JP3028161B2 - Paint containing eggshell membrane - Google Patents
Paint containing eggshell membraneInfo
- Publication number
- JP3028161B2 JP3028161B2 JP4254157A JP25415792A JP3028161B2 JP 3028161 B2 JP3028161 B2 JP 3028161B2 JP 4254157 A JP4254157 A JP 4254157A JP 25415792 A JP25415792 A JP 25415792A JP 3028161 B2 JP3028161 B2 JP 3028161B2
- Authority
- JP
- Japan
- Prior art keywords
- eggshell membrane
- paint
- eggshell
- membrane
- paint containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paints Or Removers (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は卵殻膜を配合したことを
特徴とする新規塗料に関する。さらに詳しくは、塗料製
造時の分散性がよく、塗布時の密着性、付着性がよく、
かつ吸・放湿性に優れる塗料に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel paint containing an eggshell membrane. In more detail, the dispersibility at the time of paint production is good, the adhesion at the time of application, the adhesion is good,
The present invention also relates to a paint having excellent moisture absorption and release properties.
【０００２】[0002]
【従来の技術】コラーゲン、ゼラチン、ミルクカゼイ
ン、セルロース等の天然物を粉末状にして塗料あるいは
合成樹脂等に配合し、これらの塗膜に天然物の有する吸
湿性、保湿性、通気性、密着性、さらには天然皮革様の
風合いを付与することが行われている（特開昭６２−２
５７９３号、特開昭６２−２５７９７４号、特開平３−
３９３７１号、特公昭５２−３９６５２）。また、配合
する天然物として卵白および卵黄を使用した水系固形塗
料が開示されているが、その配合目的が塗料の固形化に
あり、吸湿性、放湿性等を付与するというものではない
（特公昭５４−２７８５４）。従来これら天然物の粉末
を得るためには非常に煩雑な工程が必要であると同時
に、得られた粉末が臭い、色等を有し、さらにコラーゲ
ン等は繊維状の高分子であるため粉末が綿状に絡み合
い、塗料に配合する場合非常に分散しにくく塗装時の表
面がきれいに仕上がらないという欠点があった。2. Description of the Related Art Powders of natural products such as collagen, gelatin, milk casein, and cellulose are blended into paints or synthetic resins, and the hygroscopicity, moisture retention, air permeability, and adhesion of natural products to these coatings. And imparting a natural leather-like texture (Japanese Unexamined Patent Publication No. Sho 62-2).
No. 5793, JP-A-62-257974, JP-A-3-
No. 39371, JP-B-52-39652). A water-based solid paint using egg white and egg yolk as a natural product to be blended is disclosed, but the purpose of blending is to solidify the paint and is not intended to impart hygroscopicity, moisture release, etc. 54-27854). Conventionally, obtaining these natural product powders requires extremely complicated steps, and at the same time, the obtained powder has an odor, color, and the like. It is entangled in a flocculent form and has the drawback that when it is incorporated into a coating, it is very difficult to disperse and the surface at the time of coating cannot be finished cleanly.
【０００３】一方、鳥類の卵殻の内面に存在する卵殻膜
は蛋白質の一種であり火傷や切傷等の皮膚疾患の治療剤
および化粧品の素材として、また卵殻膜の持つ重金属吸
着能を利用した重金属除去剤として利用することが知ら
れている（特開平２−１８２１５４、特開平２−２６５
６０、特開平２−２３１４２６、特公昭５４−２２４９
９、特開昭５８−１５０４３３）。このように卵殻膜は
多方面への利用が例示されているが塗料への利用はいま
だ見いだされていない。[0003] On the other hand, eggshell membranes existing on the inner surface of the eggshell of birds are a kind of protein and are used as a therapeutic agent for skin diseases such as burns and cuts and as a raw material for cosmetics, and for heavy metal removal utilizing the heavy metal adsorption ability of eggshell membranes. It is known to use as an agent (JP-A-2-182154, JP-A-2-265)
60, JP-A-2-231426, JP-B-54-2249
9, JP-A-58-150433). As described above, the use of eggshell membranes in various fields is exemplified, but the use thereof in paints has not been found yet.
