JP3027912B2 - Manufacturing method of hot rolled steel sheet with excellent hole spreadability - Google Patents

Manufacturing method of hot rolled steel sheet with excellent hole spreadability

Info

Publication number
JP3027912B2
JP3027912B2 JP7008172A JP817295A JP3027912B2 JP 3027912 B2 JP3027912 B2 JP 3027912B2 JP 7008172 A JP7008172 A JP 7008172A JP 817295 A JP817295 A JP 817295A JP 3027912 B2 JP3027912 B2 JP 3027912B2
Authority
JP
Japan
Prior art keywords
less
molten steel
inclusions
steel
slab
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP7008172A
Other languages
Japanese (ja)
Other versions
JPH08176661A (en
Inventor
東成 福山
誠 村岡
信一郎 勝
茂樹 野村
修二 中居
健司 坂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
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Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP7008172A priority Critical patent/JP3027912B2/en
Publication of JPH08176661A publication Critical patent/JPH08176661A/en
Application granted granted Critical
Publication of JP3027912B2 publication Critical patent/JP3027912B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Treatment Of Steel In Its Molten State (AREA)
  • Heat Treatment Of Steel (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、ホィールディスク、自
動車足廻り部品をはじめとする、苛酷な孔拡げ成形また
は伸びフランジ成形と張出し成形とを受ける部材用に適
した、優れた加工性、特に孔拡げ性および耐微小張出し
割れ性を示す、高強度熱延鋼板の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to excellent workability, particularly for members subjected to severe hole expansion forming or stretch flange forming and overhang forming, such as wheel discs and automobile undercarriage parts. The present invention relates to a method for producing a high-strength hot-rolled steel sheet exhibiting hole expandability and micro-extension crack resistance.

【0002】[0002]

【従来の技術】省資源・省エネルギーの観点から、鉄鋼
材料、例えば、高張力熱延鋼板に対しても、一層の高強
度化と成形性の向上が望まれている。特に、車両重量の
軽減のために、ホィールディスク、自動車足廻り部品な
どに高張力鋼を使用する傾向が強まり、高張力熱延鋼板
の孔拡げ性の改善が望まれてきた。
2. Description of the Related Art From the viewpoint of resource saving and energy saving, there is a demand for steel materials, for example, high-strength hot-rolled steel sheets, to have higher strength and improved formability. In particular, in order to reduce the weight of the vehicle, there is an increasing tendency to use high-tensile steel for wheel discs, automobile suspension parts, and the like, and it has been desired to improve the hole-expandability of high-tensile hot-rolled steel sheets.

【0003】また、最近のホィールディスクや自動車足
廻り部品においては、孔拡げ性だけでなく、ディスクの
ナット座、足廻り部品の張出し部などに十分な伸びが要
求される。これらの箇所では、表層介在物起因による微
小張出し割れが発生し易いからである。
Further, in recent wheel discs and vehicle suspension parts, not only the hole expandability but also the nut seat of the disk and the overhang portion of the suspension parts need to be sufficiently elongated. This is because in these places, minute overhang cracks due to surface inclusions are likely to occur.

【0004】熱延鋼板の孔拡げ性の改善に関する公知技
術には下記のものがある。 特開昭55−107732号公報:C量の低下により孔拡げ性
(伸びフランジ性) を向上させたものであるが、440 N/m
m2 クラス以上の高強度化は困難である。
[0004] The following are known techniques for improving the hole expandability of a hot-rolled steel sheet. Japanese Patent Application Laid-Open No. 55-107732: hole expandability due to decrease in C content
(Stretch flangeability), but 440 N / m
m 2 or more classes of high strength is difficult.

【0005】特開昭54−88827 号公報: REM、Caまたは
Zrを添加して硫化物を球状化させ、酸化物をすべてAl脱
酸し、さらにTi添加と熱間圧延および巻取条件制御によ
って、パーライト中のセメンタイトを球状化し、孔拡げ
性 (伸びフランジ性) を向上させる。球状ではあるが硫
化物とアルミナが鋼中に残存するので、耐微小張出し割
れ性は不十分である。
JP-A-54-88827: REM, Ca or
Zr is added to spheroidize sulfides, all oxides are deoxidized with Al, and cementite in pearlite is spheroidized by addition of Ti and hot rolling and winding conditions control to expand pores (stretch flangeability). ) To improve. Although it is spherical, the sulfide and alumina remain in the steel, so that the micro overhang cracking resistance is insufficient.

【0006】特開昭61−84330 号公報:巻取条件制御に
より、フェライト+ベイナイト組織にすることで孔拡げ
性 (バーリング性) を向上させる。特開昭54−88827 号
と同様、介在物制御が不十分であり、耐微小張出し割れ
性は満足できない。
Japanese Patent Application Laid-Open No. 61-84330: A ferrite + bainite structure is obtained by controlling the winding conditions to improve the hole expanding property (burring property). As in Japanese Patent Application Laid-Open No. 54-88827, the control of inclusions is insufficient, and the resistance to micro overhang cracking cannot be satisfied.

【0007】[0007]

【発明が解決しようとする課題】このように、従来技術
では孔拡げ性の改善に重点を置いていたため、組織の均
質化を図るだけで、介在物についてはあまり考慮されて
いなかった。即ち、ASTM-A法におけるA系介在物 (硫化
物系延伸型介在物) の低減を図っただけで、B系介在物
(群落介在物) 、C系介在物 (角状介在物) 、D系介在
物 (球状介在物)の低減対策はなされていない。そのた
め、異質な介在物が起点となる成形割れまたは疲労亀裂
発生の可能性はますます高くなっており、特に微小張出
し割れ (ポッチ割れ) がそれらの起因となることから、
耐微小張出し割れ性の改善が急務となっている。
As described above, in the prior art, since the emphasis was placed on the improvement of the hole expandability, the inclusions were not considered much, only to homogenize the structure. In other words, only the reduction of A-based inclusions (sulfide-based elongated inclusions) in the ASTM-A method was
No countermeasures have been taken to reduce (cluster inclusions), C-based inclusions (square inclusions), and D-based inclusions (spherical inclusions). For this reason, the possibility of forming cracks or fatigue cracks originating from foreign inclusions is becoming increasingly high, and in particular, micro-extension cracks (potch cracks) cause them,
There is an urgent need to improve micro overhang crack resistance.

【0008】従来の熱延鋼板用の介在物対策としては、
次に示すように形態制御がほとんどで、介在物量の削減
という抜本的な解決を図った例はない。 特開昭56−9317号公報: CaO吹込みにより、脱酸、脱硫
を施した上、Caを吹込み、介在物の形態制御を図る方法
であるが、介在物量の削減には至らない。
[0008] As measures against inclusions for conventional hot-rolled steel sheets,
As shown below, the form control is almost the same, and there is no example of a drastic solution of reducing the amount of inclusions. JP-A-56-9317: This is a method of controlling the form of inclusions by injecting Ca and then deoxidizing and desulfurizing and then injecting Ca, but this does not reduce the amount of inclusions.

【0009】特開昭56−98415 号公報: (製鋼) 出鋼時
にCaO を投入し、取鍋へAlを投入し、Arをバブリングす
ることで脱硫性を確保し、さらに必要があれば、Ca合金
を添加するが、Ca合金の添加は高価とならざるを得な
い。
Japanese Patent Application Laid-Open No. 56-98415: (Steel Making) At the time of tapping, CaO is charged, Al is charged into a ladle, and desulfurization is ensured by bubbling Ar. An alloy is added, but adding a Ca alloy has to be expensive.

