JP2630367B2 - Ice base material for ice plate formation - Google Patents

Ice base material for ice plate formation

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Publication number
JP2630367B2
JP2630367B2 JP29729093A JP29729093A JP2630367B2 JP 2630367 B2 JP2630367 B2 JP 2630367B2 JP 29729093 A JP29729093 A JP 29729093A JP 29729093 A JP29729093 A JP 29729093A JP 2630367 B2 JP2630367 B2 JP 2630367B2
Authority
JP
Japan
Prior art keywords
ice
water
sheet
base material
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP29729093A
Other languages
Japanese (ja)
Other versions
JPH07124289A (en
Inventor
保 北村
志郎 佐々木
瑛一路 滝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIPPON KOMUTETSUKU KK
SENI DOBOKU KAIHATSU KK
Toyobo Co Ltd
Original Assignee
NIPPON KOMUTETSUKU KK
SENI DOBOKU KAIHATSU KK
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIPPON KOMUTETSUKU KK, SENI DOBOKU KAIHATSU KK, Toyobo Co Ltd filed Critical NIPPON KOMUTETSUKU KK
Priority to JP29729093A priority Critical patent/JP2630367B2/en
Publication of JPH07124289A publication Critical patent/JPH07124289A/en
Application granted granted Critical
Publication of JP2630367B2 publication Critical patent/JP2630367B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、屋外でアイススケート
リンクの施工を容易にするシート状の氷盤形成用アイス
ベース材に係り、昼間の外気温が上昇し易い時期でも、
また、地温の上がり易いアスファルト舗装面上、排水性
の良い玉砂利上、凹凸の激しい面上、さらには傾斜面、
垂直面でも場所を選ばず、任意面に氷結層を得るための
ものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sheet-like ice base material for forming an ice skating rink which facilitates the construction of an ice skating rink outdoors.
In addition, on the asphalt pavement surface where the ground temperature tends to rise, on the gravel with good drainage, on the surface with severe unevenness, and further on the slope,
It is for obtaining a frozen layer on an arbitrary surface regardless of the location even on a vertical surface.

【0002】[0002]

【従来の技術】従来、この種のものにあっては、下記の
ようなものになっている。屋外で氷盤を得るには厳寒
期、氷結するまで帯水する地盤、あるいは舗装盤上に散
水するか、水を容器に入れた状態にすれば凍結した氷盤
が得られる。しかし、特にアイススケート、アイスホッ
ケーリンク等は、冬期も早い時期から、滑走出来るリン
クの設置はスケーターの要望が強く、散水によっての氷
盤の建設が試みられるが、日中の外気温、日射の変化で
散水しただけのものは、夜間凍結していたものも、外気
温あるいは地温で融解し、甚だしいものは帯水もしてい
ない。そのため少なくとも降雪のある時期まで待って降
雪を踏み固めて、これに散水し、これを保水材としてア
イスベースを得る方法がとられる。その他、降雪の無い
所では、ムシロ、畳等の保水性資材を敷設し、この上か
ら散水し凍結させアイスベースを得る方法もあり、アイ
スベースが出来た後はこの上に数mmずつ散水し、凍結
させて滑走可能なアイススケートリンクが完成する。
2. Description of the Related Art Heretofore, this type is as follows. In order to obtain an ice floe outdoors, a frozen ice floe can be obtained by spraying water on a ground where water is cold until the ice freezes, or on a pavement plate, or by placing water in a container. However, especially for ice skating and ice hockey rinks, skaters are strongly demanding the installation of skating rinks from the early winter season, and construction of ice trays by watering is attempted. Some that were only sprinkled due to change, those that were frozen at night, thawed at ambient or ground temperature, and those that were drastic were not flooded. For this reason, a method is employed in which the snowfall is depressed at least until a certain period of snowfall, the waterfall is sprinkled, and the water is used as a water retention material to obtain an ice base. In places where there is no snowfall, there is also a method of laying water retention materials such as shiro, tatami, etc., sprinkling water from above and freezing to obtain an ice base, and after the ice base is made, spraying several mm on this A frozen ice skating rink is completed.

【0003】[0003]

【発明が解決しようとする課題】しかし、ムシロ、畳等
は最近手に入りにくく、また、これらの保水材料は透水
性が良く、さらに自由水として保水しているため、地盤
によっては地盤に水を吸い出されるか、外気温が上がっ
てくると、乾燥してきたり、あるいは凍結していた水も
自由落下してしまいアイスベースとしての役に立たな
い。また、降雪の時期まで待つのも、温度が下がっても
雪の降らない地方ではスケート競技のシーズンが終わっ
てからはじめて雪が降ることもあり、折角リンクを作っ
ても、時期を逃してしまって意味をなさなくなる。特
に、競技の選手は一刻も早くリンクでの練習を行いた
く、早期のリンクの開設を要求する。
However, since sashimi and tatami mats are difficult to obtain recently, and since these water-retaining materials have good water permeability and further retain water as free water, depending on the ground, there is no water on the ground depending on the ground. If the air is sucked out or the outside temperature rises, the dried or frozen water will fall freely, making it useless as an ice base. Also, waiting until the time of snowfall, snow falls for the first time after the season of skating competition in the area where the temperature drops and snow does not fall, even if you make a corner link, it means that you miss the time Will not do. In particular, competitors want to practice on the link as soon as possible, and demand that the link be established early.

【0004】さらに、降雪をアイスベースにするには、
特に夜間、大勢の人で踏み固め、散水するが、靴跡で表
面が凹凸となり表面の均し作業に相当な人力がいる。こ
れだけ労力を費やしても、昼間外気温が上昇すると全部
解けて流出してしまい、再度一から作業を始めなければ
ならないことになる。特に、これらの作業は厳寒の夜間
行われ労力が大変であった。また、これらの従来方法で
は、河川敷の排水性の良い玉砂利の上とか、凹凸の激し
い場所、更にまた傾斜面、垂直面では施工が困難であっ
た。
Further, in order to make snowfall ice-based,
Especially at night, a large number of people squeeze and sprinkle water, but the surface becomes uneven due to the footprints, and considerable manpower is required to level the surface. Even with all this effort, if the outside temperature rises during the day, it will all melt and drain, and you will have to start over from scratch. In particular, these operations were carried out during the cold nights and were labor intensive. Further, with these conventional methods, it is difficult to perform construction on a gravel with good drainage on a riverbed, in a place with severe unevenness, and further on an inclined surface or a vertical surface.

【0005】[0005]

【課題を解決するための手段】上記目的を達成するため
に、本発明は下記のようになるものである。すなわち、
本発明のものは、水中に浸漬し、充分吸水させた後、3
00Gで5分間、遠心脱水後の水分率が200%以上の
保水能力を有するシート状物で、かつ表面の明度指数が
60以上、シート全体の遮光率が80%以上である氷盤
形成用アイスベース材である。Gとは、重力の加速度で
9.8m/s2 を表わす。明度指数、遮光率で所定の水
準を得るには、ポリエステル繊維の不織布などをアイス
ベース表面に一体化して行うのが好ましい。300Gの
遠心脱水を5分間行ったとき、通常の自由水あるいは重
力水の状態で含水したものは、水分率が200%に満た
ない。重力水が遠心力により離脱したため、これらの低
水分率の保水材を凍結させると水分が無く凍結しなかっ
たり、空隙の多いアイスベースになり、この上に散水す
ると水温で解けてしまったり、また、氷の強度が無く外
力で容易に折損してしまう。300Gの遠心脱水を5分
間行ったとき、200%以上の保水能力を有するシート
状物は、吸水後ゲルになり、固着水の状態で保水する高
吸水性樹脂を利用して得られる。
Means for Solving the Problems In order to achieve the above object, the present invention is as follows. That is,
After being immersed in water and sufficiently absorbing water,
Ice cube forming ice having a water retention capacity of 200% or more after centrifugal dehydration at 00G for 5 minutes, a surface lightness index of 60 or more, and a light-shielding rate of the entire sheet of 80% or more. Base material. G represents 9.8 m / s 2 in the acceleration of gravity. In order to obtain a predetermined level of lightness index and light-shielding rate, it is preferable to integrate a nonwoven fabric of polyester fiber or the like with the ice base surface. When centrifugal dewatering at 300 G is performed for 5 minutes, the water content of ordinary water or gravity water is less than 200%. Because gravity water has separated due to centrifugal force, freezing these water retention materials with a low moisture content does not freeze because there is no moisture, it becomes an ice base with many voids, and if you spray water on it, it will melt at the water temperature, or Since the ice is not strong, it is easily broken by external force. When centrifugal dewatering at 300 G is performed for 5 minutes, a sheet-like material having a water retention capacity of 200% or more becomes a gel after absorbing water, and is obtained using a highly water-absorbent resin that retains water in a fixed water state.

【0006】高吸水性樹脂としては、デンプン・アクリ
ル酸グラフト重合体、ポリアクリル酸塩系、酢ビ・アク
リル酸塩共重合体、アクリルアミド・アクリル酸塩共重
合体、ポリエチレンオキサイド系、イソブチレン・無水
マレイン酸共重合体、PVA・無水マレイン酸共重合
体、デンプン・ポリアクリロニトリル共重合体、アクリ
ル酸塩・アクリルアミド共重合体、CMC系等が例示さ
れ、粉末状、繊維状のものがある。
Examples of the superabsorbent resin include starch / acrylic acid graft polymer, polyacrylate, vinyl acetate / acrylate copolymer, acrylamide / acrylate copolymer, polyethylene oxide, isobutylene / anhydrous. Examples thereof include a maleic acid copolymer, a PVA / maleic anhydride copolymer, a starch / polyacrylonitrile copolymer, an acrylate / acrylamide copolymer, a CMC type, and the like, and include powdery and fibrous ones.

【0007】これらは自重の100倍〜10,000倍
程度の吸水をし、300Gの遠心脱水を5分間行っても
固着水として保水しているため、200%以上の保水能
力にするには、これらを必要に応じて少量含有すればよ
い。これらの高吸水性樹脂をシート状にするには、繊維
状のものであれば、他の繊維と混合し、ニードルパンチ
等により不織布にしたり編織してもよい。粉末状のもの
であれば、布帛でサンドイッチしニードルパンチで結接
したり、袋状のものに詰めて得られる。
[0007] Since these absorb about 100 to 10,000 times their own weight and retain water as fixed water even after centrifugal dewatering at 300 G for 5 minutes, to achieve a water retention capacity of 200% or more, These may be contained in small amounts as necessary. In order to make these superabsorbent resins into a sheet shape, if they are fibrous, they may be mixed with other fibers and made into a nonwoven fabric or knitted by needle punching or the like. If it is a powder, it can be obtained by sandwiching with a cloth and joining with a needle punch, or packing in a bag.

【0008】シート状物は、広い面積に敷設するため、
少なくとも巻き取れるものでなくてはならない。本発明
のシート状物は、表面の明度指数が60以上、シートの
遮光率が80%以上である。ここで云う明度指数は、J
ISZ8729により測定し、遮光率はJISL105
5A法、ただし試験片装着前照度10,000lxによ
り測定する。
[0008] In order to lay the sheet material over a wide area,
It must be at least rollable. The sheet-like material of the present invention has a surface lightness index of 60 or more and a sheet light-shielding ratio of 80% or more. The lightness index referred to here is J
Measured according to ISZ8729, and the light-shielding ratio is JISL105
5A method, but measured by illuminance 10,000 lx before mounting the test piece.

【0009】本発明のアイスベース材は、スケートシー
ズンの早くから使用し、遅くまでリンクが使用できるも
ので、シーズンの早い時期、遅い時期は夜間凍結しても
昼間温度が上がり易く、温度が上がっても水を流出しな
いよう固着水の状態で保水し、このゲル状態のまま凍結
させるが、このとき、特に太陽光による熱線を吸収し、
アイスベース自体の温度を上げたり、太陽光の熱線がア
イスベースを透過し、アイスベースの下の地温を上昇さ
せたりするものであってはならない。
The ice base material of the present invention can be used early in the skating season and can be used for rinks until late. During the early and late seasons, the temperature during the day easily rises even if it is frozen at night, and the temperature rises. Water is retained in the state of fixed water so that water does not flow out, and it is frozen in this gel state, but at this time, it absorbs heat rays especially due to sunlight,
It must not increase the temperature of the ice base itself or allow the heat rays of sunlight to penetrate the ice base and raise the ground temperature under the ice base.

【0010】特に、夏の間駐車場になっているアスファ
ルト舗装面などにスケートリンクを設置する場合、黒い
アスファルト面は熱線を吸収し易く、表面温度が上がり
易い。アイスベース材の明度指数を60以上にすること
は熱線を反射し、アイスベース材の温度上昇を防ぎ、遮
光率が80%以上では熱線の透過を防ぎ、地温の上昇を
防ぎ、地表面を保冷する。アイスベース材の固着水での
保水能力、明度指数、遮光率の範囲を外れたものは、従
来技術によるスケートリンクと変わらなくなり良くな
い。明度指数、遮光率で所定の水準を得るには、ポリエ
ステル繊維の不織布などをアイスベース材表面に一体化
して行うのが好ましい。
[0010] In particular, when a skating rink is installed on an asphalt pavement surface which is a parking lot in summer, the black asphalt surface easily absorbs heat rays and the surface temperature tends to rise. Setting the lightness index of the ice-based material to 60 or more reflects heat rays, prevents the temperature of the ice-based material from rising, and prevents light rays from penetrating when the shading rate is 80% or more, prevents the ground temperature from rising, and keeps the ground surface cool. I do. The ice-based material having a water retention capacity of fixed water, a lightness index, and a light-shielding rate which are out of the range of the ice rink is not different from the skating rink according to the prior art and is not good. In order to obtain predetermined levels of lightness index and light-shielding ratio, it is preferable that a nonwoven fabric of polyester fiber or the like be integrated with the surface of the ice base material.

【0011】[0011]

【実施例】ポリエステルカットファイバー6デニールと
高吸水性繊維5デニールを混綿し、シート状にしたもの
をニードルパンチングし、目付150g/m2 の不織布
シートを作り、さらに表面に明度指数80で遮光性のよ
い目付60g/m2 のスパンボンド不織布をニードルパ
ンチして一体の不織布に仕上げた。このときの高吸水性
繊維5デニールの混合比率は全体で5%であった。この
複合一体の不織布について、表面スパンボンド側で測定
した明度指数は78、遮光率は90%、この不織布を水
中に30分浸漬し、充分吸水させた後300Gの遠心脱
水を5分間行い、遠心脱水後の水分率を測定したところ
絶乾重量に対し250〜300%の水分を保持してい
た。
EXAMPLE A 6-denier polyester-cut fiber and a 5-denier superabsorbent fiber were blended and formed into a sheet by needle punching to produce a 150 g / m 2 non-woven fabric sheet. A spunbonded nonwoven fabric having a good basis weight of 60 g / m 2 was needle-punched to complete an integrated nonwoven fabric. The mixing ratio of the 5 denier superabsorbent fibers at this time was 5% in total. About this composite nonwoven fabric, the lightness index measured on the surface spunbond side is 78, the light-shielding ratio is 90%, this nonwoven fabric is immersed in water for 30 minutes, sufficiently absorbed, centrifugally dehydrated at 300 G for 5 minutes, and centrifuged. When the water content after dehydration was measured, it was found that the water content was 250 to 300% of the absolute dry weight.

【0012】(比較例1)ポリエステルカットファイバ
ー6デニールと、高吸水性繊維5デニールを混綿し、シ
ート状にしたものをニードルパンチングし目付を210
g/m2 に調整した不織布シートを作った。このときの
高吸水性繊維5デニールの混合比率は2%であった。こ
の不織布シート表面で測定した明度指数は52、遮光率
は70%であった。この不織布を水中に30分浸漬し、
充分吸水させた後300Gの遠心脱水を5分間行い、遠
心脱水後の水分率を測定したところ絶乾重量に対し15
0〜200%の水分を保持していた。
Comparative Example 1 A sheet obtained by mixing 6 denier polyester cut fiber and 5 denier superabsorbent fiber was needle-punched to obtain a basis weight of 210%.
A nonwoven sheet adjusted to g / m 2 was prepared. At this time, the mixing ratio of the 5 denier superabsorbent fiber was 2%. The lightness index measured on the surface of the nonwoven fabric sheet was 52, and the light blocking ratio was 70%. Immerse this nonwoven fabric in water for 30 minutes,
After sufficient water absorption, centrifugal dehydration at 300 G was performed for 5 minutes, and the water content after centrifugal dehydration was measured.
It retained 0-200% moisture.

【0013】(比較例2)比較例1と同じ条件で210
g/m2 の不織布シートを作った。ただし、高吸水性繊
維は全く使わず、ポリエステルカットファイバー6デニ
ールが100%のものとした。ポリエステルカットファ
イバーは比較例と同じく白度がやや実施例と異なるが重
合触媒の違いで物性は変わらない。この不織布シート表
面で測定した明度指数は50、遮光率は75%であっ
た。この不織布を水中に30分浸漬し、充分吸水させた
後300Gの遠心脱水を5分間行い、遠心脱水後の水分
率を測定したところ絶乾重量に対し20〜40%の水分
を保持していた。
(Comparative Example 2) Under the same conditions as in Comparative Example 1, 210
g / m 2 nonwoven sheet was made. However, no superabsorbent fiber was used at all, and polyester cut fiber 6 denier was 100%. The polyester cut fiber is slightly different in whiteness from the example as in the comparative example, but the physical properties are not changed due to the difference in the polymerization catalyst. The lightness index measured on the surface of the nonwoven fabric sheet was 50, and the light blocking ratio was 75%. This nonwoven fabric was immersed in water for 30 minutes, and after sufficiently absorbing water, centrifugal dehydration at 300 G was performed for 5 minutes, and the water content after centrifugal dehydration was measured. .

【0014】上記3種の不織布を昼間最高温度5℃、夜
間最低温度−10℃の屋外で、全面アスファルト舗装さ
れた駐車場の一部に各400m2 敷設し、夕方この上に
充分放水して不織布に含水させた。アスファルト舗装面
は駐車場であるため5/1000程度の勾配がつけられ
余剰水は排水溝へ排水される。昼間、ほぼ晴天で太陽光
が当たるこの場所で3日間放置し、3日後の夜間、3種
の不織布の凍結状況を調査した。この時の外気温は−5
℃であった。
The above three types of non-woven fabrics are laid 400 m 2 each in a part of an asphalt-paved parking lot outdoors at a daytime maximum temperature of 5 ° C. and a nighttime minimum temperature of −10 ° C. The nonwoven was hydrated. Since the asphalt pavement is a parking lot, it has a slope of about 5/1000 and excess water is drained to drains. In the daytime, it was left for 3 days in this place where it was almost clear and exposed to sunlight, and after 3 days at night, the freezing status of the three types of nonwoven fabrics was investigated. The outside temperature at this time is -5
° C.

【0015】調査結果、実施例の不織布は完全に水を含
んだまま氷結し、アスファルト舗装面に張り付き、氷の
状態も比較例より透明で硬く、舗装面から剥すことがで
きなかった。これに対し、比較例1、比較例2は不織布
内に水が無い状態で、空隙が多く、不織布繊維が白く浮
き上がり、不織布シートが折れ易く容易にアスファルト
面から剥ぎ取ることができた。
As a result of the investigation, the nonwoven fabric of the example was frozen while completely containing water, stuck to the asphalt pavement surface, and the state of ice was clearer and harder than that of the comparative example and could not be peeled off from the pavement surface. On the other hand, Comparative Examples 1 and 2 had no voids in the non-woven fabric, had many voids, the non-woven fibers floated up white, and the non-woven fabric sheet was easily broken and easily peeled off from the asphalt surface.

【0016】これら比較例は、昼間の温度上昇と共に太
陽光の熱線によるアスファルト地表面の温度上昇が著し
く、夜間凍結した水が融解流出してしまったものと思わ
れ、アイスベースとしてはグレードの低いものと判断さ
れた。実施例の不織布は、この後、含水凍結した上に散
水したところさらに凍結し、これを繰り返したところス
ケートリンクとして適切な氷盤が形成され、良好なアイ
スベースが中に入っており、地温の上昇を防ぐため、翌
日以降、昼間も融解流出せず安定した氷盤が得られた。
In these comparative examples, the temperature rise of the asphalt ground surface due to the heat rays of the sunlight was remarkable with the rise of the daytime temperature, and it is considered that the water frozen at night was melted and flown out. Was determined to be. After that, the nonwoven fabric of the example was further frozen when it was sprinkled on water and then sprinkled, and when this was repeated, a suitable ice plate was formed as a skating rink, and a good ice base was contained therein. In order to prevent the rise, a stable ice floe was obtained without melting out during the day after the next day.

【0017】作用について効果と共に説明する。The operation and effects will be described.

【0018】[0018]

【発明の効果】本発明は、上述の通り構成されているの
で次に記載する効果を奏する。 1.雪の圧雪、ならし作業等、多大な労力が不要とな
る。 2.気温が上昇し易い、シーズンの早い時期から遅い時
期まで保冷し氷の状態が良好である。 3.設置場所を選ばない。すなわち、排水性の良い砂利
の上、凹凸の激しい場所、さらに傾斜面、垂直面にも施
工可能で、また、地温の上がり易いアスファルト舗装面
でもリンクの設置が可能である。 4.保冷効果が良く硬い氷ができる。 5.氷盤にシート状アイスベースが入っているため氷の
補強効果がある。 6.クラックが入りにくいので、地震等地盤変化にも耐
えることができる。
Since the present invention is configured as described above, the following effects can be obtained. 1. A great deal of labor such as snow compaction and leveling work is not required. 2. The temperature is easy to rise and the ice condition is good from early in the season to late in the season. 3. We do not choose setting place. In other words, it can be installed on gravel with good drainage properties, on places with severe unevenness, and on inclined or vertical surfaces, and links can be installed on asphalt pavement surfaces where the ground temperature tends to rise. 4. Good cold insulation effect and hard ice. 5. Since the ice base contains a sheet-like ice base, it has the effect of reinforcing the ice. 6. Since it is hard to crack, it can withstand ground changes such as earthquakes.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 佐々木 志郎 東京都目黒区下目黒2丁目2番16号 繊 維土木開発株式会社内 (72)発明者 滝 瑛一路 大阪市北区堂島浜二丁目2番8号 東洋 紡績株式会社内 (56)参考文献 特開 平5−309155(JP,A) ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Shiro Sasaki 2-2-16-1 Shimomeguro, Meguro-ku, Tokyo Within Textile Engineering and Construction Co., Ltd. (72) Inventor Eiichi Taki 2-2-2 Dojimahama, Kita-ku, Osaka-shi No. 8 Inside Toyo Spinning Co., Ltd. (56) References JP-A-5-309155 (JP, A)

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 水中に浸漬し、充分吸水させた後、30
0Gで5分間遠心脱水後の水分率が200%以上の保水
能力を有するシート状物で、かつ表面の明度指数が60
以上、シート全体の遮光率が80%以上であることを特
徴とする氷盤形成用アイスベース材。
1. After immersing in water and absorbing water sufficiently, 30
A sheet having a water retention capacity of 200% or more after centrifugal dehydration at 0 G for 5 minutes and a surface lightness index of 60
As described above, the ice base material for forming an ice plate, wherein the light shielding ratio of the entire sheet is 80% or more.
JP29729093A 1993-11-01 1993-11-01 Ice base material for ice plate formation Expired - Lifetime JP2630367B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29729093A JP2630367B2 (en) 1993-11-01 1993-11-01 Ice base material for ice plate formation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29729093A JP2630367B2 (en) 1993-11-01 1993-11-01 Ice base material for ice plate formation

Publications (2)

Publication Number Publication Date
JPH07124289A JPH07124289A (en) 1995-05-16
JP2630367B2 true JP2630367B2 (en) 1997-07-16

Family

ID=17844604

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29729093A Expired - Lifetime JP2630367B2 (en) 1993-11-01 1993-11-01 Ice base material for ice plate formation

Country Status (1)

Country Link
JP (1) JP2630367B2 (en)

Also Published As

Publication number Publication date
JPH07124289A (en) 1995-05-16

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