JP2776903C - - Google Patents
Info
- Publication number
- JP2776903C JP2776903C JP2776903C JP 2776903 C JP2776903 C JP 2776903C JP 2776903 C JP2776903 C JP 2776903C
- Authority
- JP
- Japan
- Prior art keywords
- transfer layer
- polymer
- weight
- recording medium
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 28
- 229920001577 copolymer Polymers 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 23
- 239000000126 substance Substances 0.000 claims description 13
- 229920001225 Polyester resin Polymers 0.000 claims description 10
- 239000004645 polyester resin Substances 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 229920001169 thermoplastic Polymers 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000806 elastomer Substances 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 6
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 229920001888 polyacrylic acid Polymers 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 238000004040 coloring Methods 0.000 description 16
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- 239000001993 wax Substances 0.000 description 13
- 239000005038 ethylene vinyl acetate Substances 0.000 description 11
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 11
- -1 polyethylene Polymers 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000000049 pigment Substances 0.000 description 7
- 229920005992 thermoplastic resin Polymers 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 241000519995 Stachys sylvatica Species 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000004698 Polyethylene (PE) Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 230000000875 corresponding Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920005680 ethylene-methyl methacrylate copolymer Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 230000004304 visual acuity Effects 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N Palmitic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive Effects 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N butyl 2-methylprop-2-enoate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 238000007757 hot melt coating Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-Dichloroethene Chemical compound ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 description 1
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 1
- PGEHNUUBUQTUJB-UHFFFAOYSA-N Anthanthrone Chemical compound C1=CC=C2C(=O)C3=CC=C4C=CC=C5C(=O)C6=CC=C1C2=C6C3=C54 PGEHNUUBUQTUJB-UHFFFAOYSA-N 0.000 description 1
- RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
- FRLJSGOEGLARCA-UHFFFAOYSA-N Cadmium sulfide Chemical compound [S-2].[Cd+2] FRLJSGOEGLARCA-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N Cetyl alcohol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- NOPFSRXAKWQILS-UHFFFAOYSA-N Docosanol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N Heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- KEMQGTRYUADPNZ-UHFFFAOYSA-N Heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 229920001207 Noryl Polymers 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N Phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920001721 Polyimide Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N Propanamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229960003351 Prussian blue Drugs 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N Stearyl alcohol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N Thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- REZQBEBOWJAQKS-UHFFFAOYSA-N Triacontanol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 1
- DLFVBJFMPXGRIB-UHFFFAOYSA-N acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000012164 animal wax Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium(0) Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229940074979 cetyl palmitate Drugs 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- VOLSCWDWGMWXGO-UHFFFAOYSA-N cyclobuten-1-yl acetate Chemical class CC(=O)OC1=CCC1 VOLSCWDWGMWXGO-UHFFFAOYSA-N 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- VPNOHCYAOXWMAR-UHFFFAOYSA-N docosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCCCN VPNOHCYAOXWMAR-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical compound C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N hexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N palmityl palmitate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- SSZBUIDZHHWXNJ-UHFFFAOYSA-N palmityl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC SSZBUIDZHHWXNJ-UHFFFAOYSA-N 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 229920005670 poly(ethylene-vinyl chloride) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfones) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000011528 polyamide (building material) Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 239000012176 shellac wax Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N stearylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- KMEHEQFDWWYZIO-UHFFFAOYSA-N triacontyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC KMEHEQFDWWYZIO-UHFFFAOYSA-N 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Description