【0010】特開昭64−75622 号公報: (製鋼) 取鍋中
にCa合金を添加することで、脱硫また介在物を球状化さ
せる方法が開示されているが、介在物の低減という観点
からは不十分である。 特開平4−301029号公報:出鋼直後でのCaO 吹込みによ
り、介在物の形態制御を図る。B系介在物は減少するも
のの、D系介在物は依然削減できない。
JP-A-64-75622: (Steel Making) A method of desulfurizing or spheroidizing inclusions by adding a Ca alloy to a ladle has been disclosed, but from the viewpoint of reducing inclusions. Is not enough. JP-A-4-301029: Form control of inclusions by CaO injection immediately after tapping. Although B-based inclusions decrease, D-based inclusions still cannot be reduced.

【0011】このような介在物の形態制御だけでは、耐
微小張出し割れ性を改善することはできない。従って、
孔拡げ性と耐微小張出し割れ性を同時に改善するには、
介在物量そのものを削減するように、製鋼段階からの総
合的な見直しを含む新たな熱延鋼板の製造方法を確立す
ることが求められている。
The morphological control of inclusions alone cannot improve the resistance to micro-extension cracking. Therefore,
To simultaneously improve hole expansion and micro overhang crack resistance,
In order to reduce the amount of inclusions themselves, it is required to establish a new method of manufacturing hot-rolled steel sheets, including a comprehensive review from the steelmaking stage.

【0012】本発明の目的は、介在物量そのものを削減
することで孔拡げ性と耐微小張出し割れ性に優れた熱延
鋼板を安価に効率よく製造できる方法を提供することで
ある。
An object of the present invention is to provide a method capable of inexpensively and efficiently producing a hot-rolled steel sheet having excellent hole expandability and micro-extension crack resistance by reducing the amount of inclusions.

【0013】ここに、本発明における「孔拡げ性」と
は、鋼板を直径12mmに打抜いた後、60°円錐ポンチで打
抜孔を押し拡げ、孔周縁に発生したクラックが板厚を貫
通した時点で止めた時の孔径の変化率として定義され、
これが70%以上のものを得ることが目標である。
[0013] Here, the "hole spreading property" in the present invention means that after punching a steel plate to a diameter of 12 mm, the punching hole is pushed and expanded with a 60 ° conical punch, and cracks generated on the periphery of the hole penetrate the plate thickness. Defined as the rate of change of pore size when stopped at the time,
The goal is to get more than 70% of this.

【0014】また、「耐微小張出し割れ性」とは、10R
球頭ポンチによる張出し成形を行ったときの張出し成形
加工部に局部的凹み (鋼板表面のキレツ) がみられるか
否かをもって定義され、難加工用途としてはこれを100
個成形して凹み発生が2以下の場合を合格とし、ホィー
ルディスクのナット座のような超難加工用途としては、
これを200 個成形し凹み発生が3個以下の場合を合格と
する。
[0014] The "micro-extension cracking resistance" refers to 10R
It is defined by whether or not there is a local dent (scratch on the steel sheet surface) in the bulging part when bulging with a ball-head punch is performed.
If the dent occurrence is 2 or less after forming individually, it is considered as acceptable, and for ultra-hard machining applications such as wheel disc nut seats,
200 pieces were molded, and the case where the number of dents was 3 or less was determined to be acceptable.

【0015】[0015]

【課題を解決するための手段】本発明者らは、上述の目
的達成のために種々検討を重ね、以下のような知見を得
た。
Means for Solving the Problems The present inventors have conducted various studies to achieve the above-mentioned object, and have obtained the following findings.

【0016】1)出鋼時に CaO+Al2O3 系フラックスを投
入することにより、高い脱硫能が出鋼段階で実現するた
め、Arバブリングの強攪拌のみで脱硫が可能となる。 2)従来は、介在物対策としてA系介在物、つまり硫化物
(MnS 、FeS)のみを制御するだけであったためAl2O3
残存することがあったが、それらと同時にB系 (Al
2O3)、D系(CaO) 介在物の低減をも両立させることで、
孔拡げ性と耐微小張出し割れ性を同時に改善することが
できる。
1) By introducing a CaO + Al 2 O 3 system flux at the time of tapping, a high desulfurization ability is realized at the tapping stage, so desulfurization can be achieved only by vigorous stirring of Ar bubbling. 2) Conventionally, A-based inclusions, that is, sulfide
(MnS, FeS) was only controlled, so Al 2 O 3 sometimes remained.
2 O 3 ), D-type (CaO)
The hole expandability and the resistance to micro-extension cracking can be simultaneously improved.

【0017】3)低融点フラックスとして、 CaO+Al2O3
系フラックスを用いるとともに、それに引き続く取鍋中
ではArのみを吹込み、その量を最適化したことにより、
A系、B系、D系介在物の低減を図ることができる。 4)さらに、ホィールディスク用途としては、Si量が高い
場合、外観に問題が発生しやすいため、脱Si処理を組み
合わせることがより効果的である。 5)低Sかつ、低Siを同時に達成できる製鋼方法を確立す
ることで、安定的にホィールディスクを製造する方法が
実現できる。
3) As the low melting point flux, CaO + Al 2 O 3
By using a system flux and injecting only Ar into the ladle following it and optimizing its amount,
A system, B system, and D system inclusions can be reduced. 4) Furthermore, for wheel disc applications, when the amount of Si is high, problems in appearance are likely to occur, so it is more effective to combine the removal of Si. 5) By establishing a steelmaking method that can simultaneously achieve low S and low Si, a method for stably manufacturing wheel disks can be realized.

【0018】[0018]

【課題を解決するための手段】本発明者らは、孔拡げ性
と耐介在物割れ性の向上を図るべく、介在物の低減を狙
うと同時に、さらに必要に応じて鋼板表面の美麗さを確
保すべく (縞状スケールを抑制すべく) 低Si量に抑えた
製鋼方法で製造したスラブを、孔拡げ性、伸びに最適な
熱延条件で巻き取ることを特徴としたものであり、その
要旨とするところは次の通りである。
Means for Solving the Problems The present inventors aim to reduce inclusions in order to improve hole expandability and crack resistance to inclusions, and at the same time, to improve the beauty of the steel sheet surface if necessary. In order to secure (suppress the stripe scale), slabs manufactured using a steelmaking method with a low Si content are wound up under hot rolling conditions that are optimal for hole expandability and elongation. The summary is as follows.

