JP2694631B2 - High temperature exhaust gas forced rapid cooling device - Google Patents

High temperature exhaust gas forced rapid cooling device

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Publication number
JP2694631B2
JP2694631B2 JP6011792A JP1179294A JP2694631B2 JP 2694631 B2 JP2694631 B2 JP 2694631B2 JP 6011792 A JP6011792 A JP 6011792A JP 1179294 A JP1179294 A JP 1179294A JP 2694631 B2 JP2694631 B2 JP 2694631B2
Authority
JP
Japan
Prior art keywords
cooling
exhaust gas
gas
pressure water
temperature exhaust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP6011792A
Other languages
Japanese (ja)
Other versions
JPH07213849A (en
Inventor
哲人 田村
Original Assignee
株式会社タステム
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社タステム filed Critical 株式会社タステム
Priority to JP6011792A priority Critical patent/JP2694631B2/en
Publication of JPH07213849A publication Critical patent/JPH07213849A/en
Application granted granted Critical
Publication of JP2694631B2 publication Critical patent/JP2694631B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Chimneys And Flues (AREA)
  • Incineration Of Waste (AREA)
  • Treating Waste Gases (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、熱媒等として従来使用
されていた有害物質PCB(ポリ塩化ビフェニール)の
廃棄による地球環境の汚染を防止するためのPCB廃棄
処理工程におけるPCBガス焼却炉からの高温排ガスの
強制急速冷却装置に関するものである。
BACKGROUND OF THE INVENTION The present invention relates to a PCB gas incinerator in a PCB disposal process for preventing pollution of the global environment due to disposal of a harmful substance PCB (polychlorinated biphenyl) which has been conventionally used as a heat medium or the like. The present invention relates to a forced rapid cooling device for high temperature exhaust gas.

【0002】[0002]

【従来の技術】従来、例えば大形のトランスや高圧コン
デンサ等の機器に含まれる汚染物質PCBを廃棄焼却処
理する方法としては、我が国にあっては燃焼温度1,1
50℃、滞溜時間2秒、過剰酸素3%でテストを行い分
解効率が99.9999%すなわち、6−ナインが確認
されることが方法実施のための必要最低限の条件であっ
た。
2. Description of the Related Art Conventionally, as a method of discarding and incinerating a contaminant PCB contained in a device such as a large transformer or a high-voltage capacitor, a combustion temperature of 1,1 is used in Japan.
A test was performed at 50 ° C., a residence time of 2 seconds, and excess oxygen of 3%, and the decomposition efficiency was 99.9999%, that is, 6-nine was confirmed.

【0003】これらの条件を比較的小型の装置で、効率
的に処理を達成するために、例えば、本願発明と同一発
明者によりPCB廃油燃焼処理方法(特願平5−241
419号)及びこの方法に関連する廃油燃焼装置(特願
平5−229067号)等が提案開示されている。
[0003] In order to achieve these conditions efficiently with a relatively small apparatus, for example, a PCB waste oil combustion treatment method (Japanese Patent Application No. 5-241) has been proposed by the same inventor as the present invention.
No. 419) and a waste oil combustion apparatus related to this method (Japanese Patent Application No. 5-229067).

【0004】[0004]

【発明が解決しようとする課題】しかしながら、以上の
ような従来の提案例にあっては、PCBガスの焼却によ
り排出される燃焼ガスは、1,400℃以上、例えば
1,800℃の高温で燃焼分解させるために、この焼却
炉からの排ガス温度は1,600℃以上のガスが排出さ
れ、これが冷却するとき、温度範囲700〜200℃に
おいて有害物質ダイオキシンが発生する。このため別個
にダイオキシン除去手段を講ずる必要がある。
However, in the above-mentioned conventional proposals, the combustion gas discharged by the incineration of PCB gas is at a high temperature of 1,400 ° C. or higher, for example, 1,800 ° C. In order to combust and decompose, a gas having an exhaust gas temperature of 1,600 ° C. or higher is discharged from the incinerator, and when cooled, dioxin harmful substances are generated in a temperature range of 700 to 200 ° C. Therefore, it is necessary to take a separate dioxin removing means.

【0005】本発明は、以上のような局面にかんがみて
なされたもので、上記のような高温の排ガスを強制急速
冷却することにより、ダイオキシンの化学反応時間であ
る1/10秒以内に、ガス温度を200℃以下とするこ
とにより、ダイオキシンの発生を抑制するための強制急
速冷却装置構成の提供を目的としている。
The present invention has been made in view of the above situation, and by forcedly rapidly cooling the high-temperature exhaust gas as described above, the gas can be discharged within 1/10 seconds which is the chemical reaction time of dioxin. It is an object of the present invention to provide a forced rapid cooling device configuration for suppressing the generation of dioxins by controlling the temperature to 200 ° C or lower.

【0006】[0006]

【課題を解決するための手段】このため、本発明におい
ては、この種の高温排ガス強制急速冷却装置を、PCB
ガス焼却炉からの1600℃以上の高温排ガスを急速に
冷却するための装置であって、一次及び二次の各冷却手
段より成り、前記一次冷却手段は、前記高温排ガスを導
入して冷却水内を通過させるためのガイド手段と、この
通過ガスの温度を、1/10秒以内に200℃以下に冷
却するための第一の高圧水スプレー手段と、この冷却済
みガスを排出するための出口手段とを有すると共に、前
記二次冷却手段は、冷却水コイル管と、このコイル管を
冷却するための第二の高圧水スプレー手段と、前記一次
冷却手段の冷却水を前記冷却水コイル管内に供給するた
めの高圧水ポンプと、前記コイル管内の冷却済み高圧水
を前記一次冷却手段の第一の高圧水スプレー手段に供給
するための高圧送水管とを有するよう構成することによ
り、前記目的を達成しようとするものである。
Therefore, in the present invention, a high temperature exhaust gas forced rapid cooling device of this type is provided in a PCB.
A device for rapidly cooling high-temperature exhaust gas of 1600 ° C. or higher from a gas incinerator, which comprises primary and secondary cooling means, and the primary cooling means introduces the high-temperature exhaust gas into cooling water. Means for passing the gas, a first high-pressure water spray means for cooling the temperature of the passing gas to 200 ° C. or less within 1/10 seconds, and an outlet means for discharging the cooled gas. And the secondary cooling means supplies a cooling water coil tube, a second high-pressure water spray means for cooling the coil tube, and cooling water of the primary cooling means into the cooling water coil tube. The object is achieved by comprising a high-pressure water pump for supplying the high-pressure water in the coil tube and a high-pressure water pipe for supplying the high-pressure water in the coil tube to the first high-pressure water spray means of the primary cooling means. It is what you are trying to achieve.

【0007】[0007]

【作用】以上のような本発明装置により、廃PCB液の
PCBガス焼却炉からの高温排ガスの温度を、ダイオキ
シンを発生する化学反応温度範囲700〜200℃以下
にその反応所要時間1/10秒以内で強制急速冷却する
ことにより、ダイオキシンを発生させることなく、次の
有害物質除去工程に移して無公害大気排出を実現するこ
とができる。
With the apparatus of the present invention as described above, the temperature of the high temperature exhaust gas from the PCB gas incinerator of the waste PCB liquid is controlled within the chemical reaction temperature range of 700 to 200 ° C. for generating dioxins, and the reaction time is 1/10 seconds. By forcibly and rapidly cooling it within the range, it is possible to move to the next step of removing harmful substances and realize pollution-free atmospheric emission without generating dioxin.

【0008】[0008]

【実施例】以下に本発明を実施例に基づいて説明する。
図1に、本発明に係るPCBガス焼却炉からの高温排ガ
スの強制急速冷却装置の一実施例の概要構成のフロー線
図を示す。この冷却装置は、一次及び二次冷却塔1,9
より成る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below based on embodiments.
FIG. 1 shows a flow diagram of a schematic configuration of an embodiment of a forced rapid cooling device for hot exhaust gas from a PCB gas incinerator according to the present invention. This cooling system consists of primary and secondary cooling towers 1, 9
Consisting of

【0009】1は一次ガス冷却塔で、前工程の1,80
0℃の高温で燃焼分解させる廃PCBガス焼却炉からの
1,600℃以上の高温排ガス2がダクトより導入され
る。これらの排ガス2が冷却するとき、700〜200
℃の温度範囲の間でダイオキシンが発生するので、その
発生の化学反応時間1/10秒以内に200℃以下に急
速冷却しようとするものである。図2は、この一次ガス
冷却塔1の具体的構成の一断面図例である。
Numeral 1 is a primary gas cooling tower, which is 1,80 in the previous step.
High-temperature exhaust gas 2 of 1,600 ° C. or higher from a waste PCB gas incinerator, which is decomposed by combustion at a high temperature of 0 ° C., is introduced from a duct. When these exhaust gas 2 cools, 700-200
Since dioxin is generated in the temperature range of ° C, it is intended to rapidly cool it to 200 ° C or lower within the chemical reaction time of 1/10 seconds of the generation. FIG. 2 is an example of a cross-sectional view of a specific configuration of the primary gas cooling tower 1.

【0010】図1,2において、3は高温排ガス室で、
高温排ガス2は、塔1の頂部の冷却済ガス出口4から静
圧−500mmで吸引するよう構成されている。5aは塔
1底部に溜められた冷却水5のガイド弁、6は遮弊板、
7は高圧送水管、8は第一の高圧水スプレー装置、12
は高圧水ポンプ、13は、フロート弁13aを有する水
位調整タンク、15は、塔1内の残留蒸気と塵とを除く
ためのデミスタ兼セパレータである。
In FIGS. 1 and 2, 3 is a high temperature exhaust gas chamber,
The hot exhaust gas 2 is configured to be sucked from the cooled gas outlet 4 at the top of the tower 1 at a static pressure of -500 mm. 5a is a guide valve for the cooling water 5 stored at the bottom of the tower 1, 6 is an obstruction plate,
7 is a high-pressure water pipe, 8 is a first high-pressure water spray device, 12
Is a high-pressure water pump, 13 is a water level adjusting tank having a float valve 13a, and 15 is a demister / separator for removing residual vapor and dust in the tower 1.

【0011】また、二次冷却塔9は、塔内に冷却水コイ
ル管9aを有し、この冷却水コイル管9aには、一次冷
却塔1底部の冷却水5を高圧水ポンプ12により下方か
ら圧送し、管の上端部から前記高圧送水管7を通じて一
次冷却塔内の高圧水スプレー装置8に導いている。10
は高圧スプレー装置8の上方から下方に向けて通風する
ための送風機である。
Further, the secondary cooling tower 9 has a cooling water coil tube 9a in the tower, and the cooling water 5 at the bottom of the primary cooling tower 1 is supplied to the cooling water coil tube 9a from below by a high-pressure water pump 12. It is pressure-fed and guided from the upper end of the pipe to the high-pressure water spray device 8 in the primary cooling tower through the high-pressure water feed pipe 7. 10
Is a blower for ventilating the high-pressure spray device 8 from above to below.

【0012】二次冷却塔9内の冷却コイル管9a内の水
は、底部の冷却水16(14はそのフロート弁14a付
き水位調整タンク)を高圧水ポンプ11で導かれた高圧
スプレー装置17により冷却されて、高圧送水管7を通
じて一次冷却塔1内の第二の高圧スプレー装置8に導か
れて、冷却水5内を通過した高温ガス2を急速冷却させ
る。
The water in the cooling coil tube 9a in the secondary cooling tower 9 is supplied by a high pressure spray device 17 in which the bottom cooling water 16 (14 is a water level adjusting tank with its float valve 14a) is guided by a high pressure water pump 11. The high-temperature gas 2 that has been cooled and guided to the second high-pressure spray device 8 in the primary cooling tower 1 through the high-pressure water supply pipe 7 and has passed through the cooling water 5 is rapidly cooled.

【0013】以上のように、一次冷却塔1内では、高温
排ガス2の急速冷却により、ガスの高熱を水蒸気に変
え、蒸発熱でガス熱を奪っているため、莫大な水蒸気が
発生する。これを抑制するため、上方からこれらの水蒸
気を高圧水スプレー8を下方に叩き付けて水蒸気温度を
低下させ、同塔1内でガスの冷却と水蒸気の冷却とを行
う。塔1内は密閉されており、排ガスならびに水蒸気の
いずれも外部への漏れを生じないよう密閉処理を行って
いる。
As described above, in the primary cooling tower 1, since the high temperature exhaust gas 2 is rapidly cooled, the high heat of the gas is converted into steam, and the heat of vaporization removes the gas heat, so that a huge amount of steam is generated. In order to suppress this, the high-pressure water spray 8 is tapped downward from above to lower the temperature of the steam, and the gas and the steam are cooled in the tower 1. The inside of the tower 1 is sealed, and a sealing process is performed so that neither the exhaust gas nor the steam leaks to the outside.

【0014】上記動作を要約すると、冷却済ガス出口4
より−500mmの静圧で一次冷却塔1のガス室3内に引
込まれた1,600℃の高温排ガス2は、遮弊板6の下
を冷却水5の中を潜り抜け、ガイド弁5aを通って出口
4へ進もうとする。この時、水5と高温排ガス2とが接
触し、発生した大量の水蒸気を、高圧送水管7(管内の
冷却水はここでは50℃以下である)からの高圧水スプ
レー8を、高熱化された水蒸気に吹付けて急速冷却する
もので、このスプレー8の水量は、ガス1m3に対して
例えば33l/s、即ち、1秒間に33lを33m3
ガスに吹付けるように構成され、その水の速度は16m
/sである。
To summarize the above operation, the cooled gas outlet 4
The high-temperature exhaust gas 2 of 1,600 ° C. drawn into the gas chamber 3 of the primary cooling tower 1 with a static pressure of −500 mm passes through the cooling water 5 under the obstruction plate 6 and passes through the guide valve 5a. Attempt to pass through Exit 4. At this time, the water 5 and the high-temperature exhaust gas 2 come into contact with each other, and a large amount of steam generated is highly heated by the high-pressure water spray 8 from the high-pressure water pipe 7 (cooling water in the pipe is 50 ° C. or lower here). and by blowing the steam intended to rapid cooling, water of the spray 8, for example, 33l / s with respect to the gas 1 m 3, that is, is configured to 33l per second as blowing the gas of 33m 3, the The speed of water is 16m
/ S.

【0015】高圧送水管7中の冷却水は二次冷却塔9の
中で、高圧水ポンプ11により循環されており、冷却塔
9は冷却水コイル管9aでこの冷却水を50℃以下に冷
却している。また塔底部の水16は、高圧水ポンプ11
により、高圧スプレー17に送られ、ここから噴出され
る高圧のスプレー水は大形送風機10により周囲大気と
熱交換を行うように構成されている。
The cooling water in the high-pressure water supply pipe 7 is circulated in the secondary cooling tower 9 by the high-pressure water pump 11, and the cooling tower 9 cools this cooling water to 50 ° C. or less by the cooling water coil pipe 9a. doing. The water 16 at the bottom of the tower is supplied to the high-pressure water pump 11.
Thus, the high-pressure spray water sent to the high-pressure spray 17 and ejected from the high-pressure spray 17 is configured to exchange heat with the surrounding atmosphere by the large blower 10.

【0016】以上の冷却装置により、高温排ガス2は1
/10秒以内に200℃以下(実際には約100℃)に
急冷されて、ダイオキシンを発生することなく、次工程
で例えばNOx 等の有害成分を取除いて大気中に無公害
排出することができる。
With the above cooling device, the high temperature exhaust gas 2 is reduced to 1
Within 10 seconds, it is rapidly cooled to below 200 ° C (actually about 100 ° C), and without producing dioxin, remove harmful components such as NO x in the next step and emit it to the atmosphere without pollution. You can

【0017】[0017]

【発明の効果】以上説明したように、本発明による高温
排ガス強制急速冷却装置によれば、廃PCB液のPCB
ガス焼却炉からの高温排ガスの温度を、ダイオキシンを
発生する化学反応温度範囲700〜200℃以下にその
反応所要時間1/10s以内で強制急速冷却することに
より、ダイオキシンを発生させることなく、次の有害物
質除去工程に移して無公害大気排出を実現することがで
きる。
As described above, according to the high temperature exhaust gas forced rapid cooling device according to the present invention, the PCB of the waste PCB liquid is
The temperature of the hot exhaust gas from the gas incinerator is forcibly and rapidly cooled within the chemical reaction temperature range of 700 to 200 ° C. for generating dioxin within 1/10 s of the reaction time, without generating dioxin. It is possible to move to the process of removing harmful substances to achieve pollution-free atmospheric emission.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 一実施例装置の概要構成フロー線図FIG. 1 is a schematic configuration flowchart of an apparatus according to an embodiment.

【図2】 一次ガス冷却塔の具体的構成の一断面図例[FIG. 2] Example of one cross-sectional view of a specific configuration of a primary gas cooling tower

【符号の説明】[Explanation of symbols]

1 一次ガス冷却塔 2 高温排ガス 4 冷却済ガス出口 5,16 冷却水 5a 冷却水ガイド 7 高圧送水管 8,17 高圧水スプレー装置 9 二次冷却塔 9a 冷却水コイル管 11,12 高圧水ポンプ 1 Primary Gas Cooling Tower 2 High Temperature Exhaust Gas 4 Cooled Gas Outlet 5,16 Cooling Water 5a Cooling Water Guide 7 High Pressure Water Pipe 8,17 High Pressure Water Spray Device 9 Secondary Cooling Tower 9a Cooling Water Coil Pipe 11,12 High Pressure Water Pump

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 PCBガス焼却炉からの1600℃以上
の高温排ガスを急速に冷却するための装置であって、一
次及び二次の各冷却手段より成り、前記一次冷却手段
は、前記高温排ガスを上方より下方に向けて導入して冷
却水内を通過させるためのガイド手段と、前記冷却水内
を通過する通過ガスの温度を、1/10秒以内に200
℃以下に冷却するための第一の高圧水スプレー手段と、
この冷却済みガスを排出するための出口手段とを有する
と共に、前記二次冷却手段は、冷却水コイル管と、この
コイル管を冷却するための第二の高圧水スプレー手段
と、前記一次冷却手段の冷却水を前記冷却水コイル管内
に供給するための高圧水ポンプと、前記コイル管内の冷
却済み高圧水を前記一次冷却手段の第一の高圧水スプレ
ー手段に供給するための高圧送水管とを有することを特
徴とする高温排ガス強制急速冷却装置。
1. An apparatus for rapidly cooling high-temperature exhaust gas at 1600 ° C. or higher from a PCB gas incinerator, comprising primary and secondary cooling means, wherein the primary cooling means controls the high-temperature exhaust gas. Guide means for introducing downward from above and passing through the inside of the cooling water;
The temperature of the passing gas passing through the
A first high-pressure water spray means for cooling below ℃,
The secondary cooling means has a cooling water coil tube, a second high-pressure water spraying means for cooling the coil tube, and an outlet means for discharging the cooled gas. A high pressure water pump for supplying the cooling water into the cooling water coil tube, and a high pressure water pipe for supplying the cooled high pressure water in the coil tube to the first high pressure water spray means of the primary cooling means. A high-temperature exhaust gas forced rapid cooling device characterized by having.
JP6011792A 1994-02-03 1994-02-03 High temperature exhaust gas forced rapid cooling device Expired - Fee Related JP2694631B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6011792A JP2694631B2 (en) 1994-02-03 1994-02-03 High temperature exhaust gas forced rapid cooling device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6011792A JP2694631B2 (en) 1994-02-03 1994-02-03 High temperature exhaust gas forced rapid cooling device

Publications (2)

Publication Number Publication Date
JPH07213849A JPH07213849A (en) 1995-08-15
JP2694631B2 true JP2694631B2 (en) 1997-12-24

Family

ID=11787770

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6011792A Expired - Fee Related JP2694631B2 (en) 1994-02-03 1994-02-03 High temperature exhaust gas forced rapid cooling device

Country Status (1)

Country Link
JP (1) JP2694631B2 (en)

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JPH0677662B2 (en) * 1987-03-25 1994-10-05 三井造船株式会社 Waste incinerator exhaust gas treatment method

Cited By (2)

* Cited by examiner, † Cited by third party
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KR101353431B1 (en) * 2013-03-13 2014-01-20 양미혜 Gas cooling system
WO2014142531A1 (en) * 2013-03-13 2014-09-18 Lee In Seob Gas cooling apparatus

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