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ãæããé«æ§èœã®æç±è»¢åèšé²åªäœãæäŸããããšãã§ãããDescription: BACKGROUND OF THE INVENTION The present invention relates to a thermal transfer recording medium. More specifically, the present invention relates to a thermal transfer recording medium. The present invention relates to a heat-sensitive transfer recording medium which has a low glossiness, can provide a legible printed image, has excellent confidentiality, generates few voids, and has a high resolution. [Related Art and Problems to be Solved by the Invention] In recent years, by adopting a thermal transfer recording method for a facsimile, storage stability of a recorded image is improved as compared with a thermal coloring method used for a conventional facsimile. At the same time, attempts have been made to enable printing on plain paper. However, a printed image obtained from a conventional thermal transfer recording medium has a problem that the glossiness of the surface is high and it is difficult to read. Therefore, for example, by providing a mat layer containing a resin and a matting pigment between the support and the ink layer, a thermal transfer recording medium for removing gloss of a printed image, a support and an ink layer There has been proposed a thermal transfer recording medium or the like in which an anchor layer that forms fine irregularities is provided on the peeled surface of the ink layer to remove gloss of a printed image. However, in these thermal transfer recording media, the glossiness of the printed image is removed, but when used in a high-temperature environment such as a facsimile machine where the power is on all day and heat is easily stored, for example, as shown in FIG. Thermal transfer recording medium,
Since the ink layer A containing the heat-fusible substance is easily separated inside the ink layer, separation at the interface C with the mat layer (or anchor layer) B, which is the intended separation surface of the ink layer A, is prevented. As a result, there is a problem that the film thickness of the ink layer A transferred onto the transfer receiving medium becomes thin and the print density decreases. In addition, in FIG. 2, D is a support. Further, in the conventional thermal transfer recording medium, after the ink layer has been transferred to the transfer receiving body, a so-called white spot that is readable and corresponding to the shape of the printed image occurs, so that the problem of poor confidentiality is caused. is there. Further, in general, in order to improve the quality of a printed image formed by a thermal transfer recording medium and obtain a clear printed image, it is desired that the generation of voids be small and the resolving power be high. The present invention has been made based on the above circumstances. An object of the present invention is to provide a printed image in which the density does not decrease even in a high-temperature environment, and the glossiness of the surface is low and the legibility is easy to read.
In addition, it is an object of the present invention to provide a thermal transfer recording medium which is free from voids and has high resolution. [Means for Solving the Problems] In order to solve the above problems, as a result of intensive studies by the present inventors, a specific non-transfer layer containing a specific substance is provided between the support and the transfer layer. In the specific thermal transfer recording medium provided, surprisingly, even in a high-temperature environment, the transfer layer peels off due to cohesive failure near the interface with the non-transfer layer in the transfer layer, so that the density does not decrease, Further, the present inventors have found that a printed image having a low glossiness on the surface and which is easy to read can be obtained, excellent in confidentiality, little occurrence of voids, and high in resolving power. The structure of the invention according to claim 1 has a non-transfer layer containing a thermoplastic polymer and a color material between a support and a transfer layer containing a heat-fusible substance and a color material, and the non-transfer layer. Wherein the thermoplastic polymer is a mixture of at least one member selected from the following group A and at least one member selected from the following B group. [Group A] α-olefin polymer, α-olefin-maleic anhydride copolymer, α-olefin-alkyl (meth) acrylate copolymer, α-olefin-vinyl acetate copolymer, α-olefin (meth) Acrylic acid copolymer, vinyl acetate polymer, alkyl (meth) acrylate polymer, (meth) acrylic acid polymer, styrene elastomer. [Group B] Polyester resin, polyurethane resin, polyvinyl chloride. Hereinafter, the thermal transfer recording medium of the present invention will be described in detail for a support, a non-transfer layer, a transfer layer, and the like. âSupportâ The support in the thermal transfer recording medium of the present invention preferably has good heat resistance and high dimensional stability. Examples of the material include papers such as plain paper, condenser paper, laminated paper, and coated paper; resin films such as polyethylene, polyethylene terephthalate, polystyrene, polypropylene, and polyimide; composites of paper and resin film; and aluminum foil. Any of metal sheets and the like are suitably used. The thickness of the support is usually 30 ÎŒm or less, preferably 2 to 6 ÎŒm.
When the thickness of the support exceeds 30 ÎŒm, the thermal conductivity is deteriorated, and the print quality may be deteriorated. In the thermal transfer recording medium of the present invention, the configuration on the back side of the support is arbitrary, and for example, a backing layer such as an anti-sticking layer may be provided. âNon-Transfer Layerâ One of the important points in the present invention is that at least one selected from the group A and at least one selected from the group B between the support and the transfer layer described in detail below. It is to have a non-transfer layer containing a mixture with one kind. By providing the non-transfer layer, in the thermal transfer recording medium of the present invention, when the transfer layer to be described in detail below is separated from the support side, the transfer layer is stable near the interface between the non-transfer layer and the transfer layer even in a high temperature environment. It is possible to form a clear printed image that is easy to read because it has high density and low glossiness on the surface while achieving high density. More specifically, even in a high-temperature environment, stable cohesive failure peeling is realized near the interface between the non-transfer layer and the transfer layer, so that the transfer layer moves to the medium to be transferred at a predetermined thickness and the density does not decrease, By forming fine irregularities on the transfer layer where the transfer layer is peeled off, that is, on the surface of the print image, a print image with low glossiness on the surface can be formed. In addition, the non-transfer layer remains on the support even after the transfer layer has been transferred to the medium to be transferred, and contains a coloring material, so that the occurrence of the so-called white spots described above is prevented,
The thermal transfer recording medium of the present invention has excellent confidentiality. Such an action or function of the non-transfer layer is mainly brought about by the thermoplastic polymer and the coloring material contained in the non-transfer layer. A thermoplastic polymer selected from the group A described above [hereinafter, this may be referred to as a polymer (I). ] And a thermoplastic polymer selected from the aforementioned group B [hereinafter, this may be referred to as a polymer (II). The above polymer in a mixture with
The ratio of each of I) and the polymer (II) is such that the polymer (I) is usually 3 to 80% by weight, preferably 3 to 50% by weight, and the polymer (II) is usually 3 to 50% by weight. It is 80% by weight, preferably 20-60% by weight. If the proportion of the polymer (I) in the mixture is less than 3% by weight, the adhesive strength between the non-transfer layer and the transfer layer may be reduced, which may make the mixture unsuitable for practical use. On the other hand, when the proportion of the polymer (II) in the mixture is less than 3% by weight, the adhesive force between the non-transfer layer and the support is reduced, and even after the transfer layer is transferred to the transfer medium. The non-transfer layer to be left on the support may peel off from the support. In any case, if the ratio of each of the polymer (I) and the polymer (II) is out of the above range, the effect of the present invention may not be sufficiently exerted. The polymer (I) has a melt index (MI value) of usually from 1 to 3,000.
0, preferably a compound in the range of 5 to 1,000, specifically, an α-olefin polymer, α-olefin-maleic anhydride copolymer, α
-Olefin-alkyl (meth) acrylate copolymer, α-olefin-vinyl acetate copolymer, α-olefin (meth) acrylic acid copolymer, vinyl acetate polymer, alkyl (meth) acrylate polymer, (meth) It is preferably at least one of an acrylic acid polymer and a styrene-based elastomer. More specifically, α-olefin polymers such as ethylene polymer and propylene polymer; maleic anhydride-modified ethylene-vinyl acetate copolymer (maleic anhydride-modified)
Î-olefin-maleic anhydride copolymer such as EVA); α-olefin-alkyl (meth) acrylate copolymer such as ethylene-ethyl acrylate copolymer (EEA) and ethylene-methyl methacrylate copolymer (EMMA) Î-olefin-vinyl acetate copolymer such as ethylene-vinyl acetate copolymer (EVA); vinyl acetate polymer; alkyl (meth) such as methyl methacrylate (MMA) polymer and butyl methacrylate (BMA) polymer. A) acrylate polymers; acrylic acid (AA) polymers, methacrylic acid (MAA) polymers; and polystyrene, styrene-acryl copolymers, polybutadiene-styrene copolymers, polyisoprene-styrene copolymers, polyolefin-styrene copolymers. At least one selected from styrene-based elastomers such as coalescing is preferred. Among the compounds selected from Group A, preferred are ethylene-vinyl acetate copolymer (EVA), ethylene ethyl acrylate, and styrene-based elastomer, and particularly preferred is styrene-based elastomer. The polymer (II) is a compound having a number average molecular weight in the range of usually 1,000 to 100,000, preferably 2,000 to 50,000, and specifically, a polyester resin, a polyurethane resin and a polyether selected from the group B. It is preferably one of vinyl chloride. Among these, polyester resins are preferred. Preferred examples of the combination of the polymer (I) and the polymer (II) contained in the non-transfer layer include, for example, a combination of an ethylene-vinyl acetate copolymer and a polyester resin. The content of the mixture of the polymer (I) and the polymer (II) in the non-transfer layer is 10% by weight or more, preferably 20 to 80% by weight. The non-transfer layer contains the coloring material together with the thermoplastic polymer. The coloring material has an effect of preventing the above-mentioned so-called white spots from occurring after the transfer layer is transferred to the transfer medium. Therefore, it is preferable that the color of the color material contained in the transfer layer is the same as the color of the color material in the transfer layer described in detail below. As the coloring material, those similar to the coloring material in the thermosoftening coloring material layer described in detail below can be suitably used. The content of the coloring material in the non-transfer layer is usually 80% by weight or less, preferably 10 to
60% by weight. The non-transfer layer may contain a heat-fusible substance together with the thermoplastic polymer and the coloring material. As the heat-fusible substance, the same heat-fusible substance that can be contained in the transfer layer described in detail below can be suitably used. The content of the heat-fusible substance when the non-transfer layer contains the heat-fusible substance,
Usually, it is 50% by weight or less, preferably 2 to 50% by weight. The non-transfer layer containing the above components can be coated on the support by a coating method such as an aqueous coating method, a coating method using an organic solvent, or a hot melt coating method. The layer thickness of the non-transfer layer is usually in the range of 0.3 to 5 ÎŒm, preferably 0.2 to 2 ÎŒm.
m. By setting this layer thickness within the above range, the object of the present invention can be sufficiently achieved. On this non-transfer layer, a transfer layer described below is laminated adjacent thereto. âTransfer Layerâ The transfer layer contains a heat-fusible substance and a coloring material. Examples of the heat-fusible substance include vegetable waxes such as carnauba wax, wood wax, ouriculi wax and espar wax; animal waxes such as beeswax, insect wax, shellac wax and spermaceti; paraffin wax, microcrystal wax, polyethylene wax, ester Petroleum waxes such as waxes and acid waxes; and waxes such as mineral waxes such as montan wax, ozokerite and ceresin. In addition to these waxes, palmitic acid, stearic acid, margaric acid and behen Higher fatty acids such as acids; palmityl alcohol;
Higher alcohols such as stearyl alcohol, behenyl alcohol, marganyl alcohol, myricyl alcohol and eicosanol; higher fatty acid esters such as cetyl palmitate, myricyl palmitate, cetyl stearate and myricyl stearate; acetamide, propionamide, palmitamide, Amides such as stearic acid amide and amide wax; and higher amines such as stearylamine, behenylamine and palmitylamine. These may be used alone or in combination of two or more. Among these, preferred are those having a melting point of 50 to 120 measured using a Yanagimoto MJP-2 type.
Wax in the range of ° C. The content of the heat-fusible substance in the transfer layer is usually preferably in the range of 30 to 90% by weight or less. Examples of the coloring material include pigments such as inorganic pigments and organic pigments, and dyes. Examples of the inorganic pigment include titanium dioxide, carbon black, zinc oxide, Prussian blue, cadmium sulfide, iron oxide, and chromates of lead, zinc, barium, and calcium. Examples of the organic pigment include azo-based, thioindigo-based, anthraquinone-based, anthranthrone-based, and triphenedioxazine-based pigments, vat dye pigments, phthalocyanine pigments such as copper phthalocyanine and its derivatives, and quinacridone pigments. Examples of the organic dye include an acid dye, a direct dye, a disperse dye, an oil-soluble dye, and a metal-containing oil-soluble dye. Among these various coloring materials, carbon black is particularly preferred. The content of the coloring material in the transfer layer is usually in the range of 5 to 30% by weight, preferably in the range of 10 to 25% by weight. The transfer layer may further contain a thermoplastic resin together with the hot-melt substance and the coloring material. When the thermoplastic resin is contained, the cohesive force in the transfer layer can be easily adjusted. Examples of the thermoplastic resin include polyethylene and its copolymer resin, polypropylene resin, polystyrene and its copolymer resin, methyl methacrylate resin, vinyl chloride resin and its copolymer resin, vinylidene chloride resin, vinyl acetate resin, and cellulose resin. Resins, ionomer resins, polyamide resins, polyethers, polycarbonates, polyester resins, polyphenylene oxide and noryl resins, polysulfones, fluorine resins, silicone resins, and the like. These may be used alone or in combination of two or more. Among the thermoplastic resins, preferred is an ethylene copolymer. Examples of the ethylene copolymer include an ethylene-vinyl acetate copolymer, an ethylene-ethyl acrylate copolymer, an ethylene-methyl methacrylate copolymer,
Examples include ethylene-isobutyl acrylate copolymer, ethylene-acrylic acid copolymer, ethylene-vinyl alcohol copolymer, ethylene-vinyl chloride copolymer, and ethylene-acrylate metal salt copolymer. When the thermoplastic resin is used, the content of the thermoplastic resin component in the transfer layer is usually 50% by weight or less, and preferably 40% by weight or less. Further, the transfer layer may contain, in addition to the above components, a surfactant such as a compound containing a polyoxyethylene chain. The transfer layer may further contain inorganic or organic fine particles (metal powder, silica gel, etc.) and oils (linseed oil, mineral oil, etc.). The transfer layer can be coated on the non-transfer layer by using a coating method such as an aqueous coating method or a coating method using an organic solvent. The thickness of the transfer layer is usually in the range of 0.5 to 8 ÎŒm, preferably 1.5 to 6.
It is in the range of 0 ÎŒm. -Others- The heat-sensitive transfer recording medium of the present invention is usually prepared by applying the non-transfer layer and the transfer layer on the support in this order, and then optionally through a drying step, a surface smoothing step, and the like. It can be manufactured by cutting into the shape of. The thermal transfer recording medium thus obtained can be used in the form of a wide tape or a typewriter ribbon generally used for a line printer or the like, but the planar shape of the thermal transfer recording medium of the present invention can be used. Preferred is a sheet having substantially the same width as the recording paper used in the line printer. Although the thermal transfer method using the thermal transfer recording medium of the present invention is not different from the normal thermal transfer recording method, a case where a most typical thermal head is used as a heat source will be described as an example. First, the transfer layer of the thermal transfer recording medium and the medium to be transferred, such as plain paper, are brought into close contact with each other, and a heat pulse is applied by a thermal head to locally heat the heat-softening color material layer corresponding to a desired printing or transfer pattern. I do. The temperature of the heated portion of the transfer layer rises, for example, as shown in FIG. 1 (a), the transfer layer 1 softens quickly and peels off from the vicinity of the interface with the non-transfer layer 2 due to cohesive failure. Is transferred onto the transfer-receiving medium. After the transfer layer 1 is transferred, the first
As shown in FIG. 2B, the non-transfer layer 2 remains on the support 3. [Examples] Next, examples of the present invention and comparative examples are shown, and the present invention will be described more specifically. (Example 1) Solvent coating using a wire bar on a 4.5 ÎŒm-thick polyethylene terephthalate film with the following non-transfer layer composition over a length corresponding to the width of JIS A4 paper so as to have a layer thickness of 1 ÎŒm. The non-transferable layer was formed on the thermal transfer recording medium of the present invention by a coating method. Non-transfer layer composition Ethylene-vinyl acetate copolymer (vinyl acetate content 28% by weight) 20% by weight Polyester resin 60% by weight ["Vylon 200" manufactured by Toyobo Co., Ltd.] Carbon black 20 Next, the following heat-softening colorant layer composition was coated on the non-transfer layer by a hot melt coating method using gravure so as to have a thickness of 4 ÎŒm to form a transfer layer. A thermal transfer recording medium was obtained. Transfer layer composition Carbon black: 20% by weight Ethylene-vinyl acetate copolymer: 10% by weight Paraffin wax: 50% by weight Oxidized wax: 20% by weight The obtained thermal transfer recording medium is transferred to a thermal printer (260 mm width). Line head, 180D
PI (platen rubber hardness: 40 degrees) was recorded (printed) on plain paper (Beck smoothness: 20 seconds), and the gloss, resolution, voids and density of the printed image were evaluated. The results are shown in Table 1. The glossiness, resolution, void, density reduction, and confidentiality of the printed image were evaluated as follows. Glossiness: Using a glossmeter, measure the glossiness of the printed image under the condition that both the incident angle and the reflection angle are 60 °.
15 or more was evaluated as x. Resolving power: ã± ã€: no blurring was observed by visually observing the blur of the 1-dot key line, â: slight blurring was observed, and x: blurred. Void: Observed visually. Density reduction: Printing is performed under the conditions of a machine temperature of 40 ° C.