【0019】(1) 転炉出鋼時に、CaO をベースとし、Al
2O3 、CaF2、SiO2のうちの少なくとも1種を含む低融点
フラックスと、AlとCaCO3 をベースとするスラグ改質材
を溶湯中に投入し、かつ取鍋精錬時に不活性ガスを吹込
むことにより、化学組成が C:0.03〜0.20wt%、Si:2.0 wt%以下、Mn:0.3 〜2.
0 wt%、S:0.002 wt%以下、残部Feおよび不可避的不
純物からなる溶鋼を溶製する工程と、得られた溶鋼を連
続鋳造によりスラブとする工程と、 前記スラブを仕上温度: 800〜950 ℃、巻取温度: 400
〜550 ℃の条件で熱間圧延する工程と、を包含すること
を特徴とする、孔拡げ性と耐微小張出し割れ性に優れる
熱延鋼板の製造方法。
(1) At the time of tapping the converter, it is based on CaO and Al
2 O 3 , CaF 2 , a low melting point flux containing at least one of SiO 2 and a slag modifier based on Al and CaCO 3 are charged into the molten metal, and an inert gas is introduced during ladle refining. By blowing, the chemical composition is as follows: C: 0.03 to 0.20 wt%, Si: 2.0 wt% or less, Mn: 0.3 to 2.
0 wt%, S: 0.002 wt% or less, a step of smelting molten steel consisting of a balance of Fe and unavoidable impurities, a step of continuously casting the obtained molten steel into a slab, and a finishing temperature of the slab: 800 to 950. ℃, winding temperature: 400
A process of hot rolling at a temperature of up to 550 ° C., comprising the steps of:

【0020】(2) 転炉出鋼時に塩基度8以上の媒溶剤を
投入した後、上記(1) を繰り返し、取鍋精錬時に吹き込
む不活性ガスの流量を溶鋼 250トン当たり10〜60 Nm3
(0.04〜0.24Nm3/Ton)に規制することで溶鋼の化学組成
のSi量を0.2 %以下としたことを特徴とする、孔拡げ性
と耐微小張出し割れ性に優れる熱延鋼板の製造方法。
(2) After a medium solvent having a basicity of 8 or more is charged at the time of baking out of the converter, the above (1) is repeated, and the flow rate of the inert gas blown during ladle refining is adjusted to 10 to 60 Nm 3 per 250 tons of molten steel.
(0.04 to 0.24Nm 3 / Ton), a method for producing a hot-rolled steel sheet having excellent hole expandability and resistance to micro overhang cracking, characterized in that the amount of Si in the chemical composition of molten steel is reduced to 0.2% or less by regulating it. .

【0021】(3) 前記溶製した鋼が、Cr:1.0 wt%以
下、Ti:0.1 wt%以下、Nb:0.1 wt%以下の1種または
2種以上の元素をさらに含有することを特徴とする、上
記(1) または(2) の熱延鋼板の製造方法。
(3) The smelted steel further contains one or more elements of Cr: 1.0 wt% or less, Ti: 0.1 wt% or less, and Nb: 0.1 wt% or less. The method for producing a hot-rolled steel sheet according to the above (1) or (2).

【0022】(4) 前記溶製した鋼が、P:0.1 wt%以
下、Cu:0.5 wt%以下、Ni:0.5 wt%以下の1種または
2種以上の元素をさらに含有することを特徴とする、上
記(1) ないし(3) のいずれかに記載の熱延鋼板の製造方
法。
(4) The smelted steel further contains one or more elements of P: 0.1 wt% or less, Cu: 0.5 wt% or less, and Ni: 0.5 wt% or less. The method for producing a hot-rolled steel sheet according to any one of the above (1) to (3).

【0023】[0023]

【作用】次に、本発明における各工程の作用を具体的に
説明する。本発明は、上述のように製鋼工程、連続鋳造
工程、そして熱間圧延工程から成る。
Next, the operation of each step in the present invention will be specifically described. The present invention comprises a steel making process, a continuous casting process, and a hot rolling process as described above.

【0024】製鋼工程 転炉出鋼中に、改質フラックスとスラグ改質剤とを溶湯
に投入し、取鍋内溶鋼には不活性ガスを吹込む。本発明
において用いる改質フラックスは、取鍋内でのスラグを
低融点、かつ低粘度の方向へスラグ組成に変えるためと
同時に脱硫作用を発揮させるためであり、そのような目
的を達成できれば、制限はないが、本発明ではCaO をベ
ースにしてAl2O3 、CaF2、SiO2のうち少なくとも1種を
含むもの、好ましくは、CaO +Al2O3 、CaO +CaF2+Al
2O3 から成る群から選んだ少なくとも1種である。
Steelmaking Step During the tapping of the converter, the reforming flux and the slag modifier are charged into the molten metal, and an inert gas is blown into the molten steel in the ladle. The reforming flux used in the present invention is to change the slag in the ladle into a low melting point and a slag composition in the direction of low viscosity and at the same time to exert a desulfurizing action. Although there is no, the present invention is based on the CaO Al 2 O 3, those containing CaF 2, at least one of SiO 2, preferably, CaO + Al 2 O 3, CaO + CaF 2 + Al
At least one member selected from the group consisting of 2 O 3 .

【0025】また、スラグ改質剤は、スラグ中の低級酸
化物の低減のために添加するのであって、その限りでは
特定のものに制限されないが、例えば、AlとCaCO3 をベ
ースとするもので、好ましくは、Al+CaCO3 、Al+CaCO
3 +Al2O3 である。
The slag modifier is added to reduce lower oxides in the slag, and is not limited to a specific one as long as it is, for example, a slag modifier based on Al and CaCO 3. And preferably, Al + CaCO 3 , Al + CaCO
3 + Al 2 O 3 .

【0026】本発明の好適態様にあっては、転炉吹錬時
に塩基度8以上の高塩基度媒溶剤を投入することで、取
鍋流出時のスラグ組成中のSiO2を低減させる。そして、
出鋼時に CaO−Al2O3 系低融点フラックスとAlとCaCO3
をベースとするスラグ改質材を投入する。このことで、
高塩基度スラグ組成であって、脱S能を発揮できるだけ
のスラグ流動性を確保させる。
In a preferred embodiment of the present invention, a high basicity solvent having a basicity of 8 or more is introduced during the blowing of the converter to reduce SiO 2 in the slag composition at the time of ladle outflow. And
During tapping CaO-Al 2 O 3 based low-melting flux and Al and CaCO 3
Slag modifier based on With this,
It has a high basicity slag composition and ensures slag fluidity that can exhibit the de-S ability.

【0027】続いて取鍋では、Arガス量を好ましくは溶
鋼トン当たり0.04〜0.24 Nm3と制限することで脱SとSi
の再溶解のバランスを図る。また、このとき、取鍋処理
時間を短縮すること、およびスラグ粘性低下の相乗効果
で、介在物割れ原因となるD系介在物も同時に削減でき
る。
Subsequently, in the ladle, the S gas and the Si content are reduced by limiting the amount of Ar gas to preferably 0.04 to 0.24 Nm 3 per ton of molten steel.
Balance of re-dissolution. Also, at this time, the D-type inclusions that cause inclusion cracking can be reduced at the same time due to the synergistic effect of shortening the ladle processing time and lowering the slag viscosity.

【0028】すなわち、本発明の上述の好適態様にあっ
ては、スラグ組成を低SiO2側に移すことで、脱S性の向
上を図り、Siの再溶解を防止するだけでなく、D系介在
物量の混入を根本的に防止することに特徴がある。
That is, in the above-mentioned preferred embodiment of the present invention, the slag composition is shifted to the low SiO 2 side to improve the de-S property and prevent the re-dissolution of Si. It is characterized by fundamentally preventing the inclusion of inclusions.

【0029】ここで、高塩基度媒溶材は、例えば、CaO
+SiO2+CaF2の混合物あるいはCaO+SiO2+MgO を示
し、塩基度=CaO/SiO2:8〜40が望ましい。 不活性ガスはスラグ=溶鋼の界面脱硫反応を促進するた
め、Ar、Ne、Heの不活性ガスであればよい。経済性から
Arが好ましい。
Here, the high basicity solvent is, for example, CaO
+ SiO 2 + CaF 2 or CaO + SiO 2 + MgO, basicity = CaO / SiO 2 : 8 to 40 is desirable. The inert gas may be an inert gas of Ar, Ne, or He in order to promote an interfacial desulfurization reaction of slag = molten steel. Economical
Ar is preferred.

【0030】したがって、本発明によれば、CaO-Al2O3
系低融点フラックスおよびスラグ改質材を投入すること
で、取鍋内でのスラグの滓化促進を図り、続いて取鍋で
はArガスを吹込み、スラグ−溶鋼界面での脱硫を行うの
である。
Therefore, according to the present invention, CaO—Al 2 O 3
By introducing a low melting point flux and a slag modifier, the slag is promoted in the ladle, and then the Ar gas is blown into the ladle to perform desulfurization at the slag-molten steel interface. .

【0031】従来のCa処理では、取鍋内でのCaO 吹込み
により、溶鋼内部からの脱硫を図るものに対して、本発
明では、不活性ガス吹込みにより、スラグ=溶鋼界面だ
けの脱硫機構を利用するのである。
In the conventional Ca treatment, desulfurization from the inside of molten steel is attempted by blowing CaO in a ladle, whereas in the present invention, desulfurization mechanism only at the slag-molten steel interface is performed by blowing inert gas. Use

【0032】Ca処理では、出鋼後にCaO 系改質フラック
スを投入するため、湯面温度の大幅な低下を招き、これ
に伴い、CaO 吹込時の温度確保のため、RH脱ガス槽にて
O2吹込を実施するため、Al2O3 介在物 (B系、D系) が
多数発生してしまう。さらに取鍋でのCaO 吹込みでは、
球状化した硫化物は、スラグ=溶鋼界面までには、浮上
しきらず、鋼中に残存し、D系介在物となってしまう。
In the Ca treatment, the CaO-based reforming flux is introduced after tapping, which causes a significant drop in the temperature of the molten metal, and accordingly, in order to secure the temperature during CaO injection, the RH degassing tank is used.
Since O 2 blowing is performed, a large number of Al 2 O 3 inclusions (B-based and D-based) are generated. In addition, by blowing CaO on the ladle,
The spheroidized sulfide does not float up to the interface between the slag and the molten steel, remains in the steel, and becomes a D-based inclusion.

【0033】従って本発明では、湯面の温度降下が小さ
く、さらには、低融点かつ低粘度となるスラグ組成とす
べく、転炉出鋼時に低融点フラックスおよびスラグ改質
材を投入し、次いで不活性ガス吹込みのみによる界面脱
硫反応を実施するところに特徴がある。
Therefore, in the present invention, a low melting point flux and a slag modifying material are introduced during the tapping of the converter so as to obtain a slag composition having a small temperature drop of the molten metal surface and a low melting point and low viscosity. It is characterized in that an interfacial desulfurization reaction is performed only by blowing in an inert gas.

【0034】不活性ガスの吹き込みは、取鍋内溶鋼に浸
漬したインジェクションランスを用いて行っても、ある
いは適宜吹き込みプラグを設けて行ってもよい。例えば
Arガスなどの不活性ガスの吹き込み量は、特に制限はな
いが、溶鋼の流動をもたらす程度であればよく、スラグ
層と溶鋼との過度の混合が見られないよう、通常は溶鋼
1トン当たり0.02〜0.4 Nm3 程度であれば十分である。
The blowing of the inert gas may be performed by using an injection lance immersed in the molten steel in the ladle, or by providing a blowing plug as appropriate. For example
The amount of the inert gas such as Ar gas to be blown is not particularly limited, but may be sufficient to cause the flow of the molten steel. About 0.02 to 0.4 Nm 3 is sufficient.

【0035】しかしながら、本発明の好適態様にあって
は、Arガスなどの不活性ガスの吹き込み量は、溶鋼トン
当たり0.04〜0.24 Nm3とするのが好ましい。かくして本
発明により、ASTM-A法で規定するA系だけでなく、B
系、D系介在物の大幅削減が可能となり、耐微小張出し
割れ性が飛躍的に向上する。
However, in a preferred embodiment of the present invention, it is preferable that the blowing amount of the inert gas such as Ar gas is 0.04 to 0.24 Nm 3 per ton of molten steel. Thus, according to the present invention, not only the system A defined by the ASTM-A method but also the system B
And D-based inclusions can be greatly reduced, and the resistance to micro-extension cracking is dramatically improved.

【0036】連続鋳造工程 取鍋での脱硫によって目標とするSレベルおよびSiレベ
ルになった時点で、除滓を行い、次いで例えば慣用の連
続鋳造によってスラブを得る。
Continuous Casting Step When desulfurization in a ladle reaches the target S level and Si level, deslagging is performed, and then a slab is obtained by, for example, conventional continuous casting.

【0037】熱間圧延工程 孔拡げ性向上には、組織の均一化が必要であるが、ベイ
ナイト単相では延性不足、フェライト単相では強度不足
となる。また、残存介在物起因の割れ発生を防ぐべく、
結晶粒は大きい方が有効となる。
Hot Rolling Step In order to improve the hole expandability, it is necessary to homogenize the structure, but the bainite single phase has insufficient ductility and the ferrite single phase has insufficient strength. In addition, to prevent the occurrence of cracks due to residual inclusions,
Larger crystal grains are more effective.

【0038】そのため、熱間圧延の仕上温度はポリゴナ
ルフェライト粒の粗大化を図るべく、高温仕上げとし、
加工CCT 図においてフェライトノーズを横切り、ベイナ
イト域で完了するようにする。
For this reason, the finishing temperature of the hot rolling is set to a high temperature finish in order to increase the size of polygonal ferrite grains.
Cross the ferrite nose in the processed CCT diagram to complete in the bainite area.

【0039】仕上温度 フェライトのポリゴナル化、粗大化を図るため、800 ℃
以上が必要である。950 ℃より高いと通板性が低下し、
経済性の低下を招く。
Finishing temperature : 800 ° C. in order to make the ferrite polygonal and coarse.
The above is necessary. If it is higher than 950 ° C, the threadability will decrease,
This leads to reduced economics.

【0040】巻取温度 ベイナイト形成のため、加工連続冷却曲線図( 加工CCT
図) でのベイナイト域における巻取が必要のため、400
〜550 ℃となる。本発明において溶鋼の組成を限定する
理由は次の通りである。なお、本明細書において「%」
は特にことわりがないかぎり、「重量%」である。
For forming bainite at the winding temperature , a continuous cooling curve for processing (processing CCT)
(Fig.)
~ 550 ° C. The reasons for limiting the composition of molten steel in the present invention are as follows. In this specification, "%"
"%" Is "% by weight" unless otherwise specified.

【0041】C:Cは、フェライトの固溶強化、ベイナ
イトの生成のため、0.03%以上とする。0.20%より多い
と孔拡げ性が急激に劣化する。好ましくは、0.05〜0.15
%である。
C: C is set to 0.03% or more for solid solution strengthening of ferrite and formation of bainite. If it is more than 0.20%, the hole expandability is rapidly deteriorated. Preferably, 0.05 to 0.15
%.

