JP2916965B2 - Iron structural parts - Google Patents
Iron structural partsInfo
- Publication number
- JP2916965B2 JP2916965B2 JP4066994A JP6699492A JP2916965B2 JP 2916965 B2 JP2916965 B2 JP 2916965B2 JP 4066994 A JP4066994 A JP 4066994A JP 6699492 A JP6699492 A JP 6699492A JP 2916965 B2 JP2916965 B2 JP 2916965B2
- Authority
- JP
- Japan
- Prior art keywords
- iron
- zinc
- chromic acid
- film
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、鉄製構造部品の基材表
面に、鉄を核とし亜鉛が被覆されたブラスト材料を前記
基材表面に投射することにより、亜鉛めっき層が形成さ
れ、さらに、クロム酸系皮膜が形成されてなる鉄製構造
部品に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a zinc-plated layer formed by projecting a blast material coated with zinc with iron as a nucleus on the surface of a substrate of an iron structural component. And a steel structural part having a chromic acid-based film formed thereon.
【０００２】ここで、鉄とは、純鉄に限られず、鋼、鋳
鉄、各種鉄合金を含む概念である。[0002] Here, iron is a concept including not only pure iron but also steel, cast iron and various iron alloys.
【０００３】また、亜鉛とは、亜鉛ばかりでなく、亜鉛
とアルミニウム、銅、マグネシウム等との合金を指す。
さらに、鉄製構造部品とは、自動車の組み立て等に使用
するボルト・ナット、リベット等の固着具、及びプレス
部品を含む概念である。[0003] Zinc refers to not only zinc but also alloys of zinc with aluminum, copper, magnesium and the like.
Further, the iron structural component is a concept including bolts and nuts, fasteners such as rivets, and press components used for assembling automobiles and the like.
【０００４】[0004]
【従来の技術】鉄の防錆処理方法として、環境汚染要素
の少ないいわゆるブラスト亜鉛被覆法で亜鉛めっき層を
形成し、該亜鉛めっき層上に焼成クロメート皮膜を形成
する構成の下記方法が提案されている（特開昭６０−２
４５７８４号公報参照）。2. Description of the Related Art As a method for preventing rust on iron, the following method has been proposed in which a galvanized layer is formed by a so-called blast zinc coating method with less environmental pollution elements, and a calcined chromate film is formed on the galvanized layer. (Japanese Patent Laid-Open No. 60-2)
No. 45784).
【０００５】「鉄または鉄合金を核とし、この核周囲に
鉄合金亜鉛層を介して亜鉛または亜鉛合金を被着してな
る独立した被着粒子の集合体からなるブラスト材料を鉄
または鉄合金表面に投射することによって、鉄または鉄
合金表面に亜鉛被覆皮膜を形成し、このように形成され
た表面に水溶性クロム酸化合物と還元剤と還元性金属粉
末と水からなる組成物を適用し、焼成してクロメート皮
膜を形成することからなる鉄または鉄合金の表面処理
法。」[0005] A blast material consisting of an aggregate of independent adhered particles having iron or an iron alloy as a core and zinc or a zinc alloy applied around the core via a zinc layer of an iron alloy is used as an iron or iron alloy. By projecting on the surface, a zinc coating film is formed on the iron or iron alloy surface, and a composition comprising a water-soluble chromate compound, a reducing agent, a reducing metal powder, and water is applied to the surface thus formed. , A surface treatment method for iron or an iron alloy, which comprises firing to form a chromate film. "
【０００６】[0006]
【発明が解決しようとする課題】しかし、ボルト・ナッ
ト、プレス部品等、自動車の鉄製構造部品に、上記表面
処理法で防錆処理したものでは、昨今の、自動車部品に
おける耐食性の高度化の要求（冬期の高速道路における
融雪剤の散布、海上道路の延長距離の増大等に伴う）
を、満足させることは困難となってきている。However, in the case of steel structural parts such as bolts and nuts, pressed parts and the like, which have been subjected to rust-preventive treatment by the above-mentioned surface treatment method, there is a recent demand for higher corrosion resistance of automotive parts. (Due to the spread of snowmelt on the highways in winter and the increase in the length of offshore roads, etc.)