【０００４】[0004]
【発明が解決しようとする課題】上記の状況から、塗料
製造時の分散性がよく、塗布時の密着性・付着性がよ
く、かつ吸・放湿性に優れた天然物の出現およびこれを
配合した新規塗料が強く求められている。In view of the above circumstances, the emergence and blending of natural products which have good dispersibility in the production of paint, good adhesion and adhesion during application, and excellent absorption and desorption of moisture. There is a strong need for new paints.
【０００５】[0005]
【課題を解決するための手段】上記課題を解決するため
鋭意研究した結果、卵殻膜を配合することで目的とする
塗料の得られることを初めて見いだし本発明を完成する
に至った。以下、本発明について詳述する。Means for Solving the Problems As a result of earnest studies to solve the above problems, it has been found for the first time that a desired paint can be obtained by blending an eggshell membrane, and the present invention has been completed. Hereinafter, the present invention will be described in detail.
【０００６】本発明の卵殻膜は鳥類の卵殻の内側に存在
する膜を指し、用いる時の形態は卵殻膜の粉末および化
学的・生物的な方法により可溶化した卵殻膜の蛋白質で
ある。あるいはサクシニル化、アシル化処理等の化学処
理した卵殻膜の誘導体も用いることができる。さらに必
要に応じて、卵殻膜および誘導体にホルマリン、グルタ
ルアルデヒド、ヘキサメチレンジイソシアネート等の架
橋剤による架橋、酸化染料、タンニン染料等の染色等を
施すことができる。さらには卵殻膜の持つ金属吸着能を
利用して、銀、銅、亜鉛、アルミニュウム等の金属を卵
殻膜に吸着させ、抗菌性あるいは耐光性を付与したもの
を使用することもできる。塗料に配合する時、これら卵
殻膜の粒径は平均0.01−100 μｍが適当である。[0006] The eggshell membrane of the present invention refers to a membrane existing inside the eggshell of birds, and when used, forms are eggshell membrane powder and eggshell membrane proteins solubilized by chemical and biological methods. Alternatively, a derivative of eggshell membrane that has been chemically treated such as succinylation or acylation can also be used. If necessary, the eggshell membranes and derivatives can be cross-linked with a cross-linking agent such as formalin, glutaraldehyde, hexamethylene diisocyanate, or dyed with an oxidation dye, a tannin dye, or the like. Furthermore, by utilizing the metal-adsorbing ability of the eggshell membrane, a metal having silver, copper, zinc, aluminum or the like adsorbed on the eggshell membrane to provide antibacterial properties or light resistance can also be used. When incorporated into a paint, the average particle size of these eggshell membranes is suitably from 0.01 to 100 μm.
【０００７】本発明の塗料中の卵殻膜の含有量は、ビヒ
クルに対して５−40％、好ましくは10−30％使用する。
塗料のビヒクルにはアクリル樹脂等の合成樹脂または天
然樹脂、可塑剤等の通常の塗料材料が用いられる。[0007] The content of the eggshell membrane in the paint of the present invention is 5-40%, preferably 10-30%, based on the vehicle.
As the vehicle of the coating material, a general coating material such as a synthetic resin such as an acrylic resin or a natural resin, a plasticizer or the like is used.
【０００８】[0008]
【実施例】以下本発明を実施例により説明するが、これ
により本発明が限定されることはない。 実施例１ 割卵後の卵殻10ｋｇを二倍量の水とともにミキサーにて
破砕し、デカンテーションにより卵殻膜を回収し、さら
に乾燥、粉砕して卵殻膜粉末0.2 ｋｇ（平均粒径７μ
ｍ）を得た。EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited thereto. Example 1 10 kg of eggshell after breaking eggs was crushed with a mixer with twice the amount of water, the eggshell membrane was recovered by decantation, dried and pulverized, and 0.2 kg of eggshell membrane powder (average particle size 7 μm)
m).
