a silver halide emulsion layer and a surface protective layer are formed on both sides. Silver photographic light-sensitive material III was produced.

4) Production of silver halide photographic light-sensitive material IV A silver halide photographic light-sensitive material IV was produced in the same manner as in the preparation of the silver halide photographic light-sensitive material I described above, except that the magenta dye was not contained in the upper layer of the undercoat layer. Was manufactured. However, when producing a fine particle monodisperse non-tabular grain emulsion,
The following magenta dye B was added to the emulsion so as to give a coating amount of 20 mg / m ² , and an increase in crossover (that is, an increase in sensitivity) due to removal of the dye layer was confirmed by adding a dye to this emulsion layer. And the sensitivity was adjusted so as to be equivalent to that of the silver halide photographic material I. Magenta dye B

[0119]

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(4) Measurement of characteristics of silver halide photographic light-sensitive material 1) Measurement of sensitivity A tungsten light source having a color temperature of 2856 K ゜ (light of 545 nm by a filter) was used using a filter having a filter characteristic shown in FIG. The light-sensitive material was exposed to light using an irradiation light (corresponding to the main emission wavelength of a radiation intensifying screen to be used together later), and the sensitivity was measured. That is, exposure was performed by irradiating the photosensitive material with the above-mentioned irradiation light through a neutral step wedge for 1/20 second. After exposure, the photosensitive material is processed with an automatic developing machine (manufactured by Fuji Photo Film Co., Ltd., trade name: FPM-5000) to have a developer RDIII (manufactured by Fuji Photo Film Co., Ltd., having the same composition as the developer A described above). ) And developed at 35 ° C. for 25 seconds (total processing time 90 seconds). After the photosensitive layer on the side opposite to the exposed surface is peeled off, the density is measured and a characteristic curve is obtained. From the characteristic curve, an exposure amount necessary for obtaining a density obtained by adding 0.5 to the minimum density (Dmin) is calculated. The sensitivity is shown in Table 2 in lux seconds. Incidentally, per to calculate the exposure amount, and emission from a tungsten light source was measured illuminance of light is transmitted through the filter with PI-3F type luminometer (calibration already ones).

2) Measurement of crossover The silver halide photographic light-sensitive material was treated with a radiation intensifying screen A
(Using a terbium-activated gadolinium oxysulfide phosphor (main emission wavelength: 545 nm, green light)) was sandwiched between black paper and X-rays were irradiated from the black paper side. The same X-ray source as that used in the evaluation of the intensifying screen was used. By changing the X-ray irradiation amount by the distance method,
X-rays were irradiated. After irradiation, the light-sensitive material was developed by the same method as that used in the above-described sensitivity measurement.
The developed photosensitive material was divided into two parts, and the respective photosensitive layers were peeled off. The density of the photosensitive layer on the side in contact with the intensifying screen was higher than the density of the photosensitive layer on the opposite side. A characteristic curve is obtained for each photosensitive layer, and an average value of the sensitivity difference (Δlog E) in a linear portion (from 0.5 to 1.0) of the characteristic curve is obtained. Was calculated. Crossover (%) = 100 / (antilog (ΔlogE) +1) Even when the intensifying screen was changed to another, almost the same value was obtained.

Table 2 shows the calculated crossover (%).

(5) Evaluation of the characteristics of the assembly of the silver halide photographic light-sensitive material and the radiation intensifying screen 1) Measurement of sensitivity and gamma Exposure and development were carried out using the same method as in the sensitivity measurement of the intensifying screen described above, except that they were arranged as usual. Sensitivity is minimum density (Dmin)
The reciprocal of the X-ray exposure required to obtain a density of +1.0 is
Based on the sensitivity of the assembled HR-4 / Super HRS (10
0) is shown as a relative value. Gamma is 0.
The average gamma was between 8 and 1.2.