Is difficult to satisfy.
【０００７】本発明は、上記にかんがみて、ブラスト亜
鉛被覆法で亜鉛めっき層が形成され、さらに、クロム酸
系皮膜が形成されてなる鉄製構造部品において、格段に
耐食性の向上した鉄製構造部品を提供することを目的と
する。[0007] In view of the above, the present invention relates to an iron structural component having a galvanized layer formed by a blast zinc coating method and further having a chromic acid-based film formed thereon. The purpose is to provide.
【０００８】[0008]
【課題を解決するための手段】本発明は、上記課題を下
記構成により、解決するものである。According to the present invention, the above-mentioned object is achieved by the following constitution.
【０００９】 基材表面に、鉄を核として亜鉛が被覆さ
れたブラスト材料を投射することにより、亜鉛めっき層
が形成され、さらに、該亜鉛めっき層上にクロム酸系被
膜が形成されてなる鉄製構造部品において、前記クロム
酸系被膜が、三酸化クロムおよび燐酸二水素金属塩を必
須配合成分とし、両者の配合比を前者／後者＝９／１〜
４／６とする水系被膜剤の加熱硬化膜で形成されてなる
ことを特徴とする。A zinc plating layer is formed by projecting a blast material coated with zinc with iron as a nucleus on the surface of the base material, and further, a chromic acid-based coating is formed on the zinc plating layer. In the structural component, the chromic acid-based coating contains chromium trioxide and metal dihydrogen phosphate as essential components, and the mixing ratio of both is former / latter = 9/1 to 1.
It is characterized by being formed of a heat-cured film of an aqueous coating agent of 4/6.
【００１０】[0010]
【手段の詳細な説明】以下、本発明の手段について、詳
細に説明する。なお、配合単位は、特に断らない限り重
量単位である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The means of the present invention will be described in detail below. The blending units are weight units unless otherwise specified.
【００１１】(1) 本発明の鉄製構造部品は、鉄製構造部
品の基材表面に、鉄を核とし亜鉛が被覆されたブラスト
材料を投射することにより、亜鉛めっき層が形成され、
さらに、該亜鉛めっき層上にクロム酸系皮膜が形成され
てなることを前提とする。(1) The iron-made structural component of the present invention has a galvanized layer formed by projecting a blast material coated with zinc using iron as a nucleus on the base material surface of the iron-made structural component.
Further, it is assumed that a chromic acid-based film is formed on the galvanized layer.
【００１２】ここで亜鉛めっき層の形成は、特公昭５９
−９３１２号公報に記載されている下記方法に準じて形
成する。Here, the formation of the galvanized layer is described in
And formed according to the following method described in US Pat.
【００１３】「鉄または鉄合金を核とし、この核の周囲
に鉄亜鉛合金層を介して亜鉛または亜鉛合金を被着して
なる独立した複層粒子の集合体からなるブラスト用材料
を、鉄または鉄合金の表面に投射することを特徴とする
鉄または鉄合金表面の亜鉛合金コーテング法。」また、
亜鉛めっき層の厚みは、通常、１〜１０μｍである。[0013] A blasting material comprising an aggregate of independent multi-layer particles having iron or an iron alloy as a nucleus and zinc or a zinc alloy applied on the nucleus via an iron-zinc alloy layer is referred to as an iron Or a zinc alloy coating method on the surface of iron or iron alloy, which is projected onto the surface of iron alloy. "
The thickness of the galvanized layer is usually 1 to 10 μm.
【００１４】なお、この亜鉛めっき層の形成に先立ち、
基材表面は、常法により清浄化しておく。即ち、トリク
ロロエチレン、トリクロロエタン等の有機溶剤、または
アルカリ洗浄剤等の水性洗浄剤を用いて油脂類の除去を
行って、表面を活性化しておく。または、ショットブラ
スト等の物理的方法によって表面を清浄化してもよい。Prior to the formation of the galvanized layer,
The surface of the substrate is cleaned by a conventional method. That is, the surface is activated by removing oils and fats using an organic solvent such as trichloroethylene and trichloroethane or an aqueous detergent such as an alkaline detergent. Alternatively, the surface may be cleaned by a physical method such as shot blasting.