【0042】Si:フェライトの固溶強化、パーライトの
生成抑制のために添加する。但し、2.0%より多いと、
溶接部の脆化を招く。好ましくは1.50%以下とする。本
発明の好適態様によれば、Siが0.2 %より多いと、鋼板
表面に縞状スケールが多発するため、外観の美麗さを保
つべく0.2 %以下とする。
Si: added for strengthening solid solution of ferrite and suppressing generation of pearlite. However, if it is more than 2.0%,
This leads to embrittlement of the weld. Preferably, it is set to 1.50% or less. According to a preferred embodiment of the present invention, if the content of Si is more than 0.2%, striped scale frequently occurs on the surface of the steel sheet, so that the content is set to 0.2% or less in order to maintain beautiful appearance.

【0043】Mn:低C化の強度補償のため、更にベイナ
イト生成のため、0.3 %以上は不可欠となる。しかし2.
0 %より多いと焼入性上昇で延性が劣化する。好ましく
は、0.70〜1.60%である。
Mn: 0.3% or more is indispensable for compensating the strength for lowering the C content and for generating bainite. But 2.
If it is more than 0%, ductility is deteriorated due to an increase in hardenability. Preferably, it is 0.70 to 1.60%.

【0044】S:介在物形成に大きく影響するので、0.
002 %以下とする。好ましくは、0.0015%以下、さらに
好ましくは0.0005%以下である。
S: Since it greatly affects the formation of inclusions,
002% or less. Preferably it is 0.0015% or less, more preferably 0.0005% or less.

【0045】本発明にあっては、さらに所望により、
(I) Cr :1.0 wt%以下、Ti:0.1 wt%以下、Nb:0.1
wt%以下の1種または2種以上、および/または (II)
P:0.1 wt%以下、Cu:0.5 wt%以下、Ni:0.5 wt%以
下の1種または2種以上を含有してもよい。
In the present invention, if desired,
(I) Cr: 1.0 wt% or less, Ti: 0.1 wt% or less, Nb: 0.1
one or more of wt% or less, and / or (II)
One or more of P: 0.1 wt% or less, Cu: 0.5 wt% or less, and Ni: 0.5 wt% or less may be contained.

【0046】Cr、Ti、Nb:これらは、いずれも高強度化
に有効な元素であって、所望により少なくとも1種含有
される。Crは、590 N/mm2 以上の高強度化に有効な焼入
れ硬化元素である。1.0 %よりも多いと延性劣化とな
る。
Cr, Ti, Nb: These are all effective elements for increasing the strength, and may contain at least one element as desired. Cr is a quench hardening element effective for increasing the strength to 590 N / mm 2 or more. If it exceeds 1.0%, ductility is deteriorated.

【0047】Tiは、540 N/mm2 以上の高強度化に有効な
析出強化元素である。しかし、0.2%よりも多いと、YR
が高くなり過ぎ、形状凍結性低下を招く。Nbは、Tiと同
じく、540 N/mm2 以上の高強度化に有効な析出強化元素
であるが、0.1 %よりも多いと、YRが高くなり過ぎ、Ti
と同じく形状凍結性が低下する。
Ti is a precipitation strengthening element effective for increasing the strength to 540 N / mm 2 or more. However, if it exceeds 0.2%, YR
Becomes too high, and the shape freezing property is reduced. Nb, like Ti, is a precipitation strengthening element effective for increasing the strength to 540 N / mm 2 or more, but if it exceeds 0.1%, the YR becomes too high and Ti
Similarly, the shape freezing property is reduced.

【0048】P、Cu、Ni:これらの元素も耐食性の改善
を図る場合に少なくとも1種添加される。PとCuの同時
添加は固溶強化と、母材耐食性の改善に有効である。Ni
は、Cuチェッキング防止のため、Cuと同量添加するのが
好ましい。しかし、P:0.1 %より多いと粒界脆化を招
き、Cu:0.5 %、Ni:0.5 %より多いとリサイクル性、
経済性が低下する。好ましくはP、Cuを同時添加する
か、あるいはP、Cu、Niを同時添加する。次に、実施例
によって本発明の作用効果をさらに具体的に説明する。
P, Cu, Ni: At least one of these elements is also added to improve corrosion resistance. Simultaneous addition of P and Cu is effective for solid solution strengthening and improvement of base metal corrosion resistance. Ni
Is preferably added in the same amount as Cu to prevent Cu checking. However, if the content of P is more than 0.1%, grain boundary embrittlement is caused. If the content of Cu is more than 0.5% and the content of Ni is more than 0.5%, recyclability and
Economic efficiency decreases. Preferably, P and Cu are added simultaneously, or P, Cu and Ni are added simultaneously. Next, the operation and effect of the present invention will be described more specifically with reference to examples.

【0049】[0049]

【実施例】 (実施例1)表1に示す鋼組成を有する溶鋼を転炉で溶製
し、下記の操作にしたがって転炉出鋼時に改質フラック
スとスラグ改質材とを溶鋼に投入し、取鍋脱硫を行っ
た。
EXAMPLES (Example 1) Molten steel having a steel composition shown in Table 1 was smelted in a converter, and a modified flux and a slag modifier were introduced into the molten steel at the time of exiting the converter according to the following operation. Ladle desulfurization was performed.

【0050】本発明例では、250 ton 転炉の出鋼時に、
取鍋溶鋼中にフラックスとして表3に示す低融点フラッ
クスを1.0 ton 投入した後で、直ちに表3に示す自己分
解性フラックスを300 kg投入した。
In the example of the present invention, at the time of tapping of a 250 ton converter,
After 1.0 ton of the low melting point flux shown in Table 3 was introduced into the ladle molten steel as a flux, 300 kg of the self-decomposable flux shown in Table 3 was immediately introduced.

【0051】続いて吐出孔が取鍋底近傍までくるよう
に、インジェクションランスを取鍋溶鋼中に浸漬させ、
アルゴンガスを15分間、4Nm3/min だけ吹込んだ。次い
で、このようにして溶製した溶鋼を連続鋳造してスラブ
を得た。表1の鋼種A1〜A14 参照。
Subsequently, the injection lance was immersed in the molten steel so that the discharge hole was located near the bottom of the ladle.
Argon gas was blown at 4 Nm 3 / min for 15 minutes. Next, the molten steel thus produced was continuously cast to obtain a slab. See steel types A1 to A14 in Table 1.

【0052】表1の比較例B1では、250 ton 転炉の出鋼
後に、取鍋溶鋼中に改質フラックス(CaO)を1.0 ton 投
入し、直ちにスラグ改質材(Al 50%+Al2O3 50%) を50
0 kg投入した。
In Comparative Example B1 of Table 1, after tapping from the 250 ton converter, 1.0 ton of the modified flux (CaO) was introduced into the ladle molten steel, and immediately the slag modifier (Al 50% + Al 2 O 3 50%) to 50
0 kg was introduced.

【0053】続いて酸素ガスをインジェクションにより
10分間 2.5 Nm3/minだけ吹込み、さらにインジェクショ
ンランスから脱硫剤 (CaO パウダー) を750 kg吹込んだ
後、溶鋼を連続鋳造してスラブを得た。
Subsequently, oxygen gas is injected by injection.
After blowing at 2.5 Nm 3 / min for 10 minutes and further 750 kg of a desulfurizing agent (CaO powder) from an injection lance, molten steel was continuously cast to obtain a slab.