2) Measurement of MTF The photosensitive material to be evaluated was placed between two intensifying screens to be evaluated in the same manner as above, and the rectangular chart for MTF measurement was photographed. 2m from the X-ray tube
The chart was placed at the position of, and X-ray exposure was performed. The photosensitive material after photographing is used in the roller transport type automatic developing machine (FPM-5).
000) in the same manner as above, and a measurement sample was prepared. The exposure amount during X-ray photography was also adjusted in the same manner as described above. Next, the measurement sample was operated with a microdensitometer, and the concentration profile was measured. This operation 2
The average was calculated by repeating 0 times, and this was used as the concentration profile for calculating the CTF. Thereafter, the peak of the rectangular wave at each frequency of the density profile was detected, and the density contrast at each frequency was calculated. Next, the above-mentioned density contrast was converted into an effective exposure amount rectangular contrast using a characteristic curve obtained separately. In order to derive the MTF, first, as a model MTF (ν), MTF (ν) = b
(1+ (au) ² ) ⁻¹ (a and u are parameters, respectively) was assumed. In the same procedure as the derivation of the Coltman's equation, the effective exposure rectangular contrast is calculated as MTF (ν) and its high frequency components MTF (3), MTF (5), ~~~~~
, Expressed in MTF (111), and the above parameters were determined to match the experimental values. The procedure of the formula transformation is described in detail in Uchida et al., "Radiation Image Information Engineering (I)" (Tssho Sangyo Kensha, 1981), page 171. Then, the MTF (ν) was determined by substituting the value into the above equation.

3) Measurement of noise power spectrum (NPS ₀ (ν)) 2 m from the X-ray tube using the same X-ray source (80 Kvp, 3 mm aluminum equivalent material, water 7 cm wide filter) used for MTF measurement And the exposure was adjusted to adjust the exposure amount to 1.0 when a photosensitive material was developed, thereby preparing an NPS ₀ measurement sample. The obtained sample was scanned with a macrodensitometer. As the aperture at this time, the density was measured at a sampling interval of 20 μm using a slit having a scanning direction of 30 μm and a vertical direction of 500 μm. 8192 (dots /
(Line) × 12 (Line) sampling was performed, and the result was divided into 256 points to perform FFT processing.
The average number of FFTs is 1,320. The noise power spectrum was calculated from the result.

4) Calculation of NEQ NEQ (ν) = (log ₁₀ e × γ · MTF (ν)) ² /
Calculation is performed according to the formula of NPS ₀ (ν), and the assembly HR-4 / Super is calculated.
The NEQ value of HRS was shown as a relative value with reference (assumed as 100). For the result, the spatial frequency is 1 line / mm
And the value of 3 lines / mm are shown as representative values.

5) Calculation of DQE DQE was calculated according to the following equation: DQE (ν) = NEQ (ν) / Q (Q represents an incident X-ray quantum number). NEQ (ν) uses the above relative value, and Q is inversely proportional to the sensitivity of the assembly. Therefore, the above equation can be expressed as follows. Relative DQE (ν) = Relative NEQ × Relative sensitivity The relative DQE (ν) is obtained from this equation, and the assembly HR-4 / S
The DQE value of the upper HRS was shown as a relative value with reference (100). For the result, spatial frequency 1
The values of lines / mm and 3 lines / mm are shown as representative values.

6) Visual evaluation Chest phantom, Kyoto Chemical Co., Ltd., three-phase 12 pulses 1
00Kvp (3mm thick aluminum equivalent filter installed), focal spot size 0.6mm × 0.6m
Using an X-ray source of m, a phantom is placed at a distance of 140 cm, and then a scattered radiation cut grid with a grid ratio of 8: 1, and then an assembly of a photosensitive material and an intensifying screen are taken. Done. The development process is
As in the case of the measurement of the photographic characteristics, the automatic developing machine FPM-5 was used.
000, developer RDIII, and fixer F described above,
Processing was performed at 35 ° C. for 90 seconds (development time was 25 seconds). A certain point in the lung field was determined, and the amount of X-ray exposure was adjusted by changing the exposure time so that the density was 1.6.
The finished chest phantom photographs were arranged in a shakasten and visually evaluated. Primarily, the visibility of the vascular shadow in the lung field was evaluated. A was very good, B was good, C was somehow diagnosable, and D was not diagnosable. In addition, in the case where the same score shows a significant difference, a or z is added to the end of the score mark, such as Aa (excellent in A) and Az (poor in A).

The above evaluation results are shown in Tables 3 and 4. Table 3 ─────────────────────────────── Assembly Photosensitive material / sensitized Photosensitive material sensitivity Crossover No. Screen (lux Seconds) (%) 組 Comparative assembly 1 Photosensitive material I / HR-8 0135 3.6 2 Photosensitive material II / HR-8 0.0240 3.0 Present assembly 3 Photosensitive material I / Test A 0.0135 3.6 4 Photosensitive material II / Test A 0.0240 3.05 Photosensitivity Material II / Test B 0.0240 3.0 Comparative assembly 6 Photosensitive material II / HR-12 0.0240 3.0 7 Super HRS / HR-3 0.0076 188 Super HRS / HR-4 0.0076 189 Super HRS / HR-8 0.0076 18 10 Photosensitive material III / HR-8 0.0068 3.6 11 Photosensitive material III / HR-4 0.0068 3.6 12 Photosensitive material IV / HR-8 0175 28 13 T-Mat M2 / HR-4 0.0055 3.0 14 T-Mat M2 / HR-8 0.0055 3.0 15 GTU / HR-8 0.0093 16 16 GTU / Trimax12 0.0093 16 ── ─────────────────────────────

Table 4 ──────────────────────────────────── Assembly Sensitivity γ DQE NEQ MTF Visual Number (Dmin + 1.0) (0.8-1.2) 1 piece 3 pieces 1 piece 3 pieces 1 piece 3 pieces Evaluation ───────────────────────────組 Comparative assembly 1 87 2.90 158 105 181 121 0.70 0.27 B2 48 2.90 161 109 335 227 0.71 0.27 A Invented assembly 3 100 2.90 173 132 173 132 0.77 0.37 A4 55 2.90 179 135 325 245 0.77 0.37 Aa 5 66 2.90 186 115 281 174 0.72 0.28 A Comparative assembly 6 73 2.90 170 56 233 77 0.65 0.15 Ca 7 55 2.55 72 89 131 162 0.82 0.51 Ca 8 100 2.55 100 100 100 100 0.75 0.37 C 9 180 2.55 148 93 82 52 0.65 0.23 D 10 180 2.70 155 100 86 56 0.70 0.27 C 11 100 2.70 105 110 105 110 0.78 0.40 Cz 12 88 2.90 125 60 142 68 0.67 0.21 C 13 117 2.92 110 113 94 97 0.84 0.48 Cz 14 219 2.90 147 95 67 43 0.70 0.28 D 15 155 2.88 129 64 83 41 0.67 0.24 C 16 204 2.90 197 56 97 28 0.61 0.16 D ───────────────────────── ───────────

The following facts were found from the above data. 1) The assembly of (1) and (2) for comparison has a DQE of 1.5 to 2 .5 compared to the assembly of (7) and (8) for comparison.
0 times higher, good balance between image quality and sensitivity. 2) However, the combination of (3) and (4) according to the present invention using the intensifying screen A of the prototype is the above-mentioned (1) for comparison.
Compared with the combination of (2) and (2), a slight increase in DQE (1 line / mm) and a large increase in DQE (3 lines / mm) were observed, and the sensitivity was also improved. There is also an improvement in MTF. Note that, in visual observation of an X-ray image, the visibility of a blood vessel shadow is particularly excellent. 3) The assembly (5) according to the present invention using the intensifying screen B of the prototype has less "roughness" particularly in the visual observation of the X-ray image than the above-described various assemblies according to the present invention. The visibility was the best. 4) The assembly (6) for comparison has a good granularity, but there is no particular problem in diagnosis, but visual observation of the X-ray image shows "blur" in the blood vessel image. Also, MT
There is also a problem that F (modulation transfer function) is low, and DQE (quantum detection efficiency) is remarkably low especially at 3 lines / mm, so that it is difficult to sufficiently form an X-ray image.

5) The assembly of (9) for comparison shows a DQE similar to that of (1) and (2) for comparison.
F was low, and visual observation of the X-ray image showed that "blur" and "roughness" were severe, and diagnosis with the X-ray image was impossible. 6) For the assembly of (10) and (14) for comparison, a photosensitive material having high sensitivity and low crossover and an intensifying screen having a large amount of X-ray absorption are used, but the sensitivity as an assembly is low. Since the MTF is too high, the MTF is high. However, according to visual observation of the X-ray image, “graininess” is severe, and diagnosis with the X-ray image is difficult. 7) The combination of (11) and (13) for comparison uses a photosensitive material with high sensitivity and low crossover and an intensifying screen with small X-ray absorption, so that the MTF is extremely high. DQE and NEQ were not high, and "graininess" was severe even in visual observation of an X-ray image, making diagnosis with the X-ray image difficult. 8) The assembly of (12) for comparison uses a photosensitive material that has more crossover than the photosensitive material suitable for use in the assembly of the present invention. And DQE and NEQ at 3 lines / mm are reduced. Also, in visual observation of X-ray images,
I was worried about the blurring of the blood vessel image. 9) The crossover of the photosensitive material used in the combination of (15) and (16) for comparison was higher than the specification of the present invention, and the sensitivity was high, but the MTF was low and the X-ray image was low. Was inferior to the X-ray image obtained by the combination of (1) and (2) for comparison, and was not satisfactory.

Example 2 (1) Production of silver halide photographic light-sensitive materials V, VI, VII, VIII An undercoating upper layer (dye layer) of a support used for production of silver halide photographic light-sensitive material I of Example 1 ) Of Table 5
Except that the combination of the magenta dye B and the mordant C was changed, the same materials and methods were used to prepare four types of silver halide photographic materials, silver halide photographic materials V, VI, VII,
VIII was produced.

Table 5 Photosensitive material Amount of magenta dye B applied Amount of mordant C applied Photosensitive material ^{V 40mg / m 2 110mg / m} 2 photosensitive material ^{VI 80mg / m 2 225mg / m} 2 photosensitive material ^{VII 160mg / m 2 450mg / m} 2 photosensitive material ^{VIII 200mg / m 2 550mg / m} 2

Magenta dye B

[0136]

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Mordant C

[0138]

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(Acrylic acid is added to the mordant dispersion in such a ratio that the amount of -COOH is １ ／ by weight with respect to the total amount of nitrogen of the mordant and polymerized).
The coating amount shown in Table 5 is per one side.

(2) Measurement of Characteristics of Silver Halide Photosensitive Material The sensitivity and crossover on one side of the photosensitive layer were measured and calculated by the method described in Example 1. Table 6 shows the measured sensitivity and the calculated crossover (%). The data of the photosensitive material I of Example 1 are also shown for reference.

Table 6 Photosensitive material Single-sided sensitivity (Dmin +0.5) Crossover Photosensitive material I 0.0135 luxsecond 5.3% Photosensitive material V 0.0133 luxsecond 16% Photosensitive material VI 0.0136 luxsecond 10% Photosensitive material VII 0.0135 luxsecond 5.5% Photosensitive material VIII 0.0134 Lux seconds 4.2%

The sensitivities of the photosensitive layers of the photosensitive materials I, V, VI, VII and VIII are almost the same, and it can be seen that the used dye is well fixed to the undercoating upper layer (dye layer). The light-sensitive material using magenta dye B / mordanting agent C showing the same level of crossover as light-sensitive material I
VII, and 160 mg / m
It was found that an application amount of m ² was required.

(3) The sensitivity and image quality of the photosensitive material VII exhibiting the same crossover as that of the photosensitive material I were examined by the method described in Example 1 using the radiation intensifying screen A.
Within the range of the experimental error, the sensitivity, MTF, DQE, and NEQ are all the same as the combination of the photosensitive material I and the radiographic intensifying screen A, and the type of the dye for reducing the crossover is changed. It was also found that good sensitivity and image quality could be obtained.

(4) Next, photosensitive materials I, V, VI, VII,
For each of VIII, residual color was examined by the following method. Adjust the size of the photosensitive material to 24cm x 30cm,
The unexposed photosensitive material was developed using two types of developing machines of a roller transport type. 1) Automatic developing machine FPM-5000 (manufactured by Fuji Photo Film Co., Ltd.) Developer RDIII (described above) Developing time 25 seconds, temperature 35 ° C. Fixing solution F (described above) Fixing time 20 seconds, temperature 25 ° C. Rinse water Rinse time 12 seconds, Temperature 25 ° C drying Drying time 26 seconds, temperature 55 ° C (total processing time 90 seconds) 2) Automatic developing machine FPM-9000 (manufactured by Fuji Photo Film Co., Ltd.) Highly active developer * Developing time 13.7 seconds, temperature 35 ° C Fixing solution F (described above) Fixing time 10.6 seconds, temperature 25 ° C water washing Water washing time 6.2 seconds, temperature 25 ° C drying Drying time 14.1 seconds, temperature 55 ° C (total processing time 45 seconds) Note: High active development The liquid used was 2.4 g of 1-phenyl-3-pyrazolidone in the aforementioned developer RDIII (developer A).
/ L. The residual color of each photosensitive material after the development processing was visually evaluated. Table 7 shows the results.

Table 7 Photosensitive material FPM-5000 (90 seconds) FPM-9000 (45 seconds) Photosensitive material IAB Photosensitive material VBE Photosensitive material VI Ca D Photosensitive material VII CD Photosensitive material VIII DD

The evaluation symbols shown in Table 7 have the following meanings. A: No residual color is observed. B: Slight residual color, but no practical problem. C: There is a residual color, but it is a practically acceptable level.
(Ca has slightly less residual color than C) D: The residual color is conspicuous. From the results shown in Table 7, it is understood that the photosensitive material I using the microcrystalline solid dye as the dye layer component provides the best image. In the case of the photosensitive material I, even after the treatment for 45 seconds, only a residual color of a practically acceptable level appeared.

Example 3 (1) Production of Silver Halide Photographic Material IX, X, XI The photosensitive emulsion A (fine-grain monodisperse non-tabular grains) used in the production of the silver halide photographic material of Example 1 Three types of silver halide photographs were prepared by using the same material and method except that the grain emulsion A) and the photosensitive emulsion C (tabular grain emulsion C) were used in combination as shown in Table 8 to form a laminated photosensitive layer. Light-sensitive materials, silver halide photographic light-sensitive materials IX, X and XI were produced.

Table 8 Photosensitive material Upper photosensitive layer (Emulsion C) Lower photosensitive layer (Emulsion A) Photosensitive material I - 2000mg / m ² photosensitive material ^{IX 100mg / m 2 2000mg / m} 2 photosensitive material ^{X 200mg / m 2 2000mg / m} 2 photosensitive material ^{XI 400mg / m 2 2000mg / m} 2 The coating amount shown in Table 8 is the amount of silver per side.

(2) Measurement of Characteristics of Silver Halide Photosensitive Material 1) According to the method described in Example 1, a sample photosensitive material was sandwiched between two radiation intensifying screens A, and log E =
Exposure was performed at a step of 0.15, development processing and density measurement were performed, and a characteristic curve was obtained. Dmin +1.0 sensitivity and Dmi
The average gamma (γ made at the points of n + 0.1 and Dmin + 0.5
₁ ) and the average gamma (γ ₂ ) formed by Dmin + 1.2 and Dmin + 1.6. Table 9 shows the results. 2) In the same manner as in Example 1, the photographic material of the sample was used in combination with intensifying screen A, and the chest phantom was set to 100K.
Images were taken with Vp X-rays. Since the assemblies have different sensitivities, the image density was adjusted by changing the exposure time so that the lung field densities became equal (about 1.6). The developing process was performed using the automatic developing machine FPM-5000 under the same developing conditions as in Example 1. The finished photos were arranged in a Shakasten and visually evaluated. The visibility of the blood vessel shadow and the structure of the mediastinum in the lung field was evaluated using the following evaluation symbols. A: extremely good (Az is slightly inferior to A), B: good,
C: Not good but diagnosable, D: Poorly diagnosable.

Table 9  Photosensitive material / sensitivity γ₁ γ_Two Pulmonary blood vessel image Mediastinum image Intensifying screen (Dmin + 1.0)  I / A 100 1.30 4.2 AC IX / A 102 1.00 3.8 AC V / A 110 0.75 3.6 AB XI / A 118 0.55 3.4 Az A

From the results shown in Table 9, when a small amount of the tabular grain emulsion C was laminated on the upper layer of the photosensitive layer, the latitude of the legs was widened and the discrimination of blood vessel shadow was not deteriorated, and the mediastinum was not deteriorated. It was found that the information amount of the information increased. In addition, the roughness of the image is smaller than that of the combination of the photosensitive material I and the intensifying screen A compared to the combination of the photosensitive material I and the intensifying screen A
Alternatively, it was found that the combination of the light-sensitive material XI and the intensifying screen A was excellent, and the latter two combinations provided the highest level of X-ray images.

[0152]

The combination of the silver halide photographic light-sensitive material of the present invention and a radiographic intensifying screen has good sensitivity, and the provided X-ray image shows high sharpness. Therefore, an X-ray image with extremely high visibility can be obtained without increasing the amount of X-ray exposure to the human body. Therefore, the combination of the silver halide photographic light-sensitive material of the present invention and a radiographic intensifying screen is extremely effective for improving the accuracy of actual medical diagnosis.

[Brief description of the drawings]

FIG. 1 is a spatial frequency (lp / mm) for explaining characteristics of a radiation intensifying screen used in a combination of a silver halide photographic light-sensitive material of the present invention and a radiation intensifying screen.
4 is a graph showing the relationship between the contrast transfer function (CTF).

FIG. 2 is a spectrum showing characteristics of a green light filter used in combination with a tungsten light source for sensitivity measurement of a silver halide photographic light-sensitive material.

──────────────────────────────────────────────────続 き Continuation of front page (72) Inventor Terumi Matsuda 798 Miyadai, Kaisei-cho, Ashigara-gun, Kanagawa Fuji Photo Film Co., Ltd. (56) References JP-A-4-339890 (JP, A) JP-A-2- 298939 (JP, A) (58) Field surveyed (Int. Cl. ⁷ , DB name) G03C 5/17 G21K 4/00

Claims (12)

(57) [Claims] 1. A radiation image-forming assembly comprising a silver halide photographic material and two radiation intensifying screens respectively disposed on the front side and the rear side of the photographic material, wherein (1) radiation At least one of the intensifying screens
X-ray energy shows the absorption of more than 25% with respect to X-rays of 80 KVp, contrast transfer function (CTF) is,
0.79 or more at 1 spatial frequency / mm, and spatial frequency
A radiation intensifying screen of 0.33 or more at several lines / mm ; (2) a silver halide photographic material having a silver halide photographic photosensitive layer on the front side and the rear side of a support, respectively; And at least one of the photosensitive layers is exposed to monochromatic light having the same wavelength as the main emission peak wavelength of the radiation intensifying screen defined in the above (1) and having a half width of 15 ± 5 nm. Then, using a developing solution having the following composition, a developing process was performed at a developing solution temperature of 35 ° C. and a developing time of 25 seconds. After the photosensitive layer on the side opposite to the exposed surface was peeled off, the concentration was measured. The sensitivity required for the exposure amount required to reach a value obtained by adding 0.5 to the minimum density is from 0.010 lux seconds to 0.035 lux seconds. Developer composition Potassium hydroxide 21 g Potassium sulfite 63 g Boric acid 10g Hydroquinone 25g After 1 liter by addition of triethylene glycol 20 g 5-nitroindazole 0.2g glacial acetic acid 10 g 1-phenyl-3-pyrazolidone 1.2 g 5-methylbenzotriazole 0.05g Glutaraldehyde 5g Potassium bromide 4g water, pH 10. 02 between the support and at least one photosensitive layer.
Dyeing consisting of microcrystalline dye particles that are decolorized by the development processing described above
And (3) radiating light emitted from a radiation intensifying screen disposed in front of the silver halide photographic light-sensitive material to the rear light-sensitive layer of the silver halide photographic light-sensitive material. Wherein the crossover is 10% or less, and a combination of a silver halide photographic material and a radiation intensifying screen. 2. The radiation intensifying screen defined in (1) above has a configuration in which a protective film , a phosphor layer, and a support layer are arranged in this order when viewed from the side facing the silver halide photographic material. Wherein the protective film is a transparent synthetic resin having a thickness of 5 μm or less formed on the phosphor layer.
An assembly of the silver halide photographic material according to claim 1 which is a film and a radiation intensifying screen. 3. A stepwise exposure of a silver halide photographic light-sensitive material by X-rays, and an exposure image obtained under the development processing conditions of the above (2) is represented by an optical density (D) and an exposure amount (logE) on a coordinate axis unit. In a characteristic curve on rectangular coordinates of equal length,
Minimum density (Dmin) + density 0.1 point and minimum density (Dmi)
n) + the point of density 0.5 and the average gamma (γ) to be formed is 0.
5 to 0.9, and the average gamma (γ) formed by the point of minimum density (Dmin) + density 1.2 and the point of minimum density (Dmin) + density 1.6 is 3.2 to 4.0. An assembly of the silver halide photographic light-sensitive material according to claim 1 having a certain characteristic curve and a radiation intensifying screen. 4. The combination of a silver halide photographic light-sensitive material and a radiographic intensifying screen according to claim 1, wherein each of the front and rear radiographic intensifying screens has the characteristics defined in the above (1). 5. The combination of a silver halide photographic light-sensitive material and a radiation intensifying screen according to claim 1, wherein the front and rear photosensitive layers each have the characteristics defined in the above (2). 6. X-ray energy shows the absorption of more than 25% with respect to X-rays of 80 KVp, contrast transfer function
(CTF) is 0.79 or more at a spatial frequency of 1 line / mm,
A silver halide photographic light-sensitive layer is provided on the front side and the rear side of the support, respectively, for use in combination with a radiation intensifying screen having a spatial frequency of 3 lines / mm and 0.36 or more. At least one of the photosensitive layers has the same wavelength as the main emission peak wavelength of the radiation intensifying screen, and is exposed to monochromatic light having a half width of 15 ± 5 nm, and has the following composition: And a developer temperature of 35.
Developing process at 25 ° C. for a developing time of 25 seconds, the photosensitive layer on the side opposite to the exposed surface was peeled off and measured, and the density obtained in the photosensitive layer became a value obtained by adding 0.5 to the minimum density. The sensitivity required for the exposure is 0.010 lux-second to 0.035 lux-second, and developer composition potassium hydroxide 21 g potassium sulfite 63 g boric acid 10 g hydroquinone 25 g triethylene glycol 20 g 5-nitroindazole 0.2 g After 1 liter by the addition of glacial acetic acid 10 g 1-phenyl-3-pyrazolidone 1.2 g 5-methylbenzotriazole 0.05g glutaraldehyde 5g potassium bromide 4g water, adjusted to PH10.02. Further, the support and at least one photosensitive layer
In the meantime, the microcrystalline dye particles that are decolorized in the above development process
A silver halide photographic material, comprising a dye layer comprising: 7. Stepwise exposure with X-rays, and the exposure image obtained under the development processing conditions of the above (2) is characterized in that the optical density (D) and the exposure amount (logE) on the orthogonal coordinates are equal in the unit length of the coordinate axis. In the curve, the minimum density (Dmin) + the density of 0.
The average gamma (γ) formed by the point 1 and the point of minimum density (Dmin) + density 0.5 is 0.5 to 0.9, and the point of minimum density (Dmin) + density 1.2 and minimum density The average gamma (γ) formed by (Dmin) + point of density 1.6 is 3.2-4.
7. The silver halide photographic material according to claim 6, which has a characteristic curve of 0. 8. The radiation sensitizing screen defined in (1) above.
For X-rays with an X-ray energy of 80 KVp
The halogen according to claim 1, which exhibits an absorption amount of 2.8% or more.
An assembly of a silver halide photographic material and a radiation intensifying screen. 9. The radiation sensitizing screen defined in the above (1).
The contrast transfer function (CTF) of the
One is / mm at 0.802 or more claims 1 or serial to 8
Silver halide photographic light-sensitive material and radiographic intensifying screen
And the assembly. 10. A radiosensitizing disk defined in the above (1).
Lean contrast transfer function (CTF)
10. The method according to claim 9 , wherein the number is 0.869 or more at several lines / mm .
Silver halide photographic materials and radiographic intensifying screens
Assembly. 11. A radiation sensitizing disk defined in the above (1).
Lean contrast transfer function (CTF)
9. A value of 0.375 or more at several lines / mm.
To silver halide photographic according to any one of the paragraphs 1 1
An assembly of materials and a radiographic intensifying screen. 12. A radiation sensitizing disk defined in the above (1).
Lean contrast transfer function (CTF)
The number is 3 or more per mm, and is 0.494 or more.
Silver halide photographic materials and radiographic intensifying screens
Assembly.