【００１５】 (2) そして、本発明は、上記構成の鉄製
構造部品において、上記クロム酸系被膜が、三酸化クロ
ムおよび燐酸二水素金属塩を必須配合成分とし、両者の
配合比を前者／後者＝９／１〜４／６（望ましくは７／
１〜１／１）とする水系被膜剤の加熱硬化膜で形成され
てなることを特徴とする。(2) In the present invention, in the iron-made structural component having the above-described configuration, the chromic acid-based coating includes chromium trioxide and a metal salt of dihydrogen phosphate as essential components, and the mixing ratio of both is the former / the latter. = 9/1 to 4/6 (desirably 7 /
It is characterized in that it is formed of a heat-cured film of an aqueous coating agent to be 1 to 1/1).
【００１６】燐酸二水素金属塩の比率が過少であると、
防錆性向上の作用を奏しがたく、燐酸二水素金属塩の比
率が過多であると、硬化皮膜の耐水性が劣化する。When the proportion of the metal dihydrogen phosphate is too small,
It is difficult to achieve the effect of improving the rust resistance, and if the ratio of the metal dihydrogen phosphate is excessive, the water resistance of the cured film deteriorates.
【００１７】また、必須配合成分の配合量（三酸化クロ
ムと燐酸二水素金属塩の合計量）で、１０〜７０％（望
ましくは４０〜６０％）とする。１０％未満では、所定
の被覆膜厚（通常、0.1 μｍ）を得がたく、７０％を越
えると両成分の飽和溶解度を越え沈殿が発生し易くな
る。The amount of the essential components (total amount of chromium trioxide and metal dihydrogen phosphate) is 10 to 70% (preferably 40 to 60%). If it is less than 10%, it is difficult to obtain a predetermined coating film thickness (usually 0.1 μm), and if it exceeds 70%, the saturation solubility of both components is exceeded and precipitation tends to occur.
【００１８】上記燐酸二水素金属塩の金属としては、カ
ルシウム・アルミニウム・マグネシウム・亜鉛等を挙げ
ることができる。なお、燐酸二水素塩の一部を、燐酸一
水素金属塩・燐酸正金属塩に置換してもよい（水溶性の
場合は約１／２以下、難溶性の場合は約１／９以下）。Examples of the metal of the metal dihydrogen phosphate include calcium, aluminum, magnesium, and zinc. In addition, a part of dihydrogen phosphate may be replaced by metal monohydrogen phosphate / metal phosphate normal (about 1/2 or less in the case of water solubility, and about 1/9 or less in the case of poor solubility). .
【００１９】また、三酸化クロムの一部を、クロム酸塩
・重クロム酸金属塩（カリウム・ナトリウム・マグネシ
ウム・亜鉛等の）または、三酸化二クロムと置換しても
よい（水溶性の場合は約１／２以下、難溶性の場合は約
１／９以下）。A part of the chromium trioxide may be replaced with a chromate / metal dichromate (such as potassium, sodium, magnesium, zinc, etc.) or dichromium trioxide (in the case of water solubility). Is about 1/2 or less, and when it is hardly soluble, about 1/9 or less).
【００２０】また、他の配合成分として、一価・二価の
アルコール類及び界面活性剤を、通常使用する。Further, monohydric / dihydric alcohols and surfactants are usually used as other components.
【００２１】アルコール類は、クロム酸を還元重合させ
る作用を奏すると推定され、具体的には、エチルアルコ
ール、イソプロピルアルコール、イソブチルアルコー
ル、セロソルブ（以上一価）、エチレングリコール、ジ
エチレングリコール、ポリエチレングリコール（分子量
２００〜６００）等を使用可能である。アルコール類の
配合量は、必須配合成分の種類及び配合量により異なる
が、通常、１〜１０％とする。Alcohols are presumed to have an action of reducing and polymerizing chromic acid. Specifically, alcohols include ethyl alcohol, isopropyl alcohol, isobutyl alcohol, cellosolve (monohydric), ethylene glycol, diethylene glycol, and polyethylene glycol (molecular weight). 200 to 600) can be used. The blending amount of the alcohol varies depending on the kind and blending amount of the essential blending component, but is usually 1 to 10%.
【００２２】界面活性剤は、コーテイング膜のレベリン
グ性を高める作用を奏し、好ましくは、フッ素系界面活
性剤を使用する。その配合量は、通常、0.01〜0.1 ％と
する。The surfactant has an effect of improving the leveling property of the coating film, and a fluorine-based surfactant is preferably used. The amount is usually 0.01 to 0.1%.
【００２３】 (3) 上記要件の水系皮膜剤を前記亜鉛め
っき層上に塗布し、加熱硬化させて本発明のクロム酸系
皮膜を形成する。[0023] (3) The requirement of a water-based skin layer agent is applied to the galvanized layer, heated and cured to form a chromic acid based coating of the present invention.
【００２４】塗布方法は、特に限定されないが、浸漬含
浸法またはスプレー法により行なう。また、必要によ
り、重ね塗りしてもよい。The coating method is not particularly limited, but is performed by a dipping impregnation method or a spray method. Moreover, you may apply repeatedly, if needed.
【００２５】加熱硬化の条件は、通常、１００〜４００
℃×５〜１２０min とする。加熱温度１００℃未満で
は、耐水性が劣り、４００℃を越えると皮膜にクラック
の発生が増加、膜特性が低下するおそれがある。The conditions for heat curing are usually from 100 to 400
C. x 5-120 min. If the heating temperature is lower than 100 ° C., the water resistance is inferior. If the heating temperature is higher than 400 ° C., the occurrence of cracks in the film increases, and the film properties may be deteriorated.
【００２６】上記クロム酸系皮膜の膜厚は、通常、0.05
〜１０μｍ（望ましくは 0.1〜５μｍ）とする。0.05μ
ｍ未満では耐熱性・硬度・耐食性等に対する効果が十分
に得られず、１０μｍを越えると皮膜の内部応力の蓄積
による膜質の低下及び着膜のための時間を要し、膜の均
一性に問題が生じ易い。The thickness of the chromic acid-based coating is usually 0.05
To 10 μm (preferably 0.1 to 5 μm). 0.05μ
If it is less than m, the effects on heat resistance, hardness, corrosion resistance, etc. cannot be sufficiently obtained. If it exceeds 10 μm, deterioration of the film quality due to accumulation of internal stress of the film and time for film deposition are required, and there is a problem in film uniformity. Tends to occur.
【００２７】[0027]
【発明の作用・効果】本発明の鉄製構造部品は、基材表
面に、鉄を核とし亜鉛が被覆されたブラスト材料を投射
することにより、亜鉛めっき層が形成され、さらに、該
亜鉛めっき層上にクロム酸系皮膜が形成されてなるもの
において、クロム酸系皮膜が、三酸化クロム及び燐酸二
水素金属塩を必須配合成分とし、両者の配合比を前者／
後者＝９／１〜４／６とする水系水系皮膜剤で形成され
てなることを特徴とすることにより、後述の実施例で支
持されるごとく、耐食性が著しく向上した鉄製構造部品
を得ることができる。According to the present invention, a zinc-plated layer is formed by projecting a blast material coated with zinc using iron as a nucleus on the surface of a base material. The chromic acid-based coating is formed on the chromic acid-based coating, and the chromic acid-based coating has chromium trioxide and metal dihydrogen phosphate as essential components, and the mixing ratio of both is the former /
By being characterized by being formed with an aqueous water-based coating agent in which the latter = 9/1 to 4/6, it is possible to obtain an iron structural part having significantly improved corrosion resistance, as supported by the examples described later. it can.
【００２８】その理由は、下記の如くであると推定され
る。The reason is presumed to be as follows.
【００２９】鉄及び鉄合金上に電気科学的に犠牲陽極と
なるべく亜鉛めっき層をブラスト被覆法で形成し電気化
学防食を行い、さらにブラスト亜鉛被覆法であるが故に
発生する多孔性を活用し、微溶解性のリン酸・クロム酸
複合化合物で充填することによってクロムの不働態化に
よる電気化学防食を呈していると考えられる。A galvanized layer is formed on iron and an iron alloy by a blast coating method to become a sacrificial anode electrochemically, electrochemical corrosion protection is performed, and further, the porosity generated due to the blast zinc coating method is utilized. It is considered that by filling with a slightly soluble phosphoric acid / chromic acid composite compound, electrochemical corrosion protection due to passivation of chromium is exhibited.
【００３０】クロム酸系皮膜の耐食性は、生成する皮
膜はガラス状で密着良く被覆するため、下地金属と空気
及び水分との接触を断ち、酸素の供給を遮蔽する、皮
膜中には６価クロムが残存しており加熱硬化によって微
溶解性になっているため、長時間に渡って経時的に６価
クロムを金属表面に補給し、６価クロムによる不働態化
を促進させる、の各作用が相乗して得られると考えられ
る。The corrosion resistance of the chromic acid-based film is such that the resulting film is glassy and is coated with good adhesion, thereby cutting off the contact between the underlying metal and air and moisture and blocking the supply of oxygen. Remains and is slightly soluble by heat curing, so that hexavalent chromium is replenished to the metal surface over time over a long period of time to promote the passivation by hexavalent chromium. It is thought that they can be obtained in a synergistic manner.
【００３１】[0031]
【実施例】以下、本発明の効果を確認するために、比較
例とともに行なった実施例について説明をする。EXAMPLES Hereinafter, examples performed together with comparative examples to confirm the effects of the present invention will be described.
【００３２】(1) ブラスト亜鉛被覆法で鉄・合金亜鉛め
っきが形成された下記各鉄製構造部品（被塗布物）を、
予め調製しておいた表１・２に示す組成の水系皮膜剤に
浸漬塗布して、引き上げ後、遠心乾燥（８００ｒｐｍ×
３０秒）し、さらに、表示の条件で塗膜を加熱硬化させ
た。(1) Each of the following iron structural parts (substrates to be coated), on which iron / alloy zinc plating is formed by blast zinc coating,
Dip-coating with a water-based coating agent having the composition shown in Tables 1 and 2 prepared in advance, pulling it up, centrifugal drying (800 rpm ×
30 seconds), and the coating was cured by heating under the indicated conditions.
【００３３】＜実施例１＞ＳＫ材軟鋼自動車部品用ボル
ト、被覆量１７０ｍｇ／ｄｍ2 。<Example 1> SK material bolt for mild steel automobile parts, coating amount 170 mg / dm 2 .
【００３４】＜実施例２、比較例１＞ＳＰＣＣプレス部
品、被覆量１００ｍｇ／ｄｍ2 。Example 2, Comparative Example 1 Pressed parts of SPCC, coating amount 100 mg / dm 2 .
【００３５】＜実施例３・８、比較例２・４〜７＞ＳＫ
材軟鋼フランジボルト、被覆量１２０ｍｇ／ｄｍ2 。<Examples 3.8, Comparative Examples 2.4-7> SK
Material mild steel flange bolts, coverage 120 mg / dm 2.
【００３６】＜実施例４〜７、比較例３＞ＳＫ材軟鋼フ
ランジボルト、被覆量１５０ｍｇ／ｄｍ2 。<Examples 4 to 7, Comparative Example 3> SK mild steel flange bolt, covering amount 150 mg / dm 2 .
【００３７】なお、比較例４〜７は、前述の特開昭６０
−２４５７８４号公報における実施例１〜４に対応する
ものである。Incidentally, Comparative Examples 4 to 7 are described in
This corresponds to Examples 1 to 4 in JP-A-245784.
【００３８】(2) こうして得た各構造部品について、下
記項目の試験を行なった。表１・２に示す試験結果か
ら、本発明の構造部品は、従来品に比して、格段に耐食
性及び表面硬度が向上していることが判る。(2) The following items were tested for each of the structural parts thus obtained. From the test results shown in Tables 1 and 2, it can be seen that the structural component of the present invention has significantly improved corrosion resistance and surface hardness as compared with the conventional product.
【００３９】塩水噴霧試験…耐熱試験（２００度×５
ｈ）後、 JIS Z 2371 に準じて行なった。Salt spray test: heat resistance test (200 degrees × 5)
h) Thereafter, the measurement was performed according to JIS Z 2371.
【００４０】[0040]
【表１】 [Table 1]
【００４１】＊１）「フロラード ＦＣ−９５」住友３
Ｍ社製* 1) "Floraldo FC-95" Sumitomo 3
M company
【００４２】[0042]
【表２】 [Table 2]
【００４３】＊１）「フロラード ＦＣ−９５」住友３
Ｍ社製 ＊２）日本油脂（株）製非イオン界面活性剤 ＊３）ダイヤモンドシャムロック社製非イオン界面活性
剤* 1) "Floraldo FC-95" Sumitomo 3
* 2) Nonionic surfactant manufactured by NOF Corporation * 3) Nonionic surfactant manufactured by Diamond Shamrock
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭63−105976（ＪＰ，Ａ) 特公 昭49−29407（ＪＰ，Ｂ１) 特公 昭47−48777（ＪＰ，Ｂ１) 特公 昭43−10205（ＪＰ，Ｂ１) (58)調査した分野(Int.Cl.6，ＤＢ名) C23C 22/00 - 22/86 C23C 24/04 C23C 28/00 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-63-105976 (JP, A) JP-B-49-29407 (JP, B1) JP-B-47-48777 (JP, B1) JP-B-43 10205 (JP, B1) (58) Fields investigated (Int. Cl. 6 , DB name) C23C 22/00-22/86 C23C 24/04 C23C 28/00
Claims (1)
れたブラスト材料を投射することにより、亜鉛めっき層
が形成され、さらに、該亜鉛めっき層上にクロム酸系被
膜が形成されてなる鉄製構造部品において、 前記クロム酸系被膜が、三酸化クロムおよび燐酸二水素
金属塩を必須配合成分とし、両者の配合比を前者／後者
＝９／１〜４／６とする水系被膜剤の加熱硬化膜で形成
されてなることを特徴とする鉄製構造部品。1. A zinc plating layer is formed by projecting a blast material coated with zinc using iron as a nucleus on a surface of a base material, and further, a chromic acid-based coating is formed on the zinc plating layer. In the iron-made structural part, the chromic acid-based coating comprises chromium trioxide and metal dihydrogen phosphate as essential components, and a mixing ratio of the former and the latter is 9/1 to 4/6 . An iron structural part formed by a heat-cured film .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4066994A JP2916965B2 (en) | 1992-03-25 | 1992-03-25 | Iron structural parts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4066994A JP2916965B2 (en) | 1992-03-25 | 1992-03-25 | Iron structural parts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05271957A JPH05271957A (en) | 1993-10-19 |
| JP2916965B2 true JP2916965B2 (en) | 1999-07-05 |
Family
ID=13332072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4066994A Expired - Lifetime JP2916965B2 (en) | 1992-03-25 | 1992-03-25 | Iron structural parts |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2916965B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10204654A (en) * | 1997-01-21 | 1998-08-04 | Aoyama Seisakusho Co Ltd | Treatment of surface of metal |
| CN102797927A (en) * | 2012-07-27 | 2012-11-28 | 联塑市政管道（河北）有限公司 | Novel pipe fitting and manufacturing method thereof |
| CN110565099B (en) * | 2019-09-03 | 2021-03-02 | 本溪陆甲科技有限公司 | Double protective agent for corrosion of chromium-plated hydraulic part in water-glycol hydraulic system |
-
1992
- 1992-03-25 JP JP4066994A patent/JP2916965B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05271957A (en) | 1993-10-19 |
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