【0054】比較例B2では、250 ton 転炉の出鋼中に、
取鍋溶鋼中にインジェクションランスを浸漬させ、スラ
グ改質材(Al 50%+Al2O3 50%) を450 kg吹込み、引き
続き脱硫剤 (CaO 80%+CaF2 20 %) を500 kg吹込ん
だ。そして溶鋼を連続鋳造してスラブを得た。
In Comparative Example B2, during tapping of a 250 ton converter,
The injection lance was immersed in the ladle molten steel, and 450 kg of the slag modifier (Al 50% + Al 2 O 3 50%) was injected, followed by 500 kg of the desulfurizing agent (CaO 80% + CaF 2 20%). . And slab was obtained by continuously casting molten steel.

【0055】比較例B3では、250 ton 転炉の出鋼後に、
取鍋溶鋼中にスラグ改質材(Al 50%+Al2O3 50%) を40
0 kg投入した。そしてインジェクションランスを取鍋溶
鋼中に浸漬させ、アルゴンガスを10分間4Nm3/min だけ
吹込み、溶鋼を連続鋳造してスラブを得た。
In Comparative Example B3, after tapping from a 250 ton converter,
Add slag modifier (50% Al + 50% Al 2 O 3 ) to molten steel in ladle
0 kg was introduced. Then, the injection lance was immersed in the ladle molten steel, and argon gas was blown at 4 Nm 3 / min for 10 minutes to continuously cast the molten steel to obtain a slab.

【0056】このようにして各製鋼連続鋳造工程にて製
造したスラブを加熱温度1270℃まで加熱し、同じく表1
に示す各仕上温度、巻取温度の熱間圧延条件で、板厚2.
6 mmまで熱間圧延を行った。そして各コイルは酸洗後、
切板ラインで切板とした。引張試験はJIS 5号試験片を
用いた。
The slabs thus produced in each steelmaking continuous casting process were heated to a heating temperature of 1270 ° C.
Under the hot rolling conditions of each finishing temperature and winding temperature shown in
Hot rolling was performed to 6 mm. And after pickling each coil,
The plate was cut on the cutting line. A JIS No. 5 test piece was used for the tensile test.

【0057】孔拡げ試験は鋼板を直径12mmで打抜いた
後、60°円錐ポンチで孔を押し拡げ、クラックが板厚を
貫通した時点で止め、打抜孔 (直径12mm) との変化率で
孔拡げ性を表した。B系およびD系介在物量は、ASTM-A
法により測定し、ASTM法規定によりHeavy,Thinの各シリ
ーズにおいて3.0 ランク以下の介在物個数の総和で表し
た。
In the hole expansion test, after a steel plate was punched with a diameter of 12 mm, the hole was pushed and expanded with a 60 ° conical punch, stopped when the crack penetrated the plate thickness, and changed at a rate of change from the punched hole (diameter 12 mm). Expressed expandability. The content of B type and D type inclusions is ASTM-A
It was measured by the method and expressed by the sum of the number of inclusions of 3.0 ranks or less in each of the Heavy and Thin series according to the ASTM method regulations.

【0058】微小張出し割れ試験は、10R球頭ポンチに
よる張出し成形を行い、変形部の凹部の個数を測定し、
試験片100 個中の凹部個数の総和が2以下の場合を耐微
小張出し割れ性が良とし、3以上の場合を不良とした。
In the micro-extension cracking test, extension molding was performed using a 10R ball-head punch, and the number of concave portions in the deformed portion was measured.
The case where the sum of the number of concave portions in 100 test pieces was 2 or less was regarded as good in micro-extension crack resistance, and the case where the total was 3 or more was defective.

【0059】[0059]

【表1】 [Table 1]

【0060】[0060]

【表2】 [Table 2]

【0061】[0061]

【表3】 [Table 3]

【0062】本発明により、引張強さ440 N/mm2 以上を
有し、孔拡げ性、耐微小張出し割れ性に優れた熱延鋼板
が得られる。比較例1では、孔拡げ性を確保すべく、製
鋼工程でCa処理を行ったが、B系介在物が多数鋼中に存
在するため、耐微小張出し割れ性が損なわれた。
According to the present invention, a hot-rolled steel sheet having a tensile strength of 440 N / mm 2 or more and having excellent hole expandability and micro-extension cracking resistance can be obtained. In Comparative Example 1, although the Ca treatment was performed in the steelmaking process in order to secure the hole expandability, the micro-extension crack resistance was impaired because a large number of B-based inclusions were present in the steel.

【0063】比較例2では、製鋼工程で脱硫剤吹込みし
た結果、D系介在物が多数発生し、耐微小張出し割れ性
が損なわれた。比較例3〜5では熱延条件が外れたた
め、孔拡げ性が低下した。比較例6では、C量が過多の
ため、孔拡げ性 (および伸び) が低下した。比較例7で
は、製鋼工程で脱硫処理を行っておらず、さらに介在物
削減処理を十分実施していないため、孔拡げ性および耐
微小張出し割れ性とも損なわれた。
In Comparative Example 2, as a result of blowing the desulfurizing agent in the steel making process, a large number of D-based inclusions were generated, and the resistance to micro overhang cracking was impaired. In Comparative Examples 3 to 5, the hot rolling conditions were removed, so that the hole expandability was reduced. In Comparative Example 6, the hole expandability (and elongation) was reduced due to an excessive amount of C. In Comparative Example 7, since the desulfurization treatment was not performed in the steel making process and the inclusion reduction treatment was not sufficiently performed, the hole expanding property and the resistance to micro-overhang cracking were also impaired.

【0064】(実施例2)本例では、下記の操作にしたが
って転炉出鋼時に低融点フラックスとスラグ改質材とを
溶鋼に投入し、取鍋脱硫を行った。
Example 2 In this example, a low melting point flux and a slag modifier were charged into molten steel at the time of converter tapping according to the following operation, and ladle desulfurization was performed.

【0065】本発明例では、250 ton 転炉の出鋼時に、
表4に示す高塩基度媒溶剤を投入した後、出鋼時に低融
点フラックスを1.0 ton 、引続きスラグ改質材を300 kg
投入した。
In the example of the present invention, at the time of tapping of the 250 ton converter,
After adding the high basicity solvent shown in Table 4, the low melting point flux was 1.0 ton and the slag modifier was 300 kg at the time of tapping.
I put it in.

【0066】続いて吐出孔が取鍋底近傍までくるよう
に、インジェクションランスを取鍋溶鋼中に浸漬させ、
アルゴンガスをそれぞれ例No.1〜14に示す量だけ吹込
み、溶鋼を連続鋳造してスラブを得た。
Subsequently, the injection lance was immersed in the molten steel so that the discharge hole reached the vicinity of the bottom of the ladle.
Argon gas was blown in the amounts shown in Examples Nos. 1 to 14, and molten steel was continuously cast to obtain slabs.

【0067】比較例B1では、250 ton 転炉の吹錬時に表
4に示す媒溶剤を、また出鋼後に取鍋中に低融点フラッ
クスを1.0 ton 投入し、直ちにスラグ改質材を500 kg投
入した。
In Comparative Example B1, the solvent shown in Table 4 was added during blowing of a 250 ton converter and 1.0 ton of a low melting point flux was introduced into a ladle after tapping, and 500 kg of a slag modifier was immediately added. did.

【0068】続いて酸素ガスをインジェクションにより
50 Nm3だけ吹込み、さらにインジェクションランスから
脱硫剤 (CaO パウダー) を750 kg吹込んだ後、溶鋼を連
続鋳造してスラブを得た。
Subsequently, oxygen gas is injected by injection.
After injecting only 50 Nm 3 and further injecting 750 kg of desulfurizing agent (CaO powder) from the injection lance, molten steel was continuously cast to obtain a slab.

【0069】比較例B2では、表4の低塩基度媒溶剤を本
発明例における高塩基度媒溶剤の代わりに投入した。比
較例B3、B4は、Arガス吹込量を4および72 Nm3にした。
In Comparative Example B2, the low basicity solvent shown in Table 4 was used instead of the high basicity solvent in the present invention. In Comparative Examples B3 and B4, the Ar gas blowing rates were 4 and 72 Nm 3 .

【0070】比較例B5は、250 ton 転炉の吹付時に表5
の媒溶剤を、さらに、出鋼後に、取鍋溶鋼中にスラグ改
質材を400 kg投入した。そしてインジェクションランス
を取鍋溶鋼中に浸漬させ、アルゴンガスを4Nm3だけ吹込
み、溶鋼を連続鋳造してスラブを得た。
Comparative Example B5 shows the results of Table 5 when spraying with a 250 ton converter.
After the tapping, 400 kg of a slag modifier was introduced into the ladle molten steel. Then, the injection lance was immersed in the ladle molten steel, and argon gas was blown in by 4 Nm 3 to continuously cast the molten steel to obtain a slab.

【0071】このようにして各製鋼連続鋳造工程にて製
造したスラブを加熱温度1270℃まで加熱し、同じく表5
に示す各仕上温度、巻取温度の熱間圧延条件で、板厚2.
6 mmまで熱間圧延を行った。そして各コイルは酸洗後、
切板ラインで切板とした。
The slab produced in each steelmaking continuous casting process was heated to a heating temperature of 1270 ° C.
Under the hot rolling conditions of each finishing temperature and winding temperature shown in
Hot rolling was performed to 6 mm. And after pickling each coil,
The plate was cut on the cutting line.

【0072】引張試験はJIS 5号試験片を用いた。孔拡
げ試験は鋼板を直径12mmで打抜いた後、60°円錐ポンチ
で孔を押し拡げ、クラックが板厚を貫通した時点で止
め、打抜孔 (直径12mm) との変化率で孔拡げ性を表し
た。
The tensile test used a JIS No. 5 test piece. In the hole expansion test, after punching a steel plate with a diameter of 12 mm, the hole is pushed and expanded with a 60 ° conical punch, stopped when the crack penetrates the plate thickness, and the hole expansion property is determined by the rate of change from the punched hole (diameter 12 mm). expressed.

【0073】B系およびD系介在物量は、ASTM-A法によ
り測定し、ASTM法規定によりHeavy,Thinの各シリーズに
おいて3.0 ランク以下の介在物個数の総和で表した。微
小張出し割れ試験は、10R球頭ポンチによる張出し成形
を行い、変形部の凹部の個数を測定し、試験片200 個中
の凹部個数の総和が3以下の場合を耐微小張出し割れ性
が良とし、4以上の場合を不良とした。
The amounts of B- and D-system inclusions were measured by the ASTM-A method, and represented by the sum of the number of inclusions of 3.0 ranks or less in each of the Heavy and Thin series according to the ASTM method. The micro overhang cracking test is performed by overhanging with a 10R ball-head punch, and the number of recesses in the deformed portion is measured. If the total number of recesses in 200 test pieces is 3 or less, the micro overhang cracking resistance is considered to be good. , 4 or more was regarded as defective.

【0074】表面性状は、酸洗後の鋼板表面に、コイル
トップ/10mにて幅2mm×長さ5mm以上の縞状スケール
が10ヶ以上発生した場合を不良、9ヶ以下の場合を良と
した。これらの試験結果は表6にまとめて示す。
[0074] The surface properties were determined as defective if the stripped scale having a width of 2 mm x length of 5 mm or more at the coil top / 10 m or more was generated on the steel sheet surface after pickling, and good if the number was 9 or less. did. The results of these tests are summarized in Table 6.

【0075】[0075]

【表4】 [Table 4]

【0076】[0076]

【表5】 [Table 5]

【0077】[0077]

【表6】 [Table 6]

【0078】本発明により、引張強さ440 N/mm2 以上を
有し、孔拡げ性、耐微小張出し割れ性、さらに表面性状
にに優れた熱延鋼板が得られる。比較例No.15 では、孔
拡げ性を確保すべく、製鋼工程でCaO 処理を行ったが、
B系介在物が多数鋼中に存在するため、耐微小張出し割
れ性が損なわれた。
According to the present invention, a hot-rolled steel sheet having a tensile strength of 440 N / mm 2 or more and having excellent hole expanding properties, micro-extension cracking resistance, and excellent surface properties can be obtained. In Comparative Example No. 15, the CaO treatment was performed in the steelmaking process to ensure the hole expandability.
Since a large number of B-based inclusions were present in the steel, the resistance to micro overhang cracking was impaired.

【0079】比較例No.16 では、低塩基度媒溶剤とし
て、高SiO2系を用いたので、D系介在物が多数発生し、
耐微小張出し割れ性が損なわれた。比較例No.17 ではAr
吹込量が少ないため、S量が高く、孔拡げ性が損なわれ
た。
In Comparative Example No. 16, since a high SiO 2 system was used as the low basicity solvent, a large number of D-based inclusions were generated.
The resistance to micro overhang cracking was impaired. In Comparative Example No. 17, Ar
Since the blowing amount was small, the S amount was high, and the hole expandability was impaired.

【0080】比較例No.18 では、Ar吹込量が多いため、
Si量が高く表面性状が損なわれた。比較例No.19 〜21で
は、熱間圧延条件が本発明の範囲を外れたため、孔拡げ
性が低下した。
In Comparative Example No. 18, since the Ar blowing amount was large,
The Si content was high and the surface properties were impaired. In Comparative Examples Nos. 19 to 21, the hot rolling conditions were out of the range of the present invention, so that the hole expandability was reduced.

【0081】比較例No.22 では、C量が過多のため、孔
拡げ性、伸びが低下した。比較例No.23 では、製鋼工程
で脱硫処理を行っておらず、さらに介在物削減処理を十
分実施していないため、孔拡げ性および耐微小張出し割
れ性とも損なわれた。
In Comparative Example No. 22, since the amount of carbon was excessive, the hole expandability and elongation were reduced. In Comparative Example No. 23, since the desulfurization treatment was not performed in the steel making process and the inclusion reduction treatment was not sufficiently performed, the hole expansion property and the resistance to micro-overhang cracking were also impaired.

【0082】[0082]

【発明の効果】以上説明したように、本発明によれば、
取鍋脱硫を行うだけで、脱硫はもちろん介在物の除去も
効果的に行われ、その手段の簡便さから本発明の実用上
の意義は大きい。
As described above, according to the present invention,
By simply performing ladle desulfurization, desulfurization as well as removal of inclusions is effectively performed, and the practical significance of the present invention is significant because of the simplicity of the means.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 野村 茂樹 茨城県鹿島郡鹿島町大字光3番地 住友 金属工業株式会社鹿島製鉄所内 (72)発明者 中居 修二 茨城県鹿島郡鹿島町大字光3番地 住友 金属工業株式会社鹿島製鉄所内 (72)発明者 坂 健司 茨城県鹿島郡鹿島町大字光3番地 住友 金属工業株式会社鹿島製鉄所内 (56)参考文献 特開 平5−9572(JP,A) 特開 平4−276016(JP,A) 特許2976852(JP,B2) (58)調査した分野(Int.Cl.7,DB名) C21D 8/00,8/02 C21C 5/36,5/46 C21C 7/064,7/076 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Shigeki Nomura 3, Kashima-cho, Kashima-gun, Ibaraki Pref., Sumitomo Metal Industries, Ltd. Inside the Kashima Steel Works of Metal Industry Co., Ltd. (72) Kenji Saka, 3rd light section, Kashima-cho, Kashima-gun, Ibaraki Prefecture Sumitomo Metal Industries Co., Ltd. Kashima Works (56) References JP 5-9572 (JP, A) JP Hei 4-276016 (JP, A) Patent 2976852 (JP, B2) (58) Fields investigated (Int. Cl. 7 , DB name) C21D 8/00, 8/02 C21C 5/36, 5/46 C21C7 / 064,7 / 076

Claims (4)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 転炉出鋼時に、CaO をベースとし、Al2O
3 、CaF2、SiO2のうちの少なくとも1種を含む低融点フ
ラックスと、AlとCaCO3 をベースとするスラグ改質材を
溶湯中に投入し、かつ取鍋精錬時に不活性ガスを吹込む
ことにより、化学組成が C:0.03〜0.20wt%、Si:2.0 wt%以下、 Mn:0.3 〜2.0 wt%、S:0.002 wt%以下、 残部Feおよび不可避的不純物 からなる溶鋼を溶製する工程と、 得られた溶鋼を連続鋳造によりスラブとする工程と、 前記スラブを仕上温度: 800〜950 ℃、巻取温度: 400
〜550 ℃の条件で熱間圧延する工程と、 を包含することを特徴とする、孔拡げ性と耐微小張出し
割れ性に優れる熱延鋼板の製造方法。
(1) At the time of converter tapping, based on CaO, Al 2 O
3. A low melting point flux containing at least one of CaF 2 and SiO 2 and a slag modifier based on Al and CaCO 3 are charged into the molten metal, and an inert gas is blown during ladle refining. Thus, a process of melting molten steel having a chemical composition of C: 0.03 to 0.20 wt%, Si: 2.0 wt% or less, Mn: 0.3 to 2.0 wt%, S: 0.002 wt% or less, with the balance being Fe and unavoidable impurities. Forming a slab by continuous casting of the obtained molten steel; finishing temperature of the slab: 800 to 950 ° C .; winding temperature: 400
A method of hot rolling at a temperature of up to 550 ° C., comprising the steps of:
【請求項2】 転炉出鋼時に塩基度8以上の高塩基度媒
溶剤を投入した後、CaO をベースとし、Al2O3 、CaF2
SiO2のうちの少なくとも1種を含む低融点フラックス
と、AlとCaCO3 をベースとするスラグ改質材を溶湯中に
投入し、かつ取鍋精錬時に不活性ガスを溶鋼250 トン当
たり10〜60 Nm3 (0.04〜0.24Nm3/Ton)吹込むことによ
り、化学組成が C:0.03〜0.20wt%、Si:0.2 wt%以下、 Mn:0.3 〜2.0 wt%、S:0.002 wt%以下、 残部Feおよび不可避的不純物 からなる溶鋼を溶製する工程と、 得られた溶鋼を連続鋳造によりスラブとする工程と、 前記スラブを仕上温度: 800〜950 ℃、巻取温度: 400
〜550 ℃の条件で熱間圧延する工程と、 を包含することを特徴とする、孔拡げ性と耐微小張出し
割れ性に優れる熱延鋼板の製造方法。
2. A high basicity solvent having a basicity of 8 or more is supplied during the tapping of the converter, and then, based on CaO, Al 2 O 3 , CaF 2 ,
And a low melting flux containing at least one of SiO 2, Al and the CaCO 3 was charged with slag modifier based on the melt, and the inert gas the molten steel 250 tons per during ladle refining 10-60 Nm 3 by writing (0.04~0.24Nm 3 / Ton) spray, chemical composition C: 0.03~0.20wt%, Si: 0.2 wt% or less, Mn: 0.3 ~2.0 wt%, S: 0.002 wt% or less, the balance A step of smelting molten steel composed of Fe and unavoidable impurities; a step of forming the slab by continuous casting of the obtained molten steel; a finishing temperature of the slab: 800 to 950 ° C .;
A method of hot rolling at a temperature of up to 550 ° C., comprising the steps of:
【請求項3】 前記溶製した鋼が、Cr:1.0 wt%以下、
Ti:0.1 wt%以下、Nb:0.1 wt%以下の1種または2種
以上の元素をさらに含有することを特徴とする、請求項
1または2記載の熱延鋼板の製造方法。
3. The molten steel according to claim 1, wherein Cr: 1.0 wt% or less;
The method for producing a hot-rolled steel sheet according to claim 1 or 2, further comprising one or more elements of Ti: 0.1 wt% or less and Nb: 0.1 wt% or less.
【請求項4】 前記溶製した鋼が、P:0.1 wt%以下、
Cu:0.5 wt%以下、Ni:0.5 wt%以下の1種または2種
以上の元素をさらに含有することを特徴とする、請求項
1ないし3のいずれかに記載の熱延鋼板の製造方法。
4. The method according to claim 1, wherein the melted steel has a P content of 0.1 wt% or less,
The method for producing a hot-rolled steel sheet according to any one of claims 1 to 3, further comprising one or more elements of Cu: 0.5 wt% or less and Ni: 0.5 wt% or less.
JP7008172A 1994-10-25 1995-01-23 Manufacturing method of hot rolled steel sheet with excellent hole spreadability Expired - Fee Related JP3027912B2 (en)

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JP26048694 1994-10-25
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KR100395099B1 (en) * 1996-12-19 2003-11-17 주식회사 포스코 Refining method of steel for pipes
CN1064085C (en) * 1998-07-16 2001-04-04 江苏江南铁合金厂 Agent for refining and heat-insulating of molten steel surface and its preparation process
UA76140C2 (en) * 2001-04-02 2006-07-17 Nucor Corp A method for ladle refining of steel
US7981224B2 (en) * 2003-12-18 2011-07-19 Nippon Steel Corporation Multi-phase steel sheet excellent in hole expandability and method of producing the same
WO2009149581A1 (en) * 2008-06-12 2009-12-17 鞍钢股份有限公司 Additive for preparing steel containning super-finely dispersed oxide, producing method and application of the same
CN103045792B (en) * 2013-01-08 2014-08-27 秦皇岛首秦金属材料有限公司 Smelting technology of low-sulfur steel for thick plates during whole-course bottom blowing nitrogen production of converter
CN112522596B (en) * 2019-09-19 2022-10-21 宝山钢铁股份有限公司 High-strength high-hole-expansion steel based on scrap steel and production method thereof
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