JP2920094B2 - Insulated double-walled container made of synthetic resin and method of manufacturing the same - Google Patents

Insulated double-walled container made of synthetic resin and method of manufacturing the same

Info

Publication number
JP2920094B2
JP2920094B2 JP7260550A JP26055095A JP2920094B2 JP 2920094 B2 JP2920094 B2 JP 2920094B2 JP 7260550 A JP7260550 A JP 7260550A JP 26055095 A JP26055095 A JP 26055095A JP 2920094 B2 JP2920094 B2 JP 2920094B2
Authority
JP
Japan
Prior art keywords
container
synthetic resin
resin
double
space
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP7260550A
Other languages
Japanese (ja)
Other versions
JPH0998891A (en
Inventor
雅司 山田
泰彦 小宮
孝文 藤井
篤彦 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Sanso Corp
Original Assignee
Nippon Sanso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Sanso Corp filed Critical Nippon Sanso Corp
Priority to JP7260550A priority Critical patent/JP2920094B2/en
Priority to KR1019960038263A priority patent/KR100260956B1/en
Priority to EP19960114453 priority patent/EP0763483B1/en
Priority to US08/710,056 priority patent/US5904264A/en
Priority to DE1996613920 priority patent/DE69613920T2/en
Priority to CA 2185298 priority patent/CA2185298A1/en
Priority to CN96122043A priority patent/CN1158235A/en
Publication of JPH0998891A publication Critical patent/JPH0998891A/en
Priority to US08/931,186 priority patent/US6036801A/en
Application granted granted Critical
Publication of JP2920094B2 publication Critical patent/JP2920094B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Thermally Insulated Containers For Foods (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemically Coating (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、クーラーボック
ス、魔法瓶、保温弁当箱、保温食器などとして使用され
る合成樹脂製断熱二重壁容器およびその製造方法に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a synthetic resin insulated double-walled container used as a cooler box, a thermos bottle, an insulated lunch box, an insulated tableware and the like, and a method for producing the same.

【0002】[0002]

【従来の技術】従来から提案されている合成樹脂製断熱
二重壁容器の1つに、合成樹脂製の内容器と外容器で構
成された二重壁容器の空間層に空気より熱伝導率の小さ
いガスを封入したものがある。この合成樹脂製断熱二重
壁容器は、二重壁の空間層側の面にガスバリア性を高め
る目的で、メッキ膜による金属被膜が形成されている。
内外容器には、耐熱水性の樹脂として一般にポリカーボ
ネート樹脂が用いられているが、ポリカーボネート樹脂
で成形された内容器の外面や外容器の内面には直接メッ
キ膜を付着させることができないため、メッキ可能な樹
脂を含む塗料を塗布してメッキ膜を施していた。
2. Description of the Related Art One of the heat-insulating double-walled containers made of synthetic resin that has been proposed in the past is that the thermal conductivity of air in a space layer of a double-walled container composed of an inner container made of synthetic resin and an outer container is higher than that of air. There is a gas filled with a small gas. In this heat-insulating double-walled container made of synthetic resin, a metal coating of a plating film is formed on the surface of the double wall on the space layer side in order to enhance gas barrier properties.
Polycarbonate resin is generally used for the inner and outer containers as a hot water resistant resin, but plating is not possible because the plating film cannot be directly attached to the outer surface of the inner container or the inner surface of the outer container molded with polycarbonate resin. A coating containing a suitable resin was applied to form a plating film.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、ポリカ
ーボネート樹脂は有機溶剤、漂白剤、洗剤等に対する耐
薬品性が劣るためにメッキ膜を形成したい面に塗料を塗
布しても、塗料の溶剤によって成形品にクラック(ソル
ベントクラック)が発生する恐れがあり、クラックが発
生した場合は合成樹脂製断熱二重壁容器のガスバリア性
が損なわれる不都合が生じる。また、二重壁容器の空間
部に低熱伝導率ガスを封入する後工程においても、接着
剤を用いて封止板で封止をする際、接着剤に含まれる溶
剤によって封止部の近傍や封止板にクラックを発生する
恐れがある。さらに、実際の使用上においても、内容物
の食品や飲料水、漂白剤、各種洗剤等によってクラック
が発生することが十分考えられる。また、ポリカーボネ
ート樹脂は、樹脂自体のガスバリア性が良くないので、
ガスバリア性を付与するために高精度のメッキ膜を施す
必要があり、それに伴い製造コストが増加する不都合が
ある。
However, polycarbonate resin is inferior in chemical resistance to organic solvents, bleaching agents, detergents, and the like. Cracks (solvent cracks) may occur, and when the cracks occur, there arises a disadvantage that the gas barrier properties of the insulated double wall container made of synthetic resin are impaired. Also, in the subsequent step of sealing the low thermal conductivity gas into the space of the double-walled container, when sealing with a sealing plate using an adhesive, a solvent contained in the adhesive may be used in the vicinity of the sealing portion, Cracks may occur in the sealing plate. Further, even in actual use, it is sufficiently conceivable that cracks are generated by the contents of food, drinking water, bleach, various detergents and the like. In addition, since polycarbonate resin has poor gas barrier properties of the resin itself,
In order to impart gas barrier properties, it is necessary to apply a highly accurate plating film, and there is a disadvantage that the production cost increases accordingly.

【0004】本発明は、上記事情に鑑みてなされたもの
で、製造時に使用する溶剤や内容物等によるクラックの
発生を防止することができ、安価で耐久性に優れる合成
樹脂製断熱二重壁容器およびその製造方法を提供するも
のである。
The present invention has been made in view of the above circumstances, and is capable of preventing the occurrence of cracks due to a solvent or contents used during manufacturing, and is inexpensive and has excellent durability. A container and a method for producing the container are provided.

【0005】[0005]

【課題を解決するための手段】本発明の請求項1に係る
発明は、合成樹脂製の内容器と外容器とをそれぞれの口
部で連結して内容器を外容器内に空間を隔てて収容して
二重壁容器となし、前記内容器と外容器とで形成した空
間部を断熱層としてなる合成樹脂製の断熱二重壁容器に
おいて、前記内容器と外容器が耐薬品性の樹脂で形成さ
れてなり、かつ前記空間部に面する表面のうち少なくと
も内容器の表面に金属からなる輻射防止材を設けてな
り、また、前記外容器の底部壁の中央に開孔部を設けて
なるとともに、前記空間部にキセノン、クリプトン、ア
ルゴンのうち少なくとも1種の低熱伝導率ガスを封入し
てなり、前記開孔を耐薬品性の樹脂からなる封止板で封
じてなることを特徴とする合成樹脂製断熱二重壁容器で
ある。請求項2に係る発明は、前記耐薬品性の樹脂がポ
リカーボネートとポリエステルとの混合樹脂であること
を特徴とする請求項1記載の合成樹脂製断熱二重壁容器
である。請求項3に係る発明は、金属からなる輻射防止
材が金属箔であることを特徴とする請求項1または2記
載の合成樹脂製断熱二重壁容器である。請求項4に係る
発明は、金属からなる輻射防止材がメッキ膜であること
を特徴とする請求項1または2記載の合成樹脂製断熱二
重壁容器である。請求項5に係る発明は、前記空間部の
輻射防止材のメッキ膜を、該メッキ膜を形成すべき表面
にのみABS樹脂系塗料を塗布し、メッキ膜が形成され
てなることを特徴とする請求項4記載の合成樹脂製断熱
二重壁容器である。請求項6に係る発明は、合成樹脂製
の内容器と外容器とをそれぞれの口部で連結して内容器
を外容器内に空間を隔てて収容して二重壁容器となし、
前記内容器と外容器とで形成した空間部を断熱層として
なる合成樹脂製の断熱二重壁容器の製造方法において、
内容器と外容器を耐薬品性の樹脂を用いて形成し、内容
器と外容器の空間部に面する表面のうち、少なくとも内
容器の表面に金属からなる輻射防止材を形成した後、内
外容器を空間部を有せしめて接合し、該空間部にキセノ
ン、クリプトン、アルゴンのうち少なくとも1種の低熱
伝導率ガスを封入することを特徴とする合成樹脂製断熱
二重壁容器の製造方法である。請求項7に係る発明は、
前記耐薬品性の樹脂がポリカーボネートとポリエステル
との混合樹脂であることを特徴とする請求項6記載の合
成樹脂製断熱二重壁容器の製造方法である。請求項8に
係る発明は、金属からなる輻射防止材が金属箔であるこ
とを特徴とする請求項6または7記載の合成樹脂製断熱
二重壁容器の製造方法である。請求項9に係る発明は、
金属からなる輻射防止材がメッキ膜であることを特徴と
する請求項6または7記載の合成樹脂製断熱二重壁容器
の製造方法である。請求項10に係る発明は、前記空間
部の輻射防止材のメッキ膜を、該メッキ膜を形成すべき
表面にのみABS樹脂系塗料を塗布した後、当該塗布面
にのみメッキ膜を形成することを特徴とする請求項9記
載の合成樹脂製断熱二重壁容器の製造方法である。
According to a first aspect of the present invention, an inner container made of a synthetic resin and an outer container are connected to each other at respective mouths, and the inner container is separated from the outer container by a space. A synthetic resin insulated double-walled container that accommodates and forms a double-walled container and has a space formed by the inner container and the outer container serving as a heat-insulating layer, wherein the inner container and the outer container are made of a chemical-resistant resin. In the surface facing the space portion, at least a surface of the inner container is provided with a radiation preventing material made of metal, and an opening is provided in the center of the bottom wall of the outer container. And at least one of xenon, krypton, and argon having a low thermal conductivity gas is sealed in the space, and the opening is sealed with a sealing plate made of a chemical resistant resin. Is a heat-insulated double-walled container made of synthetic resin. The invention according to claim 2 is the synthetic resin insulated double-walled container according to claim 1, wherein the chemical-resistant resin is a mixed resin of polycarbonate and polyester. The invention according to claim 3 is the synthetic resin insulated double-walled container according to claim 1 or 2, wherein the radiation preventing material made of metal is a metal foil. According to a fourth aspect of the present invention, there is provided the synthetic resin insulated double-walled container according to the first or second aspect, wherein the radiation preventing material made of metal is a plating film. The invention according to claim 5 is characterized in that the plating film of the radiation preventing material in the space portion is formed by applying an ABS resin paint only to the surface on which the plating film is to be formed, thereby forming a plating film. An insulated double-walled container made of a synthetic resin according to claim 4. The invention according to claim 6, wherein the inner container made of synthetic resin and the outer container are connected at their respective mouths, and the inner container is housed with a space in the outer container to form a double-walled container,
In the method for producing a heat-insulating double-walled container made of a synthetic resin in which a space formed by the inner container and the outer container serves as a heat-insulating layer,
After forming the inner container and the outer container using a chemical-resistant resin and forming a metal anti-radiation material on at least the surface of the inner container, of the surface facing the space between the inner container and the outer container, A method of manufacturing a heat insulating double-walled container made of synthetic resin, characterized in that the container has a space portion and is joined, and the space portion is filled with at least one kind of low thermal conductivity gas of xenon, krypton, and argon. is there. The invention according to claim 7 is
7. The method according to claim 6, wherein the chemical-resistant resin is a mixed resin of polycarbonate and polyester. The invention according to claim 8 is the method for producing a synthetic resin insulated double-walled container according to claim 6 or 7, wherein the radiation preventing material made of metal is a metal foil. The invention according to claim 9 is
8. The heat insulating double-wall container made of synthetic resin according to claim 6, wherein the radiation preventing material made of metal is a plating film.
It is a manufacturing method of. The invention according to claim 10 is that, after applying an ABS resin-based coating only to the surface on which the plating film is to be formed, the plating film of the radiation preventing material in the space is formed on the coating surface only. The method for producing a synthetic resin insulated double-walled container according to claim 9, characterized in that:

【0006】[0006]

【発明の実施の形態】図1は本発明の合成樹脂製断熱二
重壁容器の一例を示すものであり、この合成樹脂製断熱
二重壁容器は、容器1と、その上部開口に被せられた蓋
21とからなっている。
FIG. 1 shows an example of a heat-insulating double-walled container made of synthetic resin according to the present invention. The heat-insulating double-walled container made of synthetic resin is covered with a container 1 and an upper opening thereof. Lid 21.

【0007】この容器1は、外容器2と内容器3とから
なり、これら内外容器間の空間部4を低熱伝導率ガスを
封入した断熱層5とする二重壁構造の丼状または椀状を
なしている。これらの内外容器2,3は、耐薬品性かつ
耐熱水性の合成樹脂からなり、樹脂材料を射出成形もし
くはブロー成形により成形されている。使用される樹脂
は耐薬品性であるので、容器1を形成後、内容物を入れ
たり、容器を洗剤等で洗っても、容器1にクラックが生
じる心配がなく、容器1の強度を維持することができ
る。上記耐薬品性とは、有機溶剤、漂白剤、洗剤などの
薬品が接しても変化を生じることのない性質を言う。
The container 1 comprises an outer container 2 and an inner container 3, and a space portion 4 between the inner and outer containers is a heat insulating layer 5 filled with a low thermal conductivity gas. Has made. The inner and outer containers 2 and 3 are made of a chemical-resistant and hot-water-resistant synthetic resin, and are formed by injection molding or blow molding of a resin material. Since the resin to be used is chemically resistant, even if the contents are put into the container 1 or the container is washed with a detergent or the like after forming the container 1, there is no fear that the container 1 will be cracked, and the strength of the container 1 is maintained. be able to. The chemical resistance refers to a property that does not change even when in contact with chemicals such as an organic solvent, a bleach, and a detergent.

【0008】外容器2の底部中央には、断熱層5側に向
けて凹む凹部10が形成され、この凹部10の中央部に
は開孔部8が穿設され、かつ凹部10内には封止板9が
挿入固定され、開孔部8が封止されている。この封止板
9も、前記内外容器2,3と同じく、耐薬品性かつ耐熱
水性の合成樹脂からなり、この封止板9は接着剤により
凹部10内に気密に固着されている。この封止板9を耐
薬品性の合成樹脂で形成したことにより、この開孔部8
から空間部4に低熱伝導率ガスを封入した後、開孔部8
を封止板9で接着剤を用いて封止しても、接着剤に含ま
れる溶剤によりこの封止板9にクラックが生じる心配が
ない。また、洗剤等によっても封止板9にクラックが生
じることがない。
A recess 10 is formed in the center of the bottom of the outer container 2 so as to be recessed toward the heat insulating layer 5. An opening 8 is formed in the center of the recess 10, and a seal is provided in the recess 10. The stop plate 9 is inserted and fixed, and the opening 8 is sealed. The sealing plate 9 is also made of a chemical-resistant and hot-water-resistant synthetic resin, like the inner and outer containers 2 and 3, and the sealing plate 9 is air-tightly fixed in the concave portion 10 by an adhesive. Since the sealing plate 9 is made of a chemical-resistant synthetic resin,
After the low thermal conductivity gas is sealed in the space 4 from the opening 8, the opening 8
Is sealed with a sealing plate 9 using an adhesive, there is no concern that cracks may occur in the sealing plate 9 due to the solvent contained in the adhesive. Also, cracks do not occur in the sealing plate 9 due to the detergent or the like.

【0009】封止板9による封止に用いる接着剤として
は、シアノアクリレート系の接着剤が用いられる。この
接着剤は固化後の気密性が高く、かつ瞬間的に強力な接
着力が得られるので、容器1の空間部4に充填された低
熱伝導率ガスの封止が可能となる。
As an adhesive used for sealing with the sealing plate 9, a cyanoacrylate-based adhesive is used. This adhesive has a high airtightness after solidification, and a strong adhesive force can be obtained instantaneously, so that the low thermal conductivity gas filled in the space 4 of the container 1 can be sealed.

【0010】容器1の空間部4に封入される低熱伝導率
ガスとしては、キセノン、クリプトン、アルゴンのうち
少なくとも1種のガスが用いられる。これらのガスの熱
伝導度はキセノン(κ=0.52×10-2W・m-1・K
-1;0℃)、クリプトン(κ=0.87×10-2W・m
-1・K-1;0℃)、アルゴン(κ=1.63×10-2
・m-1・K-1;0℃)であり、空気(κ=2.41×1
-2W・m-1・K-1;0℃)よりも小さく、これらのガ
スは単独で、あるいは2種以上の混合ガスとして大気圧
程度の封入圧力で封入される。これらの低熱伝導率ガス
を用いることにより、容器1の断熱性能を高めることが
できる。また、これらの低熱伝導率ガスは不活性であ
り、その使用において環境上好適である。
As the low thermal conductivity gas sealed in the space 4 of the container 1, at least one of xenon, krypton, and argon is used. The thermal conductivity of these gases is xenon (κ = 0.52 × 10 -2 W · m -1 · K
−1 ; 0 ° C.), krypton (κ = 0.87 × 10 −2 W · m)
−1 · K −1 ; 0 ° C.), argon (κ = 1.63 × 10 −2 W)
· M -1 · K -1 ; 0 ° C) and air (κ = 2.41 x 1)
0 −2 W · m −1 · K −1 ; 0 ° C.), and these gases are sealed alone or as a mixture of two or more kinds at a sealing pressure of about atmospheric pressure. By using these low thermal conductivity gases, the heat insulating performance of the container 1 can be improved. Also, these low thermal conductivity gases are inert and are environmentally suitable for their use.

【0011】外容器端部6と内容器端部7は振動溶着ま
たはスピン溶着で接合され、この接合により空間部4が
形成される。振動溶着またはスピン溶着によれば、内外
容器2,3の接合部を容易かつ確実に密閉構造にするこ
とができるとともに、その接合強度も大きくなる。
The outer container end 6 and the inner container end 7 are joined by vibration welding or spin welding, and a space 4 is formed by this joining. According to the vibration welding or the spin welding, the joint between the inner and outer containers 2 and 3 can be easily and surely made to have a sealed structure, and the joining strength is increased.

【0012】外容器2と内容器3の射出成形に当たり、
耐薬品性の樹脂としてポリカーボネートとポリエステル
との混合樹脂が用いられる。この混合樹脂は、好ましく
はポリカーボネートとポリエステルの混合重量比が7:
3程度でブレンドしたものである。この混合樹脂は、有
機溶剤、漂白剤、洗剤等の薬品に接しても変化を受ける
ことがない耐薬品性を有しているので、メッキ膜形成の
ために内容器3の外面や外容器2の内面に、メッキ形成
用のABS樹脂系の塗料を塗布しても、塗料の溶剤によ
るクラック(ソルベントクラック)が生じることがな
い。また容器1を形成後、内容物を入れたり、洗剤等で
洗っても内容器3の内面や外容器3の外面にクラックが
生じる心配がない。また、この混合樹脂は耐熱水性であ
り、ガスバリア性もポリカーボネートより数段優れる。
したがって、空間部4に充填された上記低熱伝導率ガス
が器壁を透過して容器外へ逃散する率は極めて小さい。
このため商品寿命が短くて済む場合は、ガスバリア性を
高めるために内外容器2,3間の空間部4に面する表面
にメッキ膜を形成することが不要となる。なお、ポリエ
ステルにはポリエチレンテレフタレートやポリブチレン
テレフタレートが含まれる。
In the injection molding of the outer container 2 and the inner container 3,
A mixed resin of polycarbonate and polyester is used as the chemical resistant resin. This mixed resin preferably has a mixing weight ratio of polycarbonate and polyester of 7:
It is a blend of about three. Since this mixed resin has chemical resistance that does not change even when it comes into contact with chemicals such as an organic solvent, a bleaching agent, and a detergent, the outer surface of the inner container 3 or the outer container 2 for forming a plating film is formed. Even when an ABS resin paint for plating is applied to the inner surface of the substrate, cracks (solvent cracks) due to the solvent of the paint do not occur. Even after the container 1 is formed, even if the contents are put into the container 1 or the container 1 is washed with a detergent or the like, there is no fear that the inner surface of the inner container 3 or the outer surface of the outer container 3 is cracked. In addition, this mixed resin is hot water resistant and has several levels of gas barrier properties better than polycarbonate.
Therefore, the rate at which the low thermal conductivity gas filled in the space portion 4 passes through the vessel wall and escapes outside the container is extremely small.
Therefore, when the product life is short, it is not necessary to form a plating film on the surface facing the space 4 between the inner and outer containers 2 and 3 in order to enhance gas barrier properties. The polyester includes polyethylene terephthalate and polybutylene terephthalate.

【0013】外容器2と内容器3の間に形成された空間
部4に面する表面のうち少なくとも内容器3の表面に、
金属箔からなる輻射防止材11が形成されている。金属
箔としてはアルミ箔、銅箔、銀箔等が用いられる。これ
らの箔は接着剤や両面テープで取り付けられ、空間部4
を経る輻射伝熱を抑えることができる。
At least the surface of the inner container 3 among the surfaces facing the space 4 formed between the outer container 2 and the inner container 3
An anti-radiation material 11 made of metal foil is formed. Aluminum foil, copper foil, silver foil and the like are used as the metal foil. These foils are attached with adhesive or double-sided tape, and the space 4
Radiant heat transfer through the substrate.

【0014】上記金属箔に代えてメッキ膜による輻射防
止材11を形成しても良い。メッキとしては銅メッキ、
銀メッキ等が用いられ、化学メッキの上に電気メッキに
よりメッキ膜が付けられる。これにより、容器1の輻射
伝熱を抑えることができるとともに、内外容器のガスバ
リア性を高めることができる。上述したようにポリカー
ボネートとポリエステルとの混合樹脂はガスバリア性に
優れるため、従来メッキ不良とされていた部分的なメッ
キ膜の不着が、ある程度許容できるようになり、メッキ
の不良率を下げることができる。したがって、製造コス
トを下げることが可能となる。
[0014] Instead of the metal foil, an anti-radiation material 11 of a plating film may be formed. Copper plating as plating,
Silver plating or the like is used, and a plating film is formed on the chemical plating by electroplating. Thereby, the radiation heat transfer of the container 1 can be suppressed, and the gas barrier properties of the inner and outer containers can be enhanced. As described above, since the mixed resin of polycarbonate and polyester has excellent gas barrier properties, partial non-adhesion of the plating film, which has been conventionally regarded as poor plating, can be tolerated to some extent, and the defective rate of plating can be reduced. . Therefore, the manufacturing cost can be reduced.

【0015】内外容器2,3の空間部4に面する器壁に
直接メッキ膜を形成することができない上記混合樹脂に
は、メッキ膜を形成する面にのみABS樹脂系塗料を塗
布して、塗布面にのみメッキ膜を形成する。ABS樹脂
系塗料の塗布面のメッキ膜の付着性は良好となるので、
内容器端部7や外容器端部6の接合部や開孔部8を除い
た面にのみ塗料を塗布して緻密なメッキ膜を形成するこ
とができる。
An ABS resin paint is applied only to the surface on which the plating film is to be formed, on the above-mentioned mixed resin in which a plating film cannot be directly formed on the vessel wall facing the space portion 4 of the inner and outer containers 2, 3. A plating film is formed only on the application surface. Since the adhesion of the plating film on the application surface of the ABS resin paint becomes good,
A paint can be applied only to the surface excluding the joint 7 of the inner container end 7 and the outer container end 6 and the opening 8 to form a dense plating film.

【0016】このように形成された容器1の開口内には
蓋21が着脱容易に係合される。蓋21は下面壁22と
上面壁23からなり、上下面壁で形成される空間には発
泡スチロール、ウレタン等で形成された断熱材24が配
設され、下面壁22と上面壁23の端部を接合して形成
されている。上面壁23にはツマミ25となる凸部が形
成される。このような蓋21を容器1に被せることによ
り、容器1の保温効果を高めることができる。なお、こ
の蓋21の断熱材24に代えて、上述した容器1におけ
る低熱伝導率ガスを封入した断熱層5と同様の断熱構造
を採用することも可能である。
A lid 21 is easily fitted into and detached from the opening of the container 1 thus formed. The lid 21 includes a lower surface wall 22 and an upper surface wall 23, and a heat insulating material 24 formed of styrene foam, urethane, or the like is disposed in a space defined by the upper and lower surfaces walls, and joins the ends of the lower surface wall 22 and the upper surface wall 23. It is formed. A convex portion serving as a knob 25 is formed on the upper surface wall 23. By covering such a lid 21 on the container 1, the heat retaining effect of the container 1 can be enhanced. Instead of the heat insulating material 24 of the lid 21, it is also possible to adopt the same heat insulating structure as the heat insulating layer 5 in which the low thermal conductivity gas in the container 1 is filled.

【0017】次に、本発明の合成樹脂製断熱二重壁容器
の製造方法を説明する。容器1の製造に際し、まず内容
器3と外容器2を、耐薬品性の樹脂を用いて成形する。
耐薬品性の樹脂としては、ポリカーボネートとポリエス
テルとの混合樹脂が好適に用いられる。内外容器2,3
を耐薬品性の樹脂で形成することにより、容器1に内容
物を入れたり、洗剤で洗ったりしても内外容器にクラッ
クを生じることがなく、内外容器の強度を維持すること
ができる。また、内外容器2,3の成形に用いた樹脂が
メッキ膜を形成し難い樹脂である場合、この樹脂にメッ
キ膜による輻射防止材を形成するためにABS樹脂系塗
料を塗布する場合にも、塗料の溶剤により塗布面にクラ
ックが発生することがない。
Next, a method for producing the synthetic resin insulated double-walled container of the present invention will be described. When manufacturing the container 1, first, the inner container 3 and the outer container 2 are molded using a chemically resistant resin.
As the chemical resistant resin, a mixed resin of polycarbonate and polyester is preferably used. Inner and outer containers 2,3
Is formed of a chemical-resistant resin, the inner and outer containers can be maintained in a strong condition without causing cracks in the inner and outer containers even if the contents are put into the container 1 or washed with a detergent. In addition, when the resin used for molding the inner and outer containers 2 and 3 is a resin that is difficult to form a plating film, even when an ABS resin-based paint is applied to the resin to form an anti-radiation material by the plating film, Cracks do not occur on the coated surface due to the solvent of the paint.

【0018】その後、内容器3と外容器2の空間部4に
面する表面のうち、少なくとも内容器3の表面に金属か
らなる輻射防止材11を形成する。これらの表面に輻射
防止材11を形成するには、アルミ箔、銅箔、銀箔など
の金属箔を接着剤や両面テープで接着固定する方法、化
学メッキや電気メッキによって銅、銀をメッキする方法
が用いられる。電気メッキによって金属メッキを形成す
る場合、メッキを形成すべき表面部分にABS樹脂系塗
料を塗布し、その塗布部分にメッキを形成することによ
って、容易かつ確実にメッキ層を形成することができ
る。
Thereafter, a radiation preventing material 11 made of metal is formed on at least the surface of the inner container 3 among the surfaces of the inner container 3 and the space portion 4 of the outer container 2 facing the space portion 4. In order to form the radiation preventing material 11 on these surfaces, a method of bonding and fixing a metal foil such as an aluminum foil, a copper foil, and a silver foil with an adhesive or a double-sided tape, or a method of plating copper or silver by chemical plating or electroplating. Is used. When metal plating is formed by electroplating, a plating layer can be easily and reliably formed by applying an ABS resin-based paint to a surface portion on which plating is to be formed and forming a plating on the applied portion.

【0019】次に、内容器3と外容器2を組合せ、内容
器端部7と外容器端部6とを振動溶着またはスピン溶着
により接合して一体化し、内外容器2,3間に空間部4
を有する二重壁容器とする。次に、この二重壁容器を倒
置し、外容器2の開孔部8から空間部4内の空気を排気
し、その後開孔部8を通して空間部4内に、キセノン、
クリプトン、アルゴンのうちの少なくとも1種からなる
低熱伝導率ガスを封入し、直ちに開孔部8と凹部10に
接着剤を塗布して凹部10に封止板9を挿入し、封止板
9を接着固定して開孔部8を完全に封止する。これによ
り断熱性能の高い二重壁構造の容器1が作製される。
Next, the inner container 3 and the outer container 2 are combined, and the inner container end 7 and the outer container end 6 are joined by vibration welding or spin welding to be integrated, and a space is formed between the inner and outer containers 2 and 3. 4
And a double-walled container having Next, the double-walled container is turned over, the air in the space 4 is exhausted from the opening 8 of the outer container 2, and then xenon,
A low thermal conductivity gas composed of at least one of krypton and argon is sealed, an adhesive is immediately applied to the opening 8 and the recess 10, and the sealing plate 9 is inserted into the recess 10. The opening 8 is completely sealed by bonding. Thereby, the container 1 having a double wall structure having high heat insulation performance is manufactured.

【0020】蓋21は、適宜な合成樹脂材料を用いて上
部材23とツマミ25を有する下部材22を作製し、そ
れらの間の空間に発泡ポリスチレンやウレタンなどの断
熱材24を充填して上部材23と下部材22のそれぞれ
の端部を接合して製造される。なお、蓋21の製造にお
いて、上述した容器1の製造方法を適用し、内部の断熱
材24に代えて低熱伝導率ガスを封入しても良い。
For the lid 21, an upper member 23 and a lower member 22 having a knob 25 are prepared using an appropriate synthetic resin material, and a space therebetween is filled with a heat insulating material 24 such as polystyrene foam or urethane. It is manufactured by joining the respective ends of the member 23 and the lower member 22. In the manufacture of the lid 21, the above-described method of manufacturing the container 1 may be applied, and a low thermal conductivity gas may be filled in place of the heat insulating material 24 inside.

【0021】[0021]

【実施例】図1に示す容器1を作製し、その断熱性能を
確認した。外容器2と容器3をそれぞれポリカーボネ
ートとポリエチレンテレフタレートとの重量比7:3の
混合樹脂を用いて射出成形により作製した。 その後、
外容器2の内面と内容器3の外面に内外容器の接合部と
開孔部8を除いてABS塗料を塗布して、メッキ工程に
流して化学銅メッキを施した後、電気銅メッキを施して
メッキ膜を形成した。続いて、外容器2と内容器3をそ
れぞれの端部6,7にて振動溶着で接合して二重壁容器
を作製した。次いでこの二重壁容器を倒置し、真空ポン
プに連通した排気管路とクリプトンガス供給管路とが切
換え可能に接続された接続管路の先端にパッキンを備え
たガス置換封入封止装置を用い、該接続管路の先端のパ
ッキンを二重壁容器の開孔部8周辺に押付けた状態で、
開孔部8から空間部4内の空気を真空排気し、その後空
間部4にクリプトンガスを大気圧程度の封入圧力となる
ように封入した。そしてガス封入完了直後に、パッキン
を取り外して開孔部8にシアノアクリレート系の接着剤
を滴下して封止し、同接着剤を片面に塗布した封止板9
を開孔部8周囲の凹部10に挿入して接着固定し、開孔
部8を完全に封止するとともに開孔部8を保護した。以
上のようにして作製した容器1は、製造コストが安く、
長期にわたって優れた断熱性能および耐久性を備えてい
た。 (断熱性能の確認) 得られた容器1に95℃の湯を入れ、発泡ポリスチレン
からなる断熱材を充填した蓋21を被せて放置し、1時
間後の湯温を測定した結果、75℃であった。
EXAMPLE A container 1 shown in FIG. 1 was prepared, and its heat insulating performance was confirmed. Outer container 2 and the inner container 3, respectively polycarbonate and polyethylene terephthalate and the weight ratio of 7: were prepared by injection molding using a 3 mixed resin. afterwards,
An ABS paint is applied to the inner surface of the outer container 2 and the outer surface of the inner container 3 except for a joint portion between the inner and outer containers and the opening 8, and is subjected to a chemical copper plating in a plating process, followed by an electrolytic copper plating. Thus, a plating film was formed. Subsequently, the outer container 2 and the inner container 3 were joined at their ends 6 and 7 by vibration welding to produce a double-walled container. Next, this double-walled container is inverted, and a gas replacement enclosing sealing device equipped with packing at the end of a connection pipe in which an exhaust pipe connected to a vacuum pump and a krypton gas supply pipe are switchably connected is used. In a state where the packing at the end of the connection pipe is pressed around the opening 8 of the double-walled container,
The air in the space 4 was evacuated from the opening 8 and then krypton gas was sealed in the space 4 to a pressure of about atmospheric pressure. Immediately after gas filling is completed, the packing is removed, a cyanoacrylate-based adhesive is dropped into the opening 8 to seal the opening, and a sealing plate 9 coated with the adhesive on one side is provided.
Was inserted into the concave portion 10 around the opening 8 and fixed by adhesion. The opening 8 was completely sealed and the opening 8 was protected. The container 1 manufactured as described above has a low manufacturing cost,
It had excellent insulation performance and durability for a long time. (Confirmation of heat insulation performance) Into the obtained container 1, hot water at 95 ° C was placed, covered with a lid 21 filled with a heat insulating material made of expanded polystyrene, and allowed to stand. One hour later, the hot water temperature was measured. there were.

【0022】[0022]

【発明の効果】以上説明したように、本発明の合成樹脂
製断熱二重壁容器は、内容器と外容器が耐薬品性の樹脂
で形成されてなり、開孔を耐薬品性の樹脂からなる封止
板で封じてなるものなので、製造上及び実使用上に溶
剤、洗剤、漂白剤などの薬品、或いは内容物等で容器の
内外表面にクラックが発生することがない。したがって
本発明によれば、耐久性に優れた合成樹脂製断熱二重壁
容器が得られる。
As described above, the synthetic resin insulated double-walled container of the present invention has the inner container and the outer container formed of a chemical-resistant resin, and the opening is formed of the chemical-resistant resin. Since it is sealed with a sealing plate, no cracks occur on the inner and outer surfaces of the container due to chemicals such as solvents, detergents and bleaching agents, or contents during production and actual use. Therefore, according to the present invention, an insulated double-walled container made of synthetic resin having excellent durability can be obtained.

【0023】また、二重壁容器の空間部に面する表面の
うち少なくとも内容器の表面に金属からなる輻射防止材
を設けてなり、空間部にキセノン、クリプトン、アルゴ
ンのうち少なくとも1種の低熱伝導率ガスを封入したも
のなので、空間部の低熱伝導率ガスによる断熱と輻射防
止材による輻射伝熱の低減とによって、断熱性能の高い
合成樹脂製断熱二重壁容器が得られる。
Further, a radiation preventing material made of metal is provided on at least the surface of the inner container out of the surface facing the space of the double-walled container, and at least one of xenon, krypton, and argon is provided in the space. Since the conductive gas is sealed therein, a heat-insulating double-walled container made of synthetic resin having high heat-insulating performance can be obtained by heat insulation of the space portion by the low thermal conductivity gas and reduction of radiation heat transfer by the radiation prevention material.

【0024】また、耐薬品性の樹脂としてポリカーボネ
ートとポリエステルとの混合樹脂が用いられ、この混合
樹脂は耐有機溶剤性でもあるので、内容器の外面や外容
器の内面にメッキ膜形成のためにABS樹脂系の塗料を
塗布する場合でも、塗料に含まれる溶剤によるクラック
が発生しない。また、この樹脂はガスバリア性に優れる
ため、金属による輻射防止材がメッキ膜の場合、メッキ
の不着がある程度許容され、メッキの不良率を下げるこ
とができる。さらにメッキ膜形成の場合はガスバリア性
を高めることができる。また、輻射防止材が金属箔であ
る場合は、簡易な取付操作で輻射伝熱の低減が可能とな
る。さらに金属箔の場合は、ABS樹脂系の塗料の塗布
および金属箔の取付のための装置等が不要であるので、
合成樹脂製断熱二重壁容器を安価にすることができる。
Also, a mixed resin of polycarbonate and polyester is used as the resin having chemical resistance, and since this mixed resin is also resistant to organic solvents, it is necessary to form a plating film on the outer surface of the inner container or the inner surface of the outer container. Even when an ABS resin-based paint is applied, no crack is generated by the solvent contained in the paint. Further, since this resin has excellent gas barrier properties, when the radiation preventing material made of metal is a plating film, non-sticking of plating is allowed to some extent, and the defective rate of plating can be reduced. Further, in the case of forming a plating film, gas barrier properties can be improved. Further, when the radiation preventing material is a metal foil, the radiation heat transfer can be reduced by a simple mounting operation. Furthermore, in the case of a metal foil, an apparatus or the like for applying an ABS resin paint and attaching the metal foil is not required.
Insulated double wall containers made of synthetic resin can be made inexpensive.

【0025】また、内外容器をメッキ膜の付き難い樹脂
で形成した場合は、内外容器のメッキ膜を形成すべき面
にABS樹脂系塗料を塗布して、当該塗布面にのみメッ
キ膜を形成することができるのでメッキの精度を上げる
ことができ、とりわけ内外容器の接合部や開孔部を除い
た部分にメッキ膜を形成することができる。
When the inner and outer containers are formed of a resin to which a plating film is hardly attached, an ABS resin paint is applied to the surface of the inner and outer containers on which the plating film is to be formed, and the plating film is formed only on the application surface. Therefore, the accuracy of plating can be improved, and in particular, a plating film can be formed on a portion other than a joint portion and an opening portion of the inner and outer containers.

【0026】本発明の合成樹脂製断熱二重壁容器の製造
方法においては、内容器と外容器を耐薬品性の樹脂を用
いて成形するので、得られる容器は溶剤や洗剤、内容物
等でクラックを生じることがない。また、内外容器を接
合後、内容器と外容器の空間部に面する表面のうち、少
なくとも内容器の表面に金属からなる輻射防止材を形成
した後、内外容器を空間部を有せしめて接合し、該空間
部にキセノン、クリプトン、アルゴンのうち少なくとも
1種の低熱伝導率ガスを封入するので、断熱性能の高い
合成樹脂製断熱二重壁容器を作製することができる。
In the method for producing a heat-insulated double-wall container made of synthetic resin of the present invention, the inner container and the outer container are molded using a chemical-resistant resin. There is no crack. In addition, after joining the inner and outer containers, of the surface facing the space portion of the inner container and the outer container, after forming an anti-radiation material made of metal on at least the surface of the inner container, the inner and outer containers are joined by having a space portion. Then, since at least one kind of low thermal conductivity gas of xenon, krypton, and argon is sealed in the space, a heat insulating double wall container made of synthetic resin having high heat insulating performance can be manufactured.

【0027】また、耐薬品性の樹脂がポリカーボネート
とポリエステルとの混合樹脂であるので、内外容器のメ
ッキ膜形成面にABS樹脂系の塗料を塗布しても、塗料
の溶剤によりクラックが生じることがなく、容器の耐久
性を高めることができる。また、この混合樹脂はガスバ
リア性も高いので、メッキ膜によらない金属箔による輻
射伝熱の低減が可能となり、製造工程を簡素化すること
ができる。
Further, since the chemical-resistant resin is a mixed resin of polycarbonate and polyester, even if an ABS resin-based paint is applied to the plating film forming surfaces of the inner and outer containers, cracks may occur due to the solvent of the paint. And the durability of the container can be increased. Further, since the mixed resin has a high gas barrier property, it is possible to reduce radiant heat transfer by the metal foil not depending on the plating film, thereby simplifying the manufacturing process.

【図面の簡単な説明】[Brief description of the drawings]

【図1】図1は本発明の合成樹脂製断熱二重壁容器の一
例を示す断面図である。
FIG. 1 is a cross-sectional view showing an example of a synthetic resin insulated double-walled container of the present invention.

【符号の説明】[Explanation of symbols]

1……容器、2……外容器、3……内容器、4……空間
部、5……断熱層、8……開孔部、9……封止板、11
……輻射防止材。
DESCRIPTION OF SYMBOLS 1 ... container, 2 ... outer container, 3 ... inner container, 4 ... space part, 5 ... heat insulation layer, 8 ... opening part, 9 ... sealing plate, 11
…… Anti-radiation material.

フロントページの続き (72)発明者 田中 篤彦 東京都港区西新橋1丁目16番7号 日本 酸素株式会社内 (56)参考文献 実開 昭63−242983(JP,U) 実開 昭63−10962(JP,U) 実開 昭55−131163(JP,U) (58)調査した分野(Int.Cl.6,DB名) A47J 41/02 C23C 18/16 - 18/20 Continuing from the front page (72) Inventor Atsuhiko Tanaka 1-16-7 Nishi-Shimbashi, Minato-ku, Tokyo Inside Japan Oxygen Co., Ltd. (56) References JP-A 63-242983 (JP, U) JP-A 63-10962 (JP, U) Japanese Utility Model Showa 55-131163 (JP, U) (58) Fields investigated (Int. Cl. 6 , DB name) A47J 41/02 C23C 18/16-18/20

Claims (10)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 合成樹脂製の内容器と外容器とをそれぞ
れの口部で連結して内容器を外容器内に空間を隔てて収
容して二重壁容器となし、前記内容器と外容器とで形成
した空間部を断熱層としてなる合成樹脂製の断熱二重壁
容器において、前記内容器と外容器が耐薬品性の樹脂で
形成されてなり、かつ前記空間部に面する表面のうち少
なくとも内容器の表面に金属からなる輻射防止材を設け
てなり、また、前記外容器の底部壁の中央に開孔部を設
けてなるとともに、前記空間部にキセノン、クリプト
ン、アルゴンのうち少なくとも1種の低熱伝導率ガスを
封入してなり、前記開孔部を耐薬品性の樹脂からなる封
止板で封じてなることを特徴とする合成樹脂製断熱二重
壁容器。
An inner container made of a synthetic resin and an outer container are connected to each other at respective mouths, and the inner container is housed in the outer container with a space therebetween to form a double-walled container. In a heat-insulating double-walled container made of a synthetic resin in which a space formed by a container serves as a heat-insulating layer, the inner container and the outer container are formed of a chemical-resistant resin, and have a surface facing the space. Among them, at least a surface of the inner container is provided with an anti-radiation material made of metal, and also, an opening is provided in the center of the bottom wall of the outer container, and at least xenon, krypton, and argon are provided in the space. A heat-insulated double-wall container made of synthetic resin, wherein one kind of low thermal conductivity gas is sealed, and the opening is sealed with a sealing plate made of a chemical-resistant resin.
【請求項2】 前記耐薬品性の樹脂がポリカーボネート
とポリエステルとの混合樹脂であることを特徴とする請
求項1記載の合成樹脂製断熱二重壁容器。
2. The insulated double wall container made of synthetic resin according to claim 1, wherein the chemical resistant resin is a mixed resin of polycarbonate and polyester.
【請求項3】 金属からなる輻射防止材が金属箔である
ことを特徴とする請求項1または2記載の合成樹脂製断
熱二重壁容器。
3. The heat insulating double-walled container made of synthetic resin according to claim 1, wherein the radiation preventing material made of metal is a metal foil.
【請求項4】 金属からなる輻射防止材がメッキ膜であ
ることを特徴とする請求項1または2記載の合成樹脂製
断熱二重壁容器。
4. The insulated double-wall container made of synthetic resin according to claim 1, wherein the radiation preventing material made of metal is a plating film.
【請求項5】 前記輻射防止材のメッキ膜を、該メッキ
膜を形成すべき表面にのみABS樹脂系塗料を塗布し、
メッキ膜が形成されてなることを特徴とする請求項4記
載の合成樹脂製断熱二重壁容器。
5. An ABS resin paint is applied only to the surface on which the plating film is to be formed, and
The insulated double-wall container made of synthetic resin according to claim 4, wherein a plated film is formed.
【請求項6】 合成樹脂製の内容器と外容器とをそれぞ
れの口部で連結して内容器を外容器内に空間を隔てて収
容して二重壁容器となし、前記内容器と外容器とで形成
した空間部を断熱層としてなる合成樹脂製の断熱二重壁
容器の製造方法において、内容器と外容器を耐薬品性の
樹脂を用いて形成し、内容器と外容器の空間部に面する
表面のうち、少なくとも内容器の表面に金属からなる輻
射防止材を形成した後、内外容器を空間部を有せしめて
接合し、該空間部にキセノン、クリプトン、アルゴンの
うち少なくとも1種の低熱伝導率ガスを封入することを
特徴とする合成樹脂製断熱二重壁容器の製造方法。
6. An inner container made of a synthetic resin and an outer container are connected at their respective mouths, and the inner container is housed in the outer container with a space therebetween to form a double-walled container. In a method of manufacturing a heat-insulated double-walled container made of a synthetic resin in which a space formed by a container is used as a heat-insulating layer, the inner container and the outer container are formed using a chemical-resistant resin, and the space between the inner container and the outer container is formed. After forming an anti-radiation material made of metal on at least the surface of the inner container out of the surfaces facing the parts, the inner and outer containers are joined together with a space, and at least one of xenon, krypton, and argon is formed in the space. What is claimed is: 1. A method for producing a heat-insulated double-walled container made of synthetic resin, comprising filling a kind of low thermal conductivity gas.
【請求項7】 前記耐薬品性の樹脂がポリカーボネート
とポリエステルとの混合樹脂であることを特徴とする請
求項6記載の合成樹脂製断熱二重壁容器の製造方法。
7. The method according to claim 6, wherein the chemical-resistant resin is a mixed resin of polycarbonate and polyester.
【請求項8】 金属からなる輻射防止材が金属箔である
ことを特徴とする請求項6または7記載の合成樹脂製断
熱二重壁容器の製造方法。
8. The method for producing a heat-insulated double-wall container made of synthetic resin according to claim 6, wherein the radiation preventing material made of metal is a metal foil.
【請求項9】 金属からなる輻射防止材がメッキ膜であ
ることを特徴とする請求項6または7記載の合成樹脂製
断熱二重壁容器の製造方法
9. The method of claim 6 or 7 production methods of the synthetic resin insulated double-walled vessel wherein a radiation prevention material composed of a metal is plated film.
【請求項10】 前記輻射防止材のメッキ膜を、該メッ
キ膜を形成すべき表面にのみABS樹脂系塗料を塗布し
た後、当該塗布面にのみメッキ膜を形成することを特徴
とする請求項9記載の合成樹脂製断熱二重壁容器の製造
方法。
10. An anti-radiation material plating film, wherein an ABS resin paint is applied only to the surface on which the plating film is to be formed, and then the plating film is formed only on the application surface. 10. The method for producing a synthetic resin insulated double-walled container according to item 9.
JP7260550A 1995-09-13 1995-10-06 Insulated double-walled container made of synthetic resin and method of manufacturing the same Expired - Fee Related JP2920094B2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP7260550A JP2920094B2 (en) 1995-10-06 1995-10-06 Insulated double-walled container made of synthetic resin and method of manufacturing the same
KR1019960038263A KR100260956B1 (en) 1995-09-13 1996-09-04 Plastic insulating double wall receptacle and cover
US08/710,056 US5904264A (en) 1995-09-13 1996-09-10 Thermally insulated double-walled synthetic resin container and thermally insulated double-walled synthetic resin lid
DE1996613920 DE69613920T2 (en) 1995-09-13 1996-09-10 Heat-insulated, double-walled synthetic resin container and heat-insulated, double-walled synthetic resin lid
EP19960114453 EP0763483B1 (en) 1995-09-13 1996-09-10 Thermally insulated double-walled synthetic resin container and thermally insulated double-walled synthetic resin lid
CA 2185298 CA2185298A1 (en) 1995-09-13 1996-09-11 Thermally insulated double-walled synthetic resin container and thermally insulated double-walled synthetic resin lid
CN96122043A CN1158235A (en) 1995-09-13 1996-09-13 Synthetic resin adiabatic two-layered wall vessel and cover made of the same
US08/931,186 US6036801A (en) 1995-09-13 1997-09-16 Method for producing a thermally insulated double-walled synthetic resin container and lid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7260550A JP2920094B2 (en) 1995-10-06 1995-10-06 Insulated double-walled container made of synthetic resin and method of manufacturing the same

Publications (2)

Publication Number Publication Date
JPH0998891A JPH0998891A (en) 1997-04-15
JP2920094B2 true JP2920094B2 (en) 1999-07-19

Family

ID=17349521

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7260550A Expired - Fee Related JP2920094B2 (en) 1995-09-13 1995-10-06 Insulated double-walled container made of synthetic resin and method of manufacturing the same

Country Status (1)

Country Link
JP (1) JP2920094B2 (en)

Also Published As

Publication number Publication date
JPH0998891A (en) 1997-04-15

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