【０００９】実施例２ 割卵後の卵殻10ｋｇを0.2 Ｍ硫化ナトリウム溶液50Ｌに
加え、95℃にて１時間加熱し卵殻膜を可溶化した。濾過
により得た卵殻膜蛋白質溶液に5N硫酸を攪拌しながら徐
々に加えpHを4.3 とした。室温で一時間放置後、沈澱し
た蛋白質を布濾過により分離・回収し水洗した。得られ
た蛋白質を水２Ｌに懸濁し、水酸化ナトリウムにてｐＨ
10とし可溶化した。次に塩酸にてｐＨ4.5 とし再沈澱
後、水洗した。これら可溶化、沈澱、水洗の操作を３回
繰り返した。水洗後の沈澱を乾燥・粉砕して卵殻膜蛋白
質の粉末100 ｇ（平均粒径10μｍ）を得た。Example 2 10 kg of eggshell after breaking eggs was added to 50 L of 0.2 M sodium sulfide solution and heated at 95 ° C. for 1 hour to solubilize the eggshell membrane. 5N sulfuric acid was gradually added to the eggshell membrane protein solution obtained by filtration with stirring to adjust the pH to 4.3. After standing at room temperature for one hour, the precipitated protein was separated and collected by cloth filtration and washed with water. The obtained protein is suspended in 2 L of water, and the pH is adjusted with sodium hydroxide.
It was set to 10 and solubilized. Next, the pH was adjusted to 4.5 with hydrochloric acid, and the precipitate was washed again with water. These operations of solubilization, precipitation and washing with water were repeated three times. The precipitate after washing with water was dried and pulverized to obtain 100 g of an egg shell membrane protein powder (average particle size: 10 μm).
【００１０】実施例３ 実施例１で得られた卵殻膜粉末10ｇを５％グルタルアル
デヒド溶液300 ｍｌに加え、室温にて５時間攪拌しなが
ら処理した。濾過により回収後、水洗・乾燥・粉砕し架
橋処理した卵殻膜粉末10.2ｇを得た。Example 3 10 g of the eggshell membrane powder obtained in Example 1 was added to 300 ml of a 5% glutaraldehyde solution, and the mixture was stirred at room temperature for 5 hours. After collecting by filtration, 10.2 g of eggshell membrane powder washed, dried, pulverized and cross-linked was obtained.
【００１１】実施例４ 実施例１で得た卵殻膜粉末50ｇにエタノール75ｇを加え
てホモミキサーで分散させた。この液に油性塗料（アク
リル樹脂液45ｇ、顔料９ｇ、シンナー80ｇ、硬化剤６
ｇ）140 ｇを加え、ホモミキサーで分散させ油性塗料と
した。Example 4 To 50 g of the eggshell membrane powder obtained in Example 1, 75 g of ethanol was added and dispersed with a homomixer. Add oily paint (45 g of acrylic resin liquid, 9 g of pigment, 80 g of thinner,
g) 140 g was added and dispersed with a homomixer to obtain an oil-based paint.
【００１２】実施例５ 実施例１で得られた卵殻膜粉末50ｇに少量のエタノール
を加え分散後、水100ｍｌを加えホモミキサーにて分散
させた。この液に水性塗料（アクリル樹脂液100 、顔料
30ｇ、水190 ｇ）320 ｇを加え、ホモミキサーで分散さ
せ水性塗料とした。Example 5 A small amount of ethanol was added to 50 g of the eggshell membrane powder obtained in Example 1 and dispersed, and then 100 ml of water was added and dispersed using a homomixer. Add water-based paint (acrylic resin liquid 100, pigment
30 g, water 190 g) and 320 g were added, and the mixture was dispersed with a homomixer to obtain an aqueous paint.
【００１３】このようにして得られた塗料は塗布時の密
着性・付着性がよく、吸・放湿性に優れており、塗料製
造時における卵殻膜の分散性もよい。The paint thus obtained has good adhesion and adhesion during application, excellent absorption and desorption properties, and good dispersibility of the eggshell membrane during the production of the paint.
【００１４】[0014]
【発明の効果】資源的に豊富で、非常に安定な蛋白素材
である卵殻膜を配合した本発明の塗料は、塗布時の密着
性・付着性がよく、吸・放湿性に優れている。さらには
塗料製造時における卵殻膜の分散性もよいことから極め
て有用な塗料である。EFFECTS OF THE INVENTION The paint of the present invention containing an eggshell membrane which is a very stable protein material which is abundant in resources is excellent in adhesion and adhesion when applied, and excellent in absorption and desorption. Further, it is an extremely useful paint because the eggshell membrane has good dispersibility during the production of the paint.
フロントページの続き (56)参考文献 特開 昭57−68743（ＪＰ，Ａ) 特開 昭63−309273（ＪＰ，Ａ) 特開 平２−231426（ＪＰ，Ａ) 特開 平２−182154（ＪＰ，Ａ) 特開 平４−148649（ＪＰ，Ａ) 特開 平４−311767（ＪＰ，Ａ) 特公 昭48−18802（ＪＰ，Ｂ１) 特公 昭33−3720（ＪＰ，Ｂ１) 特公 昭31−1328（ＪＰ，Ｂ１) 特許169109（ＪＰ，Ｃ１) 特許132965（ＪＰ，Ｃ２) (58)調査した分野(Int.Cl.7，ＤＢ名) C09D 201/00 C09D 7/12 C09D 133/00 C09D 189/00 Continuation of the front page (56) References JP-A-57-68743 (JP, A) JP-A-63-309273 (JP, A) JP-A-2-231426 (JP, A) JP-A-2-182154 (JP) JP-A-4-148649 (JP, A) JP-A-4-311767 (JP, A) JP-B-48-18802 (JP, B1) JP-B-33-3720 (JP, B1) JP-B-A 31-1328 (JP, B1) Patent 169109 (JP, C1) Patent 132965 (JP, C2) (58) Fields investigated (Int. Cl. 7 , DB name) C09D 201/00 C09D 7/12 C09D 133/00 C09D 189/00
Claims (1)
（ただし、卵殻膜を含有するポリウレタン樹脂を用いる
場合を除く）。1. A paint containing an eggshell membrane (except when a polyurethane resin containing an eggshell membrane is used).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4254157A JP3028161B2 (en) | 1992-08-28 | 1992-08-28 | Paint containing eggshell membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4254157A JP3028161B2 (en) | 1992-08-28 | 1992-08-28 | Paint containing eggshell membrane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0680913A JPH0680913A (en) | 1994-03-22 |
| JP3028161B2 true JP3028161B2 (en) | 2000-04-04 |
Family
ID=17261023
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4254157A Expired - Fee Related JP3028161B2 (en) | 1992-08-28 | 1992-08-28 | Paint containing eggshell membrane |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3028161B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8034264B2 (en) | 2006-05-23 | 2011-10-11 | Ivoclar Vivadent Ag | Process for the preparation of colored blanks and dental shaped parts |
| US8173562B2 (en) | 2006-05-23 | 2012-05-08 | Ivoclar Vivadent Ag | Shaded zirconia ceramics |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG78412A1 (en) | 1999-03-31 | 2001-02-20 | Ciba Sc Holding Ag | Oxime derivatives and the use thereof as latent acids |
| KR100523276B1 (en) * | 2003-07-12 | 2005-10-24 | (주)디오 | Method for Manufacturing Protein Fibrin Paint |
| CN100515791C (en) * | 2004-08-19 | 2009-07-22 | 丘比株式会社 | Composition for forming ink-receiver layer, method of producing the same and printing base |
| KR100669821B1 (en) * | 2005-03-25 | 2007-01-19 | 유진화 | Paint comprising a natural materials and producing method thereof |
| JP5850863B2 (en) | 2010-02-24 | 2016-02-03 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Latent acids and their use |
-
1992
- 1992-08-28 JP JP4254157A patent/JP3028161B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8034264B2 (en) | 2006-05-23 | 2011-10-11 | Ivoclar Vivadent Ag | Process for the preparation of colored blanks and dental shaped parts |
| US8173562B2 (en) | 2006-05-23 | 2012-05-08 | Ivoclar Vivadent Ag | Shaded zirconia ceramics |
| US8541329B2 (en) | 2006-05-23 | 2013-09-24 | Ivoclar Vivadent Ag | Process for the preparation of coloured blanks and dental shaped parts |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0680913A (en) | 1994-03-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |