JP2653044B2 - Measurement output recording device - Google Patents

Measurement output recording device

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Publication number
JP2653044B2
JP2653044B2 JP61234061A JP23406186A JP2653044B2 JP 2653044 B2 JP2653044 B2 JP 2653044B2 JP 61234061 A JP61234061 A JP 61234061A JP 23406186 A JP23406186 A JP 23406186A JP 2653044 B2 JP2653044 B2 JP 2653044B2
Authority
JP
Japan
Prior art keywords
measurement output
peak
output
sampling
measurement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP61234061A
Other languages
Japanese (ja)
Other versions
JPS6388427A (en
Inventor
俊明 福間
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimazu Seisakusho KK
Original Assignee
Shimazu Seisakusho KK
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Filing date
Publication date
Application filed by Shimazu Seisakusho KK filed Critical Shimazu Seisakusho KK
Priority to JP61234061A priority Critical patent/JP2653044B2/en
Publication of JPS6388427A publication Critical patent/JPS6388427A/en
Application granted granted Critical
Publication of JP2653044B2 publication Critical patent/JP2653044B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/27Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
    • G01N21/272Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration for following a reaction, e.g. for determining photometrically a reaction rate (photometric cinetic analysis)

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Mathematical Physics (AREA)
  • Theoretical Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Spectrometry And Color Measurement (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Description

【発明の詳細な説明】 イ 産業上の利用分野 本発明は分光光度計による時間送り記録のような長時
間にわたる測定器出力のデータ収集方式に関する。
Description: TECHNICAL FIELD The present invention relates to a method for collecting data of an output of a measuring instrument over a long period of time, such as time recording by a spectrophotometer.

ロ 従来の技術 長時間にわたる測定値の記録には通常記録計が用いら
れるが、大量の記録紙を消費し、記録の保管場所にも困
るので、XYレコーダとかCRTデイスプレイのような記録
範囲の限定された装置によつて記録したい場合が多い
が、この場合測定出力は一旦メモリに格納し、事後的に
メモリ内容を読出して記録する。このため大容量のメモ
リを要し、測定出力の時間的変化を精密に記録しようと
すると、測定出力のサンプリング間隔を細かくしなけれ
ばならないからメモリの必要容量はますます大きくな
る。所が測定対象によつては、測定出力の時間的変化が
通常は小さくてゆつくりしており、時々大きなピークが
現われると云うものがある。例えば分光光度計を用いて
流通している試料の吸光度の時間変化を測定するような
場合にこのような事例が多く、クロマトグラフの出力記
録とか原子吸光分光分析においてもこのような出力状態
を呈する。このような出力状態を呈する場合の測定記録
ではピークが現れていない期間が長くて、その期間に対
してメモリ容量を大量に消費するのは無駄であるから、
測定出力のサンプリング間隔を大にすると、ピークの記
録精度が低下し、ピークの記録精度を高めようとする
と、メモリの利用率が低下し、コスト高の装置となる。
(B) Conventional technology Recorders are usually used to record measurement values over a long period of time.However, because a large amount of recording paper is consumed and the storage location of the records is also inconvenient, the recording range is limited, such as with an XY recorder or CRT display. In many cases, it is desired to record the data by a device which has been used. In this case, the measurement output is temporarily stored in a memory, and the content of the memory is read and recorded afterwards. For this reason, a large-capacity memory is required, and if the temporal change of the measurement output is to be accurately recorded, the sampling interval of the measurement output must be reduced, so that the required memory capacity is further increased. However, depending on the object to be measured, the temporal change of the measurement output is usually small and slow, and a large peak sometimes appears. For example, such a case is often observed when measuring the time change of the absorbance of a circulating sample using a spectrophotometer, and such an output state is exhibited even in a chromatographic output record or an atomic absorption spectrometric analysis. . In the measurement record in the case of such an output state, the period during which no peak appears is long, and it is useless to consume a large amount of memory capacity during that period.
If the sampling interval of the measurement output is increased, the recording accuracy of the peak decreases, and if the recording accuracy of the peak is increased, the utilization rate of the memory decreases, resulting in an expensive device.

ハ 発明が解決しようとする問題点 本発明は上述したような状況に鑑み通常時間的変化が
少く、時々ピークが現われる型の測定出力の記録におい
て、比較的小容量のメモリで精度の良いピーク時の測定
記録を可能にすると共に、その動作が安定に行われるよ
うにしようとするものである。
C. Problems to be Solved by the Invention In view of the above-described situation, the present invention usually has a small temporal change, and a type of measurement output in which a peak sometimes appears. The purpose of the present invention is to enable measurement and recording of data, and to stably perform the operation.

ニ 問題点解決のための手段 測定出力の時間的変化率を検出し、時間的変化率の小
さな間は測定出力のサンプリング間隔或いはメモリへの
データ格納間隔を広くし、変化率の大きな間は上記間隔
を狭くすると共に、ピーク検出により測定出力のピーク
通過中はピーク頂上付近でも狭い上記間隔を維持するよ
うに自動制御を行なうようにした。
D) Means for solving the problem Detect the temporal change rate of the measurement output, widen the sampling interval of the measurement output or the data storage interval to the memory while the temporal change rate is small, and The interval is narrowed, and automatic control is performed so as to maintain the narrow interval even near the peak apex while the measured output passes through the peak by peak detection.

ホ 作用 上述したように測定出力の時間的変化率の小さな間は
例えばサンプリング間隔が大きいからメモリの容量消費
が少く、時間変化率の大きな間は測定上重要な期間で、
その間はサンプリング間隔がせまく測定記録の精度低下
を来さないから、メモリ容量の有効利用ができ、小容量
のメモリで長時間の測定記録を精度を落さずにすること
ができる。測定出力のピーク頂上付近では測定出力の時
間的変化率は小さいが本発明によれば、ピーク頂上が過
ぎる迄は狭いサンプリング間隔が維持されるので、その
まゝピークの立下り側の変化速度の大きな部分につなが
り、ピーク頂上付近でサンプリング間隔が変わってピー
クの形が不明になったり、ノズルの影響でサンプリング
間隔が頻繁に切換わるバタツキが起こると云うことがな
い。
E. As described above, when the temporal change rate of the measurement output is small, for example, the sampling interval is large, so that the memory capacity consumption is small, and while the time change rate is large, it is an important period for measurement.
In the meantime, the sampling interval is short and the accuracy of the measurement record does not decrease, so that the memory capacity can be effectively used, and the long-time measurement record can be performed with a small-capacity memory without lowering the accuracy. Although the temporal change rate of the measured output is small near the peak of the measured output, according to the present invention, a narrow sampling interval is maintained until the peak is passed, so that the rate of change of the falling side of the peak is not changed. It does not lead to a large portion, and the sampling interval changes near the peak apex, and the shape of the peak becomes unclear, and there is no flutter that frequently changes the sampling interval due to the influence of the nozzle.

ヘ 実施例 第1図は本発明の一実施例の測定出力サンプリング間
隔設定ルーチンのフローチヤートである。この実施例で
は測定出力サンプリング間隔はPoとPo/10の2種類を用
い、前回と今回のサンプリングデータの差を基準値と比
較して、差が基準値以下ならサンプリング間隔をPoと
し、基準値以上ならサンプリング間隔をPoの1/10にす
る。第1図のフローチヤートに従つて動作を説明する
と、サンプリング間隔がPo(広い)か否かに応じて
(イ)、サンプリング間隔がPoのときは動作は(ロ)の
ステツプに進み、今回サンプリングデータと前回サンプ
リングデータとの差が第1基準ΔA1より大きか否か判別
し、差がΔA1より小(NO)のとき、動作は(ハ)のステ
ツプに進んで次回のサンプリングピツチをPoに設定し、
一回のサンプリング動作を終つて次回は再び(イ)のス
テツプから始まる。動作がステツプ(イ)から(ロ)に
来て(ロ)の判定がYESつまり変化率が大のとき、動作
は(ニ)のステツプに行き、次回サンプリング間隔をP
=Po/10にセツトし、次回動作がスタートする。このと
き(イ)のステツプはサンプリング間隔がPoでない(N
O)から動作は(ホ)のステツプに行き、測定出力のピ
ークが過ぎたか否か判定する。測定出力のピークの検出
は別のプログラムで行われており、ピークが未だ過ぎて
いない(NO)ときは動作は(ニ)に行き、引続きサンプ
リング間隔Pがセツトされる。(ホ)のステツプがYES
即ち測定出力のピークが過ぎたと判定されたときは、動
作はステツプ(ヘ)に進み、測定値変化量が第2基準Δ
A2より小さいか否か判定し、小さい(YES)のとき動作
は(ハ)のステツプに進んでサンプリング間隔はPoに戻
される。(ヘ)のステツプがNOのとき動作は(ニ)のス
テツプへ行き、引続きサンプリングピツチはせまいPの
まゝとなる。
F. Embodiment FIG. 1 is a flowchart of a measurement output sampling interval setting routine according to an embodiment of the present invention. In this embodiment, two types of measurement output sampling intervals, Po and Po / 10, are used. The difference between the previous and current sampling data is compared with a reference value. If so, set the sampling interval to 1/10 of Po. The operation will be described according to the flowchart of FIG. 1. According to whether the sampling interval is Po (wide) or not (a), when the sampling interval is Po, the operation proceeds to step (b), and the current sampling is performed. It is determined whether or not the difference between the data and the previous sampling data is larger than the first reference ΔA1. If the difference is smaller than ΔA1 (NO), the operation proceeds to step (c) and the next sampling pitch is set to Po. And
After one sampling operation, the next time starts again with the step (a). If the operation comes from step (a) to (b) and the determination in (b) is YES, that is, if the change rate is large, the operation goes to step (d) and the next sampling interval is set to P.
= Set to Po / 10, the next operation starts. At this time, in step (a), the sampling interval is not Po (N
From O), the operation proceeds to step (E) to determine whether the peak of the measured output has passed. The detection of the peak of the measurement output is performed by another program. If the peak has not yet passed (NO), the operation goes to (D), and the sampling interval P is subsequently set. Step (e) is YES
That is, when it is determined that the peak of the measured output has passed, the operation proceeds to step (f), and the measured value change amount is set to the second reference Δ
It is determined whether it is smaller than A2, and if smaller (YES), the operation proceeds to step (c), and the sampling interval is returned to Po. When the step (f) is NO, the operation proceeds to the step (d), and the sampling pitch remains narrow P.

以上の動作でステツプ(ホ)(ヘ)について説明す
る。測定出力の時間変化が小さい通常時は前回今回のサ
ンリングデータの差をモニタして次回のサンプリング間
隔を決定しているが、測定出力のピークが現われている
間は前回今回のサンプリングデータの差のモニタはして
いない。これはサンプリング間隔がせまいので、ノイズ
の影響が大きく、差の値の変動が大きいからであり、こ
のため別途測定出力のピークを過ぎたことを確認(ホの
ステツプ)して、測定値変化量を調べる。こゝで測定値
変化量は何点か前(例へば10点前)のサンプリングデー
タと今回のサンプリングデータとの差が第2基準ΔA2よ
り小さくなつているか否かチエツクする。このようにし
て差データのノイズの影響は小さくできるが、このやり
方をピークの立上りから用いると、ピーク頂上付近では
差データが小さくなつて基準以下になる可能性があるの
で、ピーク頂点をサンプリング点で何点か(例えば10
点)過ぎたことを確認するのである。
Steps (e) and (f) will be described in the above operation. Normally, when the time change of the measurement output is small, the difference between the previous sampling data is monitored by monitoring the difference between the previous sampling data and the next sampling interval. I do not monitor. This is because the sampling interval is narrow, so that the influence of noise is large and the value of the difference fluctuates greatly. Therefore, it is separately confirmed that the peak of the measurement output has passed (step E), and the measurement value change amount Find out. Here, it is checked whether or not the difference between the measured data change amount and the current sampling data is smaller than the second reference ΔA2 by several points (for example, 10 points before). In this way, the influence of noise on the difference data can be reduced.However, if this method is used from the rising edge of the peak, the difference data may become smaller and smaller than the standard near the peak apex. Some points (for example, 10
Point) to confirm that it has passed.

第2図は以上の動作によるサンプリング点の並び状態
を例示するものである。サンプリング点aと次のbとの
間で測定出力の差がΔA1を超えており、従つてbから後
はサンプリング間隔がせまくなり、ピーク頂点を何点が
過ぎたv点で所定点数前のu点との測定出力の差をΔA2
と比較し、この動作をv点以後の各サンプリング点で行
つてy点に来たとき、y点から所定点数前のx点の測定
出力との差がΔA2以下となつて、以後サンプリング間隔
は平常のPoに戻る。
FIG. 2 exemplifies a state of arrangement of sampling points by the above operation. The difference in the measured output between the sampling point a and the next b exceeds ΔA1, so that the sampling interval becomes narrower after b, and the number of points past the peak apex v and v ΔA2
When this operation is performed at each sampling point after the point v and comes to the point y, the difference between the measured output at the point x and a predetermined number of points before the point y is ΔA2 or less, and the sampling interval thereafter becomes Return to normal Po.

上述実施例ではサンプリング間隔は2種類であるが、
測定出力の変化率に応じて何段階か用いるようにするこ
ともできる。また上例でサンプリングされたデータを一
定ピツチでCRTとかXYプロツタに表示すれば時間軸が著
るしく圧縮され、しかもピークの所は時間軸を伸張した
形の表示になつてせまい範囲に長時間分のデータが表示
でき、しかも重要なピーク部分は正確に表示されてい
る。XYプロツタで記録するとき、サンプリング間隔に応
じてドツトの色を変えるようにすると、時間圧縮された
部分とそうでない部分が一目で分つて便利であり、また
サンプリング間隔が変つた位置に目印のドツトを打つよ
うにすれば、表示全体の時間計算が容易になる。
In the above embodiment, there are two types of sampling intervals.
It is also possible to use several stages according to the rate of change of the measurement output. In addition, if the data sampled in the above example is displayed on a CRT or XY plotter at a fixed pitch, the time axis will be markedly compressed, and the peaks will be displayed in an expanded form on the time axis for a long time in a narrow range. Minute data can be displayed, and important peaks are accurately displayed. When recording with an XY plotter, if the dot color is changed according to the sampling interval, the time-compressed part and the non-time-compressed part can be easily identified at a glance, and the dot of the mark will be displayed at the position where the sampling interval changes. By hitting, the time calculation of the entire display becomes easy.

更に上述実施例では測定出力のサンプリング間隔と測
定出力のメモリへの格納間隔を同じにしているが、測定
出力は常時短い時間間隔でサンプリングし、測定出力の
スムージング処理等を行いつゝ、サンプリングデータか
ら適当間隔でデータを抜取つてメモリに転送するように
し、スムージング等の処理を施されたデータについて時
間微分を行い、その微分値の大きさで上記データ抜取り
間隔を大小切換えるようにしてもよい。
Further, in the above embodiment, the sampling interval of the measurement output and the storage interval of the measurement output in the memory are the same, but the measurement output is always sampled at a short time interval, and the smoothing processing of the measurement output is performed. , Data may be extracted at appropriate intervals and transferred to a memory, time-differentiated on data that has been subjected to processing such as smoothing, and the size of the data extraction interval may be switched according to the magnitude of the differential value.

ト 効果 上述した所から明かなように本発明によれば、測定上
重要な測定出力の変化の大きな所は細かいサンプリング
間隔でデータがメモリされ、その他の所は粗いサンプリ
ング間隔でメモリされるので、測定記録の精度を損うこ
となく、小容量のメモリで長時間の測定データを収容で
き、時間軸を圧縮した表示が容易かつ大事な部分が見易
い形で行われる。
G Effect According to the present invention, it is clear from the above that according to the present invention, data where the change of the measurement output which is important for measurement is large is stored at a fine sampling interval, and other portions are stored at a coarse sampling interval. A long-term measurement data can be stored in a small-capacity memory without impairing the accuracy of the measurement record, and the compressed time axis is displayed easily and important parts are easily viewed.

【図面の簡単な説明】[Brief description of the drawings]

第1図は本発明の一実施例におけるサンプリング間隔設
定のルーチンのフローチヤート、第2図は上記実施例に
よる測定出力サンプリング状態を示すグラフである。
FIG. 1 is a flowchart of a routine for setting a sampling interval in one embodiment of the present invention, and FIG. 2 is a graph showing a measurement output sampling state according to the above embodiment.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】測定出力をメモリに記憶させるため、測定
出力の前回サンプリングデータと今回サンプリングデー
タとを比較することにより、上記測定出力の時間的変化
をモニタする手段と、上記モニタ手段のモニタ結果によ
り、上記測定出力の時間的変化率に応じてメモリへの複
数段階のデータ格納間隔の一つを選定する手段と、選定
されたデータ格納間隔で上記測定出力をメモリに格納す
る手段と共に、上記モニタ手段により測定出力のピーク
検出を行い、ピーク検出前にあっては測定出力の時間的
変化率が一つの値以上になったとき上記データ格納間隔
を大から小に切換え、そのサンプリング間隔をピーク検
出後まで維持し、ピーク検出後においては測定出力の時
間変化率を今回と複数回前のサンプリングデータとから
求め、そのときの変化率が或る値以下になったとき上記
データ格納間隔を小から大に切換える制御手段を備えた
ことを特徴とする測定出力記録装置。
1. A means for monitoring a temporal change in the measurement output by comparing the previous sampling data and the current sampling data of the measurement output to store the measurement output in a memory, and a monitoring result of the monitoring means. With the means for selecting one of a plurality of stages of data storage intervals in the memory in accordance with the temporal change rate of the measurement output, and the means for storing the measurement output in the memory at the selected data storage interval, The peak of the measured output is detected by the monitoring means, and before the peak is detected, when the temporal change rate of the measured output becomes one value or more, the data storage interval is switched from large to small, and the sampling interval is set to the peak. After the peak is detected, after the peak is detected, the time change rate of the measurement output is obtained from the current time and the sampling data of a plurality of times before. Rate measurement output recording apparatus, wherein a comprises a control means for switching the large the data storage apart from small when it becomes less than a certain value.
JP61234061A 1986-09-30 1986-09-30 Measurement output recording device Expired - Lifetime JP2653044B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61234061A JP2653044B2 (en) 1986-09-30 1986-09-30 Measurement output recording device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61234061A JP2653044B2 (en) 1986-09-30 1986-09-30 Measurement output recording device

Publications (2)

Publication Number Publication Date
JPS6388427A JPS6388427A (en) 1988-04-19
JP2653044B2 true JP2653044B2 (en) 1997-09-10

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Application Number Title Priority Date Filing Date
JP61234061A Expired - Lifetime JP2653044B2 (en) 1986-09-30 1986-09-30 Measurement output recording device

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Country Link
JP (1) JP2653044B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3699263B2 (en) * 1997-12-22 2005-09-28 富士通株式会社 Tracking control device

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57149061A (en) * 1981-03-12 1982-09-14 Matsushita Electric Ind Co Ltd Consumable electrode type pulse arc welding machine
JPS58167924A (en) * 1982-03-29 1983-10-04 Shimadzu Corp Scanning type spectroscope device
JP2564788B2 (en) * 1984-11-27 1996-12-18 株式会社島津製作所 Spectroscopic measuring device for changes over time
JPS61138119A (en) * 1984-12-11 1986-06-25 Horiba Ltd Data recording method on vehicle type tachograph device

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