The above was evaluated as â. Confidentiality: The prints after printing were visually observed by reflected light, and those with some missing were rated as x, and those without any missing were rated as o. (Example 2) In the same manner as in Example 1, except that the following non-transfer layer composition was used in place of the non-transfer layer composition used in Example 1, the following non-transfer layer composition was used. did. The results are shown in Table 1. Non-transfer layer composition Styrene-butadiene-styrene copolymer ["Clayton G1300" manufactured by Shell Chemical Co.] ... 10% by weight polyester resin ... 80% by weight ["UE3600"; manufactured by Unitika Ltd.] Carbon black ... ... 10% by weight (Comparative Example 1) Same as Example 1 except that the following non-transfer layer composition was used in place of the non-transfer layer composition used in Example 1 Then, a non-transfer layer and a transfer layer were laminated on the support in this order to produce a thermal transfer recording medium, and the thermal transfer recording medium was evaluated. The results are shown in Table 1. Non-transfer layer composition Ethylene-vinyl acetate copolymer 80% by weight (vinyl acetate content 28% by weight) Carbon black 20% by weight (Comparative Example 2) Used in Example 1 in Example 1 A non-transfer layer and a transfer layer were laminated in this order on a support in the same manner as in Example 1 except that the following non-transfer layer composition was used instead of the non-transfer layer composition described above. A thermal transfer recording medium was manufactured, and the thermal transfer recording medium was evaluated. The results are shown in Table 1. Non-transfer layer composition Polyester resin 80% by weight [Byron 200; manufactured by Toyobo Co., Ltd.] Carbon black 20% by weight (Comparative Example 3) In Example 1, used in Example 1 A non-transfer layer and a transfer layer were laminated in this order on a support in the same manner as in Example 1 except that the following non-transfer layer composition was used instead of the non-transfer layer composition described above. A thermal transfer recording medium was manufactured, and the thermal transfer recording medium was evaluated. The results are shown in Table 1. Non-transfer layer composition Polyester resin 60% by weight Carbon black 20% by weight Fluororesin particles (average particle diameter 0.3Ï) 20% by weight (Evaluation) As is evident from Table 1, the thermal transfer recording medium of the present invention has no reduction in density even in a high-temperature environment, has excellent confidentiality, has high resolution, and has little voids. It was confirmed that a high quality printed image could be formed. [Effects of the Invention] According to the present invention, (1) Since the non-transfer layer between the support and the transfer layer contains a specific compound, it is always transferred even in a high-temperature environment such as a line printer of a facsimile machine. The transfer layer peels off due to stable cohesive destruction occurring near the interface between the layer and the non-transfer layer, so that there is no decrease in density and the printed image has low gloss on the surface of the printed image and is easy to read. (2) After the transfer layer is transferred onto the medium to be transferred, the non-transfer layer remaining on the support contains a coloring material, so that a readable so-called white spot may occur. Without
(3) It is possible to provide a high-performance thermal transfer recording medium having various advantages such as (3) high resolution and low occurrence of voids.
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ïŒâŠâŠè»¢åå±€ãïŒâŠâŠé転åå±€ãïŒâŠâŠæ¯æäœBRIEF DESCRIPTION OF THE DRAWINGS FIGS. 1 (a) and 1 (b) are cross-sectional views showing the relationship between a transfer layer and a non-transfer layer in a thermal transfer recording medium of the present invention, and FIG. FIG. 2 is an explanatory cross-sectional view illustrating an example of the thermal transfer recording medium of FIG. 1 ... transfer layer, 2 ... non-transfer layer, 3 ... support
Claims (1)
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ã©ã¹ãããŒã 矀 ããªãšã¹ãã«æš¹èãããªãŠã¬ã¿ã³æš¹èãããªå¡©åããã«ãClaims (1) A non-transfer layer containing a thermoplastic polymer and a color material is provided between a support and a transfer layer containing a heat-fusible substance and a color material, and the non-transfer layer is Wherein the thermoplastic polymer is a mixture of at least one selected from the following group A and at least one selected from the following group B. [Group A] α-olefin polymer, α-olefin-maleic anhydride copolymer, α-olefin-alkyl (meth) acrylate copolymer, α-olefin-vinyl acetate copolymer, α-olefin- (meth ) Acrylic acid copolymers, vinyl acetate polymers, alkyl (meth) acrylate polymers, (meth) acrylic acid polymers, styrene elastomers. [Group B] Polyester resin, polyurethane resin, polyvinyl chloride.
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