JP2668388B2 - Liquid polishing composition - Google Patents
Liquid polishing compositionInfo
- Publication number
- JP2668388B2 JP2668388B2 JP63120020A JP12002088A JP2668388B2 JP 2668388 B2 JP2668388 B2 JP 2668388B2 JP 63120020 A JP63120020 A JP 63120020A JP 12002088 A JP12002088 A JP 12002088A JP 2668388 B2 JP2668388 B2 JP 2668388B2
- Authority
- JP
- Japan
- Prior art keywords
- composition
- weight
- present
- bacteria
- polishing composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、長期保存安定性に優れた液体研磨性組成物
に関するものである。さらに詳しくは長期間保存して
も、色調、香り、外観等の性状の変化をきたさない液体
クレンザー組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial field of use] The present invention relates to a liquid abrasive composition having excellent long-term storage stability. More specifically, the present invention relates to a liquid cleanser composition which does not cause any change in properties such as color tone, fragrance and appearance even when stored for a long period of time.
液体クレンザー組成物は、界面活性剤水溶液中に水不
溶性研磨物質を分散させるとともに、さらに、無機塩、
ハイドロトロープ剤、有機高分子等の分散安定剤を添加
したもので、従来各種のものが知られている（例えば、
特公昭59−48080号公報、特開昭59−59796号公報、特公
昭60−6998号公報、特開昭62−95400号公報、特開昭62
−70497号公報等）。The liquid cleanser composition has a water-insoluble abrasive substance dispersed in an aqueous surfactant solution, and further an inorganic salt,
Hydrotropes, dispersion stabilizers such as organic polymers have been added, and various types are conventionally known (for example,
JP-B-59-48080, JP-A-59-59796, JP-B-60-6998, JP-A-62-95400, JP-A-62
No. -70497).
ところで、このような液体クレンザー組成物において
は、その添加物や水を経由して細菌が浸入しやすい。そ
して、従来の液体クレンザー組成物は、細菌の繁殖に適
した成育条件を与えるため、長期間保存しておくと、細
菌の繁殖によって、その色調、香り、外観等の性状が劣
化し、品質の悪化したものとなる。このような品質劣化
は、手肌へのマイルド性を付与するために天然果汁と保
湿剤を添加した時には、特に顕著である。By the way, in such a liquid cleanser composition, bacteria easily enter through the additive or water. Then, the conventional liquid cleanser composition gives a growth condition suitable for the growth of bacteria, and therefore, when it is stored for a long period of time, due to the growth of bacteria, its color tone, scent, appearance and the like properties are deteriorated, and the quality of the composition is improved. It will be worse. Such deterioration in quality is particularly remarkable when natural juice and a humectant are added to impart mildness to hand skin.
（目的） 本発明は、細菌汚染されやすい天然果汁を含む液体研
磨性組成物に見られる前記細菌繁殖による品質劣化の問
題を解決することを目的とする。(Purpose) An object of the present invention is to solve the problem of quality deterioration due to bacterial propagation, which is observed in a liquid abrasive composition containing natural juice which is easily contaminated with bacteria.
（問題点を解決するための手段） 本発明者らは、前記目的を達成すべく鋭意研究を重ね
た結果、特定の抗菌剤を配合することによってその目的
を達成し得ることを見出し、本発明を完成するに到っ
た。(Means for Solving the Problems) As a result of intensive studies to achieve the above object, the present inventors have found that the object can be achieved by blending a specific antibacterial agent. Was completed.
すなわち、本発明によれば、天然果汁（Ａ）と、保湿
剤（Ｂ）と、５−クロロ−２−メチル−４−イソチアゾ
リン−３−オン又は２−メチル−４−イソチアゾリン−
３−オンあるいはそれらの混合物からなる抗菌剤（Ｃ）
を含有する液体研磨性組成物が提供される。That is, according to the present invention, natural juice (A), humectant (B), and 5-chloro-2-methyl-4-isothiazolin-3-one or 2-methyl-4-isothiazoline-
Antibacterial agent (C) comprising 3-one or a mixture thereof
A liquid abrasive composition comprising:
本発明の組成物は、手肌へのマイルド性を付与すらた
めに、天然果汁と保湿剤を含有する。天然果汁として
は、ライム、レモン、オレンジ、パインアップル等の日
本農林規格に定めた果汁飲料基準の天然果汁が用いら
れ、希釈品や濃縮品であってもよい。その添加量は、未
希釈及び未濃縮の天然果汁換算で0.01〜0.1重量％、好
ましくは0.03〜0.06重量％である。The composition of the present invention contains a natural fruit juice and a moisturizer in order to even impart mildness to the hand skin. As the natural juice, lime, lemon, orange, pine apple, and other natural juices based on fruit juice beverages defined by Japanese Agricultural Standards are used, and may be diluted or concentrated products. The amount of addition is 0.01 to 0.1% by weight, preferably 0.03 to 0.06% by weight in terms of undiluted and unconcentrated natural juice.
保湿剤としては、従来公知のものが用いられる。この
ようなものとしては、例えば、ミリスチン酸イソプロピ
ル、パルミチン酸イソプロピル等の高級脂肪酸アルキル
エステルや、ピロリドンカルボン酸又はその塩（例え
ば、ピロリドンカルボン酸ナトリウム、ピロリドンカル
ボン酸カリウム、ピロリドンカルボン酸トリエタノール
アミド等の塩）が挙げられる。保湿剤は、0.001〜0.01
重量％の範囲で添加するのが好ましい。As the humectant, a conventionally known humectant is used. Examples thereof include higher fatty acid alkyl esters such as isopropyl myristate and isopropyl palmitate, and pyrrolidonecarboxylic acid or salts thereof (for example, sodium pyrrolidonecarboxylate, potassium pyrrolidonecarboxylate, and pyrrolidonecarboxylic acid triethanolamide). Salt). Moisturizer, 0.001-0.01
It is preferable to add in the range of weight%.
水不溶性研磨性としては、従来公知のものが用いられ
る。このようなものとしては、例えば、硅砂及び石英砂
等のシリカ類、パーライト、シラス、白土及び長石等の
アルミナシリケート類、天然ゼオライト、炭酸カルシウ
ム、砂もしくは貝ガラ等の天然粉砕物、リン酸カルシウ
ム、酸化鉄、酸化アルミニウム、酸化チタン、炭酸バリ
ウム等の粉体が用いられる。組成物に十分な研磨力を保
持させるためには、モース硬度３以上で且つ半均粒径５
〜40μｍの粉体の使用が好ましい。平均粒径が５μｍ認
満であれば、研磨力が乏しく、40μｍを超えると被洗物
の表面を傷付け易くなる。尚、ここで言う平均粒径と
は、ストークスの式を利用した沈降法による測定で得ら
れるメジアン径を意味する。上記研磨剤の添加量は７〜
70重量％が良く、40〜55重量％が更に好ましい。７重量
％未満であれば研磨力が乏しく、且つ保存安定性も劣
り、70重量％を超えると粘度が高くなり、ボルトから出
しにくくなる。Conventionally known water-insoluble abrasives are used. As such, for example, silicas such as silica sand and quartz sand, perlite, shirasu, alumina silicates such as clay and feldspar, natural zeolite, calcium carbonate, natural ground products such as sand or shellfish, calcium phosphate, oxidation. Powders such as iron, aluminum oxide, titanium oxide, and barium carbonate are used. In order for the composition to retain sufficient polishing power, the Mohs hardness is 3 or more and the semi-uniform particle size is 5
The use of powders of 4040 μm is preferred. When the average particle size is 5 μm, the polishing power is poor, and when the average particle size exceeds 40 μm, the surface of the article to be washed is easily damaged. The average particle size referred to here means the median diameter obtained by the measurement by the sedimentation method using the Stokes equation. The amount of the abrasive added is 7 to
70% by weight is preferable, and 40 to 55% by weight is more preferable. If it is less than 7% by weight, the polishing power is poor and the storage stability is poor. If it exceeds 70% by weight, the viscosity increases and it is difficult to remove it from the bolt.
本発明の組成物には、抗菌剤として、５−クロロ−２
−メチル−４−イソチアゾリン−３−オン又は２−メチ
ル−４−イソチアゾリン−３−オンあるいはそれらの混
合物を添加する。この抗菌剤は有効必要量で添加され、
好ましくは0.005〜0.05重量％の割合で添加される。The composition of the present invention contains 5-chloro-2 as an antibacterial agent.
-Methyl-4-isothiazolin-3-one or 2-methyl-4-isothiazolin-3-one or mixtures thereof are added. This antibacterial agent is added in effective required amount,
Preferably, it is added at a ratio of 0.005 to 0.05% by weight.
本発明の組成物には、通常、界面活性剤が添加される
が、その添加は必須ではなく、場合によっては省略する
ことも可能である。界面活性剤の具体例としては、例え
ば、炭素数８〜18のアルキル基を有する直鎖アルキルベ
ンゼンスルホン酸塩、α−オレフィンスルホン酸塩、ア
ルキルスルホン酸塩、ポリオキシエチレンアルキル硫酸
塩等のアニオン活性剤や脂肪酸アルカノールアミド又は
その誘導体、ポリオキシエチレンアルキルフェニルエー
テル、ポリオキシエチレン−ポリオキシプロピレンアル
キルエーテル等のノニオン界面活性剤が用いられるが、
洗浄力、泡立ちの点から直鎖アルキルベンゼンスルホン
酸塩と脂肪酸アルカノールアミドの酸化エチレン付加物
若しはく脂肪酸ジエタノールアミドを併用するのが好ま
しい。界面活性剤の添加量は、最終組成の粘度を考慮し
て、通常２〜10重量％の範囲で選択されるが、５〜８重
量％が好ましい。A surfactant is usually added to the composition of the present invention, but the addition is not essential and can be omitted in some cases. Specific examples of the surfactant include, for example, anionic activities such as linear alkylbenzene sulfonates having an alkyl group having 8 to 18 carbon atoms, α-olefin sulfonates, alkyl sulfonates, and polyoxyethylene alkyl sulfates. Nonionic surfactants such as agents and fatty acid alkanolamides or derivatives thereof, polyoxyethylene alkyl phenyl ether, polyoxyethylene-polyoxypropylene alkyl ether are used,
From the viewpoint of detergency and foaming, it is preferable to use a linear alkylbenzene sulfonate and an ethylene oxide adduct of fatty acid alkanolamide or fatty acid diethanolamide in combination. The addition amount of the surfactant is usually selected in the range of 2 to 10% by weight in consideration of the viscosity of the final composition, but is preferably 5 to 8% by weight.
本発明の組成物には、以上の成分の他にも、液体研磨
性組成物としての性能を損わない範囲で、トルエンスル
ホン酸、安息香酸、クエン酸又はそれらの塩や、プロピ
レングリコール、エチレングリコール、グリセリン等の
ハイドロトロープ剤、香料、着色剤、防錆剤を添加する
ことができる。The composition of the present invention, in addition to the above components, as long as the performance as a liquid abrasive composition is not impaired, toluenesulfonic acid, benzoic acid, citric acid or a salt thereof, propylene glycol, ethylene Hydrotropes such as glycol and glycerin, fragrances, colorants, and rust inhibitors can be added.
（発明の効果） 本発明の液体研磨性組成物は、長期保存においても、
細菌の繁殖はなく、色調、香り、外観等の性状の劣化を
生じるようなことはない。しかも、天然果汁と保湿剤を
含むことから、手肌に対する感触はマイルドである。(Effect of the Invention) The liquid abrasive composition of the present invention can be used for long-term storage.
Bacteria do not propagate, and properties such as color tone, scent, and appearance do not deteriorate. Moreover, since it contains natural fruit juice and a moisturizer, the feel on the skin is mild.
（実施例） 次に本発明を実施例によりさらに詳細に説明する。(Example) Next, the present invention will be described in more detail with reference to examples.
実施例１ 次表に示す成分組成の液体研磨性組成物を調製した。Example 1 A liquid abrasive composition having the component composition shown in the following table was prepared.
次に、前記で得た組成物について、その長期保存性を
調べるための保存性促進試験を次のようにして行った。 Next, the composition obtained above was subjected to a preservative acceleration test for examining its long-term preservability as follows.
組成物に対し、腸内細菌群／線膿菌／汚染酵母群／カ
ビ菌＝1/1/1/1の混合菌を３×107個植え込み、35℃で放
置した後、２週間目の細菌数（個/g）を測定するととも
に、組成物の外観及び香りについても以下の基準で評価
した。The composition was inoculated with 3 × 10 7 mixed bacteria of intestinal bacteria group / Pseudomonas aeruginosa / contaminated yeast group / mold bacterium = 1/1/1/1, left at 35 ° C., and then 2 weeks later The number of bacteria (cells / g) was measured, and the appearance and aroma of the composition were evaluated according to the following criteria.
外 観： ○…異常なし △…若干黒褐色を示す ×…黒褐色を示す 香 り： ○…異常なし △…若干腐敗臭を示す ×…強い腐敗臭を示す 以上の結果を表−２にまとめて示す。表−２の結果か
ら、抗菌剤を有効量（0.005〜0.05重量％）を含む本発
明の組成物は、細菌の繁殖がなく、長期間放置してもそ
の性状劣化が生じないことがわかる。Appearance: ○… No abnormality △… Slight black brown color ×… Black brown color Fragrance: ○… No abnormality △… Slightly rotten odor ×… Strong rotten smell The above results are summarized in Table-2. . From the results in Table 2, it can be seen that the composition of the present invention containing an effective amount (0.005 to 0.05% by weight) of the antibacterial agent does not propagate bacteria and does not deteriorate in properties even if left for a long period of time.
実施例２ 実施例１において、天然果汁、保湿剤及び抗菌剤の成
分組成を表−３に示した通りのものにした以外は同様に
して組成物を調製した。また、この組成物について、実
施例１と同様にして、保存性促進試験を行った。その結
果を表−３に示す。 Example 2 A composition was prepared in the same manner as in Example 1 except that the component compositions of the natural juice, the humectant, and the antibacterial agent were as shown in Table-3. Further, the composition was subjected to a preservability acceleration test in the same manner as in Example 1. Table 3 shows the results.
表−３に示された結果から、同種の抗菌剤であって
も、本発明で特定した以外の抗菌剤では本発明の目的を
達成し得ないことがわかる。From the results shown in Table 3, it can be seen that even with the same type of antibacterial agent, the purpose of the present invention cannot be achieved with an antibacterial agent other than the one specified in the present invention.
実施例３ 表−４に示した成分組成の組成物（微量の香料を含
む、水バランスで全体で100重量部に調整）を調製し
た。また、この組成物について、実施例１と同様にし
て、その保存性促進試験を行った。その結果を表−４に
示す。 Example 3 A composition having the component composition shown in Table 4 (including a trace amount of fragrance, adjusted to a total of 100 parts by weight with a water balance) was prepared. Further, the composition was subjected to a preservability promotion test in the same manner as in Example 1. Table 4 shows the results.
なお、表−４に示したPOE（９）POP（15）ラウリルエ
ーテルは、ラウリルアルコールにエチレンオキシド９モ
ル及びプロピレンオキシド15モルを付加重合させた生成
物を意味する。The POE (9) POP (15) lauryl ether shown in Table 4 means a product obtained by addition polymerization of lauryl alcohol with 9 mol of ethylene oxide and 15 mol of propylene oxide.
Claims (1)
クロロ−２−メチル−４−イソチアゾリン−３−オン又
は２−メチル−４−イソチアゾリン−３−オンあるいは
それらの混合物からなる抗菌剤（Ｃ）を含有する液体研
磨性組成物。1. A natural juice (A), a humectant (B), and 5-
A liquid abrasive composition containing an antibacterial agent (C) comprising chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one or a mixture thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63120020A JP2668388B2 (en) | 1988-05-16 | 1988-05-16 | Liquid polishing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63120020A JP2668388B2 (en) | 1988-05-16 | 1988-05-16 | Liquid polishing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01289888A JPH01289888A (en) | 1989-11-21 |
| JP2668388B2 true JP2668388B2 (en) | 1997-10-27 |
Family
ID=14775922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63120020A Expired - Lifetime JP2668388B2 (en) | 1988-05-16 | 1988-05-16 | Liquid polishing composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2668388B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6235299B1 (en) * | 1998-02-27 | 2001-05-22 | Buckman Laboratories International Inc | Potentiation of biocide activity using diethanolamide |
| US7838481B2 (en) * | 2006-04-07 | 2010-11-23 | Beckman Coulter, Inc. | Formaldehyde-free cleaner composition for cleaning blood analyzers and method of use |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6054281B2 (en) * | 1977-03-28 | 1985-11-29 | 株式会社パ−マケム・アジア | Fungicide |
| FI63056C (en) * | 1977-12-22 | 1983-04-11 | Unilever Nv | FLYTANDE TVAETTMEDELSBLANDNING SOM SAERSKILT LAEMPAR SIG FOER DISKNING |
| JPS5754104A (en) * | 1980-09-18 | 1982-03-31 | Takeda Chem Ind Ltd | Antifungal composition |
| JPS6466298A (en) * | 1987-09-08 | 1989-03-13 | Kao Corp | Liquid cleanser composition |
-
1988
- 1988-05-16 JP JP63120020A patent/JP2668388B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01289888A (en) | 1989-11-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |