JP2619404B2 - Non-woven coated material with excellent printability - Google Patents
Non-woven coated material with excellent printabilityInfo
- Publication number
- JP2619404B2 JP2619404B2 JP62205150A JP20515087A JP2619404B2 JP 2619404 B2 JP2619404 B2 JP 2619404B2 JP 62205150 A JP62205150 A JP 62205150A JP 20515087 A JP20515087 A JP 20515087A JP 2619404 B2 JP2619404 B2 JP 2619404B2
- Authority
- JP
- Japan
- Prior art keywords
- coating
- nonwoven fabric
- coating liquid
- layer
- undercoat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明はすぐれた印刷性を有する不織布塗工物に関す
る。Description: FIELD OF THE INVENTION The present invention relates to a nonwoven fabric coating having excellent printability.
不織布は裁断面がホツレない、織物ライクである、適
度な物性を有している等の特徴を生して数多くの用途で
使用されていることは周知のとおりである。しかしなが
ら不織布は紙やフィルムに比べてその地合の不均一性が
極めて大きく、又多孔性であるため、不織布に直接印刷
した場合、（ｉ）インキの所要量が多い、（ii）インキ
光沢が出ない、（iii）インキの裏抜けによる汚れ、ブ
ロッキング等のトラブルが発生する、（iv）グラビア印
刷の網点再現性が悪く、印刷上りが不鮮明である等の欠
点があり、一部の用途以外には不織布に印刷しても商品
価値が認められていないのが実状である。It is well known that non-woven fabrics are used in many applications because of their features such as non-frayed cut surfaces, woven-like shapes, and appropriate physical properties. However, non-woven fabrics have extremely large non-uniformity in formation compared to paper and film, and are porous. Therefore, when directly printed on non-woven fabrics, (i) a large amount of ink is required, and (ii) ink gloss is high. There are drawbacks such as no printing, (iii) troubles such as smearing and blocking caused by ink strike-through, and (iv) poor dot reproducibility of gravure printing and unclear printing finish. In fact, no commercial value has been recognized even when printed on non-woven fabrics.
かかる欠点を解消する方法として、紙の印刷適性を向
上させる公知の方法、すなわちクレー顔料を主成分とす
る塗料を紙に塗工するクレーコート法が考えられる。し
かしながらこの公知の方法を不織布に応用した場合、不
織布の地合の不均一性ならびに多孔性であるため、塗料
が裏抜けして工程トラブルを引き起したり、塗料の所要
量が必要以上に消費され、その結果不織布が本来有して
いるドレープ性が損われかつ物性、特に引裂強力の低下
が著しく実用化には到っていないのが現状である。As a method for solving such a defect, a known method for improving the printability of paper, that is, a clay coating method in which a paint containing a clay pigment as a main component is applied to paper can be considered. However, when this known method is applied to a nonwoven fabric, the nonuniformity of the formation of the nonwoven fabric and the porosity of the nonwoven fabric cause the paint to strike through and cause a process trouble, or the required amount of the paint is consumed more than necessary. As a result, the drapability inherent to the nonwoven fabric is impaired, and the physical properties, particularly the tear strength, are remarkably reduced.
そこで本発明は不織布のすぐれた特性を保持しつつ且
つ印刷性にすぐれた不織布塗工物を提供することを目的
とする。Therefore, an object of the present invention is to provide a nonwoven fabric coated material having excellent printability while maintaining excellent characteristics of the nonwoven fabric.
本発明の目的は不織布の片面又は両面に固形分として
3g/m2〜20g/m2のアンダーコート層を介して、顔料とバ
インダーを含む塗料層を設けて成る不織布塗工物によっ
て達成される。The purpose of the present invention is as a solid on one or both sides of the nonwoven fabric.
Via an undercoat layer of 3g / m 2 ~20g / m 2 , it is achieved by non-woven fabric coating composed by providing a coating layer containing a pigment and a binder.
以下本発明を詳細に説明する。本発明の特徴は不織布
と顔料とバインダーを含む塗料層（以下塗工層と称す
る）との間にアンダーコート層を設け、顔料とバインダ
ーを含む塗料液（以下塗工液と称する）の不織布への浸
透を適度に抑制し薄い塗工層で平滑な表面を有する塗工
層を設けていることにある。その際アンダーコート層に
対する塗工液の濡れ角度が50度から100度の範囲になる
ような組合せでアンダーコート剤ならびに塗工液を選定
するとより好ましい。Hereinafter, the present invention will be described in detail. A feature of the present invention is that an undercoat layer is provided between a nonwoven fabric and a paint layer containing a pigment and a binder (hereinafter, referred to as a coating layer) to form a coating liquid containing a pigment and a binder (hereinafter, referred to as a coating liquid) into a nonwoven fabric. Is to provide a coating layer having a smooth surface with a thin coating layer. In this case, it is more preferable to select the undercoat agent and the coating liquid in such a combination that the wetting angle of the coating liquid to the undercoat layer is in the range of 50 to 100 degrees.
本発明で用いられる不織布は短繊維、すなわちステー
プルファイバーをカード法によりシート化し、しかる後
バインダーで接合されたもの、又はサーマルボンド法で
接合されたいわゆる短繊維不織布及びスパンボンド法で
つくられた長繊維不織布、ニードルパンチ法でつくられ
た不織布等各種の不織布を対象とし、且つ用いられる繊
維の種類についてもナイロン、ポリエステル、ポリプロ
等の合成繊維ならびに再生繊維及び天然繊維等の各種の
繊維が対象となる。しかし、不織布の強度、耐熱性、耐
久性及び寸法安定性等総合的にすぐれた品質特徴を有す
るポリエステル繊維からなるスパンボンド法からつくら
れ、且つ部分的に熱圧着されたポリエステル系の長繊維
不織布で不織布を構成する繊維の繊度は1.0〜10.0デニ
ールの範囲の不織布を用いるとより好ましい。The nonwoven fabric used in the present invention is a short fiber, that is, a staple fiber formed into a sheet by a card method and then bonded with a binder, or a so-called short fiber nonwoven fabric bonded by a thermal bond method and a long fiber formed by a spun bond method. Various types of non-woven fabrics such as fiber non-woven fabrics and non-woven fabrics made by the needle punch method are targeted, and the types of fibers used are also synthetic fibers such as nylon, polyester, polypropylene, etc., and various fibers such as regenerated fibers and natural fibers. Become. However, polyester-based long-fiber non-woven fabrics made by the spunbond method consisting of polyester fibers that have comprehensively excellent quality characteristics such as strength, heat resistance, durability and dimensional stability of the non-woven fabric and are partially thermocompressed The fineness of the fibers constituting the nonwoven fabric is more preferably in the range of 1.0 to 10.0 denier.
不織布の目付（１平方メートル当りのグラム数）は20
g/m2以上が好ましい。目付が20g/m2以下の不織布では地
合の不均一性が著しく、本発明の方法をもってしても塗
工液を塗工する際塗工液の裏抜けにより工程トラブルを
引き起したり、本発明の目的とする均一塗工層の形成が
極めて困難である。不織布の目付の高い方は特に限定さ
れるものではなく、目的とする商品により選択されれば
よい。Nonwoven fabric weight (grams per square meter) is 20
g / m 2 or more is preferable. In the nonwoven fabric having a basis weight of 20 g / m 2 or less, the non-uniformity of the formation is remarkable, and even when using the method of the present invention, when applying the coating liquid, a process trouble is caused by strikethrough of the coating liquid, It is extremely difficult to form a uniform coating layer for the purpose of the present invention. The higher the basis weight of the nonwoven fabric is not particularly limited, and may be selected depending on the intended product.
次に本発明で重要であるアンダーコート層に対する塗
工液の濡れ角度の関係について詳述する。本発明で称す
るアンダーコート層に対する塗工液の濡れ角度（以下濡
れ角度と称する）とは、ポリエステルフィルム（東レル
ミラー＃ 125−Ｔ）にアンダーコート剤をバーコーター
No.28で塗工し、140℃、２分間乾燥し約10ミクロンの厚
みの塗膜を形成させる。しかる後アンダーコート剤の塗
膜の上に約0.1ccの塗工液を滴下し、アンダーコート剤
の塗膜と塗工液の接触角を直読式ゴニオメーターで読み
とり、その角度を本発明では濡れ角度と称する。なお、
本発明では直読式ゴニオメーターとして、エルマ光学
（株）社製、エルマゴニオメーター式接触計を用いた。Next, the relationship of the wetting angle of the coating liquid to the undercoat layer, which is important in the present invention, will be described in detail. The wetting angle (hereinafter referred to as the wetting angle) of the coating liquid with respect to the undercoat layer referred to in the present invention means that the polyester film (East Lell mirror # 125-T) is coated with an undercoat agent using a bar coater.
Coat with No.28 and dry at 140 ° C for 2 minutes to form a film with a thickness of about 10 microns. Thereafter, about 0.1 cc of the coating solution is dropped on the undercoat agent coating film, the contact angle between the undercoat agent coating film and the coating solution is read by a direct-reading goniometer, and the angle is wet in the present invention. Called angle. In addition,
In the present invention, an elma goniometer type contact meter manufactured by Elma Optical Co., Ltd. was used as a direct reading goniometer.
濡れ角度は50度から100度の範囲、更に好しくは60度
から90度の範囲になるようにアンダーコート剤ならびに
塗工液を選定しなければならない。濡れ角度が50度未満
の場合は塗工液がアンダーコート層を介して不織布繊維
層へ浸透し、均一な塗工層を得るためには多量の塗工液
が必要であるのみならず、不織布の柔軟性が失なわれ、
塗工物の引裂強度の低下が著しい。濡れ角度が100度以
上の場合は塗工液の撥液現象による塗工ムラが発生し均
一な塗工層を得ることができ難く、かつ不織布と塗工層
との接着強度の低下が著しい。The undercoat agent and the coating solution must be selected so that the wetting angle is in the range of 50 to 100 degrees, more preferably in the range of 60 to 90 degrees. If the wetting angle is less than 50 degrees, the coating liquid penetrates into the nonwoven fiber layer through the undercoat layer, and not only a large amount of coating liquid is required to obtain a uniform coating layer, but also the nonwoven cloth Loses the flexibility of
The tear strength of the coated product is significantly reduced. When the wetting angle is 100 degrees or more, coating unevenness occurs due to the liquid repellency of the coating liquid, making it difficult to obtain a uniform coating layer, and significantly lowering the adhesive strength between the nonwoven fabric and the coating layer.
アンダーコート剤としては、アクリル系、ポリエステ
ル系、メラミン系等の合成樹脂エマルジョン又はPVA、
澱粉、CMC等の水溶性高分子溶液の単独又は混合したも
のを用いることができる。アンダーコート剤の不織布に
対する塗工量は固形分として約3g/m2から約20g/m2の範
囲が好しいが、この範囲に限定されるものではない。不
織布にアンダーコート剤を塗工する方法としては、ロー
ルコート法、ブレードコート法、エアーナイフコート法
等通常工業的に行われている方法で、特に限定されるも
のではない。塗工した後は通常工業的に行われている乾
燥機で水分を蒸発させる。As an undercoat agent, acrylic, polyester, melamine or other synthetic resin emulsion or PVA,
Water-soluble polymer solutions such as starch and CMC can be used alone or as a mixture. The coating amount relative to the nonwoven fabric of the undercoat agent in the range of from about 3 g / m 2 to about 20 g / m 2 as solids virtuous arbitrary, but is not limited to this range. The method for applying the undercoat agent to the nonwoven fabric is a method commonly used in the industrial field such as a roll coating method, a blade coating method, and an air knife coating method, and is not particularly limited. After the coating, the moisture is evaporated by a dryer which is usually used industrially.
本発明で称する塗工液とは、不織布に不透明性を与
え、かつ印刷性を向上させることを目的とする顔料、例
えばカオリン、酸化チタン、炭酸カルシューム等と顔料
のバインダー、例えばスチレン、ブタジエン、ラバーラ
テックス、ポリビニールアルコール水溶液等を成分とす
る、顔料とバインダーの混合溶液である塗料液であり、
各成分の組合せ、混合比率等に限定されるものではな
く、上記以外の添加剤、例えば消泡剤、界面活性剤等を
添加することも差しつかえない。The coating liquid referred to in the present invention is a pigment for imparting opacity to a nonwoven fabric and improving printability, for example, kaolin, titanium oxide, calcium carbonate and the like, and a binder for the pigment, for example, styrene, butadiene, and rubber. Latex, polyvinyl alcohol aqueous solution, etc., a coating solution that is a mixed solution of a pigment and a binder,
It is not limited to the combination and mixing ratio of each component, and additives other than the above, such as an antifoaming agent and a surfactant, may be added.
アンダーコート層に対する塗工液の濡れ角度の所定の
範囲の調整はラテックスの選定ならびに界面活性剤等の
添加剤を塗料液、クリヤー樹脂液に添加することにより
容易に調整することができる。不織布に塗工液を塗工す
る方法は、アンダーコート剤の塗工方法と同様通常工業
的に行われている方法でよく、塗工液の粘度等の性質と
必要とする塗工量を勘案して塗工方法を決めることがで
きる。塗工した後の乾燥は通常工業的に行われている乾
燥機を用いて水分を蒸発すればよい。The adjustment of the predetermined range of the wetting angle of the coating liquid to the undercoat layer can be easily adjusted by selecting a latex and adding an additive such as a surfactant to the coating liquid and the clear resin liquid. The method of applying the coating liquid to the non-woven fabric may be a method which is usually performed industrially, similar to the method of applying the undercoat agent, and takes into account properties such as the viscosity of the coating liquid and the required coating amount. And determine the coating method. Drying after coating may be performed by evaporating water using a drier usually used industrially.
不織布に対する塗工液の塗工量は不織布塗工物の用途
・目的ならびに不織布の表面形状等で影響を受け一概に
決めることはできないが、一般的には塗工層の均一性、
塗工物の柔軟性ならびに経済性等から塗工量は固形分と
して10〜100g/m2の範囲が好しいが、この範囲に限定さ
れるものではない。The amount of the coating liquid applied to the nonwoven fabric is affected by the application and purpose of the nonwoven fabric coating and the surface shape of the nonwoven fabric, and cannot be determined in a unified manner, but in general, the uniformity of the coating layer,
The coating amount is preferably in the range of 10 to 100 g / m 2 as a solid content from the viewpoint of flexibility and economy of the coating material, but is not limited to this range.
以下実施例により更に詳細に説明する。 Hereinafter, the present invention will be described in more detail with reference to examples.
実施例−１ 旭化成工業（株）社製ポリエステルパンボンドE5050
（目付50g/m2）の片面にアンダーコート剤をエアーナイ
フコート法で塗工し、熱風乾燥機で乾燥した。アンダー
コート剤の塗工量は固形分として7g/m2であった。使用
したアンダーコート剤の成分組成は次の通りである。Example-1 Polyester Pan Bond E5050 manufactured by Asahi Kasei Kogyo Co., Ltd.
An undercoating agent was applied to one surface of the fabric (with a basis weight of 50 g / m 2 ) by an air knife coating method, and dried with a hot air drier. The coating amount of the undercoat agent was 7 g / m 2 as a solid content. The component composition of the undercoat agent used is as follows.
薬品名 混合比率 （重量パーセント） ニカゾールAC（アクリルエマルジョン）−102 （日本カーバイト社） 50％ ポリマロン351（荒川科学社） （ウレタン水溶液） 20％ ミルベンSM850（昭和高分子社） （メラミン系水溶液） 30％ 次にアンダーコート剤を塗工した面に下記の組成の塗
料をエアーナイフコート法で塗工し、熱風乾燥機で乾燥
して不織布塗工物が得られた。Chemical name Mixing ratio (weight percent) Nicazole AC (acryl emulsion) -102 (Nippon Carbide) 50% Polymaron 351 (Arakawa Science) (urethane aqueous solution) 20% Milbene SM850 (Showa Kogakusha) (melamine aqueous solution) 30% Next, a paint having the following composition was applied to the surface coated with the undercoat agent by an air knife coating method, and dried with a hot air drier to obtain a nonwoven fabric coating.
＜塗工液の組成＞ 薬品名 混合比率 （重量パーセント） カオリンUW−90 （カオリン）（エンゲルバード社） 40 ％ チタンKA−100（チタン工業社） （酸化チタン） ５ ％ タマパールPCC（奥多摩工業社） （炭酸カルシューム） 20 ％ 旭化成ラテックスＬ−1622 （Ｓ・Ｂ・Ｒ）（旭化成工業社） 30 ％ ゴーセノールNH−18 （PVA）（日本合成化学工業社） 4.5％ 消泡剤Ｐ−822（東邦化学社） （炭化水素系鉱物油） 0.5％ なお、この組合せにおけるアンダーコート剤に対する
塗工液の濡れ角度は65度であった。<Composition of coating liquid> Chemical name Mixing ratio (% by weight) Kaolin UW-90 (Kaolin) (Engelbird) 40% Titanium KA-100 (Titanium Kogyo) (Titanium oxide) 5% Tamapearl PCC (Okutama Kogyo) (Calcium carbonate) 20% Asahi Kasei Latex L-1622 (SBR) (Asahi Kasei Kogyo) 30% Gohsenol NH-18 (PVA) (Nippon Synthetic Chemical Industry) 4.5% Defoamer P-822 (Toho) Chemical company) (hydrocarbon mineral oil) 0.5% The wetting angle of the coating liquid to the undercoat agent in this combination was 65 degrees.
実施例−２ 実施例−１で得られたアンダーコート剤を塗工した不
織布に下記の塗工液の組成の塗工液で実施例−１と同じ
塗工・乾燥方法により不織布の塗工物を得た。この組合
せにおけるアンダーコート剤に対する塗工液の濡れ角度
は90度であった。Example 2 A nonwoven fabric coated on the nonwoven fabric coated with the undercoat agent obtained in Example 1 by the same coating and drying method as in Example 1 using a coating solution having the following coating solution composition: I got The wetting angle of the coating liquid to the undercoat agent in this combination was 90 degrees.
＜塗工液の組成＞ 薬品名 混合比率 （重量パーセント） カオリンUW−90 40 ％ チタンKA−100 ５ ％ タマパールPCC 20 ％ 旭化成ラテックスＬ−1622 20 ％ ニカゾールAC−102 （アクリル酸エステル系エマルジョン） 10 ％ ゴーセノールNH−18 4.5％ 消泡剤Ｐ−822 0.5％ 比較例−１ 実施例−１と同じ不織布にアンダーコート剤を塗工せ
ずに直接実施例−１で用いた塗工液を実施例−１と同一
条件で塗工・乾燥した。塗工時には塗工液が不織布より
裏抜けし、工程の各種ロール等に塗工液が附着し、工程
トラブルが頻発した。<Composition of coating liquid> Chemical name Mixing ratio (weight percent) Kaolin UW-90 40% Titanium KA-100 5% Tamapearl PCC 20% Asahi Kasei latex L-1622 20% Nicazole AC-102 (acrylate ester emulsion) 10 % Gohsenol NH-18 4.5% Antifoaming agent P-822 0.5% Comparative Example-1 The same non-woven fabric as in Example-1 was coated directly with the coating liquid used in Example-1 without applying the undercoat agent. Coating and drying were performed under the same conditions as -1. During coating, the coating liquid slipped through the nonwoven fabric, and the coating liquid adhered to various rolls in the process, causing frequent process troubles.
比較例−２ 実施例−１で得られたアンダーコート剤を塗工した不
織布に実施例−１で用いた塗料に界面活性剤（日信化学
社のサーフィノール0.01重量パーセント）を添加しアン
ダーコート剤に対する塗工液の濡れ角度を40度に調整し
た塗工液を実施例−１と同一条件下で塗工・乾燥した。
大きな工程トラブルは無ったが、塗工時にはわずかな塗
工液の不織布からの裏抜け現象があった。Comparative Example 2 A surfactant (0.01% by weight of Nissin Chemical Co., Ltd., Surfynol) was added to the non-woven fabric coated with the undercoat agent obtained in Example 1 and added to the paint used in Example 1 to undercoat. The coating liquid in which the wetting angle of the coating liquid with respect to the agent was adjusted to 40 degrees was applied and dried under the same conditions as in Example-1.
Although there was no major process trouble, there was a phenomenon in which a slight amount of the coating liquid slipped through the nonwoven fabric during coating.
比較例−３ 実施例−１で得られたアンダーコート剤を塗工した不
織布に実施例−１で用いた塗工液の組成のうち、混合比
率をゴーセノールNH−18を4.95％、消泡剤Ｐ−822を0.0
5％に変え、濡れ角度を110度に調整した塗工液を用いて
実施例−１と同一条件で塗工・乾燥した。塗工時には塗
工液の著しい撥液現象が観察された。Comparative Example-3 In the composition of the coating solution used in Example-1, the mixing ratio of gohsenol NH-18 was 4.95%, and the defoaming agent was applied to the nonwoven fabric coated with the undercoat agent obtained in Example-1. P-822 to 0.0
The coating liquid was changed to 5%, and the coating liquid was adjusted and wetted at 110 degrees under the same conditions as in Example 1 and dried. At the time of coating, a remarkable lyophobic phenomenon of the coating liquid was observed.
以上実施例−１及び２、ならびに比較例−１〜３で得
られた不織布塗工物の物性を表−１に示す。The physical properties of the nonwoven fabric coatings obtained in Examples 1 and 2 and Comparative Examples 1-3 are shown in Table 1.
表−１から明らかなように、実施例−１及び２で得ら
れた不織布の塗工物は比較例−1,2に比べ網点再現性な
らびに引裂強力の性質において極めてすぐれており、こ
のことは不織布に塗工された塗工層が均一に形成されて
おり、かつ塗工液の不織布繊維層への浸透が抑制されて
いることを示している。 As is evident from Table 1, the coatings of the nonwoven fabrics obtained in Examples 1 and 2 are extremely superior in the halftone dot reproducibility and the tear strength as compared with Comparative Examples 1 and 2. Indicates that the coating layer applied to the nonwoven fabric is formed uniformly, and that the penetration of the coating liquid into the nonwoven fabric fiber layer is suppressed.
本発明の不織布塗工物は前述のように構成されている
ので、通常のコート紙に匹敵する程すぐれた印刷適性を
有しており、かつ引裂強力に代表される如く、不織布本
来有している物性を損うことなく、したがってこれまで
の不織布では望みえなかったすぐれた印刷された不織布
が得られ、巾広い用途へ応用できる。特にアンダーコー
ト剤に対する塗工液の濡れ角度を50度から100度の範囲
に選定することにより、不織布繊維層への塗工液の浸透
を適度に抑制し、比較的少量な塗工液で均一な塗工層を
形成することができる。Since the coated nonwoven fabric of the present invention is configured as described above, it has excellent printability comparable to ordinary coated paper, and has a natural nonwoven fabric as represented by tear strength. Thus, an excellent printed non-woven fabric, which was not expected with a conventional non-woven fabric, can be obtained without impairing the physical properties of the conventional non-woven fabric, and can be applied to a wide range of uses. In particular, by setting the wetting angle of the coating liquid to the undercoat agent in the range of 50 to 100 degrees, the penetration of the coating liquid into the nonwoven fabric fiber layer is appropriately suppressed, and a relatively small amount of the coating liquid is uniform. It is possible to form a suitable coating layer.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭61−41372（ＪＰ，Ａ) 特開 昭53−70194（ＪＰ，Ａ) 特開 昭59−22683（ＪＰ，Ａ) ────────────────────────────────────────────────── ─── Continuation of front page (56) References JP-A-61-41372 (JP, A) JP-A-53-70194 (JP, A) JP-A-59-22683 (JP, A)
Claims (2)
ジョン又は水溶性高分子溶液の単独又は混合物が固形分
として3g/m2〜20g/m2で塗工されたアンダーコート層を
介して、顔料とバインダーを含む塗料層を設けて成る不
織布塗工物。On one or both sides according to claim 1] non-woven fabric, through the undercoat layer alone or a mixture of synthetic resin emulsion or a water-soluble polymer solution was coated at 3g / m 2 ~20g / m 2 as a solid component, A non-woven fabric coated article provided with a paint layer containing a pigment and a binder.
工液のアンダーコート層に対する濡れ角度が50度から10
0度になるような組合わせで前記アンダーコート層と前
記塗料層が形成されていることを特徴とする特許請求の
範囲第１項記載の不織布塗工物。2. The method according to claim 1, wherein the wetting angle of the coating liquid used for forming the coating layer with respect to the undercoat layer is 50 to 10 degrees.
2. The non-woven fabric coated product according to claim 1, wherein the undercoat layer and the paint layer are formed in such a combination as to be 0 degrees.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62205150A JP2619404B2 (en) | 1987-08-20 | 1987-08-20 | Non-woven coated material with excellent printability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62205150A JP2619404B2 (en) | 1987-08-20 | 1987-08-20 | Non-woven coated material with excellent printability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6449639A JPS6449639A (en) | 1989-02-27 |
| JP2619404B2 true JP2619404B2 (en) | 1997-06-11 |
Family
ID=16502248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62205150A Expired - Fee Related JP2619404B2 (en) | 1987-08-20 | 1987-08-20 | Non-woven coated material with excellent printability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2619404B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010125799A (en) * | 2008-11-28 | 2010-06-10 | Asahi Kasei Fibers Corp | Print performance functional paper |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0580747U (en) * | 1992-04-07 | 1993-11-02 | オカモト株式会社 | A decorative sheet that excels in unevenness |
| CN114392908A (en) * | 2021-12-17 | 2022-04-26 | 沪东中华造船(集团)有限公司 | Method for spraying surface coating on fine cloth of faucet in cabin |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5370194A (en) * | 1976-11-29 | 1978-06-22 | Toray Industries | Printing sheet |
| JPS5922683A (en) * | 1982-07-28 | 1984-02-04 | Dynic Corp | Manufacture of lustrous sheet material for printing |
| JPS6141372A (en) * | 1984-07-30 | 1986-02-27 | ダイニツク株式会社 | Printing sheet |
| JPH0247009Y2 (en) * | 1984-12-17 | 1990-12-11 |
-
1987
- 1987-08-20 JP JP62205150A patent/JP2619404B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010125799A (en) * | 2008-11-28 | 2010-06-10 | Asahi Kasei Fibers Corp | Print performance functional paper |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6449639A (en) | 1989-02-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5600366B2 (en) | Paper and paper making method | |
| EP0825031B1 (en) | Fusible printable coating for durable images | |
| EP1914087B1 (en) | Synthetic nonwoven wallcoverings with aqueous ground coating | |
| US5759673A (en) | Ink jet recording sheet | |
| US20080107912A1 (en) | Multi-Layer Coated Products and Curtain Coating Process for Same | |
| KR20010100896A (en) | Paper having improved print quality and method of making the same | |
| KR20170082585A (en) | Thermal sublimation paper, method for the production thereof, and use thereof | |
| US10632778B2 (en) | Tacky microporous transfer material | |
| SK202004A3 (en) | Prepreg | |
| EP3302991A2 (en) | Transfer material for sublimation printing | |
| EP0663300B1 (en) | Ink jet recording sheet | |
| JP2619404B2 (en) | Non-woven coated material with excellent printability | |
| US4226749A (en) | Sizing composition with cationic and anionic component | |
| US3345196A (en) | Coated polyolefin sheets particularly for book covers and method of producing the same | |
| JP3794133B2 (en) | Coated printing paper that maintains the texture of the base paper before coating | |
| JP3555258B2 (en) | Matte coated paper with uncoated paper texture | |
| WO2004069550A1 (en) | Ink-jet recording sheet | |
| JP3087350B2 (en) | Printing sheet | |
| JPH04189173A (en) | Recording medium for printing | |
| JPH06212549A (en) | Printing base material and its production | |
| JP2003155371A (en) | Porous membrane, method for preparing the same and sheet having the same | |
| WO2023079510A1 (en) | Transfer paper for sublimation printing | |
| JP2005120502A (en) | Method for producing coated paper or paperboard | |
| JPH06262712A (en) | Manufacture of printing sheet | |
| JP5135855B2 (en) | Method for producing coated paper for printing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |