JP2829902B2 - Water-based damping paint composition - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a vibration damping paint used for reducing noise caused by vibration or vibration of various kinds of equipment and structures, such as automobiles, construction machines, home appliances, precision equipment, building structures, and the like. About.

[0001]

2. Description of the Related Art Conventionally, in order to reduce noise due to vibration or vibration of various devices and structures as described above, asphalt-based damping sheets or damping steel sheets,
Various types of damping materials have been used. Also, a so-called damping paint has been used as a paint-type damping material which can be applied to complicated shapes and is easy to construct. This vibration damping paint is obtained by dissolving or dispersing a film forming component such as a resin in an organic solvent or the like, and blending a filler or the like with the coating material. To form a coating film by drying, and absorb vibration of the object to be coated to reduce noise.

Conventionally, organic solvent-based coatings containing an organic solvent as a diluent have been used in many cases, but recently, with the regulation of VOC (volatile organic compounds) related to environmental problems,
Instead of organic solvent-based paints, water-based paints that do not contain organic solvents have attracted attention. For example, Japanese Patent Application Laid-Open No. 1-279981 discloses a water-based coating composition capable of performing thick film coating and exhibiting excellent coating film performance. However, when the present coating composition is used as a vibration damping coating, coating workability,
The storage stability of the paint was not a problem, but the vibration damping properties near room temperature were insufficient. Further, Japanese Patent Application No. 6-66471 discloses a vibration damping coating composition exhibiting excellent film performance and vibration damping properties. And there was a problem in coating workability and storage stability.

[0003]

DISCLOSURE OF THE INVENTION The present invention solves the above problems and has excellent vibration damping properties at around room temperature, and has excellent stability during storage of paint, and excellent paintability such as spray coating and brush coating. The purpose is to propose a water-based damping paint.

[0004]

Means for Solving the Problems As a result of repeated studies to achieve the above object, the present inventors have found that a specific amount of an inorganic filler and a synthetic resin powder are blended in a specific vehicle. As a result, the present inventors have found that a water-based vibration damping paint having excellent coating properties, storage stability, and vibration damping properties and excellent coating film performance such as adhesion to a substrate can be obtained, thereby completing the present invention. That is, in the present invention, the glass transition temperature is -50 to 40 ° C.
Crylate ester copolymer, styrene-acrylic acid ester
Ter copolymer, ethylene-vinyl acetate copolymer alone or
Is a vehicle for two or more synthetic resin emulsions, or
Synthetic resin emulsion and asphalt emulsion
With respect to 100 parts by mass of the solid content of the vehicle blended at a ratio of 5:95 to 95: 5, 50 to 430 parts by mass of an inorganic filler,
And a water-based vibration damping coating composition comprising 10 to 100 parts by mass of a synthetic resin powder. Hereinafter, the present invention will be described in detail.

The vehicle of the present invention comprises:Glass transition temperature is -5
Acrylate copolymer at 0-40 ° C, styrene-
Acrylic ester copolymer, ethylene-vinyl acetate copolymer
A polymer alone or two or more synthetic resin emulsions,
Or the synthetic resin emulsion and asphalt emulsion
Blended in a ratio of 5:95 to 95: 5From
Become. The synthetic resin emulsion that can be used in the present invention is
Of synthetic resin, which is the main component of
It is emulsified and dispersed, and its main component content (solid
The shape component is not particularly limited, but is preferably 30 to 70% by mass.
preferable. In addition, the main components of the above synthetic resin emulsionMinute
Is the adhesion to the substrate, or the chemical and
Aqueous and damping aspectsLapreferable.

Examples of the acrylate copolymer include methyl acrylate, ethyl acrylate, n-propyl acrylate, isopropyl acrylate and n-acrylate.
Copolymers consisting of a combination of two or more of butyl acrylate, isobutyl acrylate, cyclohexyl acrylate, 2-ethylhexyl acrylate, benzyl acrylate, tetracyclododecyl acrylate, norbornyl acrylate, and acrylic acid esters thereof and vinyl toluene , Acrylonitrile, methacrylonitrile, copolymers with other copolymerizable monomers such as vinyl acetate, and preferably two or more of ethyl acrylate, n-butyl acrylate, isobutyl acrylate, and 2-ethylhexyl acrylate. Is a copolymer comprising a combination of Examples of the styrene-acrylate copolymer include a copolymer of styrene and one or more acrylates described above, and a copolymer of styrene and 2-ethylhexyl acrylate is preferred. Here, the glass transition temperature of the synthetic resin which is a main component of the synthetic resin emulsion, -50～40 ° C. der
And preferably -40 to 20 ° C. When the temperature is lower than -50 ° C, the coating film becomes soft at room temperature, and the vibration damping property is reduced, and the tackiness of the coating film surface tends to increase,
If it exceeds 40 ° C., the coating film becomes too hard at room temperature,
This is because there is a tendency that cracks occur during drying.

Further, the vehicle of the present invention may be used in combination with the above synthetic resin emulsion and asphalt in addition to the above synthetic resin emulsion.
Luto emulsion is blended at a ratio of 5:95 to 95: 5.
May be used . The asphalt emulsion that can be used in the present invention is obtained by emulsifying or dispersing petroleum asphalt such as straight asphalt and blown asphalt in water, and the content (solid content) of the main component thereof is not particularly limited, but is 30 to 70. % By mass is preferred. These asphalt emulsions may be used alone or in combination of two or more. When using synthetic resin emulsion and asphalt emulsion together,
A preferred compounding ratio is in the range of 20:80 to 80:20.

Further, the inorganic fillers usable in the present invention include calcium carbonate, barium sulfate, kaolin, clay, talc, mica, diatomaceous earth, alumina, gypsum,
Examples include inorganic fillers such as cement, converter slag powder, shirasu powder, and glass powder, and these may be used alone or in combination of two or more. However, from the viewpoint of vibration damping properties, raw material cost, paint stability, coating film adhesion, etc., calcium carbonate is used alone or a mixture of calcium carbonate and two or more other inorganic fillers is used. Is preferred. The particle size of the inorganic filler is not particularly limited, but if the average particle size is large, the storage stability of the paint and the spray coating property tend to be deteriorated, and if the average particle size is small, the dispersibility of the filler tends to be deteriorated. , The average particle size is usually 0.1 to
It is in the range of 300 μm, preferably in the range of 1 to 150 μm.

The synthetic resin powder usable in the present invention includes alkyd resin, epoxy resin, silicone resin, phenol resin, polyester resin, acrylic resin, acetal resin, polyethylene resin, polyether resin, polycarbonate resin, polystyrene resin, polypropylene Powders such as resin and polyamide resin may be mentioned, and these may be used alone or in combination of two or more. However, it is preferable to use the polyester resin powder alone or as a mixture of two or more of the polyester resin powders and other synthetic resin powders in view of the stability of the paint, the adhesion of the coating film, and the like. As the polyester resin powder, for example, polyethylene terephthalate resin, polypropylene terephthalate resin, polybutylene terephthalate resin, polyhexamethylene terephthalate resin, polycyclohexane 1,4-dimethylol terephthalate resin, and the terephthalic acid or glycol component of these polyester resins Part or all of isophthalic acid, phthalic acid, methyl terephthalic acid, other acid components such as methyl isophthalic acid, or trimethylene glycol, tetramethylene glycol,
Powders such as those replaced with a glycol component such as hexamethylene glycol, diethylene glycol and the like are included. The particle size of the synthetic resin powder is not particularly limited, but if the average particle size is large, the storage stability of the coating and spray coating properties tend to be poor, and if the average particle size is small, the dispersibility tends to be poor. Is usually in the range of 0.1 to 300 μm, preferably in the range of 1 to 150 μm.

The mixing ratio of the water-based damping coating composition according to the present invention is such that acrylic acid having a glass transition temperature of -50 to 40 ° C is used.
Stel copolymer, styrene-acrylate copolymer
Or two or more ethylene-vinyl acetate copolymers
A vehicle for the synthetic resin emulsion of the above, or the synthetic resin
5:95 fat emulsion and asphalt emulsion
The inorganic filler is 50 to 430 parts by mass, preferably 50 to 400 parts by mass, particularly preferably 70 to 300 parts by mass, based on 100 parts by mass of the solid content of the vehicle mixed at a ratio of ~ 95: 5 . The synthetic resin powder is 10 to 100 parts by mass,
Preferably 10 to 60 parts by mass, particularly preferably 20 to 4 parts by mass.
0 parts by mass. If the amount of the inorganic filler and the synthetic resin powder is too large relative to the vehicle, the amount of the vehicle becomes relatively small, and the viscosity of the paint becomes too high, so that spray coating, brush coating and the like cannot be performed, The paintability deteriorates. In addition, not only the adhesion to the object to be coated is reduced, but also the flexibility and strength of the dried coating are reduced, and a good coating cannot be obtained. Conversely, if the amounts of the inorganic filler and the synthetic resin powder are too small, the amount of the coloring agent becomes relatively large, and the vibration damping property is reduced. Also, if the amount of the synthetic resin powder is too small relative to the inorganic filler, the amount of the inorganic filler is relatively large, and the storage stability of the coating is reduced.If the amount is too large, the amount of the inorganic filler is small. However, the damping performance is reduced. Therefore, to form a good dry coating film, storage stability, excellent paintability, and to obtain good vibration damping properties, the amount of the vehicle, inorganic filler, synthetic resin powder is in the above range. I do.

The water-based vibration damping coating composition of the present invention may further contain, if necessary, other additives such as a dispersant, a viscosity modifier, an antifreezing agent, a stabilizer, an anti-skinning agent, a rust inhibitor and a coloring agent. And the like, and if necessary, can be diluted with water or the like.

The water-based vibration damping coating composition of the present invention can be applied by a method known to those skilled in the art, for example, by an ordinary method such as air spraying, airless spraying, brush coating, spatula coating, and roller coating. it can. In this case, if the coating film thickness is too thin, the drying of the coating film is quick, but sufficient vibration damping properties cannot be obtained, and if it is too thick, the vibration damping properties are improved,
Not only takes a long time to dry the coating film, but also a good coating film cannot be obtained, such as sagging or cracking. Therefore, the thickness is preferably about 0.1 to 5 mm, preferably about 0.5 to 3 mm. ing. As a method for drying the coating film, a usual method, for example, natural drying, hot air drying, electric furnace drying, infrared / far infrared drying, etc. can be adopted.

[0013]

Next, the present invention will be described more specifically with reference to examples and comparative examples. The present invention is not limited by these examples. The samples used in the examples and comparative examples are shown below. (1) Acrylic ester copolymer emulsion: Ethyl acrylate, butyl acrylate, copolymer of 2-ethylhexyl acrylate, glass transition temperature: -39
° C, solid content: 57% by mass (2) Styrene-acrylate copolymer emulsion: Copolymer of styrene and 2-ethylhexyl acrylate, glass transition temperature: 20 ° C, solid content: 50% by mass (3 ) Ethylene-vinyl acetate copolymer emulsion: glass transition temperature: 0 ° C., solid content: 55 mass (4) Asphalt emulsion: straight asphalt emulsion, solid content: 57 mass% (5) Calcium carbonate: average particle size 7 μm (6 ) Talc: average particle size 14 μm (7) Polyester resin powder: average particle size 25 μm (8) Polyethylene powder: average particle size 100 μm

The evaluation test of the examples and the comparative examples was performed by the following method. <Adjustment of paint> The components shown in Tables 1 to 7 were mixed at the mixing ratios shown in Tables 1 to 7 to prepare paints, and the performances of these paints were evaluated in the following manner. Are also shown in Tables 1 to 7. <Storage stability> The storage stability of the paint was evaluated by observing the bottom of the paint after treating 100 g of the prepared paint with a centrifugal separator at a rotation speed of 1300 rpm for 30 minutes and easily recovering the fluidity by stirring. The case was judged as pass (○), and the case where the sample could not be recovered was judged as failed (×). <Spray coating property> The spray coating property was evaluated as good (○) when the pattern formation was good in spray coating using an electric diaphragm pump and a good atomization state was obtained, and the pattern formation was poor. A case where a good atomization state was not obtained was regarded as reject (x).

<Adhesion> The adhesion of the coating film was evaluated by applying each coating material to a 0.8 mm thick steel sheet so that the film thickness after drying was 1 mm,
After drying for 10 days in a constant temperature bath of 65% humidity, a test piece was cut into the coating surface in a 10 × 10 grid pattern at intervals of 2 mm with a knife until the base material was reached, and then a cellophane tape was pressed. When all the squares remained on the substrate when the tape was peeled off at once, the test was passed (O), and when even one of the tapes was peeled off, the test was failed (X). <Measurement of Vibration Suppression Performance> The measurement of the vibration suppression performance was performed in a length of 200 m in accordance with the method for testing the vibration damping characteristics of a damping steel sheet specified in JIS G0602.
m, width 25 mm, thickness 0.8 mm, applied to one side of electrodeposited stainless steel plate with a coating so that the film thickness after drying is about 2 mm, and dried at room temperature for vibration damping performance measurement The test piece was evaluated by a loss coefficient measured at 20 ° C. and 1000 Hz by a central excitation half width method. The larger the value of the loss coefficient, the better the vibration damping performance. Paint preparing each component in Examples 1 to 1 3 and Comparative Examples 1-4 Table 1-7 were mixed in proportions shown in Table 1-7, various properties of these paints in the above manner evaluated.

[0016]

[Table 1]

[0017]

[Table 2]

[0018]

[Table 3]

[0019]

[Table 4]

[0020]

[Table 5]

[0021]

[Table 6]

[0022]

[Table 7]

[0023]

According to the water-based vibration damping coating composition of the present invention,
Good damping performance can be obtained at around room temperature, and a damping paint excellent in storage stability of the paint, paintability such as spray coating, brush coating, and adhesion can be obtained.

Continued on the front page (72) Inventor Mitsuru Sato 1134-2, Gondogendo, Satte-shi, Saitama Cosmo Research Institute, Inc. (72) Inventor Takao Kimura 1134-2, Gondogendo, Satte-shi, Saitama Cosmo Sogo (56) References JP-A-6-88055 (JP, A) JP-A-3-277767 (JP, A) JP-A-62-227966 (JP, A) JP-A-55-58262 (JP, A) (58) Fields investigated (Int. Cl. ⁶ , DB name) C09D 101/00-201/10 C08L 1/00-101/14 C08K 3/00-13/08 C09D 5/00- 7/14 F16F 9 / 30,15 / 02

Claims (2)

(57) [Claims] An accelerator having a glass transition temperature of -50 to 40 ° C.
Lylic acid ester copolymer, styrene-acrylic acid ester
Copolymer, ethylene-vinyl acetate copolymer alone or
Two or more synthetic resin emulsions, or before
Synthetic resin emulsion and asphalt emulsion
The solid content of the vehicle is 1 in a ratio of 5:95 to 95: 5.
An aqueous damping coating composition comprising 50 to 430 parts by mass of an inorganic filler and 10 to 100 parts by mass of a synthetic resin powder with respect to 00 parts by mass. 2. The vehicle according to claim 1, wherein the vehicle has a glass transition temperature of -50 to 4.
Styrene-acrylate copolymer at 0 ° C, ethyl
Or vinyl acetate copolymer alone or two or more synthetic resins
Emulsion vehicle or the synthetic resin emulsion
And asphalt emulsion from 5:95 to 95: 5
2. The water-based vibration damper according to claim 1, which is a coloring agent blended at a ratio of:
Paint composition.